Mixture Contains Solid Polymer Derived From Reactant Containing Chalcogen Patents (Class 525/93)
  • Publication number: 20020004571
    Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Application
    Filed: May 14, 2001
    Publication date: January 10, 2002
    Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
  • Publication number: 20020004558
    Abstract: The present invention relates to a novel thermoplastic elastomer composition with superior oil resistance along with elastomeric flexibility, creep resistance at high temperature, superior mechanical strength and moldability. The composition comprises (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two A polymer blocks comprised mainly of a vinyl aromatic compound and at least one B polymer block comprised mainly of a conjugated diene compound; and (b) 30-300 parts by weight of a partially crosslinked thermoplastic elastomer obtained by polymerizing an acrylate monomer absorbed in a polyolefin. The novel composition can be applied as a material for various molded parts.
    Type: Application
    Filed: May 27, 1998
    Publication date: January 10, 2002
    Inventor: TETSUO MASUBUCHI
  • Patent number: 6334820
    Abstract: The present invention provides a solid golf ball having the improved shot feeling without damaging the durability and good carry. The solid golf ball has an intermediate layer between a core and a cover layer. The intermediate layer is a cured body of a thermoplastic resin composition including components (a) and (b). The component (a) is selected from a group consisting of a first block copolymer including at least one polymer block A of an aromatic vinyl compound and at least one polymer block B of a conjugated diene compound, and a second block copolymer obtained by hydrogenating said first block copolymer. The component (b) consisting of ionomer.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: January 1, 2002
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Takashi Sasaki
  • Patent number: 6326084
    Abstract: The invention relates to a method of high frequency welding of non-polar thermoplastic elastomers characterized in that said elastomers comprise a polar modifier. Furthermore, the invention relates to shaped articles obtainable by said method.
    Type: Grant
    Filed: April 21, 1998
    Date of Patent: December 4, 2001
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Trazollah Ouhadi, Jacques Horrion, Ernst Van Issum
  • Patent number: 6262175
    Abstract: A thermoplastic elastomer composition containing in percentages by weight based on the total weight of the composition, about 5% to about 90% vulcanized rubber crumb; about 5% to about 60% polyolefin; about 2% to about 30% uncured rubber or styrene-based thermoplastic elastomer; and about 2% to about 30% vinyl polymer selected from vinyl homopolymers, copolymers and mixtures. The composition in total contains less than 15% styrene block copolymer.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: July 17, 2001
    Assignee: NRI Technology Inc.
    Inventors: James R. Jury, Alfred Wing Yan Chien
  • Patent number: 6261655
    Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency (“RF”) susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent wherein the radio frequency susceptible polymer is selected from the group consisting of ethylene acrylic acid copolymers, ethylene methacrylic acid copolymers, polyimides, polyurethanes, polyesters, and polyureas.
    Type: Grant
    Filed: June 17, 1999
    Date of Patent: July 17, 2001
    Assignee: Baxter International Inc.
    Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T. K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 6228940
    Abstract: A game ball comprising an ionomeric cover which includes a combination of ionomeric crosslinks and radiation induced covalent crosslinks. The game ball cover may include non-ionomeric materials. The game ball cover is superior in at least one of cut resistance and scuff resistance to a conventional cover that does not have the covalent crosslinks but is otherwise substantially identical in composition. The game ball cover of the invention is particularly useful for improving the durability of golf balls to be struck with sharp-grooved clubs.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: May 8, 2001
    Assignee: Spalding Sports Worldwide, Inc.
    Inventors: Michael J. Sullivan, Thomas J. Kennedy, III, R. Dennis Nesbitt, Mark L. Binette
  • Patent number: 6221991
    Abstract: Polar polymers having the following formula: FG-(Q)d-Rn-Z-J-[A(R1R2R3)]x   (I) wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitrites of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: April 24, 2001
    Assignee: FMC Corporation
    Inventors: Robert J. Letchford, James A. Schwindeman, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 6201065
    Abstract: Gel-forming macromers including at least four polymeric blocks, at least two of which are hydrophobic and at least one of which is hydrophilic, and including a crosslinkable group are provided. The macromers can be covalently crosslinked to form a gel on a tissue surface in vivo. The gels formed from the macromers have a combination of properties including thermosensitivity and lipophilicity, and are useful in a variety of medical applications including drug delivery and tissue coating.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: March 13, 2001
    Assignee: Focal, Inc.
    Inventors: Chandrashekhar P. Pathak, Shikha P. Barman, C. Michael Philbrook, Amarpreet S. Sawhney, Arthur J. Coury, Luis Z. Avila, Mark T. Kieras
  • Patent number: 6191229
    Abstract: The present invention provides (meth)acryl syrup which shows excellent storage stability as a molding material, and also provides a method of manufacturing the (meth)acryl syrup in a shorter period of time compared with the conventional method, and a molding material which permits a molded article having excellent heat-resistance, solvent-resistance, weathering resistance, and water-resistance, etc., to be manufactured. The (meth)acryl syrup is manufactured, for example, by polymerizing a monomer component including (meth)acrylic ester and a vinyl monomer having a carboxyl group in a presence of a thiol compound, and subsequently processing the reaction mixture with maleic anhydride and a basic compound. The molding material includes the (meth)acryl syrup, and may also include a thickening agent, derivatives of succinic acid, a reinforcing material, etc.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: February 20, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Masazumi Sasabe, Akihiko Fukada, Keiichiro Mizuta
  • Patent number: 6187854
    Abstract: A pigment dispersion useful for forming coating compositions containing dispersed pigment, a carrier liquid and an AB-block polymer dispersant (binder); the AB block polymer has a number average molecular weight of about 5,000-20,000 and contains 20-80% by weight of a polymeric A segment and correspondingly 80-20% by weight of a polymeric B segment; wherein the polymeric A segment of the block polymer is of polymerized glycidyl (meth)acrylate monomers reacted with an acid from the group of aromatic carboxylic acids or aliphatic carboxylic acids; and the B segment is of polymerized alkyl (meth)acrylate monomers having 1-12 carbon atoms in the alkyl group, hydroxy alkyl (meth)acrylate monomers having about 1-4 carbon atoms in the alkyl group; and wherein the weight ratio of pigment to binder in the dispersion is about 1/100-200/100.
    Type: Grant
    Filed: August 19, 1998
    Date of Patent: February 13, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Harry J. Spinelli, Henry L. Jakubauskas, Patrick F. McIntyre, James G. King
  • Patent number: 6172180
    Abstract: The present invention relates to a block copolymer containing 1-50 first polymer segments and 1-50 second polymer segments. Each first polymer segment has an average mole fraction of monomers possessing a branch point of 0.0001 to 1, whereas each second polymer segment has an average mole fraction of monomers possessing a branch point of 0 to 0.5. The average molecular weights range from 5-2,000 kDa for the first polymer segments, which constitute 5-95% by weight of the block copolymer. The average molecular weights also range from 5-2,000 kDa for the second polymer segments, which constitute 5-95% by weight of the block copolymer. The ratio of the average mole fraction of monomers possessing a branch point of the second polymer segments to that of the first polymer segments is 0 to 0.5. An example of such a copolymer has ethylene oxide or ethylene oxide/propylene oxide as the first polymer segment and polysulfone as the second polymer segment. This block copolymer can further be blended with a bulk polymer.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: January 9, 2001
    Assignee: Circe Biomedical, Inc.
    Inventors: Lawrence F. Hancock, Stephen M. Fagan, Claudy J.-P. Mullon
  • Patent number: 6168862
    Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency (“RF”) susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: January 2, 2001
    Assignee: Baxter International Inc.
    Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T. K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 6162866
    Abstract: Thermoplastic molding compositions comprise:______________________________________ A) from 20 to 96% by weight of star polymers obtainable by polymerizing vinylaromatic monomers with a branched monomer building block which contains at least two vinylaromatic functions, B) from 3 to 50% by weight of copolymers comprising vinylaromatic monomers, 1,1-diphenylethylene and, if desired, dienes, C) from 1 to 15% by weight of polyarylene ethers, D) from 0 to 5% by weight of nucleating agents, E) from 0 to 5% by weight of antioxidants, F) from 0 to 5% by weight of stabilizers, and G) from 0 to 50% by weight of fibrous or particulate fillers.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: December 19, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Josef Wunsch, Konrad Knoll, Hermann Gausepohl
  • Patent number: 6143826
    Abstract: A polymer blend comprising:(A) an acrylic resin;(B) a block copolymer consisting essentially of a polymer block of a polymerized aromatic vinyl compound and/or a polymer block of a polymerized methacrylate monoester and a polyolefin polymer block; and(C) a polymer miscible with the acrylic resin (A) and immiscible with the block copolymer (B),wherein the absolute value (.vertline..eta..sub.AC -.eta..sub.B .vertline.) of the difference between the refractive index (.eta..sub.AC) of the blend of the acrylic resin (A) and the polymer (C) and the refractive index (.eta..sub.B) of the block copolymer (B) is 0.01 or less. This polymer block has excellent transparency, softness and other properties.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: November 7, 2000
    Assignee: Kuraray Co., Ltd.
    Inventors: Takashi Ohnaga, Katsunori Takamoto, Yukihiro Fujieda, Katsuei Takahashi, Kenichi Hamada
  • Patent number: 6133363
    Abstract: The invention relates to a method of manufacturing dispersions of water-sble cationic vinyl polymers which can be used as process aids for separation processes, e.g. as flocculation aids, coagulation agents, retention agents or dehydration accelerators. The dispersions are produced by radical homopolymerization of cationic, hydrophobically modified vinyl monomers or their copolymerization with water-soluble vinyl monomers in aqueous saline solutions. In this respect block copolymers are used as dispersion stabilizers, and which are formed from a cationic vinyl monomer and ethyleneoxide.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: October 17, 2000
    Assignee: Fraunhofer-Gesellschaft zur Foerderung der Angewandten Forschung E.V.
    Inventors: Werner Jaeger, Arvid Zimmermann, Karl-Heinz Reichert, Katrin Zeitz
  • Patent number: 6127507
    Abstract: A composition comprising in admixture with a polymer, preferably a polyurethane, and a compatible surface-modifying macromolecule having (i) a central portion of a segmented block oligomeric copolymer comprising at least one polar hard segment, and (ii) .varies.-.omega. terminal polyfluoro oligomeric groups, in a surface modifying enhancing amount. The composition is of use in providing articles having improved surface properties, particularly, medical devices having improved resistance to enzyme degradation with acceptable blood compatibility.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: October 3, 2000
    Inventor: Paul J. Santerre
  • Patent number: 6096435
    Abstract: A thermoplastic polymer composition is provided that includes 100 parts by weight of a block copolymer and/or its hydrogenate having polymer blocks of an aromatic vinyl compound and polymer blocks of a conjugated diene compound, and from 5 to 95 parts by weight of a block copolymer having polymer blocks of an aromatic vinyl compound and/or an olefinic compound and polymer blocks having a constitutional unit derived from a (meth) acrylic compound, a laminate containing a layer of the composition, and a hot-melt adhesive that includes the composition. Because it has good melt adhesiveness, the composition of the invention can firmly adhere in melt to various polar or non-polar materials. Using the composition, it is easy to produce laminates having a layer of the composition and a layer of some other material, through melt shaping or any other melt adhesion techniques.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: August 1, 2000
    Assignee: Kuraray Co., Ltd.
    Inventors: Kazuhiko Maekawa, Masanari Uno, Atsushi Itoh, Hiroshi Hayashihara, Kazushige Ishiura, Shigeru Kawahara, Shiroh Kishii
  • Patent number: 6087435
    Abstract: A polystyrene-based resin composition, comprising (A) a styrene-based resin with a mainly syndiotactic configuration, (B) a polyolefin, and (C) rubber polymer particles as main components, exhibits excellent heat resistance and impact resistance.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: July 11, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6051655
    Abstract: A composition amenable to injection molding and extrusion comprises a syndiotactic styrene resin, a thermoplastic resin such as a polyolefin and an inorganic filler optionally contains a rubber.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 18, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6046275
    Abstract: A composition comprises (A) a syndiotactic styrene-based resin and (C) rubber polymer particles such as graft copolymers, butadiene or isoprene block copolymers optionally hydrogenated and/or modified with maleic anhydride, and other rubbers, and, optionally, (B) a thermoplastic resin such as a polycarbonate, and/or (D) a filler such as glass fibers.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: April 4, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
  • Patent number: 6046274
    Abstract: The invention relates to a flexible composition comprising a vinyl chloride polymer and a block copolymer. The latter comprises a poly(ethylene oxide) block and a block of a polymer which is miscible with the vinyl chloride polymer, other than the latter itself. The invention also relates to a poly(ethylene oxide)/poly-.epsilon.-caprolactone diblock copolymer which can be used in this composition, as well as to the use of this composition for the manufacture of an article and to an article comprising this composition.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: April 4, 2000
    Assignee: Solvay (Societe Anonyme)
    Inventors: Dominique Grandjean, Zdenek Hruska, Danny Van Hoyweghen, Henri Wautier
  • Patent number: 5998019
    Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency ("RF") susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: December 7, 1999
    Assignee: Baxter International Inc.
    Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T.K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 5989723
    Abstract: A conductive polyester-based alloy sheet having three layers laminated together by co-extrusion, which comprises one substrate layer and two surface layers, wherein the surface layers are conductive and comprise polyester, acrylonitrile-butadiene-styrene (abbreviated as ABS) and/or polystyrene (abbreviated as PS), a compatibilizer, and a toughening agent, wherein the surface layers have a surface conductivity of not more than 10.sup.8 ohms. The melt flow index of the material for the conductive layers during the extrusion step is not less than 5.0 g/min (loading, 10 Kg; temperature, 250.degree. C.). The substrate layer is made from acrylonitrile-butadiene-styrene and/or polystyrene.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: November 23, 1999
    Assignee: Far Eastern Textile Ltd.
    Inventors: Tsan Hung Tsai, Rong Shiun Pan, Cheng Chung Wu, Yuan Hwey Hsu, Jen Hao Wei, Shung Mine Hong
  • Patent number: 5990241
    Abstract: The present invention comprises novel preparations of polyoxypropylene/polyoxyethylene copolymers which retain the therapeutic activity of the commercial preparations, but are substantially free from the undesirable effects which are inherent in the prior art preparations. Because the preparations of polyoxypropylene/polyoxyethylene copolymers which comprise the present invention are a less polydisperse population of molecules than the prior art polyoxypropylene/polyoxyethylene copolymers, the biological activity of the copolymers is better defined and more predictable.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: November 23, 1999
    Assignee: CytRx, Corporation
    Inventors: R. Martin Emanuele, Robert L. Hunter, Paula H. Culbreth
  • Patent number: 5959009
    Abstract: The invention relates to waterproof or water resistant compositions for application to the lashes comprising a styrene-ethylene-propylene copolymer as gellant, a film forming agent, and a volatile oil.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: September 28, 1999
    Assignee: E-L Management Corp
    Inventors: Richard A. Konik, Rachel J. Painter, George J. Stepniewski
  • Patent number: 5948862
    Abstract: The present invention provides a multi-piece solid golf ball having good shot feel, while keeping the characteristics inherent to the solid golf ball, i.e. excellent flight performance. The present invention related to a multi-piece solid golf ball comprising a core, one or more intermediate layers formed on the core, and a cover covering the intermediate layer, wherein at least one of the intermediate layer is mainly composed of a heated mixture comprising at least two materials selected from the following three materials:(A) ionomer resin,(B) thermoplastic elastomer having terminal OH groups, and(C) either epoxy-group containing styrene-butadiene-styrene block copolymer or epoxy-group containing styrene-isoprene-styrene block copolymer, and the intermediate layer has a JIS-C hardness of 40 to 80, and the core has a JIS-C hardness difference ranging from its center to the surface of not more than 15.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: September 7, 1999
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Yoshinori Sano, Keiji Moriyama
  • Patent number: 5945481
    Abstract: A case for memory disks having excellent antistatic properties, which comprises a thermoplastic resin composition comprising 100 parts by weight of the following component (A), 3 to 30 parts by weight of the following component (B) and 5 to 40 parts by weight of the following component (C):component (A): a crystalline propylene resin having a melt flow rate (MFR) of 1 to 80 g/10 min;component (B): a thermoplastic elastomer selected from (b.sup.1) olefin copolymer elastomers having a Mooney viscosity (ML.sub.1+4 (100.degree. C.)) of 10 to 85, and (b.sup.2) hydrogenated products of a block copolymer of styrene or a derivative thereof and a conjugated diene, containing 15 to 50% by weight of styrene or a derivative thereof, having a weight-average molecular weight of 50,000 to 220,000; andcomponent (C): an acrylamide copolymer.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: August 31, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toshikazu Mizutani, Jichio Deguchi
  • Patent number: 5929151
    Abstract: A polyketone composition having improved processability consisting of a polyketone, a thermosettable epoxy resin and a curing agent sufficient to cure the epoxy resin when exposed to processing temperatures such as injection molding to form a finished article. When the composition is exposed to processing temperatures to form a finished article, the article consists of a continuous polyketone phase having dispersed therein cured particles of epoxy resin.
    Type: Grant
    Filed: October 30, 1997
    Date of Patent: July 27, 1999
    Inventors: Gerrijt De Wit, Hendricus F. Zirkzee
  • Patent number: 5910542
    Abstract: Pressure sensitive structural adhesive and sealant compositions comprising: (a) a polymer system comprising from 95 to 15 percent by weight of a telechelic polymer and from 5 to 85 percent by weight of a heterotelechelic polymer wherein at least one of the functionalities thereon is the same as the functionality on the telechelic polymer, and (b) a dual curing system wherein one element of the curing system cures the telechelic polymer and the common functionality on the heterotelechelic polymer and the other element cures the functionality on the heterotelechelic polymer but does not cure under the conditions required to cure the telechelic polymer to form a structural adhesive or sealant composition. In a preferred embodiment, the polymer system is comprised of a hydroxyl functional telechelic diol or polyol polymer and the heterotelechelic polymer is a monohydroxylated polydiene polymer which also has epoxidized olefin functionality.
    Type: Grant
    Filed: May 13, 1998
    Date of Patent: June 8, 1999
    Assignee: Shell Oil Company
    Inventors: David John St. Clair, James Robert Erickson
  • Patent number: 5900464
    Abstract: Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; ?A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: May 4, 1999
    Assignee: FMC Corporation
    Inventors: Robert J. Letchford, James A. Schwindeman, Conrad W. Kamienski, Roderic P. Quirk
  • Patent number: 5889118
    Abstract: A thermomorphic pressure sensitive adhesive is provided. The adhesive includes a continuous crystalline polymer component and a discrete crosslinked elastomeric polymer component. The pressure sensitive adhesive has at least one distinct crystalline melting point and is capable of transitioning between a secondary shape and a primary shape upon an increase in temperature.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: March 30, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Joaquin Delgado, Spencer F. Silver
  • Patent number: 5872185
    Abstract: In a golf ball comprising a core, an intermediate layer, and a cover, the intermediate layer is formed of a resin component consisting essentially of 10-60 parts by weight of a thermoplastic elastomer having a crystalline polyethylene block and 90-40 parts by weight of an ionomer resin having a melt index of 3-20 g/10 min. at 190.degree. C. The resin component is easily moldable into a highly resilient intermediate layer. The ball has improved flight performance, durability and feel.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: February 16, 1999
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yasushi Ichikawa, Hisashi Yamagishi, Hiroshi Higuchi, Shunichi Kashiwagi
  • Patent number: 5837749
    Abstract: The invention herein is curable adhesive and sealant compositions and a non-aqueous solvent free process for producing such compositions which comprise a mono-ol, tackifying resin, and a monohydroxylated epoxidized polydiene polymer which is comprised of at least two polymerizable ethylenically unsaturated hydrocarbon monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation and wherein the polymer contains from 0.1 to 7.0 milliequivalents of epoxy per gram of polymer. The process involves mixing the components together with a photoinitiator which is selected from the group consisting of diaryl, especially diaryliodonium, salts characterized by the general formula: ##STR1## where Y is ##STR2## where R is hydrogen, aryl, alkyl, or an alkylhalide; n is an integer of at least 1, Z is I, Cl, or Br, preferably I, and X is a complex metal halide anion or a complex halide anion of a strong protonic acid.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: November 17, 1998
    Assignee: Shell Oil Company
    Inventors: James Robert Erickson, James Crivello
  • Patent number: 5834559
    Abstract: A thermoplastic resin composition having excellent antistatic properties comprising 100 parts by weight of the following component (A), 3 to 30 parts by weight of the following component (B) and 5 to 40 parts by weight of the following component (C): component (A): a crystalline propylene resin having a melt flow rate (MFR) of 1 to 80 g/10 min; component (B): a thermoplastic elastomer selected from (b.sup.1) olefin copolymer elastomers having a Mooney viscosity (ML.sub.1+4 (100.degree. C.)) of 10 to 85, and (b.sup.2) hydrogenated products of a block copolymer of styrene or a derivative thereof and a conjugated diene, containing 15 to 50% by weight of styrene or a derivative thereof, having a weight-average molecular weight of 50,000 to 220,000; and component (C): an acrylamide copolymer.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: November 10, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Jichio Deguchi, Toshikazu Mizutani
  • Patent number: 5824740
    Abstract: Disclosed is a golf ball having good shot feel and controllability as well as satisfactory flight performance and cut resistance. The golf ball has a core and a cover for covering the core, wherein said cover has a stiffness modulus of 100 to 250 MPa and comprises a heated mixture of an ionomer resin and a glycidyl group-modified styrene-based block copolymer having a JIS-A hardness of 30 to 90 as base resin, and optionally a maleic anhydride-modified olefin copolymer.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: October 20, 1998
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Yoshikazu Yabuki, Yoshinori Sano, Hiroaki Tanaka
  • Patent number: 5824751
    Abstract: The biodegradable composition comprises at least poly(beta-hydroxybutyric acid) or a biodegradable copolymer thereof and a stereospecifically regular block copolymer having the structure units of formula (I): ##STR1## where R1 is a hydrocarbon group having 1 to 14 carbon atoms, optionally including double bonds, oxygen atoms or both of them; and m and n are respectively an integer ranging from 300 to 5,000, or having the structure units of formula (II): ##STR2## where R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are either a hydrogen atom or a methyl group; and m and n are respectively an integer ranging from 300 to 5,000.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: October 20, 1998
    Assignee: Takasago Koryo Kogyo Kabushiki Kaisha (Takasago International Corporation)
    Inventors: Yoji Hori, Yoko Takahashi, Hideyuki Hongo, Akio Yamaguchi, Toshimitsu Hagiwara
  • Patent number: 5814705
    Abstract: The present invention provides a composition that softens at a predetermined temperature, preferably between about 20.degree. C. and 90.degree. C., and more preferably between about 20.degree. C. and about 62.degree. C., comprising at least one block copolymer having at least two thermal transition temperatures. The composition is characterized by at least two thermal transition temperatures, one of which is a predetermined lower transition temperature, preferably between about 20.degree. C. to 90.degree. C., and more preferably between about 20.degree. C. to about 62.degree. C., and one of which is an upper transition temperature. The present invention also provides a method of making the composition, a method of making biomedical materials and articles, and toys and toy components, with shape-memory properties from the composition, and biomedical materials and articles, and toys and toy components, with shape-memory properties made from the composition.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 29, 1998
    Assignee: Thoratec Laboratories Corporation
    Inventors: Robert S. Ward, Judy S. Riffle
  • Patent number: 5804657
    Abstract: Pressure sensitive structural adhesive and sealant compositions comprising: (a) a polymer system comprising from 95 to 15 percent by weight of a telechelic polymer and from 5 to 85 percent by weight of a heterotelechelic polymer wherein at least one of the functionalities thereon is the same as the functionality on the telechelic polymer, and (b) a dual curing system wherein one element of the curing system cures the telechelic polymer and the common functionality on the heterotelechelic polymer and the other element cures the functionality on the heterotelechelic polymer but does not cure under the conditions required to cure the telechelic polymer to form a structural adhesive or sealant composition. In a preferred embodiment, the polymer system is comprised of a hydroxyl functional telechelic diol or polyol polymer and the heterotelechelic polymer is a monohydroxylated polydiene polymer which also has epoxidized olefin functionality.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: September 8, 1998
    Assignee: Shell Oil Company
    Inventors: David John St. Clair, James Robert Erickson
  • Patent number: 5777028
    Abstract: The present invention relates to an impact resistant polystyrene composition which comprises 5 to 97% by weight of an (a) styrenic polymer having syndiotactic configuration, 2 to 95% by weight of a (b) rubbery elastomer having an olefinic component or a polyolefin, and 0.5 to 10% by weight of a (c) styrene/olefin block or graft copolymer having a micro-phase separation temperature of 180.degree. C. at the highest when diluted with dioctyl phthalate to a solution with a concentration of 60% by weight; according to the present invention, an impact resistant polystyrene composition can be provided which is greatly enhanced in impact resistance and extensibility without impairing heat resistance and modulus of elasticity.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: July 7, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akihiko Okada, Nobuyuki Sato
  • Patent number: 5777030
    Abstract: A polymer blend composition comprising (A) a monovinylarene/conjugated diene block copolymer, and (B) a styrenic polymer of styrene/methyl methacrylate is provided. A process for preparing the composition and articles prepared from the composition are also provided.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: July 7, 1998
    Assignee: Phillips Petroleum Company
    Inventors: Mark D. Hanes, William H. Beever, David L. Hartsock
  • Patent number: 5756589
    Abstract: The present invention relates to a rubber composition containing substantial silica reinforcement and pneumatic tires having treads comprised of such rubber composition. The rubber composition comprises an elastomer, substantial silica reinforcement, optionally a minor amount of carbon black reinforcement, and a triblock copolymer of terminal hard styrene based segments and of internal diene based elastomer segments.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: May 26, 1998
    Assignee: Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, David John Zanzig, Mark Samuel Sinsky
  • Patent number: 5733964
    Abstract: Heterogeneous polymer mixtures comprising a polymer in liquid or supercritical CO.sub.2 are stabilized by employing a poly(propylene oxide) or poly(butylene oxide) based surfactant. These surfactants are especially well suited for stabilizing heterogeneous polymer mixtures formed by micronizing techniques as well as by precipitation of a compressed fluid antisolvent applications.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: March 31, 1998
    Assignees: Board of Regents, The University of Texas System, Air Products and Chemicals, Inc.
    Inventors: Keith P. Johnston, Steven Paul Wilkinson, Mark Leonard O'Neill, Lloyd Mahlon Robeson, Simon Mawson, Richard Henry Bott, Carrington Duane Smith
  • Patent number: 5721322
    Abstract: The specification discloses a method and additive for increasing the surface activity of non-polar polymeric materials, and a non-polar polymeric material exhibiting increased surface activity. The invention employs an additive of the formulaA-B-A.sup.1wherein each of the A and A.sup.1 blocks which may be the same or different has a number molecular weight in the range of from about 200 to about 1000 daltons and is selected from the group substituted and unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and alkylaryl units derived from one or more esters, organic acids, organic halides or organic acid halides, and units derived from alkyl or aryl isocyanates or ester-amides. The B-block is a polyepichlorohydrin unit derived from a polyepichlorohydrin polyol having at least two terminal hydroxyl groups and having an average molecular weight in the range of from about 400 to about 4000 daltons.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: February 24, 1998
    Assignee: Arizona Chemical Company
    Inventors: Xinya Lu, Eric S. Gardiner
  • Patent number: 5693711
    Abstract: There is disclosed a resin composition which comprises:(a) an .alpha.-olefin/unsaturated carboxylic acid copolymer type ionomeric resin; and(b) a block copolymer having at least one polymer block A comprising an aromatic vinyl compound and at least one polymer block B comprising a conjugated diene compound, and having a hydroxyl group at the terminal of the block copolymer, or a hydrogenated product thereof.
    Type: Grant
    Filed: October 29, 1996
    Date of Patent: December 2, 1997
    Assignee: Kuraray Co., Ltd.
    Inventors: Isamu Akiba, Hiromichi Nakata, Shiroh Kishii, Atsushi Ohishi, Masao Ishii
  • Patent number: 5691414
    Abstract: The invention herein is a solvent free process for producing UV curable adhesive and sealant compositions comprising a monool, tackifying resin, and a monohydroxylated epoxidized polydiene polymer which is comprised of at least two polymerizable ethenically unsaturated hydrocarbon monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation and wherein the polymer contains from 0.1 to 7.0 milliequivalents of epoxy per gram of polymer. The process involves predispersing an insoluble photoinitiator in a component of the formulation with which it is more compatible than with the tackifying resin, and then adding the tackifying resin to the predispersion.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: November 25, 1997
    Assignee: Shell Oil Company
    Inventors: Kathleen Suzanne Kiibler, Jeffrey George Southwick
  • Patent number: 5686527
    Abstract: Multiple component polymer compositions for fabrication into articles. In particular, polymeric compositions comprising a heat resistant polymer; a radio frequency ("RF") susceptible polymer; a compatibilizing polymer; the composition having physical properties within the range a<40,000 psi; b>=70%; c<30%; d>1.0; e<0.1%; f<0.1%; g>=0.05; h<=60%; i=0; wherein: a is the mechanical modulus of the composition measured according to ASTM D-882; b is the percent recovery in length of the composition after an initial 20% deformation; c is the optical haze of the composition being 9 mils in thickness according to ASTM D-1003; d is the loss tangent of the composition at 1 Hz measured at melt processing temperatures; e is the elemental halogen content by weight of the composition; f is the low molecular weight water soluble fraction of the composition; g is the dielectric loss between 1 and 60 MHz and over temperatures of 25.degree. to 250.degree. C.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: November 11, 1997
    Assignee: Baxter International Inc.
    Inventors: Dean Laurin, Angeles Lillian Buan, Lecon Woo, Michael T. K. Ling, Yuan Pang Samuel Ding, William Anderson, Larry A. Rosenbaum, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
  • Patent number: 5684082
    Abstract: There is disclosed a method for adhering rubber to reinforcing materials which comprises embedding a textile fiber or metal reinforcing material in a vulcanizable rubber composition comprising rubber, a vulcanizing agent, reinforcement, a methylene donor, a methylene acceptor and a maleic anhydride functionalized triblock copolymer having polystyrene endblocks and poly-(ethylene/butylene) midblocks.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: November 4, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Thomas Joseph Segatta
  • Patent number: 5656687
    Abstract: There is disclosed a method for adhering rubber to reinforcing materials which comprises embedding a textile fiber or metal reinforcing material in a vulcanizable rubber composition comprising rubber, a vulcanizing agent, reinforcement, a methylene donor, a methylene acceptor and a maleic anhydride functionalized triblock copolymer having polystyrene endblocks and poly-(ethylene/butylene) midblocks.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: August 12, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Thomas Joseph Segatta
  • Patent number: 5616625
    Abstract: A process for foaming polyurethane reactive hot melt adhesive comprising the steps of:a) melting a reactive polyurethane adhesive containing 0.05 to 0.5% by weight of a 2,2'dimorpholinodiethyl ether or di(2,6-dimethylmorpholinodiethyl)ether catalyst in a heated reservoirb) pumping the adhesive from the heated into a heated reservoir recirculating foaming device;c) foaming the adhesive by injecting therein an effective amount of an anhydrous gas;d) discharging a portion of the foamed adhesive through an orifice onto a substrate to be bonded; ande) recirculating the remaining foamed adhesive back to the foaming device for discharge at a later time.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: April 1, 1997
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Ju-Ming Hung, James W. Nowicki