Core-shell Patents (Class 525/902)
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Patent number: 8501855Abstract: A multi-stage aqueous emulsion polymer, an aqueous coating composition including the emulsion polymer, and a method for providing a coating including the emulsion polymer are provided. The multistage emulsion polymer includes from 10% to 30% by wt., based on the wt. of the multistage emulsion polymer, of a first polymer shell having an acid number of from 5 to 100, the first polymer having a calculated Mn of from 1000 to 4500 and a calculated Tg of lower then 100° C.; and from 70% to 90% by wt., based on the wt. of the multistage emulsion polymer, of a second polymer core having an acid number of from 0 to one-half the acid number of the first polymer, the second polymer having a calculated Mn of greater than 20,000.Type: GrantFiled: April 1, 2011Date of Patent: August 6, 2013Assignee: Rohm and Haas CompanyInventors: Gary W. Dombrowski, William J. Rosano
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Patent number: 8450395Abstract: Disclosed is a resin having excellent impact resistance and color, and a method of preparing the same, and more specifically, a resin having the excellent impact resistance and color, and a method of preparing the same, in which the resin includes (a) an occlusion seed consisting of i) a base seed including 99.95 to 99 wt % of alkyl methacrylate and 0.05 to 1 wt % of crosslinker, and ii) a copolymer of aromatic vinyl compound and alkyl acrylate occluding the base seed; (b) a polymer core surrounding the occlusion seed; and (c) a polymer shell surrounding the core, and according to the present invention, it is effective in providing a resin having superior impact strength, transparency, and color, in which the resin can be used as an excellent impact modifier when applying on a polymethylmethacrylate resin, and a method of preparing the same.Type: GrantFiled: November 10, 2010Date of Patent: May 28, 2013Assignee: LG Chem, Ltd.Inventors: Se Eun Lee, Dong Jo Ryu, Seon Hee Han, Jeong Heon Ahn
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Patent number: 8445559Abstract: A polymeric particle including a core, a first shell, and a second shell is provided: the core including, when dry, at least one void; the first shell polymer having a calculated glass transition temperature (“Tg”) greater than 50° C. and including, as polymerized units, from 15% to 60%, by weight based on the weight of the first shell, monomer selected from the group consisting of acrylonitrile, methacrylonitrile, acrylamide, methacrylamide, and mixtures thereof; and from 0.3% to 10%, by weight based on the weight of the first shell polymer, multiethylenically unsaturated monomer; and the second shell polymer having a Tg of from ?60° C. to 50° C.; wherein the weight ratio of the second shell polymer to the total of all other structures of the polymeric particle is from 0.5:1 to 3:1. The particle provides binding functionality and, when dry, opacity and energy savings. A method for providing a polymeric particle and a method for providing opacity to a dry coating are also provided.Type: GrantFiled: June 24, 2009Date of Patent: May 21, 2013Assignee: Rohm and Haas CompanyInventor: James Keith Bardman
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Patent number: 8415436Abstract: The present invention provides a polymer particle and a method of preparing the same. More precisely, the invention provides a polymer particle having optimum impact strength and improved elastic recovery rate by forming the brush having softness on the surface of the monodisperse polymer particle by the anion dispersion polymerization using a conjugated diene monomer.Type: GrantFiled: November 19, 2007Date of Patent: April 9, 2013Assignee: LG Chem, Ltd.Inventors: Bo-ryeong Han, Moon-seok Chun, Do-yeon Park, Su-kyung Kim, Chong-min Koo, Bum-jae Lee, Choel-han Gang
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Patent number: 8404781Abstract: Butadiene is anionically polymerized (or block copolimerized with styrene) in a low-boiling non-polar solvent in presence of rganolithiura compounds. At the end of the polymerization, the non-polar solvent is switched with styrene and the new solution is stored in tanks in relation to the type of polybutadiene (or its block copolymer with styrene) obtained. The polybutadiene solution (and/or its block copolymer with styrene) with the desired set of properties is then fed to a production plant of high impact vinyl aromatic (co)polymers.Type: GrantFiled: November 28, 2008Date of Patent: March 26, 2013Assignee: Polimeri Europa S.p.A.Inventors: Riccardo Inglese, Leonardo Chiezzi, Fabio Montanari, Alessandro Casalini
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Patent number: 8389633Abstract: Disclosed therein is method for preparing novel suspension polymer comprising tetrafluoroethylene polymer, and powders or granules produced by the method. The suspension polymer of the present invention can be obtained by suspension polymerization of a styrene-based monomer, an acrylic monomer or a mixed monomer thereof in the presence of PTFE, followed by filtering and drying, and can be used as flame retarding properties improver of engineering plastic and the like.Type: GrantFiled: January 20, 2006Date of Patent: March 5, 2013Inventor: Ji-Ho Park
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Patent number: 8383734Abstract: The present invention relates to bone cements and, more particularly, to acrylic-based orthopedic bone cements, their use in spinal applications, and methods for making the same. An embodiment of the present invention provides a method of grafting PMMA brushes on cross-linked PMMA nanospheres comprising at least one of the following steps: performing a hydrolysis reaction of surface methyl ester groups of said cross-linked PMMA nanospheres to form surface carboxylic acid groups of said cross-linked PMMA nanospheres; forming a 2-aminoethyl acrylate compound; coupling said surface carboxylic acid groups of said cross-linked PMMA nanospheres with said 2-aminoethyl acrylate compound to form a coupled compound with an initiating site; and grafting said PMMA brushes onto said initiating site.Type: GrantFiled: April 21, 2010Date of Patent: February 26, 2013Assignee: Syracuse UniversityInventors: Julie M. Hasenwinkel, Jeremy L. Gilbert, Danieli C. Rodrigues, Rebecca Bader
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Patent number: 8383726Abstract: Disclosed is a thermoplastic resin composition having excellent impact resistance at a low temperature, while maintaining high transparency; this thermoplastic resin composition is obtained by compounding an impact resistance improver into a thermoplastic resin, the impact resistance improver being composed of a graft copolymer which is obtained by polymerizing a vinyl monomer component in the presence of a polymer mixture containing a polymer having butadiene units as an essential component and a polymer having styrene units as an essential component, the polymer mixture containing 45 to 65% by mass of the butadiene units and 35 to 55% by mass of the styrene units.Type: GrantFiled: August 29, 2007Date of Patent: February 26, 2013Assignees: Mitsubishi Rayon Co., Ltd., Cheil Industries Inc.Inventors: Osamu Okunaka, Hiroyuki Nishii, Takashi Shouji, Keiji Nakamura, Tae Uk Kim, Byung Choon Lee
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Patent number: 8349961Abstract: A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer comprising a rigid matrix consisting of vinylaromatic polymers or copolymers and of an elastomeric phase dispersed in the matrix in form of particles with a strictly bimodal distribution which comprises the functionalization of a first elastomeric fraction by means of a catalytic system containing a stable free radical initiator and subsequently the polymerization of the thus obtained mixture also in presence of a second non functionalized elastomeric fraction.Type: GrantFiled: December 6, 2005Date of Patent: January 8, 2013Assignee: Polimeri Europa S.p.A.Inventors: Leonardo Chiezzi, Luca Monti, Aldo Longo
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Patent number: 8252867Abstract: The present invention relates to an impact strength modifier for thermoplastic polyester resin and a thermoplastic polyester resin composition containing the same, more precisely an impact strength modifier for thermoplastic polyester resin prepared by graft-polymerization of a) 20-80 weight % of multilayered rubber latex in which the ratio of particle diameter (Pb/Pa) of an inner layer (Pa) to outer layer is 1.05-1.5, and glass transition temperature of the inner layer or the outer layer is up to ?30° C.; and b) 20-80 weight % of vinyl monomer. According to the present invention, a thermoplastic polyester resin composition having excellent transparency and improved impact strength can be provided by containing an impact strength modifier for thermoplastic polyester resin having multilayered structure in which content of rubber latex, glass transition temperature, particle diameter and refraction index are regulated.Type: GrantFiled: December 24, 2008Date of Patent: August 28, 2012Assignee: LG Chem, Ltd.Inventors: Yoon-Ho Kim, Geon-Soo Kim, Sang-Il Nam
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Patent number: 8242205Abstract: A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers, and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.Type: GrantFiled: August 24, 2009Date of Patent: August 14, 2012Assignee: Lubrizol Advanced Materials, Inc.Inventors: Alexander V. Lubnin, Dennis Malaba, Vic Stanislawczyk, Gary D. Calhoun
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Patent number: 8236898Abstract: A melt-mixed composition of non-melt flowable polytetrafluoroethylene (PTFE) and melt-fabricable perfluoropolymer is provided that exhibits thixotropy at increasing shear rate in the molten state and high elongation at break even at PTFE concentrations well above 4 wt %, based on the combined weight of the PTFE and the perfluoropolymer, e.g. at least 200% up to at least 30 wt % PTFE, the composition also exhibiting the structure of a dispersion of submicrometer-size particles of the PTFE in a continuous phase of the melt-fabricable perfluoropolymer.Type: GrantFiled: September 22, 2011Date of Patent: August 7, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Heidi Elizabeth Burch, Sundar Kilnagar Venkataraman, Ralph Munson Aten
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Patent number: 8232347Abstract: A high-quality oxygen-absorbing resin composition which is obtained without suffering resin scorching. Also provided are pellets for the oxygen-absorbing resin composition which comprise a thermoplastic resin (A) and an oxidation catalyst. After the pellets are mixed with a trigger resin and a thermoplastic resin (C), the trigger resin functions as a trigger to cause the oxidation of the thermoplastic resins (A) and (C) to proceed. As a result, the resultant composition absorbs oxygen.Type: GrantFiled: February 5, 2010Date of Patent: July 31, 2012Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Takayuki Ishihara, Hiroaki Goto, Yoshihiro Ohta, Yuji Yamaguchi, Go Saito
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Patent number: 8133943Abstract: Disclosed is a polylactic acid/polycarbonate resin composition including (A) about 100 parts by weight of a mixed resin including: (a1)) about 10 to about 90 wt % of a polycarbonate resin and (a2) about 10 to about 90 wt % of a polylactic acid resin; (B) about 1 to about 50 parts by weight of a flame retardant based on about 100 parts by weight of the mixed resin; (C) about 1 to about 30 parts by weight of an acryl-based copolymer based on about 100 parts by weight of the mixed resin; and (D) about 1 to about 20 parts by weight of an impact-reinforcing agent based on about 100 parts by weight of the mixed resin.Type: GrantFiled: November 18, 2009Date of Patent: March 13, 2012Assignee: Cheil Industries Inc.Inventors: Jin-Kyung Cho, Hyung-Tak Lee, Doo-Han Ha, Chang-Do Jung
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Patent number: 8067482Abstract: A process for the preparation of plastic molded articles which can be used in the dental field, the process including the steps of: mixing A) at least one polymerizable component and B) at least one initiator in desensitized form to form a paste having a consistency does not demix during injection; injecting the paste into a cuvette; and polymerizing the mixture by applying heat.Type: GrantFiled: March 2, 2007Date of Patent: November 29, 2011Assignee: Ivoclar Vivadent AGInventors: Volker Rheinberger, Wolfgang Wachter, Gottfried Rohner
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Patent number: 8039557Abstract: A process for the preparation of vinylaromatic (co)polymers grafted on an elastomer in a controlled way, comprising the dissolving of an elastomer, such as polibutadiene, in a mixture consisting of a monomer and of a solvent in the presence of a polymerization catalytic system, which comprises an initiator of free radicals and a stable initiator of free radicals. The mixture obtained in this way is heated to a temperature of about 100° C. to functionalize the rubber, then more monomer is added and the temperature is raised to start the polymerization reaction.Type: GrantFiled: March 7, 2005Date of Patent: October 18, 2011Assignee: Polimeri Europa S.p.A.Inventors: Aldo Longo, Leonardo Chiezzi
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Patent number: 8017695Abstract: This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.Type: GrantFiled: December 27, 2007Date of Patent: September 13, 2011Inventors: Steven Luo, Junko Kurazumi, Yoichi Ozawa, Timothy L. Tartamella, Mark Smale, Kevin McCauley
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Patent number: 8013063Abstract: The present invention relates to acryl-silicone hybrid impact modifiers, the method of their manufacture, and vinyl chloride resin compositions containing the above. The acryl-silicone hybrid impact modifier of the present invention contains a seed obtained through emulsion copolymerization of vinyl monomers and hydrophilic monomers; an acryl-silicone hybrid rubber core covering the seed in which a polyorganosiloxane rubber phase is dispersed locally onto the inner part and surface of the acrylic rubber core containing alkyl acrylate polymers and a shell covering the above rubber core and containing alkyl methacrylate polymers. Thermoplastic resins containing the above, particularly by being added to vinyl chloride resins, they have effects of granting superior impact resistance, weatherability, and high gloss.Type: GrantFiled: May 13, 2004Date of Patent: September 6, 2011Assignee: LG Chem, Ltd.Inventors: Kwang-jin Lee, Jeong-heon Ahn, Hye-kyong Lee
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Patent number: 8008397Abstract: Provided are a rubber latex having a multi-layer structure, wherein an inner-layer rubber latex has a refractive index greater than that of an outer-layer rubber latex, a graft copolymer prepared from the rubber latex, a polyvinyl chloride (PVC) resin blend containing the graft copolymer, and a method of preparing the rubber latex. The PVC resin blend containing the graft copolymer including the rubber latex according to the present invention has improved color property and low-temperature impact strength than conventional PVC resins.Type: GrantFiled: August 8, 2006Date of Patent: August 30, 2011Assignee: LG Chem, Ltd.Inventors: Yoon Ho Kim, Wonsuk Jang, Geon Soo Kim
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Patent number: 7960479Abstract: A copolymer of formula 1 in which M1 is a unit obtainable from ring opening metathesis polymerization (ROMP); R is an alkyl, ether, ester or aryl unit; M2 and M3 are independently selected from units obtainable by reversible addition fragmentation chain transfer polymerization (RAFT); X is a terminal unit selected from the group consisting of dithioester, trithiocarbonate, xanthate; and m is an integer from 2 to 1 million, n is an integer from 2 to 500,000 and k is an integer from 2 to 500,000.Type: GrantFiled: November 2, 2007Date of Patent: June 14, 2011Assignee: Conopco, Inc.Inventors: Chong Cheng, Ezat Khoshdel, Karen Lynn Wooley
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Patent number: 7956105Abstract: Disclosed is a silicone impact modifier with a high refractive index. The silicone impact modifier can include (A) a rubber core including (a1) an organosiloxane cross-linked (co)polymer with a particle size of about 50 to about 400 nm and (a2) an alkylacrylate-styrenic aromatic compound cross-linked copolymer; and (B) a plastic shell including a vinyl (co)polymer. The refractive index of the silicone impact modifier of the present invention can be about 1.49 to about 1.59.Type: GrantFiled: June 27, 2007Date of Patent: June 7, 2011Assignee: Cheil Industries Inc.Inventors: Han Su Lee, Sung Sig Min, Byung Choon Lee, Byeong Do Lee
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Patent number: 7956127Abstract: Disclosed herein are a polycarbonate resin composition and a plastic article produced from the resin composition. The polycarbonate resin composition includes about 85 to about 99 parts by weight of a polycarbonate resin and about 1 to about 15 parts by weight of a core-shell graft copolymer, wherein the core-shell graft copolymer has a core-shell structure in which a vinyl monomer including methyl methacrylate and phenyl methacrylate is grafted onto a rubber.Type: GrantFiled: December 18, 2007Date of Patent: June 7, 2011Assignee: Cheil Industries Inc.Inventors: Byung Choon Lee, Tae Uk Kim
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Patent number: 7943704Abstract: The present invention provides a process for preparing emulsion polymer particles of a hollow core/shell structure in the presence of a monomer plasticizer having a ceiling temperature less than 181° C. wherein a polymerization inhibitor or reducing agent is not added to the aqueous emulsion of the core shell particles during the neutralization and swelling stage. The obtained core shell particles are useful in paints, paper coatings, foams, and cosmetics.Type: GrantFiled: July 10, 2006Date of Patent: May 17, 2011Assignee: BASF AktiengesellschaftInventors: Konrad Roschmann, Arno Tuchbreiter, Ekkehard Jahns, Joerg Leuninger, Bernhard Schuler, Oliver Wagner, Michaela Reinsch, Robert Wrazidlo
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Patent number: 7875684Abstract: The invention discloses thermosetting water-based paint comprising water-dispersible acrylic polymer particles which are obtained through multi-stage emulsion polymerization of radical polymerizable unsaturated monomers using a specific reactive emulsifying agent, said monomers comprising amido-containing radical polymerizable unsaturated monomer having at least 2 radical polymerizable unsaturated groups per molecule, methacrylic acid and hydroxyl-containing radical polymerizable unsaturated monomer; and coating film-forming methods which use the thermosetting water-based paint.Type: GrantFiled: December 20, 2005Date of Patent: January 25, 2011Assignee: Kansai Paint Co., Ltd.Inventors: Noritoshi Nakane, Yoshiyuki Yukawa
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Patent number: 7868098Abstract: The invention relates to a process for preparing (meth)acrylate-based ABA triblock copolymers with an olefinic functionalization of the A blocks.Type: GrantFiled: August 30, 2006Date of Patent: January 11, 2011Assignee: Evonik Roehm GmbHInventors: Gerd Loehden, Sven Balk, Monika Maerz, Christine Troemer
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Patent number: 7868063Abstract: Disclosed is a powdered polymeric lubricant having a multi-layer structure as a processing aid capable of being used to improve processability of a vinyl chloride resin, and a manufacturing method thereof. The powdered polymeric lubricant having multi-layer structure according to the present invention has an excellent ability to prevent its adhesion to a metal surface upon its processing so as to give a long-term workability to extrusion, calendaring, blow molding, injection molding, etc., when a small amount of the powder of the present invention is mixed with a vinyl chloride resin. Accordingly, the present invention provides a powdered polymeric lubricant capable of controlling compatibility with the vinyl chloride resin and minimizing the adhesive property to a metal surface of a processing machine when a vinyl chloride resin is processed with a polymer including a silicone-based polymer.Type: GrantFiled: June 2, 2006Date of Patent: January 11, 2011Assignee: LG Chem, Ltd.Inventors: Hyung-jun Son, Jeong-heon Ahn, Yong-hun Lee, Jung-sup Han
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Patent number: 7855257Abstract: A novel copolymer, graft copolymer, copolymer particles, flame retardant, and resin composition are provided. A copolymer including a polymer (A) segment having a glass transition temperature not more than ?10° C., and a polymer (C) segment having at least a unit derived from a monomer (B) which has two or more of aromatic rings and one or more radical reactive groups in one molecule; a graft copolymer having the component (B) grafted onto the component (A); and copolymer particles thereof are obtained. A flame retardant resin composition is obtained by using the copolymer as a flame retardant and blending the flame retardant with the resin.Type: GrantFiled: May 9, 2005Date of Patent: December 21, 2010Assignee: Kaneka CorporationInventor: Kazunori Saegusa
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Patent number: 7847027Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.Type: GrantFiled: December 29, 2006Date of Patent: December 7, 2010Assignee: Eastman Kodak CompanyInventors: Peter J. Ghyzel, Joseph F. Bringley, David J. Giacherio, Lawrence P. DeMejo, Terry C. Schultz, Todd Emrick
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Patent number: 7838112Abstract: This invention discloses a process for synthesizing a modified crosslinked elastomeric particle which comprises a two-step polymerization of a conjugated diolefin monomer and a vinyl aromatic monomer by emulsion polymerization, wherein the particle is synthesized by the steps of (1) polymerizing a conjugated diolefin monomer, alone or in combination with a vinyl aromatic monomer, and optionally a crosslinking monomer, to create a crosslinked elastomeric core having residual double bonds and an outer surface; (2) polymerizing a monomer of a vinyl aromatic monomer, alone or in combination with a diolefin monomer, to create a polymeric shell, wherein the polymeric shell is grafted to the outer surface of the polymeric core by reacting with the residual double bonds of the polymeric core; and (3) coagulating the core-shell emulsion latex solution to recover the particles.Type: GrantFiled: November 30, 2004Date of Patent: November 23, 2010Assignee: The Goodyear Tire & Rubber CompanyInventors: Eric Sean Castner, Lei Zheng, Feng Anne Xie, Ping Zhang
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Patent number: 7834086Abstract: This invention relates to coating compositions that include water; a latex polymer and a silane coupling agent. The latex polymer preferably comprises acetoacetoxy functionality, or is a multistage latex, or is an acetoacetoxy functional multistage latex. The silane coupling agent is preferably a functionalized silane coupling agent (more preferably an epoxy-functional silane coupling agent). The compositions may be used to coat a variety of substrates, including wood, cement and fiber cement. Articles having the coating applied thereto are also provided.Type: GrantFiled: June 4, 2007Date of Patent: November 16, 2010Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, Michael C. Wildman, Bruce A. Johnson, Carl H Weber
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Patent number: 7812090Abstract: Coating compositions for cementitious substrates may be made from a silane-functional multistage latex polymer. The compositions adhere well to cementitious substrates and resist crush damage such as may be caused by stacking coated substrate boards.Type: GrantFiled: August 15, 2008Date of Patent: October 12, 2010Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, Michael C. Wildman, Bruce A. Johnson, Carl H. Weber
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Patent number: 7807751Abstract: A core-shell particle is formed by a method that includes forming a crosslinked polyorganosiloxane core, reacting a graftlinking agent with the crosslinked polyorganosiloxane core, and polymerizing a poly(alkenyl aromatic) shell around the graftlinking agent-functionalized polyorganosiloxane core. The method produces a core-shell particle with improved adhesion between shell and core. The core-shell particle is useful as an impact modifier in thermoplastic compositions.Type: GrantFiled: November 7, 2008Date of Patent: October 5, 2010Assignee: Sabic Innovative Plastics IP B.V.Inventors: Amol Adhikrao Mohite, Sathya Narayanan Muthukrishnan, Abhijit Som
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Patent number: 7776237Abstract: Process for improving the brilliance of color and the stability of a colored polymer system, which is composed of a matrix and of discrete polymer particles distributed in accordance with a defined spatial lattice structure in the matrix, and which is obtained by filming of an emulsion polymer with core/shell structure, which comprises using an emulsion polymer obtainable by polymerizing monomers in at least one first stage (core monomers), then polymerizing monomers in at least one further, second stage (transition stage), and finally polymerizing monomers in a third stage (shell monomers), where, based on the percentage constitution of the monomer mixtures of the three stages, at most 30% by weight of the monomers of the first stage are identical with those of the third stage, and 5% of the monomers of the second stage are identical with, respectively, those of the first and those of the third stage, and not more than 60% by weight of the monomers of the 2nd stage here are monomers absent in the 1st staType: GrantFiled: May 4, 2004Date of Patent: August 17, 2010Assignee: BASF AktiengesellschaftInventors: Xu He, Reinhold J. Leyrer, Holger Schöpke
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Patent number: 7745536Abstract: The present invention relates to an acryl-silicon rubber complex polymer which has a seed-core-shell structure wherein vinyl monomer and hydrophilic monomer are cross-linked on the seed; the acryl-silicon complex IPN core having an IPN (interpenetrating network) structure formed by radical polymerization of acryl monomer and hydrosilyation of silicon rubber in which silicon rubber particles are dispersed by being cross-linked to acryl rubber, in a continuous phase, is formed on the seed; and a shell prepared by graft-polymerization of C1-C4 alkyl methacrylate to the acryl-silicon complex IPN core is formed on the core, and a method of preparation and use of the same, thereby having excellent impact resistance, weatherability and gloss, so that it can be effectively used as an impact modifier for vinyl chloride resin.Type: GrantFiled: October 13, 2006Date of Patent: June 29, 2010Assignee: LG Chem, Ltd.Inventors: Kwang-jin Lee, Jeong-heon Ahn, Hye-kyong Lee, Boo-ho Seo, Ji-min Lee
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Patent number: 7732051Abstract: A method for producing magnetic particles includes forming a hydrophobic first polymer layer on the surface of a mother particle containing superparamagnetic particles, forming a second polymer layer having glycidyl groups at least on its surface on the first polymer layer, and introducing a polar group containing one or more of at least one atom selected from the group consisting of an oxygen atom, a nitrogen atom, and a sulfur atom by chemically modifying the glycidyl groups.Type: GrantFiled: July 2, 2007Date of Patent: June 8, 2010Assignee: JSR CorporationInventors: Kouji Tamori, Eiji Takamoto, Masaru Ueno, Tetsuo Fukuta, Tomohiro Uetsuhara, Mitsuhiro Murata
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Patent number: 7645511Abstract: This invention discloses a process for synthesizing a modified crosslinked elastomeric particle which comprises a two-step polymerization of a conjugated diolefin monomer and a vinyl aromatic monomer by emulsion polymerization, wherein the particle is synthesized by the steps of (1) polymerizing a conjugated diolefin monomer, alone or in combination with a vinyl aromatic monomer, and optionally a crosslinking monomer, to create a crosslinked elastomeric core having residual double bonds and an outer surface; (2) polymerizing a monomer of a vinyl aromatic monomer, alone or in combination with a diolefin monomer, to create a polymeric shell, wherein the polymeric shell is grafted to the outer surface of the polymeric core by reacting with the residual double bonds of the polymeric core; and (3) coagulating the core-shell emulsion latex solution to recover the particles.Type: GrantFiled: March 28, 2006Date of Patent: January 12, 2010Assignee: The Goodyear Tire & Rubber CompanyInventors: Eric Sean Castner, Lei Zheng, Feng Anne Xie, Ping Zhang
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Patent number: 7638561Abstract: An aqueous inkjet ink composition suitable for printing on a hydrophobic surface such as a vinyl surface including an aqueous vehicle, a self-dispersed pigment, a silicone-containing surfactant and an aqueous emulsion polymer having a glass transition temperature (Tg) of from ?40° C. to 150° C. Also provided is a method for printing an image on a hydrophobic substrate.Type: GrantFiled: June 8, 2005Date of Patent: December 29, 2009Assignee: Rohm and Haas CompanyInventors: Zhenwen Fu, Hailan Guo, Michael Hallden-Abberton, Himal H. Ray
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Patent number: 7605193Abstract: The invention describes a novel impact modifier, built up from core-shell1- and shell 2, the core being capable of plastic deformation. Good mechanical properties were achieved using a small amount of impact modifier.Type: GrantFiled: November 22, 2006Date of Patent: October 20, 2009Assignee: Roehm GmbH & Co. KGInventors: Klaus Schultes, Thomas Suefke, Reiner Mueller, Thomas Arndt, Goerg Michler, Joachim Laatsch
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Patent number: 7582698Abstract: A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers; and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.Type: GrantFiled: December 11, 2003Date of Patent: September 1, 2009Assignee: Lubrizol Advanced Materials, Inc.Inventors: Alexander V. Lubnin, Dennis Malaba, Vic Stanislawczyk, Gary D. Calhoun
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Patent number: 7579406Abstract: The present invention relates to a transparent thermoplastic resin composition which characteristically contains A) 20-80 weight % of graft copolymer composed of a) conjugated diene rubber latex; b) intermediate layer prepared by copolymerization of acrylic acid alkylester derivative and aromatic vinyl derivative with the above a); and c) graft layer prepared by copolymerization of methacrylic acid alkylester derivative or acrylic acid alkylester derivative, a romatic vinyl derivative and vinyl cyan derivative with the above b) and B) 20-80 weight % of MSAN copolymer prepared by copolymerization of methacrylic acid alkylester derivative or acrylic acid alkylester derivative, aromatic vinyl derivative and vinyl cyan derivative.Type: GrantFiled: August 18, 2005Date of Patent: August 25, 2009Assignee: LG Chem, Ltd.Inventors: Jeong-su Choi, Mi-young Lee, Hyong-min Bahn, Keun-hoon Yoo, Won-seok Lee
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Patent number: 7560520Abstract: Methods and systems for modifying a polymer are disclosed herein. A matrix is generally provided having a surface thereof, wherein the matrix comprises a plurality of hyperbranched polymers. The plurality of hyperbranched polymers can be chemically bound to a plurality of surfactants or order to modify the surface and produce a polymeric material thereof. The surface is tailored with a plurality of functional groups that self-assemble and are deliverable to the surface of the solution, including interfaces thereof, thereby permitting a high-density assembly of functional groups to operate in concert with one another in order to generate a modified surface thereof. The polymeric material produced thereof can be reversibly adaptable to environmental conditions through a blooming of varying surface functional group to the surface of the solution.Type: GrantFiled: November 7, 2005Date of Patent: July 14, 2009Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Joshua A. Orlicki, Robert E. Jensen, Matthew S. Bratcher, Steven H. McKnight
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Patent number: 7435783Abstract: An aqueous polymer emulsion comprising water and swollen multi-stage polymer is provided. The swollen multi-stage polymer has low dry bulk density, as measured by centrifugation. To achieve the low dry bulk density, the polymer is highly swollen in such a way that it does not subsequently collapse. The polymer is useful in paint and paper coatings.Type: GrantFiled: November 8, 2004Date of Patent: October 14, 2008Assignee: Rohm and Haas CompanyInventors: Robert Mitchell Blankenship, James Keith Bardman
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Patent number: 7422879Abstract: Porous films are provided which include a blend of a film forming polymer and a non-film forming material, the film having a network of pores or channels throughout the film. The porous polymer films are formed between 0° and 80° C., retain porosity at elevated temperatures and are non-friable. A process for preparing porous polymer films and their applications are disclosed.Type: GrantFiled: April 27, 2004Date of Patent: September 9, 2008Assignee: Rohm and Haas CompanyInventors: Matthew S. Gebhard, Patricia M. Lesko, Albert B. Brown, David H. Young
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Patent number: 7420016Abstract: In order, in the case of a moulding composition for the production of sanitary-ware components, comprising a methyl-methacrylate-based syrup and from 50 to 85%, expressed in terms of the moulding composition, of an inorganic filler, to obtain an improvement in the scratch-proofness and the abrasion resistance of the shaped components which are obtained therefrom, it is proposed that the composition furthermore comprise elastomer particles or elastomer particle aggregates having a particle size <100 ?m in an amount in the range of 5% by weight to <20% by weight, expressed in terms of the mass of the syrup.Type: GrantFiled: August 11, 2006Date of Patent: September 2, 2008Assignee: BLANCO GmbH + Co KGInventors: Andreas Hajek, Thomas Heck, Stefan Harke, Thomas Wilhelm
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Patent number: 7411020Abstract: In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.Type: GrantFiled: December 28, 2004Date of Patent: August 12, 2008Assignee: 3M Innovative Properties CompanyInventors: James G. Carlson, John C. Clark, James P. DiZio, David J. Kinning, Ramesh C. Kumar, Chetan P. Jariwala
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Patent number: 7402613Abstract: A water-based ink for ink-jet printing, comprising colored particles containing: (a) a core particle having a colorant; and (b) a shell having a resin and encapsulating the core particle, wherein the resin comprises a monomer unit having a hydroxyl group in an amount of 0.1 to 50 weight % based on the total weight of the shell.Type: GrantFiled: September 6, 2002Date of Patent: July 22, 2008Assignee: Konica CorporationInventors: Hidetaka Ninomiya, Hiroaki Ando
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Publication number: 20070282034Abstract: A core-shell particle including a core with poly(arylene ether) and a shell with an ethylenically unsaturated copolymer is described. Also described are a method of forming the particle, a composition including the particle, and an article including such a composition.Type: ApplicationFiled: May 30, 2006Publication date: December 6, 2007Inventors: Ben Patel, Brennan Smith, Norberto Silvi, Gary William Yeager, Vijay Gopalaktishnan
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Patent number: 7235600Abstract: The present invention concerns a waterborne copolymer dispersion comprising at least one alkenyl functional dendritic polymer being copolymerized to the polymer backbone of at least one homo or copolymer obtainable by polymerization, such as emulsion polymerization, in an aqueous medium of at least one at least one polymerizable allyl, vinyl, maleic or diene monomer. The dendritic polymer is built up from a dendritic core polymer and at least one alkenyl functional compound bonded to the core polymer. In a further aspect the present invention concerns the use of said copolymer dispersion.Type: GrantFiled: August 13, 2003Date of Patent: June 26, 2007Assignee: Celanese Emulsion Norden ABInventors: Jan-Erik Jonsson, Ola Karlsson
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Patent number: 7217747Abstract: The plastics additives powder compositions of the present invention are provided as powder particles having impact modifier particles and processing aid particles which are coagulated and dried. When blended in thermoplastic resins, such as PVC, the subject plastics additives powders both increase the impact strength and improve process efficiency and melt strength. The impact and processing properties achieved by the present invention are more efficient than using separate impact modifier and processing aid powders. The method of preparing the powder compositions of the present invention also enable impact modifier particles having rubber weight fractions greater than 88% to be isolated as free-flowing powders.Type: GrantFiled: July 24, 2003Date of Patent: May 15, 2007Assignee: Rohm and Haas CompanyInventors: Jane Elizabeth Weier, Morris Christopher Wills, Robert William Coyle
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Patent number: 7179852Abstract: The invention relates to a novel impact-resistance modifier, constructed from a core-shell 1 and a shell 2, whereby the core is plastically deformable. The invention is characterised by excellent mechanical properties obtained by a low content of impact-resistance modifier.Type: GrantFiled: July 26, 2001Date of Patent: February 20, 2007Assignee: Roehm GmbH & Co. KGInventors: Klaus Schultes, Thomas Suefke, Reiner Mueller, Thomas Arndt, Goerg Michler, Joachim Laatsch