Abstract: The present invention provides a composition comprising at least one monomer of Formula I, at least one monomer of Formula II, and at least one alkali metal salt of Formula III and/or Formula IV The present invention also provides a process of fabricating a three-dimensional object, comprising i) dispensing a build material that comprises a model material composition and a support material composition; ii) curing the layer dispensed in step i); iii) repeating step i) and ii) so as to sequentially form a plurality of layers in a configured pattern corresponding to the shape of the object; and iv) removing the support material from the build material.

Abstract: Provided are a perfluoroelastomer composition which contains 100 parts by weight of a perfluoroelastomer containing a constituent unit derived from a nitrile group-containing monomer, and 0.01 to 5 parts by weight of ketjen black; and a sealing material including a crosslinked product of the perfluoroelastomer composition.

Abstract: The present invention relates to a method for manufacturing of partially fluorinated polymers, notably vinylidene fluoride (VDF)-based polymers, in emulsion polymerization, and to a polymer obtained from said method.

Abstract: The presently claimed invention relates to novel monomers which can be used for preparing polymers which are useful as dispersants for pigments and fillers, as wetting agent and as thickening agents in liquid compositions.

Abstract: The present disclosure relates to the field of shape memory materials, it discloses a betaine-based shape memory polymer and the preparation method thereof. The polymer is formed through free radical polymerization of an unsaturated betaine monomer, an acrylic monomer, and an ethylene glycol divinyl ether monomer with the addition of an initiator. The betaine-based shape memory polymer has thermosensitive shape memory property and wet sensitive shape memory property, and it has good biocompatibility and an excellent shape memory property, antibacterial property. It is of great potential for use in engineering, construction, daily life and medical service.

Abstract: To provide a method for purifying trifluoroethylene, by which from a fluid containing trifluoroethylene, a C1-5 alkane or alkene (excluding trifluoroethylene) in which at least one hydrogen atom may be substituted with a chlorine atom or a fluorine atom can be efficiently removed, and a method for producing trifluoroethylene by which trifluoroethylene can be efficiently produced. A fluid containing trifluoroethylene is brought into contact with at least one type of synthetic zeolite selected from synthetic zeolites 3A, 4A and 5A.

Abstract: The present invention provides a chlorotrifluoroethylene copolymer endowed with stress cracking resistance, chemical resistance and thermal stability. The present invention is a chlorotrifluoroethylene copolymer constituted of chlorotrifluoroethylene unit, tetrafluoroethylene unit and a monomer [A] unit derived from a monomer [A] copolymerizable with chlorotrifluoroethylene and tetrafluoroethylene, wherein the sum of chlorotrifluoroethylene unit and the tetrafluoroethylene unit amounts to 90 to 99.9 mole percent and the monomer [A] unit amounts to 0.1 to 10 mole percent.

Abstract: This invention relates to a method for preparing a star-shaped polycarboxylate superplasticizer by the first esterification step with polyol and (meth)acrylic acid as main reactants and the second polymerization step. In the first step, the star-shaped polymerizable active ends were synthesized by esterification between polyol and (meth)acrylic acid in the presence of catalyst. In the second step, the final star-shaped polycarboxylate superplasticizer was prepared by radical polymerization among the product obtained in first step, unsaturated polyoxyethylene ethers, molecular weight regulator and unsaturated carboxylic acid in the presence of initiator. The production process of this invention exhibits some characteristics including simple, easily controllable, high polymerization degree, low cost and pollution free. The star-shaped molecular structure of polycarboxylate superplasticizer can be achieved through synthesizing active “core” by esterification and “arm” by radical polymerization.

Abstract: Provided is a process for producing a copolymer of diallyldialkylammonium salt and a maleic acid which copolymer is free of residual monomers and polymerization initiator and hence stably exhibits excellent performances in various uses, and the process comprises polymerizing a monomer mixture comprising diallyldialkylammonium salt and maleic acid in the presence of persulfate as a radical polymerization initiator in water or a polar solvent, and completion of the polymerization-reaction, decomposing the radical polymerization initiator to produce a copolymer comprising diallyldialkylammonium salt constituent unit and a maleic acid constituent unit.

Abstract: The present invention relates to a continuous process for the production of a superabsorbent polymer comprising providing an acidic liquid aqueous monomer mixture containing dissolved oxygen; continuously feeding the aqueous monomer mixture to a reactor; introducing a source of carbonate or hydrogen carbonate into the aqueous monomer mixture prior to entry into the reactor thereby forming a gas phase comprising carbon dioxide and at least a part of the dissolved oxygen, the gas phase being dispersed in the liquid phase; subjecting the gas/liquid mixture to at least partial phase separation immediately prior to or after entry into the reactor and at least partially removing the separated gaseous phase; subjecting the liquid phase in the reactor to free-radical polymerization to obtain the superabsorbent polymer, and continuously removing the superabsorbent polymer from the reactor.

Abstract: The present invention provides an acryloylmorpholine polymer and the use thereof and a filtrate reducer for drilling fluid. The acryloylmorpholine polymer comprises structural units expressed by formula (1), structural units expressed by formula (2), and structural units expressed by formula (3), wherein, at least a part of the structural units expressed by formula (2) can be bonded with at least a part of the structural units expressed by formula (3) into cross-linked structural unit expressed by formula (4); wherein, R1-R9 are H or C1-C3 linear or branched alkyl respectively, y is an integer within 1-5 range, M is H or an alkali metal element, X is O or NH, and R10 is C1-C5 linear or branched alkylidene. The acryloylmorpholine polymer and filtrate reducer for drilling fluid have outstanding filtrate reduction and viscosity increasing effects.

Abstract: A method of making polymer particles includes making an aqueous gel reaction mixture; forming an emulsion comprising dispersed aqueous phase micelles of gel reaction mixture in a continuous phase at a temperature less than about 10° C.; and performing a polymerization reaction in the micelles. Further, the emulsion comprises at least one polymerization initiator in the micelles of gel reaction mixture. The gel reaction mixture can be maintained at a temperature less than about 10° C. when it comprises the polymerization initiator.

Abstract: The invention relates to the use of compounds of the formula (I), R—CH(O—(AO)mX)—CH2—O—(AO)—CH2—CH?CH2, where: R denotes an alkyl radical which has 8 to 18 carbon atoms and can be saturated or unsaturated, straight-chain or branched; X denotes a sulfate or phosphate group or hydrogen; (AO) denotes an alkylene oxide unit, selected from the group consisting of ethylene oxide, propylene oxide or butylene oxide; n denotes a number in the range of 0 to 50; and m denotes zero or a number in the range of 1 to 30; as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers.

Abstract: The present invention has an object to provide a polyalkylene glycol-based polymer having high anti-soil redeposition ability in washing treatment and having high compatibility with surfactants. The polyalkylene glycol-based polymer includes: a structure unit (a) derived from a polyalkylene glycol-based monomer (A) of a specific structure, and a structure unit (b) derived from a carboxyl group-containing monomer (B) at specific ratios.

Abstract: The invention relates to the preparation of branched fluoropolymers having long chain branches and little or no gels, by a process involving polymerization at high temperatures using persulfates and optionally multifunctional initiators. The invention also relates to gel-free, branched polymers with strain hardening produced by the process.

Abstract: The present invention provides a redox-curing type composition that penetrates into a wet body, particularly into a tooth structure (dentin), is cured in an accelerated manner by the moisture contained in the wet body, thereby exhibits a higher bond strength than those of conventional redox-curing type compositions, and has satisfactory storage stability. The present invention is a redox-curing type composition including a polymerizable monomer (a) having an acidic group, a polymerizable monomer (b) having no acidic group, a powdery inorganic peroxide (c) with an average particle diameter of 0.01 to 50 ?m, an amine-based reducing agent (d), and a polymerization accelerator (e). The amine-based reducing agent (d) includes an aromatic amine (d?1) and an aliphatic amine (d?2), and a weight ratio (d?1):(d?2) therebetween is 5:1 to 1:50.

Abstract: Process of controlled free-radical polymerization in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer using molecular iodine and at least one oxidant whose solubility in water is at least 10 g/l for the synthesis of the first block of the block copolymer.

Abstract: The invention relates to a process for preparing maleic acid-isoprenol copolymers from a) 30% to 80% by weight of maleic acid, b) 5% to 60% by weight of isoprenol, c) 0% to 30% by weight of one or more further ethylenically unsaturated monomers, which comprises polymerizing maleic acid, isoprenol and optionally the further ethylenically unsaturated monomer in the presence of a redox initiator and of a chain transfer agent at a temperature in the range from 10 to 80° C.

Abstract: The present invention provides compositions comprising particles or agglomerates of one or more telomer or cotelomer ((co)telomer) of one or more methacrylic acids or anhydrides having a mean average particle size of from 2 ?m to 1 mm, preferably from 5 to 500 ?m. In addition, the present invention provides methods comprising aqueous solution addition polymerizing a monomer mixture of one or more methacrylic acid in the presence of a heteroatom containing compound, drying the resulting copolymer at a temperature of from 120 to 230° C. and reducing its particle size to make a (co)telomer particle or agglomerate; the methods may further comprise reacting the (co)telomer particle or agglomerate with one or more polyether polyol, alkyl polyether polyol, polyether amine or alkyl polyether amine, with heating, to form a comb polymer useful, e.g. as a superplasticizer or dispersant.

Abstract: A polymer and methods of producing the polymer for use, for instance, in mineral processing, including kaolin and calcium carbonate beneficiation are discussed. The method of producing the polymer can include polymerizing at least one monomer in the presence of a polymerization initiator, a chain transfer agent, and a polymerization stabilizer to produce a polymer containing at least one carboxylic acid, wherein the at least one monomer includes an unsaturated carboxylic acid monomer, and wherein the polymer containing at least one carboxylic acid is stable and has a molecular weight of about 1000 g/mol to about 10,000 g/mol.

Abstract: Provided is a process for producing a copolymer of diallyldialkylammonium salt and a maleic acid which copolymer is free of residual monomers and polymerization initiator and hence stably exhibits excellent performances in various uses, and the process comprises polymerizing a monomer mixture comprising diallyldialkylammonium salt and maleic acid in the presence of persulfate as a radical polymerization initiator in water or a polar solvent, and completion of the polymerization-reaction, decomposing the radical polymerization initiator to produce a copolymer comprising diallyldialkylammonium salt constituent unit and a maleic acid constituent unit.

Abstract: The present invention provides a low-molecular weight polytetrafluoroethylene powder that, when used as an additive in a coating material, etc., can form a coating with excellent texture and gliding properties, while also improving dispersibility and viscosity; and a production process therefor. The present invention is a process for producing a low-molecular weight polytetrafluoroethylene powder, the process comprising: an emulsion polymerization step of polymerizing at least tetrafluoroethylene in the presence of a polymerization initiator and an aqueous medium to produce emulsified particles thereof; an agglomeration step of agglomerating the emulsified particles to form an agglomerated powder thereof; and a suspension polymerization step of polymerizing at least tetrafluoroethylene in the presence of the agglomerated powder, a polymerization initiator, and an aqueous medium.

Abstract: The present invention relates to new cure accelerator systems for anaerobic curable compositions. These anaerobic cure systems include tetraalkyl ammonium oxidizing salts that are soluble in the (meth)acrylate component of the composition.

Abstract: The present invention discloses styrene-maleic anhydride copolymers preparations using solventless techniques. The solventless method resulted in reduced amounts of residues, such as unreacted styrene and/or maleic anhydride monomers, which makes the copolymers particularly suitable for bioapplications.

Abstract: An object of the present invention is to provide latex particles with high production reproducibility, by which a sufficiently high value of signal ?S (=value of signal?value of noise) can be realized in immunodiagnosis.

Abstract: The invention relates to copolymers based on phosphorous-containing monomers (A) and on macromonomers (B), to methods for the production thereof and to their use as additives for inorganic binding agent suspensions based on cement, lime, gypsum and anhydrite. The corresponding polymeric additives have, as flow agents, excellent water-reducing properties and hold the flowability of the concrete over a relatively long period of time (60 to 90 min.) to an almost unchanged level without having delayed action. In addition, the corresponding polymeric additives improve the processing and setting processes of the building materials produced with these additives by making possible earlier and higher resistances to pressure.

Abstract: The object of the present invention is to provide a process for producing high-quality polymer microparticles having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse polymerization of a vinyl monomer and is characterized in that the inverse suspension polymerization is conducted dividing at least two steps, that a water-soluble oxidizing agent and a water-soluble reducing agent are used as a polymerization initiator, and that the oil-soluble oxidizing agent is fed after the water-soluble reducing agent is fed.

Abstract: Iodine containing amorphous fluoropolymers having at least one fluoropolymer with a cure site, where the fluoropolymer has a Mooney viscosity of 2 or less (ML 1+10) at 100° C. according to ASTM D1646, and a peel strength to a roll mill of 10 dN/cm or less and methods for making such iodine containing amorphous fluoropolymers are described. Articles derived from the cured product of such iodine containing amorphous fluoropolymers are also described. Solutions, dispersions and coatings derived from such iodine containing amorphous fluoropolymers are also described.

Abstract: The present invention relates to a novel one step process for preparing cross-linked poly(allylamine) polymers or salts thereof using the novel cross-linking agent of Formula (IV). This invention also relates to the compound of Formula (IV) as well as to a process to obtain it. The cross-linked poly(allylamine) polymers of the invention are useful in medicine as substrate-binding polymers.

Abstract: The invention provides a method for preparing an aqueous dispersion of polymer particles comprising the following steps: (i) preparing a dispersion having a continuous aqueous phase, a dispersed organic phase comprising one or more ethylenically unsaturated monomers, and an amphiphilic RAFT agent as a stabilizer for said organic phase, and (ii) polymerizing said one or more ethylenically unsaturated monomers under the control of said amphiphilic RAFT agent to form said aqueous dispersion of polymer particles, novel amphiphilic RAFT agents for use in this method, novel RAFT agents useful in making these amphiphilic RAFT agents and methods for their manufacture.

Abstract: A method of preparing an ink includes homogenizing a dispersion to coat pigment particles in the dispersion with a monomer. An ink for use in a printing device includes pigment particles encapsulated in a polymerized monomer, where the monomer has a polarity that is higher than a polarity of a surface of the pigment particles.

Abstract: A method is disclosed in which modified and generic dental resins are combined as mixtures with reactive polymeric nanoparticles (RPNPs). Nanoparticles as additives clearly demonstrate that the RPNPs significantly influence the mechanical and shrinkage properties of the matrix and composites.

Abstract: The present invention relates to anaerobically curable compositions based on (meth)acrylate-functionalized poly(acrylate) polymers.

Abstract: A method is disclosed for producing polyvinyl chloride which includes mixing a vinyl chloride solution with an initiator solution in at least one high shear mixing device comprising at least one rotor/stator set producing a rotor tip speed of at least 5.1 m/sec (1000 ft/min), to form a polymerization mixture; and allowing the mixture to polymerize by free radical polymerization to form polyvinyl chloride. The polymerization mixture may be subjected to free radical polymerization conditions comprising a temperature in the range of about 20° C. to about 230° C. In some embodiments, the high shear mixing device produces a shear rate of at least 20,000 s?1. A system for carrying out the method is also disclosed.

Abstract: A combination of a styrene reduction agent and a catalyst that effectively and economically reduces styrene emissions in Cured-In-Place Pipe, closed molding processes. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. The catalyst is hydrogen peroxide (H2O2). A calibrated amount of the styrene reduction agent capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process, and this is followed by a calibrated amount of the H2O2 catalyst in order to reduce the residual monomer content in either process or waste streams.

Abstract: The present invention discloses styrene-maleic anhydride copolymers preparations using solventless techniques. The solventless method resulted in reduced amounts of residues, such as unreacted styrene and/or maleic anhydride monomers, which makes the copolymers particularly suitable for bioapplications.

Abstract: A process for preparing polyvinylpyrrolidones by free-radically initiated polymerization in the presence of an initiator found, which comprises performing the polymerization as a spray or droplet polymerization.

Abstract: A process for preparing a pressure-sensitive polyacrylate adhesive, characterized in that a polyacrylate composition including the atomic sequence C—S—C is admixed with at least one metal compound of type (L)yM where M=metal atom or metal ion L=counterion or ligand y=0 to 6.

Abstract: Compositions comprising a cross-linked isocyanurate homopolymer or other cross-linked triazine homopolymers in the form of a microbead that is porous or non-porous; methods of making; and methods of using the compositions are disclosed.

Abstract: A process for producing a polymer latex includes a step of mixing at least one kind of polymerizable monomer with water and a polymerization initiator to perform a polymerization, wherein the at least one kind of polymerizable monomer includes an acrylonitrile in an amount of 50 mass % or more based on a total amount of the at least one kind of polymerizable monomer.

Abstract: A method of modifying a polyethylene is disclosed. In the method ethylene or a mixture of ethylene and a C3-C10 ?-olefin is polymerized in an organic solvent with a Ziegler or single-site catalyst to form an initial polyethylene solution. The initial polyethylene solution is then reacted with a free radical initiator to produce a modified polyethylene. The modified polymer has an enhanced melt elasticity and increased long chain branching index, and is essentially free of gel.

Abstract: The invention relates to copolymers based on phosphorous-containing monomers (A) and on macromonomers (B), to methods for the production thereof and to their use as additives for inorganic binding agent suspensions based on cement, lime, gypsum and anhydrite. The corresponding polymeric additives have, as flow agents, excellent water-reducing properties and hold the flowability of the concrete over a relatively long period of time (60 to 90 min.) to an almost unchanged level without having delayed action. In addition, the corresponding polymeric additives improve the processing and setting processes of the building materials produced with these additives by making possible earlier and higher resistances to pressure.

Abstract: Curable formulations comprising: (a) at least one multifunctional acrylate having a functionality of at least two, (b) at least one mono-acrylate monomer, (c) at least one heteroatom-containing diacrylate, wherein the heteroatom is sulfur or selenium; and (d) a curing agent, have been discovered. The curable formulations show promise as precursors to high refractive index materials suitable for use in light management devices and other optical devices. In addition the novel curable formulations are useful for producing coatings, which may be useful in forming display films, in particular brightness enhancing display films.

Abstract: A stable free radical process for preparing a polymer having acid anhydride functionality includes heating a mixture comprised of a stable free radical agent, maleic anhydride or derivative thereof, and at least one polymerizable electron donor monomer to initiate exothermic reaction and during exotherm of the reaction, adding additional amounts of stable free radical agent to control the reaction temperature. The mixture may also include a stable free radical initiator. In the mixture, the maleic anhydride or derivative thereof preferably comprises from about 10% to about 70%, molar basis, of a total amount of the maleic anhydride or derivative thereof and the at least one polymerizable electron donor monomer. Typically, the heating is to a temperature of from about 100° C. to about 160° C., and the rate of addition of the additional amounts of stable free radical agent is adjusted to control the reaction temperature to be about 160° C. or less.

Abstract: A process for producing organic peroxide initiators useful in the polymerization of ethylenically unsaturated monomers. The process for making the organic peroxides includes forming an aqueous emulsion of the organic peroxide. The organic peroxide is dispersed as small droplets of from 1 to 10 microns in size in the aqueous emulsion. The organic peroxide may be added to a polymerization reactor containing an ethylenically unsaturated monomer. The organic peroxide functions as a free radical initiator to polymerize the monomer. The organic peroxide may be substantially free of organic solvents and plasticizers. The resulting polymers are of high quality.

Abstract: A formulation based on the PTFE, homopolymer or modified, comprising: 1) latex of said PTFE having a particle diameter between 5 and 100 nm, comprising an anionic fluorinated surfactant in an amount in the range 2–25% by weight based on the PTFE; 2) a non ionic fluorinated surfactant added to the PTFE latex in an amount in the range 18–60% by weight based on the PTFE.

Abstract: An initiator system for radical polymerization, which comprises a combination of compounds of the formulae:

Abstract: The invention relates to polymer beads having a high content of diacyl peroxides. A prolongation of the pot life in reaction resins based on high-boiling methacrylate esters is achieved due to this high content of peroxides.

Abstract: The invention provides a hot melt adhesive composition including a tubular reactor copolymer of ethylene and 5 to 20 mol % of comonomer units derived from an alkyl acrylate or alkyl methacrylate, wherein the copolymer has a melt index of at least 300 g/10 min. The alkyl group of the alkyl acrylate or alkyl methacrylate can be a linear or branched C1 to C12 group, particularly n-butyl. If desired, the hot melt adhesive can further include tackifiers, waxes, antioxidants and other desired additives. The hot melt adhesive composition shows improved heat resistance and favorable properties, such as has a shear adhesion fail temperature of at least 80° C., without the need to use high melting waxes. The invention further provides articles such as cartons, cases, trays, bookbindings or disposables including the hot melt adhesive compositions.

Abstract: An aqueous polymer blend composition including a predominant amount of soft polymer particles and a minor amount of hard polymer particles is provided. The soft polymer particles contain, as copolymerized units, 70 to 99.7% by weight monoethylenically unsaturated (meth)acrylic monomer and from 0.3 to 10% by weight monoethylenically unsaturated acid monomer, based on weight of soft polymer particles. The soft polymer particles are made by a select process including redox polymerization or polymerization in the presence of excess unreacted monomer. The aqueous polymer blend composition is useful for preparing dry coatings having improved dirt pickup resistance and acceptable scrub resistance. A method is provided for preparing a dry coating from the aqueous polymer blend composition.