Mixture Contains Solid Polymer Derived From Reactant Containing Chalcogen Patents (Class 525/93)
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Patent number: 6803396Abstract: Aqueous superplasticizer solutions for concrete compositions include a polymeric superplasticizer and an air-detraining effective amount of a block polyether containing ethylene oxide and propylene oxide units.Type: GrantFiled: August 16, 2001Date of Patent: October 12, 2004Assignee: BASF CorporationInventors: Sridhar Gopalkrishnan, Kenneth L. Zack, Karl-Heinz Buechner
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Publication number: 20040192844Abstract: The present invention provides a method for manufacturing a styrene-based polymer comprising the steps of continuously feeding raw materials into one end of two or more polymerization vessels connected in series; polymerizing a styrenic monomer in the coexistence of a (meth)acrylate ester monomer by using an organic radical generating agent as an initiator by a mass or solution polymerization method of continuous process; and continuously taking out a product from another end of said polymerization vessels, wherein polymerization conditions are controlled in ranges specified by the following items (a) and (b):Type: ApplicationFiled: January 5, 2004Publication date: September 30, 2004Inventors: Takeshi Ikematsu, Toshiharu Kawasaki, Ikuji Ohtani, Mitsutoshi Toyama
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Patent number: 6777082Abstract: The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.Type: GrantFiled: December 6, 2001Date of Patent: August 17, 2004Assignee: The Dow Chemical CompanyInventors: Rajen M. Patel, Pak-Wing S. Chum, Stephen F. Hahn, Leonie K. Walsh, Rexford A. Maugans, Selim Bensason, Thoi H. Ho, Calvin P. Esneault
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Publication number: 20040152838Abstract: A chemical-resistant polystyrene-based resin molded article obtained by molding a styrene-based resin composition comprising component (A): a styrene-based polymer having an atactic structure or a mixture of the styrene base polymer having an atactic structure and polyphenylene ether in a total amount of 10 to 95 parts by weight and component (B): a styrene-based polymer having primarily a syndiotactic structure in an amount of 90 to 5 parts by weight, wherein the component (B) has a relative crystallinity of 30% or less in a depth of up to 0.5 mm from the surface of the above molded article. By incorporating a rubber component which is a block polymer having a styrene content of 70 mass % or more in an amount of 3 to 97 parts by weight, a molded article excellent in transparency and chemical resistance can be obtained.Type: ApplicationFiled: December 1, 2003Publication date: August 5, 2004Inventors: Akihiko Okada, Takuma Aoyama
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Patent number: 6770370Abstract: An adhesive composition for semiconductor device, comprising 10 to 30% by weight of a reactive elastomer (A), 40 to 65% by weight of an epoxy resin (B) having two or more glycidyl ether groups, a phenol resin (C) and a curing accelerator (D), wherein a ratio of the epoxy resin (B) to the phenol resin (C) is within a range from 1:0.6 to 1:1 in terms of a functional group equivalent ratio, and an adhesive sheet for a semiconductor device using the same are provided. The composition and the sheet are superior in reflow resistance and short-time and low-temperature bonding without lowering characteristics such as heat resistance, low hygroscopicity, high adhesion and electrical insulating properties of an epoxy resin cured article.Type: GrantFiled: August 5, 2002Date of Patent: August 3, 2004Assignee: Tomoegawa Paper Co., Ltd.Inventors: Naoji Suzuki, Osamu Oka, Jun Tochihira, Akihiro Maeda
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Patent number: 6766963Abstract: A method for the manufacture of a railroad crosstie (90) from recycled rubber is disclosed. The rubber crosstie (90) has an expected life of between 30 to 60 years and can be made primarily of rubber crumbs obtained from stockpiles of discarded rubber tires. A feature of the invention is to produce a crosstie (90) having at least one longitudinal side incorporating a plurality of indentations for more effective engagement upon installation into a gravel bed to avoid slippage.Type: GrantFiled: November 7, 2002Date of Patent: July 27, 2004Assignee: Hansen Rubber Products Inc.Inventor: Steve Hansen
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Patent number: 6756106Abstract: An oil resistant, elastomeric rubber composite, particularly suited for use as an elastic tape for garments requiring a high degree of oil resistance due to conditions of its use. The rubber composite is made from a unique blend of nitrile rubber, polychloroprene (neoprene), epoxidised natural rubber and natural rubber. The elastomeric composite has excellent compatibility between two rubbers of different polarity when properly compounded and processed. The composite formed as an elastic tape has a low modulus of elasticity, good needle tear strength when sewn inside a garment, and it provides a comfortable fit for long use in addition to having reduced oil swell and oil abosorption characteristics. Elastic tapes made from the elastomeric rubber composite are particularly suitable for swimwear, shower caps, head bands, face masks and other garments with direct skin contact.Type: GrantFiled: October 15, 2002Date of Patent: June 29, 2004Assignee: Garware Elastomerics LimitedInventor: Ramesh Manjanath Telang
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Patent number: 6747064Abstract: The present invention comprises novel preparations of polyoxypropylene/polyoxyethylene copolymers which retain the therapeutic activity of the commercial preparations, but are substantially free from the undesirable effects which are inherent in the prior art preparations. Because the preparations of polyoxypropylene/polyoxyethylene copolymers which comprise the present invention are a less polydisperse population of molecules than the prior art polyoxypropylene/polyoxyethylene copolymers, the biological activity of the copolymers is better defined and more predictable.Type: GrantFiled: December 14, 2001Date of Patent: June 8, 2004Assignee: CytRx CorporationInventors: R. Martin Emanuele, Robert L. Hunter, Paula H. Culbreth
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Patent number: 6743860Abstract: The present invention relates to a thermoplastic resin composition comprising (a) 100 parts by weight of a block copolymer comprising at least two polymeric blocks A composed mainly of a vinyl aromatic compound and at least one polymeric block B composed mainly of a conjugated diene compound, or a hydrogenated block copolymer thereof, (d) 5 to 50 parts by weight of an organic peroxide, and (e) 10 to 80 parts by weight of one or more substances selected from the group consisting of multifunctional vinyl compounds and multifunctional (meth)acrylate compounds. The present invention provides a master batch of an organic peroxide in which the organic peroxide is so uniformly dispersed in a thermoplastic resin that crosslinking and/or decomposition occur uniformly, a method of preparing the same, a thermoplastic resin composition obtained using the master batch and a method of preparing the same.Type: GrantFiled: August 2, 2002Date of Patent: June 1, 2004Assignee: Riken Technos CorporationInventor: Hiroki Mizuno
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Patent number: 6734247Abstract: An improved tough, transparent polymer alloy comprised of 90 to 20 weight percent of a brittle polymer with a weight average molecular weight greater than 180,000; 0 to 60 weight percent of a rubbery polymer; 0 to 80 weight percent of a ductile polymer; and between greater than 0.4, i.e. between 0.5 and 3 weight percent of a plasticizer, i.e. mineral oil which resides in the brittle polymer. The brittle polymer can have molecular weights between 220,000 and 300,000, and may be as high as 400,000. In one of the preferred embodiments the brittle polymer is a copolymer of styrene and methyl methacrylate which copolymer ranges between 50 and 55 weight percent, the rubbery polymer is 0 weight percent, the ductile polymer is a styrene butadiene block copolymer ranging between 45 and 50 weight percent, and the mineral oil is 1.5 weight percent. Notched IZOD impact strength ranges between 1.0 to 6.0 ft-lb./in., preferably between 2.0 and 4.5 ft-lb./in. The haze can be less than 1.5% or it can be between 1 and 4%.Type: GrantFiled: December 13, 2001Date of Patent: May 11, 2004Assignee: Nova Chemicals Inc.Inventors: Allen Maxwell Donn, Richard Albert Cooper
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Patent number: 6730736Abstract: An alicyclic structure-containing resin composition comprising an alicyclic structure-containing resin (A) having a polar group in a proportion of 3 to 50 mol % based on the whole repeating unit in the resin, and a soft polymer (B), a varnish containing the resin composition, a sheet formed of the resin composition, and an insulating film formed of the resin composition.Type: GrantFiled: October 2, 2000Date of Patent: May 4, 2004Assignee: Nippon Zeon Co., Ltd.Inventors: Shojiro Kaita, Takashi Iga, Yasuhiro Wakizaka, Yasuo Tsunogae
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Patent number: 6673867Abstract: A heat-resistant engineering-plastic composition that satisfies a soldering-heat resistance of 260° C. for 10 to 60 secs., that is less costly, that is free of problems in injection molding process, and that is excellent in heat-aging resistance. A heat-resistant molded product made with the heat-resistant engineering-plastic composition, such as a connector mounted on printed circuit board. The heat-resistant molded product is produced by (a) melt-kneading (a1) an engineering plastic either having or introduced an active site for reacting with a specific functional group and (a2) either an organic compound that has both the said specific functional group and a polymerizing functional group in the same molecule or polyolefin that has the said specific functional group described in (a1) to obtain a resin composition, (b) melt-molding the resin composition comprising of (a), and (c) irradiating the melt-molded resin composition with ionizing radiation.Type: GrantFiled: November 13, 2001Date of Patent: January 6, 2004Assignee: Sumitomo Electric Fine Polymer, Inc.Inventors: Hiroshi Hayami, Shinya Nishikawa
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Patent number: 6664334Abstract: A golf ball maintaining favorable shot feeling, exhibiting great spin rate when hit by a short iron or the like, and that easily comes to a halt, and with high spin maintenance is provided. In a golf ball including a core and a cover surrounding the core, the cover includes an ionomer resin (A component), a thermoplastic elastomer with a rubber component or a modified product thereof (B component), and a resin (C component) having solubility with the thermoplastic elastomer with a rubber segment or a modified product thereof. The mixed ratio of the A component/B component is 0.25-4, and the C component/B component is 0.1-0.9.Type: GrantFiled: February 1, 2001Date of Patent: December 16, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Satoshi Iwami, Akira Kato, Keiji Moriyama
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Patent number: 6660790Abstract: Disclosed is a styrene polymer composition comprising a styrene/n-butyl acrylate copolymer (I) comprising styrene monomer units and n-butyl acrylate monomer units in a specific ratio, and a branched block copolymer (II) comprising vinyl aromatic hydrocarbon monomer units and conjugated diene monomer units in a specific ratio, wherein the branched block copolymer (II) has a block configuration comprising at least one vinyl aromatic hydrocarbon polymer block and at least one polymer block selected from the group consisting of at least one conjugated diene polymer block and at least one vinyl aromatic hydrocarbon/conjugated diene copolymer block, wherein the vinyl aromatic hydrocarbon polymer block of the branched block copolymer (II) exhibits, in a gel permeation chromatogram thereof, at least one peak molecular weight in each of two different specific ranges, and wherein the branched block copolymer (II) has a specific vinyl aromatic hydrocarbon block ratio.Type: GrantFiled: May 21, 2002Date of Patent: December 9, 2003Assignee: Asahi Kasei Kabushiki KaishaInventors: Susumu Hoshi, Nobuaki Kubo
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Patent number: 6646047Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, (b) 20 to 300 parts by weight of a non-aromatic softening agent for rubber, (c) 1 to 150 parts by weight of a peroxide-crosslinking type olefinic resin and/or a copolymeric rubber containing said resin, and (d) 10 to 150 parts by weight of a peroxide-decomposing type olefinic resin and/or a copolymer containing said resin, characterized in that the process comprises a step of heat-processing component (a), component (b), at least a part of component (c), at least a part of component (d) and at least a part of 1.Type: GrantFiled: April 30, 1999Date of Patent: November 11, 2003Assignee: Riken Technos CorporationInventors: Michihisa Tasaka, Akihiro Tamura, Tetsuya Sawai
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Patent number: 6642308Abstract: A high-damping elastomer composition comprises a styrene-isoprene-styrene triblock copolymer (component A) and a ethylene-methyl methacrylate random copolymer (component B). In the high-damping elastomer composition of the present invention, the styrene-isoprene-styrene triblock copolymer (component A) and the ethylene-methyl methacrylate random copolymer (component B) form a so-called “islands-in-the-sea” structure which may vary depending on the blending ratio therebetween. The components A and B are partially compatibilized with each other in a homogeneously mixed state in sea-island interfaces.Type: GrantFiled: March 14, 2001Date of Patent: November 4, 2003Assignee: Tokai Rubber Industries, Ltd.Inventors: Takeshi Nomura, Kazunobu Hashimoto
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Patent number: 6639014Abstract: Gel-forming macromers including at least four polymeric blocks, at least two of which are hydrophobic and at least one of which is hydrophilic, and including a crosslinkable group are provided. The macromers can be covalently crosslinked to form a gel on a tissue surface in vivo. The gels formed from the macromers have a combination of properties including thermosensitivity and lipophilicity, and are useful in a variety of medical applications including drug delivery and tissue coating.Type: GrantFiled: April 2, 2002Date of Patent: October 28, 2003Assignee: Focal, Inc.Inventors: Chandrashekhar P. Pathak, Shikha P. Barman, C. Michael Philbrook, Amarpreet S. Sawhney, Arthur J. Coury, Luis Z. Avila, Mark T. Kieras
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Patent number: 6610774Abstract: The invention provides an aqueous dispersion which includes i) an aqueous dispersion (I) resulting from dispersion of a block copolymer (I) composed of at least one polymer block (A) containing olefin monomer units and at least one polymer block (B) containing 2 to 100 mole percent of units derived from at least one vinyl monomer having a carboxyl or carboxylic anhydride group and 98 to 0 (zero) mole percent of units derived from another vinyl monomer or monomers copolymerizable with the carboxyl group- or carboxylic anhydride group-containing vinyl monomer, in an aqueous solution of not less than 0.05 equivalent, relative to the carboxyl or carboxylic anhydride group, of a basic substance, and ii) a polyurethane (II), iii) vinyl polymer (III) or iv) tackifier (IV) incorporated in the aqueous dispersion (I).Type: GrantFiled: June 29, 2001Date of Patent: August 26, 2003Assignee: Kuraray Co., Ltd.Inventors: Kazuhiko Maekawa, Mototsugu Yoshihara, Mitsuru Kato, Yukio Itoshima, Mamoru Omoda, Yukiatsu Komiya
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Patent number: 6608127Abstract: A golf ball exhibits a high spin and easily comes to a halt even when shot from the rough or when shot in a raining condition. The cover material of the golf ball is based on ionomer resin. The cover material has 5-50 parts by weight of a tackifier such as terpene resins, rosin ester resins or the like blended with respect to 100 parts by weight of the base material.Type: GrantFiled: July 6, 2000Date of Patent: August 19, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Akira Kato, Hidenori Hiraoka, Masatoshi Yokota, Satoshi Iwami
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Patent number: 6605236Abstract: A composition comprised of a composite comprised of an aromatic or heteroaromatic polymer comprised of monomer or monomers selected from the group consisting of pyrrole, indole, thiophene, thianaphthene, indene, azulene and ring pendant substitutent derivatives thereof as a discrete phase; and a block copolymer as a continuous phase selected from the group consisting of ionophoric and ionomeric copolymers, wherein the block copolymer has at least one apolar segment and at least one ion binding segment, wherein the ionomeric or ionophoric block copolymer is present in an amount from about 99 to about 50 percent by weight based on the combined weight of the block copolymer and the aromatic or heteroaromatic polymer, wherein the block copolymer provides micellar or vesicular domains for organization and polymerization of the monomer or monomers.Type: GrantFiled: January 3, 1994Date of Patent: August 12, 2003Assignee: Xerox CorporationInventors: Thomas W. Smith, David J. Luca
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Patent number: 6598637Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr): (a) 99 to 50 parts by weight of a first rubber containing olefinic unsaturation; and (b) 1 to 50 parts by weight of a second rubber which is different from said first rubber and which is an elastomeric block copolymer of (1) from 15 to 65 percent by weight, based on the total block copolymer, of butadiene, and (2) from 35 to 85 percent by weight, based on the total block copolymer, of styrene, which block copolymer has: (a) at least two blocks A which have polymerized units of styrene, a glass transition temperature Tg above 25° C.Type: GrantFiled: July 10, 2001Date of Patent: July 29, 2003Assignee: The Goodyear Tire & Rubber CompanyInventors: Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
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Patent number: 6583223Abstract: A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a radically polymerizable fluoroalkyl(meth)acrylate monomer, a second block made up of residues of a second radically polymerizable ethylenically unsaturated monomer, and optionally a third block made up of residues of a third radically polymerizable ethylenically unsaturated monomer. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. Also disclosed is a method of coating a substrate including the steps of applying the present thermosetting composition to the substrate; coalescing the thermosetting composition to form a substantially continuous film; and curing said thermosetting composition by the application of heat.Type: GrantFiled: September 27, 2001Date of Patent: June 24, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan D. Goetz, Kurt A. Humbert, Karl F. Schimmel, Karen A. Barkac, Simion Coca, Joanne H. Smith
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Patent number: 6576692Abstract: The present invention is directed to an epoxidized block copolymer composition comprising an epoxidized block copolymer (E) obtained by epoxidizing a block copolymer (C) comprising a polymer block (A) composed mainly of a vinyl aromatic hydrocarbon compound and a polymer block (B) composed mainly of a conjugated diene compound or a product (D) of hydrogenation of the block copolymer (C). The epoxidized block copolymer (E) meets at least one of the following requisites: (1) having a molar ratio (R) of contained hydroxyl to epoxy ranging from 0.001 to 0.Type: GrantFiled: May 28, 1999Date of Patent: June 10, 2003Assignee: Daicel Chemical Industries, Ltd.Inventors: Yoshihiro Ohtsuka, Yasuhiro Oshino, Masaki Tanaka
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Patent number: 6576707Abstract: The present invention provides a multi-piece solid golf ball having very good shot feel, excellent durability and excellent flight performance. The present invention relates to a multi-piece solid golf ball comprising a core, an inner cover and outer cover, wherein the inner cover has a Shore D hardness of 30 to 62, and is formed from an inner cover composition comprising (a) 50 to 95 parts by weight of ethylene-(meth)acrylic acid copolymer ionomer resin, and (b) 5 to 50 parts by weight of thermoplastic elastomer formed from a polymer alloy of an olefin with a block copolymer having styrene block, based on 100 parts by weight of a base resin; the outer cover is formed from a composition comprising ionomer resin as a main component, and has a Shore D hardness of 58 to 68; and the hardness of the outer cover is higher than that of the inner cover.Type: GrantFiled: December 12, 2001Date of Patent: June 10, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Keiji Ohama, Seiichiro Endo
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Publication number: 20030100675Abstract: A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a radically polymerizable fluoroalkyl (meth)acrylate monomer, a second block made up of residues of a second radically polymerizable ethylenically unsaturated monomer, and optionally a third block made up of residues of a third radically polymerizable ethylenically unsaturated monomer. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. Also disclosed is a method of coating a substrate including the steps of applying the present thermosetting composition to the substrate; coalescing the thermosetting composition to form a substantially continuous film; and curing said thermosetting composition by the application of heat.Type: ApplicationFiled: September 27, 2001Publication date: May 29, 2003Inventors: Jonathan D. Goetz, Kurt A. Humbert, Karl F. Schimmel, Karen A. Barkac, Simion Coca, Joanne H. Smith
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Patent number: 6552126Abstract: Disclosed herein is a golf ball having a core and a cover comprising a blend of ionomer and plastomer. The golf ball has an impact resistance and cut resistance comparable to a ball having a non-plastomer cover and containing higher quantities of ionomer.Type: GrantFiled: February 16, 2001Date of Patent: April 22, 2003Assignee: Spalding Sports Worldwide, Inc.Inventors: Edward J. Kaltenbacher, Joseph Domine, Michael J. Sullivan
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Publication number: 20030065048Abstract: Radiation curable adhesive comprising an epoxidized block copolymer, a saturated block copolymer and/or a rosin derived alcohol, and a photoinitiator.Type: ApplicationFiled: June 26, 2001Publication date: April 3, 2003Inventor: Charles W. Paul
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Patent number: 6541553Abstract: This invention relates to curable strippable adhesive and coating films, and also to improved high performance pressure sensitive adhesives. The adhesive comprises: (a) from 10 to 90 percent by weight of a crosslinkable epoxidized diene polymer, (b) from 0 to 70 percent by weight of a diene mono-ol polymer, with the condition that the mono-ol polymer not exceed three times the weight of the epoxidized polymer, (c) from 5 to 40 weight percent of a block copolymer of a vinyl aromatic hydrocarbon and a diene having, on average, more than one vinyl aromatic hydrocarbon block per molecule, and wherein the block copolymer can be functionalized by grafting onto it from 0.1 to 5% by weight of a carboxylic acid or anhydride, preferably maleic anhydride, (d) from 0 to 65% percent by weight of a tackifying resin, and (e) from 0.01 to 3 percent by weight of a photoinitiator.Type: GrantFiled: October 17, 2000Date of Patent: April 1, 2003Assignee: Kraton Polymers U.S. LLCInventors: James Robert Erickson, David Romme Hansen
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Publication number: 20030059906Abstract: The invention provides methods for the preparation of multiblock copolymers, dispersions of multiblock copolymers, vesicles and micelles containing multiblock copolymers, and oxidative degradation products of multiblock copolymers.Type: ApplicationFiled: October 19, 2001Publication date: March 27, 2003Inventors: Jeffrey A. Hubbell, Alessandro Napoli, Nicola Tirelli
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Patent number: 6521704Abstract: The present invention relates to methods to improve the dampening characteristics of compositions and the improved compositions. The compositions made by the method comprises (a) a polymer system selected from the group consisting of immiscible polymer blends, miscible polymer blends, copolymers, thermoplastic polymers and thermosetting polymers, and (b) a block copolymer comprising: (i) at least one block derived from aromatic vinyl units and (ii) at least one block derived from at least isoprene and a vinyl aromatic monomer and optionally butadiene, and having a glass transition temperature of at least 10° C. In a preferred embodiment, the block copolymer comprises at least one block of polystyrene and at least one block derived from isoprene, styrene and butadiene, and the polymer system comprises at least one polyamide resin.Type: GrantFiled: June 13, 2000Date of Patent: February 18, 2003Assignee: General Electric CompanyInventors: Steven F. Hubbard, Sai-Pei Ting
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Patent number: 6515072Abstract: A transparent rubber-modified styrenic resin composition contains a rubber-particle-dispersed phase (A) and a copolymer matrix (B). The phase (A) contains a rubbery copolymer which is a block copolymer formed from 10 to 50 wt % of styrenic monomers and 90 to 50 wt % of dienic monomers, wherein the rubbery copolymer block contains polystyrene block in an amount of 5 to 35 wt % based on total weight of the rubbery copolymer. The copolymer matrix (B) is composed of 12 to 70 parts by weight of styrenic unit, 20 to 80 parts by weight of (meth)acrylate unit, 1 to 20 parts by weight of vinyl cyanide unit, and 0 to 40 parts by weight of other copolymerizable monomer units, based on 100 parts by weight of total monomer unit. The content of the copolymer matrix (B) having a molecular weight of 3,000˜50,000 is in an amount of 15 to 50 wt %, based on the total weight of the copolymer matrix (B).Type: GrantFiled: December 7, 2000Date of Patent: February 4, 2003Assignee: Chi Mei CorporationInventor: Ray-Hsi Hsu
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Patent number: 6509395Abstract: Branched polymer defoamers for pigment dispersants. The branched polymers are the reaction products of a linking agent defined by formula (I): R(Y)3 (I) wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups together represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R group to form an epoxy group, and R is an alkanetriyl group containing from 3 to 10 carbon atoms, and b) at least one compound having the formula (II) R1X(EO)n(PO)m(BO)pZ (II) wherein R1 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 4 to 36 carbon atoms; x is —O—, —S—, or —NR2—where R2 is hydrogen or a C1-C4 alkyl group; Z is hydrogen, —NHR2 in place of a terminal —O— group wherein R2 has the meaning given above, or —SH, in which the —SH group is present in place of a terminal —O— group; n is a number of from 0 to 100, e.g.Type: GrantFiled: March 8, 2001Date of Patent: January 21, 2003Assignee: Cognis CorporationInventors: Kenneth Breindel, David W. Brown
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Patent number: 6508725Abstract: Golf ball compositions for use in ball covers and intermediate layers incorporate a specified block copolymer and are essentially free of ionomeric material. The compositions are outside the scope of those previously considered suitable for use in ball covers and intermediate layers. When used in ball covers, the composition provides for improved ball performance with respect to spin rate, feel, and durability. When used in ball intermediate layers, the composition provides for improved ball performance with respect to spin rate and distance. Also, a method for making a golf ball includes preparing a composition essentially free of ionomeric material including the specified block copolymer, and then incorporating the composition into a golf ball.Type: GrantFiled: April 18, 2001Date of Patent: January 21, 2003Assignee: Taylor Made Golf Company, Inc.Inventor: Hyun Jin Kim
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Patent number: 6495635Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.Type: GrantFiled: May 26, 2000Date of Patent: December 17, 2002Inventor: Gerald E. Edson
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Patent number: 6476129Abstract: The present invention relates to a novel thermoplastic elastomer composition with superior oil resistance along with elastomeric flexibility, creep resistance at high temperature, superior mechanical strength and moldability. The composition comprises (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two A polymer blocks comprised mainly of a vinyl aromatic compound and at least one B polymer block comprised mainly of a conjugated diene compound; and (b) 30-300 parts by weight of a partially crosslinked thermoplastic elastomer obtained by polymerizing an acrylate monomer absorbed in a polyolefin. The novel composition can be applied as a material for various molded parts.Type: GrantFiled: May 27, 1998Date of Patent: November 5, 2002Assignees: Asahi Kasei Kogyo Kabushiki Kaisha, Optatech CorporationInventor: Tetsuo Masubuchi
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Publication number: 20020147273Abstract: The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.Type: ApplicationFiled: December 6, 2001Publication date: October 10, 2002Inventors: Rajen M. Patel, Pak-Wing S. Chum, Stephen F. Hahn, Leonie K. Walsh, Rexford A. Maugans, Selim Bensason, Thoi H. Ho, Calvin P. Esneault
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Patent number: 6461696Abstract: The present invention provides a multiple layer thermoplastic structure of a (1) skin layer selected from the group consisting of polypropylene, ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc, and ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc blended with an ethylene and a-olefin copolymers having a density less than about 0.930 g/cc, the skin layer having a thickness of greater than about 3.0 mils; (2) a radio frequency susceptible layer adhered to the skin layer, the radio frequency susceptible layer having a dielectric loss greater than 0.05 at 1-60 MHz and at temperatures of ambient to 250° C.Type: GrantFiled: February 7, 2000Date of Patent: October 8, 2002Assignee: Baxter International Inc.Inventors: Michael T. K. Ling, Lecon Woo, Robert Wojnarowski, Ketan Shah, Gregg Nebgen, Yuan-pang Samuel Ding, Varsha Kalyankar, Keith M. K. Anderson, Lillian G. Zakarija, Colleen S. Cramer, Michael Scharf, Larry A. Rosenbaum
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Patent number: 6458864Abstract: Compounds with chain transfer groups of the formula I, II, III and IV wherein a is 1 or 2; Ar and Ar1 inter alia are phenyl; Ar2 inter alia is phenylene, these groups being unsubstituted or substituted; X is a direct bond, —O—, —S— or —N(R6)—; Y inter alia is hydrogen or C1-C12alkyl; M1 is —NR3R4 or —OH, or M1 is Ar when R1 and R2 are alkoxy, or aryloxy; R1 and R2 independently of one another e.g. are C1-C8alkyl; R3 and R4 for example are C1-C12alkyl, or together are C3-C7alkylene; R5 inter alia is C1-C6alkylene or a direct bond; R6 is for example hydrogen; and Z is a divalent radical, provided that at least one of the radicals Ar, Ar1, Ar2, R1, R2, R3, R4, R5 or Y is substituted by SH groups; are suitable for the thermal preparation of macrophotoinitiators which are polymerized photochemically to give block-copolymers.Type: GrantFiled: November 27, 2000Date of Patent: October 1, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Toshikage Asakura, Masaki Ohwa, Hitoshi Yamato, Asako Ito
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Patent number: 6451458Abstract: An electroluminescent cell which exhibits a high luminous efficiency and excellent durability is provided. The electroluminescent material comprises a unit (AB) which is formed by alternate copolymerization of hole transfer monomers and electron transfer monomers, and a unit (A) which is formed by the polymerization of hole transfer monomers, wherein the molar ratio of the total of the structural units originating from the hole transfer monomers and the structural units originating from the electron transfer monomers in the unit (AB) and the structural units originating from the hole transfer monomers in the unit (A) is from 50:50 to 5:95. The electroluminescent cell has an anode layer 2, an electroluminescent material layer 3 made from the electroluminescent material, an electron transfer luminous layer 4, and a cathode layer 5.Type: GrantFiled: November 26, 1999Date of Patent: September 17, 2002Assignees: JSR Corporation, International Center for Materials Research, TECO Electric & Machinery Co., Ltd.Inventors: Mitsuhiko Sakakibara, Yasumasa Takeuchi, Ding-kuo Ding
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Publication number: 20020115771Abstract: The present invention relates to a molding composition containing thermoplastic polyesters, impact-modifying component which contains anhydride groups, a copolymer of &agr;-olefin, acrylic compound, olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline and/or oxazinone, which has improved low-temperature impact strength; methods of making molding with the molding composition and molding containing the composition.Type: ApplicationFiled: December 20, 2001Publication date: August 22, 2002Applicant: DEGUSSA AGInventors: Ralf Schueler, Heinz Peirick, Guido Schmitz, Georg Oenbrink, Harald Haeger
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Patent number: 6408593Abstract: A polymeric roofing shingle composition is shown which includes (a) a rubber component present in the range from about 10-95% by weight, based on the total weight of the composition and (b) a polyolefin component present in the range from about 5-50% by weight, based on the total weight of the composition. A SBR/EVA closed cell rubber composition can be formulated which has a weight of less than 150 pounds per roofing square for ⅛ inch thickness and which is flame retardant at thicknesses of ⅛ inch and higher without the addition of separate flame retardant components.Type: GrantFiled: September 1, 1999Date of Patent: June 25, 2002Inventors: Pete Foster, Donald E. Dilks
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Publication number: 20020077419Abstract: There is provided a process for the continuous polymerization of polyamides which is carried out under conditions of pressure, temperature and polymer concentration in water that will ultimately yield multiple phases (including a second liquid polymer phase or a polymer precipitate). However, a single phase operation is achieved under these conditions by appropriate management of residence time and using a well-mixed reaction environment in early stages of the polymerization.Type: ApplicationFiled: September 28, 2001Publication date: June 20, 2002Inventors: Jocelyn Willis-Papi, Turget Mutel
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Publication number: 20020077420Abstract: To provide a curable composition excellent in flexibility and heat resistance. A curable composition which comprises (A) a block copolymer having at least one kind of block formed from an aliphatic hydrocarbon compound and (B) an isobutylene polymer having a silicon group bound to a hydrolyzable group or a hydroxyl group. That composition can be used as sealants, adhesives, pressure sensitive adhesives, compositions for gaskets, double layer glazing spacers and so on.Type: ApplicationFiled: December 3, 2001Publication date: June 20, 2002Inventors: Makoto Chiba, Shintaro Komitsu
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Patent number: 6383586Abstract: An adhesive composition that is specifically formulated for use in packaging medical products such as catheters between a spun-bonded polyolefin non-woven fabric and an ethylene vinyl acetate copolymer film includes from about 5 to about 65 percent by weight of a low density polyethylene; from about 35 to about 90 percent by weight of an ethylene vinyl acetate copolymers; and from about 5 to about 65 percent by weight of a linear block copolymer having at least one vinyl substituted aromatic hydrocarbon polymer block and at least one polyolefin polymer block made from an aliphatic conjugated diene.Type: GrantFiled: November 20, 2000Date of Patent: May 7, 2002Assignee: Oliver Products CompanyInventor: Robert J. Langeland
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Patent number: 6372845Abstract: A blended composition consisting of a thermoplastic olefin resin (Comp. A) with an acrylonitrile-styrene-alkyl acrylate copolymer (Comp. B) was attempted to create substitution for vinyl chloride compound prepared from vinyl chloride resin proper and a plasticizer, but resulted in inferior interdispersibility. Incorporation of an epoxy resin (Comp. C) has brought definite improvement in the interdispersibility. A resinous composition including the components A, B, and C has the utility of substitution for vinyl chloride compounds as well as its products. (Comp. C) is selected from the group consisting of epoxidized diene block copolymers including, in their molecules, a block prepared by polymerization from a vinyl aromatic monomer and another block prepared by polymerization from a conjugated diene monomer, wherein remnant diene groups after the polymerization have been epoxidized or further partially hydrogenated.Type: GrantFiled: October 29, 1999Date of Patent: April 16, 2002Assignee: Daicel Chemical Industries, Ltd.Inventors: Yoshihiro Ohtsuka, Tohru Matsuda, Shizuo Maeda, Kouichi Ishiihara, Yoshikazu Hida
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Publication number: 20020037962Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr):Type: ApplicationFiled: July 10, 2001Publication date: March 28, 2002Inventors: Annette Lechtenbohmer, Maurice Peter Catharina Jozef Klinkenberg
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Patent number: 6359014Abstract: The present invention comprises preparations of polyoxypropylene/polyoxyethylene copolymers which retain the therapeutic activity of the commercial preparations, but are substantially free from the undesirable effects which are inherent in the prior art preparations. Because the preparations of polyoxypropylene/polyoxyethylene copolymers which comprise the present invention are a less polydisperse population of molecules than the prior art polyoxypropylene/polyoxyethylene copolymers, the biological activity of the copolymers is better defined and more predictable.Type: GrantFiled: August 5, 1999Date of Patent: March 19, 2002Assignee: CytRx CorporationInventors: R. Martin Emanuele, Robert L. Hunter, Paula H. Culbreth
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Patent number: 6359066Abstract: The present invention provides a multi-layer structure golf ball having a thread rubber layer, which has good shot feel and controllability as well as satisfactory flight performance and cut resistance. The golf ball includes a thread wound core and a cover covering the thread wound core, wherein the cover is formed from a heated mixture of: (A) an ionomer resin, (B) a thermoplastic elastomer having a carboxyl group or a thermoplastic elastomer having a terminal OH group, and (C) a block copolymer having a styrene-butadiene-styrene structure in which the polybutadiene block contains epoxy groups, or a block copolymer having styrene-isoprene-styrene structure in which the polyisoprene block contains epoxy groups, the cover have a flexural modulus of from 50 to 300 MPa and a Shore D-scale hardness of from 40 to 60.Type: GrantFiled: March 28, 1997Date of Patent: March 19, 2002Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Yoshikazu Yabuki
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Patent number: 6359065Abstract: A solid golf ball having good shot feel and durability as well as satisfactory flight performance and cut resistances which comprises a solid core and a cover covering the core, wherein the cover is formed from a heated mixture of: (A) an ionomer resin, (B) a thermoplastic elastomer having a carboxyl group or a thermoplastic elastomer having a terminal OH group, and (C) a block copolymer having a styrene-butadiene-styrene structure in which the polybutadiene block contains epoxy groups, or a block copolymer having styrene-isoprene-styrene structure in which the polyisoprene block contains epoxy groups, wherein the cover has a flexural modulus of from 50 to 300 MPa and a Shore D-scale hardness of from 40 to 60.Type: GrantFiled: March 28, 1997Date of Patent: March 19, 2002Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Yoshikazu Yabuki
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Patent number: H2096Abstract: Disclosed are (1) a thermoplastic elastomeric film comprised of an elastomeric arene-diene block copolymer and particular ethylene/&bgr;-olefin copolymers having low ethylene crystallinity and (2) the process of preparing films thereof. The disclosed films have superior strength and elasticity characteristics which render them particularly useful in apparel and healthcare items such as disposable diapers.Type: GrantFiled: June 6, 1995Date of Patent: January 6, 2004Assignee: Exxon Chemical Patents, IInventors: Thomas Craig Erderly, John Hugh MacKay, Russell Harrel Narramore