Mixture Contains Solid Polymer Derived From Reactant Containing Oxygen Heterocycle Patents (Class 525/74)
  • Patent number: 4719260
    Abstract: Disclosed is a hot-melt adhesive composition comprising from about 55 to about 95 weight % of an amorphous polymer containing at least 30% propylene and from about 45 to about 5 weight % of a graft copolymer of(a) a saturated, polycyclic hydrocarbon resin, and(b) maleic anhydride.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: January 12, 1988
    Assignee: Eastman Kodak Company
    Inventors: Richard K. Stuart, Jr., Bruce W. Foster
  • Patent number: 4701493
    Abstract: An acrylic modified styrenic/N-arylmaleimide copolymer containing composition which exhibits excellent melt flow properties, impact strength and gloss upon molding is disclosed.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: October 20, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Barry D. Dean
  • Patent number: 4696972
    Abstract: A polymeric molding composition containing a polycarbonate resin, a styrenic copolymer and a methylmethacrylate-butadiene-styrene polymer is disclosed. The molding compositions of this invention exhibit excellent impact strength and can be molded over a wide range of processing conditions.
    Type: Grant
    Filed: April 1, 1985
    Date of Patent: September 29, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Larry G. Bourland
  • Patent number: 4687810
    Abstract: A rubber blend is produced by masticating a mixture of monoolefin copolymer rubber and high-diene hydrocarbon rubber while dynamically vulcanizing the monoolefin copolymer rubber. The blend is then further treated to vulcanize the high-diene hydrocarbon rubber portion. The resulting vulcanized blend has improved properties.
    Type: Grant
    Filed: January 2, 1986
    Date of Patent: August 18, 1987
    Assignee: Monsanto Company
    Inventor: Aubert Y. Coran
  • Patent number: 4684576
    Abstract: Succinic acid or succinic anhydride grafts of HDPE are blended with ungrafted LLDPE and with ungrafted LDPE to form blends having useful adhesive properties. The succinic acid or succinic anhydride groups are provided by grafting, respectively, maleic acid or maleic anhydride onto HDPE. Laminates of the blends on various metals and polymers are shown.
    Type: Grant
    Filed: February 3, 1986
    Date of Patent: August 4, 1987
    Assignee: The Dow Chemical Company
    Inventors: Ricky L. Tabor, James A. Allen
  • Patent number: 4678834
    Abstract: A polyolefin blend comprising, in physical admixture, a major portion of particles of a polyethylene and a minor portion of particles of a composition of a thermoplastic second polymer, is disclosed. The polyethylene is selected from the group consisting of homopolymers of ethylene and copolymers of ethylene and at least one C.sub.4 -C.sub.10 higher alpha-olefin, and the second polymer is a normally solid thermoplastic polymer having a melting point of less than 185.degree. C. and a shear viscosity that is not more than that of the polyethylene when measured at 200.degree. C. and a shear rate of 400 sec.sup.-1 with the proviso that the second polymer is not a homopolymer or copolymer derived solely from hydrocarbon alpha-olefins having 2-10 carbon atoms. Examples of second polymers are (a) homopolymers and copolymers of unsaturated hydrocarbons in which at least one monomer is other than a C.sub.2 -C.sub.10 alpha-olefin, e.g.
    Type: Grant
    Filed: July 18, 1985
    Date of Patent: July 7, 1987
    Assignee: Du Pont Canada Inc.
    Inventors: Daniel W. Boivin, Ronald A. Zelonka
  • Patent number: 4678602
    Abstract: A resin composition, which is very highly electroconductive, comprises a vinylaromatic copolymer containing an unsaturated dicarboxylic acid anhydride and a metallic filler. It is also improved in mechanical properties.
    Type: Grant
    Filed: May 14, 1984
    Date of Patent: July 7, 1987
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Kazunobu Tanaka, Kyozo Mori
  • Patent number: 4670349
    Abstract: An adhesive resin composition comprising(A) 100 parts by weight of a polymer having a crystallinity, determined by X-ray diffractometry, of not more than 40% selected from the group consisting of an ethylene/vinyl acetate copolymer and ethylene/alpha-olefin random copolymers,(B) 1 to 50 parts by weight of modified polyethylene having a melt flow rate of 0.01 to 50 g/10 minutes and containing 0.01 to 10% by weight of an unsaturated carboxylic acid or its derivative grafted thereto, and(C) 1 to 125 parts by weight of a hydrogenated aromatic petroleum resin in which at least 70% of the romatic ring is hydrogenated;provided that the total amount of the modified polyethylene (B) and the hydrogenated aromatic petroleum resin (C) is not more than 150 parts by weight.
    Type: Grant
    Filed: December 17, 1985
    Date of Patent: June 2, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mikio Nakagawa, Koichiro Sato, Kuniaki Kanemoto, Akito Nishimura
  • Patent number: 4663390
    Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.
    Type: Grant
    Filed: April 1, 1985
    Date of Patent: May 5, 1987
    Assignee: Atlantic Richfield Company
    Inventor: Barry D. Dean
  • Patent number: 4663389
    Abstract: Molding compositions are prepared from blends of (A) a styrene-maleic anhydride-methyl methacrylate terpolymer which contains a rubber component; (B) an ABS or MBS polymer; and (C) a polycarbonate.
    Type: Grant
    Filed: November 1, 1985
    Date of Patent: May 5, 1987
    Assignee: Monsanto Company
    Inventors: William J. Jones, Robert A. Mendelson
  • Patent number: 4661560
    Abstract: Thermoplastic molding compositions are disclosed which comprise an intimate admixture of (a) a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride, including rubber-modified copolymers thereof, and (b) impact modifiers comprising graft copolymers, copolyesters, and rubber-modified homopolymers. Optionally, the compositions can also include a polyphenylene ether resin and further, optionally, a normally liquid polybutadiene oligomer. Mixing (a) with a polyphenylene ether leads to a compatible composition, markedly improved in heat deflection temperature.
    Type: Grant
    Filed: September 21, 1984
    Date of Patent: April 28, 1987
    Assignee: General Electric Company
    Inventors: Visvaldis Abolins, John C. Goossens, Fred F. Holub, Gim F. Lee, Jr.
  • Patent number: 4661561
    Abstract: Thermoplastic molding compositions are disclosed which comprise an intimate admixture of (a) a copolymer of a vinyl aromatic compound and an .alpha., .beta.-unsaturated cyclic anhydride, including rubber-modified copolymers thereof, and (b) impact modifiers comprising graft copolymers, copolyesters, and rubber-modified homopolymers. Optionally, the compositions can also include a polyphenylene ether resin and further, optionally, a normally liquid polybutadiene oligomer. Mixing (a) with a polyphenylene ether leads to a compatible composition, markedly improved in heat deflection temperature.
    Type: Grant
    Filed: September 21, 1984
    Date of Patent: April 28, 1987
    Assignee: General Electric Company
    Inventors: Visvaldis Abolins, John C. Goossens, Fred F. Holub, Gim F. Lee, Jr.
  • Patent number: 4657975
    Abstract: A thermoplastic resin composition having high heat resistance and good impact resistance, which comprises (A) at least one unsaturated dicarboxylic acid anhydride polymer obtainable by polymerizing at least one unsaturated dicarboxylic acid anhydride and at least one aromatic vinyl compound with or without at least one other polymerizable monomer in the presence or absence of a rubbery material and (B) at least one olefin polymer chosen from (B-1) an olefin/alkyl unsaturated carboxylate copolymer, (B-2) an unsaturated carboxylic acid-modified olefin polymer and (B-3) an epoxy group-containing olefin polymer, the weight proportion of the unsaturated dicarboxylic acid anhydride polymer (A) and the olefin polymer (B) being 100:1-100.
    Type: Grant
    Filed: October 16, 1985
    Date of Patent: April 14, 1987
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Mikio Kodama, Akitoshi Ito
  • Patent number: 4654402
    Abstract: Compatibilized polymer blends are described comprising a blend of olefin polymer, cross-linkable acrylic ester copolymer rubber, and a compatibilizing amount of a graft copolymer comprising acrylic ester copolymer compatibilizing segments and olefin polymer compatibilizing segments.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: March 31, 1987
    Assignee: Monsanto Company
    Inventor: Raman Patel
  • Patent number: 4647620
    Abstract: A polyblend which has a high heat distortion temperature and good impact strength, and which may be transparent, is produced by blending 20 to 95 percent by weight of an anhydride polymer of a vinyl aromatic monomer, such as styrene or p-methylstyrene, with an unsaturated dicarboxylic acid anhydride, such as maleic anhydride, with 80 to 5 percent by weight of a methyl methacrylate homopolymer or copolymer, where at least one of the anhydride polymer or the methyl methacrylate polymer are rubber modified. Various other polymers or resins may be added to the blend, such as 10 to 60 weight percent of a vinyl chloride resin, or rubber modified vinyl chloride resin, up to 20 percent of an ungrafted rubber, or up to 40 percent of a graft copolymer of a vinyl aromatic monomer and methyl methacrylate, methacrylonitrile, or acrylonitrile or mixtures, grafted onto 10-60 percent of a substrate rubber.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: March 3, 1987
    Inventor: Kenneth W. Doak
  • Patent number: 4644034
    Abstract: A resin composition is resistant to heat and impact and comprises (a) a polyphenylene ether resin, (b) a rubber graft copolymer resin obtained from a rubbery polymer having a glass transition temperature of 0.degree. C. or lower, an aromatic vinyl monomer and an alpha, beta-unsaturated dicarboxylic anhydride monomer and (c) a block copolymer of an aromatic vinyl monomer and an aliphatic diene monomer. It may contain a mono-olefinic monomer having a nitril or carboxylic ester group as the rubber graft copolymer resin.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: February 17, 1987
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Kazunobu Tanaka, Michio Kobayashi
  • Patent number: 4642325
    Abstract: A cathode-depositing electrodeposition coating composition having excellent low-temperature curability comprising as essential ingredients(A) 100 parts by weight of a reaction product of (1) a high molecular compound having a molecular weight of 500 to 5,000 and containing carbon-carbon double bonds with an iodine number of 50 to 500 and 3 to 12% by weight of oxirane oxygen, and (2) 30 to 300 millimoles, per 100 g of the high molecular compound (1), of a specified amine compound,(B) 10 to 200 parts by weight of a reaction product of a specified diglycidyl compound with 1.9 to 2.1 moles, per molecule of the diglycidyl compound, of an alpha, beta-unsaturated carboxylic acid or an unsaturated fatty acid having a molecular weight of 100 to 350 and containing at least 10% by weight of a carbon-carbon double bond, or a mixture of both,(C) 0.
    Type: Grant
    Filed: April 5, 1985
    Date of Patent: February 10, 1987
    Assignee: Nippon Oil Company, Ltd.
    Inventors: Yutaka Otsuki, Hiroyoshi Omika, Akio Oshima, Yoshihiko Araki, Yasuyuki Tsuchiya
  • Patent number: 4640788
    Abstract: Lubricants of improved properties contain ethylene-propylene copolymers bearing graft units derived from, as a functional monomer, the reaction product of (i) an unsaturated aldehyde or ketone and (ii) a primary or secondary amine which contains at least one nitrogen atom in a heterocyclic ring.
    Type: Grant
    Filed: April 29, 1985
    Date of Patent: February 3, 1987
    Assignee: Texaco Inc.
    Inventors: Maria M. Kapuscinski, Christopher S. Liu, William P. Hart, Larry D. Grina
  • Patent number: 4639473
    Abstract: Thermoplastic, high-impact moulding compositions of (A) 5 to 80 parts by weight of a graft product of 70 to 30% by weight of a mixture of an aromatic vinyl compound and acrylonitrile and/or methacrylonitrile on 30 to 70% by weight of a rubber having a glass transition temperature of below -10.degree. as the graft base and (B) 20 to 95 parts by weight of a terpolymer of styrene and/or .alpha.-methylstyrene, p-methylstyrene and acrylonitrile and/or methacrylonitrile, the terpolymer having been produced by mass polymerization.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: January 27, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank Wingler, Otto Koch, Joachim Doering, Karl-Heinz Ott, Lothar Liebig
  • Patent number: 4632959
    Abstract: A modified polyolefin composition comprising(A) 50 to 99 parts by weight of a modified polyolefin having an intrinsic viscosity [.eta.] of 0.5 to 10 dl/g and a degree of crystallization of at least 20% selected from the group consisting of polyolefins modified with styrene-type hydrocarbons, polyolefins modified with unsaturated epoxy compounds, polyolefins modified with unsaturated silane compounds, halogenated polyolefins and hydroxyl group-containing polyolefins, and(B) 1 to 50 parts by weight of a thermoplastic polymer selected from the group consisting of(B-1) thermoplastic polymers having a flexural modulus of less than 1000 kg/cm.sup.2, a glass transition temperature (Tg) of not higher than 0.degree. C. and a weight average molecular weight (Mw) of at least 400,000, and(B-2) polar non-olefinic thermoplastic polymers or ethylenic polymers having a flexural modulus of at least 1000 kg/cm.sup.2 and an adhesion strength, with respect to the modified polyolefin (A), of not more than 200 g/cm.
    Type: Grant
    Filed: September 19, 1984
    Date of Patent: December 30, 1986
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Riichiro Nagano
  • Patent number: 4629760
    Abstract: A composition comprisinga. a major amount of an aromatic polycarbonate;b. a minor quantity of a polyester selected from polyalkylene terephthalate and polycycloalkylene terephthalate, isophthalate or a mixture of the two acids;c. a minor quantity of an elastomeric acrylate copolymer with a second order transition temperature, Tg, of less than -10.degree. C. and phenoxy resin effective to significantly maintain the impact strength and ductility at break after exposing a stressed part to brake fluid comprising alcohols and ethers.
    Type: Grant
    Filed: November 1, 1985
    Date of Patent: December 16, 1986
    Assignee: General Electric Company
    Inventors: Ping Y. Liu, Harold F. Giles, Jr.
  • Patent number: 4624869
    Abstract: In high solids alkyd resin coatings the blend of 10 to 50 weight percent of unsaturated polyester or unsaturated polyester urethane cure modifiers improves the cure, hardness, gloss and film properties of alkyd and acrylic resins adapted to cure by oxidative methods.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: November 25, 1986
    Assignee: SCM Corporation
    Inventor: Henry J. De Graaf
  • Patent number: 4612155
    Abstract: A continuous process for the grafting of ethylenically unsaturated monomers onto homopolymers of ethylene and copolymers of ethylene and C.sub.4 -C.sub.10 higher alpha-olefins is disclosed. The process involves feeding to an extruder an admixture comprising (i) a major portion of the above polymer of ethylene, (ii) the monomer, (iii) 25-500 ppm of an organic peroxide and (iv) a minor portion of a normally solid thermoplastic polymer having a melting point of less than 185.degree. C. and a shear viscosity at 200.degree. C. and a shear rate of 400 sec.sup.-1 that is not more than 50% of that of the polymer of ethylene. The organic peroxide is in the form of a composition with the thermoplastic polymer. The admixture is mixed in a first zone at a temperature above the melting point of the polymers for at least ten seconds but for less than 25% decomposition of the peroxide and then in a second zone for a period that is at least four times the half-life of the peroxide.
    Type: Grant
    Filed: July 18, 1985
    Date of Patent: September 16, 1986
    Assignee: Du Pont Canada Inc.
    Inventors: Chun S. Wong, Ronald A. Zelonka
  • Patent number: 4609706
    Abstract: High solids alkyd resin coatings are prepared by reacting at least a portion of the available hydroxyl groups on a resin with an ethylenically unsaturated monoisocyanate monomer. The new products, useful both as the major vehicle resin in high solids coatings and as a cure modifier for oxidatively curable alkyd, polyester and acrylic resins, impart improved drying and weathering properties to coatings while maintaining low paint viscosity.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: September 2, 1986
    Assignee: SCM Corporation
    Inventors: Daniel Bode, Henry J. DeGraaf
  • Patent number: 4609701
    Abstract: Blends of (a) a vinyl chloride polymer having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25.degree. C. falling within the range of about 1.50 to about 1.85; (b) a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride in which the relative proportions of said compound and said anhydride fall within the range of about 91 to about 70 weight percent of said compound and about 9 to about 30 weight percent of said anhydride; and (c) a tin-containing stabilizer and an impact modifier for vinyl chloride polymers. These blends contain 60 to 40 weight percent of (a) and 40 to 60 weight percent of (b) and have an Izod impact strength (ASTM D 256, Method A) of at least 0.5 foot pound per inch; a heat deflection temperature (ASTM D 648) at 66 psi of at least 75.degree. C.; and a dynamic thermal stability of at least 10 minutes.
    Type: Grant
    Filed: February 4, 1985
    Date of Patent: September 2, 1986
    Assignee: Ethyl Corporation
    Inventors: Jesse D. Jones, Edwin D. Hornbaker
  • Patent number: 4608414
    Abstract: A thermoplastic resin composition comprising:(A) from 10 to 90 parts by weight of an imide-modified polymer having an imido group and obtained by reacting ammonia and/or a primary amine to a copolymer prepared by the polymerization of a monomer mixture comprising from 50 to 70% by weight of an aromatic vinyl monomer and from 30 to 50% by weight of an unsaturated dicarboxylic acid anhydride;(B) from 10 to 90 parts by weight of a graft copolymer prepared by copolymerizing from 30 to 75% by weight of a mixture comprising from 40 to 80% by weight of a rubber-like polymer having a weight average particle size of from 0.3 to 0.6 .mu.m and from 20 to 60% by weight of a rubber-like polymer having a weight average particle size of from 0.1 to 0.2 .mu.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: August 26, 1986
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tomoyuki Kitsunai, Tetsuji Miura, Norio Yagi
  • Patent number: 4605720
    Abstract: Crosslinked, preferably acrylic, preferably melamine crosslinked, polymer particles formed by reactions comprising free radical addition polymerization of:(a) between about 0.5 and about 20 weight percent each of first and second monomers, each bearing functionality capable of crosslinking reaction with the other, wherein (i) either both additionally are ethylenically unsaturated monomers or (ii) the first monomer additionally is ethylenically unsaturated and the second monomer bears multiple crosslinking functionality and no ethylenic unsaturation; and(b) between about 60 and about 99 weight percent of at least one other monoethylenically unsaturated monomer;in the presence of (I) an organic liquid which is a solvent for the polymerizable monomers, but a non-solvent for the resultant polymer, and (II) polymeric dispersion stabilizer bearing one long chain non-polar hydrocarbon molecule and one vinyl unsaturation.
    Type: Grant
    Filed: February 23, 1983
    Date of Patent: August 12, 1986
    Assignee: Ford Motor Company
    Inventors: Mohinder S. Chattha, Joseph C. Cassatta
  • Patent number: 4602056
    Abstract: The invention relates to the use of grafted ethylene-vinylacetate copolymers (EVA-copolymers) for the production of hotmelt adhesives.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: July 22, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Waniczek, Gerhard Hohmann, Herbert Bartl, Ludwig Mott
  • Patent number: 4600747
    Abstract: ABS-moulding compositions consisting of a thermoplastic copolymer and a graft polymer with rubber-like graft base exhibit an improved flame resistance if the total mixture contains a compound corresponding to the formulae ##STR1## polymerized into one or both components, wherein R.sub.1 represents C.sub.2 -C.sub.6 -alkylene,R.sub.2 represents hydrogen or methyl,R.sub.3 represents a direct bond or C.sub.1 -C.sub.4 -alkylene, andR.sub.4 represents hydrogen, methyl or CH.sub.2 --OOC--CH.sub.2 --CO--CH.sub.3.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: July 15, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Zabrocki, Christian Lindner, Friedmann Muller, Joachim Doring
  • Patent number: 4596851
    Abstract: The present invention relates to thermoplastic moulding compositions containing thermoplastic polycarbonates, graft polymers, rubber-free copolymers and, if appropriate, copolymeric rubbers, and also, if appropriate, conventional additives, which are characterized in that the rubber-free copolymers contain internal epoxide compounds.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: June 24, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Otto Koch, Hans-Jurgen Kress, Horst Peters
  • Patent number: 4592960
    Abstract: A polyolefin product is produced by reacting a polyolefin grafted with a carboxylic acid or anhydride thereof with a polar polymer containing amino groups. The amino groups in the reaction products improves adhesion and compatibility properties.
    Type: Grant
    Filed: April 17, 1985
    Date of Patent: June 3, 1986
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Inoue, Tadashi Sezume, Kazuo Sei
  • Patent number: 4569969
    Abstract: Molding compositions are prepared from blends of (A) a styrene-maleic anhydride-methyl methacrylate terpolymer; (B) an ABS or MBS polymer; and (C) a polycarbonate. Component A, the styrene-maleic anhydride-methyl methacrylate terpolymers may optionally contain a rubber component.
    Type: Grant
    Filed: December 10, 1984
    Date of Patent: February 11, 1986
    Assignee: Monsanto Company
    Inventors: William J. Jones, Robert A. Mendelson
  • Patent number: 4569970
    Abstract: The present invention relates toA. Thermoplastic moulding materials based on polydiorganosiloxane/polycarbonate block copolymers and ABS polymers andB. Thermoplastic moulding compositions based on polysiloxane/polycarbonate block copolymers, elastomeric polymers and, if appropriate, polyalkylene terephthalate.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: February 11, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Winfried Paul, Hans-Jurgen Kress, Wolfgang Stix, Christian Lindner, Dieter Neuray, Werner Nouvertne
  • Patent number: 4567223
    Abstract: The hot-melt adhesives of the present invention comprise a blend of at least one propylene/C.sub.4 to C.sub.10 higher 1-olefin copolymer having an acid number of at least 5, a tackifying resin, and a high density, low viscosity polyethylene wax having a melt viscosity of about 5 to 50 cp. at 150.degree. C. This hot-melt adhesive has a novel combination of properties including low melt viscosity and fast setting which meet the requirements necessary for use in rapid bonding or closing in low and high temperature applications.
    Type: Grant
    Filed: August 31, 1984
    Date of Patent: January 28, 1986
    Assignee: Eastman Kodak Company
    Inventor: William A. Ames
  • Patent number: 4562230
    Abstract: A modified polyolefin composition useful for producing a shaped article having an excellent bonding property and an enhanced impact resistance comprises a modified olefin polymer material prepared by melting a mixture of an olefin polymer material comprising at least one crystalline ethylene-propylene random copolymer containing from 0.5 to 5% by weight of copolymerized ethylene and having a melt flow index of from 0.2 to 5 with a modifying agent consisting of at least one unsaturated dicarboxylic anhydride and a radical reaction initiator at a temperature of from 170.degree. C. to 270.degree. C. at which the mixture is melted; and a polyolefin rubber having a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 10 to 100 and mixed in an amount of from 5% to 40% based on the sum of the weight of the modified olefin polymer material and the polyolefin rubber with the modified olefin polymer material at a temperature at which the mixture is melted.
    Type: Grant
    Filed: November 10, 1983
    Date of Patent: December 31, 1985
    Assignee: UBE Industries, Ltd.
    Inventors: Osamu Fukui, Yoshihiro Inuizawa, Saburo Hinenoya, Yasufumi Takasaki
  • Patent number: 4562229
    Abstract: A novel thermoplastic polymer composition comprises a blend of a polyolefin graft copolymer, and a copolymer of styrene and maleic anhydride and modifications thereof.
    Type: Grant
    Filed: October 12, 1983
    Date of Patent: December 31, 1985
    Assignee: Occidental Chemical Corporation
    Inventors: Leigh E. Walker, Gautam R. Ranade
  • Patent number: 4558098
    Abstract: There is provided a heat-resistant methacrylic resin composition, which comprises 1 to 99% by weight of a copolymer [I] obtained by copolymerizing methyl methacrylate, an aromatic vinyl compound and maleic anhydride and 99 to 1% by weight of a copolymer [II] obtained by copolymerizing 80 to 100% by weight of methyl methacrylate and 0 to 20% by weight of other copolymerizable ethylenic monomer.The resin composition according to the present invention is excellent in characteristics such as optical characteristics, mechanical properties, weathering resistance and molding processability as well as in productivity.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: December 10, 1985
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kazumasa Kamata, Yoshio Nakai, Yasunori Shimomura
  • Patent number: 4554304
    Abstract: Hot melt adhesives with long open time good bonding to cold metals are made of blends of a maleic anhydride modified copolymer of butene-1 and ethylene, an aliphatic, substantially non-polar resin, a antioxidizing agent and, optionally, microcrystalline wax, a block copolymer and atactic polypropylene.
    Type: Grant
    Filed: May 31, 1984
    Date of Patent: November 19, 1985
    Assignee: Shell Oil Company
    Inventors: David R. Hansen, William H. Korcz
  • Patent number: 4554316
    Abstract: A thermoplastic resin composition affording a delustered shaped article which comprises (A) a rubber-modified copolymer with (B) an epoxy group-containing olefin polymer or an unsaturated carboxylic acid-modified olefin polymer (B').
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: November 19, 1985
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Hajime Sakano, Akitoshi Ito, Motoichi Yano, Yasuhiro Honda, Takayoshi Fujiwara
  • Patent number: 4554315
    Abstract: A thermoplastic blend comprising a C.sub.1 -C.sub.4 (alkylene terephthalate), a polycarbonate resin and a butadiene or an acrylate based graft copolymer was found to be amenable without pre-extrusion drying, to thermoplastic processing upon the admixing therewith an additive amount of a polymeric modifier.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: November 19, 1985
    Assignee: Mobay Chemical Corporation
    Inventors: James Y. J. Chung, Russell P. Carter, Jr., Dieter Neuray
  • Patent number: 4551500
    Abstract: A polyblend which has high heat distortion temperature and high impact strength is produced from 80 to 20 percent by weight of vinyl chloride resins, which comprise 90 to 30 percent by weight of a rubber-modified vinyl chloride resin and 10 to 70 percent by weight of a vinyl chloride resin that is not rubber-modified; and 20 to 80 percent by weight of a polymer of a vinyl aromatic monomer such as styrene, an unsaturated dicarboxylic acid anhydride, such as maleic anhydride, and an optional third monomer such as methyl methacrylate or acrylonitrile, which polymer may be a rubber-modified polymer.
    Type: Grant
    Filed: August 2, 1984
    Date of Patent: November 5, 1985
    Inventor: Kenneth W. Doak
  • Patent number: 4543391
    Abstract: Polyphenylene ether compositions having enhanced commercial value as engineering resin, which are excellent in the appearance characteristics, such as surface gloss and weld part beauty, and stress crack resistance. The present resin composition is composed of a polyether resin (PPE) and a rubber reinforced high impact polystyrene (HIPS), if desired, together with a vinyl aromatic compound resin, wherein the PPE has specific characteristics with respect to the intrinsic viscosity, the eluting amount, and others.
    Type: Grant
    Filed: November 19, 1981
    Date of Patent: September 24, 1985
    Assignee: Asahi-Dow Limited
    Inventors: Isao Kuribayashi, Kunio Fukuda
  • Patent number: 4542179
    Abstract: The addition of styrene-acrylonitrile copolymer to acrylic core-shell thermoplastic elastomers reduces mold shrinkage and improves surface hardness. The compositions are useful as moldable and extrudable rubber goods.
    Type: Grant
    Filed: September 24, 1984
    Date of Patent: September 17, 1985
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: John C. Falk, Leland B. Kliever
  • Patent number: 4533698
    Abstract: A thermoplastic resin composition consists essentially of (A) 100 parts by weight of a rubber-containing styrene type resin and (B) 1 to 45 parts by weight of a polymeric substance selected from the group consisting of a homopolymer of an acrylic acid ester, copolymers of an acrylic acid ester, and a mixture of these polymers, said component (B) having a solubility parameter of from 8.4 to 9.8 (cal/c.c.).sup.1/2, a glass transition temperature of 20.degree. C. or below, a gel content of 70% by weight or below, and relative viscosity of a substance soluble in methylethyl ketone of 20 or below.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: August 6, 1985
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Tetsuro Maeda, Akihiro Okamoto, Yoshimitsu Shimizu, Takashi Nomoto
  • Patent number: 4533700
    Abstract: A hydrocarbon resin consisting essentially of a copolymer of (A) an unsaturated chain hydrocarbon or a cyclic hydrocarbon having a vinylidene group and (B) 9,10-dihydrodicyclopentadiene or its derivative, or a hydrocarbon resin modified by addition reacting an ethylenically unsaturated carboxylic acid or its anhydride, or hydrogen, to the above-mentioned copolymer. The hydrocarbon resin and the modified hydrocarbon resin have a high softening point and a low melt viscosity, and are suitable for use in adhesives and traffic paints.
    Type: Grant
    Filed: January 19, 1984
    Date of Patent: August 6, 1985
    Assignee: Mitsui Petrochemical Industries Ltd.
    Inventors: Kinya Mizui, Masami Takeda, Tadao Iwata
  • Patent number: 4530965
    Abstract: A polymeric molding composition containing a polycarbonate resin, a styrenic copolymer and a methylmethacrylate-butadiene-styrene polymer is disclosed. The molding compositions of this invention exhibit excellent impact strength and can be molded over a wide range of processing conditions.
    Type: Grant
    Filed: February 10, 1984
    Date of Patent: July 23, 1985
    Assignee: Atlantic Richfield Company
    Inventor: Larry G. Bourland
  • Patent number: 4530957
    Abstract: Crosslinked, preferably acrylic, preferably melamine crosslinked, polymer particles formed by reactions comprising free radical addition polymerization of:(a) between about 0.5 and about 20 weight percent each of first and second monomers, each bearing functionally capable of crosslinking reaction with the other and additionally wherein the first monomer is ethylenically unsaturated and the second monomer bears multiple crosslinking functionality and no ethylenic unsaturation,(b) between about 60 and about 99 weight percent of at least one other monoethylenically unsaturated monomer;in the presence of (I) an organic liquid which is a solvent for the polymerizable monomers, but a non-solvent for the resultant polymer, and (II) polymeric dispersion stabilizer wherein the precursor of the first segment of the stabilizer comprises a long chain hydrocarbon molecule having only one reactive group per molecule, preferably being a carboxyl group.
    Type: Grant
    Filed: January 5, 1983
    Date of Patent: July 23, 1985
    Assignee: Ford Motor Company
    Inventors: Ares N. Theodore, Mohinder S. Chattha
  • Patent number: 4528329
    Abstract: A polyolefin product is produced by reacting a polyolefin grafted with a carboxylic acid or an anhydride thereof with a polar polymer containing epoxy groups. The unreacted epoxy groups in the resulting copolymer improves adhesion and compatibility with metals and other resins.
    Type: Grant
    Filed: May 2, 1983
    Date of Patent: July 9, 1985
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Inoue, Tadashi Sezume, Masaaki Isoi, Kunio Iwanami, Kazuo Sei
  • Patent number: 4526927
    Abstract: A thermoplastic molding material contains a styrene polymer, a polyphenylene ether and, as a component for improving the impact strength, a block copolymer obtained by reacting an ethylene copolymer with an active polymeric anion.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: July 2, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Hambrecht, Franz Brandstetter, Walter Ziegler, Wolfgang F. Muller, Klaus Bronstert, Adolf Echte
  • Patent number: 4514543
    Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.
    Type: Grant
    Filed: October 3, 1983
    Date of Patent: April 30, 1985
    Assignee: Atlantic Richfield Company
    Inventor: Barry D. Dean