Mixture Contains Solid Polymer Derived From Reactant Containing Chalcogen Patents (Class 525/93)
  • Patent number: 6803396
    Abstract: Aqueous superplasticizer solutions for concrete compositions include a polymeric superplasticizer and an air-detraining effective amount of a block polyether containing ethylene oxide and propylene oxide units.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: October 12, 2004
    Assignee: BASF Corporation
    Inventors: Sridhar Gopalkrishnan, Kenneth L. Zack, Karl-Heinz Buechner
  • Publication number: 20040192844
    Abstract: The present invention provides a method for manufacturing a styrene-based polymer comprising the steps of continuously feeding raw materials into one end of two or more polymerization vessels connected in series; polymerizing a styrenic monomer in the coexistence of a (meth)acrylate ester monomer by using an organic radical generating agent as an initiator by a mass or solution polymerization method of continuous process; and continuously taking out a product from another end of said polymerization vessels, wherein polymerization conditions are controlled in ranges specified by the following items (a) and (b):
    Type: Application
    Filed: January 5, 2004
    Publication date: September 30, 2004
    Inventors: Takeshi Ikematsu, Toshiharu Kawasaki, Ikuji Ohtani, Mitsutoshi Toyama
  • Patent number: 6777082
    Abstract: The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: August 17, 2004
    Assignee: The Dow Chemical Company
    Inventors: Rajen M. Patel, Pak-Wing S. Chum, Stephen F. Hahn, Leonie K. Walsh, Rexford A. Maugans, Selim Bensason, Thoi H. Ho, Calvin P. Esneault
  • Publication number: 20040152838
    Abstract: A chemical-resistant polystyrene-based resin molded article obtained by molding a styrene-based resin composition comprising component (A): a styrene-based polymer having an atactic structure or a mixture of the styrene base polymer having an atactic structure and polyphenylene ether in a total amount of 10 to 95 parts by weight and component (B): a styrene-based polymer having primarily a syndiotactic structure in an amount of 90 to 5 parts by weight, wherein the component (B) has a relative crystallinity of 30% or less in a depth of up to 0.5 mm from the surface of the above molded article. By incorporating a rubber component which is a block polymer having a styrene content of 70 mass % or more in an amount of 3 to 97 parts by weight, a molded article excellent in transparency and chemical resistance can be obtained.
    Type: Application
    Filed: December 1, 2003
    Publication date: August 5, 2004
    Inventors: Akihiko Okada, Takuma Aoyama
  • Patent number: 6770370
    Abstract: An adhesive composition for semiconductor device, comprising 10 to 30% by weight of a reactive elastomer (A), 40 to 65% by weight of an epoxy resin (B) having two or more glycidyl ether groups, a phenol resin (C) and a curing accelerator (D), wherein a ratio of the epoxy resin (B) to the phenol resin (C) is within a range from 1:0.6 to 1:1 in terms of a functional group equivalent ratio, and an adhesive sheet for a semiconductor device using the same are provided. The composition and the sheet are superior in reflow resistance and short-time and low-temperature bonding without lowering characteristics such as heat resistance, low hygroscopicity, high adhesion and electrical insulating properties of an epoxy resin cured article.
    Type: Grant
    Filed: August 5, 2002
    Date of Patent: August 3, 2004
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Naoji Suzuki, Osamu Oka, Jun Tochihira, Akihiro Maeda
  • Patent number: 6766963
    Abstract: A method for the manufacture of a railroad crosstie (90) from recycled rubber is disclosed. The rubber crosstie (90) has an expected life of between 30 to 60 years and can be made primarily of rubber crumbs obtained from stockpiles of discarded rubber tires. A feature of the invention is to produce a crosstie (90) having at least one longitudinal side incorporating a plurality of indentations for more effective engagement upon installation into a gravel bed to avoid slippage.
    Type: Grant
    Filed: November 7, 2002
    Date of Patent: July 27, 2004
    Assignee: Hansen Rubber Products Inc.
    Inventor: Steve Hansen
  • Patent number: 6756106
    Abstract: An oil resistant, elastomeric rubber composite, particularly suited for use as an elastic tape for garments requiring a high degree of oil resistance due to conditions of its use. The rubber composite is made from a unique blend of nitrile rubber, polychloroprene (neoprene), epoxidised natural rubber and natural rubber. The elastomeric composite has excellent compatibility between two rubbers of different polarity when properly compounded and processed. The composite formed as an elastic tape has a low modulus of elasticity, good needle tear strength when sewn inside a garment, and it provides a comfortable fit for long use in addition to having reduced oil swell and oil abosorption characteristics. Elastic tapes made from the elastomeric rubber composite are particularly suitable for swimwear, shower caps, head bands, face masks and other garments with direct skin contact.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: June 29, 2004
    Assignee: Garware Elastomerics Limited
    Inventor: Ramesh Manjanath Telang
  • Patent number: 6747064
    Abstract: The present invention comprises novel preparations of polyoxypropylene/polyoxyethylene copolymers which retain the therapeutic activity of the commercial preparations, but are substantially free from the undesirable effects which are inherent in the prior art preparations. Because the preparations of polyoxypropylene/polyoxyethylene copolymers which comprise the present invention are a less polydisperse population of molecules than the prior art polyoxypropylene/polyoxyethylene copolymers, the biological activity of the copolymers is better defined and more predictable.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: June 8, 2004
    Assignee: CytRx Corporation
    Inventors: R. Martin Emanuele, Robert L. Hunter, Paula H. Culbreth
  • Patent number: 6743860
    Abstract: The present invention relates to a thermoplastic resin composition comprising (a) 100 parts by weight of a block copolymer comprising at least two polymeric blocks A composed mainly of a vinyl aromatic compound and at least one polymeric block B composed mainly of a conjugated diene compound, or a hydrogenated block copolymer thereof, (d) 5 to 50 parts by weight of an organic peroxide, and (e) 10 to 80 parts by weight of one or more substances selected from the group consisting of multifunctional vinyl compounds and multifunctional (meth)acrylate compounds. The present invention provides a master batch of an organic peroxide in which the organic peroxide is so uniformly dispersed in a thermoplastic resin that crosslinking and/or decomposition occur uniformly, a method of preparing the same, a thermoplastic resin composition obtained using the master batch and a method of preparing the same.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: June 1, 2004
    Assignee: Riken Technos Corporation
    Inventor: Hiroki Mizuno
  • Patent number: 6734247
    Abstract: An improved tough, transparent polymer alloy comprised of 90 to 20 weight percent of a brittle polymer with a weight average molecular weight greater than 180,000; 0 to 60 weight percent of a rubbery polymer; 0 to 80 weight percent of a ductile polymer; and between greater than 0.4, i.e. between 0.5 and 3 weight percent of a plasticizer, i.e. mineral oil which resides in the brittle polymer. The brittle polymer can have molecular weights between 220,000 and 300,000, and may be as high as 400,000. In one of the preferred embodiments the brittle polymer is a copolymer of styrene and methyl methacrylate which copolymer ranges between 50 and 55 weight percent, the rubbery polymer is 0 weight percent, the ductile polymer is a styrene butadiene block copolymer ranging between 45 and 50 weight percent, and the mineral oil is 1.5 weight percent. Notched IZOD impact strength ranges between 1.0 to 6.0 ft-lb./in., preferably between 2.0 and 4.5 ft-lb./in. The haze can be less than 1.5% or it can be between 1 and 4%.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: May 11, 2004
    Assignee: Nova Chemicals Inc.
    Inventors: Allen Maxwell Donn, Richard Albert Cooper
  • Patent number: 6730736
    Abstract: An alicyclic structure-containing resin composition comprising an alicyclic structure-containing resin (A) having a polar group in a proportion of 3 to 50 mol % based on the whole repeating unit in the resin, and a soft polymer (B), a varnish containing the resin composition, a sheet formed of the resin composition, and an insulating film formed of the resin composition.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: May 4, 2004
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shojiro Kaita, Takashi Iga, Yasuhiro Wakizaka, Yasuo Tsunogae
  • Patent number: 6673867
    Abstract: A heat-resistant engineering-plastic composition that satisfies a soldering-heat resistance of 260° C. for 10 to 60 secs., that is less costly, that is free of problems in injection molding process, and that is excellent in heat-aging resistance. A heat-resistant molded product made with the heat-resistant engineering-plastic composition, such as a connector mounted on printed circuit board. The heat-resistant molded product is produced by (a) melt-kneading (a1) an engineering plastic either having or introduced an active site for reacting with a specific functional group and (a2) either an organic compound that has both the said specific functional group and a polymerizing functional group in the same molecule or polyolefin that has the said specific functional group described in (a1) to obtain a resin composition, (b) melt-molding the resin composition comprising of (a), and (c) irradiating the melt-molded resin composition with ionizing radiation.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: January 6, 2004
    Assignee: Sumitomo Electric Fine Polymer, Inc.
    Inventors: Hiroshi Hayami, Shinya Nishikawa
  • Patent number: 6664334
    Abstract: A golf ball maintaining favorable shot feeling, exhibiting great spin rate when hit by a short iron or the like, and that easily comes to a halt, and with high spin maintenance is provided. In a golf ball including a core and a cover surrounding the core, the cover includes an ionomer resin (A component), a thermoplastic elastomer with a rubber component or a modified product thereof (B component), and a resin (C component) having solubility with the thermoplastic elastomer with a rubber segment or a modified product thereof. The mixed ratio of the A component/B component is 0.25-4, and the C component/B component is 0.1-0.9.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: December 16, 2003
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Satoshi Iwami, Akira Kato, Keiji Moriyama
  • Patent number: 6660790
    Abstract: Disclosed is a styrene polymer composition comprising a styrene/n-butyl acrylate copolymer (I) comprising styrene monomer units and n-butyl acrylate monomer units in a specific ratio, and a branched block copolymer (II) comprising vinyl aromatic hydrocarbon monomer units and conjugated diene monomer units in a specific ratio, wherein the branched block copolymer (II) has a block configuration comprising at least one vinyl aromatic hydrocarbon polymer block and at least one polymer block selected from the group consisting of at least one conjugated diene polymer block and at least one vinyl aromatic hydrocarbon/conjugated diene copolymer block, wherein the vinyl aromatic hydrocarbon polymer block of the branched block copolymer (II) exhibits, in a gel permeation chromatogram thereof, at least one peak molecular weight in each of two different specific ranges, and wherein the branched block copolymer (II) has a specific vinyl aromatic hydrocarbon block ratio.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: December 9, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Susumu Hoshi, Nobuaki Kubo
  • Patent number: 6646047
    Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, (b) 20 to 300 parts by weight of a non-aromatic softening agent for rubber, (c) 1 to 150 parts by weight of a peroxide-crosslinking type olefinic resin and/or a copolymeric rubber containing said resin, and (d) 10 to 150 parts by weight of a peroxide-decomposing type olefinic resin and/or a copolymer containing said resin, characterized in that the process comprises a step of heat-processing component (a), component (b), at least a part of component (c), at least a part of component (d) and at least a part of 1.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: November 11, 2003
    Assignee: Riken Technos Corporation
    Inventors: Michihisa Tasaka, Akihiro Tamura, Tetsuya Sawai
  • Patent number: 6642308
    Abstract: A high-damping elastomer composition comprises a styrene-isoprene-styrene triblock copolymer (component A) and a ethylene-methyl methacrylate random copolymer (component B). In the high-damping elastomer composition of the present invention, the styrene-isoprene-styrene triblock copolymer (component A) and the ethylene-methyl methacrylate random copolymer (component B) form a so-called “islands-in-the-sea” structure which may vary depending on the blending ratio therebetween. The components A and B are partially compatibilized with each other in a homogeneously mixed state in sea-island interfaces.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: November 4, 2003
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Takeshi Nomura, Kazunobu Hashimoto
  • Patent number: 6639014
    Abstract: Gel-forming macromers including at least four polymeric blocks, at least two of which are hydrophobic and at least one of which is hydrophilic, and including a crosslinkable group are provided. The macromers can be covalently crosslinked to form a gel on a tissue surface in vivo. The gels formed from the macromers have a combination of properties including thermosensitivity and lipophilicity, and are useful in a variety of medical applications including drug delivery and tissue coating.
    Type: Grant
    Filed: April 2, 2002
    Date of Patent: October 28, 2003
    Assignee: Focal, Inc.
    Inventors: Chandrashekhar P. Pathak, Shikha P. Barman, C. Michael Philbrook, Amarpreet S. Sawhney, Arthur J. Coury, Luis Z. Avila, Mark T. Kieras
  • Patent number: 6610774
    Abstract: The invention provides an aqueous dispersion which includes i) an aqueous dispersion (I) resulting from dispersion of a block copolymer (I) composed of at least one polymer block (A) containing olefin monomer units and at least one polymer block (B) containing 2 to 100 mole percent of units derived from at least one vinyl monomer having a carboxyl or carboxylic anhydride group and 98 to 0 (zero) mole percent of units derived from another vinyl monomer or monomers copolymerizable with the carboxyl group- or carboxylic anhydride group-containing vinyl monomer, in an aqueous solution of not less than 0.05 equivalent, relative to the carboxyl or carboxylic anhydride group, of a basic substance, and ii) a polyurethane (II), iii) vinyl polymer (III) or iv) tackifier (IV) incorporated in the aqueous dispersion (I).
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: August 26, 2003
    Assignee: Kuraray Co., Ltd.
    Inventors: Kazuhiko Maekawa, Mototsugu Yoshihara, Mitsuru Kato, Yukio Itoshima, Mamoru Omoda, Yukiatsu Komiya
  • Patent number: 6608127
    Abstract: A golf ball exhibits a high spin and easily comes to a halt even when shot from the rough or when shot in a raining condition. The cover material of the golf ball is based on ionomer resin. The cover material has 5-50 parts by weight of a tackifier such as terpene resins, rosin ester resins or the like blended with respect to 100 parts by weight of the base material.
    Type: Grant
    Filed: July 6, 2000
    Date of Patent: August 19, 2003
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akira Kato, Hidenori Hiraoka, Masatoshi Yokota, Satoshi Iwami
  • Patent number: 6605236
    Abstract: A composition comprised of a composite comprised of an aromatic or heteroaromatic polymer comprised of monomer or monomers selected from the group consisting of pyrrole, indole, thiophene, thianaphthene, indene, azulene and ring pendant substitutent derivatives thereof as a discrete phase; and a block copolymer as a continuous phase selected from the group consisting of ionophoric and ionomeric copolymers, wherein the block copolymer has at least one apolar segment and at least one ion binding segment, wherein the ionomeric or ionophoric block copolymer is present in an amount from about 99 to about 50 percent by weight based on the combined weight of the block copolymer and the aromatic or heteroaromatic polymer, wherein the block copolymer provides micellar or vesicular domains for organization and polymerization of the monomer or monomers.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: August 12, 2003
    Assignee: Xerox Corporation
    Inventors: Thomas W. Smith, David J. Luca
  • Patent number: 6598637
    Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr): (a) 99 to 50 parts by weight of a first rubber containing olefinic unsaturation; and (b) 1 to 50 parts by weight of a second rubber which is different from said first rubber and which is an elastomeric block copolymer of (1) from 15 to 65 percent by weight, based on the total block copolymer, of butadiene, and (2) from 35 to 85 percent by weight, based on the total block copolymer, of styrene, which block copolymer has: (a) at least two blocks A which have polymerized units of styrene, a glass transition temperature Tg above 25° C.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: July 29, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6583223
    Abstract: A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a radically polymerizable fluoroalkyl(meth)acrylate monomer, a second block made up of residues of a second radically polymerizable ethylenically unsaturated monomer, and optionally a third block made up of residues of a third radically polymerizable ethylenically unsaturated monomer. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. Also disclosed is a method of coating a substrate including the steps of applying the present thermosetting composition to the substrate; coalescing the thermosetting composition to form a substantially continuous film; and curing said thermosetting composition by the application of heat.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: June 24, 2003
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan D. Goetz, Kurt A. Humbert, Karl F. Schimmel, Karen A. Barkac, Simion Coca, Joanne H. Smith
  • Patent number: 6576692
    Abstract: The present invention is directed to an epoxidized block copolymer composition comprising an epoxidized block copolymer (E) obtained by epoxidizing a block copolymer (C) comprising a polymer block (A) composed mainly of a vinyl aromatic hydrocarbon compound and a polymer block (B) composed mainly of a conjugated diene compound or a product (D) of hydrogenation of the block copolymer (C). The epoxidized block copolymer (E) meets at least one of the following requisites: (1) having a molar ratio (R) of contained hydroxyl to epoxy ranging from 0.001 to 0.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: June 10, 2003
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Yoshihiro Ohtsuka, Yasuhiro Oshino, Masaki Tanaka
  • Patent number: 6576707
    Abstract: The present invention provides a multi-piece solid golf ball having very good shot feel, excellent durability and excellent flight performance. The present invention relates to a multi-piece solid golf ball comprising a core, an inner cover and outer cover, wherein the inner cover has a Shore D hardness of 30 to 62, and is formed from an inner cover composition comprising (a) 50 to 95 parts by weight of ethylene-(meth)acrylic acid copolymer ionomer resin, and (b) 5 to 50 parts by weight of thermoplastic elastomer formed from a polymer alloy of an olefin with a block copolymer having styrene block, based on 100 parts by weight of a base resin; the outer cover is formed from a composition comprising ionomer resin as a main component, and has a Shore D hardness of 58 to 68; and the hardness of the outer cover is higher than that of the inner cover.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: June 10, 2003
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Keiji Ohama, Seiichiro Endo
  • Publication number: 20030100675
    Abstract: A thermosetting composition that includes a first reactant having functional groups; a second reactant having functional groups coreactive with the functional groups of the first reactant; and a block copolymer flow control agent. The block copolymer includes a first block made up of residues of a radically polymerizable fluoroalkyl (meth)acrylate monomer, a second block made up of residues of a second radically polymerizable ethylenically unsaturated monomer, and optionally a third block made up of residues of a third radically polymerizable ethylenically unsaturated monomer. The first, second and third blocks are made of different residues from each other and the block copolymer has a polydispersity index of less than 2.5. Also disclosed is a method of coating a substrate including the steps of applying the present thermosetting composition to the substrate; coalescing the thermosetting composition to form a substantially continuous film; and curing said thermosetting composition by the application of heat.
    Type: Application
    Filed: September 27, 2001
    Publication date: May 29, 2003
    Inventors: Jonathan D. Goetz, Kurt A. Humbert, Karl F. Schimmel, Karen A. Barkac, Simion Coca, Joanne H. Smith
  • Patent number: 6552126
    Abstract: Disclosed herein is a golf ball having a core and a cover comprising a blend of ionomer and plastomer. The golf ball has an impact resistance and cut resistance comparable to a ball having a non-plastomer cover and containing higher quantities of ionomer.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: April 22, 2003
    Assignee: Spalding Sports Worldwide, Inc.
    Inventors: Edward J. Kaltenbacher, Joseph Domine, Michael J. Sullivan
  • Publication number: 20030065048
    Abstract: Radiation curable adhesive comprising an epoxidized block copolymer, a saturated block copolymer and/or a rosin derived alcohol, and a photoinitiator.
    Type: Application
    Filed: June 26, 2001
    Publication date: April 3, 2003
    Inventor: Charles W. Paul
  • Patent number: 6541553
    Abstract: This invention relates to curable strippable adhesive and coating films, and also to improved high performance pressure sensitive adhesives. The adhesive comprises: (a) from 10 to 90 percent by weight of a crosslinkable epoxidized diene polymer, (b) from 0 to 70 percent by weight of a diene mono-ol polymer, with the condition that the mono-ol polymer not exceed three times the weight of the epoxidized polymer, (c) from 5 to 40 weight percent of a block copolymer of a vinyl aromatic hydrocarbon and a diene having, on average, more than one vinyl aromatic hydrocarbon block per molecule, and wherein the block copolymer can be functionalized by grafting onto it from 0.1 to 5% by weight of a carboxylic acid or anhydride, preferably maleic anhydride, (d) from 0 to 65% percent by weight of a tackifying resin, and (e) from 0.01 to 3 percent by weight of a photoinitiator.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: April 1, 2003
    Assignee: Kraton Polymers U.S. LLC
    Inventors: James Robert Erickson, David Romme Hansen
  • Publication number: 20030059906
    Abstract: The invention provides methods for the preparation of multiblock copolymers, dispersions of multiblock copolymers, vesicles and micelles containing multiblock copolymers, and oxidative degradation products of multiblock copolymers.
    Type: Application
    Filed: October 19, 2001
    Publication date: March 27, 2003
    Inventors: Jeffrey A. Hubbell, Alessandro Napoli, Nicola Tirelli
  • Patent number: 6521704
    Abstract: The present invention relates to methods to improve the dampening characteristics of compositions and the improved compositions. The compositions made by the method comprises (a) a polymer system selected from the group consisting of immiscible polymer blends, miscible polymer blends, copolymers, thermoplastic polymers and thermosetting polymers, and (b) a block copolymer comprising: (i) at least one block derived from aromatic vinyl units and (ii) at least one block derived from at least isoprene and a vinyl aromatic monomer and optionally butadiene, and having a glass transition temperature of at least 10° C. In a preferred embodiment, the block copolymer comprises at least one block of polystyrene and at least one block derived from isoprene, styrene and butadiene, and the polymer system comprises at least one polyamide resin.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: February 18, 2003
    Assignee: General Electric Company
    Inventors: Steven F. Hubbard, Sai-Pei Ting
  • Patent number: 6515072
    Abstract: A transparent rubber-modified styrenic resin composition contains a rubber-particle-dispersed phase (A) and a copolymer matrix (B). The phase (A) contains a rubbery copolymer which is a block copolymer formed from 10 to 50 wt % of styrenic monomers and 90 to 50 wt % of dienic monomers, wherein the rubbery copolymer block contains polystyrene block in an amount of 5 to 35 wt % based on total weight of the rubbery copolymer. The copolymer matrix (B) is composed of 12 to 70 parts by weight of styrenic unit, 20 to 80 parts by weight of (meth)acrylate unit, 1 to 20 parts by weight of vinyl cyanide unit, and 0 to 40 parts by weight of other copolymerizable monomer units, based on 100 parts by weight of total monomer unit. The content of the copolymer matrix (B) having a molecular weight of 3,000˜50,000 is in an amount of 15 to 50 wt %, based on the total weight of the copolymer matrix (B).
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: February 4, 2003
    Assignee: Chi Mei Corporation
    Inventor: Ray-Hsi Hsu
  • Patent number: 6509395
    Abstract: Branched polymer defoamers for pigment dispersants. The branched polymers are the reaction products of a linking agent defined by formula (I): R(Y)3  (I) wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups together represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R group to form an epoxy group, and R is an alkanetriyl group containing from 3 to 10 carbon atoms, and b) at least one compound having the formula (II) R1X(EO)n(PO)m(BO)pZ  (II) wherein R1 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 4 to 36 carbon atoms; x is —O—, —S—, or —NR2—where R2 is hydrogen or a C1-C4 alkyl group; Z is hydrogen, —NHR2 in place of a terminal —O— group wherein R2 has the meaning given above, or —SH, in which the —SH group is present in place of a terminal —O— group; n is a number of from 0 to 100, e.g.
    Type: Grant
    Filed: March 8, 2001
    Date of Patent: January 21, 2003
    Assignee: Cognis Corporation
    Inventors: Kenneth Breindel, David W. Brown
  • Patent number: 6508725
    Abstract: Golf ball compositions for use in ball covers and intermediate layers incorporate a specified block copolymer and are essentially free of ionomeric material. The compositions are outside the scope of those previously considered suitable for use in ball covers and intermediate layers. When used in ball covers, the composition provides for improved ball performance with respect to spin rate, feel, and durability. When used in ball intermediate layers, the composition provides for improved ball performance with respect to spin rate and distance. Also, a method for making a golf ball includes preparing a composition essentially free of ionomeric material including the specified block copolymer, and then incorporating the composition into a golf ball.
    Type: Grant
    Filed: April 18, 2001
    Date of Patent: January 21, 2003
    Assignee: Taylor Made Golf Company, Inc.
    Inventor: Hyun Jin Kim
  • Patent number: 6495635
    Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: December 17, 2002
    Inventor: Gerald E. Edson
  • Patent number: 6476129
    Abstract: The present invention relates to a novel thermoplastic elastomer composition with superior oil resistance along with elastomeric flexibility, creep resistance at high temperature, superior mechanical strength and moldability. The composition comprises (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two A polymer blocks comprised mainly of a vinyl aromatic compound and at least one B polymer block comprised mainly of a conjugated diene compound; and (b) 30-300 parts by weight of a partially crosslinked thermoplastic elastomer obtained by polymerizing an acrylate monomer absorbed in a polyolefin. The novel composition can be applied as a material for various molded parts.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: November 5, 2002
    Assignees: Asahi Kasei Kogyo Kabushiki Kaisha, Optatech Corporation
    Inventor: Tetsuo Masubuchi
  • Publication number: 20020147273
    Abstract: The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
    Type: Application
    Filed: December 6, 2001
    Publication date: October 10, 2002
    Inventors: Rajen M. Patel, Pak-Wing S. Chum, Stephen F. Hahn, Leonie K. Walsh, Rexford A. Maugans, Selim Bensason, Thoi H. Ho, Calvin P. Esneault
  • Patent number: 6461696
    Abstract: The present invention provides a multiple layer thermoplastic structure of a (1) skin layer selected from the group consisting of polypropylene, ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc, and ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc blended with an ethylene and a-olefin copolymers having a density less than about 0.930 g/cc, the skin layer having a thickness of greater than about 3.0 mils; (2) a radio frequency susceptible layer adhered to the skin layer, the radio frequency susceptible layer having a dielectric loss greater than 0.05 at 1-60 MHz and at temperatures of ambient to 250° C.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: October 8, 2002
    Assignee: Baxter International Inc.
    Inventors: Michael T. K. Ling, Lecon Woo, Robert Wojnarowski, Ketan Shah, Gregg Nebgen, Yuan-pang Samuel Ding, Varsha Kalyankar, Keith M. K. Anderson, Lillian G. Zakarija, Colleen S. Cramer, Michael Scharf, Larry A. Rosenbaum
  • Patent number: 6458864
    Abstract: Compounds with chain transfer groups of the formula I, II, III and IV wherein a is 1 or 2; Ar and Ar1 inter alia are phenyl; Ar2 inter alia is phenylene, these groups being unsubstituted or substituted; X is a direct bond, —O—, —S— or —N(R6)—; Y inter alia is hydrogen or C1-C12alkyl; M1 is —NR3R4 or —OH, or M1 is Ar when R1 and R2 are alkoxy, or aryloxy; R1 and R2 independently of one another e.g. are C1-C8alkyl; R3 and R4 for example are C1-C12alkyl, or together are C3-C7alkylene; R5 inter alia is C1-C6alkylene or a direct bond; R6 is for example hydrogen; and Z is a divalent radical, provided that at least one of the radicals Ar, Ar1, Ar2, R1, R2, R3, R4, R5 or Y is substituted by SH groups; are suitable for the thermal preparation of macrophotoinitiators which are polymerized photochemically to give block-copolymers.
    Type: Grant
    Filed: November 27, 2000
    Date of Patent: October 1, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Toshikage Asakura, Masaki Ohwa, Hitoshi Yamato, Asako Ito
  • Patent number: 6451458
    Abstract: An electroluminescent cell which exhibits a high luminous efficiency and excellent durability is provided. The electroluminescent material comprises a unit (AB) which is formed by alternate copolymerization of hole transfer monomers and electron transfer monomers, and a unit (A) which is formed by the polymerization of hole transfer monomers, wherein the molar ratio of the total of the structural units originating from the hole transfer monomers and the structural units originating from the electron transfer monomers in the unit (AB) and the structural units originating from the hole transfer monomers in the unit (A) is from 50:50 to 5:95. The electroluminescent cell has an anode layer 2, an electroluminescent material layer 3 made from the electroluminescent material, an electron transfer luminous layer 4, and a cathode layer 5.
    Type: Grant
    Filed: November 26, 1999
    Date of Patent: September 17, 2002
    Assignees: JSR Corporation, International Center for Materials Research, TECO Electric & Machinery Co., Ltd.
    Inventors: Mitsuhiko Sakakibara, Yasumasa Takeuchi, Ding-kuo Ding
  • Publication number: 20020115771
    Abstract: The present invention relates to a molding composition containing thermoplastic polyesters, impact-modifying component which contains anhydride groups, a copolymer of &agr;-olefin, acrylic compound, olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline and/or oxazinone, which has improved low-temperature impact strength; methods of making molding with the molding composition and molding containing the composition.
    Type: Application
    Filed: December 20, 2001
    Publication date: August 22, 2002
    Applicant: DEGUSSA AG
    Inventors: Ralf Schueler, Heinz Peirick, Guido Schmitz, Georg Oenbrink, Harald Haeger
  • Patent number: 6408593
    Abstract: A polymeric roofing shingle composition is shown which includes (a) a rubber component present in the range from about 10-95% by weight, based on the total weight of the composition and (b) a polyolefin component present in the range from about 5-50% by weight, based on the total weight of the composition. A SBR/EVA closed cell rubber composition can be formulated which has a weight of less than 150 pounds per roofing square for ⅛ inch thickness and which is flame retardant at thicknesses of ⅛ inch and higher without the addition of separate flame retardant components.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: June 25, 2002
    Inventors: Pete Foster, Donald E. Dilks
  • Publication number: 20020077419
    Abstract: There is provided a process for the continuous polymerization of polyamides which is carried out under conditions of pressure, temperature and polymer concentration in water that will ultimately yield multiple phases (including a second liquid polymer phase or a polymer precipitate). However, a single phase operation is achieved under these conditions by appropriate management of residence time and using a well-mixed reaction environment in early stages of the polymerization.
    Type: Application
    Filed: September 28, 2001
    Publication date: June 20, 2002
    Inventors: Jocelyn Willis-Papi, Turget Mutel
  • Publication number: 20020077420
    Abstract: To provide a curable composition excellent in flexibility and heat resistance. A curable composition which comprises (A) a block copolymer having at least one kind of block formed from an aliphatic hydrocarbon compound and (B) an isobutylene polymer having a silicon group bound to a hydrolyzable group or a hydroxyl group. That composition can be used as sealants, adhesives, pressure sensitive adhesives, compositions for gaskets, double layer glazing spacers and so on.
    Type: Application
    Filed: December 3, 2001
    Publication date: June 20, 2002
    Inventors: Makoto Chiba, Shintaro Komitsu
  • Patent number: 6383586
    Abstract: An adhesive composition that is specifically formulated for use in packaging medical products such as catheters between a spun-bonded polyolefin non-woven fabric and an ethylene vinyl acetate copolymer film includes from about 5 to about 65 percent by weight of a low density polyethylene; from about 35 to about 90 percent by weight of an ethylene vinyl acetate copolymers; and from about 5 to about 65 percent by weight of a linear block copolymer having at least one vinyl substituted aromatic hydrocarbon polymer block and at least one polyolefin polymer block made from an aliphatic conjugated diene.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: May 7, 2002
    Assignee: Oliver Products Company
    Inventor: Robert J. Langeland
  • Patent number: 6372845
    Abstract: A blended composition consisting of a thermoplastic olefin resin (Comp. A) with an acrylonitrile-styrene-alkyl acrylate copolymer (Comp. B) was attempted to create substitution for vinyl chloride compound prepared from vinyl chloride resin proper and a plasticizer, but resulted in inferior interdispersibility. Incorporation of an epoxy resin (Comp. C) has brought definite improvement in the interdispersibility. A resinous composition including the components A, B, and C has the utility of substitution for vinyl chloride compounds as well as its products. (Comp. C) is selected from the group consisting of epoxidized diene block copolymers including, in their molecules, a block prepared by polymerization from a vinyl aromatic monomer and another block prepared by polymerization from a conjugated diene monomer, wherein remnant diene groups after the polymerization have been epoxidized or further partially hydrogenated.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: April 16, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Yoshihiro Ohtsuka, Tohru Matsuda, Shizuo Maeda, Kouichi Ishiihara, Yoshikazu Hida
  • Publication number: 20020037962
    Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr):
    Type: Application
    Filed: July 10, 2001
    Publication date: March 28, 2002
    Inventors: Annette Lechtenbohmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6359014
    Abstract: The present invention comprises preparations of polyoxypropylene/polyoxyethylene copolymers which retain the therapeutic activity of the commercial preparations, but are substantially free from the undesirable effects which are inherent in the prior art preparations. Because the preparations of polyoxypropylene/polyoxyethylene copolymers which comprise the present invention are a less polydisperse population of molecules than the prior art polyoxypropylene/polyoxyethylene copolymers, the biological activity of the copolymers is better defined and more predictable.
    Type: Grant
    Filed: August 5, 1999
    Date of Patent: March 19, 2002
    Assignee: CytRx Corporation
    Inventors: R. Martin Emanuele, Robert L. Hunter, Paula H. Culbreth
  • Patent number: 6359066
    Abstract: The present invention provides a multi-layer structure golf ball having a thread rubber layer, which has good shot feel and controllability as well as satisfactory flight performance and cut resistance. The golf ball includes a thread wound core and a cover covering the thread wound core, wherein the cover is formed from a heated mixture of: (A) an ionomer resin, (B) a thermoplastic elastomer having a carboxyl group or a thermoplastic elastomer having a terminal OH group, and (C) a block copolymer having a styrene-butadiene-styrene structure in which the polybutadiene block contains epoxy groups, or a block copolymer having styrene-isoprene-styrene structure in which the polyisoprene block contains epoxy groups, the cover have a flexural modulus of from 50 to 300 MPa and a Shore D-scale hardness of from 40 to 60.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: March 19, 2002
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Yoshikazu Yabuki
  • Patent number: 6359065
    Abstract: A solid golf ball having good shot feel and durability as well as satisfactory flight performance and cut resistances which comprises a solid core and a cover covering the core, wherein the cover is formed from a heated mixture of: (A) an ionomer resin, (B) a thermoplastic elastomer having a carboxyl group or a thermoplastic elastomer having a terminal OH group, and (C) a block copolymer having a styrene-butadiene-styrene structure in which the polybutadiene block contains epoxy groups, or a block copolymer having styrene-isoprene-styrene structure in which the polyisoprene block contains epoxy groups, wherein the cover has a flexural modulus of from 50 to 300 MPa and a Shore D-scale hardness of from 40 to 60.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: March 19, 2002
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Yoshikazu Yabuki
  • Patent number: H2096
    Abstract: Disclosed are (1) a thermoplastic elastomeric film comprised of an elastomeric arene-diene block copolymer and particular ethylene/&bgr;-olefin copolymers having low ethylene crystallinity and (2) the process of preparing films thereof. The disclosed films have superior strength and elasticity characteristics which render them particularly useful in apparel and healthcare items such as disposable diapers.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 6, 2004
    Assignee: Exxon Chemical Patents, I
    Inventors: Thomas Craig Erderly, John Hugh MacKay, Russell Harrel Narramore