Contains Two Or More Graft Or Graft-type Copolymers Or A Graft Or A Graft Type Copolymer And At Least One Block Or Block-type Copolymer Patents (Class 525/71)
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Publication number: 20110224355Abstract: The present invention provides a thermoplastic resin composition for a vehicular lamp housing, which is excellent in balance of physical properties with regard to such as impact resistance and fluidity, and of which hot plate weldability, vibration weldability and laser weldability are improved when a vehicular lamp housing is welded with other members.Type: ApplicationFiled: September 9, 2009Publication date: September 15, 2011Applicant: NIPPON A&L INC.Inventors: Hajime Tomita, Tokuo Tatsuda, Tetsuya Yamamoto, Seiji Tamai
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Patent number: 8013062Abstract: The invention relates to the production and use of block copolymers which are obtained by means of controlled radical polymerization in the presence of nitroxides for the purpose of reinforcing fragile polymer matrices. The invention offers advantages such as (i) simplicity of copolymer synthesis and use and (ii) fine dispersion of the copolymer molecules in the fragile matrix, which ensures both the transparency of the material and high reinforcement against impact. More specifically, the invention relates to the radical synthesis of block copolymers comprising at least three blocks, which include one block having a glass transition temperature of less than 0° C. and a thermoplastic end block having a glass transition temperature of more than 0° C., thereby guaranteeing compatibility with the fragile matrix to be reinforced against impact.Type: GrantFiled: January 21, 2003Date of Patent: September 6, 2011Assignee: Arkema FranceInventors: Anne-Valerie Ruzette, Florence Chauvin, Olivier Guerret, Denis Bertin, Bruno Vuillemin, Ludwik Leibler, Pierre Gerard, Yannick Ederle
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Patent number: 8007919Abstract: The invention concerns a coextrusion binder comprising a mixture of at least one ethylene homo- or copolymer (A1) of density ranging between 0.940 and 0.980 g/cm3 with at least one propylene homo- or copolymer (B), said mixture being grafted by at least one functional monomer and optionally diluted in at least one non-grafted ethylene homo- or copolymer (A2) of density ranging between 0.940 and 0.980 g/cm3; the grafting rate of said coextrusion binder being less than 0.5% wt. % based on the total weight of said binder; the density of said tie ranging between 0.940 and 0.980 g/cm3. The invention also concerns a structure comprising said type of binder as well as its use.Type: GrantFiled: May 23, 2006Date of Patent: August 30, 2011Assignee: Arkema FranceInventors: Jerome Chauveau, Fabrice Chopinez, Arnaud Gerbaulet, Jean-Laurent Pradel
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Publication number: 20110187018Abstract: The invention relates to an improved process for controlling the amount of crosslinking in polyolefin based articles such as fibers or films. The invention relates to mixing silane grafted material together with ungrafted material prior to crosslinking. The article can then be formed and cured, optionally with a curing catalyst which can preferably be applied to the surface of a shaped article. The amount of crosslinking will be controlled in part by the level of silane grafting on the grafted silane material as well as the amount of the grafted material in the blend.Type: ApplicationFiled: November 15, 2010Publication date: August 4, 2011Applicant: Dow Global Technologies Inc.Inventors: Hong Peng, Jerry C. Wang, Hongyu Chen, John D. Weaver, Stephen E. Hill, Yushan Hu, Richard C. Abel
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Patent number: 7989083Abstract: To provide an acid-modified polypropylene resin which can be used for an adhesive capable of bonding a polyolefin type resin and a polar resin with sufficient force, its production process and a resin composition using it. An acid-modified polypropylene resin, which is obtained by grafting an organic acid component to a polypropylene resin, wherein the polypropylene resin is an isotactic polypropylene resin, the grafted amount X (wt %) of the organic acid component in the acid-modified polypropylene resin is within a range of from 1.0 wt % to 20.0 wt %, and the melt flow rate Y (g/10 min) of the acid-modified polypropylene resin satisfies the expression: Y?18.5 exp(0.82X), a process for producing such an acid-modified polypropylene resin, a resin composition using it and a laminate.Type: GrantFiled: April 28, 2006Date of Patent: August 2, 2011Assignee: Mitsubishi Chemical CorporationInventors: Kenichi Morikawa, Katsutoshi Ohno
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Patent number: 7956128Abstract: A thermoplastic resin composition for a refrigerator according to the present invention can include (A) about 20 to about 40 parts by weight of an acrylonitrile-butadiene-styrene graft copolymer resin prepared by grafting in emulsion polymerization about 60 to about 30% by weight of a monomer mixture comprising a cyanide vinyl compound and an aromatic vinyl compound to about 40 to about 70% by weight of a rubber polymer having an average particle size of about 0.1 to about 0.4 ?m; (B) about 1 to about 20 parts by weight of a styrenic copolymer comprising (b1) about 0 to about 75% by weight of a styrenic copolymer prepared by copolymerizing about 5 to about 20% by weight of a rubber polymer having an average particle size of about 0.Type: GrantFiled: June 28, 2007Date of Patent: June 7, 2011Assignee: Cheil Industries Inc.Inventors: Kang Yeol Park, Hee Jung Park, Jae Hyung Lee
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Publication number: 20110124813Abstract: Rubber-reinforced vinyl aromatic polymers having a strictly bimodal morphology, comprising from 55 to 90% by weight of a rigid polymeric matrix and from 10 to 45% by weight of a rubbery phase dispersed inside said rigid polymeric matrix, in the form of grafted and occluded particles and wherein said rubber particles consist of from 60 to 99% by weight of particles with a capsule or “core-shell” morphology and from 1 to 40% by weight of particles with a “salami” morphology, said percentages being measured on the basis of the weight of the rubber particles only.Type: ApplicationFiled: December 22, 2010Publication date: May 26, 2011Applicant: POLIMERI EUROPA S.p.A.Inventors: Alessandro CASALINI, Luca Monti, Anna Grazia Rossi
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Publication number: 20110097561Abstract: The present invention provides an optical film and s retardation film characterized in that each of them includes: an acrylic resin; and 20-65 parts by weight of at least two graft copolymers containing a conjugated diene-based rubber, based on 100 parts by weight of the acrylic resin, wherein at least two of the graft copolymers have different particle sizes. The present invention also provides a production method therefore.Type: ApplicationFiled: June 3, 2009Publication date: April 28, 2011Inventors: Byoung-II Kang, Chang-Hun Han, Chan-Hong Lee, Dae-Woo Lee, Jae-Bum Seo, Sang-Seop Kim
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Patent number: 7906576Abstract: Rubber-reinforced vinyl aromatic polymers having a strictly bimodal morphology, comprising from 55 to 90% by weight of a rigid polymeric matrix and from 10 to 45% by weight of a rubbery phase dispersed inside said rigid polymeric matrix, in the form of grafted and occluded particles and wherein said rubber particles consist of from 60 to 99% by weight of particles with a capsule or “core-shell” morphology and from 1 to 40% by weight of particles with a “salami” morphology, said percentages being measured on the basis of the weight of the rubber particles only.Type: GrantFiled: July 2, 2004Date of Patent: March 15, 2011Assignee: Polimeri Europa S.p.A.Inventors: Alessandro Casalini, Luca Monti, Anna Grazia Rossi
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Patent number: 7897686Abstract: The present invention relates to a method for preparing a graft rubber latex having a low residual monomer content, and more precisely, a method for preparing a graft rubber latex having a high rubber content, which is characterized by graft-copolymerization of a mixture of a rubber latex having a gel content of at least 95% and an average particle diameter of 2,500˜5000 ?, a monomer mixture comprising one or more compounds selected from a group consisting of aromatic vinyl compound, vinyl cyan compound and acrylate compound, and small particle size latex produced by emulsion polymerization. The method of the present invention has the advantages of speedy processes with excellent latex stability and at the same time reducing residual monomer content in the latex upon completion of the polymerization, improving perceived quality of the product and increasing yield.Type: GrantFiled: October 3, 2006Date of Patent: March 1, 2011Assignee: LG Chem, Ltd.Inventors: Joo-byung Chai, Chan-hong Lee, Keun-hoon Yoo, Jin-hyoung Lee, Jae-hwan Jung
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Publication number: 20110045295Abstract: A novel adhesive composition suitable for composing multilayered coatings onto large, industrial equipment such as pipeline tubes is devised. The composition is a blend based on a polyethylene which determines the blend's favorable properties, which polyethylene itself can be used further in coating cables and for producing mouldings, especially rotomoulded articles.Type: ApplicationFiled: February 18, 2009Publication date: February 24, 2011Applicant: Basell Polyolefine GmbHInventors: Heinz Vogt, Shahram Mihan, Gerd Mannebach, Gerhardus Meier, Joachim Berthold, Manfred Hecker
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Patent number: 7893156Abstract: The present invention provides a block copolymer or a hydrogenated product thereof excellent in low-temperature shrinkability, natural shrinkability, rigidity and the like, excellent in a balance of physical properties such as blocking resistance, resistance to fusion bonding in hot water, impact resistance and the like, and having a few fish eyes (FE's) caused by gels. Further, the invention provides a heat shrinkable film and a heat shrinkable multilayer film suitable for drink container packaging, cap seals and the like, using such a block copolymer or the hydrogenated product thereof.Type: GrantFiled: April 23, 2003Date of Patent: February 22, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Susumu Hoshi, Masahiro Mori, Yukio Yamaura, Toshinori Shiraki
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Patent number: 7847027Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.Type: GrantFiled: December 29, 2006Date of Patent: December 7, 2010Assignee: Eastman Kodak CompanyInventors: Peter J. Ghyzel, Joseph F. Bringley, David J. Giacherio, Lawrence P. DeMejo, Terry C. Schultz, Todd Emrick
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Patent number: 7829071Abstract: The present invention is directed to bimodal polymer compositions and personal care fixatives containing bimodal polymer compositions. The present invention includes a bimodal polymer composition having a first polymer with anionic character and a second polymer with cationic character and wherein the polymers form an interpenetrating polymer network. In one embodiment, the present invention also includes personal care fixatives (e.g., health care, hygiene or cosmetic compositions) containing the bimodal polymer composition. The present invention also includes methods for forming bimodal polymer compositions.Type: GrantFiled: March 8, 2005Date of Patent: November 9, 2010Assignee: Interpolymer CorporationInventors: Norwin W. Wolff, Timothy L. Martin, Thomas L. Hiff
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Patent number: 7824666Abstract: The present invention is directed to bimodal polymer compositions and personal care fixatives containing bimodal polymer compositions. The present invention includes a bimodal polymer composition having a first polymer with anionic character and a second polymer with cationic character and wherein the polymers form an interpenetrating polymer network. In one embodiment, the present invention also includes personal care fixatives (e.g., health care, hygiene or cosmetic compositions) containing the bimodal polymer composition. The present invention also includes methods for forming bimodal polymer compositions.Type: GrantFiled: October 14, 2008Date of Patent: November 2, 2010Assignee: Interpolymer CorporationInventors: Norwin W. Wolff, Timothy L. Martin, Thomas L. Hiff
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Patent number: 7824773Abstract: A polymer composition containing (a) a high impact polystyrene (HIPS) component with a block copolymer grafted to polystyrene, a rubbery conjugated diene content of one to seven weight percent based on HIPS weight, less than 10 weight-percent gel concentration, an average rubber particle size of between one and 0.01 micrometers, about 40 to about 90 volume percent of the rubber particles have diameters of less than about 0.4 microns and from about 10 to about 60 volume percent of the rubber particles have diameters between about 0.4 and about 2.5 microns, a majority of rubber particles with a core/shell morphology and a concentration that accounts for 10 to 70 weight-percent of the total polymer composition weight and one to five weight-percent rubbery diene based on total polymer composition weight; (b) from 10 to 70 weight percent of a general purpose polystyrene and from about 2 to about 80 weight-percent of a styrene block copolymer component, both based on total polymer composition weight.Type: GrantFiled: July 27, 2006Date of Patent: November 2, 2010Assignee: Dow Global Technologies Inc.Inventors: Robert L. McGee, Stephen J. Skapik, III
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Patent number: 7820762Abstract: Disclosed is a resin composition having excellent impact resistance and resistance to whitening by impact without deteriorating excellent transparency of a methacrylic resin. Specifically, an impact resistance modifier composed of a multilayered polymer having at least three layers, namely an innermost-layer polymer derived from an alkyl methacrylate, an intermediate-layer polymer derived from an alkyl acrylate and an outer-layer polymer having its Tg within the range of 20 to 80° C., wherein mass average particle diameter of the intermediate-layer polymer is 200 to 300 nm and the mass ratio of each layer is within an appropriate range, is blended with a methacrylic resin.Type: GrantFiled: March 28, 2005Date of Patent: October 26, 2010Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Toshio Nagasaka, Toshimi Yanai, Hiroki Hatakeyama
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Patent number: 7790804Abstract: The invention provides a process for the purification of polymer polyols that ensures a reduction of acrylonitrile, styrene as well as the residual amounts of optionally used chain regulator, and of occurring recombination products of the initiator when azo initiators are used, to levels of <25 ppm of acrylonitrile, <50 ppm styrene, <50 ppm chain regulator and <280 ppm of recombination products by stripping using packed columns.Type: GrantFiled: June 22, 2007Date of Patent: September 7, 2010Assignee: Bayer MaterialScience AGInventors: Michael Brockelt, Ludwig Deibele, Manfred Dietrich, Markus Hadley, Jan Thomas Leu, Guido Naberfeld, Ralf Dohrn
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Patent number: 7776964Abstract: The thermoplastic ABS resin composition according to the present invention comprises (a) 2 to 25 parts by weight of a graft copolymer particle containing rubbers having a volume average particle diameter range from 0.05 ?m to less than 0.18 ?m; (b) 2 to 25 parts by weight of a graft copolymer particle containing rubbers having a volume average particle diameter range from 0.18 ?m to less than 0.4 ?m; (c) 2 to 18 parts by weight of a graft copolymer particle containing rubbers having a volume average particle diameter range from 0.4 ?m to less than 4 ?m; (d) 10 to 70 parts by weight of a branched vinyl cyanide-vinyl aromatic copolymer; and (e) 1 to 60 parts by weight of a long-chain linear vinyl cyanide-vinyl aromatic copolymer.Type: GrantFiled: March 31, 2005Date of Patent: August 17, 2010Assignee: Cheil Industries Inc.Inventors: Bang Duk Kim, Jae Ho Yang, Tae Uk Kim
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Patent number: 7776963Abstract: Adhesive formulations having acrylate monomer or methacrylate monomer, or mixtures thereof, and having a reducing agent and an initiator (e.g., peroxide). The formulations may include a chelating agent solution to improve storage stability and other properties. Further, the mole ratio of the initiator to the reducing agent may be adjusted to control weight loss of the adhesives during cure. Polyvinyl acetate or its derivatives may also be employed in the adhesive formulations to reduce weight loss during cure. Moreover, certain embodiments of the formulations include a toughening-agent copolymer having a glass transition temperature (of at least one domain) that is lower than ?50° C. (?58° F.). These toughening-agent copolymers may be added to the adhesive formulations to improve impact strength and other properties of the cured adhesives at lower temperatures, e.g., ?40° C. (?40° F.), while maintaining performance of the cured adhesives at higher temperatures, e.g., 82° C. (180° F.).Type: GrantFiled: May 3, 2005Date of Patent: August 17, 2010Assignee: Illinois Tool Works Inc.Inventors: Xiaobin Wang, Daniel K. Doe, Patricia M. Savory, Kenneth A. Lambert
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Publication number: 20100168332Abstract: Disclosed are a polylactic acid resin composition that includes (A) about 10 to about 80 wt % of a polylactic acid resin; (B) about 5 to about 50 wt % of a rubber modified vinyl-based graft copolymer; (C) about 10 to about 80 wt % of a vinyl-based copolymer; and (D) about 5 to about 75 wt % of poly(meth)acrylic acid alkyl ester, and a molded product made using the same.Type: ApplicationFiled: December 30, 2009Publication date: July 1, 2010Applicant: CHEIL INDUSTRIES INC.Inventors: Young-Mi CHUNG, Doo-Han HA, Chang-Do JUNG
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Publication number: 20100116435Abstract: The invention relates to a composition for an acrylic structural adhesive containing a mixture of block copolymers, of elastomer and of elastomeric polymer particles.Type: ApplicationFiled: April 4, 2008Publication date: May 13, 2010Applicant: JacretInventors: Arnaud Curet, Régis David
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Patent number: 7709573Abstract: A thermoplastic molding composition having improved properties is disclosed. The composition comprises polycarbonate resin, a first graft polymer, a first free copolymer, a second graft polymer and a second free copolymer; the weight-average molecular weight of the first free copolymer being lower by at least 32,000 g/mol with regard to that of the second free copolymer. The inventive composition features improved balance of melt flowability and ductility, good resistance to hydrolysis and process stability.Type: GrantFiled: December 5, 2006Date of Patent: May 4, 2010Assignee: Bayer MaterialScience AGInventors: Thomas Eckel, Andreas Seidel, Dieter Wittmann
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Publication number: 20100105836Abstract: The present invention provides a thermoplastic resin composition excellent in impact resistance, delamination resistance and surface appearance The present invention relates to a thermoplastic resin composition comprising: 5 to 95% by mass of an aliphatic polyester (A), 4 to 94% by mass of an olefin-based resin (B) and 1 to 40% by mass of an aromatic vinyl-based polymer (C) where the total amount of component (A), component (B) and component (C) is 100% by mass, the aromatic vinyl-based polymer (C) being at least one selected from: an aromatic vinyl-based polymer (C1) which is an elastomer comprising a block copolymer comprising a polymer block mainly comprising an aromatic vinyl compound and a polymer block mainly comprising a conjugated diene compound, an aromatic vinyl-based polymer (C2) which is an elastomer obtained by hydrogenation of the aromatic vinyl-based polymer (C1), and an aromatic vinyl-based polymer (C3) which is a graft copolymer obtained by polymerizing a vinyl-based monomer containing anType: ApplicationFiled: September 27, 2007Publication date: April 29, 2010Inventors: Masaaki Mawatari, Tatsuya Toneri
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Patent number: 7705089Abstract: A rubber-modified styrene resin composition having excellent impact resistance, high tensile strength, and good moldability is provided. The present invention is accomplished by a rubber-modified styrene resin composition containing 99.9 to 97 percent by weight of a rubber-modified styrene resin (E) and 0.1 to 3 percent by weight of a polyorganosiloxane-containing graft copolymer (D), the polyorganosiloxane-containing graft copolymer (D) being a specific copolymer prepared with a polyorganosiloxane (A) produced by polymerizing 99.9 to 99.6 percent by weight of a organosiloxane with 0.1 to 0.4 percent by weight of a graft-linking agent.Type: GrantFiled: May 28, 2004Date of Patent: April 27, 2010Assignee: Kaneka CorporationInventors: Takao Shibata, Akira Takaki, Kazunori Saegusa
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Patent number: 7674855Abstract: A thermoplastic molding composition having improved melt flow and chemical resistance is disclosed. The composition contains A) at least one member selected from the group consisting of aromatic polycarbonate and polyester carbonate, B) a graft polymer of at least one vinyl monomer on at least one rubber having a glass transition temperature of <10° C. as graft base and C) vinyl (co)polymer having weight-average molecular weight of 1500 to 5000 g/mol and glass transition temperature of >40° C. The composition may optionally further contain D) a phosphorus-based flame retardant and E) an anti-dripping agent.Type: GrantFiled: June 18, 2004Date of Patent: March 9, 2010Assignee: Bayer MaterialScience AGInventors: Andreas Seidel, Thomas Eckel, Marc Vathauer
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Publication number: 20100048816Abstract: The present invention relates to a methacryl resin composition having excellent impact strength and transmittancy, and more specifically, to a graft copolymer prepared by preparing graft prepolymer by inputting a monomer mixture comprising 60 to 100 wt % of alkyl methacrylate, and 0 to 40 wt % of one or more compound selected from a group consisting of aromatic vinyl compound and alkyl acrylate compound to perform graft polymerization and adding acid, salt, or polymer coagulant when the monomer conversion of the polymerization is 70% to 95% and then continuously performing the polymerization to have an increased particle size to 100 to 500 nm in a graft polymerization process among processes of preparing the graft polymer including a seed-rubber core-graft polymerization process, a preparing method thereof, and a methacryl resin composition including the graft polymer.Type: ApplicationFiled: August 20, 2009Publication date: February 25, 2010Applicant: LG CHEM, LTD.Inventors: Dong-jo Ryu, Jeong-heon Ahn, Se-eun Lee
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Patent number: 7655726Abstract: The present invention relates to novel molding compositions based on semicrystalline engineering thermoplastics which, in conventional processing techniques, give moldings with reduced surface gloss. A feature of the molding compositions is that they comprise, in a polymer matrix, if appropriate with the usual additives, polymer particles with a median size d50 of from 0.1 ?m to 100 ?m, and comprise at least one other incompatible or semicompatible polymer which has not been chemically crosslinked, and also, if appropriate, comprise salt-like additives. The invention further relates to moldings which are produced by means of conventional processing techniques, in particular via injection molding, from these matt-effect molding compositions.Type: GrantFiled: March 28, 2008Date of Patent: February 2, 2010Assignee: Ticona GmbHInventors: Joachim Clauss, Christine Kostler, Arnold Schneller, Klaus Kurz
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Patent number: 7642316Abstract: The present invention is a rubber modified monovinylidene aromatic polymer composition which can be used in conventional thermoforming or other highly orienting forming or shaping processes to produce tough, cost effective, transparent containers or other packaging materials.Type: GrantFiled: July 28, 2005Date of Patent: January 5, 2010Assignee: Dow Global Technologies, Inc.Inventors: Jose M. Rego, Aude G. Pochon, Amaia Montoya-Goni
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Patent number: 7638574Abstract: This invention is based upon the discovered that crosslinked core-shell particles can be used as a filler in low cost emulsion styrene-butadiene rubber (ESBR) with excellent results being attained. In fact, such core-shell particle filled ESBR exhibits performance similar to silica filled solution styrene-butadiene rubber (SSBR) in terms of dynamic response, Payne effect, rebound and tan ? at 0° C. and 100° C. The utilization of such crosslinked core-shell particles in rubber compounds offers the additional advantage of weight reduction since the core-shell particles are significantly less dense than carbon black or silica fillers. The use of the crosslinked core-shell polymers of this invention in rubber formulations in place of silica also offers the advantage of not needing any expensive silane coupling agents to attain required levels of polymer/filler interaction. Accordingly, no silane coupling agent is used in the rubber compounds of this invention which leads to reduced cost.Type: GrantFiled: June 30, 2005Date of Patent: December 29, 2009Assignee: The Goodyear Tire & Rubber CompanyInventors: Ping Zhang, Lei Zheng, Feng Anne Xie, Eric Sean Castner
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Publication number: 20090275700Abstract: A propylene-based polymer composition for adhesive use and a laminate structure thereof are provided, wherein decrease of bonding strength is prevented when the laminate structure is formed and heat treatment is applied and whitening in bending process is suppressed. Provided are a propylene-based polymer composition (D) for adhesive use comprising (i) 40 to 92 wt % of a graft-modified polypropylene (A); (ii) 5 to 30 wt % of an ethylene.?-olefin copolymer (B) having a melt flow rate (MFR) of 0.01 to 10 g/10 min at 230° C. under a load of 2.16 kg and a density of 0.940 g/cm3 or less; and (iii) 3 to 30 wt % of a block copolymer (C) composed of an olefin crystalline segment and an ethylene.?-olefin segment, wherein the sum of (A), (B) and (C) is 100 wt %, and a laminate comprising at least one layer of the propylene-based polymer composition for adhesive use.Type: ApplicationFiled: March 24, 2006Publication date: November 5, 2009Inventors: Hideki Mochizuki, Shigeyuki Yasui, Seiji Ota
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Publication number: 20090269531Abstract: Disclosed is a resinous composition having reduced susceptibility to scratch formation during abrasion of its surface, wherein the composition comprises: (i) 10-40 wt. %, based on the weight of resinous components in the composition, of at least one rubber modified thermoplastic resin comprising a discontinuous elastomeric phase dispersed in a first rigid thermoplastic phase, wherein at least a portion of the first rigid thermoplastic phase is grafted to the elastomeric phase, and wherein the elastomeric phase comprises structural units derived from a monomer selected from the group consisting of butadiene and butadiene-styrene mixture; and wherein the first rigid thermoplastic phase comprises structural units derived from at least one vinyl aromatic monomer, at least one monoethylenically unsaturated nitrile monomer, and optionally at least one (C1-C12)alkyl- and aryl-(meth)acrylate monomer; and (ii) 90-60 wt.Type: ApplicationFiled: October 23, 2008Publication date: October 29, 2009Inventors: Dominique Arnould, Frank Huijs, Ronald Akkermans
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Publication number: 20090246533Abstract: The invention concerns a coextrusion binder comprising a mixture of at least one ethylene homo- or copolymer (A1) of density ranging between 0.940 and 0.980 g/cm3 with at least one propylene homo- or copolymer (B), said mixture being grafted by at least one functional monomer and optionally diluted in at least one non-grafted ethylene homo- or copolymer (A2) of density ranging between 0.940 and 0.980 g/cm3, the grafting rate of said coextrusion binder being less than 0.5 wt. % based on the total weight of said binder; the density of said binder ranging between 0.940 and 0.980 g/cm3. The invention also concerns a structure comprising said type of binder as well as its use.Type: ApplicationFiled: May 23, 2006Publication date: October 1, 2009Applicant: Arkema FranceInventors: Jerome Chauveau, Fabrice Chopinez, Arnaud Gerbaulet, Jean-Laurent Pradel
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Patent number: 7592392Abstract: The present invention relates to a novel process for the preparation of solid-supported scavenging reagents and solid-supported functional polymers. The invention further relates to novel solid-supported functional polymers and to their use in organic synthesis and combinatorial chemistry.Type: GrantFiled: March 31, 2004Date of Patent: September 22, 2009Assignee: Merck & Co. Inc.Inventors: Craig W. Lindsley, David D. Wisnoski
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Patent number: 7569638Abstract: To provide a thermoplastic elastomer composition which is excellent in light resistance and flexibility and has high tear strength. [MEANS FOR SOLVING PROBLEMS] A thermoplastic elastomer composition comprising 100 parts by mass of acrylic multi-layer polymer particles (A) which each comprise at least two layers, i.e., at least one inner rubber layer (I) and at least one outermost thermoplastic resin layer (II), 5 to 300 parts by mass of an ethylene/vinyl ester copolymer (B), and 0.5 to 150 parts by mass of a graft copolymer (C) composed of an ethylene/vinyl ester copolymer backbone and a graft bonded to the backbone which consists of units derived from a monomer having a polarity higher than that of the backbone.Type: GrantFiled: April 25, 2005Date of Patent: August 4, 2009Assignee: Kuraray Co., Ltd.Inventors: Hiroshi Ozawa, Yuichi Katoh, Motohiro Fukuda
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Patent number: 7560520Abstract: Methods and systems for modifying a polymer are disclosed herein. A matrix is generally provided having a surface thereof, wherein the matrix comprises a plurality of hyperbranched polymers. The plurality of hyperbranched polymers can be chemically bound to a plurality of surfactants or order to modify the surface and produce a polymeric material thereof. The surface is tailored with a plurality of functional groups that self-assemble and are deliverable to the surface of the solution, including interfaces thereof, thereby permitting a high-density assembly of functional groups to operate in concert with one another in order to generate a modified surface thereof. The polymeric material produced thereof can be reversibly adaptable to environmental conditions through a blooming of varying surface functional group to the surface of the solution.Type: GrantFiled: November 7, 2005Date of Patent: July 14, 2009Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Joshua A. Orlicki, Robert E. Jensen, Matthew S. Bratcher, Steven H. McKnight
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Publication number: 20090176047Abstract: Polymer compositions with adhesive properties comprising: (1) at least one fluoropolymer (A) grafted by at least one compound (a), wherein the compound (a) contains at least one functional group (f1) capable of conferring adhesion properties on the fluoropolymer; (2) at least one olefin polymer (B) grafted by at least one compound (b), wherein the compound (b) contains at least one functional group (f2) capable of conferring adhesion properties on the olefin polymer and of reacting with the functional group (f1) contained in the compound (a); and (3) at least one polymer (C) chosen from polyesters and polyamides,Type: ApplicationFiled: June 26, 2007Publication date: July 9, 2009Applicant: SOLVAY (SOCIETE ANONYME)Inventors: Henri Wautier, Fernand Gauthy
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Patent number: 7557158Abstract: Thermoplastic polymer compositions are disclosed that can be processed into capstocks having a reduced gloss appearance, high impact strength and superior weatherability. The capstocks described herein are especially useful for extrusion into articles. They are also useful for application to various poor weathering structural plastic articles for preparing multi-layered composites having improved weatherability. Methods for manufacturing structural plastic capstocks and composites and articles produced therefrom having reduced gloss appearance are also described.Type: GrantFiled: August 18, 2005Date of Patent: July 7, 2009Assignee: Rohm and Haas CompanyInventor: Paul VanRheenen
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Patent number: 7557159Abstract: Thermoplastic resin compositions are provided. A heat-resistant ABS thermoplastic resin composition including a graft ABS polymer, an ?-methylstyrene copolymer, an imide-substituted copolymer, and an additive for improving elongation and impact strength is excellent in weld strength, chemical resistance, impact strength, and elongation. A thermoplastic resin composition including a graft ABS polymer, a ?-methylstyrene copolymer, and an additive for improving wettability is excellent in weld strength and wettability.Type: GrantFiled: December 31, 2005Date of Patent: July 7, 2009Assignee: LG Chem, Ltd.Inventors: Jaewook Lee, Seung Hun Chae, Jaehyug Cha, Seonglyong Kim, Chanhong Lee
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Publication number: 20090156719Abstract: One aspect of the invention relates to a transparent ABS resin composition having excellent impact resistance and flowability, which comprises about 10 to about 50 parts by weight of a rubber/(meth)acrylate-aromatic vinyl-unsaturated nitrile graft copolymer; about 50 to about 90 parts by weight of a thermoplastic resin matrix; and about 0.2 to about 0.5 parts by weight of a fluidizer, per 100 parts by weight of a base resin comprising the rubber/(meth)acrylate-aromatic vinyl-unsaturated nitrile graft copolymer and the thermoplastic resin matrix.Type: ApplicationFiled: February 13, 2009Publication date: June 18, 2009Applicant: CHEIL INDUSTRIES INC.Inventors: Young Sub JIN, Jae Keun HONG, Hwan Seok PARK, Byeong Do LEE
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Patent number: 7547745Abstract: A hardener composition useful for curing epoxy resins including a blend of (a) a carboxylic anhydride which is a copolymer of an ethylenically unsaturated anhydride and a vinyl compound; (b) a copolymer of an ethylenically unsaturated anhydride and an elastomer; and optionally (c) a stabilizing agent such as a block copolymer to prevent phase separation of components (a) and (b). The hardener composition is particularly useful in electrical laminates applications.Type: GrantFiled: January 11, 2008Date of Patent: June 16, 2009Assignee: Dow Global Technologies, Inc.Inventor: Ludovic Valette
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Publication number: 20090137437Abstract: Through hydrolysis of reaction products of polyethylene or Fischer-Tropsch waxes and ?,?-unsaturated carboxylic acids or their derivatives it is possible to gain access to innovative ionomer waxes which, in contrast to known ionomers of low molecular mass, exhibit low melt viscosities even at high degrees of hydrolysis. The ionomer waxes of the invention are suitable inter alia as components of pigment masterbatches, as plastics additives, and for application in polishes, paints, and printing inks.Type: ApplicationFiled: November 21, 2008Publication date: May 28, 2009Inventor: Gerd Hohner
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Publication number: 20090130351Abstract: The present invention provides a production process of a heat shrinkable film which is transparent, excellent in the balance of physical properties such as rigidity, elongation and shrink properties in both MD and TD, especially has a uniform film thickness and good stability in extrusion molding film while utilizing an inflation method; a block copolymer or hydrogenated product thereof, or a composition composed thereof excellent in tensile properties, optical properties, hardness, stretch properties, molding processability, shrink properties and solvent resistance and therefore suited for extrusion, injection molding and foams. The production process of a heat shrinkable film has a first inflation step of forming a tube having a thickness of from 0.05 to 0.5 mm by using a block copolymer having a vinyl aromatic hydrocarbon content of from 65 to 95 wt. % and a conjugated diene content of from 5 to 35 wt.Type: ApplicationFiled: September 12, 2006Publication date: May 21, 2009Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Susumu Hoshi, Ryoko Fukuoka, Yasutaka Nakamura
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Composition derived from a softening agent and a thermoplastic resin composition containing the same
Patent number: 7528197Abstract: This invention provides a softening agent composition obtained by blending and heat treating (a) 100 parts by weight of at least one non-aromatic hydrocarbon softening agent for rubber; (b) 0.1 to 10 parts by weight of an organic peroxide; and (c) 0.1 to 50 parts by weight of a crosslinking aid, with the proviso that the weight ratio of component (b) to component (c) is 1 or less. The softening agent composition is useful and very easy to handle in the production of a thermoplastic resin composition.Type: GrantFiled: November 19, 2007Date of Patent: May 5, 2009Assignee: Riken Technos CorporationInventors: Naganori Masubuchi, Michihisa Tasaka -
Patent number: 7514502Abstract: The present invention relates to an acrylonitrile (ASA) type thermoplastic resin composition with excellent weatherability and appearance properties, and more particularly, to an acrylate-styrene-acrylonitrile type thermoplastic resin composition comprising a) an acrylate-styrene-acrylonitrile graft copolymer; b) a butadienc-acrylonitrile methylmethacrylate graft copolymer; c) a copolymer of aromatic vinyl compound and vinylcyanide compound; and d) an alkyl acrylate copolymer, which has remarkably improved appearance properties such as scratch resistance, color (color stability) and gloss as well as excellent basic properties and weatherability.Type: GrantFiled: November 6, 2003Date of Patent: April 7, 2009Assignee: LG Chem, Ltd.Inventors: Dong-sung Kim, Chan-hong Lee, Seong-lyong Kim, Han-jong You
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Publication number: 20090088526Abstract: The invention relates to an impact-resistant transparent composition comprising a copolymer having repeat units resulting from the polymerization of acrylonitrile and of at least one vinylaromatic monomer, a particulate block copolymer and a core-shell copolymer.Type: ApplicationFiled: December 8, 2006Publication date: April 2, 2009Inventors: Laurent Gervat, Christophe Navarro, Pierre Gerard, Stephane Girois
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Publication number: 20090087664Abstract: Methods of directed self-assembly of multi-block (i.e., triblock and higher-order) copolymers on patterned substrates and related compositions are provided. According to various embodiments, the methods involve depositing copolymer materials on substrates configured to drive the assembly of micro-phase separated films that exhibit the same morphology as that copolymer materials in the bulk. In certain embodiments, binary patterns are used to drive the triblock copolymer films. The binary two-dimensional surface patterns are transformed into three-component and three-dimensional structures throughout the thickness of the overlying copolymer films.Type: ApplicationFiled: October 12, 2006Publication date: April 2, 2009Inventors: Paul Franklin Nealey, Frank S. Bates, Juan J. de Pablo
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Publication number: 20080262156Abstract: The invention relates to an impact modified acrylic sheet composition having a bimodal distribution of impact modifier particle sizes. The composition provides an optimal balance of impact performance and appearance after melt processing.Type: ApplicationFiled: September 28, 2006Publication date: October 23, 2008Applicant: ARKEMA FRANCEInventors: Harold R. Banyay, Brian Edgecombe
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Publication number: 20080207831Abstract: Disclosed is a composition including, or produced from, PVC, filler, and an impact strength-retaining amount of a modifier wherein the modifier includes is or a halogenated polyolefin, a core-shell resin, or combinations thereof. Also disclosed is a process which comprises combining the modifier to a blend that comprises or is produced by combining rigid PVC and one or more fillers. Further disclosed are articles comprising or produced from the composition.Type: ApplicationFiled: February 28, 2007Publication date: August 28, 2008Inventor: Stewart Carl Feinberg
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Patent number: 7417088Abstract: The present invention relates to a thermoplastic resin composition, more precisely, a thermoplastic resin composition with enhanced impact resistance, gloss, weather resistance and scratch resistance, compared with the conventional thermoplastic resin compositions, by containing an acrylate-styrene-acrylonitrile (ASA) graft copolymer, an aromatic vinyl compound and vinyl cyan compound copolymer, an alkyl methacrylate/aromatic vinyl compound/vinyl cyan compound terpolymer and a di-block copolymer (aromatic vinyl compound/vinyl cyan compound—alkyl methacrylate/aromatic vinyl compound/vinyl cyan compound).Type: GrantFiled: August 29, 2006Date of Patent: August 26, 2008Assignee: LG Chem, Ltd.Inventors: Tae-bin Ahn, Hyun-taek O, Jung-tae Park, Min-jung Kim, Keun-hoon Yoo