From Metal Containing Monomer Patents (Class 526/240)
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Patent number: 6084032Abstract: A polymer composition containing carboxyl groups which has excellent water solubility, thickening properties and flow characteristics. The composition comprises (A) a crosslinked polymer comprising (a) an .alpha.,.beta.-unsaturated carboxylic acid and (b) a compound having at least two ethylenically unsaturated groups, and (B) at least one polymer comprising N-vinylpyrrolidone as essential monomer.Type: GrantFiled: April 22, 1998Date of Patent: July 4, 2000Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Masato Fujikake, Shinji Kobayashi, Shigeki Hamamoto, Mitsutaka Tabata, Tomoki Kawakita
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Patent number: 6063184Abstract: The invention relates to a random styrene-maleic anhydride (SMA) copolymer in free acid or salt form wherein the copolymer has the following types and numbers of monomer units ##STR1## in which M is selected from hydrogen, a cation and a residue of a hydrophobic polyalkylene glycol or polysiloxane, R is the residue of methylpoly(ethylene)glycol of molecular weight (weight-average) 900-2000, x=0.35-0.75 and y=0.25-0.65. These copolymers are particularly useful as superplasticizers in cementitious compositions such as concretes and mortars.Type: GrantFiled: May 22, 1998Date of Patent: May 16, 2000Assignee: MBT Holding AGInventors: Bernhard Leikauf, Max Oppliger, Salvatore Valenti
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Patent number: 6057412Abstract: An amphipathic compound represented by any of the following Formulas: ##STR1## (R.sub.1 is a linear or branched, saturated hydrocarbon group having 6 to 48 carbon atoms, or a linear or branched, unsaturated hydrocarbon group containing 1 to 12 unsaturated double bond and having 6 to 48 carbon atoms; Y is NH, N--(CH.sub.2 --CH.dbd.CH.sub.2), or O; Q is --CH.sub.2 --C(R.sub.2).dbd.CH.sub.2 or --R.sub.4 --O--CO--C(R.sub.2).dbd.CH.sub.2 ; and M is alkali metal, an ammonium group, or --(CH.sub.2 CH.sub.2 O).sub.m H), a copolymer of the amphipatic compound with a copolymerizable ethylenically unsaturated compound and, a paper making additive containing a water soluble or dispersible high molecular compound as an active ingredient and processes for producing these high molecular compounds.Type: GrantFiled: July 17, 1998Date of Patent: May 2, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Toshihiko Takaki, Masaru Tanabe, Hiroshi Itoh, Masayuki Yanagi, Shoko Oyanagi, Hiroyoshi Watanabe
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Patent number: 6057410Abstract: Polymeric ligands, polymeric metallocenes, and processes for preparing same are provided. The process for preparing polymeric metallocenes comprises reacting a polymeric ligand, a transition metal compound, and an alkali metal compound. In one embodiment, a process for preparing polymeric ligands comprises reacting at least one bridged cyclopentadienyl-type monomer and an initiator under polymerization conditions. In another embodiment, a polymeric ligand is represented by the formula [Q'].sub.n, wherein Q' is a unit containing at least one bridged cyclopentadienyl-type group and wherein n is 1-5000. In another embodiment, a polymeric metallocene is represented by the formula [Q"MX.sub.m ].sub.Type: GrantFiled: March 26, 1998Date of Patent: May 2, 2000Assignee: Phillips Petroleum CompanyInventors: Helmut G. Alt, Peter Schertl, Bernd Peifer, Syriac J. Palackal, M. Bruce Welch
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Patent number: 6037429Abstract: In one aspect, the present invention provides a water-soluble and shelf-stable aqueous fluorochemical polymeric treatment useful to treat porous substrates to render them repellent to water- and oil-based stains. The treatment comprises a water-soluble fluorochemical polymer containing only carbon atoms in the backbone, with a plurality of each of the following groups pendent from the backbone: (a) fluoroaliphatic groups, (b) carboxyl-containing groups, (c) oxyalkylene or polyoxyalkylene groups, and, optionally, (d) silyl groups.Type: GrantFiled: June 16, 1995Date of Patent: March 14, 2000Assignee: 3M Innovative Properties CompanyInventors: Jeffrey G. Linert, Patricia M. Savu
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Patent number: 5994485Abstract: A vinyl chloride/vinyl acetate copolymer characterized in that it has a peak at a signal position of from 6.0 to 8.0 ppm in the .sup.1 H-NMR measurement.Type: GrantFiled: May 20, 1998Date of Patent: November 30, 1999Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hirohisa Otake, Yukihisa Hoshino
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Patent number: 5962580Abstract: A method for providing a waterborne coating composition having improved color acceptance is provided. More particularly, a method for improving the color acceptance of a waterborne coating composition containing an emulsion-polymerized addition polymer by incorporating a polymerizable surfactant into the polymer with a certain surface coverage of bound surfactant is provided.Type: GrantFiled: June 7, 1995Date of Patent: October 5, 1999Assignee: Rohm and Haas CompanyInventors: Asare Nkansah, Robert David Solomon, Stewart Orlyn Williams
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(Meth) acrylic resin compositions for marine antifouling paints and corresponding paint compositions
Patent number: 5919840Abstract: This organosoluble (meth)acrylic resin composition is characterized in that it includes a polymer containing units derived from methacrylic acid which are esterified with --Ti(OR).sub.3 groups, mixed with free Ti(OR).sub.4, which represents the excess of Ti(OR).sub.4 which has been introduced for the preparation of the said polymer in sufficient quantity for the resulting composition to be organosoluble and not in gel form, R representing one of ethyl, isopropyl, n-butyl, t-butyl, 2-ethylhexyl and t-amyl. It may be the product of esterification in a solvent medium of a polymer containing units derived from methacrylic acid with Ti(OR).sub.4, the Ti/COOH molar ratio being higher than 1, preferably being between 3/1 and 10/1; or the product of radical copolymerization in a solvent medium of at least one methacrylic acid esterified with Ti(OR).sub.3 and of at least one comonomer, in the presence of Ti(OR).sub.4, in a quantity which would have corresponded to a reaction between the methacrylic acid and Ti(OR).Type: GrantFiled: August 21, 1997Date of Patent: July 6, 1999Assignee: Elf Atochem, S.A.Inventors: Didler Vanhoye, Michel Camail, Andre Margaillan, Jean-Louis Vernet, Marie Humbert -
Patent number: 5891935Abstract: The invention relates to binders for antifouling coating compositions, which can be prepared by copolymerizing polymerizable monomers, wherein, as polymerizable monomers, mixtures ofA) at least one of the compounds of the general formula I ##STR1## and B) at least one ethylenically unsaturated compound having the general formula II ##STR2## with or without C) at least one ethylenically unsaturated compound are polymerized.Type: GrantFiled: October 23, 1997Date of Patent: April 6, 1999Assignee: Witco GmbHInventor: Uwe Schneider
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Patent number: 5891973Abstract: Disclosed herein is a game ball and method for making the same. The game ball has an ionomeric cover which includes a combination of ionomeric crosslinks and covalent crosslinks. The game ball cover is superior in at least one of cut resistance and scuff resistance to a conventional cover that does not have covalent crosslinks but is otherwise substantially identical in composition. The game ball cover of the invention is particularly useful for improving the durability of golf balls to be struck with sharp-grooved clubs.Type: GrantFiled: October 2, 1997Date of Patent: April 6, 1999Assignee: Lisco, Inc.Inventors: Michael J. Sullivan, Thomas Kennedy
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Patent number: 5874511Abstract: A process for the production of polymers by free radical polymerization, characterized in that there is added to the polymerization system one or more compounds of the general formula (A). ##STR1## where R.sup.1 is hydrogen or a group capable of activating the vinylic carbon towards free radical addition;Y is OR.sup.2 or CH.sub.2 X(R.sup.2).sub.nwhere R.sup.2 is an optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, or optionally substituted saturated, unsaturated or aromatic carbocyclic or heterocyclic ring;X is an element other than carbon selected from Groups IV, V, VI or VII of the Periodic Table or a group consisting of an element selected from Groups IV, V, or VI to which is attached one or more oxygen atoms; andn is a number from 0 to 3, such that the valency of the group X is satisfied and, when n is greater than 1, the groups represented by R.sup.2 may be identical or different.Type: GrantFiled: June 24, 1996Date of Patent: February 23, 1999Assignees: E. I. du Pont de Nemours and Company, Commonwealth Scientific and Industrial Research OrganisationInventors: Ezio Rizzardo, Gordon Francis Meijs, San Hoa Thang
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Patent number: 5868966Abstract: Hybrid materials are formed having a homogeneous distribution of a conductive organic polymer or copolymer in an inorganic matrix. The conductive organic polymer may be electronically conductive, e.g., polyaniline, or may be ionically conductive, e.g., sulfonated polystyrene. The inorganic matrix is formed as a result of sol-gel chemistry, e.g., by the hydrolysis and condensation of tetraethyl orthosilicate and trialkoxysilyl groups in the organic polymers. A homogeneous distribution of organic polymer in the inorganic matrix is achieved by preparing separate solutions of organic polymer and sol-gel monomer, and then combining those solutions with a catalyst and stirring, to form a homogeneous clear solution. Upon evaporation of the solvent and other volatiles, a monolithic hybrid material may be formed. The combination of conductive organic polymer in an inorganic matrix provides desirable adhesion properties to an inorganic substrate while maintaining the conductivity of the organic polymer.Type: GrantFiled: August 22, 1996Date of Patent: February 9, 1999Assignee: Drexel UniversityInventors: Yen Wei, Jui-Ming Yeh, Wei Wang, Guang-Way Jang
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Patent number: 5857925Abstract: A golf ball including a core, and a gamma irradiated, ionomeric, dimpled cover having a Shore D hardness of 55 or less as measured on a non-dimpled portion of the cover, the dimples maintaining their shape when the cover is subjected to heat treatment at 160.degree.-180.degree. F. for at least one hour. In making the golf ball, the dimpled cover is subjected to gamma irradiation in a dosage sufficient to increase the vicat softening point in degrees Fahrenheit of the cover by at least 2.5%.Type: GrantFiled: July 11, 1997Date of Patent: January 12, 1999Assignee: Lisco, Inc.Inventors: Michael J. Sullivan, Mark L. Binette, Thomas Kennedy, Michelle A. Bellinger
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Patent number: 5856415Abstract: A method for producing a metal-containing transparent polymer by the reaction of a metal carboxylate, with a clear setting resin system comprising a thermosetting resin and a curing agent. The reaction occurs in a temperature in the range of from about 0.degree. to about 100.degree. C. under conditions which prevent air from being entrapped in the mixture, either during mixing of the reagents or during reaction. The metal carboxylate contains from about 20 to about 60 weight percent of metal. The reagents react for a time sufficient to form a transparent polymer. The resins include preferably epoxies, polyesters, polyurethane, polyisocyanurate, polyether sulfones, polyimides, and mixtures of two or more of these thermoset polymers. The final metal-containing transparent polymer preferably contains at least 15% by weight of the metal. Preferred metals include antimony, barium, bismuth, cadmium, cerium, cobalt, copper, iron, lead, molybdenum, tungsten, ranadium, and zirconium.Type: GrantFiled: August 28, 1997Date of Patent: January 5, 1999Assignee: Bar-Ray Products, Inc.Inventors: Arthur Lagace, Ray C. Lapof
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Patent number: 5856418Abstract: A water-soluble monomer is shown by general formula (1) below. This monomer, for example, can be obtained by reacting asparagic acid and maleic anhydride in an aqueous basic solution under cooled conditions. A water-soluble polymer has a structural unit of general formula (2) below and a weight-average molecular weight of about 800 to about 8,000,000, and is, for example, produced by polymerizing a monomer including the water-soluble monomer of general formula (1). The water-soluble polymer has excellent chelating and dispersing actions and therefore can favorably be used for various purposes, such as, detergent compositions, inorganic-pigment dispersants, fiber-treating agents, water-treating agents, wood pulp-bleaching assistants.Type: GrantFiled: April 9, 1997Date of Patent: January 5, 1999Assignee: Nippon Shokubai Co., Ltd.Inventors: Yoshihiro Maeda, Shigeru Yamaguchi
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Patent number: 5849834Abstract: A W/O type emulsified composition comprising an oil phase containing ethyl cellulose and a solvent capable of swelling ethyl cellulose and a water phase containing a water soluble polymer(s) emulsified as a water-in-oil type (W/O type) emulsion. A W/O type emulsified composition comprising an oil phase containing ethyl cellulose and a solvent capable of swelling ethyl cellulose and a water phase containing a polyion complex comprising cationized cellulose and sodium hyaluronate emulsified as a water-in-oil type (W/O type) emulsion.Type: GrantFiled: March 10, 1997Date of Patent: December 15, 1998Assignee: Shiseido Co., Ltd.Inventors: Fumiaki Matsuzaki, Toshio Yanaki, Michihiro Yamaguchi
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Patent number: 5847064Abstract: An organometallic polymer having the following moiety: ##STR1## is disclosed. R.sub.1 and R.sub.2 are independently selected from the group of H, alkyl having 30 or fewer carbons, alkenyl having 30 or fewer carbons, and aromatic having one to ten rings; n=0-30; p=0-30; and M is a metal selected from the group consisting of Sn, Ge, Pb, Hg, Ni, Pd, Pt, Cr, Fe, Co, Cu, and Zn. Most preferably, M is Sn, R.sub.1 and R.sub.2 are n-butyl, n is 3, and p is 3. A preferred antibacterial/antifungal composition may be formed by combining the polymer with a suitable carrier.Type: GrantFiled: February 27, 1997Date of Patent: December 8, 1998Assignee: University of FloridaInventors: Kenneth B. Wagener, Patrick S. Wolfe, Fernando J. Gomez
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Patent number: 5837776Abstract: Aqueous dispersions of water soluble nonionic and anionically charged vinyl and allyl addition polymers can be obtained by polymerizing in the presence of an anionically charged water soluble polymer stabilizer in a saturated salt solution. Methods for the preparation of these polymers, and their compositions are disclosed.Type: GrantFiled: January 10, 1997Date of Patent: November 17, 1998Assignee: Nalco Chemical CompanyInventors: Radhakrishnan Selvarajan, John R. Hurlock
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Patent number: 5834576Abstract: A novel acrylic ester which is represented by general formula (2) ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or an organic residue, R.sub.3 represents an organic residue, n is a positive number among 1 to 3, and m is a positive number among 1 to 100 and which is applicable to various uses, is obtained by reacting an acrylic ester of general formula (3) ##STR2## wherein R.sub.1 represents a hydrogen atom or an organic residue, and R.sub.3 represents an organic residue, with a cyclic ether compound of general formula (4) ##STR3## wherein R.sub.2 represents a hydrogen atom or an organic residue, and n is a positive number among 1 to 3. Moreover, a novel acrylic acid derivative whose use is even wider is obtained by hydrolyzing the acrylic acid derivative.Type: GrantFiled: February 27, 1996Date of Patent: November 10, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Hideaki Nagano, Koichi Nakagawa, Keiji Yurugi, Mitsuaki Makino, Tsuyoshi Hirata, Koichiro Nagare, Yuichi Kita
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Patent number: 5821300Abstract: The invention relates to binders for antifouling coating compositions, which are prepared by copolymerizing a mixture of polymerizable monomers comprisingA) at least one of the compounds of the general formula I ##STR1## and B) at least one ethylenically unsaturated compound having the general formula II ##STR2## with optionally C) at least one ethylenically unsaturated compound, where the molar ratio of (A+B) to C is from 1:0 to 1:10, are polymers in the presence of a free-radical initiator and inert solvent.Type: GrantFiled: October 23, 1997Date of Patent: October 13, 1998Assignee: Witco GmbHInventor: Uwe Schneider
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Patent number: 5792822Abstract: A transparent plastic material and an optical article formed of the material which have no variation in color, no generation of precipitation, properties to selectively absorb only light of a specific wavelength, selectively block or reduce light of a wavelength which is dazzling to human eyes, and block harmful ultraviolet light. A transparent plastic material includes a polymer obtained by polymerizing one or more polymerizable monomersin the presence of a polymerization initiator or polymerization catalyst, wherein the polymer contains a complex compound of Formula (I):A.sub.2 M(OH)(H.sub.2 O) (I)wherein M denotes Sc, Y, La, Pt, Nd, Pm, Sm, Gd, Dy, Ho, Er, Tm, or Lu; A is a ligand for forming a chelate complex having a structure shown below ##STR1## and containing at least one of an aryl group and a heterocyclic group.Type: GrantFiled: February 23, 1996Date of Patent: August 11, 1998Assignee: Seiko Epson CorporationInventors: Toshiyuki Miyabayashi, Jun Kinoshita
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Patent number: 5786392Abstract: Compounds of formula (I) are disclosed: ##STR1## wherein L.sup.1 is a main group atom, L.sup.2 is a neutral ligand, M is a transition element or a metal element of Group 13, 14, 15, or 16 of the Periodic Table, x is the number of coordination sites of M, R.sup.1 is a polymerizable group, R.sup.2, R.sup.3, and R.sup.4 are ligands, and R.sup.5 is an anionic ligand. The compounds or monomers of formula (I) are capable of conversion to polymers by combination with one or more other known monomers, such as methyl methacrylate. Such polymers can then be added as a binder in a paint formulation to make marine antifouling coating compositions. Also described is a method to prevent fouling on surfaces wherein a composition containing a metal complex compound of formula (II): ##STR2## wherein M, x, L.sup.2, n, and R.sup.4 have the same meaning as in formula (I), is applied to the surface susceptible to fouling.Type: GrantFiled: March 25, 1997Date of Patent: July 28, 1998Inventors: Gary S. Silverman, Haewon L. Uhm, Kenneth K.S. Tseng
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Patent number: 5763553Abstract: The invention is related to the synthesis of novel types of maleic-acrylic copolymers containing 60 to 100% of maleate units (by weight), respectively, 40 to 0% of acrylate units (by weight) based on the sum of both monomeric units composing the copolymer. These copolymers show significant techno-economical and ecological advantages over previously synthesized and described acrylic-maleic copolymers. According to the optimal synthetic procedure for this class of copolymers, one uses very concentrated starting alkaline maleate solutions (at best over 60%), hydrogen peroxide and alkaline peroxy salts as initiators--catalysts for the copolymerization process, as well as reaction temperatures between 105.degree. and 115.degree. C. The obtained copolymers have average molecular masses around 20000, while CCDC values are approximately 17-18 ml 0,25M Calcium Acetate per 1 g of copolymer. The obtained copolymers are well suited for their use as incrustation inhibitors, dispersants or ionic exchangers.Type: GrantFiled: January 3, 1997Date of Patent: June 9, 1998Inventor: Dusan A. Miljkovic
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Patent number: 5739232Abstract: Curable and cured water based compositions having improved substrate adhesion, methods for their preparation and uses are provided. The coating and adhesive compositions comprise a water soluble compound, a metal salt of an .alpha., .beta.-ethylenically unsaturated compound, and a cure initiator. The compositions of the present invention are useful as substrate coating and adhesive compositions.Type: GrantFiled: August 1, 1995Date of Patent: April 14, 1998Assignee: Sartomer CompanyInventors: Thomas W. Hazell, Walter Nagel, C. Richard Costin, Gary W. Ceska
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Patent number: 5739178Abstract: A polymeric material incorporating a polyvalent cation chelating agent in an amount effective to inhibit the growth of an ocular pathogen, particularly a protozoan, can be used to produce eye care products such as contact lens cases and containers for containing eye care solutions and contact lenses.Type: GrantFiled: May 15, 1995Date of Patent: April 14, 1998Assignee: AllerganInventors: Charles Hayes Powell, David C. Rupp
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Patent number: 5708049Abstract: A contact lens colored with a poly(meth)acrylate-combined metallophthalocyanine compound represented by the following formula (I): ##STR1## wherein M represents a metal atom to which phthalocyanine can coordinate, R represents a halogen atom, m is an integer of 0 to 4, R.sup.1 represents a hydrogen atom or a methyl group, and A represents a hydrogen atom, a C.sub.1-12 alkyl group, a hydroxyC.sub.1-12 alkyl group or a glycerol group. The colored contact lens has sufficiently high fastness, so that the lens undergoes neither color change nor color fading even when it is sterilized by boiling.Type: GrantFiled: February 7, 1996Date of Patent: January 13, 1998Assignee: Seiko Epson CorporationInventors: Hiroshi Katagiri, Tadao Kojima, Youichi Ushiyama
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Patent number: 5707445Abstract: An admixture for concrete comprising, as an essential component, a copolymer prepared by copolymerizing (a) a polyalkylene glycol monoester monomer having 110 to 300 mols of an oxyalkylene group(s) each having 2 to 3 carbon atoms, with (b) at least one monomer selected from among acrylic monomers, unsaturated dicarboxylic monomers and allylsulfonic monomers. When this admixture is used in preparing concrete, the resulting concrete composition undergoes little change in the slump for a lengthened time, so that the quality of the concrete composition can be easily controlled.Type: GrantFiled: June 13, 1996Date of Patent: January 13, 1998Assignee: Kao CorporationInventors: Fujio Yamato, Shuichi Fujita, Yoshiaki Tanisho, Kazushige Kitagawa, Haruyuki Satoh
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Patent number: 5698512Abstract: Water soluble polymers are prepared from an allyloxybenzenesulfonic acid monomer, a methallyl sulfonic acid monomer, a copolymerizable nonionic monomer, and a copolymerizable olefinically unsaturated carboxylic acid monomer. Aqueous compositions containing the water soluble polymers and nonionic surfactants are stable to phase separation of the polymer from the nonionic surfactant.Type: GrantFiled: June 18, 1996Date of Patent: December 16, 1997Assignee: National Starch and Chemical Investment Holding CorporationInventors: Anne-Marie B. Austin, Allen M. Carrier, Michael L. Standish
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Patent number: 5681479Abstract: Phosphonic coletomers of the formula I: ##STR1## wherein X.sub.5 is hydrogen, an alkali metal atom, an alkaline earth metal atom, or an ammonium or amine residue; and A.sub.2 is a copolymer residue comprising two different residues ##STR2## wherein r is an integer ranging from 2 to 100, and wherein, in the first residue, W.sub.3 is --COOH, and in the second residue, W.sub.3 is --CONHC(CH.sub.3).sub.2 CH.sub.2 SO.sub.3 X.sub.5 wherein X.sub.5 is as hereinbefore defined. The cotelomers inhibit scale and corrosion in aqueous systems.Type: GrantFiled: June 7, 1995Date of Patent: October 28, 1997Assignee: FMC Corporation (UK ) LimitedInventors: Elizabeth A. Kerr, Jan Rideout
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Patent number: 5670593Abstract: To provide a fluorine-containing olefin represented, for example, by CH.sub.2 .dbd.CFCF.sub.2 --R.sub.f.sup.6 --(CH.sub.2).sub.k --X.sup.2 ?wherein, X.sup.2 is --CH.sub.2 OH, ##STR1## or ##STR2## R.sub.f.sup.6 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or --OR.sub.f.sup.7 -- (Rf.sup.7 is a fluorine-substituted fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-substituted fluorine-containing ether group having 3 to 50 carbon atoms), k is 0 or an integer of 1 to 6!; a fluorine-containing polymer with functional group which is prepared by polymerizing the above-mentioned olefin, has good affinity with various heat-resisting thermoplastic resins and is capable of forming homogeneous dispersion with the thermoplastic resin; and a thermoplastic resin composition comprising the above-mentioned fluorine-containing polymer with functional group and an aromatic polyester or the like as the heat-resisting thermoplastic resin.Type: GrantFiled: February 9, 1996Date of Patent: September 23, 1997Assignee: Daikin Industries, Ltd.Inventors: Takayuki Araki, Tetsuo Shimizu, Takafumi Yamato, Masahiro Kumegawa, Yoshihisa Yamamoto
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Patent number: 5668203Abstract: A haloceramic material having integral, interpenetrating networks of haloelastomer, metal oxide, and optionally polyorganosiloxane forms highly advantageous seals such as gaskets, tapes, diaphragms, bearing, o-rings and the like. The haloceramer seals properties include a combination of thermal stability, chemical inertness and flexibility.Type: GrantFiled: June 7, 1995Date of Patent: September 16, 1997Assignee: Xerox CorporationInventors: Santokh S. Badesha, Arnold W. Henry, Donald A. Seanor
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Patent number: 5652296Abstract: A water-based adhesive comprising water-soluble polymers having carboxy groups and quaternary ammonium groups wherein the polymers can be derived by copolymerizing one or more unsaturated aliphatic carboxylic acid monomers, such as acrylic acid and/or methacrylic acid, and alkylaminoalkyl(meth)acrylate or alkylaminoalkyl(meth)acrylamide, such as dimethylaminoethyl methacrylate or dimethylaminopropylmethacrylamide and the water-based adhesive is a viscous liquid that is colorless, relatively odorless, and free of organic solvents.Type: GrantFiled: March 15, 1996Date of Patent: July 29, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventor: Neil A. Randen
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Patent number: 5648441Abstract: A polymerizable mixture containing acrylic acid or a partially cross-linked oligomer acrylate is used for the manufacture of a non fogging or low fogging layer on a substrate. The polymerizable mixture contains 1 to 10% W of a salt, in particular a salt of acrylic acid, as well as any necessary further additives.Type: GrantFiled: June 24, 1996Date of Patent: July 15, 1997Assignee: Gurit-Worbla AGInventors: Martin Keller, Martin Lenhard
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Patent number: 5627244Abstract: Disclosed is a process for producing a polymer of an unsaturated carboxylic acid or a derivative thereof, the process comprising polymerizing an unsaturated carboxylic acid or a derivative thereof in a water-soluble organic solvent-water mixture in the presence of at least one polymerization catalyst selected from the group consisting of a metal compound of the formulaL.sub.p.M.X.sub.q ( 1)wherein M is Ti, Zr, Hf or V, L is cyclopentazienyl, indenyl, fluorenyl or a derivative of these, X is halo, H, lower alkyl, lower alkoxyl, aryloxy, phenyl or benzyl, p and q each represents an integer including 0 and p+q is equal to the valence of M, and a metal compound of the formulaR.M.Y.sub.r ( 2)wherein M is defined above, R is a group formed by bonding, via a lower alkylene or di(lower alkyl)silylene group, two groups being cyclopentadienyl, indenyl, fluorenyl or a derivative of these, Y is halo, H, lower alkyl, lower alkoxyl, aryloxy, phenyl or benzyl, r is equal to the valence number of M minus 2.Type: GrantFiled: April 26, 1995Date of Patent: May 6, 1997Assignees: Sumitomo Chemical Co., Ltd., Nichia Chemical Industries Ltd.Inventor: Tsuneyuki Sato
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Patent number: 5616651Abstract: There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance.Type: GrantFiled: October 20, 1995Date of Patent: April 1, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Mariano S. Ni no, Hung D. Ngoc
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Patent number: 5610255Abstract: Polysuccinimide and polyaspartic acid are prepared by polymerizing maleic anhydride, ammonia and water or maleic acid derivatives or fumaric acid derivatives in bulk or dissolved in solvents in a continuous kneading reactor. The polysuccinimide formed can be converted into polyaspartic acid and polyaspartate salts by hydrolysis.Type: GrantFiled: August 18, 1995Date of Patent: March 11, 1997Assignee: Bayer AGInventors: Torsten Groth, Winfried Joentgen, Nikolaus M uller, Ulrich Liesenfelder
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Patent number: 5610249Abstract: The present invention provides a process for producing a styrene or styrene derivative polymer of narrow molecular weight distribution, which comprises (co)polymerizing a styrene or styrene derivative monomer using, as the catalyst system, a mixture of a free radical compound, a radical polymerization initiator and a phosphorus compound. With the present process, the polymerization speed is very high and a monodisperse polymer of narrow molecular weight distribution can be obtained easily.Type: GrantFiled: January 24, 1996Date of Patent: March 11, 1997Assignee: Kansai Paint Co., Ltd.Inventor: Tetsuo Ogawa
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Patent number: 5605994Abstract: The present invention relates to bis-imidazolyl compounds of the formula: ##STR1## and polymers having the above-identified bis-imidazolyl compounds as a polymerizable unit. The present invention further relates to a method for scavenging trace quantities of metal ions from various effluents sources using the polymers of the instant invention. The instant invention also is directed to the use of the above-identified polymers as corrosion inhibiting agents and as a film for use in gel electrophoresis.Type: GrantFiled: June 6, 1995Date of Patent: February 25, 1997Assignee: Research Corporation Technologies, Inc.Inventors: J. Thomas Ippoliti, Gary A. Mabbott, Jeremy Hans, Michelle Stohlmeyer
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Patent number: 5604291Abstract: Phosphonic telomer intermediates for preparing the telomers of U.S. Pat. No. 5,376,731 may be produced by an aqueous process comprising (a) reacting hypophosphorous acid with a carbonyl compound which is preferably an aldehyde, a ketone or an imine, and (b) reacting the product of (a) with an olefinic reactant or reactants in the presence of a suitable initiator especially a free radical initiator. The telomer intermediates are themselves useful as scale inhibitors in aqueous systems.Type: GrantFiled: September 16, 1994Date of Patent: February 18, 1997Assignee: FMC Corporation (UK) LimitedInventors: Elizabeth A. Kerr, Jan Rideout
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Patent number: 5589537Abstract: Single phase solid materials containing metal clusters are produced by dissolving a metal cluster having chemically bound polymerizable organic ligands in a polymerizable organic solvent, homogeneously dispersing the metal cluster, and then copolymerizing the organic solvent and the chemically bound polymerizable organic ligands.Type: GrantFiled: June 7, 1995Date of Patent: December 31, 1996Assignee: Cornell Research Foundation, Inc.Inventors: Josh H. Golden, Francis J. DiSalvo, Jean M. J. Frechet
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Patent number: 5587443Abstract: New compounds corresponding to formula (I) ##STR1## and their use as emulsifiers for aqueous emulsions and, in the case of carboxylic acid derivatives, also as reactive groups for linking to biologically active substrates. New polymers synthesized from the emulsifiers and other monomers are also claimed.Type: GrantFiled: August 8, 1994Date of Patent: December 24, 1996Assignee: Bayer AktiengesellschaftInventors: Ludger Heiliger, Adolf Schmidt, Joachim Probst
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Patent number: 5565535Abstract: A method for improving the substrate adhesion properties of polymer concrete composition including a substantially non-aqueous slurry of (i) an aggregate component, (ii) a monomer binder component in an amount effective to bind the aggregate component, upon curing, into a polymer concrete, and (iii) a polymerization catalyst. The method involves adding a crosslinking-effective amount of a metal salt of an .alpha., .beta.-ethylenically unsaturated carboxylic acid to the polymer concrete.Type: GrantFiled: June 7, 1995Date of Patent: October 15, 1996Assignee: Sartomer Company, Inc.Inventors: C. Richard Costin, Michael A. Bailey, Walter R. Nagel
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Patent number: 5561205Abstract: A tetravalent organotin containing compound where the tin atom is attached via an alkyl group to a phenyl moiety with a polymerizable group thereon, is useful as a monomer. A polymer prepared from the monomer. A transesterification catalyst prepared from the polymer and a process for conducting a transesterification reaction using the transesterification catalyst.Type: GrantFiled: March 31, 1995Date of Patent: October 1, 1996Assignee: Rohm and Haas Co.Inventors: Oian Jiang, Christine McDade, Andrew W. Gross
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Patent number: 5554695Abstract: There are disclosed a styrenic copolymer which comprises at least one structural unit represented by the general formula (I) ##STR1## and a structural unit represented by the general formula (II) ##STR2## or a structural unit represented by the general formula (IX) ##STR3## wherein the symbols are each as previously defined in the specification, the structural unit (II) or (IX) being contained in an amount of 0.01 to 99.9 mol %; and a process for the production of the above copolymer.The above styrenic copolymer has a high degree of syndiotactic configuration in the stereoregularity of the main chain of the structural unit (I) as well as adhesivity and compatibility with a resin of a different type.Type: GrantFiled: May 4, 1995Date of Patent: September 10, 1996Assignee: Idemitsu Kosan Co. Ltd.Inventors: Shuji Machida, Toshinori Tazaki
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Patent number: 5548047Abstract: A process for producing a highly water absorptive polymer comprising the steps of subjecting a water-soluble ethylenically unsaturated monomer comprising as the main component acrylic acid and/or an alkali metal or ammonium salt thereof, and optionally containing a crosslinking agent to a water-in-oil type of reverse-phase polymerization in the presence of water, a water-soluble radical polymerization initiator, a dispersant and a hydrophobic hydrocarbon solvent to form a slurry of water-containing particles of a highly water absorptive polymer in the solvent, adding a polymerizable monomer to the slurry, and polymerizing the polymerizable monomer to obtain agglomerates of the particles of the highly water absorptive polymer.Type: GrantFiled: May 16, 1995Date of Patent: August 20, 1996Assignee: Mitsubishi Chemical CorporationInventors: Kiichi Ito, Shuhei Yada, Miho Oomori, Toshiko Nakamura
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Patent number: 5547612Abstract: Water soluble polymers are prepared from an allyloxybenzenesulfonic acid monomer, a methallyl sulfonic acid monomer, a copolymerizable nonionic monomer, and a copolymerizable olefinically unsaturated carboxylic acid monomer. The polymers are used to disperse particulate matter and to inhibit the formation and deposition of mineral scale in aqueous systems and are used in detergent compositions.Type: GrantFiled: February 17, 1995Date of Patent: August 20, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Anne-Marie B. Austin, Allen M. Carrier, Michael L. Standish
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Patent number: 5548049Abstract: Polymers consisting of (a) 1-50% weight of N-allyliminodiacetic acid and its salts; (b) 50-99% weight of one or several unsaturated, polymerisable carboxylic acids having the formula (I), in which R.sup.1 stands for hydrogen, C.sub.1-C.sub.4 alkyl or COOM, R.sup.2 stands for hydrogen or C.sub.1-C.sub.4 alkyl, R.sup.3 stands for hydrogen, C.sub.1-C.sub.4 alkyl or CH.sub.2 COOM and M stands for hydrogen, ammonium, an alkali metal or an alkaline earth metal; and (c) 0-40% by weight water soluble monomers copolymerisable with (a) and (b). These polymers preferably contain acrylic acid, methacrylic acid and maleic acid as unsaturated polymerisable carboxylic acids. Also disclosed are the use of these polymers as complexing agents, as peroxide stabilizers and builders in washing products, as dispersing agents and hardness stabilizers.Type: GrantFiled: December 29, 1994Date of Patent: August 20, 1996Assignee: Chemishe Fabrik Stockhausen GmbHInventors: Helmut Brehm, Kurt Dahmen, Richard Mertens
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Patent number: 5532323Abstract: An absorbent resin exhibiting a high absorption ratio, having only a small water-soluble component content, and have excellent gel stability to withstand the effect of aging is produced. The production of the absorbent resin comprises a step of polymerizing a water-soluble monoethylenically unsaturated monomer by using, in a proportion of 0.01-0.3 mol % based on the amount of the water-soluble monoethylenically unsaturated monomer, a cross-linking agent having at least one group of the following formula I: ##STR1## wherein R.sup.1 is an alkylene group of 2 to 4 carbon atoms interposed between two polymerizing unsaturated groups in the molecular unit thereof and then heat-treating the resin produced by the polymerization at a temperature in the range of from 160.degree. to 230.degree. C.Type: GrantFiled: March 4, 1993Date of Patent: July 2, 1996Assignee: Nippon Shokubai Co., Ltd.Inventors: Kazutaka Yano, Katsuhiro Kajikawa, Kinya Nagasuna, Yoshio Irie
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Patent number: 5525661Abstract: Paper surface sizing properties of aqueous solutions of high molecular weight (at least 100,000 Daltons weight average) styrene-maleate half ester polymers are improved by forming the maleate half ester using oxyalkylene-alkyl alcohol, preferably 2-(n-butoxy) ethyl alcohol.Type: GrantFiled: April 21, 1995Date of Patent: June 11, 1996Assignee: Monsanto CompanyInventor: Kang I. Lee
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Patent number: 5523367Abstract: A composition which comprises a water-polymer and a process for using the polymer to absorb a fluid are disclosed. The water-insoluble polymer comprises repeate units derived from: (a) an ampholytic monomer which is a polymerizable vinylic amine-containing monomer and an acid having an ethylenic moiety; (b) at least one olefinic comonomer; and optionally, (c) one crosslinking agent which has at least two polymerizable olefinic functionalities wherein the olefinic functionalities are suitable for crosslinking.Type: GrantFiled: January 23, 1995Date of Patent: June 4, 1996Assignee: Phillips Petroleum CompanyInventor: Iqbal Ahmed