Solid Block Or Block-type Copolymer Derived From Reactant Containing Plural Unsaturation Patents (Class 525/98)
  • Patent number: 8853328
    Abstract: The present invention relates to a sheet composition containing at least one of either a polystyrene-based copolymer or an ethylene vinyl acetate-based copolymer, to a sheet produced from the same, to a laminated sheet containing the sheet, and to a composite sheet containing the laminated sheet. The sheet according to the present invention is provided with a high functional stability including wear resistance, oil resistance, and aging resistance, and superior embossing retention characteristics.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: October 7, 2014
    Assignee: LG Hausys, Ltd.
    Inventors: Sang-Deuk Choi, Kyeung-Ho Kim, Yong-Gu Kweon, Kyo-Hoon Shin
  • Patent number: 8853326
    Abstract: An RF-weldable thermoplastic elastomer composition, including a thermoplastic elastomer of non-RF-weldable or poorly RF-weldable character, e.g., a styrenic copolymer/olefinic polymer blend thermoplastic elastomer, and polyol in an amount that is less than 1% by weight, based on weight of the thermoplastic elastomer, and is effective to enhance RF-weldability of the thermoplastic elastomer. The composition may also contain an antistatic ionomer, in an amount that is less than 15% by weight, based on weight of the thermoplastic elastomer. Films of such composition are usefully employed to form RF-welded film articles, such as blood bags, IV fluid bags, glucose bags, urine bags, stool bags, biological sample bags, pouches, covers, and liners.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: October 7, 2014
    Assignee: Polyzen Inc.
    Inventors: Tilak M. Shah, Kimberly Ogburn, Christopher D. Strom
  • Patent number: 8853306
    Abstract: The invention relates to a bituminous composition containing at least one bitumen and at least one polyolefin capable of forming a supramolecular assembly comprising one or more associative group(s). The invention also relates to the use of such bituminous composition for the preparation of asphalt mixtures useful for the coating of rolling surfaces, for the preparation of water-proofing coatings, and for the preparation of adhesive formulations.
    Type: Grant
    Filed: August 18, 2010
    Date of Patent: October 7, 2014
    Assignee: Ceca S.A.
    Inventors: Juan Antonio Gonzalez Leon, Gilles Barreto
  • Publication number: 20140288228
    Abstract: The present invention relates to polypropylene compositions with a balance of high strength, good clarity, excellent stress whitening resistance, and excellent impact properties—especially at low temperatures—for use in demanding plastics applications. Blends consist of both homopolymer and random copolymer polypropylene fractions, as well as propylene-ethylene elastomers and styrenic based elastomers. The invention also covers molded articles made from these blends.
    Type: Application
    Filed: March 18, 2014
    Publication date: September 25, 2014
    Applicant: Asahi Kasei Plastics North America, Inc.
    Inventors: Sameer G. MEHTA, Michael James BALOW, Vaibhav Vishnu APTE, Laura Therese Shereda
  • Patent number: 8835560
    Abstract: Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: September 16, 2014
    Assignee: Styrolution GmbH
    Inventors: Konrad Knoll, Daniel Wagner, Andrea Colombo, Geert Verlinden
  • Patent number: 8835561
    Abstract: Branched block polymers, and the rubber compositions containing them, which can be used, in particular, for manufacturing tires or semi-finished products for tires. Processes for preparing said polymers and compositions are also disclosed.
    Type: Grant
    Filed: July 31, 2006
    Date of Patent: September 16, 2014
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Sylvie Gandon-Pain, Alain Hut
  • Patent number: 8835562
    Abstract: Improved methods for preparing sulfonated block polymers with acyl sulfates in non-halogenated aliphatic solvents are provided. The methods include the sulfonation of a precursor block polymer with an acyl sulfate in a reaction mixture further comprising at least one non-halogenated aliphatic solvent to form a sulfonated block polymer, wherein the initial concentration of the precursor block polymer is in the range of from about 0.1 wt % to a concentration that is below the limiting concentration of the precursor block polymer based on the total weight of the reaction mixture. A sulfonation degree of greater than about 1.0 milliequivalent sulfonic acid per gram sulfonated block polymer can be achieved substantially free of polymer precipitation and free of disabling gelation.
    Type: Grant
    Filed: July 7, 2009
    Date of Patent: September 16, 2014
    Assignee: Stepan Company
    Inventors: Gregory Paul Dado, Dale Lee Handlin, Jr., Carl Lesley Willis
  • Patent number: 8822597
    Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: September 2, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel
  • Patent number: 8809456
    Abstract: This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: August 19, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun F. Tse, Aspy K. Mehta, Joann M. Canich, Matthew W. Holtcamp, John R. Hagadorn, Charles J. Ruff
  • Patent number: 8802774
    Abstract: Embodiments of the invention provide block composites comprising a soft copolymer, a hard polymer and a block copolymer having a soft segment and a hard segment, wherein the hard segment of the block copolymer is the same composition as the hard polymer in the block composite and the soft segment of the block copolymer is the same composition as the soft copolymer of the block composite and their use as impact modifiers.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: August 12, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Edmund M. Carnahan, Colin LiPiShan, Kim L. Walton, Gary R. Marchand, Benjamin C. Poon, Phillip D. Hustad, Brian A. Jazdzewski, Didem Oner-Deliormanli
  • Patent number: 8795809
    Abstract: An elastic film material that resists the propagation of a tear. The film material includes an SEEPS elastomeric block copolymer and has a time to break of at least 10 hours. The elastomeric block copolymer has a Tm of between about 10° C. and 20° C.
    Type: Grant
    Filed: February 14, 2011
    Date of Patent: August 5, 2014
    Assignee: The Procter & Gamble Company
    Inventor: Todd Leon Mansfield
  • Publication number: 20140213728
    Abstract: The present invention provides a hydrogenated block copolymer which has an excellent balance in a transparency, optical property, flexibility, mechanical property, moldability, heat resistance, gas barrier property, low moisture absorbency and non-adsorptive property of chemical. Also, the present invention has an object to provide a resin composition containing the hydrogenated block copolymer as a resin component, and a film and container containing the composition. The present invention relates to a hydrogenated block copolymer containing a Block A of a hydrogenated vinyl aromatic polymer and a Block B of a polymer containing isobutylene.
    Type: Application
    Filed: March 31, 2014
    Publication date: July 31, 2014
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Naoyuki KOSAKA, Toshihisa Ishihara, Kenjiro Takayanagi
  • Publication number: 20140197032
    Abstract: Selectively amino- or phosphino-functionalized block copolymers, and their preparation, for use as anion exchange membrane materials. The selectively functionalized block copolymers have at least two end blocks A each of which are substantially free of amino- or phosphino-functional groups, and have at least one interior block D which comprises on average at least one amino- or phosphino-functionalized polymer unit of formula (I) wherein Z is nitrogen or phosphorous; R1 is hydrogen or alkyl; R2 is hydrogen or is tertiary alkyl; R each independently, is hydrogen or is alkyl optionally substituted by a moiety -(A1-NRa)xRb; or two R groups, together with the Z to which they are bonded, form an optionally substituted ring; x is 1, 2 or 3; A1 is straight chain alkylene optionally substituted by one or more methyl and/or ethyl groups; and Ra and Rb, each independently, is hydrogen or alkyl; or a corresponding onium salt.
    Type: Application
    Filed: January 13, 2014
    Publication date: July 17, 2014
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Carl Lesley Willis, Irwan Hidajat, Mike Heniff
  • Publication number: 20140199908
    Abstract: The present invention provides hot melt adhesives for disposable products. The hot melt adhesives may be applied at high-speed and at low temperature ranges. The hot melt adhesives also provide excellent adhesion to polyethylene and a nonwoven fabric. The hot melt adhesive comprises (A) a thermoplastic block copolymer, which is a copolymer of a vinyl-based aromatic hydrocarbon with a conjugated diene compound; and (B) a propylene homopolymer having a melting point of 100° C. or lower, which is obtainable by polymerizing propylene using a metallocene catalyst. The disposable products are produced at high-speeds and low temperature with the inventive hot melt, and therefore, the disposal products are produced efficiently and safely, and a nonwoven fabric and a polyethylene film of the disposable products are less likely to peel.
    Type: Application
    Filed: March 14, 2014
    Publication date: July 17, 2014
    Applicant: HENKEL AG & CO. KGAA
    Inventor: Kentarou INOUE
  • Patent number: 8772415
    Abstract: The disclosure provides a hydrogenated straight-chain block copolymer, obtained by selective hydrogenation of a straight-chain block copolymer.
    Type: Grant
    Filed: August 7, 2007
    Date of Patent: July 8, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yasuhiro Kusanose, Masahiro Fujiwara, Daisuke Shimizu
  • Patent number: 8760040
    Abstract: The present invention relates to one of energy conversion devices, actuator and a dielectric layer used in the actuator. The present invention provides a polymer blend composition capable of easily controlling the ability of converting electrical energy to mechanical energy, which is prepared by blending a piezoelectric polymer with a flexible elastomeric block copolymer showing an effective miscibility therewith, and a tunable actuator using the same.
    Type: Grant
    Filed: November 3, 2011
    Date of Patent: June 24, 2014
    Assignee: Korea Institute of Science and Technology
    Inventors: Chong-Min Koo, Kyung-Youl Baek, Soon-Man Hong, Seung-Sang Hwang, Hee-La Kwak, Kyung-ho Min, Jin-Hong Lee, Kie-Yong Cho, Sang-Hee Park
  • Patent number: 8754169
    Abstract: A method for forming a rubber-modified polymeric composition includes polymerizing vinyl aromatic monomer within a mixture including the vinyl aromatic monomer and an interpolymer having at least one block of polyisoprene, at lest one block of polystyrene, and at lest one block of polybutadiene to thereby form the rubber-modified polymeric composition, where the interpolymer includes an internal block of polyisoprene.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: June 17, 2014
    Assignee: Bridgestone Corporation
    Inventors: Mark N. Dedecker, James E. Hall, Daniel F. Graves
  • Patent number: 8741973
    Abstract: The invention relates to elastic expanded polymer foams and also a process for producing expanded polymer foams by sintering a mixture comprising foam particles P1 and P2 composed of different thermoplastic polymers or polymer blends, wherein the foam particles P1 are obtained by prefoaming expandable, thermoplastic polymer particles comprising A) from 45 to 97.9 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin having a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin having a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer, C2) from 0.0 to 10 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent, where the sum of A) to E) is 100% by weight.
    Type: Grant
    Filed: March 1, 2010
    Date of Patent: June 3, 2014
    Assignee: BASF SE
    Inventors: Carsten Schips, Jens Aβmann, Georg Gräβel, Geert Janssens, Maximillian Hofmann, Holger Ruckdäschel, Jürgen Lambert, Christof Zylla
  • Patent number: 8734956
    Abstract: The present invention provides a polybutylene terephthalate resin composition which satisfies performances such as high durability in an environment of heating and cooling cycles and adhesion properties to an addition-reaction type silicone rubber. Specifically, provided is the polybutylene terephthalate resin composition, exhibiting excellent adhesion properties to the addition-reaction type silicone rubber, including: (A) 100 parts by weight of polybutylene terephthalate resin; (B) 5 to 30 parts by weight of a styrene-based thermoplastic elastomer containing 40% by weight or less of styrene component; and (C) 20 to 100 parts by weight of glass fiber.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: May 27, 2014
    Assignee: Wintech Polymer Ltd.
    Inventors: Kouichi Sakata, Hiroyuki Amano
  • Patent number: 8729143
    Abstract: Expandable, thermoplastic polymer bead material composed of a multiphase polymer mixture which comprises blowing agent and has at least one continuous phase of a thermoplastic polymer, where at least two different disperse phases P1 and P2 are present, disperse in the continuous phase, and also to processes for its production, and to use for the production of elastic molded foams.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: May 20, 2014
    Assignee: BASF SE
    Inventors: Carsten Schips, Klaus Hahn, Maximilian Hofmann, Holger Ruckdäschel, Jens Assmann, Geert Janssens, Georg Gräβel, Jurgen Lambert, Christof Zylla
  • Patent number: 8722799
    Abstract: There is provided a thermoplastic elastomer composition having excellent flexibility, mechanical properties, scratch resistance, abrasion resistance, and low-temperature characteristics. A crosslinked thermoplastic elastomer composition comprising 5 to 70 parts by mass of (C) a hydrogenated product of a block copolymer having at least one conjugated diene monomer unit block and at least one vinyl aromatic monomer unit block, and 20 to 150 parts by mass of (D) an olefin-based resin, based on 100 parts by mass of the total of (A) an ethylene-?-olefin copolymer comprising an ethylene unit and an ?-olefin unit having 3 to 20 carbon atoms, and (B) a copolymer having at least one hydrogenated copolymer block mainly composed of a conjugated diene monomer unit and a vinyl aromatic monomer unit, wherein a mass ratio ((A)/(B)) of the (A) component and the (B) component is from 20/80 to 75/25.
    Type: Grant
    Filed: December 4, 2009
    Date of Patent: May 13, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yutaka Eguchi, Shinichi Shibayama, Yoshifumi Araki
  • Patent number: 8716400
    Abstract: Embodiments of the invention provide block composites comprising a soft copolymer, a hard polymer and a block copolymer having a soft segment and a hard segment, wherein the hard segment of the block copolymer is the same composition as the hard polymer in the block composite and the soft segment of the block copolymer is the same composition as the soft copolymer of the block composite and their use as impact modifiers.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: May 6, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Edmund M. Carnahan, Colin Lipishan, Kim L. Walton, Gary R. Marchand, Benjamin C. Poon, Phillip D. Hustad, Brian A. Jazdzewski, Didem Oner-Deliormanli
  • Patent number: 8709560
    Abstract: Polymeric compositions and methods of making and using such compositions are provided. The compositions incorporate a first polymeric component that is at least one high density polyethylene and a second polymeric component that is at least one polymer including propylene-derived units having a heat of fusion of less than 75 J/g wherein the propylene-derived units have an isotactic triad fraction of about 65% to about 99%. The polymeric compositions are found to have desirable environmental stress crack resistance properties and impact resistance properties. The polymeric compositions are useful in a variety of applications such as molded containers and extruded pipes.
    Type: Grant
    Filed: September 16, 2005
    Date of Patent: April 29, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Srivatsan Srinivas Iyer, Thomas Michael Miller
  • Patent number: 8691884
    Abstract: Crosslinked flame retardant thermoplastic elastomer gels are provided. The crosslinked flame retardant thermoplastic elastomer gels comprise a char catalyst, a char former, a maleic anhydride-modified styrene ethylene/butylene styrene polymer, and a softener oil. Methods are provided of making crosslinked flame retardant thermoplastic elastomer gels.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: April 8, 2014
    Assignee: Tyco Electronics Corporation
    Inventors: Mark W. Ellsworth, Michael A. Oar, Miguel A. Morales
  • Patent number: 8664320
    Abstract: A film composition comprising one or more propylene-based polymers and one or more hydrocarbon resins, and methods for making the same are provided. The propylene-based polymer may have (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences, and (iii) a heat of fusion less than 65 J/g. The hydrocarbon resin may have a glass transition temperature greater than 20° C.
    Type: Grant
    Filed: December 7, 2012
    Date of Patent: March 4, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Michael Glenn Williams
  • Publication number: 20140058040
    Abstract: The present invention is concerned with a resin composition containing an olefin-based resin and a copolymer of a conjugated diene compound and a non-conjugated olefin. In view of the fact that the copolymer is a block copolymer, the impact resistance and low temperature properties can be enhanced.
    Type: Application
    Filed: March 5, 2012
    Publication date: February 27, 2014
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Takayuki Yako, Atsushi Fukushima
  • Patent number: 8648139
    Abstract: An elastic film for a hygienic article is made by first premixing polymer components to form a polymer composite that contains styrene block copolymers and then extruding the polymer composite to make at least one layer. During the premixing or the extruding zeolites are added having pores of a size larger than 2.5 Angstrom and smaller than 5.5 Angstrom.
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: February 11, 2014
    Assignee: Mondi Gronau GmbH
    Inventor: Mike Rolefs
  • Patent number: 8637604
    Abstract: A block copolymer comprising at least one polymer block A comprising conjugated diene monomer units, and at least one polymer block B comprising conjugated diene monomer units and aromatic vinyl monomer units. This block copolymer is characterized in that (1) the polymer block A has a glass transition temperature of ?88° C. to ?45° C., (2) the polymer block B has a glass transition temperature of 30° C. to 90° C., (3) the content of aromatic vinyl monomer units in the whole block copolymer is 3-52 wt. %, (4) the aromatic vinyl block ratio in the whole block copolymer is smaller than 69 wt. %, and (5) the viscosity of a 5 wt. % solution of the block copolymer in styrene is 30-80 mPa·s. The block copolymer is useful as a resin modifier.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: January 28, 2014
    Assignee: Zeon Corporation
    Inventors: Masao Nakamura, Kazuya Ito, Hidenori Yamagishi
  • Patent number: 8629213
    Abstract: The invention relates to a composition including at least one elastomer and at least one supramolecular polymer. The supramolecular polymer is obtained by the reaction of at least one trifunctional compound (A), having first and second functions, with: at least one compound (B) having at least one reactive group capable of reacting with the first functions of (A) and at least one associative group; and at least one at least bifunctional compound (C) having functions capable of reacting with the second functions of compound (A) in order to form ester, thioester and amide bridges.
    Type: Grant
    Filed: September 21, 2010
    Date of Patent: January 14, 2014
    Assignee: Arkema France
    Inventors: Manuel Hidalgo, Christelle Plaut, Alfredo Defrancisci
  • Patent number: 8618214
    Abstract: Provided is a fiber-reinforced composite. The composite has a propylene polymer including 90 wt % or more of propylene monomeric units based on the weight of the propylene polymer; a plurality of fibers of a solid, flexible material grafted to the propylene polymer; and an elastomer. The fibers are present in the composite at 10 wt % to 80 wt % based on the total weight of the composite. The propylene polymer is present in the composite at from 30 wt % to 95 wt % based on the total weight of the composite. The elastomer is present in the composite at from 5 wt % to 50 wt % based on the total weight of the composite. Greater than 50 wt % of the fibers are dispersed within the propylene polymer based on the total weight of the fibers in the composite. There is also provided a process for making a fiber-reinforced composite.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: December 31, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Andy Haishung Tsou, John Henry Dunsmuir, Donald Andrew Winesett
  • Publication number: 20130331519
    Abstract: A resin composition having as a main ingredient a block copolymer composed of at least one type of vinyl aromatic hydrocarbon and a conjugated diene, the resin composition being characterized in that the Vicat softening point temperature measured under a 10-N load as per ISO306 is 65-90° C., the flexural strength measured as per ISO178 is 58-80 MPa, the proportion of the conjugated diene in the resin composition is 10-25 mass %, and the resin composition has molecular weight peaks, the peaks being derived from the block copolymer composed of the vinyl aromatic hydrocarbon and the conjugated diene, at molecular weights in the ranges of 70,000-150,000 and 150,000-350,000, respectively.
    Type: Application
    Filed: February 24, 2012
    Publication date: December 12, 2013
    Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHA
    Inventors: Tadashi Sawasato, Eiji Sato, Katumi Ito
  • Publication number: 20130324656
    Abstract: Provided are a block copolymer and a thermoplastic elastomer composition each of which is excellent in both tensile strength and elastic recovery, and has good abrasion resistance. Specifically, provided are a hydrogenated block copolymer, which is obtained by hydrogenating a block copolymer having two or more polymer blocks (a) each containing a structural unit derived from an aromatic vinyl compound and one or more polymer blocks (b) each containing structural units derived from isoprene and 1,3-butadiene, in which the hydrogenated block copolymer has a crystallization peak temperature (Tc) defined as described below of ?3 to 15° C., and a thermoplastic elastomer composition containing the hydrogenated block copolymer: (crystallization peak temperature (Tc)) a peak top temperature of an exothermic peak observed when the temperature of a sample is increased from 30° C. to 150° C. at a rate of temperature increase of 10° C./min and then the sample is cooled to ?100° C.
    Type: Application
    Filed: February 14, 2012
    Publication date: December 5, 2013
    Applicant: KURARAY CO., LTD.
    Inventors: Yosuke Jogo, Kenji Shachi, Nobuhiro Moriguchi
  • Patent number: 8598275
    Abstract: A golf ball has a layer comprising a compatibilized blend of thermoplastic polyurethane, polyolefin, and hydrophobic thermoplastic polyurethane. The layer may be part of the cover, for example an inner layer of a two-layer cover layer. The layer may be an intermediate layer between the core and the cover.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: December 3, 2013
    Assignee: Nike, Inc.
    Inventor: Bradley C. Tutmark
  • Patent number: 8592522
    Abstract: The object of the present invention is to provide an oxygen-absorbing resin composition having a high oxygen absorbability and capable of absorbing oxygen for a long period of time. The present invention provides an oxygen-absorbing resin composition comprising polyolefin resin (A) obtained by polymerizing an olefin having 2 to 8 carbon atoms, resin (B) which is other than resin (A) and which acts as a trigger for the oxidation of resin (A), and transition metal catalyst (C), wherein resin (B) is dispersed in the matrix of resin (A) so that the oxidation reaction of matrix resin (A) is caused and thus oxygen is absorbed when the oxygen-absorbing resin composition is brought into contact with oxygen. This oxygen absorbing resin composition has a high oxygen absorbability and is advantageous in cost because oxygen is absorbed in resin (A).
    Type: Grant
    Filed: February 23, 2005
    Date of Patent: November 26, 2013
    Assignee: Toyo Seikan Kaisha, Ltd.
    Inventors: Ikuo Komatsu, Hiroaki Goto, Shigenobu Murakamai, Takayuki Ishihara
  • Patent number: 8592035
    Abstract: To provide a pressure-sensitive adhesive composition for a removable pressure-sensitive adhesive tape which can be, after attaching to an adherend, easily removed from the adherend by stretching the pressure-sensitive adhesive tape and does not cause adhesive transfer on the adherend or damage of the adherend. A pressure-sensitive adhesive composition comprises a cohesive component comprising a styrene-based block copolymer, and a basic component.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: November 26, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Aizoh Sakurai, Eiji Mizuno
  • Publication number: 20130299731
    Abstract: The invention relates to unique applications for the novel high melt flow, low viscosity, selectively hydrogenated styrene-butadiene-styrene (hSBS) or selectively hydrogenated controlled distribution styrene-butadiene/styrene-styrene (hSBSS) block copolymers, wherein the melt flow rate of said block copolymer is at least 100 g/10 min. at 230° C. under 2.16 kg mass according to ASTM D1238. These block copolymers are novel and have the highest melt flow rate of any styrenic block copolymer also possessing high strength and elasticity. It has applications that prior to the present invention were not normally possible due to the normal low melt flow rate of styrenic block copolymers. The present invention also encompasses various fields of use such as a fiberglass hSBS or hSBSS reinforced mat, low viscosity hSBS or hSBSS coatings for industrial uses, hot melt adhesives prepared from hSBS or hSBSS blended with polyalpha-olefins, and elastic film, fiber, and nonwoven constructions using hSBS or hSBSS.
    Type: Application
    Filed: July 12, 2013
    Publication date: November 14, 2013
    Applicant: KRATON POLYMERS U.S. LLC
    Inventors: Kathryn Wright, Hiroshi Kato
  • Patent number: 8580884
    Abstract: A novel block copolymer composition including a hydrogenated block copolymer that has at least one block A and at least one block B, and wherein (a) prior to hydrogenation each A block is a mono alkenyl arene homopolymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene, (b) subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced, (c) each A block having a number average molecular weight between about 3,000 and about 60,000 and each B block having a number average molecular weight between about 30,000 and about 300,000, (d) each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units, (e) the total amount of mono alkenyl arene in the hydrogenated block copolymer is about 5 percent w
    Type: Grant
    Filed: November 11, 2010
    Date of Patent: November 12, 2013
    Assignee: Kraton Polymers U.S. LLC
    Inventor: Ruidong Ding
  • Publication number: 20130285271
    Abstract: Thermally sensitive polymers containing polymerizable carbon-carbon unsaturation and/or aliphatically bound halogen are devolatilized in a devolatilizing extruder. The thermally sensitive polymer is blended with a second polymer, which does not contain polymerizable carbon-carbon unsaturation or more than 5% by weight aliphatically bound halogen, and which has a molecular weight of from 25,000 to 175,000. The blend is then devolatilized in the extruder to produce a devolatilized polymer blend. Thermal degradation of the thermally sensitive polymer is minimized in this process.
    Type: Application
    Filed: October 12, 2011
    Publication date: October 31, 2013
    Applicant: Dow Global Technologies LLC
    Inventors: Eung K. Kim, Daniel A. Beaudoin, Mark A. Barger
  • Patent number: 8552114
    Abstract: The present invention provides a block copolymer composition and method of making the same having the structures (A2-B)n-X-(A1) or (A2-B2)n-X-(B1A1), where A1 and A2 are each a polymer block of a monoalkenyl arene and B, B1, and B2 are each a polymer block of one or more conjugated dienes or a hydrogenated diene polymer, n is an integer from 2 to 30 and X is the residue of a coupling agent.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: October 8, 2013
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Dale Lee Handlin, Jr., Peter Pasman, Glenn H. Fredrickson, Carl L. Willis, Robert C. Bening
  • Patent number: 8541504
    Abstract: Provided in this invention is an impact absorber composition comprising a copolymer containing an aromatic vinyl compound, wherein the peak of tan ? of the copolymer obtained from the measurement of the dynamic viscoelasticity is in the range of more than 0° C. to 20° C. or less, the value of tan ? is 0.4 or more in the whole temperature range of 5° C. to 15° C., and the value of tan ? at 15° C. is 0.5 or more.
    Type: Grant
    Filed: February 19, 2008
    Date of Patent: September 24, 2013
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yasuhiro Kusanose, Yoshifumi Araki
  • Patent number: 8541503
    Abstract: A polymeric nanoparticle composition is provided. The nanoparticle may be of a core/shell configuration with an interphase region connecting the core and the shell. The mean average diameter of the polymer nanoparticles may be less than about 250 nm. The size, composition, and/or configuration of the interphase region may be varied to achieve desired physical and/or chemical properties of the resulting polymeric nanoparticles, and of the compositions into which the nanoparticles are compounded.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: September 24, 2013
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Georg Böhm, Sandra Warren, Xiao-Dong Pan, James E. Hall
  • Patent number: 8536279
    Abstract: A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: September 17, 2013
    Assignee: Styrolution GmbH
    Inventors: Konrad Knoll, Jürgen Koch, Piyada Charoensirisomboon, Daniel Wagner, Geert Verlinden, Roland Weidisch
  • Patent number: 8513347
    Abstract: This invention relates a composition comprising: (i) at least one low molecular weight polyolefin; (ii) a block copolymer obtainable by selectively hydrogenating a block copolymer having terminal polymeric blocks of a vinyl aromatic monomer and a mid-block prepared originally with an olefin and subsequently hydrogenated; and (iii) polypropylene; (iv) with the proviso that when (i) is a PAO having a molecular weight of between about 400 and 1000 g/mole, either: (a) (iii) is a homopolymer characterized by an MFR greater than 2 g/10 min, (b) (iii) is a copolymer; or (c) (iii) is a polymer or copolymer made by a metallocene catalyst; or (d) the composition does not contain calcium carbonate.
    Type: Grant
    Filed: July 7, 2006
    Date of Patent: August 20, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun Fu Tse, Thottinal Abraham Mathew, Feng Li
  • Publication number: 20130209742
    Abstract: Provided are a styrene resin composition for use in electronic component packaging such as embossed carrier tape, a sheet which has a large drawing ratio (pocket depth) and in which pockets exhibiting superior transparency and strength and can be thermoformed, and a carrier tape which is thermoformed from the sheet and which allows the verification of letters and the like formed on packaged electronic components from outside the pockets. The electronic component packaging sheet includes: (A) 29-65 mass parts of a styrene-conjugated diene block copolymer; (B) 51-15 mass parts of a polystyrene resin; and (C) 20-9 mass parts of an impact resistant polystyrene resin. Components (A)-(C) each have a weight average molecular weight within a specified range.
    Type: Application
    Filed: October 6, 2011
    Publication date: August 15, 2013
    Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHA
    Inventors: Junpei Fujiwara, Masatoshi Kawata
  • Publication number: 20130209716
    Abstract: An inflatable article is provided with an elastomer layer that is airtight towards inflation gases. The elastomer layer includes at least one rubber composition, and the rubber composition includes at least: as a non-thermoplastic elastomer, a butyl rubber, used alone or as a blend with one or more other non-thermoplastic elastomers (preferably diene elastomers); a crosslinking system; optionally a reinforcing filler at a content within a range from 0 to 120 phr; and a thermoplastic elastomer that includes a polyisobutylene block. A content of the thermoplastic elastomer is within a range from 3 to 80 parts by weight per 100 parts of non-thermoplastic elastomer.
    Type: Application
    Filed: July 7, 2011
    Publication date: August 15, 2013
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Emmanuel Custodero, Marc Greiveldinger, Cyrille Guery
  • Patent number: 8497321
    Abstract: A tacky resin composition which has proper initial tackiness, is sufficiently inhibited from rising in tackiness with time, can keep tackiness at a proper range even when it receives a slight heat history or is stored for a long time, has very small dependence on peeling speed, and can provide high transparency to a pressure-sensitive adhesive film or sheet as required, and a pressure-sensitive adhesive film or sheet for the surface protection of an article, which is obtained form the tacky resin composition. The tacky resin composition comprises (A) 5 to 80 parts by weight of an olefin polymer (component A), (B) 5 to 80 parts by weight of an ethylene/unsaturated ester copolymer (component B) and (C) 1 to 60 parts by weight of a styrene-based elastomer and/or an olefin-based elastomer (component C) based on 100 parts by weight of the total of the components A, B and C.
    Type: Grant
    Filed: January 28, 2009
    Date of Patent: July 30, 2013
    Assignee: Du Pont-Mitsui Polychemicals Co., Ltd.
    Inventors: Masataka Aoyama, Yoshitaka Hironaka, Hisao Gonohe
  • Patent number: 8497322
    Abstract: A homogenous blend comprising from 10% to 90% by weight of a metallocene catalyzed polyethylene (mPE) and from 90% to 10% by weight of styrene-butadiene block copolymers comprising from 5% to 40% by weight of 1,3 butadiene monomer units and from 60% to 95% by weight of styrene monomer unites. The blend of the invention is used to make peelable films for food packaging applications.
    Type: Grant
    Filed: June 19, 2012
    Date of Patent: July 30, 2013
    Assignee: Total Petrochemicals Research Feluy
    Inventor: Pascal Fourcade
  • Patent number: 8492479
    Abstract: A process for preparing a functionalized or unfunctionalized diene block copolymer comprising at least one polyether block of number-average molecular weight approximately from 150 to 5000 g/mol linked to at least one block constituted of a diene elastomer via at least one silicon atom. The process allows a high degree of grafting of the polyether to the polymer chains. Also disclosed is a reinforced rubber composition, especially intended for the manufacture of tires, comprising such a diene block copolymer which is intended to interact with the reinforcing filler. Such a rubber composition has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: July 23, 2013
    Assignees: Michelin Recherche et Technique S.A., Compagnie Generale des Etablissements Michelin
    Inventors: Pierre Robert, Nicolas Seeboth, Jean-Michel Favrot, Philippe Chaboche
  • Patent number: 8481644
    Abstract: Compositions comprising a coupled interpolymer such as polybutadiene which may be suitable for HIPS and ABS have been discovered. The coupled interpolymer composition comprises an interpolymer comprising one or more monomeric units derived from a diene wherein the coupled interpolymer composition is characterized by: (A) a halide content of less than about 30 ppm based on the total weight of the coupled interpolymer; (B) a molecular weight distribution of from about 1.6 to about 2.4; and (C) a vinyl content of from about 5 to about 15 weight percent based on the total weight of the coupled interpolymer.
    Type: Grant
    Filed: June 2, 2009
    Date of Patent: July 9, 2013
    Assignee: Styron Europe GmbH
    Inventors: Evemarie Hamann, Vera Steinert, Norbert Jantsch
  • Patent number: 8470928
    Abstract: A one- or two-component adhesive containing: a) a binding agent having reactive isocyanate groups or silane groups, and b) a nonreactive polymer having a glass transition temperature, measured by means of DSC, in the range from ?40° C. to +60° C. This preferably has, in a cured state, at a temperature at least in the range from ?10 to +50° C., a dynamic mechanical loss factor tan ? of at least 0.4 at a frequency in the range from 10 to 400 Hz. Use of an adhesive of this kind for the adhesive bonding of components in the manufacture or repair of vehicles, in particular for bonding windows into place in the context of direct glass bonding.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: June 25, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Manfred Schumann, Kersten Kreiner