Mixture Contains Solid Polymer Derived From Reactant Containing Oxygen Heterocycle Patents (Class 525/74)
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Patent number: 5047467Abstract: A process for producing a grafted alkyd resin, which comprises graft-copolymerizing an alkyd resin with 0.01 to 5.0% by weight of at least one vinyl monomer selected from the group consisting of nitrogen-containing vinyl monomers and phosphorus-containing vinyl monomers.Type: GrantFiled: August 2, 1989Date of Patent: September 10, 1991Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Masahide Amemoto, Hikaru Watanabe, Akio Shoji
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Patent number: 5047475Abstract: Disclosed is a resin composition comprising (A) from 1-98 wt. parts of a graft copolymer obtained by graft-polymerizing (a) 5-80 wt. % of a rubbery polymer and (b) 95-20 wt. % of a monomer mixture consisting of 40-90 wt. % of an aromatic vinyl compound, 60-10 wt. % of a vinyl cyanide compound and 0-50 wt. % of another ethylenically unsaturated compound copolymerizable therewith, (B) 1-40 wt. % parts of a modified copolymer selected from (B.sub.1) a modified vinyl copolymer obtained by polymerizing (a) 40-90 wt. % of an aromatic vinyl compound, (b) 60-10 wt. % of a vinyl cyanide compound, (c) 0.01-10 wt. % of a monomer having an epoxy, carboxyl or amino group, and (d) 0-40 wt. % of another ethylenically unsaturated compound, and (B.sub.2) a modified olefinic copolymer obtaind by copolymerizing (e) 50-95 wt. % of ethylene or propylene, (f) 0.1-20 wt. % of a monomer having an epoxy, carboxyl or amino group, and (g) 0-40 wt. % of another ethylenically unsaturated compound, (C) 1-60 wt.Type: GrantFiled: August 3, 1989Date of Patent: September 10, 1991Assignee: Toray Industries, Inc.Inventors: Takuya Ogawa, Masatoshi Iwamoto, Kazumasa Chiba, Kazuhisa Yano
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Patent number: 5045401Abstract: Multicomponent thermoplastic resin blends are disclosed which have a nonisothermal crystallization half life of less than thirty seconds. Especially preferred are three component resin blends comprising a maleic anhydride grafted HDPE, an unmodified LLDPE copolymer having a density between about 0.905 and 0.93 g/cc, and an unmodified LLDPE copolymer having a density between about 0.89 and 0.92 g/cc. These thermoplastic resin blends can be used as the adhesive layer in multilayer structures. They are especially useful in blown film multilayer structures and they show particularly good adhesion to polar substrates, e.g., EVOH substrates.Type: GrantFiled: December 21, 1989Date of Patent: September 3, 1991Assignee: The Dow Chemical CompanyInventors: Ricky L. Tabor, Gerald M. Lancaster, Michael W. Potts, Thomas I. Butler
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Patent number: 5043392Abstract: Functionalized thermoplastics such as styrene-maleic anhydride copolymers polystyrene or maleated polyolefins may be thoughened with halogenated rubbers which are copolymers of isoprene and isobutylene provided a dialkyl or dihydroxyalkyl amino alkanol is present as a compatibilizer. The toughened thermoplastics have about a two fold increase in IZOD impact resistance.Type: GrantFiled: January 22, 1990Date of Patent: August 27, 1991Assignee: Polysar LimitedInventors: James Lunt, Susan A. M. May, Patricia A. Leivo
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Patent number: 5039719Abstract: A glass fiber-reinforced thermoplastic resin comprising:(i) 100 parts by weight of a blend of a polyamide and a styrene copolymer which in turn is a blend of a high impact polymer such as ABS and a carboxylated styrene copolymer and, optionally, a styrene copolymer with acrylonitrile or MMA;(ii) 5 to 100 parts by weight of glass fiber reinforcement, which glass fiber has a coat on it of a binder which comprises a polymeric binder composition and a silane binder, both being specified.Type: GrantFiled: July 16, 1990Date of Patent: August 13, 1991Assignees: Monsanto Kasei Company, Nippon Glass Fiber Co., Ltd.Inventors: Makoto Watanabe, Akio Kisaichi
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Patent number: 5034449Abstract: A polyblend composition containing an olefin polymer, a rubber-modified styrenic resin, and a block copolymer compatibilizer is disclosed. In a preferred embodiment, a crystalline propylene polymer, a styrene/maleic anhydride random thermoplastic copolymer modified with a grafted styrene/butadiene rubber, and a hydrogenated styrene/butadiene block copolymer are intimately mixed to form a useful thermoplastic polyblend.Type: GrantFiled: September 11, 1989Date of Patent: July 23, 1991Assignee: Arco Chemical Technology, Inc.Inventor: Ramesh Mallikarjun
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Patent number: 5026770Abstract: The invention relates to a resin composition comprising a mixture of resins, a first resin of which consists of the reaction product of an epoxidized fatty acid ester of a polyvalent alcohol with a carboxylic acid and a second resin consists of an ester of a polyvalent alcohol, modified with carboxylic acid.The resin mixture, contains an unsaturated polyester resin having a molecular weight of 1200-20,000 per double bond and an acid number of 5-50, from about 50% to about 90% of the unsaturation being formed by a semi-ester of an .alpha.,.beta.-unsaturated dicarboxylic acid.Type: GrantFiled: January 3, 1990Date of Patent: June 25, 1991Assignee: Stamicarbon B.V.Inventors: Paulus J. H. M. Smeets, Caspar G. M. Paas, Willem P. M. Kraanen
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Patent number: 5024888Abstract: A hot melt adhesive and a laminar structure fabricated from a blend comprising a modified or unmodified ethylenic copolymer, a modified or unmodified butene-1 homopolymer or copolymer, a stabilizer and one or more of: a tackifying resin compatible with the major amount of modified polymer, a wax, and atactic polypropylene.Type: GrantFiled: July 30, 1990Date of Patent: June 18, 1991Assignee: Shell Oil CompanyInventors: Charles C. Hwo, Simone Mostert
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Patent number: 5021113Abstract: An adhesive composition comprising a plurality of selectively hydrogenated block copolymers, each of said block copolymers comprising at least one polymeric block containing predominantly monoalkenyl aromatic hydrocarbon monomer units and at least one polymeric block containing predominantly conjugated diolefin monomer units, at least one of which block copolymers is carboxylated and at least one of which block copolymers is not carboxylated and laminated structures comprising a plurality of polymeric layers tied together with said adhesive composition. The adhesive composition contains a relatively minor amount of carboxyl groups, on average, per polymer chain in the composition and is particularly useful in the preparation of laminated structures via coextrusion or similar processes, wherein the various layers are brought together in the molten phase while in motion, when one or more layers in the laminated structure comprises a polar group reactive with the carboxyl groups.Type: GrantFiled: June 25, 1990Date of Patent: June 4, 1991Assignee: Shell Oil CompanyInventors: Andrea Sanders, Glenn R. Himes
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Patent number: 5015690Abstract: A modifier composition which provides retention of surface smoothness and internal appearance while imparting improved low-temperature impact properties to molded thermoplastics and the thermoplastic molding compositions containing said modifier, the modifier comprising a crystalline thermoplastic resin and a modifier formed by combining a grafted EPM or EPDM rubber and a reactive polystyrene.Type: GrantFiled: February 28, 1989Date of Patent: May 14, 1991Assignee: Copolymer Rubber & Chemical CorporationInventor: William G. Williams
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Patent number: 5010119Abstract: An adhesive composition which contains a thermoplastic elastomeric polymer which includes ethylene propylene rubber, ethylene propylene diene monomer, polyisobutylene butyl rubber, ethylene vinyl acetate graft copolymers thereof with C.sub.3 to C.sub.10 unsaturated mono- and polycarboxylic acids, a tackifiying resin and a encapsulated maleated polymer di- or polyamine cross-linking agent having 2-10 carbon atoms, which is useful as a hot melt or pressure sensitive adhesive having enhanced higher temperature properties. Also claimed is the encapsulated polyamine itself. Preferably, the encapsulating material is maleated polypropylene.Type: GrantFiled: November 25, 1988Date of Patent: April 23, 1991Inventors: Kenneth O. McElrath, Jr., Martha H. Robertson, Wai Yan Chow
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Patent number: 5004783Abstract: A polymer blend comprises a high nitrile copolymer and a compatible thermoplastic polymer or copolymer containing polar groups, formed from monomers selected from the group consisting of alkylacrylamides, aliphatic and cyclic methacrylates, unsaturated carboxylic acid anhydrides, vinyl pyrrolidones, heterocyclic ring compounds containing two hetero atoms, lactones and phosphorus-containing monomers that form highly crystalline polymers. Such blends can be used to form films and membranes having improved thermal, mechanical and optical properties.Type: GrantFiled: August 22, 1988Date of Patent: April 2, 1991Assignee: The Standard Oil CompanyInventors: Elena S. Percec, Doreen Y. Takigawa
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Patent number: 5003004Abstract: A blend of a softer continuous phase polymer reinforced with harder acrylic star polymer particles having reactive functional groups with crosslinking ability built in or provided by a third polymer. The harder polymer has a T.sub.g at least 10.degree. C. above that of the softer polymer, and the acrylic star polymer is preferably made by group transfer polymerization. This blend provides coating compositions, films and bulk polymer with enhanced toughness and flexibility.Type: GrantFiled: October 25, 1988Date of Patent: March 26, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventor: John A. Simms
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Patent number: 5001194Abstract: A functionalized polymeric composition, said polymeric composition comprising a first phase and a second phase. The first phase comprises a first copolymer of a monovinylidene monomer and a comonomer selected to have at least one reactive epoxide functionality. The second phase is dispersed with the first phase. The second phase comprises a copolymer of an olefin monomer and one or more ethylenically unsaturated monomers copolymerizable with the olefin monomer wherein at least one of the ethylenically unsaturated monomers copolymerizable with the olefin monomer comprises a reactive functionality capable of reacting with one or more of the reactive epoxide functionalities of the first copolymer.Type: GrantFiled: July 7, 1989Date of Patent: March 19, 1991Assignee: The Dow Chemical CompanyInventor: David E. Henton
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Patent number: 4997875Abstract: Disclosed is a composition comprising about from 20 to 65 percent by weight of a fiber reinforcing-agent, preferably glass fiber, dispersed in as-polymerized propylene polymer material, e.g., propylene homopolymer, having a melt flow rate (MFR) of about from 55 to 430 dg/min. The composition is useful in the manufacture of large and complex fiber-reinforced articles and parts by injection molding.Type: GrantFiled: March 31, 1989Date of Patent: March 5, 1991Assignee: Himont IncorporatedInventors: Kathleen A. Geddes, Ralph A. Guyer, Richard C. Miller
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Patent number: 4997872Abstract: A resinous composition suitable for powder coating comprises (A) 80-98 parts by weight of a polypropylene composition comprising a crystalline propylene polymer grafted with an unsaturated carboxylic acid or an anhydride thereof, (B) 20-2 parts by weight of an ethylene/.alpha.-olefin copolymer having a density of 0.860-0.915 g/cm.sup.3, (C) 0.001-1.0 part by weight of a polymer of vinyl cycloalkane having 6 or more carbon atoms, and (D) 0-10 parts by weight of a metal oxide or a metal hydroxide.Type: GrantFiled: September 8, 1989Date of Patent: March 5, 1991Assignee: Sumitomo Chemical Company, Ltd.Inventors: Tadayuki Ohmae, Hisao Tanaka, Mitsuyuki Okada
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Patent number: 4994508Abstract: A composition comprising,(a) 1 to 99 parts by weight of a specific hydrogenated product of a block copolymer having at least one polymer block composed mainly of a vinyl aromatic compound and at least one polymer block composed mainly of a conjugated diene compound, a modified product which comprises said product modified with an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof, or a mixture of said product and said modified product, wherein the content of the vinyl aromatic compound prior to hydrogenation is 5 to 95% by weight and a content of vinyl linkages [V] prior to hydrogenation which originated from the conjugated diene compound is 10 to 80%, said product satisfying the following conditions;(1) the hydrogenated ratio [A] of the total of aliphatic double bonds which originated from the conjugated diene compound is not lower than 5% and lower than 50%, and[B]/[V].sup.Type: GrantFiled: July 14, 1988Date of Patent: February 19, 1991Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Yasuo Hattori
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Patent number: 4990554Abstract: A polyolefin composition is disclosed, which comprises a polyolefin and an inorganic filler, wherein the polyolefin composition comprising (A) 75 to 97% by weight of a polyolefin component comprising (a) 90-65 parts by weight of a polymer composition comprising a crystalline polypropylene component and an ethylene-propylene random copolymer component and having an ethylene content of 7% by weight or less and/or a propylene homopolymer and (b) 10 to 35 parts by weight of a polyethylene having a melt index of not lower than 10 g/10 min., said melt index being from 1.0 to 50 times that of the polymer (a), and (B) 25 to 3% by weight of a fibrous inorganic filler having an average fiber diameter of 0.1 to 0.8 micrometer and an aspect ratio of 20 to 60.The polyolefin composition is capable of providing, upon molding, articles having good surface appearance, in particular glossiness and improved mechanical strengths with less warping and deformation.Type: GrantFiled: May 23, 1989Date of Patent: February 5, 1991Assignee: Idemitsu Petrochemical Company LimitedInventors: Manabu Nomura, Ryozo Tomomatsu, Toshifumi Shimazaki
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Patent number: 4987165Abstract: A novel thermoplastic resin composition is here disclosed which contains (I) 99 to 1% by weight of a polysulfone or polyether sulfone; (II) 1 to 99% by weight of an acrylonitrile-butadiene-styrene resin; (III) 0.1 to 100 parts by weight, based on 100 parts by weight of the aforesaid resin (I)+(II), of a multi-phase structure thermoplastic resin which is composed of 5 to 95% by weight of an epoxy group-containing olefin copolymer and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one kind of vinyl monomer, either of the polymer or copolymer being in the state of a dispersion phase having a particle diameter of 0.001 to 10 .mu.m; and (IV) 0 to 150 parts of an inorganic filler.Furthermore, a method for preparing the aforesaid composition is also disclosed.Type: GrantFiled: September 28, 1989Date of Patent: January 22, 1991Assignees: Nippon Petrochemicals Co., Ltd., Nippon Oil & Fats Co., Ltd.Inventors: Yuichi Orikasa, Suehiro Sakazume
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Patent number: 4985496Abstract: Disclosed is a thermoplastic resin composition comprising (A) a graft copolymer obtained by emulsion-graft-polymerizing 0 to 20% by weight of an acrylic monomer and 0 to 60% by weight of an aromatic vinyl monomer in the presence of 40 to 80% by weight (as solids) of a diene type rubber polymer latex containing at least 50% by weight of a diene type rubber polymer having a weight average particle diameter of at least 0.3 .mu.m, and (B) a copolymer of an .alpha.,.beta.-unsaturated cyclic anhydride and an aromatic vinyl compound. The thermoplastic resin composition has a high heat resistance and impact resistance.Type: GrantFiled: June 15, 1989Date of Patent: January 15, 1991Assignee: Mitsubishi Rayon Company, Ltd.Inventors: Kazuo Kishida, Kiyokazu Kitai, Masaaki Mohri
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Patent number: 4985475Abstract: The invention provides a grease compatible encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized compound, a crosslinking agent, and an oxirane containing material which provides improved hydrolytic stability to the encapsulant composition.Type: GrantFiled: November 25, 1988Date of Patent: January 15, 1991Assignee: Minnesota Mining and ManufacturingInventors: Thomas S. Croft, Hartwick Haugen
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Patent number: 4983435Abstract: As an adhesive used between a polypropylene layer and an ethylene/vinyl alcohol copolymer layer, there is provided an adhesive composition that comprises 98.9 to 59.9% by weight of a modified polypropylene (A) partly or fully grafted with an unsaturated carboxylic acid or its derivative, 1.0 to 40% by weight of an ethylene/.alpha.-olefin copolymer (B) having a density of 0.915 to 0.940 g/cc, and a melting point of 115.degree. to 130.degree. C., and 0.1% by weight or more but less than 3% by weight of a hydrocarbon type synthetic elastomer (C).Type: GrantFiled: October 31, 1988Date of Patent: January 8, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toru Ueki, Hajime Sentoku, Takashi Miyazaki, Eiichi Sugihara
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Patent number: 4978715Abstract: Impact- and solvent-resistant resin blends are prepared from a polyphenylene ether, or blend thereof with a polystyrene, a linear polyester such as a poly(alkylene dicarboxylate), at least one elastomeric polyphenylene ether-compatible impact modifier and at least one polymer containing a substantial proportion of aromatic polycarbonate units as a compatibilizing agent. There may also be present a minor amount of at least one epoxide and/or masked isocyanate such as triglycidyl isocyanurate or a glycidyl methacrylate polymer. The polyphenylene ether is preferably inactivated by reaction with at least one non-volatile carboxylic acid or anhydride and/or by extrusion with vacuum venting.Type: GrantFiled: August 15, 1988Date of Patent: December 18, 1990Assignee: General Electric CompanyInventors: Sterling B. Brown, Dennis J. McFay, John B. Yates, III, Gim F. Lee
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Patent number: 4977212Abstract: An adhesive resin composition useful for bonding a resin having gas barrier properties and a hydrophobic thermoplastic resin which comprises an ethylene-acrylate or methacrylate copolymer grafted with an ethylenic unsaturated carboxylic acid or its acid anhydride; and 0.02 to 0.6 equivalent to the ethylenic unsaturated carboxylic acid or its acid anhydride of a periodic table group Ia or IIa metal hydroxide, or said metal hydroxide and an ethylene-acrylate or methacrylate copolymer. A laminated material of a resin having gas barrier properties and a hydrophobic thermoplastic resin laminated with the adhesive resin composition and a resin composition comprising the adhesive resin composition, a resin having gas barrier properties and a hydrophobic thermoplastic resin are also disclosed.Type: GrantFiled: July 20, 1988Date of Patent: December 11, 1990Assignees: Kuraray Co., Ltd., Nippon Petrochemicals Co., Ltd.Inventors: Toshiyuki Akazawa, Takuji Okaya, Takashi Inoue, Toshitaka Kobayashi
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Patent number: 4977206Abstract: A hot melt adhesive and a laminar structure fabricated from a blend comprising a modified or unmodified ethylenic copolymer, a modified or unmodified butene-1 homopolymer or copolymer, a stabilizer and one or more of: a tackifying resin compatible with the major amount of modified polymer, a wax, and atactic polypropylene.Type: GrantFiled: February 3, 1989Date of Patent: December 11, 1990Assignee: Shell Oil CompanyInventors: Charles C. Hwo, Simone Mostert
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Patent number: 4975487Abstract: A polymeric polyblend comprising a vinylidene chloride interpolymer and a thermoplastic graft copolymer.Type: GrantFiled: November 9, 1988Date of Patent: December 4, 1990Assignee: The Dow Chemical CompanyInventor: Yun C. Sun
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Patent number: 4975474Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.Type: GrantFiled: October 11, 1989Date of Patent: December 4, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert J. Barsotti, Patrick H. Corcoran
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Patent number: 4973624Abstract: A resin composition for coating comprising (A) a polyester-modified vinyl copolymer obtained by copolymerization of (a) a polyester resin having 5 to 60% by weight of oil or fatty acid component with special physical limitations, (b) a polymerizable unsaturated monomer having at least one tertiary amino group, (c) a polymerizable unsaturated monomer having at least one carboxyl group, and (d) an unsaturated monomer copolymerizable with the components (b) or (c), and (B) an epoxy resin can be cured at room temperature or with slight heating to give a coating film excellent in dispersibility of pigment having large oil absorption.Type: GrantFiled: February 24, 1989Date of Patent: November 27, 1990Assignee: Hitachi Chemical Company, Ltd.Inventors: Eiichi Ohtani, Masayuki Mogami, Kengo Kobayashi, Shigeyoshi Tanaka
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Patent number: 4973625Abstract: Composite moisture and oxygen barrier structures in the form of films, sheets, tubes and bottles are described which are composed of foils of high density polyethylene and foils of polar oxygen barrier resins adhered to each other with a coextruded bonding resin composition composed of blends of predominantly high density polyethylene containing low levels of a grafted unsaturated dicarboxylic acid anhydride and linear low density polyethylenes which are copolymers of ethylene with either octene-1 or butene-1. The preferred dicarboxylic acid anhydride is maleic anhydride. The oxygen barrier resins are preferably ethylene/vinyl alcohol copolymers or amorphous polycarboxylamides from condensation polymerization of aliphatic diamines and aromatic dicarboxylic acids.Type: GrantFiled: September 23, 1987Date of Patent: November 27, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Edward J. Deyrup
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Patent number: 4972020Abstract: A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, abrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.Type: GrantFiled: February 7, 1989Date of Patent: November 20, 1990Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Fusakazu Hayano, Hideo Morita
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Patent number: 4972027Abstract: Disclosed is a composition curable at a low temperature and characterized in that the composition comprises:(a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing a radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising as its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer,(b) a chelate compound admixed with a nonaqueous dispersion.Type: GrantFiled: November 15, 1988Date of Patent: November 20, 1990Assignee: Kansai Paint Company, LimitedInventors: Osamu Isozaki, Noboru Nakai, Shinji Sugiura, Satoru Ito, Seiji Takami
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Patent number: 4968747Abstract: Thermoplastic resin compositions having good toughness and resistance to heat deformation are obtained by blending crystalline propylene polymers, elastomeric olefin polymers, random styrenic copolymers, and epoxy group-containing copolymers. For example, the composition may be a blend of polypropylene, ethylene-propylene or ethylene-propylene-diene monomer rubber, styrene/maleic anhydride copolymer, and ethylene/glycidyl methacrylate or ethylene/glycidol methacrylate/vinyl acetate copolymer. Physical properties are enhanced by the use of a two step blending procedure.Type: GrantFiled: March 30, 1990Date of Patent: November 6, 1990Assignee: Arco Chemical Technology, Inc.Inventor: Ramesh Mallikarjun
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Patent number: 4957968Abstract: The present invention relates to an adhesive thermoplastic elastomer composition comprising three major components as follows:(a) at least one polyolefin modified by a chemically reactive functional group such as a carboxylic acid or its derivatives including anhydride, acid chloride, isocyanate, oxazoline, epoxide, amine and hydroxide;(b) at least one other polymer prepared from one or more of the following: ethylene, propylene, butylene, isobutylene, octene-1, 4 methyl pentene-1, hexene-1 or mixtures; and(c) at least one olefinic elastomer, including elastomeric ethylene-propylene copolymers, elastomeric ethylene-propylene terpolymers, polyisoprene, polyisobutylene, ethylene-propylene copoloymer rubber, polybutadiene, natural rubber, elastomeric polyesters, polyurethane elastomers, polyamide elastomers and mixtures.Type: GrantFiled: August 9, 1988Date of Patent: September 18, 1990Assignee: Monsanto CompanyInventors: Ashok M. Adur, Robert C. Constable
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Patent number: 4957964Abstract: The thermoplastic resin composition of the invention comprises (A) from 50 to 90 parts by weight of a copolymer of an aromatic vinyl monomer and an unsaturated dicarboxylic acid anhydride, e.g. copolymer of styrene and maleic anhydride, (B) from 50 to 10 parts by weight of an ABS or MBS resin and (C) from 0.01 to 1.0 part by weight of an organopolysiloxane. In contrast to conventional polymer blend compositions composed of the above mentioned components (A) and (B), the inventive resin composition is capable of giving a shaped article having a greatly improved impact strength without adverse influences on the heat resistance and surface luster of the shaped articles molded of a resin composition of this type inherent thereto.Type: GrantFiled: February 14, 1990Date of Patent: September 18, 1990Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Ryozo Okumura, Eiichi Terada, Shigemi Kawazoe
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Patent number: 4950541Abstract: Succinic acid or succinic anhydride grafts of linear ethylene polymers are blended with other polymers or resins, e.g. polyesters and the like, to form blends having useful adhesive properties. The adhesive properties are useful in various laminates and in bicomponent fibers which comprise a core of a performance fiber, especially a polyester such as PET or PBT and polyamides, and a sheath of the grafted LDPE, HDPE or LDPE. The succinic acid or succinic anhydride groups are provided by grafting, respectively, maleic acid or maleic anhydride onto the LDPE, LLDPE, and HDPE, especially by a process wherein the grafting is done in a twin-screw, co-rotating extruder with the maleic acid or maleic anhydride being injected into a pressured zone of the extruder. The acid containing grafted polymer is dyeable in contradistinction to ungrafted polymer.Type: GrantFiled: December 22, 1988Date of Patent: August 21, 1990Assignee: The Dow Chemical CompanyInventors: Ricky L. Tabor, Gerald M. Lancaster, Zdravko Jezic, Gene P. Young, John O. Biesser
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Patent number: 4942096Abstract: The present invention relates to a polypropylene resin composition useful as an adhesive comprising(A) from about 51 wt. % to about 99 wt. % of a modified polypropylene resin graft-modified with a radical-polymerizable polar unsaturated compound or a mixture of the modified polypropylene resin graft-modified with a radical polymerizable polar unsaturated compound with an unmodified polypropylene resin,(B) a substantially non-crystalline .alpha.-olefin copolymer, and(C) an ethylene/.alpha.-olefin coplymer having a density of from about 0.860 g/cm.sup.3 to less than about 0.910 g/cm.sup.3, a n-hexane insolubility of at least about 50 wt. % and a melting point of at least 100.degree. C.,wherein the combined weights of components (B) and (C) is from about 1 wt. % to about 49 wt. %, and the weight ratio of (B)/(C) is from about 1/99 to about 99/1.Type: GrantFiled: November 17, 1989Date of Patent: July 17, 1990Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masaru Abe, Yoichi Kawai, Takashi Miyazaki
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Patent number: 4942200Abstract: Thermoplastic compositions consisting essentially of 25-80 weight percent polyamide, 10-70 weight percent polyarylate, 0.5-30 weight percent elastomeric modifier, and 0.5-7 weight percent epoxy functional polymer, where the epoxy functional polymer and the polyarylate are preblended with each other, show unexpectedly superior resistance to high speed puncture, even as compared with the same formulation absent preblending.Type: GrantFiled: March 9, 1988Date of Patent: July 17, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventors: Edmund A. Flexman, James J. Sosnowski
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Patent number: 4937286Abstract: Thermoplastic moulding compositions ofA. 90 to 30 parts by weight of a copolymer prepared by solution or bulk polymerization of a.sub.1 30 to 45% by weight of .alpha.-methylstyrene, a.sub.2 26 to 35% by weight of acrylonitrile and a.sub.3 44 to 20% by weight of styrene and/or p-methylstyrene, and with a content of incorporated acrylonitrile of 27-30% by weight,B. 5 to 60 parts by weight of a random copolymer of b.sub.1 18 to 24% by weight of maleic anhydride and b.sub.2 82 to 76% by weight of styrene and/or p-methylstyrene andC. 5 to 40 parts by weight of a graft polymer of 70 to 30% by weight of a mixture of c.sub.1 a vinylaromatic and/or C.sub.1 -C.sub.4 -alkyl and c.sub.2 acrylonitrile, on 30 to 70% by weight of a rubber with a glass transistion temperature of less than -10.degree. C.Type: GrantFiled: October 13, 1987Date of Patent: June 26, 1990Assignee: Bayer AktiengesellschaftInventors: Frank Wingler, Klaus Summermann, Ulrich Jansen, Joachim Doring, Alfred Pischtschan
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Patent number: 4921910Abstract: Functionalized thermoplastics such as styrene-maleic anhydride copolymers or maleated polyolefins may be toughened with halogenated rubbers which are copolymers of isoprene and isobutylene provided a dialkyl or dihydroxyalkyl amino alkanol is present as a compatibilizer. The toughened thermoplastics have about a two fold increase in IZOD impact resistance.Type: GrantFiled: April 19, 1989Date of Patent: May 1, 1990Assignee: Polysar LimitedInventors: James Lunt, Susan A. M. May, Patricia A. Leivo
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Patent number: 4914138Abstract: A polymer blend comprises a high nitrile polymer and a compatible polyolefin functionalized with an unsaturated compound selected from the group consisting of unsaturated carboxylic acids, esters, anhydrides and imides. Such blends can be used to form films and membranes having improved thermal, mechanical and optical properties. The blend combines the low oxygen permeability of high nitrile polymers with the low water vapor permeability of the polyolefins and are, therefore, useful in the packaging industry. A method for forming blends of high nitrile polymers with polyolefins includes the step of functinalizing a polyolefin prepared from a monoolefin having from 2 to about 6 carbon atoms with an unsaturated compound selected from the group consisting of unsaturated carboxylic acids, esters, anhydrides and imides and blending from about 99 to 1 parts by weight of the functionalized polyolefin with from about 1 to 99 parts by weight of the high nitrile polymer.Type: GrantFiled: August 22, 1988Date of Patent: April 3, 1990Assignee: The Standard Oil CompanyInventors: Elena S. Percec, Lucy Melamud, Gerald P. Coffey
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Patent number: 4912161Abstract: Thermoplastic moulding compounds containing(A) from 5-90 parts by weight of one or more thermoplastic polymers,(B) from 5-90 parts by weight of one or more graft polymers and(C) from 0.25-40 parts by weight of a blocked copolymer corresponding to the idealized formula (I)A - B - A; B - A - B or (A - B).sub.x (I)whereinA denotes the residue of a homopolymer, e.g. of styrene, andB denotes the residue of a homopolymer of a cyclic carbonate or lactone.Type: GrantFiled: March 6, 1989Date of Patent: March 27, 1990Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Edgar Leitz, Karl-Heinz Ott, Alfred Pischtschan
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Patent number: 4912162Abstract: Disclosed is a graft copolymer resin prepared by graft polymerizing a vinyl compound onto a composite-structured acrylic rubber whose particles are composed of a core consisting of a diene rubber enlarged by treatment with an acid group-containing copolymer latex, and an outer layer consisting of an acrylate polymer having a crosslinked structure formed by the combined use of a graft-linking agent and a cross-linking agent. This graft copolymer resin may be blended with a rigid thermoplastic resin in a specific proportion. This resin composition imparts a good gloss to the molded articles formed therefrom, while retaining excellent impact resistance and weather resistance.Type: GrantFiled: February 3, 1987Date of Patent: March 27, 1990Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuo Kishida, Yutaka Toyooka, Haruyoshi Kitahara
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Patent number: 4908397Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.Type: GrantFiled: June 27, 1988Date of Patent: March 13, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert J. Barsotti, Patrick H. Corcoran
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Patent number: 4906677Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; and(c) 0.1-7% by weight, based on the weight of the binder, of a phosphonium catalyst or a blend of a phosphonium catalyst and a tertiary amine catalyst which may or may not contain hydroxyl groups.Type: GrantFiled: June 27, 1988Date of Patent: March 6, 1990Assignee: E. I. Du Pont de Nemours & CompanyInventors: Robert Barsotti, Lester S. Cohen
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Patent number: 4904309Abstract: A chemical cleaning method for removing scales and other substances deposited on the interior of a polymerization reactor used in emulsion polymerization or suspension polymerization. This method comprises chemically cleaning the interior using an aqueous solution or dispersion of an alkali agent and a surfactant. According to this method of cleaning, scales deposited on the interior of a polymerization reactor, in particular, scales deposited during polymerization on the inside surface, an agitator and baffle-plates of the reactor are completely removed.Type: GrantFiled: October 26, 1988Date of Patent: February 27, 1990Assignee: Kanegafuchi Chemical Industry Co., Ltd.Inventors: Takamichi Komabashiri, Toragoro Mitani, Hiroaki Yamauchi, Hideo Yasui
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Patent number: 4900787Abstract: A thermoplastic resin composition affording a delustered shaped article which comprises (A) a rubber-modified copolymer with (B) an epoxy group-containing olefin polymer or an unsaturated carboxylic acid-modified olefin polymer (B').Type: GrantFiled: September 7, 1988Date of Patent: February 13, 1990Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Hajime Sakano, Akitoshi Ito, Motoichi Yano, Yasuhiro Honda, Takayoshi Fujiwara
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Patent number: 4898911Abstract: A melt-blended resin composition useful as a modifier for improving the impact resistance of thermoplastic resins which comprises (a) a polymer containing at least one epoxy group per molecule and having a modulus of elasticity in bending of at most 10.sup.4 kg/cm.sup.2, e.g. an .alpha.-olefin/glycidyl ester or ether copolymer, and (b) a copolymer of an .alpha.-olefin and an .alpha.,.beta.-unsaturated carboxylic acid wherein at least 5% by mole of the carboxyl groups are neutralized with an alkali metal.Type: GrantFiled: December 24, 1987Date of Patent: February 6, 1990Assignee: Kanegafuchi Kagaku Kogyo KabushikiInventors: Shunitsu Miyashita, Kenji Mogami
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Patent number: 4897447Abstract: A thermoplastic molding composition and modifier for improving the impact strength and toughness thereof in which the modifier is the combination of (1) an EPM or EPDM rubber grafted with an alpha-beta unsaturated dicarboxylic acid or anhydride or an epoxy functional alpha-beta ethylenically unsaturated hydrocarbon and (2) an epoxy acrylate oligomer of bisphenol A.Type: GrantFiled: December 28, 1987Date of Patent: January 30, 1990Assignee: Copolymer Rubber & Chemical Corp.Inventor: William G. Williams
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Patent number: 4894416Abstract: A low gloss thermoplastic with good physical properties consists of a blend of ASA and a gloss-reducing amount of a glycidyl (meth)acrylate copolymer.Type: GrantFiled: December 27, 1988Date of Patent: January 16, 1990Assignee: General Electric CompanyInventor: Robert R. Gallucci
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Patent number: 4886857Abstract: Styrene based resin compositions comprise a styrene resin and a graft copolymer obtained by graft-polymerizing, in the presence of a butadiene based rubbery polymer, a monomer mixture composed of a monomer containing 1-50 ethylene oxide groups and one ethylenically-unsaturated bond and styrene or a monomer mixture compound of styrene as a principal component and at least one monomer copolymerizable with styrene. The a styrene based resin compositions are obtained by blending the graft copolymer with a styrene resin and having excellent impact strength and visual properties.Type: GrantFiled: March 21, 1988Date of Patent: December 12, 1989Assignee: Kureha Kagaku Kogyo K. K.Inventors: Masanori Ota, Fumio Akutsu, Kazuo Takahashi