Mixture Contains Solid Block Or Block-type Copolymer Derived From Ethylenically Unsaturated Hydrocarbon Reactants Only At Least One Of Which Contains At Least Four Carbon Atoms Patents (Class 525/95)
  • Patent number: 4256234
    Abstract: Container closure having an easily openable liner, said liner being composed of a composition comprising a base resin consisting of 95 to 30% by weight of a crystalline polyolefin and 5 to 70% by weight of a lowly crystalline or amorphous copolymer of ethylene with otherolefin, a lubricant in an amount of 0.001 to 5% by weight based on said base resin and a polymer containing at least 10% by weight of a conjugated diene in an amount of 1 to 15% by weight based on said base resin. This closure has a good sealing property and an easy openability in combination.
    Type: Grant
    Filed: November 30, 1978
    Date of Patent: March 17, 1981
    Assignee: Japan Crown Cork Co. Ltd.
    Inventors: Fumio Mori, Junichi Itsubo, Gunji Matsuda, Shigeru Nagashima, Kozo Nakamura
  • Patent number: 4250273
    Abstract: Thermoplastic elastomer compositions of the present invention comprise a blend of from about 10 to about 50 parts by weight of a crystalline 1-olefin polymer, from about 80 to about 15 parts by weight of a styrene-butadiene rubber, and from about 5 to about 55 parts by weight of a highly saturated elastomer. The thermoplastic blends have very good physical properties, especially tear strength, tensile strength, elongation at break, low temperature impact resistance, minimum creep at high temperatures, and smooth surfaces when injection molded. The compositions, which may be partially cured, also have excellent aging properties, as well as paint adhesion. The compositions are a true thermoplastic in that they can be repeatedly processed and yet maintain their good physical properties.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: February 10, 1981
    Assignee: The Firestone Tire & Rubber Company
    Inventors: Georg G. A. Bohm, Gary R. Hamed, Lee E. Vescelius
  • Patent number: 4247661
    Abstract: Certain thermoplastic blends have substantially improved hot strength (i.e., cohesive strength and resistance to sagging or tearing during milling or other hot processing). The blends comprise (1) at least one ethylene-propylene (EP) or ethylene-propylene-diene (EPDM) polymer and (2) at least one highly crystalline polyallomer, and are useful for tubing, wire and cable insulation, molded items and the like.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: January 27, 1981
    Assignee: The B. F. Goodrich Company
    Inventors: Richard M. Herman, Martin Batiuk
  • Patent number: 4242402
    Abstract: A normally nontacky but potentially tacky adhesive lift-off tape which comprises an adhesive film composition which normally exhibits a plastic nontacky state but is convertible to an elastomeric tacky state by the application of substantial stress, i.e., stretching sufficiently or striking with typewriter type, as well as the process of applying the said adhesive film. This film composition consists essentially of thermoplastic and elastomeric A-B block copolymers wherein the A-blocks are thermoplastic and the B-blocks are elastomeric and about 20-120 parts per one hundred parts by weight of the block copolymers of certain normally solid resins adapted to associate principally with the thermoplastic A-blocks of said copolymers. In these copolymers the A-blocks are derived from styrene or styrene homologues and the B-blocks are derived from conjugated dienes or lower alkenes.
    Type: Grant
    Filed: April 2, 1979
    Date of Patent: December 30, 1980
    Assignee: Johnson & Johnson
    Inventor: Ralf Korpman
  • Patent number: 4210686
    Abstract: A multiple-layered, autoclavable, flexible plastic sheet comprises (a) at least one first layer consisting essentially of 30 to 90 percent by weight of a block copolymer having thermoplastic rubbery characteristics and having rubbery olefin blocks and blocks of a polystyrene; and from 10 to 70 percent by weight of a polyolefin derived principally from at least one of propylene, ethylene and 4-methylpentene-1, said polyolefin having a Vicat Softening Temperature of about 120.degree. C.; and (b) at least one second layer consisting essentially of a polyolefin derived principally by from at least one of propylene, ethylene, and 4-methylpentene-1 and being of semi-crystalline characteristics to exhibit low permeability to water vapor, the first and second layers being bonded together in alternating arrangement.
    Type: Grant
    Filed: June 19, 1978
    Date of Patent: July 1, 1980
    Assignee: Baxter Travenol Laboratories Inc.
    Inventors: Henry Gajewski, Dean G. Laurin, Paul Measells, R. Daniel Webster
  • Patent number: 4201834
    Abstract: A non-tacky powder composition useful for coating applications is disclosed. A method of preparing the non-tacky powder composition is also disclosed. This powder composition comprises tacky powder particles and, adhering to the tacky surface of these tacky powder particles in a non-continuous layer, smaller solid particles which are hard and non-tacky. The tacky powder particles comprise a melt blend mixture of a thermoplastic elastomer and a specifically defined melt flow modifier. The smaller solid particles which are hard and non-tacky comprise a specifically defined melt flow modifier which has a glass transistion temperature greater than about 20.degree. C. The final powder composition is non-tacky and is particularly useful in coating glass containers. A process for coating substrates such as a glass container with this composition, as well as the coated glass container, is also disclosed.
    Type: Grant
    Filed: December 5, 1978
    Date of Patent: May 6, 1980
    Assignee: Celanese Corporation
    Inventors: Martin J. Hannon, Richard K. Greene
  • Patent number: 4198983
    Abstract: A catheter, preferably a balloon-type catheter, is disclosed in which the catheter shaft is made of a thermoplastic material and thus may be extrudable, the shaft consisting essentially of (a) from 40 to 70 percent by weight of an elastic composition which comprises: from 50 to 99.5 percent by weight of a block copolymer having thermoplastic rubber characteristics with a central, rubbery polyolefin block and terminal blocks of polystyrene, and optionally including up to about 45 percent by weight of polypropylene, plus from 0.5 to 10 percent by weight of a cross-linked organic silicone elastomer; and (b) from 30 to 60 percent by weight of a hydrophobic oil-type plasticizer to provide the desired degree of softness to said elastic composition.
    Type: Grant
    Filed: April 28, 1978
    Date of Patent: April 22, 1980
    Assignee: Baxter Travenol Laboratories, Inc.
    Inventors: Lawrence F. Becker, Henry M. Gajewski
  • Patent number: 4199490
    Abstract: A block copolymer latex composition comprising (A) an aqueous latex containing at least one of block copolymers consisting of conjugated diolefin blocks and monovinyl-substituted aromatic compound blocks prepared by solution-polymerization, and having a molecular weight of 5,000 to 500,000 and a content of monovinyl-substituted aromatic compound of 10 to 70% by weight, and (B) a latex of rubber system, latex of synthetic resin system or a mixture thereof, the composition containing 5 to 87% by weight of (A) and 95 to 13% by weight of (B) in terms of solid matters, has very superior film-forming properties and provides films having improved strength.
    Type: Grant
    Filed: February 16, 1977
    Date of Patent: April 22, 1980
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Shunji Kamiya, Kunio Satake, Tomiho Sone, Tsutomu Teraoka
  • Patent number: 4196116
    Abstract: Novel compositions are disclosed which include a polyphenylene ether resin, an alkenyl aromatic resin modified with an EPDM rubber, and a hydrogenated diblock copolymer. Also included within the scope of this invention are reinforced and flame-retardant compositions of the polyphenylene ether resin, the alkenyl aromatic resin modified with an EPDM rubber, and the hydrogenated diblock copolymer.
    Type: Grant
    Filed: November 28, 1977
    Date of Patent: April 1, 1980
    Assignee: General Electric Company
    Inventors: William R. Haaf, Glenn D. Cooper
  • Patent number: 4191685
    Abstract: Compositions comprising a polyphenylene ether and, optionally, a styrene resin, an aromatic phosphate, phosphonate or phosphine oxide, an aromatic halogen compound and an impact modifier comprising a diene polymer have excellent flame retardant properties during large scale flammability tests. The compositions will tolerate large amounts of aromatic halogen compound without discoloration and processing difficulties. In comparison with compositions of the present state of the art, peak burn temperatures are reduced, smoke is less dense, and flaming drips are eliminated in large as well as small scale burn tests.
    Type: Grant
    Filed: October 3, 1977
    Date of Patent: March 4, 1980
    Assignee: General Electric Company
    Inventors: William R. Haaf, Gim F. Lee, Jr.
  • Patent number: 4188432
    Abstract: Shaped articles which are resistant to attack by fatty substances and chemicals and which have impact resistance comparable to high impact polystyrene are produced by extrusion or injection molding of a composition consisting essentially of high impact styrene-butadiene graft copolymer or a mixture thereof with no more than about 55% styrene homopolymer and small proportions of polyethylene or polypropylene and of a block copolymer X-Y-X in which each X is a polystyrene block of about 5,000 to 10,000 molecular weight and Y is a hydrogenated polybutadiene block of 25,000 to 50,000 molecular weight. The articles are characterized by having a skin which is substantially enriched in polyolefin.
    Type: Grant
    Filed: March 30, 1978
    Date of Patent: February 12, 1980
    Assignee: Shell Oil Company
    Inventors: Geoffrey Holden, Lam H. Gouw
  • Patent number: 4181635
    Abstract: A pressure-sensitive adhesive composition having excellent tackiness and improved thermal resistance comprises (A) a low molecular weight polyisoprene, which may be obtained by polymerizing isoprene monomer with the aid of a lithium-type catalyst, said polyisoprene having a cis-1,4 content of not less than 75%, a viscosity average molecular weight of 8,000 to 77,000 and an Mw/Mn value (Mw: weight average molecular weight; Mn: number average molecular weight) of 1.0 to 2.7 and (B) an elastomer.
    Type: Grant
    Filed: February 17, 1978
    Date of Patent: January 1, 1980
    Assignee: Kuraray Co., Ltd.
    Inventors: Hideo Takamatsu, Shobu Minatono, Katsuyoshi Terao, Junnosuke Yamauchi
  • Patent number: 4175101
    Abstract: Novel block copolymers of acrylonitrile having good gas-barrier and impact-resistance properties are prepared by copolymerizing acrylonitrile and another comonomer, such as methyl acrylate, using an elastomer prepolymer containing free-radical initiator groupings as the copolymerization initiator.
    Type: Grant
    Filed: November 14, 1977
    Date of Patent: November 20, 1979
    Assignee: Standard Oil Company
    Inventors: Kenneth C. Benton, Timothy J. Williamson