Solid Block Or Block-type Copolymer Derived From Reactant Containing Plural Unsaturation Patents (Class 525/98)
  • Publication number: 20110269879
    Abstract: The present invention relates to a high-strength inflammable blend resin composition including a polyphenylene sulfide resin and a polyethylene terephthalate resin. More specifically, the resin composition of the present invention includes: a basic blend resin containing 10 to 80 wt. % of a polyphenylene sulfide resin, and 20 to 90 wt. % of a polyethylene terephthalate resin; and 0.1 to 20 parts by weight of a modified polystyrene or a styrene-based elastomer with respect to 100 parts by weight of the basic blend resin.
    Type: Application
    Filed: December 30, 2009
    Publication date: November 3, 2011
    Applicant: SK Chemicals Co., Ltd.
    Inventors: Sung-Gi Kim, Jae-Bong Lim, Jong-In Lee, Chang-Hyun Lee, Sung-Su Bae, Sang-Mook Lee
  • Patent number: 8048947
    Abstract: The present invention provides a nanocomposite of a star branched elastomer and a clay. The nanocomposite can be a mixture of a halogenated star branched elastomer and a clay, desirably an exfoliated clay, suitable for use as an air barrier. The halogenated star-branched elastomer can be the primary halogenated elastomer in the blend, and a ratio of the star-branched elastomer to clay can be from 2:1 to 500:1.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: November 1, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Caiguo Gong, Carmen Neagu, Beverly Jean Poole, Anthony Jay Dias, Kriss Randall Karp, Molly Westermann Johnston
  • Patent number: 8048362
    Abstract: A polyolefin-based resin composition of the invention has an addition polymerization-based block copolymer (I) and a polyolefin-based resin (II). The addition polymerization-based block copolymer (I) is selected from block copolymers comprising at least one polymer block A and at least one polymer block B, and the hydrogenated products thereof. The polymer block A comprises an aromatic vinyl compound unit comprising at least 1% by mass of an alkylstyrene-derived structural unit (a), in which at least one alkyl group having 1 to 8 carbon atoms is bound to a benzene ring. The polymer block B comprises a conjugated diene compound unit. A moiety of polymer block A can undergo crosslinking upon exposure to an active energy ray. After being molded into a desired shape, the composition is exposed to an active energy ray to carry out the crosslinking reaction. The composition exhibits flexibility, heat resistance, mechanical properties and solvent resistance in a well-balanced manner.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: November 1, 2011
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenji Suzuki, Kenji Shachi, Mizuho Maeda
  • Patent number: 8044142
    Abstract: This invention provides a polymer alloy comprising a polyphenylene sulfide resin and a polyphenylene ether resin. This polymer alloy can eliminate molding whitening which, upon molding, occurs on the surface of the molded product, can impart excellent surface appearance and flame retardance, and further can improve balance between heat resistance and toughness (impact strength) and mechanical strength. The resin composition comprises 45 to 99 parts by weight of a polyphenylene sulfide resin comprising (a) 0 to 96% by weight of a specific linear polyphenylene sulfide resin and (b) 100 to 4% by weight of a specific crosslinking-type polyphenylene sulfide resin. The resin composition further comprises (c) 55 to 1 part by weight of a polyphenylene ether resin. Further, the resin composition comprises (d) 1 to 20 parts by weight, based on 100 parts by weight in total of components (a) to (c), of a styrene copolymer and/or an ethylene copolymer containing any one functional group of glycidyl and oxazolyl groups.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: October 25, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yoshikuni Akiyama, Minoru Sakata
  • Publication number: 20110257337
    Abstract: Provided is a hot-melt adhesive composition which can be easily applied at a relatively low temperature, has a long open time, and also has high holding power. A hot-melt adhesive composition comprising a block copolymer composition which includes a block copolymer A and a block copolymer B, and a tackifying resin, wherein a weight ratio (A/B) of the block copolymer A and the block copolymer B is 25/75 to 90/10, and an aromatic vinyl monomer unit content of the block copolymer A is 41% or greater.
    Type: Application
    Filed: December 25, 2009
    Publication date: October 20, 2011
    Inventors: Ryouji Oda, Sadaharu Hashimoto, Ayako Furuko
  • Patent number: 8039553
    Abstract: The present invention relates to an adhesive composition comprising (A) a block copolymer composition comprising a block copolymer (a) formed from at least two polymer blocks composed mainly of a monoalkenyl aromatic compound and at least one polymer block composed mainly of a conjugated diene compound and a block copolymer (b) formed from a polymer block composed mainly of a monoalkenyl aromatic compound and a polymer block composed mainly of a conjugated diene compound, wherein the block copolymer (a) has a GPC peak molecular weight of 60,000 to 110,000 in terms of standard polystyrene, the polymer block composed mainly of a monoalkenyl aromatic compound has a peak molecular weight of 10,000 to 30,000 and a molecular weight distribution Mw/Mn of 1.0 to 1.
    Type: Grant
    Filed: August 5, 2004
    Date of Patent: October 18, 2011
    Assignee: Japan Elastomer Co., Ltd.
    Inventors: Masahiro Fujiwara, Yukinori Nakamichi
  • Publication number: 20110251308
    Abstract: Functionalized multi-arm polymers which comprise the reaction product of a coupling agent and a polymer synthesized by anionic polymerization. Furthermore, the invention relates to their preparation method and their different uses, especially as hot-melt adhesives.
    Type: Application
    Filed: December 10, 2009
    Publication date: October 13, 2011
    Applicant: DYNASOL ELASTOMEROS, S.A.
    Inventors: Sergio Corona Galvan, Rafael Polo Abad, Ma Dolores parellada Ferrer, Alejandro Claudio Esquivel de al Garza
  • Patent number: 8030374
    Abstract: An object of the present invention is to prevent, in blending an inorganic filler for the purpose of improving rigidity of a thermoplastic resin, deterioration in impact resistance and surface smoothness caused by the inorganic filler. The invention relates to a polyphenylene ether based resin composition containing (a) from 10 to 93% by weight of a polyphenylene ether based resin and optionally a styrene based resin, (b) from 2 to 20% by weight of a styrene based thermoplastic elastomer modified with an imidazolidinone compound, and (c) from 5 to 60% by weight of an inorganic filler that has been surface treated with a silane compound.
    Type: Grant
    Filed: August 8, 2003
    Date of Patent: October 4, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Juro Ozeki, Toru Yamaguti
  • Patent number: 8013062
    Abstract: The invention relates to the production and use of block copolymers which are obtained by means of controlled radical polymerization in the presence of nitroxides for the purpose of reinforcing fragile polymer matrices. The invention offers advantages such as (i) simplicity of copolymer synthesis and use and (ii) fine dispersion of the copolymer molecules in the fragile matrix, which ensures both the transparency of the material and high reinforcement against impact. More specifically, the invention relates to the radical synthesis of block copolymers comprising at least three blocks, which include one block having a glass transition temperature of less than 0° C. and a thermoplastic end block having a glass transition temperature of more than 0° C., thereby guaranteeing compatibility with the fragile matrix to be reinforced against impact.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: September 6, 2011
    Assignee: Arkema France
    Inventors: Anne-Valerie Ruzette, Florence Chauvin, Olivier Guerret, Denis Bertin, Bruno Vuillemin, Ludwik Leibler, Pierre Gerard, Yannick Ederle
  • Patent number: 8012539
    Abstract: The present invention relates to an improved method for making sulfonated block copolymers and to methods for making membranes from such block copolymers. In particular, the present invention relates to an improved method for making sulfonated block copolymers having at least two polymer end blocks that are resistant to sulfonation and at least one polymer interior block that is susceptible to sulfonation where the sulfonation agent is C2 to C8 acyl sulfate. In the improved process the residual carboxylic acid formed from the C2 to C8 acyl sulfate is converted to C1 to C4 alkyl esters by contacting the residual carboxylic acid with at least a 0.9:1 molar ratio of a C1 to C4 alcohol to residual carboxylic acid, resulting in an improved sulfonated block copolymer solution. The present invention further relates to the use of such sulfonated block copolymer solutions to prepare various membranes and other articles.
    Type: Grant
    Filed: May 9, 2008
    Date of Patent: September 6, 2011
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Dale Lee Handlin, Jr., Scott Russell Trenor, Gregory Paul Dado
  • Patent number: 8008398
    Abstract: Foamable compositions which are usable for the manufacture of foamed, flexible, heat resistant, thermoplastic elastomeric articles, and which comprises at least: (a) 100 pbw of one or more selectively hydrogenated block copolymers, (b) 5 to 50 pbw per 100 pbw of component (a) of one or more different selectively hydrogenated block copolymers, (c) 42 to 80 pbw per 100 pbw of component (a) of a linear crystalline polymer comprising propylene as the major component, (d) from 100 to 250 pbw per 100 pbw of component (a) of a softener compatible with blocks B and B?, and (e) from 0.01 to 3 wt. %, relative to the weight of the primary components (a) to (e) of a solid chemical nucleating agent of the endothermic group in combination with a blowing agent.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: August 30, 2011
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Xavier Muyldermans, Emmanuelle Coignoul
  • Patent number: 7977428
    Abstract: To provide a block copolymer composition excellent in balance of transparency, impact resistance, etc. in the form of not only an excluded product and a blow molded product but also an injection molded product.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: July 12, 2011
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Kurimura, Jun Watanabe, Takeshi Oda, Norihiro Shimizu
  • Publication number: 20110129627
    Abstract: Polymer composition comprising—a heterophasic propylene copolymer comprising a polypropylene matrix and an elastomeric propylene copolymer comprising at least one comonomer selected from the group consisting of ethylene and C4 to C20 ?-olefin, and—a styrenic based elastomer(s) (B), wherein the styrene content in each styrenic based elastomer (B) is equal or below 15 wt.-%, and the total amount of the styrenic based elastomer(s) (B) based on the total amount of polymers present in the polymer composition is of 16.0 to 46.0 wt.-%.
    Type: Application
    Filed: July 27, 2009
    Publication date: June 2, 2011
    Applicant: Borealis AG
    Inventors: Tonja Schedenig, Christelle Grein, Dietrich Gloger
  • Publication number: 20110104487
    Abstract: The present invention is related to pressure-sensitive hot melt adhesive compositions and their applications. In particular, the adhesive compositions described herein comprise a block copolymer component, a hydrocarbon tackifier resin component, and a propylene-based polymer component.
    Type: Application
    Filed: September 13, 2010
    Publication date: May 5, 2011
    Inventors: Jurgen Schroeyers, Eddy Swiggers
  • Publication number: 20110092633
    Abstract: This invention relates to a rubber composition capable of improving fracture properties and wear resistance of a tire, and more particularly to a rubber composition formed by compounding a non-compatible polymer blend, which comprises at least two rubber components and forms a polymer phase A and a polymer phase B, with a block copolymer comprising a block-a composed of the same monomer unit as a monomer unit forming the polymer phase A and a block-b composed of the same monomer unit as a monomer unit forming the polymer phase B, wherein at least one of the rubber components has at least one functional group.
    Type: Application
    Filed: June 11, 2009
    Publication date: April 21, 2011
    Applicant: BRIDGESTONE CORPORATION
    Inventor: Hideyuki Nukaga
  • Patent number: 7928184
    Abstract: The present invention provides a method of manufacturing a stabilized polyacetal resin, comprising the step of applying a heat treatment to a polyacetal resin having an unstable terminal group in the presence of an unstable terminal group decomposer selected from the following Group I, Group II and Group III, thereby decreasing the unstable terminal group: unstable terminal group decomposer of Group I: (I) a quaternary ammonium salt of an acidic cyclic amide compound, unstable terminal group decomposer of Group II: (II) a quaternary ammonium salt of a polycarboxylic acid intramolecularly having four or more carboxyl groups and/or a quaternary ammonium salt of an aminocarboxylic acid intramolecularly having one or more carboxyl group(s), unstable terminal group decomposer of Group III: (III) a quaternary ammonium salt, wherein a compound providing a counter-anion of a quaternary ammonium salt is at least one selected from the group consisting of the following (i) to (v): (i) a carbonic acid monoester
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: April 19, 2011
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Hiroaki Nakao
  • Patent number: 7915342
    Abstract: A polymeric composition having a MFR of less than 2 g/10 min. which when formed into a film has an oxygen transmission rate of equal to or greater than 300 cc/100 in2/24 h at 73° F. and 0% relative humidity per ASTM D 3895 and a water vapor transmission rate of equal to or greater than 0.5 g/100 in2/24 hrs at 100° F. and 100% relative humidity per ASTM F 1249. A polymeric film having a 2% secant modulus in the machine direction of 300 MPa to 700 MPa; an oxygen transmission rate of greater than 300 cc/100 in2/24 h at 100° F., a water vapor transmission rate of greater than 0.5 g/100 in2/24 hrs at 100° F. and 100% relative humidity; an Elmendorf tear strength in the MD of from 50 g to 400 g; an Elmendorf tear strength in the transverse direction of from 150 g to 400 g, a dart drop strength of from 200 g to about 500 g, a haze of from 0% to 85% and, gloss at 45° of from 5% to 70%.
    Type: Grant
    Filed: November 28, 2005
    Date of Patent: March 29, 2011
    Assignee: Fina Techology, Inc.
    Inventors: Juan J. Aguirre, Mark B. Miller, David L. Turner
  • Patent number: 7910208
    Abstract: Bicomponent fibers having a sheath-core morphology where the sheath is a thermoplastic polymer and the core is an elastomeric compound are made which can be continuously extruded from the melt at high production rates. The elastomeric compound comprises a coupled, selectively hydrogenated block copolymer having high flow. The block copolymer has at least one polystyrene block of molecular weight from 5,000 to 7,000 and at least one polydiene block of molecular weight from 20,000 to 70,000 and having a high vinyl content of 60 mol % or greater. The bicomponent fibers are useful for the manufacture of articles such as woven fabrics, spun bond non-woven fabrics or filters, staple fibers, yarns and bonded, carded webs. The bicomponent fibers can be made using a process comprising coextrusion of the thermoplastic polymer and elastomeric compound to produce fibers at greater than 800 mpm and having a denier from 0.1 to 50 g/9000 m.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: March 22, 2011
    Assignee: Kraton Polymers U.S. LLC
    Inventors: John E. Flood, Dale L. Handlin, Jr.
  • Patent number: 7906584
    Abstract: The invention provides a polymer composition containing an addition polymerization-based block copolymer (a), an acrylic resin (b), and a softener (c), wherein the addition polymerization-based block copolymer (a) has a weight average molecular weight of 30000 to 200000 and is at least one selected from block copolymers comprising at least one polymer block A and at least one polymer block B, and hydrogenated products of the block copolymers; the polymer block A essentially comprises an aromatic vinyl compound unit containing at least 1% by mass of an alkylstyrene-derived structural unit (I) in which at least one alkyl group having 1 to 8 carbon atoms is bound to a benzene ring; the block copolymer B comprises a conjugated diene compound unit; and the components of the polymer composition are present in respective proportions (by mass) so that the following relationships (1) and (2) hold: 0.05?Wb/Wa?2??(1) Wc/(Wa+Wb+Wc)?0.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: March 15, 2011
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenji Suzuki, Akihiro Kotaka, Kenji Shachi, Mizuho Maeda
  • Patent number: 7905872
    Abstract: An absorbent article may comprise a topsheet, a backsheet joined with the topsheet, an absorbent core interposed between the topsheet and backsheet; and one or more article elements selected from the group consisting of an anal cuff, an elasticized topsheet, a fastening system, a leg cuff, a waist elastic feature, a side panel, an ear, and combinations thereof. The article elements may comprise a slow recovery stretch laminate exhibiting an unload force at 37° C. of about 0.16 N/(g/m) or greater and a percent of initial strain after 15 seconds of recovery at 22° C. of about 10% or greater.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: March 15, 2011
    Assignee: The Procter & Gamble Company
    Inventors: Robin Lynn McKiernan, Bryn Hird, Edward Joseph Urankar, Janet Neton
  • Patent number: 7893156
    Abstract: The present invention provides a block copolymer or a hydrogenated product thereof excellent in low-temperature shrinkability, natural shrinkability, rigidity and the like, excellent in a balance of physical properties such as blocking resistance, resistance to fusion bonding in hot water, impact resistance and the like, and having a few fish eyes (FE's) caused by gels. Further, the invention provides a heat shrinkable film and a heat shrinkable multilayer film suitable for drink container packaging, cap seals and the like, using such a block copolymer or the hydrogenated product thereof.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: February 22, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Susumu Hoshi, Masahiro Mori, Yukio Yamaura, Toshinori Shiraki
  • Patent number: 7893159
    Abstract: The present invention includes a composition comprising a propylene-alpha olefin copolymer having at least seventy weight percent units derived from propylene, and from ten to twenty five weight percent units derived from ethylene or a C4-C10 alpha olefin, the propylene-alpha olefin copolymer exhibiting a heat of fusion of less than 37 Joules/gram and a melt flow rate of from 0.1 to 100 gram/10 minutes; and a styrenic block copolymer, wherein the weight ratio of the propylene-alpha olefin copolymer to the styrenic block copolymer is from 3:7 to 7:3. The composition exhibits tensile modulus of less than 20 MPa, tensile strength of at least 5 MPa, and elongation at break of at least 900% with low relative immediate set.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: February 22, 2011
    Assignee: Dow Global Technologies Inc.
    Inventor: Andy C. Chang
  • Patent number: 7884160
    Abstract: The present invention provides polymeric nanoparticles comprising triblock and optionally diblock copolymer chains. The architecture of the polymeric nanoparticles may be controlled, resulting in nanoparticles having non-spherical shapes. The present invention also provides a method of preparing the polymeric nanoparticles and a rubber article such as a tire manufactured from a formulation comprising the polymer nanoparticles.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: February 8, 2011
    Assignee: Bridgestone Corporation
    Inventors: Xiaorong Wang, Mindaugas Rackaitis, Victor J. Foltz, Edward D. Kelley, Yuan-Yong Yan
  • Publication number: 20110021102
    Abstract: A hot melt adhesive is provided that has low viscosity, a high softening point, superior heat resistance, and a high degree of adhesive strength and adhesion stability at high temperatures. The adhesives of the invention comprise (A) an amorphous alpha olefin, (B) a crystalline poly-alpha olefin and (C) hydrogenated thermoplastic block copolymer which are copolymers with vinyl aromatic hydrocarbons and conjugated diene compounds. The adhesive is particularly useful in the manufacture of articles including laminations.
    Type: Application
    Filed: September 30, 2010
    Publication date: January 27, 2011
    Inventors: Kentarou Inoue, Keiko Ide
  • Patent number: 7875678
    Abstract: Compositions, processes, and methods are provided relating to styrenic polymers, including high impact polystyrene (HIPS), also referred to as rubber-modified polystyrene. In one aspect, a process is provided for making high impact polystyrenes, comprising the steps of combining a monovinylarene component, a monovinylarene-conjugated diene block copolymer, and a conjugated diene polymer. In another aspect, the feed components form an emulsion having a continuous phase and a dispersed phase. The continuous phase comprises at least a portion of the monovinylarene component and at least a portion of the conjugated diene polymer. The dispersed phase is suspended within the continuous phase, and comprises globules having at least a portion of the monovinylarene-conjugated diene block copolymer, a remaining portion of the monovinylarene component, and a remaining portion of the conjugated diene polymer.
    Type: Grant
    Filed: April 11, 2006
    Date of Patent: January 25, 2011
    Assignee: Chevron Phillips Cheimcal Company, LP
    Inventors: Michael J. Hanner, Chen-Youn Sue, Clifford C. Pettey, Carleton Stouffer, Paul M. Hunt, Ken E. Bowen
  • Publication number: 20110003928
    Abstract: The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.
    Type: Application
    Filed: February 4, 2009
    Publication date: January 6, 2011
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Daisuke Shimizu, Yasuhiro Kusanose, Yoshifumi Araki, Masahiro Fujiwara
  • Patent number: 7863378
    Abstract: A thermoplastic elastomer composition comprising a thermoplastic vulcanized olefin elastomer (A) and an aromatic vinyl random copolymer (B), wherein the (A) component is a thermoplastic vulcanized elastomer composed of an ethylene-?-olefin copolymer (A-1) and a thermoplastic non-vulcanizable polymer (A-2) and the (B) component is a hydrogenated copolymer rubber composed mainly of random bonding which has an olefinic double bond hydrogenation ratio of 50% or more and comprises 10 to 49% by weight of a conjugated diene monomer and 51 to 90% by weight of an aromatic vinyl monomer.
    Type: Grant
    Filed: August 31, 2006
    Date of Patent: January 4, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Hajime Nishihara, Toshikazu Hoshina
  • Patent number: 7858693
    Abstract: The present invention relates to novel compositions comprising (a) anionic block copolymers having at least two blocks of a mono alkenyl arene and at least one block of a conjugated diene and mono alkenyl arene having a specific arrangement of the monomers in the copolymer block, and (b) tailored softening modifiers have a particular structure that results in a surprising improvement in properties for the composition. Also included are processes for the manufacturing such novel compositions and various end-uses and applications for such compositions.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: December 28, 2010
    Assignee: KratonPolymers U.S. LLC
    Inventors: Kathryn J. Wright, Carl L. Willis, Dale L. Handlin, Jr.
  • Patent number: 7851558
    Abstract: A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.
    Type: Grant
    Filed: October 23, 2006
    Date of Patent: December 14, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Bruce A. King, William G. Stobby, Daniel J. Murray, Anteneh Z. Worku, Inken Beulich, Sheila M. Tinetti, Stephen F. Hahn, Ray E. Drumright
  • Patent number: 7851559
    Abstract: Soft flame retardant thermoplastic compositions that are preferably halogen free and include a styrenic block copolymer having a low modulus, one or more of a polyolefin polymer or copolymer and an acrylate containing polymer or copolymer, one or more of a softener and plasticizer, an inorganic phosphorous-containing flame retardant, and optionally but preferably, a platelet filler such as a nanoclay or an organic modified clay. In a preferred embodiment, the phosphorous-containing flame retardant has a surface coating thereon which reduces sensitivity of the flame retardant to water, and thus reduces the amount of the flame retardant that can leach out in the presence of water, thereby enabling the compositions of the present invention to be utilized outdoors or other environments where exposure to water or high humidity is possible. The hardness of the compositions according to the invention preferably ranges from about Shore A 40 to about Shore A 90.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: December 14, 2010
    Assignee: Teknor Apex Company
    Inventor: Biing-Lin Lee
  • Patent number: 7847022
    Abstract: The present invention relates to articles prepared from novel anionic block copolymers of mono alkenyl arenes and conjugated dienes, and to blends of such block copolymers with other polymers. The block copolymers have mono alkenyl arene end blocks and controlled distribution blocks of mono alkenyl arenes and conjugated dienes. The block copolymer may be blended with at least one other polymer selected from the group consisting of olefin polymers, styrene polymers, amorphous resins and engineering thermoplastic resins.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: December 7, 2010
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Kathryn Wright, Dale Lee Handlin, Jr., Carl Lesley Willis, Margaret Ann Burns Clawson, Hendrik de Groot, Huan Yang, Keith E. Eiden
  • Patent number: 7838598
    Abstract: A composition to be used for the manufacture of transparent, gelfree films, comprising: a) at least 65 wt % of a styrenic block copolymer, having a molecular structure according to the formula S—(I/B)—S (1) or [S—(I/B)]n X (2), wherein each S independently is a polymer block of predominantly styrene and (I/B) is a substantially random polymer block of predominantly isoprene and butadiene, wherein n is an integer equal to or greater than 2, and wherein X is the residue of a coupling agent, wherein said styrenic block copolymer having a poly(styrene) content in the range of from 28 to 31% by weight, having poly(styrene) blocks S of a true molecular weight in the range of from 10,000 to 15,000, having a true molecular weight of the complete block copolymer in the range of from 110,000 to 160,000 and wherein the diblock S—(I/B) optionally occurs in a content of at most 20 mol %, b) from 5 to 25 wt % of a second thermoplastic resin, c) from 1 to 10 wt % of a plasticizing oil, the sum of the percentages of the comp
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: November 23, 2010
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Gert Joly, Jaak L. Moerenhout
  • Publication number: 20100292077
    Abstract: A process for preparing a polymer composite that includes reacting (a) a multi-functional monomer and (b) a block copolymer comprising (i) a first block and (ii) a second block that includes a functional group capable of reacting with the multi-functional monomer, to form a crosslinked, nano-structured, bi-continuous composite. The composite includes a continuous matrix phase and a second continuous phase comprising the first block of the block copolymer.
    Type: Application
    Filed: July 18, 2008
    Publication date: November 18, 2010
    Inventors: Marc Hillmyer, Liang Chen
  • Patent number: 7829630
    Abstract: The present invention relates to styrenated terpene resin, as well as methods of making an using the same.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: November 9, 2010
    Assignee: Arizona Chemical Company
    Inventors: Abhay K. Deshpande, George A. Locko
  • Patent number: 7824773
    Abstract: A polymer composition containing (a) a high impact polystyrene (HIPS) component with a block copolymer grafted to polystyrene, a rubbery conjugated diene content of one to seven weight percent based on HIPS weight, less than 10 weight-percent gel concentration, an average rubber particle size of between one and 0.01 micrometers, about 40 to about 90 volume percent of the rubber particles have diameters of less than about 0.4 microns and from about 10 to about 60 volume percent of the rubber particles have diameters between about 0.4 and about 2.5 microns, a majority of rubber particles with a core/shell morphology and a concentration that accounts for 10 to 70 weight-percent of the total polymer composition weight and one to five weight-percent rubbery diene based on total polymer composition weight; (b) from 10 to 70 weight percent of a general purpose polystyrene and from about 2 to about 80 weight-percent of a styrene block copolymer component, both based on total polymer composition weight.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: November 2, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Robert L. McGee, Stephen J. Skapik, III
  • Patent number: 7820270
    Abstract: A method for forming self-assembled patterns on a substrate surface is provided. First, a block copolymer layer, which comprises a block copolymer having two or more immiscible polymeric block components, is applied onto a substrate that comprises a substrate surface with a trench therein. The trench specifically includes at least one narrow region flanked by two wide regions, and wherein the trench has a width variation of more than 50%. Annealing is subsequently carried out to effectuate phase separation between the two or more immiscible polymeric block components in the block copolymer layer, thereby forming periodic patterns that are defined by repeating structural units. Specifically, the periodic patterns at the narrow region of the trench are aligned in a predetermined direction and are essentially free of defects. Block copolymer films formed by the above-described method as well as semiconductor structures comprising such block copolymer films are also described.
    Type: Grant
    Filed: August 13, 2009
    Date of Patent: October 26, 2010
    Assignee: International Business Machines Corporation
    Inventors: Charles T. Black, Ricardo Ruiz, Robert L. Sandstrom
  • Publication number: 20100240832
    Abstract: The present invention relates to a process for preparing a high impact monovinylaromatic polymer comprising admixing a rubber, at least one monovinylaromatic monomer and optionally one or more comonomer in the presence of at least a borane complex of the L-BH3 type wherein L is a Lewis base and polymerizing the monovinylaromatic monomer. The borane complex initiator, L may be an ether (e.g THF, tetrahydrofurane), a thioether (e.g dimethylthioether) or an amine. A preferred complex is an amine borane such as by way of example triethylamine borane. The present invention also relates to a high impact monovinylaromatic polymer having a weight ratio of grafted monovinylaromatic monomer and optional comonomer to the initial monovinylaromatic monomer and optional comonomer above 0.1%, advantageously above 2% and preferably in the range 2 to 4%. The invention is of particular interest to make high impact polystyrene.
    Type: Application
    Filed: January 21, 2008
    Publication date: September 23, 2010
    Applicant: TOTAL PETROCHEMICALS FRANCE
    Inventors: Michel Duc, Bruno Vuillemin, Denis Bertin, Sylvain Marque, Christophe Galindo
  • Patent number: 7794807
    Abstract: A composite sheet comprising at least one layer each of a substrate layer (layer A) made of a polystyrene resin and an ABS resin as the main components, a reinforcing layer (layer B) made of an ABS resin as the main component, and a surface layer (layer C) made of, as the main component, a polystyrene resin which contains a conductive filler, wherein the surface on at least one side is the above surface layer (layer C) is useful for a conductive composite sheet which has a small difference in physical properties between the machine and transverse directions and has high rigidity and folding endurance and which can easily be thermally formed into a tray or an embossed carrier tape.
    Type: Grant
    Filed: September 5, 2005
    Date of Patent: September 14, 2010
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Takeshi Miyakawa, Yasushi Hirokawa, Masahiro Kuramoto
  • Publication number: 20100210163
    Abstract: Hot melt adhesive compositions containing hyper-branched SBS block copolymers and end use applications thereof. The hyper-branched SBS is characterized in having a ratio between light-scattering molecular weight (of non-di-block polymer) and GPC molecular weight (of non-di-block polymer) greater than 1.4 and having ratio between light scattering molecular weight molecular weight (of non-di-block polymer) and light scattering molecular weight molecular weight (of di-block polymer) greater than 5. The ratio between light scattering molecular weight MW (of non-di-block polymer) and light scattering molecular weight MW (of di-block polymer) also defines the number of arms for the hyper branched structure. The weight average molecular weight of each arm of the hyper-branched SBS block copolymer is less than about 100,000.
    Type: Application
    Filed: February 15, 2010
    Publication date: August 19, 2010
    Inventors: Qiwei He, Yuhong Hu, Alethea Pollock, Justin Mehaffy, Michael G. Harwell
  • Patent number: 7776965
    Abstract: The present invention relates to monovinylarene-conjugated diene copolymer compositions adapted for blendability with acrylate polymers. In some embodiments, such compositions are provided that are particularly resistant to blocking when stored in pellet form.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: August 17, 2010
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: John D. Wilkey, Carleton E. Stouffer, Steven D Bridges
  • Publication number: 20100190894
    Abstract: The disclosure relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The disclosure also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The disclosure further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
    Type: Application
    Filed: July 18, 2008
    Publication date: July 29, 2010
    Applicants: TOTAL RAFFINAGE MARKETING, CENTRE NATIONAL DE RECHERCHE SCIENTIFIQUE (CNRS)
    Inventors: Pierre Chaverot, Charlotte Godivier, Ludwik Leibler, Ilias Iliopoulos, Amanda Kathryn Leach
  • Publication number: 20100152386
    Abstract: A thermoplastic polymer composition has good flexibility, lightweight properties, moldability, and heat resistance, and in particular, is excellent in wear resistance. The thermoplastic polymer composition includes: at least one block copolymer (a) selected from among an ?-methylstyrene based block copolymer having a number average molecular weight of 30,000 to 500,000 and a hydrogenated product thereof, the ?-methylstyrene based block copolymer including a polymer block A mainly composed of an ?-methylstyrene unit and a polymer block B mainly composed of a conjugated diene unit; a propylene-based polymer (b); and an ethylene-based polymer (c) having a density of 0.94 g/cm3 or less, in a ratio satisfying the following inequalities (1) and (2): 0.1?W(a)/[W(a)+W(b)+W(c)]?0.8??(1) 1?W(b)/W(c)??(2) wherein W(a), W(b), and W(c) represent the masses of the block copolymer (a), the propylene-based polymer (b), and the ethylene-based polymer (c), respectively.
    Type: Application
    Filed: May 23, 2008
    Publication date: June 17, 2010
    Applicant: Kuraray Co., Ltd.
    Inventors: Nobuhiro Miwa, Kenji Shachi
  • Patent number: 7737216
    Abstract: The present invention relates generally to monovinylarene-conjugated diene block copolymers adapted for shrinkable film applications. In one embodiment, a block copolymer is provided wherein an oriented 2 mil film of the block copolymer oriented at 100° C. or less exhibits less than 10% shrinkage at 70° C., and at least 70% shrinkage at 100° C.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: June 15, 2010
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: John M Brown, Carleton E Stouffer, John D Wilkey
  • Patent number: 7737217
    Abstract: The present invention relates to a method of making a ready-to-press agglomerated powder mixture by wet milling a powder mixture containing binder and spray drying said slurry to an agglomerated powder useful for making cutting tools for metal machining, tools for rock drilling and wear parts. If the binder is a baroplastic polymer having a pressure induced transformation from hard to soft well developed agglomerates with good flow properties and good plasticity are obtained. The hard property of the binder is used at normal pressures, during handling of the spray-dried powder and in the green body, whereas the softer properties are used at higher pressures during the pressing of the material when the pressure exceeds from about 10 to about 50 MPa.
    Type: Grant
    Filed: May 25, 2007
    Date of Patent: June 15, 2010
    Assignee: Sandvik Intellectual Property AB
    Inventors: Annika Kauppi, Ulf Jutterström
  • Patent number: 7728060
    Abstract: A rubber component containing at least one of diene rubber and ethylene-propylene-diene rubber is dynamically crosslinked. Thereby the rubber component is dispersed in a mixture of a thermoplastic elastomer and a thermoplastic resin. An ethylene oxide-propylene oxide-allyl glycidyl ether and an anion-containing salt having fluoro groups and sulfonyl groups are added to the elastomer composition to obtain a conductive dynamically crosslinked thermoplastic elastomer composition. A mixture of the obtained conductive dynamically crosslinked thermoplastic elastomer composition and a micro-capsule composed of a polymer, having acrylic groups, which forms an outer shell thereof is molded to obtain a conductive roller having Shore A hardness specified in JIS K6253 not more than 40 measured at 23° C.
    Type: Grant
    Filed: August 23, 2007
    Date of Patent: June 1, 2010
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akira Minagoshi, Kei Tajima
  • Patent number: 7714067
    Abstract: A block copolymer mixture containing a branched block copolymer characterized in that it has at least three types of polymer blocks with different molecular weights, each comprising a vinyl aromatic hydrocarbon as monomer units, the molecular weight distribution of a mixture of the polymer blocks S1, S2 and S3 each comprising a vinyl aromatic hydrocarbon as monomer units is within a specific range, and in a gel permeation chromatogram of the mixture of three types of the polymer blocks S1, S2 and S3, M1/M3 and M2/M3 are within specific ranges, where M1, M2 and M3 are peak top molecular weights of the respective polymer blocks.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: May 11, 2010
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Kurimura, Jun Watanabe, Takeshi Ootsuka, Shigeru Suzuki, Takeshi Oda, Norihiro Shimizu
  • Publication number: 20100113699
    Abstract: A process for preparing a rubber comprising polymeric composition, and the resulting compositions, and certain isoprene comprising interpolymers.
    Type: Application
    Filed: December 21, 2007
    Publication date: May 6, 2010
    Inventors: Mark N. Dedecker, James E. Hall, Daniel F. Graves
  • Publication number: 20100105837
    Abstract: The present invention discloses a thermoplastic resin composition comprising: (A) 95 to 5 parts by weight of a styrenic resin and/or a polyphenylene ether resin; (B) 5 to 95 weight parts of an olefinic resin; and (C) 1 to 28 parts by weight of a partially hydrogenated block copolymer based on 100 parts by weight of the total amount of the components (A) and (B), wherein the component (C) comprises at least one polymer block X containing a vinyl aromatic compound as a main component and at least one polymer block Y containing a conjugated diene compound as a main component, a content of the vinyl aromatic compound in the component (C) is at least 10 wt % and at most 80 wt %, the vinyl bond content before hydrogenation in the component (C) is 3 wt % or more and less than 50 wt %, and 1 mol % or more and less than 40 mol % of double bonds derived from the conjugated diene compound in the block copolymer which constitutes the component (C) are hydrogenated.
    Type: Application
    Filed: March 25, 2008
    Publication date: April 29, 2010
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Shigeru Sasaki, Katsunori Nitta
  • Patent number: 7705098
    Abstract: Chemically crosslinked polycyclooctene having excellent shape recovery properties is prepared by ring-opening metathesis polymerization of cis-cyclooctene followed by chemical crosslinking. The crosslinked polycyclooctene can be shaped, the shape memorized, a new shape imparted with the original shape being recoverable by suitable temperature adjustment. The dependence of shape memory characteristics on degree of crosslinking was established. In addition to polycyclooctene, blends thereof with other materials such as SBR, EVA, polyurethane rubbers, and inorganic fillers can be utilized to provide chemically crosslinked products having excellent and tailored shape memory properties.
    Type: Grant
    Filed: June 9, 2009
    Date of Patent: April 27, 2010
    Assignee: University of Connecticut
    Inventors: Patrick T. Mather, Changdeng Liu, Seung B. Chun, E. Bryan Coughlin
  • Publication number: 20100087559
    Abstract: A hydrogenated block copolymer obtained by selective hydrogenation of a block copolymer comprising at least two polymer blocks (A) which each comprise vinyl aromatic monomer units as the main component and may be the same or different from each other, at least two polymer blocks (B) which each comprise monomer units derived from a conjugated diene of 5 or more carbon atoms as the main component and may be the same or different from each other, and one or more polymer blocks (C) which each comprise monomer units derived from a conjugated diene of 4 or more carbon atoms as the main component and may be the same or different from each other and/or one or more random copolymer blocks (D) which each comprise monomer units (d-1) derived from a conjugated diene of 4 or more carbon atoms and vinyl aromatic monomer units (d-2) as the main components, wherein the degree of hydrogenation of olefinically unsaturated double bonds of the blocks (B) is 50% or below; the degrees of hydrogenation of olefinically unsaturated d
    Type: Application
    Filed: August 7, 2007
    Publication date: April 8, 2010
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Yasuhiro Kusanose, Masahiro Fujiwara, Daisuke Shimizu