Mixture Contains Solid Block Or Block-type Copolymer Derived From Ethylenically Unsaturated Hydrocarbon Reactants Only At Least One Of Which Contains At Least Four Carbon Atoms Patents (Class 525/95)
  • Patent number: 5789484
    Abstract: A 4-methyl-1-pentene polymer composition is prepared by melt mixing (A) a 4-methyl-1-pentene polymer, (B) a 1-butene polymer, (C) a propylene polymer, and (D) a triblock copolymer of polystyrene/ethylene-butylene copolymer/polystyrene and/or a triblock copolymer of polystyrene/ethylene-propylene copolymer/polystyrene. The composition has improved gas permeability, flexibility, and mechanical properties and is formed into a film which is heat sealable.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: August 4, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kojiro Kan, Akio Yamamoto
  • Patent number: 5786426
    Abstract: Interpenetrating polymer networks (IPN's), composed of polyisoprene (PI) and polyurethane (PU), together with a process for their preparation and their use in the manufacture of medical devices, such as catheters and catheter balloons, are disclosed. Both components are elastomers. The PI component is chemically crosslinked. The PU component is crystallizable and contains only physical crosslinks. The IPN's have glass transition temperatures in the range of from -65.degree. C. to -40.degree. C.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: July 28, 1998
    Assignee: Schneider (USA) Inc
    Inventors: Leslie H. Sperling, Clarence J. Murphy, Vinay Mishra
  • Patent number: 5786425
    Abstract: Interpenetrating polymer networks (IPN's), composed of polyisoprene (PI) and polyurethane (PU), together with a process for their preparation and their use in the manufacture of medical devices, such as catheters and catheter balloons, are disclosed. Both components are elastomers. The PI component is chemically crosslinked. The PU component is crystallizable and contains only physical crosslinks. The IPN's have glass transition temperatures in the range of from -65.degree. C. to -40.degree. C.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: July 28, 1998
    Assignee: Schneider (USA) Inc
    Inventors: Leslie H. Sperling, Clarence J. Murphy, Vinay Mishra
  • Patent number: 5777025
    Abstract: A low-sediment, low-tar, chlorine-free thermal process for preparing oil-soluble polyalkenyl derivatives of monounsaturated C.sub.4 -C.sub.10 dicarboxylic acid producing compounds is disclosed. The process involves reacting the dicarboxylic acid producing compound with a polyalkene at high temperature and under high inert gas partial pressure in the presence of a sediment-inhibiting amount of hydrocarbyl substituted sulfonic acid. The polyalkenyl derivatives are useful per se as additives in lubricating oils, functional fluids, and fuels and are also useful as intermediates in the preparation of other products (e.g., succinimides) useful as additives in lubricating oils, functional fluids, and fuels.
    Type: Grant
    Filed: February 9, 1996
    Date of Patent: July 7, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jeremy R. Spencer, Robert W. Russell, Ronald P. Wangner
  • Patent number: 5777030
    Abstract: A polymer blend composition comprising (A) a monovinylarene/conjugated diene block copolymer, and (B) a styrenic polymer of styrene/methyl methacrylate is provided. A process for preparing the composition and articles prepared from the composition are also provided.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: July 7, 1998
    Assignee: Phillips Petroleum Company
    Inventors: Mark D. Hanes, William H. Beever, David L. Hartsock
  • Patent number: 5777031
    Abstract: A thermoplastic elastomer composition comprising a block copolymer having at least two resinous endblocks and a high 1,2-addition butadiene midblock, a paraffin oil and a crystalline polyolefin. The composition exhibits greater softness, better processability and better elastic properties as compared with similar compositions made with normal amounts of a 1,2-addition. Compositions are useful for utilities such as overmolding into hard substrates, grips, medical tubing and miscellaneous rubbery articles.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: July 7, 1998
    Assignee: Shell Oil Company
    Inventors: Lie Khong Djiauw, Michael John Modic
  • Patent number: 5760135
    Abstract: This invention relates to a novel pressure sensitive adhesive formed of a liquid and solid rubber which is substantially resin free. Preferably the adhesive is formed of a weight ratio of solid rubber to liquid rubber of about 1:0.5 to about 1:7. When a thermoplastic rubber is used, an endblock associating resin can also be used with the block copolymer solid rubber composition for improving adhesion and hold properties of the composition. A minor amount of tackifier can be added without affecting the improved properties of the present invention. The adhesive can preferably be cross linked with a sulfur, sulfur-bearing agents, peroxide, isocyanate or an aluminum isopropylate composition. These adhesives exhibit improved adhesion in cold weather and oily surface applications and other properties. The pressure sensitive adhesives can be used in health care, industrial and drug delivery systems. The adhesives can be processed by a hot melt process for providing improved ecological benefits.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: June 2, 1998
    Assignee: Ralf Korpman Associates, Inc.
    Inventors: Ralf Korpman, Vera Korpman, Michael Korpman, Dennis Korpman
  • Patent number: 5753755
    Abstract: A resin composition containing (A) an amorphous polyolefin resin and (B) a block copolymer comprising a polymer block of an aromatic vinyl compound and an isobutylene polymer block, at an (A)/(B) weight ratio within a range of 95/5 to 50/50, has remarkably improved impact resistance, with no deterioration of the excellent properties essential to the amorphous polyolefin resin (A), such as transparency.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: May 19, 1998
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenji Shachi, Kazushige Ishiura
  • Patent number: 5750656
    Abstract: The invention is a process for the preparation of a sulfur-containing polymer, comprising:A. contacting sulfuric acid with one or more of fatty acid, fat or oil, and an inert solvent that allows dispersion of the sulfuric acid;B. contacting the mixture from Part A with a polymer which contains olefinic and/or aromatic unsaturation and, optionally, an organic acid anhydride under conditions such that a homogeneous sulfated or sulfonated polymer is formed wherein a sulfonated polymer is prepared when organic anhydride is present; and, optionally,C. contacting the mixture from Part B with a metal salt or one or more amine compounds under conditions such that a salt or neutralized form of a sulfated or sulfonated polymer is prepared.The process of the invention allows the preparation of homogeneous sulfonated or sulfated polymers at relatively high solids levels and at elevated temperatures.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: May 12, 1998
    Assignee: The Dow Chemical Company
    Inventor: Michael O. Myers
  • Patent number: 5750607
    Abstract: Hot melt adhesive compositions, comprising(a) a radial multiarmed block copolymer (AB).sub.n X, wherein A is a block predominantly derived from a monovinylaromatic compound, B is a block predominantly derived from butadiene and which optionally has been partially or completely hydrogenated,X is the residue of a multifunctional coupling agent,n is in the range of from 3 to 6,(b) a linear block copolymer AB, the components (a)+(b) being present in an amount of 100 parts by weight,(c) a tackifying resin, which is compatible with the blocks B, in an amount of from 100 to 500 parts by weight,(d) a plasticizer in an amount of from 100 to 300 parts by weight,(e) an antioxidant-UV stabiliser in an amount from 0.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: May 12, 1998
    Assignee: Shell Oil Company
    Inventors: Eric-Jack Gerard, Noel Raymond Maurice De Keyzer, Birgitte Maria Ludovica Christine Van De Vliet
  • Patent number: 5750623
    Abstract: Hot-melt adhesive compositions containing high molecular weight linear styrene-isoprene-styrene block copolymers or high molecular weight linear styrene-butadiene-styrene copolymers, having little or no residual diblock, and articles made therefrom. The resulting adhesive composition may include solid tackifying and liquid tackifying resins.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: May 12, 1998
    Assignees: The Dow Chemical Co., Exxon Chemical Patents, Inc.
    Inventors: Charles F. Diehl, Jean M. Tancrede
  • Patent number: 5744535
    Abstract: A polypropylene resin composition having a high moldability and capable of forming therefrom shaped articles having excellent surface hardness, thermal deformation resistance and low temperature impact resistance includes (A) 35-74 wt % of a crystalline ethylene-propylene block copolymer with an ethylene content of 0.5-15 wt %, an isotactic pentad fractional propylene of 96% or more and a MFR of 40-80 g/10 min. (230.degree. C., 2160 g); (B) 21-40 wt % of an ethylene-.alpha.-olefin copolymer produced by using a single site catalyst and having an .alpha.-olefin content of 70 mol % or more, a ratio (Mw/Mn) of 2.5 or less, and a ratio (MI.sub.10 /MI.sub.2.16) of 6 to 15; and (C) 5-25 wt % of a talc particle component having an average particle size of 3-7 .mu.m.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: April 28, 1998
    Assignee: UBE Industries, Ltd.
    Inventors: Tomohiko Akagawa, Ikunori Sakai, Shigehiro Asano
  • Patent number: 5741843
    Abstract: Disclosed are sealant compositions having excellent slump and spew resistant, even at relatively high operating temperatures for electrical connectors. The sealants, which are flowable at such elevated temperatures, comprise two essential components: elastomeric thermoplastic polymer, preferably an organic polymer composite comprising diblock and triblock copolymers, and extender for the polymer. The extender may comprise a primary and a secondary extender, such as polybutene oil and mineral oil, respectively.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: April 21, 1998
    Assignee: The Whitaker Corporation
    Inventors: Francis Frederick Koblitz, Thomas John Lynch, Ricky Charles Mellinger
  • Patent number: 5733538
    Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 31, 1998
    Assignee: Thoratec Laboratories, Inc.
    Inventor: Judy S. Riffle
  • Patent number: 5733980
    Abstract: This invention relates to block polymers containing both crystalline and elastomeric blocks, the block copolymer having an A block and a B block. The A block is a polyethylene or an ethylene polymer optionally containing an alpha-olefin and is generally crystalline. The B block contains an ethylene, .alpha.-olefin copolymer segment and optionally contain an ethylene, .alpha.-olefin, non-conjugated diene terpolymer segment. If the B block contains a diene containing segment, the diene containing segment is furthest from the junction of the A and the B blocks. Also disclosed is a process for manufacture of the block copolymers and methods for coupling the block copolymers. Coupled block copolymers are useful as thermoplastic elastomers exhibiting physical properties approaching those of crosslinked EP or EPDM elastomers, but showing thermal processability after coupling.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: March 31, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Charles Cozewith, Gary William Ver Strate, Roger K. West, Gaetano A. Capone
  • Patent number: 5726248
    Abstract: This invention relates to a novel class of polymeric compositions which have molecular weights ranging from 300 to 10,000 and are the reaction product of (a) an N-aryl or N-alkaryl substituted diphenyldiamine and (b) a conjugated or nonconjugated diene. These polymeric N-aryl substituted and N-alkaryl diphenyldiamine compounds are particularly useful as an antioxidant in diene containing polymers.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: March 10, 1998
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Paul Harry Sandstrom, Denise Jeannette Keith
  • Patent number: 5723511
    Abstract: A process for the preparation of branched thermoplastic resins comprising: heating a mixture of a free radical initiator, at least one first free radical reactive monomer, at least one free radical reactive branching agent compound, and at least one stable free radical agent, to produce a linear or unbranched polymer product with a free radical initator fragment at one end and a covalently bonded stable free radical agent at the other end of the polymerized chain of monomers; and irradiating the unbranched polymer product in the presence of a reactive compound selected from the group consisting of a free radical reactive monomer, a branching agent compound, and mixtures thereof to form a branched polymeric product.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: March 3, 1998
    Assignee: Xerox Corporation
    Inventors: Peter M. Kazmaier, Barkev Keoshkerian, Karen A. Moffat, Michael K. Georges, Gordon K. Hamer, Richard P. N. Veregin
  • Patent number: 5717029
    Abstract: The invention is a thermoformable polymer blend comprising:A) from 9 to 90 parts by weight of a monovinylidene aromatic polymer or an impact modified monovinylidene aromatic polymer, comprising from 1 to 25 weight percent of a rubber and 75 to 99 weight percent of a monovinylidene aromatic polymer matrix having a weight average molecular weight (M.sub.w) from 50,000 to 400,000, said weight percents being based on the total weight of said impact modified, monovinylidene aromatic polymer;B) from 9 to 90 parts by weight on an olefin polymer, selected from the group consisting of homopolymers of ethylene or propylene and copolymers of ethylene with one or more C.sub.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: February 10, 1998
    Assignee: The Dow Chemical Company
    Inventors: Jeffrey E. Bonekamp, Robert J. Donald, Steven B. Swartzmiller, Andre J. Uzee
  • Patent number: 5710219
    Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching, within defined limits, the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides blends of the "matched" components which blends were heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible or dispersible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: January 20, 1998
    Assignee: Regents of the University of Minnesota
    Inventors: Frank S. Bates, Jeffrey H. Rosedale, Mark F. Schulz, Kristoffer Almdal
  • Patent number: 5708083
    Abstract: A polyolefin resin composition is disclosed which comprises(a) a crystalline propylene polymer in an amount of 40% or more to less than 95% by weight,(b) an ethylene/.alpha.-olefin rubber in an amount of from 5 to 40% by weight, and(c) a linear or branched specified block copolymer in an amount of from 0.1 to 20% by weight containing a polyethylene block segment A having a melting temperature as measured with a differential scanning calorimeter of from 80.degree. to 120.degree. C. and an ethylene/.alpha.-olefin copolymer block segment B,the total content of components (a), (b), and (c) being 100% by weight, which composition has excellent dispersibility of the rubber used, so that moldings having an excellent balance between rigidity and impact resistance are obtained therefrom, and is hence suitable for use in the field of moldings required to have rigidity and impact resistance.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: January 13, 1998
    Inventors: Takanobu Kawamura, Katsuhiko Ohno, Osamu Kojima, Kouichi Hatada, Shinei Gima, Takao Nomura, Takeyoshi Nishio
  • Patent number: 5705566
    Abstract: An adhesive mixture includes a block copolymer hot melt adhesive and particles of a vapor corrosion inhibitor mixed therein to protect products against corrosion. The adhesive is used to seal flaps of containers together, secure carpet to the floor of a vehicle, secure nonwoven fabric to a shrink film so that the additive is released when the shrink film is shrunk around a product to be protected, or used as an adhesive on a tape, so that the product is protected when the tape is wrapped around the product.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: January 6, 1998
    Assignee: Transhield Technology Co., LLC
    Inventor: Gregory L. Todt
  • Patent number: 5679743
    Abstract: The disclosure describes a polyacetal resin composition comprising 100 parts by weight of a polyacetal resin (A), 0.3 to 10 parts by weight of an olefin copolymer (B) composed of 30 to 70 wt % of ethylene-propylene-diene rubber (B.sub.1), 30 to 70 wt % of an ethylene-vinyl acetate copolymer (B.sub.2) with a vinyl acetate content of 18 to 40 wt % and 1 to 25 wt % of an ethylene-(C.sub.4-6)olefin-1 copolymer (B.sub.3), and 0.1 to 10 parts by weight of a styrene-based thermoplastic elastomer (C) having a functional group.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: October 21, 1997
    Assignee: Oiles Corporation
    Inventors: Kazuo Hirai, Kingo Miyasaka, Masayuki Rokugawa, Katsumi Minou
  • Patent number: 5670564
    Abstract: Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive end groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: September 23, 1997
    Assignee: Maxdem Incorporated
    Inventors: Robert R. Gagne, Matthew Louis Marrocco, III, Mark Steven Trimmer, Neil H. Hendricks
  • Patent number: 5670577
    Abstract: This invention relates to hot melt adhesive compositions useful for waterproofing stitched seams and a method of using the same. This invention particularly relates to certain hot melt adhesives which can be directly applied to a stitched seam such that the resulting seam is resistant to water penetration.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: September 23, 1997
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventor: Glen E. Dawson, Jr.
  • Patent number: 5665822
    Abstract: Thermoplastic elastomers (TPEs) containing side chain crystalline (SCC) blocks. The SCC blocks my be hard (A) blocks or the soft (B) blocks (or both) in the TPE. Some of these TPEs are novel, e.g. those in which A blocks are SCC blocks, and the B blocks are polyethers, polyacrylates, polyamides, polyurethanes or polysiloxanes. The SCC-containing TPEs are particularly useful as matrix materials for other components which are dispersed therein, e.g. energetic solids and other thermally responsive materials.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: September 9, 1997
    Assignee: Landec Corporation
    Inventors: Steven P. Bitler, Ray F. Stewart, David A. Kamp, Robert G. Freelin, Valentine Y. Yoon
  • Patent number: 5658986
    Abstract: These copolymers are denoted by the formulae: ##STR1## P.sub.1, P.sub.2 =vinyl or dienic (p with a value of 1), or polyoxyalkylene, polyester or polyamide (p with a value of 0) polymer block;A=(1) ##STR2## with R.sub.1 denoting, among others, alkyl; (2) ##STR3## where E, G, J have various meanings; (3) ##STR4## M, joined to D, having the value ##STR5## h, i, Q and R having various meanings; D=a single bond or (cyclo)alkylene or arylene group;n=1 to 20.These polymers are iniferters in radical polymerization of vinyl monomers. The macroiniferters (I) and the polyiniferters (II) result, respectively, in triblock copolymers PA--PB--PA and diblock copolymers .paren open-st.PA--PB.paren close-st..sub.z a, z having a value from 2 to 25.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: August 19, 1997
    Assignee: Atochem
    Inventor: Gilbert Clouet
  • Patent number: 5654364
    Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching of the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides polyolefin blends heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: August 5, 1997
    Assignee: Regents of the University of Minnesota
    Inventors: Frank Steven Bates, Jeffrey Harris Rosedale, Mark Frederic Schulz, Kristoffer Almdal
  • Patent number: 5654081
    Abstract: In a method of producing an integrated circuit assembly, an IC device is metallurgically bonded to a supporting substrate. The mounting of the IC device to the substrate also includes a polymeric underfill body adhesively bonding the IC device to the substrate. The polymeric underfill body is formed of a curable underfill composition comprising epoxy resin, anhydride curing agent for the epoxy resin, amine catalyst and a minor amount of an additional component selected from alkyl-substituted imidazole and phenyl-substituted imidazole. Such additional component may act as a catalyst, as used with an amine catalyst known catalyst for the polymerization reaction of the epoxy resin with the anhydride curing agent, may act as a co-catalyst. The polymeric underfill body has improved glass transition temperature values and improved coefficient of thermal expansion values to provide good thermal stress cycling life for the integrated circuit assembly.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: August 5, 1997
    Assignee: Ford Motor Company
    Inventor: Michael G. Todd
  • Patent number: 5641848
    Abstract: Disclosed is a blown film or sheet material comprising a broad molecular weight distribution propylene polymer material having a molecular weight distribution M.sub.w /M.sub.n of about 4 to about 60, a melt flow rate of about 0.5 to about 50 dg/min, and xylene insolubles at 25.degree. C. of greater than or equal to 94%. A mixture of the broad molecular weight distribution propylene polymer material and a heterophasic olefin polymer composition can also be used.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: June 24, 1997
    Assignee: Montell North America Inc.
    Inventors: James M. Giacobbe, Steven J. Pufka
  • Patent number: 5633286
    Abstract: Novel composites are formed from a low rigidity oriented and non-oriented gelatinous elastomer composition of poly(styrene-ethylene-butylene-styrene) or poly(styrene-ethylene-proplene-styrene) triblock copolymer and high levels of a plasticizing oil. The gelatinous elastomer composition is physically interlocked with an open cell sponge thereby displacing the air space within the sponge and the gel rigidity is found to be greater than about the sum of the combined rigidity of the gelatinous elastomer composition and sponge alone. The gelatinous elastomer composite exhibits a novel combination of properties including unexpectedly high elongation and tensile strength and excellent shape retention after extreme deformation under high-velocity impact and stress conditions. The gelatinous elastomer composites can be made firm or soft and flexible.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: May 27, 1997
    Assignee: Applied Elastomerics, Inc.
    Inventor: John Y. Chen
  • Patent number: 5627235
    Abstract: The present invention encompasses nontapered block copolymers of the following structure and adhesives containing themD--A--(B--A).sub.n --D.sub.xor(D--A--B).sub.z --Ywhere A is a vinyl aromatic hydrocarbon polymer block, B and D are hydrogenated conjugated diene polymer blocks wherein if the diene is butadiene, it must have a vinyl content of at least 30 percent by weight, n is an integer from 1 to 5, x is 0 or 1, z is an integer from 2 to 30, and Y is a multifunctional coupling agent and the copolymer has a vinyl aromatic hydrocarbon content of from 9 to 35 percent by weight. The ratio of the molecular weight of D to that of B ranges in accordance with the normalized molecular weight factor which may range from greater than 0 up to 180.times.10.sup.-6.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: May 6, 1997
    Assignee: Shell Oil Company
    Inventor: Glenn R. Himes
  • Patent number: 5601889
    Abstract: This invention relates to a polymer article prepared by the process comprising the steps of: (1) blending polymer composition comprising (A) at least one ethylene vinyl acetate copolymer, (B) at least one propylene ethylene copolymer, and (C) (1) from about 0.01% to about 5% by weight of a cross-linking agent, (2) from about 0.1% to about 35% by weight of one or more polymers selected from: (i) at least one co-, or terpolymer of at least one vinyl aromatic compound; (ii) at least one co-, or terpolymer of an alpha-olefin, and at least one monomer selected from the group consisting of an acrylic acid, an acrylic ester, a vinyl silane, and a vinyl alcohol; (iii) at least one polyolefin other than a propylene homopolymer or a propylene-ethylene copolymer; (iv) at least one polyetheramide block copolymer; (v) at least one ionomer; (vi) at least one oxidized polyolefin wax, or mixtures of (1) and (2); and forming the polymer composition into the article.
    Type: Grant
    Filed: September 22, 1994
    Date of Patent: February 11, 1997
    Assignee: Ferro Corporation
    Inventors: Deenadayalu Chundury, Rajeev S. Bhatia
  • Patent number: 5597860
    Abstract: The present invention provides a vulcanizable rubber composition comprising 100 parts by weight of a polymer component consisting of 30 to 80 wt. % of an ethylene.cndot..alpha.-olefin.cndot.non-conjugated diene copolymer having a Mooney viscosity of 10 to 100 (ML.sub.1+4 100.degree. C.) and an iodine value of 20 to 45 and containing ethylene and .alpha.-olefin in a weight ratio of 50:50 to 90:10, and 20 to 70 wt. % of a styrene-conjugated diolefin block copolymer, 20 to 150 parts by weight of a reinforcing filler, 3 to 30 parts by weight of sulfur, 0 to 50 parts by weight of a styrene resin and 0 to 100 parts by weight of an extending oil.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: January 28, 1997
    Assignees: Sumitomo Chemical Company Limited, Toyoda Gosei Co., Ltd.
    Inventors: Masashi Aoshima, Hironobu Shigematsu, Takeru Wadaki, Toshikatsu Kanehara, Kazuya Watanabe, Toshiyuki Tanaka
  • Patent number: 5571864
    Abstract: The invention relates to melt-miscible polyolefin blends, and a process for preparing the melt-miscible blends, of two or more polyolefins. Matching, within defined limits, the segment length of a modifying polyolefin with the segment length of a primary polyolefin, such as polypropylene or an ethylene/alpha-olefin copolymer, provides blends of the "matched" components which blends were heretofore unknown to be melt-miscible. A broad range of polyolefin blend compositions, and of polyolefin blends containing other polymers made compatible or dispersible with the polyolefin blend compositions, are defined, all of the blend compositions having at least one melt-miscible polyolefin phase.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: November 5, 1996
    Assignee: Regents of the University of Minnesota
    Inventors: Frank S. Bates, Jeffrey H. Rosedale, Mark F. Schulz, Kristoffer Almdal
  • Patent number: 5567769
    Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: October 22, 1996
    Assignees: The Procter & Gamble Company, The Univ. of Delaware
    Inventors: Annette D. Shine, Steven D. Smith, Isao Noda
  • Patent number: 5559165
    Abstract: A pressure sensitive hot melt adhesive comprising a block copolymer and 60 to 95 parts of a liquid diluent, the adhesive being characterized by a midblock Tg less than -10.degree. C., a G' less than 15.times.10.sup.4 dynes/cm.sup.2 at 10 rad/s, 25.degree. C., a G" of 1 to 6.times.10.sup.4 dynes/cm.sup.2 and a tensile strength greater than 10 psi exhibit superior properties, without the need for any curing operation after cooling.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: September 24, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Charles W. Paul
  • Patent number: 5547746
    Abstract: A nonwoven fiber and fabric and process for production are provided which have comparable strength characteristics to conventional fibers and fabrics and are of a finer diameter. This is accomplished through a process of producing a nonwoven fabric made from at least one polymer which has a melt temperature between about 410.degree. and 470.degree. F. (210.degree. and 243.degree. C.), xylene solubles between about 3.5 and 7.0%, a melt flow rate between about 30 and 45, and an isotacticity of at least about 94%, extruding the polymer through fine openings, drawing the polymer to produce fibers of a denier of 1.4 or less, and then depositing the fiberized polymer on a collecting surface to form a web of disbursed fibers.The nonwoven fabric of this invention may be used in products such as, for example, diapers, feminine hygiene products, adult incontinence products, wound dressings, bandages, sterilization wraps, surgical drapes and wipers.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: August 20, 1996
    Assignee: Kimberly-Clark Corporation
    Inventor: Robert M. Burton, Sr.
  • Patent number: 5532309
    Abstract: A resin composition for an automobile bumper comprising components (A), (B), and (C) described below:(A) 45 to 74% by weight of a crystalline ethylene-propylene block copolymer having (a) a flexural modulus of 15,000 kg/cm.sup.2 or more, (b) an ethylene content of 5 to 20% by weight, (c) an intrinsic viscosity (decalin, 135.degree. C.) of a portion soluble in p-xylene at room temperature of 3 or more, (d) a melt flow index (MI) of 21 to 70 g/10 min., and (e) a content of a portion insoluble in boiling n-heptane of 97% by weight or more;(B) 21 to 35% by weight of elastomer selected from the group consisting of components (I), (II) and (III) and having a weight ratio of (I) : [(I)+(II)+(III)] of from 0.5 to 1.0, (a) said component (1) being an amorphous ethylene-butene copolymer having a butene content of 10 to 25% by weight and a Mooney viscosity value, (ML.sub.1+4, 100.degree. C.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: July 2, 1996
    Assignees: Ube Industries, Ltd., Toyota Jidosha Kabushiki Kaisha
    Inventors: Osamu Fukui, Kouhei Ueno, Yoshifumi Nakano, Yukimasa Hamada, Takeyoshi Nishio, Takao Nomura, Nobuya Kawamura
  • Patent number: 5532315
    Abstract: The invention is a recycling process for forming a thermoformable polymer blend comprising:A) from 9 to 90 parts by weight of a monovinylidene aromatic polymer or an impact modified monovinylidene aromatic polymer, comprising from 1 to 25 weight percent of a rubber and 75 to 99 weight percent of a monovinylidene aromatic polymer matrix having a weight average molecular weight (M.sub.w) from 50,000 to 400,000, said weight percents being based on the total weight of said impact modified, monovinylidene aromatic polymer;B) from 9 to 90 parts by weight on an olefin polymer, selected from the group consisting of homopolymers of ethylene or propylene and copolymers of ethylene with one or more C.sub.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: July 2, 1996
    Assignee: The Dow Chemical Company
    Inventors: Jeffrey E. Bonekamp, Steven B. Swartzmiller, Robert J. Donald, Andre J. Uzee
  • Patent number: 5516829
    Abstract: A heat seamable flame retardant sheet material for roofing prepared from an uncured polymeric composition of matter which comprises 100 parts by weight of a polymer blend comprising from about 50 to 90 parts by weight of halogenated polyolefins having up to about 2 percent by weight crystallinity, which polyolefins are prepared from monomers having at least 2 carbon atoms, and mixtures thereof and from about 10 to 50 parts by weight of a highly crystalline thermoplasticity promoter selected from the group consisting of polymeric olefins prepared from monomers consisting of at least two carbon atoms; from about 50 to 250 parts by weight of a filler selected from the group consisting of reinforcing and non-reinforcing materials and mixtures thereof per 100 parts of the polymer blend; from about 20 to 105 parts by weight of a processing material and mixtures thereof, per 100 parts of the polymer blend; and from about 15 to 90 parts by weight of an additive selected from the group consisting of flame retardant ma
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: May 14, 1996
    Inventors: James A. Davis, Joseph K. Valaitis
  • Patent number: 5510419
    Abstract: A polymer-modified rubber composition is formed by blending together about 5% to about 60% vulcanized styrene-butadiene rubber crumb; about 5% to about 60% uncured rubber; about 5% to about 30% styrene-based thermoplastic resin; about 1% to about 10% homogenizing agent adapted to facilitate blending of aromatic-based with non aromatic-based polymers; and about 1% to about 10% curing agent for the uncured rubber; to form a blend wherein the thermoplastic resin (c) is substantially homogeneously blended with the rubbers (a) and (b). All major components of the composition may be derived from the post industrial and post consumer waste stream. The compositions have excellent physical properties, especially stiffness and stiffness retention at elevated temperatures.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: April 23, 1996
    Assignee: National Rubber Technology Inc.
    Inventors: Michael D. Burgoyne, James F. Fisher, James R. Jury
  • Patent number: 5508334
    Abstract: Novel gelatinous compositions and articles are fromed from an intimate melt blend admixture of poly(styrene-ethylene-butylene-styrene) triblock copolymer and high levels of a plasticizing oil.The gelatinous composition is transparent and have a novel combination of properties including unexpectedly high elongation and tensile strength and excellent shape retention after extreme deformation under high-velocity impact and stress conditions. The gelatinous products of this invention are soft, flexible, and have elastic memory, characterized by a gel rigidity of from about 20 gram to about 700 gram Bloom. These and other properties are particularly essential for the gelatinous composition to have utility as toys, therapeutic hand exercising grips, shock absorbers, acoustical isolators, components for cushions, and other uses.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: April 16, 1996
    Assignee: Applied Elastomerics, Inc.
    Inventor: John Y. Chen
  • Patent number: 5500293
    Abstract: The invention provides an adhesive composition suitable for use in an insulating tape having improved plasticizer resistance, comprising from about 13 to about 42 of a polyisoprene homopolymer, from about 13 to about 42 of a styrene-isoprene-styrene copolymer, from about 25 to about 55 of an aliphatic tackifying agent containing from about 4 to about 6 carbon atoms, and from about 2 to about 20 of an end block reinforcing resin.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: March 19, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Felix P. Lau, Timothy D. Bredahl, George E. Cox
  • Patent number: 5480932
    Abstract: A polypropylene resin composition comprising: (a) 50 to 90% by weight of polypropylene, (b) 50 to 10% by weight of an ethylene-.alpha.-olefin copolymer elastomer having a Mooney viscosity (ML 1+4 (100.degree. C.)) of 10 to 100, (c) 0.5 to 10 parts by weight per 100 parts by weight of the total of the amounts of the components (a) and (b) of a linear olefinic polymer containing hydroxyl group which is liquid at room temperature, and (d) 0.5 to 15 parts by weight per 100 parts by weight of the total of the amounts of the components (a) and (b) of a linear olefinic polymer having a melting point of about 70.degree. to about 90.degree. C. and a number-average molecular weight of 1500 to 6000 and containing hydroxyl group or carbonyl group; and a protective strip for automobiles using the polypropylene resin composition are disclosed. Coating immediately after degreasing is made possible and excellent property for coating can be provided by using the polypropylene resin composition.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: January 2, 1996
    Assignees: Idemitsu Petrochemical Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Yutaka Kobayashi, Osamu Aoki, Kenji Hamabe, Atsushi Takeuchi, Takayuki Onda
  • Patent number: 5475060
    Abstract: Cycloolefin block copolymers and a process for their preparation Cycloolefin block copolymers, which in particular are suitable as phase promoters, are preferably obtained by copolymerization of polycyclic olefins, such as norbornene, with acyclic olefins, such as ethylene, by, at a molecular weight distribution M.sub.w /M.sub.n of the polymer block forming of less than 2, changing the reaction conditions one or more times in such a way that the monomer/comonomer ratio changes by at least 10% or a further polymerizable monomer is metered into the monomer or the monomers.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: December 12, 1995
    Assignee: Hoechst AG
    Inventors: Michael-Joachim Brekner, Frank Osan, Jurgen Rohrmann
  • Patent number: 5470914
    Abstract: There are disclosed novel, solid, elastomeric block copolymers with improved resistance to cold flow wherein either 1) the terminal blocks are each a polymer (I polymer) of at least one conjugated diene I, e.g., isoprene, which contains at least five carbon atoms with at least one of each pair of double-bonded carbon atoms in the polymerized diene I units being additionally single-bonded to two carbon atoms; at least one middle or interior block is a hydrogenated polybutadiene (B polymer); and at least one middle or interior block is an essentially straight chain polyethylene (E polymer) resulting from the hydrogenation of a polybutadiene composed of at least 80% of 1,4- units; or 2) the terminal blocks are random IB copolymers of at least one diene I as previously defined and hydrogenated butadiene, and at least one middle or interior block is a straight chain polyethylene (E polymer) as previously defined.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: November 28, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews
  • Patent number: 5468807
    Abstract: The present invention provides a resin composition including (a) 20-80% by weight of an amorphous polyolefin having a propylene and/or butene-1 component content of 50% by weight or more, and (b) 80-20% by weight of a crystalline polypropylene. This resin composition is well balanced in mechanical strength and flexibility and gives rise to no environmental pollution.
    Type: Grant
    Filed: August 2, 1994
    Date of Patent: November 21, 1995
    Assignees: Ube Rexene Corporation, Ube Industries, Rexene Corporation
    Inventors: Iwao Tsurutani, Takafumi Manabe, Ikuo Emoto
  • Patent number: 5468550
    Abstract: Vulcanizable elastomeric roof sheet materials for roofing having improved burn resistivity and prepared from a polymeric composition of matter comprise at least one polymer selected from the group consisting of polyolefins prepared from monomers containing at least two carbon atoms and mixtures thereof, the polymer having a crystallinity of up to about 2 percent by weight; about 20 to 125 parts by weight of one or more non-black mineral fillers per 100 parts of the polymer, about 50 to 110 parts by weight of one or more black-type fillers per 100 parts of the polymer; and from about 50 to 70 parts by weight of a processing material or softener per 100 parts of the polymer.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: November 21, 1995
    Assignee: Bridgestone/Firestone, Inc.
    Inventors: James A. Davis, Edward G. Kane, Brian S. Alexander, William F. Barham
  • Patent number: 5455303
    Abstract: Disclosed is a polymer composition of (A) a polyolefin composition consisting essentially of (i) a linear low density polyethylene and (ii) a copolymer of propylene with ethylene and/or a C.sub.4 -C.sub.8 .alpha.-olefin, where R is an alkyl radical having 2 to 10 carbon atoms and (B) a low density polyethylene.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: October 3, 1995
    Assignee: Montell North America Inc.
    Inventors: George Panagopoulos, Jr., Camillo Cagnani, Claudio Cometto
  • Patent number: 5432209
    Abstract: A propylene resin composition containing a propylene-ethylene block copolymer containing (a) a crystalline polypropylene moiety (constituent A) and an ethylene-propylene random copolymer moiety (constituent B), (b) a styrene-ethylene-butylene-styrene block copolymer which contains 10% to 25% of bound styrene, and (c) at least one filler selected from talc and inorganic whiskers and wherein the surface of the filler is treated with one of the organic compounds (I), (II) and (III) having the formulas, ##STR1## in which the various substituents and R groups are as defined in the specification and claims. The composition of the present invention has excellent mechanical strength, moldability and is capable of producing molded products having an excellent appearance.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: July 11, 1995
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Yoshihiro Sobajima, Keiko Kaba, Yoshihiro Noguchi