Mixture Contains Solid Polymer Derived From Reactant Containing Oxygen Heterocycle Patents (Class 525/74)
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Patent number: 4886857Abstract: Styrene based resin compositions comprise a styrene resin and a graft copolymer obtained by graft-polymerizing, in the presence of a butadiene based rubbery polymer, a monomer mixture composed of a monomer containing 1-50 ethylene oxide groups and one ethylenically-unsaturated bond and styrene or a monomer mixture compound of styrene as a principal component and at least one monomer copolymerizable with styrene. The a styrene based resin compositions are obtained by blending the graft copolymer with a styrene resin and having excellent impact strength and visual properties.Type: GrantFiled: March 21, 1988Date of Patent: December 12, 1989Assignee: Kureha Kagaku Kogyo K. K.Inventors: Masanori Ota, Fumio Akutsu, Kazuo Takahashi
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Patent number: 4886856Abstract: Novel graft copolymer elastomers comprising a rubbery substrate polymer and a graft copolymer of a monomer capable of grafting to the rubbery substrate and a copolymerizable comonomer having pendant reactive groups capable of functionally reacting with reactive polar functionality of a copolymer of a monovinylidene aromatic monomer and a copolymerizable polar comonomer are disclosed.Type: GrantFiled: November 27, 1987Date of Patent: December 12, 1989Assignee: The Dow Chemical CompanyInventors: Bibiana S. Y. Chen, David E. Henton
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Patent number: 4885335Abstract: A low gloss thermoplastic with good physical properties comprises a blend of a polycarbonate with an acrylonitrile-styrene-acrylate interpolymer and a gloss-reducing amount of a glycidyl (meth)acrylate copolymer.Type: GrantFiled: December 27, 1988Date of Patent: December 5, 1989Assignee: General Electric CompanyInventors: Robert R. Gallucci, Ronald J. Wroczynski, James F. Jones, Stefan F. Rasch
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Patent number: 4879343Abstract: A heat and impact resistant composition comprising:(A) 5-89 parts by weight of a graft polymer prepared by graft polymerizing 30-75 parts by weight of a mixture of 30-80% of an aromatic vinyl monomer, 10-50% of an N-substituted maleimide monomer, 10-45% of a vinyl cyanide monomer and 0-30% of another copolymerizable vinyl monomer onto 25-70 parts by weight of a diene rubber (a);(B) 10-90 parts by weight of a copolymer obtained by polymerizing a mixture of 30-80% of an aromatic vinyl monomer, 10-50% of an N-substituted maleimide monomer, 10-40% of a vinyl cyanide monomer and 0-30% of another copolymerizable vinyl monomer, or (B') an imido group--containing adduct of a copolymer obtained by reacting a primary amine and/or ammonia with a copolymer obtained by polymerizing a mixture of 30-80% of an aromatic vinyl monomer, 5-50% of an alpha, beta-unsaturated dicarboxylic acid anhydride monomer and 0-40% of another copolymerizable vinyl monomer;(C) 1-45 parts be weight of a graft polymer made by graft polymerizingType: GrantFiled: August 5, 1988Date of Patent: November 7, 1989Assignee: Mitsubishi Monsanto Chemical CompanyInventors: Yuji Aoki, Hiroaki Miyazaki
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Patent number: 4879342Abstract: The present invention relates to thermoplastic moulding compositions comprising polydiorganosiloxanepolycarbonate block copolymers, copolymers of styrene and maleic anhydrides, graft polymers and, where appropriate, further customary additives and a process for preparing these moulding compositions.Type: GrantFiled: April 13, 1988Date of Patent: November 7, 1989Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Winfried Paul, Horst Peters, Christian Lindner, Josef Buekers
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Patent number: 4871802Abstract: The invention relates to a process for the preparation of a thermoplastic consisting of a vinylaromatic compound, acrylonitril and a butadiene rubber, by means of a two-step polymerization reaction characterized in that 0.1-10 wt. % of the butadiene rubber based on the entire composition, is replaced by an acrylate rubber in the second step. The process results in a decreased concentration of residual monomers.Type: GrantFiled: February 9, 1988Date of Patent: October 3, 1989Assignee: Stamicarbon B.V.Inventors: Wilhelmus G. Duyzings, Lambert Van Lumig
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Patent number: 4870131Abstract: A composition capable of providing low gloss in a part molded therefrom consisting essentially of 20 to 50% by weight of a graft copolymer of ethylenically unsaturated monomers grafted unto a rubber with a rubber content of 5 to 80% by weight based on the weight of Component A; 80 to 50% by weight of one or more thermoplastic, rubber-free copolymers containing: (i) 1 to 25% by weight based on the total weight of Component (B) of an unsaturated dicarboxylic acid anhydride monomer and (ii) 0.5 to 2% by weight based on the total weight of Component (B) of an ethylenically unsaturated copolymerized epoxide compound.Type: GrantFiled: February 22, 1988Date of Patent: September 26, 1989Assignee: Monsanto CompanyInventors: Ramesh M. Pisipati, Joseph O. Campbell
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Patent number: 4868057Abstract: A laminated structure comprising a plurality of polymeric layers at least two of said polymeric layers bonded together with an adhesive composition comprising a modified olefin polymer and at least one selectively hydrogenated block copolymer having at least one block which is predominantly a monoalkenyl aromatic hydrocarbon polymer block and at least one block which is a hydrogenated conjugated diolefin polymeric block. The adhesive composition used in the laminated structure significantly improves compatibility of the various polymeric layers thereby enabling the laminated structure or any excess thereof to be used in recycle as well as various molding applications.Type: GrantFiled: December 21, 1987Date of Patent: September 19, 1989Assignee: Shell Oil CompanyInventor: Glenn R. Himes
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Patent number: 4863995Abstract: A propylene polymer composition is disclosed which comprises:(a) a crystalline propylene polymer having a melt-flow index of from 0.01 to 100 g/10 min.;(b) a first ethylene copolymer comprising ethylene and from about 3.0 to 50% by weight of at least one copolymerizable monomer selected from a vinyl ester and an unsaturated carboxylic acid ester; and at least one of(c) a first modified propylene polymer produced by reacting 100 parts by weight of a propylene polymer with from about 0.01 to 10 parts by weight of an organic unsaturated compound having at least one hydroxyl group and from about 0.01 to 10 parts by weight of an organic peroxide, and(d) a second ethylene copolymer comprising ethylene and at least one copolymerizable ethylenically unsaturated monomer having at least one epoxy group.The composition has excellent adhesion to two-component system polychloroprene type adhesives and two-component system chlorinated polypropylene adhesives.Type: GrantFiled: July 15, 1988Date of Patent: September 5, 1989Assignee: Showa Denko Kabushiki KaishaInventors: Hirobumi Murakami, Tsutomu Suda, Mitunobu Machida, Hide Umemura
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Patent number: 4861676Abstract: A blend of ethylene copolymer, ethylene copolymer modified by grafting with a comonomer containing pendant acid or acid derivative functionality, styrene polymer, and alicyclic resin modifier or stabilized rosin ester provides a useful adhesive, particularly for bonding polystyrene to barrier polymers.Type: GrantFiled: August 29, 1988Date of Patent: August 29, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: I-Hwa Lee
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Patent number: 4861677Abstract: A blend of ethylene vinyl acetate copolymer, ethylene vinyl acetate copolymer modified by grafting with a comonomer containing pendant acid or acid derivative functionality, and impact-modified polystyrene provides a useful adhesive particularly for bonding polystyrene to gas barrier polymers.Type: GrantFiled: June 3, 1988Date of Patent: August 29, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: I-Hwa Lee
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Patent number: 4857563Abstract: The invention provides an encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized composition and a crosslinking agent.Type: GrantFiled: March 9, 1987Date of Patent: August 15, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas S. Croft, Hartwick A. Haugen
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Patent number: 4857591Abstract: Thermoplastic moulding compositions consisting ofI. 75 to 99.5% by weight of a polymer ofA. 0 to 95% by weight, 95% or less by weight; of a graft copolymer prepared by grafting polymerization ofA.1 5 to 95% by weight of a mixture ofA.1.1 50 to 95% by weight of styrene, .alpha.-methylstyrene, nuclear-substituted styrene, methyl methacrylate or mixtures thereof andA.1.2 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof onA.2 95 to 5% by weight of a rubber with a glass transition temperature Tg or <0.degree.C., andB. 100 to 5% by weight of a thermoplastic polymer ofB.1 95 to 50% by weight of styrene, .alpha.-methylstyrene, nuclear-substituted styrene or methyl methacrylate or mixtures thereof andB.2 5 to 50% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof andII. 25 to 0.5% by weight of a hydrogenated nitrile rubber.Type: GrantFiled: June 22, 1987Date of Patent: August 15, 1989Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Hartmuth Buding, Joachim Doring, Rudolf Casper, Karl-Heinz Ott
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Patent number: 4842947Abstract: Adhesive blends especially suitable for adhesion to polypropylene and gas barrier materials are disclosed, as are composite structures incorporating such blends, and methods of making such composite structures. The blends are preferably elastomer free, and comprise a mixture of an adhesion-promoting amount of an ethylene homopolymer about 0.1 to 30 wt. % of a non-elastomeric graft copolymer of polypropylene and a graft monomer comprising a polymerizable, ethylenically unsaturated carboxylic acid or derivative, and the balance a substantially non-elastomeric ethylene/propylene copolymer wherein ethylene comprises at least 5 wt. % of the copolymer.Type: GrantFiled: January 29, 1988Date of Patent: June 27, 1989Assignee: Quantum Chemical CorporationInventors: Kevin V. Jachec, Peter D. Becker
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Patent number: 4839422Abstract: An adhesive composition which contains a thermoplastic elastomer which includes ethylene propylene rubber, ethylene propylene diene monomer, polyisobutylene butyl rubber, ethylene vinyl acetate graft copolymers thereof with C.sub.3 to C.sub.10 unsaturated mono- and polycarboxylic acids, a tackifying resin and a di- or polyamine cross-linking agent having 2-10 carbon atoms, which is useful as a hot melt or pressure sensitive adhesive having enhanced higher temperature properties.Type: GrantFiled: December 23, 1987Date of Patent: June 13, 1989Assignee: Exxon Chemical Patents Inc.Inventors: Kenneth O. McElrath, Martha L. Robertson, Wai Y. Chow
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Patent number: 4839412Abstract: Certain ethylene copolymers that contain an ethylene/anhydride graft copolymer and a magnesium hydroxide or aluminum trihydrate flame and smoke retardant have a good balance of strength and flame and smoke retardant properties. The compositions preferably also contain polyethylene, and/or ionomeric ethylene copolymer and/or an ethylene/propylene elastomer.Type: GrantFiled: September 1, 1987Date of Patent: June 13, 1989Assignee: E. I. Du Pont De Nemours and CompanyInventors: Jerald R. Harrell, Lawrence C. Muschiatti
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Patent number: 4833195Abstract: A thermoplastic pelletizable polymer composition comprising an oligomer or degraded polyolefin and an olefinic elastomer. Optionally, the composition can also include a polyolefin thermoplastic polymer. The composition, when converted to a film or fabric meets the criteria or drapability, low hardness on the Shore A scale, high melt flow and reprocessability.Type: GrantFiled: July 20, 1987Date of Patent: May 23, 1989Assignee: BP Performance Polymers, Inc.Inventors: Ashok M. Adur, Joseph M. Hogue, Jr.
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Patent number: 4826918Abstract: Thermoplastic molding compositions containingA. 10 to 98 parts by weight and preferably 10 to 95 parts by weight of one or more thermoplastic aromatic polycarbonates,B. 2 to 60 parts by weight and preferably 5 to 60 parts by weight of one or more graft polymers of:B.1 5 to 90 parts by weight and preferably 30 to 80 parts by weight of a mixture ofB.1.1 50 to 95 parts by weight styrene, .alpha.-methyl styrene, nucleus-substituted styrene, methyl methacrylate or mixtures thereof andB.1.2 50 to 5 parts by weight acrylonitrile, methacrylonitrile, methyl methacrylate, maleic acid anhydride, N-substituted maleic imide or mixtures thereof, orB.2 95 to 10 parts by weight and preferably 70 to 20 parts by weight of a rubber having a glass transition temperature T.sub.G of .ltoreq.10.degree. C.,C. 0 to 80 parts by weight of a thermoplastic copolymer of:C.1 50 to 95 parts by weight styrene, .alpha.-methyl styrene, nucleus-substituted styrene, methyl methacrylate or mixtures thereof andC.Type: GrantFiled: February 29, 1988Date of Patent: May 2, 1989Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Dieter Wittmann, Bernd Quiring, Horst Peters, Jochen Schoeps
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Patent number: 4824906Abstract: A blend of 80-99 weight percent chlorinated polyethylene containing 15-60 weight percent chlorine with 20-1 weight percent of polyethylene containing up to 5 weight percent chlorine and 0.5-5 weight percent of a grafted unsaturated dicarboxylic acid or anhydride is disclosed. The preferred chlorinated polyethylene is made by chlorinating a blend of high and low density polyethylene.Type: GrantFiled: March 10, 1988Date of Patent: April 25, 1989Assignee: E. I. DuPont De Nemours and CompanyInventors: Wolfgang Honsberg, Royce E. Ennis
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Patent number: 4822856Abstract: A process for preparing a polymeric blend stock comprising fluidizing a first particulated polymer, contacting the particulated polymer with droplets of a latex of a second polymer or polymer mixture, retaining the resulting product in a fluid state under conditions sufficient to dry the latex, and recovering the resulting dried polymeric blend stock.Type: GrantFiled: February 18, 1987Date of Patent: April 18, 1989Assignee: The Dow Chemical CompanyInventors: Eugene R. Moore, Wen H. Tong
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Patent number: 4808662Abstract: A composition of matter or a film for producing a peelable heat seal between substrates on which it is carried, comprising a blend of:(a) about 6 to about 25 weight percent of polybutylene having a melt index of about 0.1 to about 500;(b) about 75 to about 92 weight percent of modified EVA or modified low density polyethylene; and(c) about 2 to about 15 weight percent of polypropylene; andwherein said blends are coated onto either nylon or polycarbonate.Type: GrantFiled: October 13, 1987Date of Patent: February 28, 1989Assignee: Shell Oil CompanyInventor: Charles C. Hwo
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Patent number: 4806603Abstract: Polyester-based mouldings which have been hardened with little shrinkage, do not stick in the mould and therefore can be released from the mould without damage are accessible via moulding compositions containing an unsaturated polyester of defined acid number and certain end groups.Type: GrantFiled: July 13, 1987Date of Patent: February 21, 1989Assignee: Bayer AktiengesellschaftInventors: Bernhard Hess, Bert Brassat, Oskar Walter
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Patent number: 4804708Abstract: The present invention relates to thermoplastic moulding compounds based on thermoplastic polycarbonates, graft polymers and optionally thermoplastic copolymers, characterized in that the graft polymers contain at least one primary or secondary aliphatic acrylic acid ester or tert.-butyl acrylate or tert.-butyl methylacrylate incorporated by polymerization. The invention also relates to a process for the preparation of these thermoplastic moulding compounds.Type: GrantFiled: November 27, 1987Date of Patent: February 14, 1989Assignee: Bayer AktiengesellschaftInventors: Dieter Wittmann, Christian Lindner, Hans-Jurgen Kress, Horst Peters, Jochen Schoeps
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Patent number: 4801651Abstract: (A) polypropylene (10-90 weight part), (B) halogenated butyl rubber (90-10 weight part, (A)+(B)=100 weight part), (C) olefinic rubber (10-120 weight part) and (D) mineral oil softening agent (5-120 weight part) are heated in the presence of (E) metal oxide and/or metal chloride. To 100 weight part of the resulting composition are added, (F) polyolefin (100-600 weight part) and (G) vulcanizable olefinic rubber (50-500 weight part) and the components are mixed and heated in the presence of (H) organic peroxide. The resulting thermoplastic elastomer composition has good paintability, moldability, compatibility, low temperature impact strength, and especially high stiffness at elevated temperature.Type: GrantFiled: November 2, 1987Date of Patent: January 31, 1989Assignee: Tonen Sekiyukagaku K.K.Inventors: Masato Komatsu, Isao Baba, Kiyotada Narukawa, Noboru Yamamoto, Tsuyoshi Kanai
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Patent number: 4801647Abstract: A thermoplastic elastomeric composition comprising a dynamically crosslinked grafted polyolefin copolymer elastomer and a thermoplastic crystalline polyolefin is disclosed. The crosslinked elastomer is dispersed in the thermoplastic crystalline polyolefin which is present as the continuous phase. The grafted elastomer is ethylene/propylene/diene terpolymer or ethylene/propylene copolymer grafted with fumaric acid, maleic acid, maleic anhydride or derivatives thereof capable of reacting with diamine crosslinking agents.Type: GrantFiled: March 10, 1988Date of Patent: January 31, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: James R. Wolfe, Jr.
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Patent number: 4801648Abstract: The present invention relates to molding materials and sheets which possess improved aging and contact properties, and which comprise a plastic blend based on an acrylate-grafted vinyl chloride polymer, preferably polyvinyl chloride, having an acrylate content of 30-60% by weight, preferably 35-50% by weight, based on 100 parts by weight of vinyl chloride polymer. The molding materials and sheets further comprise another polymer or polymer blend having a glass transition temperature greater than 30.degree. C., preferably greater than 40.degree. C., which is compatible with the vinyl chloride graft polymer. If necessary, additional fillers, processing agents and other conventional additives may be included, so long as 28-44.9% by weight, preferably 30-44.8% by weight, of the vinyl chloride polymer grafted with acrylate is present and 55.1-72% by weight, preferably 55.2-70% by weight, of the other polymer or polymer blend is present.Type: GrantFiled: May 15, 1986Date of Patent: January 31, 1989Inventors: Roland Fink, Josef Huber-Hesselberger, Maximilian Mayr
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Patent number: 4800216Abstract: The invention relates to ABS molding compositions having a markedly reduced residual butadiene content, even at high processing temperatures.Type: GrantFiled: November 2, 1987Date of Patent: January 24, 1989Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Alfred Pischtschan
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Patent number: 4792583Abstract: Blends are disclosed of monoolefin rubber with high-diene hydrocarbon rubber in which the monoolefin rubber is in the form of discrete vulcanized particles dispersed in a matrix of unvulcanized high-diene hydrocarbon rubber. The blends can be easily processed, and in a subsequent step, the high-diene hydrocarbon portion cured to give rubber articles having the ozone resistance of the monoolefin rubber and the good physical properties of the high-diene hydrocarbon rubber.Type: GrantFiled: June 29, 1987Date of Patent: December 20, 1988Assignee: Monsanto CompanyInventor: Aubert Y. Coran
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Patent number: 4788264Abstract: A method of preparing a modified polyethylene which comprises melt kneading 100 parts by weight of (A) a high density polyethylene having a branching degree of not more than 5 per 1,000 carbon atoms of principal chain, from 0.2 to 3 parts by weight of (B) an unsaturated carboxylic acid or a derivative thereof, and from 0.01 to 0.5 part by weight of (C) an organic peroxide, the weight ratio of (C) to (B), (C)/(B), being from 0.01 to 0.5.The modified polyethylenes obtained by the use of the method of the present invention not only have excellent heat resistance, moldability, and so forth, but also are extremely improved in their adhesion property, especially in the property of adhering to a saponified ethylene-vinyl acetate copolymer, a polyamide resin, and a polyester resin, and therefore the modified polyethylenes can be advantageously used with these materials for the production of laminated boards.Type: GrantFiled: January 22, 1988Date of Patent: November 29, 1988Assignee: Idemitsu Petrochemical Co., Ltd.Inventor: Mamoru Ukita
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Patent number: 4785052Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.Type: GrantFiled: November 14, 1986Date of Patent: November 15, 1988Assignee: Arco Chemical CompanyInventor: Barry D. Dean
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Patent number: 4783505Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.Type: GrantFiled: November 14, 1986Date of Patent: November 8, 1988Assignee: ARCO Chemical CompanyInventor: Barry D. Dean
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Patent number: 4777212Abstract: The present invention relates to thermoplastic moulding compositions comprising polydiorganosiloxane-polycarbonate block copolymers, copolymers of styrene and maleic anhydrides, graft polymers and, where appropriate, further customary additives and a process for preparing these moulding compositions.Type: GrantFiled: November 21, 1986Date of Patent: October 11, 1988Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Winfried Paul, Horst Peters, Christian Lindner, Josef Buekers
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Patent number: 4774144Abstract: Adhesive blends especially suitable for adhesion to polypropylene and gas barrier materials are disclosed, as are composite structures incorporating such blends, and methods of making such composite structures. The blends are preferably elastomer free, and comprise a mixture of an adhesion-promoting amount of high molecular weight low density polyethylene having a narrow molecular weight distribution, about 0.1 to 30 wt. % of a non-elastomeric copolymer of propylene and a polymerizable, ethylenically unsaturated carboxylic acid or derivative, and the balance a non-elastomeric ethylene/propylene copolymer wherein ethylene comprises at least 5 wt. % of the copolymer.Type: GrantFiled: December 15, 1987Date of Patent: September 27, 1988Assignee: Enron Chemical CompanyInventors: Kevin V. Jachec, Peter D. Becker
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Patent number: 4767817Abstract: Shaped articles which have excellent solvent resistance and resistance to fatty acids are formed from a thermoplastic polyblend of poly(vinyl chloride) (PVC), chlorinated polyethylene (CPE), polyolefin (PO), and a graft copolymer of a polyolefin (PO-G). The thermoplastic polyblend contains a PO and PO-G (PO/PO-G) as a first continuous single phase, PVC and CPE as the second and third dispersed phases, and the relative amounts of the components are chosen so that there is, at most, an equal amount by weight of PO and PO-G each of which may be present in an amount as high as 40 parts by weight when the PVC is present in an amount in the range from 40 to 70 parts, so as to provide a mechanically compatible polyblend without miscibility or chemical compatibility. Further, a glass fiber reinforced (GFR) polyblend of PVC/CPE/PO/PO-G having a HDT of at least 95.degree. C. and sufficient thermoformability to form the desired article has excellent notched impact strength.Type: GrantFiled: March 9, 1987Date of Patent: August 30, 1988Assignee: The B. F. Goodrich CompanyInventor: Biing-Lin Lee
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Patent number: 4764546Abstract: A filler-containing polypropylene resin composition and a process for producing the same are disclosed. The composition comprises (a) from 27 to 87% by weight of a polypropylene resin, (b) from 3 to 15% by weight of a modified polypropylene resin containing from 0.1 to 3 mol % of an unsaturated dicarboxylic acid anhydride repeating unit, (c) from 5 to 30% by weight of an ethylene copolymer composed of from 82 to 98.7 mol % of an ethylene repeating unit, from 1 to 15 mol % of an ester repeating unit selected from alkyl acrylates and alkyl methacrylates having from 1 to 8 carbon atoms in the alkyl moiety thereof, and from 0.3 to 3 mol % of an unsaturated dicarboxylic acid anhydride repeating unit, and (d) from 5 to 40% by weight of a filler. The process comprises melt-mixing the components (a), (b) and (d) and then melt-mixing the resulting mixture with the component (c).Type: GrantFiled: April 23, 1987Date of Patent: August 16, 1988Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tatsuyuki Mitsuno, Hideo Shinonaga, Akio Daimon
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Patent number: 4762882Abstract: A modified polyolefin resin and a composition containing therein such modified polyolefin, having excellent adhesive property and heat-sealing property at the time of high speed forming operations, the modified polyolefin resin consisting essentially of: a copolymer of ethylene and .alpha.-olefin having 4 or more carbon atoms, the copolymer having a density in a range of from 0.890 to 0.910 g/cm.sup.3, a ratio of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn) of Mw/Mn=2 to 15, and a product of a melt tension (g) and a melt-index (g/10 min.) of a molten resin measured at 160.degree. C. of 4 or below; and unsaturated carboxylic acid or derivatives thereof grafted on the ethylene type copolymer at a ratio of from 0.01 to 3% by weight.Type: GrantFiled: June 26, 1986Date of Patent: August 9, 1988Assignee: Mitsubishi Chemical Industries LimitedInventors: Shigeaki Okano, Katsuhiko Hayashi, Yoshiteru Sakurazawa, Yoshinori Suga
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Patent number: 4761463Abstract: A thermoplastic resin composition having a matte appearance comprising:(A) 80-5 parts by weight of a graft copolymer obtained by grafting 40-95 parts by weight of diene rubber with 60-5 parts by weight of vinyl compounds consisting of0.1-40 weight % of at least one glycidyl ester of an .alpha.- and .beta.-unsaturated acid as an essential component,10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, and(B) 20-95 parts by weight of a copolymer obtained through reaction of10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, the intrinsic viscosity of the resin composition in terms of its components which are soluble in methyl ethyl ketone being 0.25-1.5 dl/g (N,N'-dimethyl formamide solution, 30.degree. C.).Type: GrantFiled: March 24, 1986Date of Patent: August 2, 1988Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Shigemi Matsumoto, Fumiya Nagoshi
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Patent number: 4753988Abstract: Impact modified copolymers of vinyl aromatic, ethylenically unsaturated nitrile and, optionally, methyl methacrylate monomer, wherein the impact modifier comprises (a) large grafted rubber particles of a rubbery alkyl acrylate polymer having a particle size from about 0.5.mu. to 0.8.mu., 0.04 to 0.5 percent by weight of a polymerized crosslinking monomer and from 0.5 to 40 percent grafted rigid phase, and (b) small grafted rubber particles of a rubbery alkyl acrylate polymer having a particle size from about 0.05.mu. to about 0.20.mu., 0.25 to about 2.0 percent of a crosslinking monomer, provided that the weight percentage of crosslinking monomer is at least twice the weight percentage of the crosslinking monomer in the large particle, and from about 15 to about 60 percent by weight grafted rigid phase.Type: GrantFiled: February 18, 1987Date of Patent: June 28, 1988Assignee: The Dow Chemical CompanyInventors: David E. Henton, Edward B. Anthony
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Patent number: 4752639Abstract: A flexible to soft shaped article containing a vinyl chloride-acrylic acid ester graft copolymer containing 20 to 60% by weight of acrylic acid ester polymer and 40 to 80% by weight of vinyl chloride and 0 to 30% by weight of other ethylenically unsaturated comonomers copolymerizable with vinyl chloride grafted thereon and optionally containing at least one member of the group consisting of other plastics, fillers, processing aids and conventional additives, the weight percentages being based on the total weight of the graft copolymer and optionally at least one additional polymer selected from the group consisting of polymers of high heat distortion resistance, polymers which lower the Shore hardness, polymers imparting elastomeric properties.Type: GrantFiled: November 12, 1986Date of Patent: June 21, 1988Assignee: Wacker-Chemie GmbHInventors: Ingo Haller, Georg Haberl
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Patent number: 4749746Abstract: A polymer composition which contains a polycarbonate resin, a styrenic/maleimide/cyclic anhydride terpolymer, and an ethylene/propylene/nonconjugated diene terpolymer chemically grafted with either styrene/acrylonitrile copolymer, methylmethacrylate/N-phenylmaleimide copolymer or polymethylmethacrylate is disclosed. The composition exhibits excellent impact strength properties upon molding.Type: GrantFiled: January 15, 1987Date of Patent: June 7, 1988Assignee: ARCO Chemical CompanyInventors: Barry D. Dean, Bi Le-Khac
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Patent number: 4748210Abstract: Vinyl chloride-grafted ethylene copolymer superior in adhesiveness both to metals, glasses or polar high molecular materials such as polyamides and to non-rigid vinyl chloride resins is provided in which backbone polymer is copolymer of ethylene, ester of monohydric alcohol of 1-8 carbon atoms with acrylic acid or methacrylic acid and maleic anhydride and pendant or grafting polymer is vinyl chloride polymer. This copolymer is produced by graft-polymerization of vinyl chloride onto the ethylene-acrylic or methacrylic ester-maleic anhydride copolymer.Type: GrantFiled: June 19, 1987Date of Patent: May 31, 1988Assignee: Sumitomo Chemical Co., Ltd.Inventors: Masahisa Okawa, Tomoyuki Emura, Yoshitaka Owatari, Kentaro Mashita, Toshio Kawakita
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Patent number: 4742116Abstract: A thermoplastic moulding compound based on a rubber-modified copolymer consisting of styrene and/or .alpha.-methylstyrene and maleic anhydride, wherein the moulding compound is composed of a mixture of:A. 50-95% (wt) of a copolymer consisting of:(i) 50-95% (wt) styrene and/or .alpha.-methylstyrene,(ii) 50-5% (wt) maleic anhydride,(iii) 0-20% (wt) acrylate,(iv) 0-20% (wt) acrylonitrile;B. 5-50% (wt) of an ethylene-propylene modified rubber or ethylene-propylene-diene modified rubber, the rubber being modified by grafting thereto a compound containing hydroxyl, amide or amine groups; andC. 0-30% (wt) of an ethylene-propylene rubber or an ethylene-propylene-diene rubber.Type: GrantFiled: December 13, 1985Date of Patent: May 3, 1988Assignee: Stamicarbon B.V.Inventors: Herman A. J. Schepers, Wilhelmus A. M. Debets
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Patent number: 4742104Abstract: The present invention relates to thermoplastic moulding compositions containing thermoplastic polycarbonates, graft polymers, rubber-free copolymers and, if appropriate, copolymeric rubbers, and also, if appropriate, conventional additives, which are characterized in that the rubber-free copolymers contain internal epoxide compounds.Type: GrantFiled: December 29, 1986Date of Patent: May 3, 1988Assignee: Bayer AktiengesellschaftInventors: Christian Lindner, Otto Koch, Hans-Jurgen Kress, Horst Peters
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Patent number: 4740543Abstract: A plastic vehicular instrument panel which is excellent in impact resistance, heat resistance, fabrication efficiency and appearance. The instrument panel is formed of a plastic material comprising as main components specified crystalline propylene-ethylene block copolymer ranging from 50 to 70 weight %, specified glass fibers ranging from 20 to 30 weight %, specified ethylene-propylene copolymer rubber ranging from 15 to 20 weight %, specified pigment ranging from 2 to 5 parts by weight relative to 100 parts by weight of total of the propylene-ethylene block copolymer, the glass fiber, and the ethylene-propylene copolymer rubber.Type: GrantFiled: August 8, 1986Date of Patent: April 26, 1988Assignee: Nissan Motor Co., Ltd.Inventors: Yoshio Matsuno, Hidehisa Watanabe
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Patent number: 4739011Abstract: A thermoplastic resin composition obtainable by blending 100 parts by weight of a mixture consisting of(A) 75 to 40% by weight of a propylene polymer,(B) 20 to 40% by weight of an ethylene-alpha-olefin copolymer, and(C) 5 to 30% by weight of a graft copolymer obtained by copolymerizing an aromatic vinyl compound and a polar vinyl compound in the presence of an ethylene-alpha-olefin copolymerwith(D) 0.1 to 5 parts by weight of an unsaturated dicarboxylic acid, an anhydride thereof or a mixture of the two, and(E) 0.01 to 0.3 part by weight of an organic radical-generating agent,and then subjecting the resulting blend to thermal treatment. Said composition has not only a high bending modulus inherently possessed by polypropylene resins but also remarkably improved coating property. Accordingly, the composition is useful as interior and exterior trim parts of automobiles and exterior trim parts of motorcycles.Type: GrantFiled: May 13, 1987Date of Patent: April 19, 1988Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Takashi Kawata, Yoshitaka Matsuo, Kenya Makino, Noboru Oshima
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Patent number: 4734456Abstract: A thermoplastic resin composition having excellent and well balanced physical properites such as chemical resistance, drop weight impact resistance and thermal stability which comprises (A) a styrenic polymer and (B) a ternary polymer comprising 50 to 98.5% by weight of an olefin, 0.5 to 10% by weight of an unsaturated dicarboxylic acid anhydride and 1 to 40% by weight of an unsaturated carboxylic acid alkyl ester, the weight proportion of the styrenic polymer (A) and the ternary polymer (B) being 100:0.5-200.Type: GrantFiled: November 10, 1986Date of Patent: March 29, 1988Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Kazuhiko Motomatsu, Mikio Kodama, Hiromichi Aoki, Ichiro Sato
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Patent number: 4728463Abstract: Brominated styrene-maleate copolymer containing at least 50 weight percent bromine and its use as a fire retardant.Type: GrantFiled: August 18, 1986Date of Patent: March 1, 1988Assignee: Ethyl CorporationInventors: Burton J. Sutker, Gen-Shing Ti, Mo A. Khuddus
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Patent number: 4728692Abstract: A thermoplastic elastomer composition and process comprising a crystalline polyolefin, halogenated butyl rubber, olefin copolymer rubber, polyolefin modified with, e.g., maleic anhydride, and, optionally nitrile rubber, wherein the halogenated butyl rubber is at least partially crosslinked using a metal oxide and/or chloride, e.g., zinc oxide. Crosslinking is achieved under dynamic mixing conditions and the resulting composition has superior strength, performance and processing properties. Furthermore, use of nitrile rubber imparts improved oil resistance to the composition.Type: GrantFiled: February 18, 1987Date of Patent: March 1, 1988Inventors: Eiji Sezaki, Takashi Mikami, Tsuyoshi Kanai, Toshio Yoshida, Kikuo Tanaka, Masaaki Saito
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Patent number: 4721752Abstract: A process for preparing an impact resistant thermoplastic moulding compound based on a copolymer consisting of styrene and/or .alpha.-methylstyrene and maleic anhydride by mixing:50-95% (wt) of a copolymer consisting of:(i) 50-95% (wt) styrene and/or .alpha.-methylstyrene,(ii) 50-5% (wt) maleic anhydride,(iii) 0-20% (wt) acrylate,(iv) 0-20% (wt) acrylonitrile;5-50% (wt) of a rubber modified with hydroxyl groups, a rubber modified with amine groups or a rubber modified with amide groups; and0-30% (wt) unmodified rubber,said mixing being conducted in the presence of 0.01-10 parts by weight of a reaction accelerator, calculated on 100 parts by weight copolymer and modified rubber, at a temperature between 160.degree. C. and 290.degree. C.Type: GrantFiled: January 2, 1986Date of Patent: January 26, 1988Assignee: Stami Carbon BVInventors: Herman A. J. Schepers, Wilhelmus A. M. Debets
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Patent number: H568Abstract: An olefin polymer composition comprising(A) 100 parts by weight of a homopolymer of 1-butene composed substantially of 1-butene units or a copolymer of 1-butene and another alpha-olefin containing at least 60 mole % of units derived from 1-butene,(B) 10 to 600 parts by weight of a homopolymer of propylene composed substantially of propylene units, a block copolymer of propylene and another alpha-olefin containing at least 50 mole % of units derived from propylene, or a random copolymer of propylene and another alpha-olefin containing at least 90 mole % of units derived from propylene, and(C) 10 to 600 parts by weight of a crystalline random copolymer of propylene and another alpha-olefin containing 50 to 87 mole % of units derived from propylene,at least one of components (A), (B) and (C) being partly modified with (D) an unsaturated carboxylic acid or its derivative; and a laminated structure comprising a substrate and a layer of a 1-butene polymer laminated thereto through an adhesive layer of the olefin poType: GrantFiled: March 13, 1986Date of Patent: January 3, 1989Assignee: Shell Oil CompanyInventors: Haruhiko Tanaka, Katutoshi Kaneko