Mixture Contains Solid Polymer Derived From Reactant Containing Oxygen Heterocycle Patents (Class 525/74)
  • Patent number: 4886857
    Abstract: Styrene based resin compositions comprise a styrene resin and a graft copolymer obtained by graft-polymerizing, in the presence of a butadiene based rubbery polymer, a monomer mixture composed of a monomer containing 1-50 ethylene oxide groups and one ethylenically-unsaturated bond and styrene or a monomer mixture compound of styrene as a principal component and at least one monomer copolymerizable with styrene. The a styrene based resin compositions are obtained by blending the graft copolymer with a styrene resin and having excellent impact strength and visual properties.
    Type: Grant
    Filed: March 21, 1988
    Date of Patent: December 12, 1989
    Assignee: Kureha Kagaku Kogyo K. K.
    Inventors: Masanori Ota, Fumio Akutsu, Kazuo Takahashi
  • Patent number: 4886856
    Abstract: Novel graft copolymer elastomers comprising a rubbery substrate polymer and a graft copolymer of a monomer capable of grafting to the rubbery substrate and a copolymerizable comonomer having pendant reactive groups capable of functionally reacting with reactive polar functionality of a copolymer of a monovinylidene aromatic monomer and a copolymerizable polar comonomer are disclosed.
    Type: Grant
    Filed: November 27, 1987
    Date of Patent: December 12, 1989
    Assignee: The Dow Chemical Company
    Inventors: Bibiana S. Y. Chen, David E. Henton
  • Patent number: 4885335
    Abstract: A low gloss thermoplastic with good physical properties comprises a blend of a polycarbonate with an acrylonitrile-styrene-acrylate interpolymer and a gloss-reducing amount of a glycidyl (meth)acrylate copolymer.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: December 5, 1989
    Assignee: General Electric Company
    Inventors: Robert R. Gallucci, Ronald J. Wroczynski, James F. Jones, Stefan F. Rasch
  • Patent number: 4879343
    Abstract: A heat and impact resistant composition comprising:(A) 5-89 parts by weight of a graft polymer prepared by graft polymerizing 30-75 parts by weight of a mixture of 30-80% of an aromatic vinyl monomer, 10-50% of an N-substituted maleimide monomer, 10-45% of a vinyl cyanide monomer and 0-30% of another copolymerizable vinyl monomer onto 25-70 parts by weight of a diene rubber (a);(B) 10-90 parts by weight of a copolymer obtained by polymerizing a mixture of 30-80% of an aromatic vinyl monomer, 10-50% of an N-substituted maleimide monomer, 10-40% of a vinyl cyanide monomer and 0-30% of another copolymerizable vinyl monomer, or (B') an imido group--containing adduct of a copolymer obtained by reacting a primary amine and/or ammonia with a copolymer obtained by polymerizing a mixture of 30-80% of an aromatic vinyl monomer, 5-50% of an alpha, beta-unsaturated dicarboxylic acid anhydride monomer and 0-40% of another copolymerizable vinyl monomer;(C) 1-45 parts be weight of a graft polymer made by graft polymerizing
    Type: Grant
    Filed: August 5, 1988
    Date of Patent: November 7, 1989
    Assignee: Mitsubishi Monsanto Chemical Company
    Inventors: Yuji Aoki, Hiroaki Miyazaki
  • Patent number: 4879342
    Abstract: The present invention relates to thermoplastic moulding compositions comprising polydiorganosiloxanepolycarbonate block copolymers, copolymers of styrene and maleic anhydrides, graft polymers and, where appropriate, further customary additives and a process for preparing these moulding compositions.
    Type: Grant
    Filed: April 13, 1988
    Date of Patent: November 7, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Winfried Paul, Horst Peters, Christian Lindner, Josef Buekers
  • Patent number: 4871802
    Abstract: The invention relates to a process for the preparation of a thermoplastic consisting of a vinylaromatic compound, acrylonitril and a butadiene rubber, by means of a two-step polymerization reaction characterized in that 0.1-10 wt. % of the butadiene rubber based on the entire composition, is replaced by an acrylate rubber in the second step. The process results in a decreased concentration of residual monomers.
    Type: Grant
    Filed: February 9, 1988
    Date of Patent: October 3, 1989
    Assignee: Stamicarbon B.V.
    Inventors: Wilhelmus G. Duyzings, Lambert Van Lumig
  • Patent number: 4870131
    Abstract: A composition capable of providing low gloss in a part molded therefrom consisting essentially of 20 to 50% by weight of a graft copolymer of ethylenically unsaturated monomers grafted unto a rubber with a rubber content of 5 to 80% by weight based on the weight of Component A; 80 to 50% by weight of one or more thermoplastic, rubber-free copolymers containing: (i) 1 to 25% by weight based on the total weight of Component (B) of an unsaturated dicarboxylic acid anhydride monomer and (ii) 0.5 to 2% by weight based on the total weight of Component (B) of an ethylenically unsaturated copolymerized epoxide compound.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: September 26, 1989
    Assignee: Monsanto Company
    Inventors: Ramesh M. Pisipati, Joseph O. Campbell
  • Patent number: 4868057
    Abstract: A laminated structure comprising a plurality of polymeric layers at least two of said polymeric layers bonded together with an adhesive composition comprising a modified olefin polymer and at least one selectively hydrogenated block copolymer having at least one block which is predominantly a monoalkenyl aromatic hydrocarbon polymer block and at least one block which is a hydrogenated conjugated diolefin polymeric block. The adhesive composition used in the laminated structure significantly improves compatibility of the various polymeric layers thereby enabling the laminated structure or any excess thereof to be used in recycle as well as various molding applications.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: September 19, 1989
    Assignee: Shell Oil Company
    Inventor: Glenn R. Himes
  • Patent number: 4863995
    Abstract: A propylene polymer composition is disclosed which comprises:(a) a crystalline propylene polymer having a melt-flow index of from 0.01 to 100 g/10 min.;(b) a first ethylene copolymer comprising ethylene and from about 3.0 to 50% by weight of at least one copolymerizable monomer selected from a vinyl ester and an unsaturated carboxylic acid ester; and at least one of(c) a first modified propylene polymer produced by reacting 100 parts by weight of a propylene polymer with from about 0.01 to 10 parts by weight of an organic unsaturated compound having at least one hydroxyl group and from about 0.01 to 10 parts by weight of an organic peroxide, and(d) a second ethylene copolymer comprising ethylene and at least one copolymerizable ethylenically unsaturated monomer having at least one epoxy group.The composition has excellent adhesion to two-component system polychloroprene type adhesives and two-component system chlorinated polypropylene adhesives.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: September 5, 1989
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Hirobumi Murakami, Tsutomu Suda, Mitunobu Machida, Hide Umemura
  • Patent number: 4861676
    Abstract: A blend of ethylene copolymer, ethylene copolymer modified by grafting with a comonomer containing pendant acid or acid derivative functionality, styrene polymer, and alicyclic resin modifier or stabilized rosin ester provides a useful adhesive, particularly for bonding polystyrene to barrier polymers.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: August 29, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: I-Hwa Lee
  • Patent number: 4861677
    Abstract: A blend of ethylene vinyl acetate copolymer, ethylene vinyl acetate copolymer modified by grafting with a comonomer containing pendant acid or acid derivative functionality, and impact-modified polystyrene provides a useful adhesive particularly for bonding polystyrene to gas barrier polymers.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: August 29, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: I-Hwa Lee
  • Patent number: 4857563
    Abstract: The invention provides an encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized composition and a crosslinking agent.
    Type: Grant
    Filed: March 9, 1987
    Date of Patent: August 15, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Thomas S. Croft, Hartwick A. Haugen
  • Patent number: 4857591
    Abstract: Thermoplastic moulding compositions consisting ofI. 75 to 99.5% by weight of a polymer ofA. 0 to 95% by weight, 95% or less by weight; of a graft copolymer prepared by grafting polymerization ofA.1 5 to 95% by weight of a mixture ofA.1.1 50 to 95% by weight of styrene, .alpha.-methylstyrene, nuclear-substituted styrene, methyl methacrylate or mixtures thereof andA.1.2 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof onA.2 95 to 5% by weight of a rubber with a glass transition temperature Tg or <0.degree.C., andB. 100 to 5% by weight of a thermoplastic polymer ofB.1 95 to 50% by weight of styrene, .alpha.-methylstyrene, nuclear-substituted styrene or methyl methacrylate or mixtures thereof andB.2 5 to 50% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or mixtures thereof andII. 25 to 0.5% by weight of a hydrogenated nitrile rubber.
    Type: Grant
    Filed: June 22, 1987
    Date of Patent: August 15, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Hartmuth Buding, Joachim Doring, Rudolf Casper, Karl-Heinz Ott
  • Patent number: 4842947
    Abstract: Adhesive blends especially suitable for adhesion to polypropylene and gas barrier materials are disclosed, as are composite structures incorporating such blends, and methods of making such composite structures. The blends are preferably elastomer free, and comprise a mixture of an adhesion-promoting amount of an ethylene homopolymer about 0.1 to 30 wt. % of a non-elastomeric graft copolymer of polypropylene and a graft monomer comprising a polymerizable, ethylenically unsaturated carboxylic acid or derivative, and the balance a substantially non-elastomeric ethylene/propylene copolymer wherein ethylene comprises at least 5 wt. % of the copolymer.
    Type: Grant
    Filed: January 29, 1988
    Date of Patent: June 27, 1989
    Assignee: Quantum Chemical Corporation
    Inventors: Kevin V. Jachec, Peter D. Becker
  • Patent number: 4839422
    Abstract: An adhesive composition which contains a thermoplastic elastomer which includes ethylene propylene rubber, ethylene propylene diene monomer, polyisobutylene butyl rubber, ethylene vinyl acetate graft copolymers thereof with C.sub.3 to C.sub.10 unsaturated mono- and polycarboxylic acids, a tackifying resin and a di- or polyamine cross-linking agent having 2-10 carbon atoms, which is useful as a hot melt or pressure sensitive adhesive having enhanced higher temperature properties.
    Type: Grant
    Filed: December 23, 1987
    Date of Patent: June 13, 1989
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth O. McElrath, Martha L. Robertson, Wai Y. Chow
  • Patent number: 4839412
    Abstract: Certain ethylene copolymers that contain an ethylene/anhydride graft copolymer and a magnesium hydroxide or aluminum trihydrate flame and smoke retardant have a good balance of strength and flame and smoke retardant properties. The compositions preferably also contain polyethylene, and/or ionomeric ethylene copolymer and/or an ethylene/propylene elastomer.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: June 13, 1989
    Assignee: E. I. Du Pont De Nemours and Company
    Inventors: Jerald R. Harrell, Lawrence C. Muschiatti
  • Patent number: 4833195
    Abstract: A thermoplastic pelletizable polymer composition comprising an oligomer or degraded polyolefin and an olefinic elastomer. Optionally, the composition can also include a polyolefin thermoplastic polymer. The composition, when converted to a film or fabric meets the criteria or drapability, low hardness on the Shore A scale, high melt flow and reprocessability.
    Type: Grant
    Filed: July 20, 1987
    Date of Patent: May 23, 1989
    Assignee: BP Performance Polymers, Inc.
    Inventors: Ashok M. Adur, Joseph M. Hogue, Jr.
  • Patent number: 4826918
    Abstract: Thermoplastic molding compositions containingA. 10 to 98 parts by weight and preferably 10 to 95 parts by weight of one or more thermoplastic aromatic polycarbonates,B. 2 to 60 parts by weight and preferably 5 to 60 parts by weight of one or more graft polymers of:B.1 5 to 90 parts by weight and preferably 30 to 80 parts by weight of a mixture ofB.1.1 50 to 95 parts by weight styrene, .alpha.-methyl styrene, nucleus-substituted styrene, methyl methacrylate or mixtures thereof andB.1.2 50 to 5 parts by weight acrylonitrile, methacrylonitrile, methyl methacrylate, maleic acid anhydride, N-substituted maleic imide or mixtures thereof, orB.2 95 to 10 parts by weight and preferably 70 to 20 parts by weight of a rubber having a glass transition temperature T.sub.G of .ltoreq.10.degree. C.,C. 0 to 80 parts by weight of a thermoplastic copolymer of:C.1 50 to 95 parts by weight styrene, .alpha.-methyl styrene, nucleus-substituted styrene, methyl methacrylate or mixtures thereof andC.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: May 2, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Dieter Wittmann, Bernd Quiring, Horst Peters, Jochen Schoeps
  • Patent number: 4824906
    Abstract: A blend of 80-99 weight percent chlorinated polyethylene containing 15-60 weight percent chlorine with 20-1 weight percent of polyethylene containing up to 5 weight percent chlorine and 0.5-5 weight percent of a grafted unsaturated dicarboxylic acid or anhydride is disclosed. The preferred chlorinated polyethylene is made by chlorinating a blend of high and low density polyethylene.
    Type: Grant
    Filed: March 10, 1988
    Date of Patent: April 25, 1989
    Assignee: E. I. DuPont De Nemours and Company
    Inventors: Wolfgang Honsberg, Royce E. Ennis
  • Patent number: 4822856
    Abstract: A process for preparing a polymeric blend stock comprising fluidizing a first particulated polymer, contacting the particulated polymer with droplets of a latex of a second polymer or polymer mixture, retaining the resulting product in a fluid state under conditions sufficient to dry the latex, and recovering the resulting dried polymeric blend stock.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: April 18, 1989
    Assignee: The Dow Chemical Company
    Inventors: Eugene R. Moore, Wen H. Tong
  • Patent number: 4808662
    Abstract: A composition of matter or a film for producing a peelable heat seal between substrates on which it is carried, comprising a blend of:(a) about 6 to about 25 weight percent of polybutylene having a melt index of about 0.1 to about 500;(b) about 75 to about 92 weight percent of modified EVA or modified low density polyethylene; and(c) about 2 to about 15 weight percent of polypropylene; andwherein said blends are coated onto either nylon or polycarbonate.
    Type: Grant
    Filed: October 13, 1987
    Date of Patent: February 28, 1989
    Assignee: Shell Oil Company
    Inventor: Charles C. Hwo
  • Patent number: 4806603
    Abstract: Polyester-based mouldings which have been hardened with little shrinkage, do not stick in the mould and therefore can be released from the mould without damage are accessible via moulding compositions containing an unsaturated polyester of defined acid number and certain end groups.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: February 21, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bernhard Hess, Bert Brassat, Oskar Walter
  • Patent number: 4804708
    Abstract: The present invention relates to thermoplastic moulding compounds based on thermoplastic polycarbonates, graft polymers and optionally thermoplastic copolymers, characterized in that the graft polymers contain at least one primary or secondary aliphatic acrylic acid ester or tert.-butyl acrylate or tert.-butyl methylacrylate incorporated by polymerization. The invention also relates to a process for the preparation of these thermoplastic moulding compounds.
    Type: Grant
    Filed: November 27, 1987
    Date of Patent: February 14, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Wittmann, Christian Lindner, Hans-Jurgen Kress, Horst Peters, Jochen Schoeps
  • Patent number: 4801651
    Abstract: (A) polypropylene (10-90 weight part), (B) halogenated butyl rubber (90-10 weight part, (A)+(B)=100 weight part), (C) olefinic rubber (10-120 weight part) and (D) mineral oil softening agent (5-120 weight part) are heated in the presence of (E) metal oxide and/or metal chloride. To 100 weight part of the resulting composition are added, (F) polyolefin (100-600 weight part) and (G) vulcanizable olefinic rubber (50-500 weight part) and the components are mixed and heated in the presence of (H) organic peroxide. The resulting thermoplastic elastomer composition has good paintability, moldability, compatibility, low temperature impact strength, and especially high stiffness at elevated temperature.
    Type: Grant
    Filed: November 2, 1987
    Date of Patent: January 31, 1989
    Assignee: Tonen Sekiyukagaku K.K.
    Inventors: Masato Komatsu, Isao Baba, Kiyotada Narukawa, Noboru Yamamoto, Tsuyoshi Kanai
  • Patent number: 4801647
    Abstract: A thermoplastic elastomeric composition comprising a dynamically crosslinked grafted polyolefin copolymer elastomer and a thermoplastic crystalline polyolefin is disclosed. The crosslinked elastomer is dispersed in the thermoplastic crystalline polyolefin which is present as the continuous phase. The grafted elastomer is ethylene/propylene/diene terpolymer or ethylene/propylene copolymer grafted with fumaric acid, maleic acid, maleic anhydride or derivatives thereof capable of reacting with diamine crosslinking agents.
    Type: Grant
    Filed: March 10, 1988
    Date of Patent: January 31, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: James R. Wolfe, Jr.
  • Patent number: 4801648
    Abstract: The present invention relates to molding materials and sheets which possess improved aging and contact properties, and which comprise a plastic blend based on an acrylate-grafted vinyl chloride polymer, preferably polyvinyl chloride, having an acrylate content of 30-60% by weight, preferably 35-50% by weight, based on 100 parts by weight of vinyl chloride polymer. The molding materials and sheets further comprise another polymer or polymer blend having a glass transition temperature greater than 30.degree. C., preferably greater than 40.degree. C., which is compatible with the vinyl chloride graft polymer. If necessary, additional fillers, processing agents and other conventional additives may be included, so long as 28-44.9% by weight, preferably 30-44.8% by weight, of the vinyl chloride polymer grafted with acrylate is present and 55.1-72% by weight, preferably 55.2-70% by weight, of the other polymer or polymer blend is present.
    Type: Grant
    Filed: May 15, 1986
    Date of Patent: January 31, 1989
    Inventors: Roland Fink, Josef Huber-Hesselberger, Maximilian Mayr
  • Patent number: 4800216
    Abstract: The invention relates to ABS molding compositions having a markedly reduced residual butadiene content, even at high processing temperatures.
    Type: Grant
    Filed: November 2, 1987
    Date of Patent: January 24, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Alfred Pischtschan
  • Patent number: 4792583
    Abstract: Blends are disclosed of monoolefin rubber with high-diene hydrocarbon rubber in which the monoolefin rubber is in the form of discrete vulcanized particles dispersed in a matrix of unvulcanized high-diene hydrocarbon rubber. The blends can be easily processed, and in a subsequent step, the high-diene hydrocarbon portion cured to give rubber articles having the ozone resistance of the monoolefin rubber and the good physical properties of the high-diene hydrocarbon rubber.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: December 20, 1988
    Assignee: Monsanto Company
    Inventor: Aubert Y. Coran
  • Patent number: 4788264
    Abstract: A method of preparing a modified polyethylene which comprises melt kneading 100 parts by weight of (A) a high density polyethylene having a branching degree of not more than 5 per 1,000 carbon atoms of principal chain, from 0.2 to 3 parts by weight of (B) an unsaturated carboxylic acid or a derivative thereof, and from 0.01 to 0.5 part by weight of (C) an organic peroxide, the weight ratio of (C) to (B), (C)/(B), being from 0.01 to 0.5.The modified polyethylenes obtained by the use of the method of the present invention not only have excellent heat resistance, moldability, and so forth, but also are extremely improved in their adhesion property, especially in the property of adhering to a saponified ethylene-vinyl acetate copolymer, a polyamide resin, and a polyester resin, and therefore the modified polyethylenes can be advantageously used with these materials for the production of laminated boards.
    Type: Grant
    Filed: January 22, 1988
    Date of Patent: November 29, 1988
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Mamoru Ukita
  • Patent number: 4785052
    Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.
    Type: Grant
    Filed: November 14, 1986
    Date of Patent: November 15, 1988
    Assignee: Arco Chemical Company
    Inventor: Barry D. Dean
  • Patent number: 4783505
    Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.
    Type: Grant
    Filed: November 14, 1986
    Date of Patent: November 8, 1988
    Assignee: ARCO Chemical Company
    Inventor: Barry D. Dean
  • Patent number: 4777212
    Abstract: The present invention relates to thermoplastic moulding compositions comprising polydiorganosiloxane-polycarbonate block copolymers, copolymers of styrene and maleic anhydrides, graft polymers and, where appropriate, further customary additives and a process for preparing these moulding compositions.
    Type: Grant
    Filed: November 21, 1986
    Date of Patent: October 11, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Winfried Paul, Horst Peters, Christian Lindner, Josef Buekers
  • Patent number: 4774144
    Abstract: Adhesive blends especially suitable for adhesion to polypropylene and gas barrier materials are disclosed, as are composite structures incorporating such blends, and methods of making such composite structures. The blends are preferably elastomer free, and comprise a mixture of an adhesion-promoting amount of high molecular weight low density polyethylene having a narrow molecular weight distribution, about 0.1 to 30 wt. % of a non-elastomeric copolymer of propylene and a polymerizable, ethylenically unsaturated carboxylic acid or derivative, and the balance a non-elastomeric ethylene/propylene copolymer wherein ethylene comprises at least 5 wt. % of the copolymer.
    Type: Grant
    Filed: December 15, 1987
    Date of Patent: September 27, 1988
    Assignee: Enron Chemical Company
    Inventors: Kevin V. Jachec, Peter D. Becker
  • Patent number: 4767817
    Abstract: Shaped articles which have excellent solvent resistance and resistance to fatty acids are formed from a thermoplastic polyblend of poly(vinyl chloride) (PVC), chlorinated polyethylene (CPE), polyolefin (PO), and a graft copolymer of a polyolefin (PO-G). The thermoplastic polyblend contains a PO and PO-G (PO/PO-G) as a first continuous single phase, PVC and CPE as the second and third dispersed phases, and the relative amounts of the components are chosen so that there is, at most, an equal amount by weight of PO and PO-G each of which may be present in an amount as high as 40 parts by weight when the PVC is present in an amount in the range from 40 to 70 parts, so as to provide a mechanically compatible polyblend without miscibility or chemical compatibility. Further, a glass fiber reinforced (GFR) polyblend of PVC/CPE/PO/PO-G having a HDT of at least 95.degree. C. and sufficient thermoformability to form the desired article has excellent notched impact strength.
    Type: Grant
    Filed: March 9, 1987
    Date of Patent: August 30, 1988
    Assignee: The B. F. Goodrich Company
    Inventor: Biing-Lin Lee
  • Patent number: 4764546
    Abstract: A filler-containing polypropylene resin composition and a process for producing the same are disclosed. The composition comprises (a) from 27 to 87% by weight of a polypropylene resin, (b) from 3 to 15% by weight of a modified polypropylene resin containing from 0.1 to 3 mol % of an unsaturated dicarboxylic acid anhydride repeating unit, (c) from 5 to 30% by weight of an ethylene copolymer composed of from 82 to 98.7 mol % of an ethylene repeating unit, from 1 to 15 mol % of an ester repeating unit selected from alkyl acrylates and alkyl methacrylates having from 1 to 8 carbon atoms in the alkyl moiety thereof, and from 0.3 to 3 mol % of an unsaturated dicarboxylic acid anhydride repeating unit, and (d) from 5 to 40% by weight of a filler. The process comprises melt-mixing the components (a), (b) and (d) and then melt-mixing the resulting mixture with the component (c).
    Type: Grant
    Filed: April 23, 1987
    Date of Patent: August 16, 1988
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Tatsuyuki Mitsuno, Hideo Shinonaga, Akio Daimon
  • Patent number: 4762882
    Abstract: A modified polyolefin resin and a composition containing therein such modified polyolefin, having excellent adhesive property and heat-sealing property at the time of high speed forming operations, the modified polyolefin resin consisting essentially of: a copolymer of ethylene and .alpha.-olefin having 4 or more carbon atoms, the copolymer having a density in a range of from 0.890 to 0.910 g/cm.sup.3, a ratio of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn) of Mw/Mn=2 to 15, and a product of a melt tension (g) and a melt-index (g/10 min.) of a molten resin measured at 160.degree. C. of 4 or below; and unsaturated carboxylic acid or derivatives thereof grafted on the ethylene type copolymer at a ratio of from 0.01 to 3% by weight.
    Type: Grant
    Filed: June 26, 1986
    Date of Patent: August 9, 1988
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Shigeaki Okano, Katsuhiko Hayashi, Yoshiteru Sakurazawa, Yoshinori Suga
  • Patent number: 4761463
    Abstract: A thermoplastic resin composition having a matte appearance comprising:(A) 80-5 parts by weight of a graft copolymer obtained by grafting 40-95 parts by weight of diene rubber with 60-5 parts by weight of vinyl compounds consisting of0.1-40 weight % of at least one glycidyl ester of an .alpha.- and .beta.-unsaturated acid as an essential component,10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, and(B) 20-95 parts by weight of a copolymer obtained through reaction of10-40 weight % of at least one vinyl cyanide compound,60-90 weight % of at least one aromatic vinyl compound, and0-30 weight % of other copolymerizable vinyl compounds, the intrinsic viscosity of the resin composition in terms of its components which are soluble in methyl ethyl ketone being 0.25-1.5 dl/g (N,N'-dimethyl formamide solution, 30.degree. C.).
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: August 2, 1988
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shigemi Matsumoto, Fumiya Nagoshi
  • Patent number: 4753988
    Abstract: Impact modified copolymers of vinyl aromatic, ethylenically unsaturated nitrile and, optionally, methyl methacrylate monomer, wherein the impact modifier comprises (a) large grafted rubber particles of a rubbery alkyl acrylate polymer having a particle size from about 0.5.mu. to 0.8.mu., 0.04 to 0.5 percent by weight of a polymerized crosslinking monomer and from 0.5 to 40 percent grafted rigid phase, and (b) small grafted rubber particles of a rubbery alkyl acrylate polymer having a particle size from about 0.05.mu. to about 0.20.mu., 0.25 to about 2.0 percent of a crosslinking monomer, provided that the weight percentage of crosslinking monomer is at least twice the weight percentage of the crosslinking monomer in the large particle, and from about 15 to about 60 percent by weight grafted rigid phase.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: June 28, 1988
    Assignee: The Dow Chemical Company
    Inventors: David E. Henton, Edward B. Anthony
  • Patent number: 4752639
    Abstract: A flexible to soft shaped article containing a vinyl chloride-acrylic acid ester graft copolymer containing 20 to 60% by weight of acrylic acid ester polymer and 40 to 80% by weight of vinyl chloride and 0 to 30% by weight of other ethylenically unsaturated comonomers copolymerizable with vinyl chloride grafted thereon and optionally containing at least one member of the group consisting of other plastics, fillers, processing aids and conventional additives, the weight percentages being based on the total weight of the graft copolymer and optionally at least one additional polymer selected from the group consisting of polymers of high heat distortion resistance, polymers which lower the Shore hardness, polymers imparting elastomeric properties.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: June 21, 1988
    Assignee: Wacker-Chemie GmbH
    Inventors: Ingo Haller, Georg Haberl
  • Patent number: 4749746
    Abstract: A polymer composition which contains a polycarbonate resin, a styrenic/maleimide/cyclic anhydride terpolymer, and an ethylene/propylene/nonconjugated diene terpolymer chemically grafted with either styrene/acrylonitrile copolymer, methylmethacrylate/N-phenylmaleimide copolymer or polymethylmethacrylate is disclosed. The composition exhibits excellent impact strength properties upon molding.
    Type: Grant
    Filed: January 15, 1987
    Date of Patent: June 7, 1988
    Assignee: ARCO Chemical Company
    Inventors: Barry D. Dean, Bi Le-Khac
  • Patent number: 4748210
    Abstract: Vinyl chloride-grafted ethylene copolymer superior in adhesiveness both to metals, glasses or polar high molecular materials such as polyamides and to non-rigid vinyl chloride resins is provided in which backbone polymer is copolymer of ethylene, ester of monohydric alcohol of 1-8 carbon atoms with acrylic acid or methacrylic acid and maleic anhydride and pendant or grafting polymer is vinyl chloride polymer. This copolymer is produced by graft-polymerization of vinyl chloride onto the ethylene-acrylic or methacrylic ester-maleic anhydride copolymer.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: May 31, 1988
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Masahisa Okawa, Tomoyuki Emura, Yoshitaka Owatari, Kentaro Mashita, Toshio Kawakita
  • Patent number: 4742116
    Abstract: A thermoplastic moulding compound based on a rubber-modified copolymer consisting of styrene and/or .alpha.-methylstyrene and maleic anhydride, wherein the moulding compound is composed of a mixture of:A. 50-95% (wt) of a copolymer consisting of:(i) 50-95% (wt) styrene and/or .alpha.-methylstyrene,(ii) 50-5% (wt) maleic anhydride,(iii) 0-20% (wt) acrylate,(iv) 0-20% (wt) acrylonitrile;B. 5-50% (wt) of an ethylene-propylene modified rubber or ethylene-propylene-diene modified rubber, the rubber being modified by grafting thereto a compound containing hydroxyl, amide or amine groups; andC. 0-30% (wt) of an ethylene-propylene rubber or an ethylene-propylene-diene rubber.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: May 3, 1988
    Assignee: Stamicarbon B.V.
    Inventors: Herman A. J. Schepers, Wilhelmus A. M. Debets
  • Patent number: 4742104
    Abstract: The present invention relates to thermoplastic moulding compositions containing thermoplastic polycarbonates, graft polymers, rubber-free copolymers and, if appropriate, copolymeric rubbers, and also, if appropriate, conventional additives, which are characterized in that the rubber-free copolymers contain internal epoxide compounds.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: May 3, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Otto Koch, Hans-Jurgen Kress, Horst Peters
  • Patent number: 4740543
    Abstract: A plastic vehicular instrument panel which is excellent in impact resistance, heat resistance, fabrication efficiency and appearance. The instrument panel is formed of a plastic material comprising as main components specified crystalline propylene-ethylene block copolymer ranging from 50 to 70 weight %, specified glass fibers ranging from 20 to 30 weight %, specified ethylene-propylene copolymer rubber ranging from 15 to 20 weight %, specified pigment ranging from 2 to 5 parts by weight relative to 100 parts by weight of total of the propylene-ethylene block copolymer, the glass fiber, and the ethylene-propylene copolymer rubber.
    Type: Grant
    Filed: August 8, 1986
    Date of Patent: April 26, 1988
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Yoshio Matsuno, Hidehisa Watanabe
  • Patent number: 4739011
    Abstract: A thermoplastic resin composition obtainable by blending 100 parts by weight of a mixture consisting of(A) 75 to 40% by weight of a propylene polymer,(B) 20 to 40% by weight of an ethylene-alpha-olefin copolymer, and(C) 5 to 30% by weight of a graft copolymer obtained by copolymerizing an aromatic vinyl compound and a polar vinyl compound in the presence of an ethylene-alpha-olefin copolymerwith(D) 0.1 to 5 parts by weight of an unsaturated dicarboxylic acid, an anhydride thereof or a mixture of the two, and(E) 0.01 to 0.3 part by weight of an organic radical-generating agent,and then subjecting the resulting blend to thermal treatment. Said composition has not only a high bending modulus inherently possessed by polypropylene resins but also remarkably improved coating property. Accordingly, the composition is useful as interior and exterior trim parts of automobiles and exterior trim parts of motorcycles.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: April 19, 1988
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Takashi Kawata, Yoshitaka Matsuo, Kenya Makino, Noboru Oshima
  • Patent number: 4734456
    Abstract: A thermoplastic resin composition having excellent and well balanced physical properites such as chemical resistance, drop weight impact resistance and thermal stability which comprises (A) a styrenic polymer and (B) a ternary polymer comprising 50 to 98.5% by weight of an olefin, 0.5 to 10% by weight of an unsaturated dicarboxylic acid anhydride and 1 to 40% by weight of an unsaturated carboxylic acid alkyl ester, the weight proportion of the styrenic polymer (A) and the ternary polymer (B) being 100:0.5-200.
    Type: Grant
    Filed: November 10, 1986
    Date of Patent: March 29, 1988
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Kazuhiko Motomatsu, Mikio Kodama, Hiromichi Aoki, Ichiro Sato
  • Patent number: 4728463
    Abstract: Brominated styrene-maleate copolymer containing at least 50 weight percent bromine and its use as a fire retardant.
    Type: Grant
    Filed: August 18, 1986
    Date of Patent: March 1, 1988
    Assignee: Ethyl Corporation
    Inventors: Burton J. Sutker, Gen-Shing Ti, Mo A. Khuddus
  • Patent number: 4728692
    Abstract: A thermoplastic elastomer composition and process comprising a crystalline polyolefin, halogenated butyl rubber, olefin copolymer rubber, polyolefin modified with, e.g., maleic anhydride, and, optionally nitrile rubber, wherein the halogenated butyl rubber is at least partially crosslinked using a metal oxide and/or chloride, e.g., zinc oxide. Crosslinking is achieved under dynamic mixing conditions and the resulting composition has superior strength, performance and processing properties. Furthermore, use of nitrile rubber imparts improved oil resistance to the composition.
    Type: Grant
    Filed: February 18, 1987
    Date of Patent: March 1, 1988
    Inventors: Eiji Sezaki, Takashi Mikami, Tsuyoshi Kanai, Toshio Yoshida, Kikuo Tanaka, Masaaki Saito
  • Patent number: 4721752
    Abstract: A process for preparing an impact resistant thermoplastic moulding compound based on a copolymer consisting of styrene and/or .alpha.-methylstyrene and maleic anhydride by mixing:50-95% (wt) of a copolymer consisting of:(i) 50-95% (wt) styrene and/or .alpha.-methylstyrene,(ii) 50-5% (wt) maleic anhydride,(iii) 0-20% (wt) acrylate,(iv) 0-20% (wt) acrylonitrile;5-50% (wt) of a rubber modified with hydroxyl groups, a rubber modified with amine groups or a rubber modified with amide groups; and0-30% (wt) unmodified rubber,said mixing being conducted in the presence of 0.01-10 parts by weight of a reaction accelerator, calculated on 100 parts by weight copolymer and modified rubber, at a temperature between 160.degree. C. and 290.degree. C.
    Type: Grant
    Filed: January 2, 1986
    Date of Patent: January 26, 1988
    Assignee: Stami Carbon BV
    Inventors: Herman A. J. Schepers, Wilhelmus A. M. Debets
  • Patent number: H568
    Abstract: An olefin polymer composition comprising(A) 100 parts by weight of a homopolymer of 1-butene composed substantially of 1-butene units or a copolymer of 1-butene and another alpha-olefin containing at least 60 mole % of units derived from 1-butene,(B) 10 to 600 parts by weight of a homopolymer of propylene composed substantially of propylene units, a block copolymer of propylene and another alpha-olefin containing at least 50 mole % of units derived from propylene, or a random copolymer of propylene and another alpha-olefin containing at least 90 mole % of units derived from propylene, and(C) 10 to 600 parts by weight of a crystalline random copolymer of propylene and another alpha-olefin containing 50 to 87 mole % of units derived from propylene,at least one of components (A), (B) and (C) being partly modified with (D) an unsaturated carboxylic acid or its derivative; and a laminated structure comprising a substrate and a layer of a 1-butene polymer laminated thereto through an adhesive layer of the olefin po
    Type: Grant
    Filed: March 13, 1986
    Date of Patent: January 3, 1989
    Assignee: Shell Oil Company
    Inventors: Haruhiko Tanaka, Katutoshi Kaneko