Mixture Contains Solid Block Or Block-type Copolymer Derived From Ethylenically Unsaturated Hydrocarbon Reactants Only At Least One Of Which Contains At Least Four Carbon Atoms Patents (Class 525/95)
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Patent number: 5420202Abstract: The present invention provides a toughened cycloaliphatic epoxy resin composition comprising:(a) a curable cycloaliphatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 2.0 to 6.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.Type: GrantFiled: April 15, 1994Date of Patent: May 30, 1995Assignee: Shell Oil CompanyInventors: David J. St. Clair, James R. Erickson
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Patent number: 5414027Abstract: Disclosed is a normally solid, high molecular weight, non-linear, substantially gel-free, propylene polymer material characterized by high melt strength due to strain hardening which is believed to be caused by free-end long chain branches of the molecular chains forming the polymer.Also disclosed is a process for making the polymer by high energy radiation of a normally solid, high molecular weight, linear, propylene polymer in a reduced active oxygen environment, maintaining the irradiated material in such environment for a specific period of time, and then deactivating free radicals in the material.Further disclosed is the use of the strain hardening polymer in extensional flow operations such as, for example, extrusion coating, film production, foaming and thermoforming.Type: GrantFiled: July 15, 1993Date of Patent: May 9, 1995Assignee: Himont IncorporatedInventors: Anthony J. DeNicola, Jr., Jeanine A. Smith, Massimo Felloni
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Patent number: 5414046Abstract: Novel thermally stable resins comprising halogens and not epoxide termination groups are described. The thermally stable resins may be employed in polymer systems to yield flame retardant polymer compositions.Type: GrantFiled: June 17, 1994Date of Patent: May 9, 1995Assignee: General Electric CompanyInventor: Gary C. Davis
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Patent number: 5412035Abstract: Pressure-sensitive adhesive (PSA) compositions containing a crystalline polymeric additive having an M.sub.w of less than 25,000 and a melting point (T.sub.a) greater than 23.degree. C., preferably 30.degree. to 60.degree. , and PSA composites of a backing, preferably a flexible backing, with such a PSA composition coated thereon. The presence of the additive causes the PSA to lose adhesive strength when heated to T.sub.a. The base resin of the PSA is preferably a polyacrylate or a styrene/butadiene copolymer. The additive, which is preferably present in amount 1 to 35%, e.g. 5 to 30%, is preferably a side chain crystallizable (SCC) polymer.Type: GrantFiled: August 12, 1992Date of Patent: May 2, 1995Assignee: Landec CorporationInventors: Edward E. Schmitt, Raymond Clarke, Andrew W. Larson, Steven P. Bitler, Ross S. Tsugita, Donald A. Schultz
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Patent number: 5412027Abstract: Homogeneous polymer blends are prepared from otherwise thermodynamically immiscible polymers, especially including block copolymers. Thus, polymers such as polystyrene/poly(methyl methacrylate) block copolymer or polystyrene/poly(1,2-butadiene) block copolymer are dissolved under pressure in supercritical fluid solvents such as chlorodifluoromethane and n-butane, respectively, and expanded through a fine nozzle. As the SCF solvent evaporates, the polymer deposits as a substantially homogeneous material.Type: GrantFiled: November 19, 1993Date of Patent: May 2, 1995Assignees: The Procter & Gamble Company, The Univ. of DelewareInventors: Annetta D. Shine, Steven D. Smith, Isao Noda
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Patent number: 5412032Abstract: A linear styrene-isoprene-styrene block copolymer composition comprised of linear polymeric blocks wherein the block copolymer composition has a coupling efficiency of from 20 to 40%, a polystyrene content of from 18 to 24%, a polystyrene block molecular weight of from 25,000 to 35,000, and an overall molecular weight of above 280,000 to 520,000. The invention also contemplates adhesive formulations comprising these block copolymer compositions and a tackifying resin.Type: GrantFiled: February 22, 1994Date of Patent: May 2, 1995Assignee: Shell Oil CompanyInventors: David R. Hansen, Steven H. Dillman
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Patent number: 5399627Abstract: The invention is drawn to radial block copolymers of the formula:(pS--pI--pB).sub.n Xwherein pS is polystyrene, pI is polyisoprene, pB is polybutadiene, X is the residue of a multifunctional coupling agent used in the production of the radial block copolymer, and n is a number greater than or equal to 3 representative of the number of branches appended to X; pressure sensitive adhesive compositions comprising such radial block copolymers and articles of manufacture produced therefrom. The pS component of the radial block copolymers of this invention comprise from about 14 to about 24 parts per 100 parts by weight of the radial block copolymer; the molecular weight (as polystyrene equivalent) of the radial block copolymer is between about 200,000 to about 400,000; and the weight amount of polybutadiene in the pI--pB segment is less than 50 weight percent.Type: GrantFiled: November 24, 1993Date of Patent: March 21, 1995Assignees: The Dow Chemical Company, Exxon Chemical Patents, Inc.Inventors: Charles F. Diehl, Jean M. Tancrede, Gary R. Marchand
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Patent number: 5391626Abstract: There are disclosed a styrenic block copolymer having a reduced viscosity of 0.01 to 20 dl/g (0.05 g/l in 1,2,4-trichlorobenzene at 135.degree. C.) which comprises highly syndiotactic styrenic-polymer segments and 10.sup.-4 to 10 mol % of heteroatom-containing styrenic polymer segments; a resin composition comprising the above styrenic block copolymer and a thermoplastic resin, an inorganic filler or an organic filler; a multi-layer material comprising at least one layer composed of the above styrenic block copolymer or the above resin composition; and a process for producing the above styrenic block copolymer which comprises polymerizing a styrenic monomer in the presence of a specific catalyst and adding a heteroatom-containing styrenic monomer to successively proceed with copolymerization reaction.Type: GrantFiled: May 20, 1993Date of Patent: February 21, 1995Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shuji Machida, Toshinori Tazaki, Noriyuki Tani
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Patent number: 5389715Abstract: A rooftop curable heat seamable sheet material for roofing prepared from an uncured polymeric composition of matter which comprises 100 parts by weight of a polymer blend comprising from about 10 to 95 parts by weight of an polymer selected from the group consisting of polyolefins having up to about 2 percent by weight crystallinity, which polyolefins are prepared from monomers having at least 2 carbon atoms, and mixtures thereof; from about 5 to 90 parts by weight of a crystallinity enhancing polymer and mixtures thereof; from about 20 to 300 parts by weight of a filler selected from the group consisting of reinforcing and non-reinforcing materials and mixtures thereof per 100 parts of the polymer blend; from about 1.5 to 10 parts by weight of a cure package a cure package capable of allowing the composition of matter to cure at temperatures of at least 50.degree. C.Type: GrantFiled: December 8, 1993Date of Patent: February 14, 1995Assignee: Bridgestone CorporationInventors: James A. Davis, Joseph K. Valaitis
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Patent number: 5364908Abstract: Resin compositions of improved dispersibility and mechanical properties are obtained by polymerizing a polymerizable compound (A), insitu in a melted thermoplastic resin (B), in the presence of a dispersant (C) reactive or compatible with at least one of the resin (B) and polymerizate of (A).Suitable dispersants include those represented by the general formula (1) or (2)R.sub.1 --L(X--M--X--L).sub.n X--M--R.sub.2 (1)R.sub.1 --L(X--M--X--L).sub.n --R.sub.2 (2)wherein R.sub.1 and R.sub.2 are groups, such as hydrocarbyl acyl, alkoxy, hydroxyl, mercapto, amino, epoxy, isocyanate, carboxylic, carboxylic anhydride, carboxylic halide and aldehyde groups; L and M are residues of a polymer having a number average molecular weight of about 500-about 3,000,000, the difference in solubility parameter between the residue L or M and the resin (B) or polymerizate of (A) being not more than 0.Type: GrantFiled: July 19, 1991Date of Patent: November 15, 1994Assignee: Sanyo Chemical Industries, Ltd.Inventors: Masafumi Oishi, Hiroshi Nishimoto, Takao Ando, Yukio Shibata, Toshiaki Okamoto, Katsura Gohda
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Patent number: 5362808Abstract: Partially crosslinked polyolefin blends containa) a polymer of from 25 to 97% by weight of a propylene polymer (I), which contains from 0 to 15% by weight of polymerized C.sub.2 -C.sub.10 -alka-1-enes, and of from 3 to 75% by weight of a further propylene polymer (II) which contains from 15 to 80% by weight of polymerized C.sub.2 -C.sub.10 -alka-1-enes,b) a random ethylene copolymer containing from 5 to 20% by weight of polymerized C.sub.3 -C.sub.10 -alk-1-enes and having a density of from 0.89 to 0.925 g/cm.sup.3 at room temperature,c) a rubber-like material having a Shore A hardness of from 30 to 90 andd) a bismaleimido compound of the following formula (I) ##STR1## where R is C.sub.1 -C.sub.20 -alkyl which may be interrupted by one or more oxygen atoms,C.sub.5 -C.sub.7 -cycloalkyl or C.sub.6 -C.sub.15 -aryl, each of which in turn may be substituted by one or more C.sub.1 -C.sub.10 -alkyl and/or C.sub.1 -C.sub.6 -alkoxy and/or C.sub.1 -C.sub.Type: GrantFiled: June 7, 1993Date of Patent: November 8, 1994Assignee: BASF AktiengesellschaftInventors: Sibylle Brosius, Bernd L. Marczinke, Harald Schwager
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Patent number: 5360855Abstract: A novel 2-substituted butadiene block copolymer is provided which provides adhesives having superior adhesion and tolerance to oil contaminated surfaces. The elastomeric block has a glass transition temperature of less than about minus 65.degree. C. with the 2 substituent being an alkyl group.Type: GrantFiled: June 22, 1993Date of Patent: November 1, 1994Assignee: Minnesota Mining & Manufacturing CompanyInventor: Ramsis Gobran
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Patent number: 5360868Abstract: Disclosed are polyolefin compositions comprising (A) a propylene homopolymer or a crystalline copolymer of propylene and ethylene or a C.sub.4-8 alpha-olefin, (B) an olefin polymer composition, and optionally either, (C) a propylene polymer composition or (D) an olefin polymer rubber.Type: GrantFiled: August 30, 1993Date of Patent: November 1, 1994Assignee: HIMONT IncorporatedInventors: Douglas D. Mosier, Mark E. Barrera, Stephen M. Dwyer
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Patent number: 5359003Abstract: Polysulfide derivatives, having the general formula (A--S--S--).sub.2 X--S--S--A processes for their production and their use for crosslinking of reversion-stable rubber vulcanizates are provided. Crosslinking with reduced reversion and loss of elastomeric properties with age is achieved by the crosslinking system provided by the invention.Type: GrantFiled: August 11, 1993Date of Patent: October 25, 1994Assignee: Huls AktiengesellschaftInventors: Gerhard Horpel, Karl-Heinz Nordsiek
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Patent number: 5358783Abstract: Blends of low styrene content polystyrene-polyisoprene-polystyrene block copolymer and high styrene content polystyrene-polyisoprene-polystyrene block copolymer can be used with tackifier resins, plasticizer oil and antioxidants to formulate pressure sensitive adhesives of improved cohesive strength vis-a-vis adhesives formed from the low styrene content polystyrene-polyisoprene-polystyrene block copolymer while maintaining good balance between tack, bonding characteristics and heat resistance.Type: GrantFiled: December 17, 1993Date of Patent: October 25, 1994Assignees: The Dow Chemical Company, Exxon Chemical Patents, Inc.Inventors: Charles F. Diehl, Jean M. Tancrede
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Patent number: 5344869Abstract: Thermoplastic molding materials contain, based in each case on the sum of components A, B and C,A: from 10 to 90% by weight of a polymer A composed of styrene and/or substituted styrene,B: from 10 to 90% by weight of a polyolefin B andC: from 5 to 40% by weight of a star block copolymer C containing not less than 50% by weight of styrene and prepared by anionic polymerization of styrene and butadiene and/or isoprene, coupling and subsequent selective hydrogenation.Type: GrantFiled: November 25, 1992Date of Patent: September 6, 1994Assignee: BASF AktiengesellschaftInventors: Stefan Seelert, Peter Klaerner, Andreas Jung, Hans Hoenl, Bertram Ostermayer
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Patent number: 5338801Abstract: Disclosed is a polyolefin composition comprising (A) a propylene polymer material and (B) an olefin polymer material selected from the group consisting of a partially crosslinked thermoplastic elastomer composition, an olefin copolymer rubber and a mixture thereof.The polyolefin composition of this invention provides reduction in gloss.Type: GrantFiled: October 20, 1993Date of Patent: August 16, 1994Assignee: Himont IncorporatedInventor: Stanley E. Eppert, Jr.
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Patent number: 5334657Abstract: A thermoformable chemical resistant polymer blend, useful in the preparation of refrigerator and freezer liners comprising:A) from 45 to 70 parts by weight impact modified monovinylidene aromatic polymer, comprising from 1 to 25 weight percent of a rubber and 75 to 99 weight percent of a monovinylidene aromatic polymer matrix having a molecular weight (Mw) from 50,000 to 400,000, said weight percents being based on the total weight of said impact modified, vinylaromatic polymer;B) from 15 to 40 parts by weight of an olefin polymer, selected from the group consisting of homopolymers of ethylene or propylene and copolymers of ethylene with one or more C.sub.4-8 .alpha.-olefins; andC) from 5 to 25 parts by weight of a compatibilizing polymer, adapted to increase interfacial adhesion between components A) and B), components A) and B) or components A), B) and C) existing in said blend as co-continuous phases, and the sum of A),B) and C) being 100 parts.Type: GrantFiled: December 18, 1992Date of Patent: August 2, 1994Assignee: The Dow Chemical CompanyInventors: Steven B. Swartzmiller, Robert J. Donald, Jeffrey E. Bonekamp
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Patent number: 5334646Abstract: Novel gelatinous compositions and articles are formed from an intimate melt blend admixture of poly(styrene-ethylene-butylene-styrene) triblock copolymer and high levels of a plasticizing oil.The gelatinous composition is transparent and have a novel combination of properties including unexpectedly high elongation and tensile strength and excellent shape retention after extreme deformation under high-velocity impact and stress conditions. The gelatinous products of this invention are soft, flexible, and have elastic memory, characterized by a gel rigidity of from about 20 gram to about 700 gram Bloom. These and other properties are particularly essential for the gelatinous composition to have utility as toys, therapeutic hand exercising grips, shock absorbers, acoustical isolators, components for cushions, and other uses.Type: GrantFiled: October 6, 1992Date of Patent: August 2, 1994Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Patent number: 5332789Abstract: Polypropylene based resins and compositions comprising the resin having extremely high stiffness, heat resistance and impact strength, with these properties being well-balanced, are provided. The polypropylene based resins are characterized by comprising:(1) a propylene polymer having a content of alpha-olefin other than propylene of not more than 4 mole percent, and the following properties (2), (3) and (4):(2) a pentad fraction (mmmm fraction) measured by .sup.13 C-NMR of not less than 96.0 percent,(3) a main elution fraction peak position of not less than 118.0.degree. C. and a peak half value width of less than 4.0, these values being measured by the temperature raising separation method, and(4) an intrinsic viscosity of not less than 0.5 dl/g, but not more than 5.0 dl/g; and,(5) a rubber content measured by pulse NMR of more than 25 percent.Type: GrantFiled: February 26, 1993Date of Patent: July 26, 1994Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akira Tanaka, Masaru Nakagawa, Hideo Kusuyama, Sueto Miyazaki, Tatsuya Housaki
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Patent number: 5331046Abstract: The present invention relates to a polyolefinic resin composition having superior paintability which comprises:(A) 40 to 80 parts by weight of a crystalline polypropylene resin;(B) 1 to 50 parts by weight of a thermoplastic olefinic rubber prepared by dynamic-crosslinking 10 to 70 parts by weight of a crystalline polypropylene resin with 90 to 30 parts by weight of an ethylene-.alpha.-olefin rubber;(C) 0.5 to 30 parts by weight of a polypropylene resin modified by grafting a polar monomer which has a physical affinity, but is not reactive, with an ethylene copolymer or ethylene copolymer rubber modified with .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof; and(D) 1 to 40 parts by weight of said modified ethylene copolymer or ethylene copolymer rubber based on 100 parts by weight of the total weight of the components (A),(B) and (C).Type: GrantFiled: October 30, 1992Date of Patent: July 19, 1994Assignee: Lucky LimitedInventors: Suk K. Chang, In S. Seo, Dae W. Hong
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Patent number: 5331047Abstract: Disclosed are films or sheets comprising a blend of 1) a heterophasic olefin polymer composition and 2) a copolymer of ethylene with a CH.sub.2 .dbd.CHR alpha-olefin, where R is a C.sub.1-8 straight or branched alkyl.Coextruded films or sheets and laminates wherein at least one layer is a film or sheet as described above, and films or sheets of blends of the olefin polymer composition and another olefin polymer are also disclosed.Type: GrantFiled: February 17, 1993Date of Patent: July 19, 1994Assignee: Himont IncorporatedInventor: James Giacobbe
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Patent number: 5317035Abstract: Polyolefin resin compositions and oriented microporous films prepared from same comprising an ethylene-propylene block copolymer having an ethylene content of about 10 to about 50 wt %, a propylene homopolymer or random propylene copolymer having up to about 10 wt % of a comonomer of ethylene or an .alpha.-olefin of 4 to 8 carbon atoms, a low molecular weight polypropylene, a beta-spherulite nucleating agent and an inorganic filler. The microporous films have improved breathability, strength, toughness and break elongation.Type: GrantFiled: December 18, 1992Date of Patent: May 31, 1994Assignee: Amoco CorporationInventors: Philip Jacoby, Charles W. Bauer, Scott R. Clingman, William T. Tapp
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Patent number: 5314951Abstract: A branched block copolymer is described, which can be defined by the formula (B.sub.1 --T--A--B.sub.2).sub.n X, where B.sub.1 and B.sub.2 are polydiene blocks, A is an aromatic polyvinyl block, T is a random copolymer segment made up of dienic monomeric and aromatic vinyl units, X is a coupling radical having a valence equal to n, and n is a whole number ranging from 3 to 20.This kind of block copolymer is used in formulations of adhesives having an excellent balance of adhesive, cohesive, rheological characteristics, as well as resistance to heat oxidation, and in compositions together with thermoplastic polymers capable of giving products with improved shock resistance and transparency.Type: GrantFiled: April 28, 1993Date of Patent: May 24, 1994Assignee: Enichem Elastomeri S.R.L.Inventors: Sergio Custro, Alessandro Zazzetta
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Patent number: 5310804Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.Type: GrantFiled: June 5, 1992Date of Patent: May 10, 1994Assignee: Novacor Chemicals (International) S.A.Inventors: Gregory Beaucage, Richard S. Stein
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Patent number: 5304599Abstract: An extrudable elastomeric composition includes an elastomeric polymer and a tackifying resin in which the extrudable elastomeric composition is adapted to form an elastic sheet having a stress relaxation of less than about 30 percent. The elastomeric polymer is a styrene-poly(ethylene-propylene)-styrene thermoplastic elastomeric block copolymer or a mixture of styrene-poly(ethylene-propylene)-styrene and styrene-poly(ethylene-butylene)-styrene elastomeric block copolymers. The extrudable elastomeric composition may also include a polyolefin and/or an extending oil.Type: GrantFiled: September 27, 1991Date of Patent: April 19, 1994Assignee: Shell Oil CompanyInventor: Glenn R. Himes
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Patent number: 5300582Abstract: Novel block copolymers are disclosed of the formula(AB).sub.p (B).sub.q Xwherein A is polymerized monovinylaromatic compound, B is polybutadiene, X is the residue of a polyfunctional curing agent, p has a number average value of at least 1.5, q has a number average value of at least 0, and p+q are at least 4. Also disclosed are compositions useful as radiation curable adhesives which comprise the block copolymer and a tackifying resin.Type: GrantFiled: June 4, 1993Date of Patent: April 5, 1994Assignee: Shell Oil CompanyInventors: Eric R. S. Debier, Martine J. Dupont
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Patent number: 5298560Abstract: A partially crosslinked thermoplastic resin composition is prepared by dynamically heat-treating a thermoplastic resin (A) in the presence of a carbon radical inducing agent (B) comprising a charge transfer complex or a combination of a hydrogen donating compound and a hydrogen accepting compound.Type: GrantFiled: May 14, 1991Date of Patent: March 29, 1994Assignee: Nippon Petrochemicals Company, LimitedInventors: Fuyuki Aida, Masaaki Miyazaki, Mamoru Nagai
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Patent number: 5292806Abstract: Blends of low styrene content polystyrene-polyisoprene-polystyrene block copolymer and high styrene content polystyrene-polyisoprene-polystyrene block copolymer can be used with tackifier resins, plasticizer oil and antioxidants to formulate pressure sensitive adhesives of improved cohesive strength vis-a-vis adhesives formed from the low styrene content polystyrene-polyisoprene-polystyrene block copolymer while maintaining good balance between tack, bonding characteristics and heat resistance.Type: GrantFiled: December 11, 1990Date of Patent: March 8, 1994Assignees: The Dow Chemical Company, Exxon Chemical Patents, Inc.Inventors: Charles F. Diehl, Jean M. Tancrede
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Patent number: 5290837Abstract: A thermoplastic composition based on a polyolefin and a vinyl aromatic polymer, having an improved combination of physical, mechanical and thermal properties, comprising:from 40 to 80% by weight of a vinyl aromatic polymer (A) containing, as an elastomeric component, from 0.5 to 5% by weight of a vinyl aromatic monomer - conjugated diene linear block polymer and from 5 to 15% of a diene rubber, from 5 to 50% by weight of a polyolefin (B) and from 10 to 50% by weight of an olefinic elastomer (C) containing, grafted thereon, a vinyl aromatic polymer, wherein the molar ratio between the vinyl aromatic polymer and the olefinic elastomer in the grafted phrase is greater than 0.8, the sum of components (A), (B) and (C) being equal to 100%.Type: GrantFiled: November 12, 1991Date of Patent: March 1, 1994Assignee: ECP Enichem Polimeri S.r.L.Inventors: Dario Ghidoni, Gian C. Fasulo, Aldo Longo, Italo Borghi
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Patent number: 5286540Abstract: A blow molded container made of a polypropylene resin obtained by injection stretch blow molding of a polypropylene resin in which the polypropylene resin is a propylene polymer composition containing from 0.0001 to 10% by weight of 3-methylbutene-1 polymer, as well as medical instruments comprising the blow molded container made of the polypropylene resin.Type: GrantFiled: March 19, 1993Date of Patent: February 15, 1994Assignee: Mitsubishi Kasei CorporationInventors: Yoshinori Suga, Eiji Tanaka, Tsunemi Yoshioka, Masaaki Uchida, Hidehito Kato, Masayuki Arai
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Patent number: 5280071Abstract: The present invention relates to a composition which exhibits antiozonant activity in diene containing rubbers comprising the reaction product of a multi-step process comprising:(1) reacting under condensation conditions an aldehyde and an amine containing compound to form a condensation product, whereinsaid aldehyde is selected from the group consisting of formaldehyde, acetaldehyde or mixtures thereof; andsaid amine containing compound is selected from the group consisting of:N,N'-di-substituted-p-phenylene diamines of the structural formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently selected from the group of radicals consisting of alkyls having 3 to 12 carbon atoms, aryls having 6 to 12 carbon atoms and aralkyls having 7 to 12 carbon atoms; and wherein said condensation conditions include:(i) the presence of an acid catalyst,(ii) a mole ratio of aldehyde to amine containing compound ranging from about 1.Type: GrantFiled: April 5, 1991Date of Patent: January 18, 1994Assignee: The Goodyear Tire & Rubber CompanyInventors: Budd H. Sturm, Joseph A. Kuczkowski, Paul H. Sandstrom, George F. Balogh
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Patent number: 5278232Abstract: A thermoplastic molding material contains, in each case based on the sum of the constituents A, B and C,A: 10 to about 90% by weight of a styrene polymer A,B: 10 to about 90% by weight of a polyolefin B, andC: 1 to 20% by weight of an unsymmetrical linear three-block copolymer C of the structure S.sub.1 -D-S.sub.2, prepared by anionic polymerization from styrene and butadiene and/or isoprene, S.sub.1 and S.sub.2 each denoting a polystyrene block and D denoting a polydiene block,wherein the three-block copolymer C has a styrene content, based on C, of from 50 to 85% by weight and the terminal blocks S.sub.1 and S.sub.2 built up from styrene differ by at least 50% in their molecular weight.Type: GrantFiled: November 30, 1992Date of Patent: January 11, 1994Assignee: Base AktiengesellschaftInventors: Stefan Seelert, Hans Hoenl, Bertram Ostermayer, Andreas Jung, Peter Klaerner
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Patent number: 5276094Abstract: An elastomeric polymer composition that exhibits improved processability and green strength comprises: from about 95 to about 70 parts by weight of one rubbery polymer selected from the group consisting of butyl rubber, chlorinated butyl rubber and brominated butyl rubber and from about 5 to about 30 parts by weight of a block copolymer having an elastomeric polyisobutylene midblock and two plastomeric endblocks of polymerized monovinylidene aromatic monomers and star-shaped block copolymers having from three to six arms wherein the inner elastomeric blocks are polyisobutylene and the outer plastomeric blocs are polymerized monovinylidene aromatic monmers for a total of 100 parts by weight of the rubbery polymer and the block copolymer. Vulcanizates of the composition that exhibit reduced permeability to gases and improved tear strength are provided together with a process for their production.Type: GrantFiled: November 12, 1992Date of Patent: January 4, 1994Assignee: Polysar Rubber Corp.Inventors: Gabor Kaszas, Judit E. Puskas
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Patent number: 5266636Abstract: A process for producing polypropylene, which comprises preliminarily polymerizing 3-methylbutene-1 in the presence of a catalyst system formed from[A] a solid titanium catalyst component containing magnesium, titanium, halogen and polycarboxylic acid esters as essential components,[B] an organoaluminum compound, and[C] an organosilicon compound represented by the general formula R.sub.n Si(OR').sub.4-n wherein R and R' represent a hydrocarbon group, and 0<n<4, the amount of the 3-methylbutene-1 preliminarily polymerized being 0.1 to 100 g per gram of the solid titanium catalyst, and thereafter, polymerizing propylene or copolymerizing propylene and an alpha-olefin in the presence of the catalyst used in the preliminary polymerization to such an extent that the amount of the monomer or monomers polymerized is from 1,000 to 100,000 times the amount of the 3-methylbutene-1 preliminarily polymerized.Type: GrantFiled: August 11, 1992Date of Patent: November 30, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Kioka, Masaya Yamada, Masanobu Ishiyama, Masao Nakano, Akinori Toyota
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Patent number: 5264479Abstract: The invention relates to lactam mixtures which give lactam melts having increased viscosity, to their production and to their use, preferably in the activated anionic polymerization of lactams (to cast polyamides). According to the invention, certain unsaturated aromatic vinyl compound/diene block copolymers (B) which dissolve in the lactam melt are added to the lactam (melt)s (A) in quantities of 1 to 15% by weight, a component (C) which is compatible with the diene block copolymers (B) and which dissolves completely or partly in the lactam melt optionally being added as an additional component. The block copolymers (B) used contain 10 to 85% by weight aromatic vinyl units and 15 to 90% by weight diene units. The block copolymers (B) may even be partly hydrogenated, epoxidized or grafted.The preferred lactam is .epsilon.-caprolactam.Lactam melts of increased viscosity are particularly suitable for taking up reinforcing materials and fillers (D) and for the production of filled cast polyamides.Type: GrantFiled: April 20, 1993Date of Patent: November 23, 1993Assignee: Bayer AktiengesellschaftInventors: Hans-Detlef Heinz, Friedrich Fahnler
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Patent number: 5262479Abstract: Improved plasticizer resistant pressure sensitive hot melt adhesive compositions are prepared by incorporating in the adhesive polymer, tackifying resin and oil 5 to 70% by weight of the adhesive of a core shell modifier comprising a crosslinked rubbery core and a glassy thermoplastic polymer shell, the core being crosslinked by the presence therein of up to 5% by weight of a polyunsaturated monomer having two or more non-conjugated sites of unsaturation of unequal reactivity.Type: GrantFiled: November 24, 1992Date of Patent: November 16, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventor: Singa D. Tobing
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Patent number: 5262468Abstract: A novel gelatinous composition is disclosed which contains an intimate melt blend admixture of poly(styrene-ethylene-butylene-styrene) triblock copolymer and high levels of a plasticizing oil.The gelatinous composition is transparent and have a novel combination of properties including unexpectedly high elongation and tensile strength and excellent shape retention after extreme deformation under high-velocity impact and stress conditions. The gelatinous products of this invention are soft, flexible, and have elastic memory, characterized by a gel rigidity of from about 20 gram to about 700 gram Bloom. These and other properties are particularly essential for the gelatinous composition to have utility as toys, therapeutic hand exercising grips, shock absorbers, acoustical isolators, and other uses.Type: GrantFiled: May 23, 1991Date of Patent: November 16, 1993Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Patent number: 5262213Abstract: The subject invention discloses a styrene-butadiene rubber (SBR) which is particularly valuable for use in making truck tire treads, said rubber being comprised of repeat units which are derived from about 10 weight percent to about 20 weight percent styrene and from about 80 weight percent to about 90 weight percent 1,3-butadiene, wherein the repeat units derived from styrene and 1,3-butadiene have a sequence distribution wherein at least about 55% of the styrene repeat units are in blocks of only one styrene repeat unit, wherein at least about 75% of the styrene repeat units are in blocks of 1 or 2 repeat units, and wherein at least about 5% of the styrene repeat units are in blocks of more than 8 repeat units, wherein from about 32% to about 40% of the repeat units derived from the 1,3-butadiene are of the cis-microstructure, wherein from about 50% to about 60% of the repeat units derived from the 1,3-butadiene are of the trans-microstructure, wherein from about 6% to about 15% of the repeat units derivedType: GrantFiled: September 14, 1992Date of Patent: November 16, 1993Assignee: The Goodyear Tire & Rubber CompanyInventors: Michael B. Rodgers, Adel F. Halasa, Wen-Liang Hsu, Barry A. Matrana, Stanley M. Mezynski
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Patent number: 5256734Abstract: A resin composition is herein provided which comprises 100 parts by weight of a polypropylene and 20 to 100 parts by weight of a hydrogenated styrene/butadiene or styrene/isoprene elastomeric block copolymer having a melt index of not less than 25 g/10 min as determined at a temperature of 230.degree. C. and a load of 2.16 kg/cm.sup.2. A method for manufacturing a coated molded article of the resin composition is herein provided and the method comprises the steps of molding said resin composition and then applying a coating directly without any preliminary surface treatment. This method can provide a molded article having low mold shrinkage factor and linear expansion coefficient, makes it possible to reduce the amount of fillers to be incorporated and is thus effective for making the weight of automobiles lighter.Type: GrantFiled: February 11, 1992Date of Patent: October 26, 1993Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Eiichi Sugihara, Keigo Suehiro, Katsumi Sekiguchi, Minoru Hoshino
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Patent number: 5254628Abstract: Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from aromatic nitrile coumpounds.The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using aromatic nitrile compounds. The resultant diene polymers or copolymers have improved raw polymer viscosity and when compounded with carbon black and cured have reduced hysteresis properties. The polymers can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.Type: GrantFiled: November 18, 1991Date of Patent: October 19, 1993Assignee: Bridgestone CorporationInventors: David F. Lawson, Mark L. Stayer, Jr., Thomas A. Antkowiak
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Patent number: 5252664Abstract: Tough transparent thermoplastics blends may be prepared by blending 10 to 99 weight percent of a block copolymer; 0.1 to 1 weight percent of particulate rubber having a particle size from 0.1 to 10 microns; and the balance a clear glassy polymer. These clear polymers are useful in a number of applications, particularly for those applications requiring quite high toughness and transparency such as packaging, containers or protective covering.Type: GrantFiled: June 27, 1991Date of Patent: October 12, 1993Assignee: Polysar LimitedInventors: Ronald J. Thompson, James Lunt, John C. Lamont, John C. Kwok
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Patent number: 5237007Abstract: A tough transparent polymer alloy comprises from 98 to 85 weight % of a styrene acrylic polymer and from 2 to 15 weight % of a blend comprising from 70 to 90 weight % of a high styrene styrene-butadiene polymer and from 30 to 10 weight % of a high butadiene styrene-butadiene polymer. The resulting alloy has good clarity and impact properties.Type: GrantFiled: March 9, 1992Date of Patent: August 17, 1993Assignee: Novacor Chemicals (International) S.A.Inventor: Michael Colella
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Patent number: 5218047Abstract: Polymer blends containa) from 20 to 70% by weight of a propylene copolymer which in turn consists of from 20 to 65% by weight of a propylene homopolymer and 30 to 85% by weight of a random propylene copolymer containing polymerized C.sub.2 -C.sub.10 -alk-1-enes andb) from 30 to 80% by weight of a polyethylene having a density of from 0.94 to 0.98 g/cm.sup.3 and a melt flow index of less than 15 g/10 min at 190.degree. C. under a weight of 2.16 kg.The novel polymer blends possess, inter alia, high rigidity, high impact strength and little tendency to undergo white fracture and are particularly suitable for the production of films and moldings.Type: GrantFiled: June 12, 1991Date of Patent: June 8, 1993Assignee: BASF AktiengesellschaftInventors: Harald Schwager, Klaus-Dieter Ruempler, Hans-Georg Braun
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Patent number: 5218048Abstract: A resin composition comprising (A) a thermoplastic resin, (B) a functional compound having one or more bonds or one or more functional groups selected from the group consisting of organic groups having a non-aromatic carbon-carbon multiple bonds, oxirane groups and substituted carboxyl groups and (C) a diamino compound represented by the following general formula:R.sup.I NH--X--NHR.sup.IIwherein R.sup.I and R.sup.II each represents a hydrogen atom or an alkyl group optionally having one or more inactive substituents, and X represents an alkylene group having 7 to 30 carbon atoms and optionally having one or more inactive substituents.Type: GrantFiled: December 10, 1990Date of Patent: June 8, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroomi Abe, Kenji Nagaoka, Takashi Sanada
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Patent number: 5212246Abstract: Disclosed are films or sheets comprising an olefin polymer composition which is comprised of(a) from about 10 to 50 parts of a propylene homopolymer having an isotactic index greater than 80, or a copolymer of propylene with ethylene and/or an another alpha-olefin, containing over 80% propylene and having an isotactic index greater than 80;(b) from about 5 to 20 parts of a semi-crystalline copolymer fraction, which copolymer is insoluble in xylene at room or ambient temperature; and(c) from about 40 to 80 parts of a copolymer fraction of ethylene with propylene and/or another alpha-olefin, and optionally with minor amounts of a diene, said copolymer fraction containing less than 40% ethylene and/or other alpha-olefin, being soluble in xylene at room temperature, and having an intrinsic viscosity from 1.5 to 4 dl/g.Type: GrantFiled: August 27, 1991Date of Patent: May 18, 1993Assignee: Himont IncorporatedInventor: Kumar Ogale
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Patent number: 5210109Abstract: This invention provides hardenable compositions useful as construction media for a wide range of applications. Particular utility is found in the dental and medical arts where such compositions are highly suitable for the formation and construction of denture base, denture baseplates, denture liners, denture repair, custom trays, veneering for crowns and bridgework, artificial teeth, veneers and repair for natural teeth, and tooth restorative fillings. Such materials having improved impact strengths and elastic moduli when hardened are disclosed which include rubber-modified polymer.Type: GrantFiled: September 21, 1992Date of Patent: May 11, 1993Assignee: Dentsply Research & Development Corp.Inventors: Louis H. Tateosian, W. Donald Wilson
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Patent number: 5210142Abstract: Polymer blends of at least one ethylene interpolymer product and at least one linear polyethylene are disclosed. The blends have a shear rate at the point of onset of melt fracture at least about 2 percent higher than that obtained for the linear polyethylene alone. The polymer blends are particularly useful for forming films and tapes wherein the melt fracture of the polymer blend is substantially reduced or eliminated, thereby improving extrudability and fabricated article appearance.Type: GrantFiled: February 13, 1992Date of Patent: May 11, 1993Assignee: The Dow Chemical CompanyInventors: Lawrence T. Kale, Lionel H. Dagenais, Shih-Yaw Lai, William R. Van Volkenburgh, John O. Bieser
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Patent number: 5210147Abstract: A predominantly linear 100% triblock sequentially polymerized hydrogenated styrene-isoprene-styrene block copolymer composition comprised of linear polymeric blocks for use in adhesives, modified thermoplastic compositions and mechanical goods.Type: GrantFiled: May 20, 1991Date of Patent: May 11, 1993Assignee: Shell Oil CompanyInventors: Jeffrey G. Southwick, Earle E. Ewins, Jr., David J. St. Clair
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Patent number: 5206301Abstract: A hydrogenated block copolymer having a number-average molecular weight of 40,000-700,000, obtained by hydrogenating at least 80% of the olefinic bonds of a block copolymer having in the molecule at least one each ofa polymer block A composed of 90% by weight or more of a vinyl aromatic compound,a polybutadiene polymer block B having a 1,2-vinyl structure of 30-70%, anda polybutadiene polymer block C having a 1,2-vinyl structure of less than 30%,in which block copolymer the blocks A, B and C are contained at a specific ratio, or a unit of the block copolymer is bonded, via a coupling agent residue, to at least one polymer block unit of the blocks A, B and C and thereby the polymer molecular chain is extended or branched; and a thermoplastic resin composition comprising the hydrogenated block copolymer.Type: GrantFiled: July 12, 1990Date of Patent: April 27, 1993Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Iwakazu Hattori, Noboru Oshima, Tooru Shibata, Yasuo Takeuchi