From Metal Containing Monomer Patents (Class 526/240)
  • Patent number: 4857615
    Abstract: The present invention relates to a method of making elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The method comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: August 15, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: William R. Bronn, Spencer F. Silver, Eugene G. Joseph
  • Patent number: 4857610
    Abstract: The present invention relates to a process and an apparatus for the continuous production of polymers and copolymers of water-soluble monomers particularly arcylic acid and/or methacrylic acid, optionally with additional comonomers, by the polymerization of an aqueous monomer solution that is introduced into the trough that is formed by an endless conveyor belt. The trough-like shape of the conveyor belt changes continuously into an extended flat profile during the polymerization process; starting from the side edges and working towards the center of the trough formed by the conveyor belt, the resulting polymer gel strand is released continuously during the transition of the curved trough-like shape of the conveyor belt into the extended, flat form.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: August 15, 1989
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Miroslav Chmelir, Josef Pauen
  • Patent number: 4857618
    Abstract: The present invention relates to elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The polymers are made by a method which comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to proudce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: August 15, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Spencer F. Silver, William R. Bronn, Eugene G. Joseph
  • Patent number: 4837288
    Abstract: Intramolecular polymer complexes synthesized from acrylamide, sodium styrene sulfonate, and methacrylamidopropyltrimethylammonium chloride, having viscosity-polymer concentration relationships that are invarient with the addition of high levels of acid, base, or salt to the fresh water system. These complexes possess a "balance" between conventional polyelectrolyte and polyampholyte behavior.
    Type: Grant
    Filed: August 5, 1987
    Date of Patent: June 6, 1989
    Assignee: Exxon Research & Engineering Company
    Inventors: Dennis G. Peiffer, Robert D. Lundbeeg
  • Patent number: 4835231
    Abstract: Disintegration type, crosslinked acrylic resin particles having an average grain diameter of 0.01 to 250 .mu. and containing metal ester bond bearing crosslinks uniformly distributed within the particle bodies are provided in spherical form by the polymerization of 5 to 98% by weight of at least one metal ester bond bearing multifunctional polymerizable monomer and 95 to 2% by weight of at least one other polymerizable monomer. The instant resin particles are specifically useful as resinous filler in an antifouling paint and other compositions.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: May 30, 1989
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Naoki Yamamori, Kazunori Kanda
  • Patent number: 4833222
    Abstract: A process for the preparation of an absorbent polymeric composition is disclosed. The process involves the polymerization of an aqueous solution of carboxylic acid monomers in a neutralized or partially neutralized form in the presence of a dispersing agent which aids in the even dispersion of the crosslinking agent. The polymers prepared exhibit high absorptive capacities and low water-soluble polymer content.
    Type: Grant
    Filed: October 22, 1987
    Date of Patent: May 23, 1989
    Assignee: The Dow Chemical Company
    Inventors: Jonathan H. Siddall, Thomas C. Johnson
  • Patent number: 4833179
    Abstract: The present invention relates to a method for suspension polymerization of a pressure-sensitive acrylate copolymer bead having a glass transition temperature of 0.degree. C. or less. The method comprises making a monomer premix comprising an acrylic acid ester of non-tertiary alcohol, the alcohol having from 1 to 14 carbon atoms, with the average number of carbon atoms being about 4 to about 12, a polar monomer copolymerizable with the acrylic acid ester, a chain transfer agent, a free-radical initiator, and a modifier moiety selected from the group consisting of 2-polystyrylethyl methacrylate macromolecular monomers, reactive zinc salts and hydrophobic silicas. The premix is then combined with a water phase containing a sufficient amount of suspending agent to form a suspension. The suspension is concurrently agitated and polymerization of the polymer premix is permitted until polymer beads are formed. The polymer beads are then collected.
    Type: Grant
    Filed: October 2, 1987
    Date of Patent: May 23, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Chung I. Young, Rudyard M. Enanoza
  • Patent number: 4820742
    Abstract: A method and apparatus for continuously manufacturing water absorbing resin. A mixed monomer solution is stored in a storage vessel and a polymerization initiator stored in an initiator storage vessel. The monomer solution is fed by gravity or otherwise through a conduit to a lower position (below the liquid surface) of a reaction chamber of a reaction vessel at a rate of, for example, 4 gallons per minute. Simultaneously, the polymerization initiator is fed at a rate of, for example, 0.2 gallons per minute by gravity or otherwise through a conduit to an opposite side of the reaction chamber, again at a lower portion (below a continuously maintained liquid level) to begin polymerization. The reaction product forms from an upper surface of the reactant mixture (mixed monomer solution plus initiator) and travels upwardly through a truncated frustoconical cone shaped upper portion of the reaction chamber as a solid resin.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: April 11, 1989
    Assignee: American Colloid Company
    Inventors: William Alexander, Maynard Teppo
  • Patent number: 4808668
    Abstract: Novel cationic, water-soluble carboxylate polymers are provided, which have a high degree of esterification. A process for making the polymers is provided by which selected quaternary salts of epoxy alkyl amine compounds are used for high conversion to ester groups, which salts have a low degradation reactivity toward the epoxy group of the esterification compound. Such a quaternary salt is glycidyl trimethyl ammonium nitrate. Processes are provided for making such quaternary salts and for use of the novel polymers for separation of water from solids, such as water from sludges.
    Type: Grant
    Filed: October 23, 1986
    Date of Patent: February 28, 1989
    Assignee: Allied-Signal Inc.
    Inventors: John V. Carioti, Richard M. Jobbins
  • Patent number: 4795801
    Abstract: The invention relates to the use of chemical grafting to produce a stable liquid composition that is capable of hardening following an optional polymerization process. Under the invention, in order to produce a composition that is liquid, at least initially and prior to any polymerization, a polymerizable organic acid comprising at least two double bonds in resonance is combined in a solvent with an inorganic filler having at least one hydroxylated group with the help of a catalyst acting as a radical upon said organic acid. By adjusting the concentration of catalyst and using a polymerizable monomer solvent, the liquid composition may be hardened by polymerization after the initial grafting reaction. By ensuring that a portion of the organic acid retains free bonds that have not combined with filler, it is also possible to induce the composition to become chemically attached to a resin or to reinforcing fibers. The invention may be applied to the production of molded objects.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: January 3, 1989
    Inventors: Herve M. J. Farge, Jean M. L. Farge
  • Patent number: 4795692
    Abstract: Radiation-sensitive interpolymers comprising 10-90 mole % of a polymerized maleimide monomer are useful as resists having high sensitivity to E-beams or X-rays.
    Type: Grant
    Filed: February 2, 1987
    Date of Patent: January 3, 1989
    Assignee: Eastman Kodak Company
    Inventors: Charles C. Anderson, Kristine M. Kolterman, Sam R. Turner
  • Patent number: 4792593
    Abstract: A terpolymer having the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of C.sub.1 to C.sub.20 alkyl groups, C.sub.6 to C.sub.20 aryl groups and C.sub.6 to C.sub.30 alkylaryl groups; R.sub.2 is hydrogen or methyl group, n is about 1 to 60; y is about 2.0 to about 35.0 mole %, and x is about 65.00 to about 98.00 mole %, z is about 0.1 to about 3.0 mole % and n is about 1 to about 60 and M is a metal cation selected from the group consisting of Groups IA, IIA, IB and IIB of the Periodic Table of Elements, wherein said terpolymer has an intri1sic viscosity of about 1 top about 25, wherein said terpolymer is formed by a free radical solution polymerization in the absence of a surfactant or emulsifier and comprises the polymerization of an acrylamide monomer, a metal acrylate monomer and an alkyl poly(etheroxy) acrylate monomer in the presence of a free radical initiation at a temperature of at least 5.degree. C. for at least 0.5 hours.
    Type: Grant
    Filed: November 5, 1987
    Date of Patent: December 20, 1988
    Assignee: Exxon Research and Engineering Company
    Inventors: Donald N. Schulz, Enock Berluche, John J. Maurer, Jan Bock
  • Patent number: 4792343
    Abstract: A dispersing agent for particles in aqueous media comprises a copolymer formed from ethyleneically unsaturated monomers including a water-soluble monomer and a monomer carying a pendant group A.sub.m B.sub.n A.sub.p R in which B is ethyleneoxy and n is at least 2, m and p are each generally 0 and R is a hydrophobic group, generally a C.sub.12-18 alkyl group or alkaryl group. The polymers generally have molecular weights in the range 500-100,000. The dispersants are particularly useful for suspending hydrophobic particles in aqueous media, for example to produce coal slurries, or to suspend hydrophilic particles in aqueous media having high electrolyte concentrations, for example for producing paints and, particularly, drilling muds formed in sea water.
    Type: Grant
    Filed: August 7, 1986
    Date of Patent: December 20, 1988
    Assignee: Allied Colloids Limited
    Inventors: Malcolm Hawe, David Farrar
  • Patent number: 4780517
    Abstract: A water thickening terpolymer of polymerized units of (A) about 50 to 98 mole percent of acrylamide, (B) about 1.9 to 49.9 mole percent of an alkali metal salt or ammonium salt of acrylic acid, and (C) about 0.1 to 5 mole percent of a copolymerizable ionic surfactant containing (1) an acrylyl or methacrylyl group, (2) a pendant hydrophobic group of 6 to 24 carbon atoms, and (3) an ionic polar group.
    Type: Grant
    Filed: August 15, 1985
    Date of Patent: October 25, 1988
    Assignee: Chevron Research Company
    Inventor: Ta Yen Ching
  • Patent number: 4778865
    Abstract: Alpha-aminoethylene phosphonate betaines of the formula ##STR1## R.sup.1 is hydrogen or methyl; X is ##STR2## a is 0, 1, 2 or 3, with the condition that when X is ##STR3## that a be greater than 1; R.sup.2 and R.sup.3 are independently C.sub.1 -C.sub.6 alkyl, aryl, benzyl, or cyclohexyl;Y is hydrogen or hydroxyl;b is 0, 1, 2, or 3;Z is C.sub.1 -C.sub.6 alkyl, aryl, benzyl, cyclohexyl, or ##STR4## and M is hydrogen, metallic cation, or ammonium ion are disclosed as are homo- and copolymers thereof.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: October 18, 1988
    Assignee: National Starch and Chemical Corporation
    Inventors: John C. Leighton, Carmine P. Iovine
  • Patent number: 4769427
    Abstract: Finely divided, gel-like crosslinked polymers are prepared by a continuous method in which a monomer mixture which contains, per 100 parts by weight of acrylic acid or methacrylic acid, from 50 to 100 mol % of which in each case are neutralized, acrylamide, methacrylamide or N-vinylpyrrolidone, from 0 to 30 parts by weight of other water-soluble monoethylenically unsaturated monomers and from 0 to 20 parts by weight of water-insoluble monoethylenically unsaturated monomers is copolymerized with from 0.01 to 5 parts by weight of a crosslinking agent, in 20-65% strength by weight aqueous solution in the presence of an initiator at from 45.degree. to 95.degree. C.
    Type: Grant
    Filed: October 22, 1986
    Date of Patent: September 6, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernhard H. Nowakowsky, Juergen Beck, Heinrich Hartmann, Christos Vamvakaris
  • Patent number: 4759776
    Abstract: The present invention is a group of new polymers and treated, semi-permeable, polymeric membranes made from the new polymers, having improved selectivity for separating components of a gas mixture. The membrane is provided by fluorinating a polymer cast into membrane form, having the general structural formula: ##STR1## wherein R.sub.1 is H or a C.sub.1 -C.sub.2 alkyl group; R.sub.2 and R.sub.3 are independently linear or branched C.sub.1 -C.sub.6 alkyl groups; R.sub.4 is a linear or branched C.sub.1 -C.sub.12 alkyl or aryl group; X is a C.sub.1 -C.sub.3 alkyl group or phenyl; m is at least 100; and n is 0 or 1.
    Type: Grant
    Filed: December 8, 1986
    Date of Patent: July 26, 1988
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Michael Langsam, Ann C. L. Savoca
  • Patent number: 4743666
    Abstract: Water-soluble copolymers containing a statistical distribution of 1-86% by weight of structural units of the formula ##STR1## 9-80% by weight of units of the formula ##STR2## 5-90% by weight of units of the formula ##STR3## and up to a total of 30% by weight of one or more units of the formulae ##STR4## wherein R.sup.1 is alkyl having 1 to 4 carbon atoms;R.sup.2 and R.sup.5 independently of one another are each hydrogen or methyl;R.sup.3 and R.sup.4 independently of one another are each hydrogen, methyl or ethyl, or together R.sup.3 and R.sup.4 are trimethylene or pentamethylene;Y is a direct bond, phenylene or a moiety of the formula --CO--NH--C(CH.sub.3).sub.2 --CH.sub.2 --;X.sym. is H.sym. or a cation;and said copolymers are useful as dyestuff auxiliaries and leather retanning agents.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: May 10, 1988
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Klaus Kuhlein, Juliane Balzer, Walter Dursch, Hans-Jerg Kleiner
  • Patent number: 4743664
    Abstract: A less colored .alpha., .beta.-unsaturated carboxylic acid polymer having a relatively small molecular weigth and a sharp molecular weight distribution is produced by supplying an .alpha.,.beta.-unsaturated carboxylic acid monomer and a hydrogensulfite from one side of a reaction column and simultaneously supplying an oxygen-containing gas concurrently with the monomer to the reaction column. The polymer obtained is preferably used as a dispersant and an antiscaling agent.
    Type: Grant
    Filed: November 19, 1986
    Date of Patent: May 10, 1988
    Inventors: Tadashi Matui, Hidetaka Tobita
  • Patent number: 4737541
    Abstract: Thickened or gelled industrial formulations comprise, for example, an aqueous acid or base formulation thickened with a small amount of a water-soluble polymer comprising acrylamide, an ionic monomer and, optionally, a crosslinking monomer. The thickened formulations can be used as industrial or household cleaners, etc., and exhibit good viscosity stability and retention capability over time.
    Type: Grant
    Filed: August 12, 1986
    Date of Patent: April 12, 1988
    Assignee: The Dow Chemical Company
    Inventors: David L. Stavenger, James W. Sanner, Patricia L. Slaber
  • Patent number: 4736005
    Abstract: High molecular weight N,N-dimethylacrylamide copolymers and terpolymers were synthesized. These polymers offer outstanding advantages as injection water viscosifiers in enhanced oil recovery processes including chemical, miscible, and steam or in processes requiring profile improvement through adsorption and/or gelation. They are very valuable in applications where high salinity is a problem since they are relatively insensitive to metal salts (such as those containing polyvalent ions, such as Ca.sup.++ and Mg.sup.++.).
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: April 5, 1988
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Kenneth F. Castner
  • Patent number: 4732698
    Abstract: A water soluble polymer composition is disclosed. The polymer has repeat units characterized by the structural formulae: ##STR1## wherein R.sub.1 is H or lower alkyl (C.sub.1 -C.sub.3)b; R.sub.2 is OH, OM, or NH.sub.2 ; M is a water soluble cation; R.sub.3 is a hydroxy substituted alkyl or alkylene radical having from 1 to about 6 carbon atoms or a non-substituted alkyl or alkylene radical having from 1 to 6 carbon atoms; X is an anionic radical; Z is H or hydrogens or a water soluble cation or cations which together counterbalance the valence of X, and D is 0 or 1. The copolymer is effective in inhibiting the precipitation of certain scale forming salts, and also acts to inhibit corrosion of metal parts in contact with water systems.
    Type: Grant
    Filed: February 10, 1987
    Date of Patent: March 22, 1988
    Assignee: Betz Laboratories, Inc.
    Inventor: Fu Chen
  • Patent number: 4731146
    Abstract: A composition useful as an adhesion promoting primer activator for curable acrylic monomer formulations, particularly anaerobic curable formulations, comprises a solution in a volatile organic solvent of a Cu(II), Co(II), Mn(II), Mn(III), or Cr(III) salt of an acid phosphate acrylic monomer. The acid phosphate monomer may be one of the formula: ##STR1## where R.sup.1 is H or methyl, R.sup.2 is a divalent organic group having 2-40 carbon atoms and A is OH or CH.sub.2 .dbd.C(R.sup.1)C(.dbd.O)OR.sup.2 O.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: March 15, 1988
    Assignee: Loctite Corporation
    Inventor: Paul J. Clark
  • Patent number: 4725655
    Abstract: Copolymers which contain, as copolymerized monomer units, monoethylenically unsaturated mono- and dicarboxylic acids are prepared by a process in which(a) from 10 to 60% by weight of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, its salt and/or, if appropriate, its anhydride,(b) from 90 to 40% by weight of a monothylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms and/or its salt and(c) from 0 to 20% by weight of another, carboxyl-free monoethylenically unsaturated monomer which is copolymerizable with (a) and (b),the percentages being based on the sum of the monomers, are polymerized in the presence of from 0.5 to 5% by weight of a water-soluble free-radical-forming initiator in an aqueous medium at from 60.degree. to 150.degree. C.
    Type: Grant
    Filed: October 16, 1986
    Date of Patent: February 16, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Wolfgang Trieselt, Albert Hettche, Rolf Schneider, Hans-Juergen Raubenheimer
  • Patent number: 4713422
    Abstract: Polymers consisting of (a) vinyl compounds having a 2,2'-bipyridyl side group, (b) vinyl compounds having a radiation-sensitive side group and, if appropriate, (c) olefines which differ from (a) and (b), and their complexes with metal compounds, with the exception of alkali metal and alkaline earth metal compounds. They are suitable for coating substrates and for the preparation of photographic relief images. Complexes with cobalt salts are effective catalysts for the polymerization of acetylene.
    Type: Grant
    Filed: July 22, 1986
    Date of Patent: December 15, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Jurgen Kaschig, Jurgen Finter
  • Patent number: 4709759
    Abstract: This invention relates to a method for enhanced recovery of petroleum from a subterranean oil-bearing formation. More particularly, this invention relates to secondary or tertiary recovery of oil employing a polymer-thickened aqueous drive fluid. The polymeric viscosifier for the drive fluid is selected from a class of hydrophobically associating, water soluble polymers containing one or more water soluble monomers and a water insoluble monomer group. The water soluble groups are acrylamide and a salt of acrylic acid and the water insoluble group is a higher alkylacrylamide. These polymers, when dissolved in an aqueous brine solution, have the ability to substantially increase the viscosity of the aqueous solution. The control of displacement fluid mobility results in more uniform sweep efficiency and improved oil recovery.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: December 1, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Jan Bock, Salvatore J. Pace, Donald N. Schulz
  • Patent number: 4710555
    Abstract: Intramolecular polymer complexes synthesized from acrylamide, sodium styrene sulfonate, and methacrylamidopropyltrimethylammonium chloride, having viscosity-polymer concentration relationships that are invarient with the addition of high levels of acid, base, or salt to the fresh water system. These complexes possess a "balance" between conventional polyelectrolyte and polyampholyte behavior.
    Type: Grant
    Filed: February 5, 1986
    Date of Patent: December 1, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Dennis G. Peiffer, Robert D. Lundberg
  • Patent number: 4709091
    Abstract: A polymer or copolymer of maleic acid is produced by neutralizing (I) maleic acid in an aqueous medium with (III) an alkali metal hydroxide or ammonia at a molar ratio of (I) to (III) in the range of 100:0 to 100:90, polymerizing (I) with a polymerization initiator, adding (III) a further amount of the alkali metal hydroxide or ammonia at a molar ratio of (I) to (III) in the range of 100:100 to 100:130 in total through the previous addition and this addition and continuing the polymerization to the complete effect.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: November 24, 1987
    Assignee: Kao Corporation
    Inventors: Yasuhisha Fukumoto, Moboru Moriyama
  • Patent number: 4699964
    Abstract: An acrylic resin composition having excellent permanent antistatic properties, which comprises a copolymer of an acrylic monomer comprising predominantly methyl methacrylate with a specific sulfonate and optionally a specific alkylene oxide and/or acidic phosphate, and a method for the production thereof. The acrylic resin composition of the invention shows excellent antistatic properties without losing the excellent properties of methacrylic resin, such as excellent transparency, mechanical properties, heat resistance, etc., and is useful for various utilities, such as preparation of advertising display, lighting fixtures, covers, nameplate, and various decoratings.
    Type: Grant
    Filed: May 7, 1986
    Date of Patent: October 13, 1987
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuyuki Kato, Masahiro Yuyama, Masahiko Moritani, Mikio Futagami
  • Patent number: 4698404
    Abstract: Improved acrylic acid absorbency resins are made utilizing a chain transfer agent during the polymerization process.
    Type: Grant
    Filed: March 16, 1987
    Date of Patent: October 6, 1987
    Assignee: Nalco Chemical Company
    Inventors: Jeffrey R. Cramm, Kristy M. Bailey
  • Patent number: 4696983
    Abstract: Compositions of salts of water-soluble, carboxyl-containing polymers and surface active agents, deposited on polymerization reactor surfaces exposed to polymerization mixtures, substantially reduce or eliminate undesirable polymer build-up on reactor surfaces during aqueous polymerization of vinylidene monomers, even when the amount of carboxyl-containing polymers deposited on the reactor surfaces is very small.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: September 29, 1987
    Assignee: The B. F. Goodrich Company
    Inventor: Louis Cohen
  • Patent number: 4681686
    Abstract: New cotelomer compounds having the formula I ##STR1## and salts thereof wherein A is a random polymeric residue comprising at least one unit of formula II ##STR2## and at least one unit of formula III, different from a unit of formula II, ##STR3## and B is hydrogen or a residue A; wherein m and n are integers such that the sum of m+n is an integer of from 3 to 100, the ratio of n:m being from 99 to 1:1 to 99, provided that the resulting telomers are water-soluble and wherein m and/or n in a residue A may be the same as or different from m and/or n in a residue B; R is hydrogen, methyl or ethyl;R.sub.1 is a residue -OX, wherein X is hydrogen, an alkali- or alkaline earth metal, ammonium or an amine residue;R.sub.2 is hydrogen, methyl or a residue --CO.sub.2 R.sub.5, wherein R.sub.5 is hydrogen or a straight- or branched chain alkyl residue having 1 to 8 carbon atoms;R.sub.3 is hydrogen, a straight- or branched chain alkyl residue having 1 to 4 carbon atoms, hydroxymethyl or a residue --CO.sub.2 R.sub.
    Type: Grant
    Filed: July 10, 1985
    Date of Patent: July 21, 1987
    Inventors: Norman Richardson, Brian Holt, Barry Cook
  • Patent number: 4677174
    Abstract: Water absorbing, cross-linked acrylate resin copolymers are prepared by aqueous polymerization of (A) acrylic acid neutralized 70 to 100 mole percent for example with ammonia, and/or caustic alkali and/or an amine; with (B) styrene and/or methyl methacrylate in an amount of 1% to 25% based on the weight of acrylic acid or acrylate, and (C) acrylamide in a mole ratio of 70 to 100 mole percent (A) to 30:0 mole percent (C); and (D) a water miscible or a water soluble polyvinyl monomer in an amount of 0.001 to 0.3 weight percent based on the total weight of (A), (B), (C) and (D).
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: June 30, 1987
    Assignee: American Colloid Company
    Inventors: William Alexander, Barbara R. Regan, Mark Anderson
  • Patent number: 4668748
    Abstract: To protect photographic films from imaging by static discharges during manufacturing and customer use, copolymers of sulfonated monomers and primary amine monomers are coated on a film base and crosslinked with an aldehyde such as glutaraldehyde, giving a water-resistant, permanent, conductive (i.e., antistatic) layer.
    Type: Grant
    Filed: October 19, 1984
    Date of Patent: May 26, 1987
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: William M. Hardam, Frank L. Schadt, III, Arthur J. Taggi
  • Patent number: 4668735
    Abstract: A polymaleate having an average molecular weight of 300 to 5000 is obtained by polymerizing a monoalkali metal maleate or monoammonium maleate at 80.degree. to 180.degree. C. in the presence of a polymerization initiator in an aqueous solvent.
    Type: Grant
    Filed: January 21, 1986
    Date of Patent: May 26, 1987
    Assignee: Kao Corporation
    Inventors: Yasuhisa Fukumoto, Noboru Moriyama
  • Patent number: 4663408
    Abstract: The present invention relates to improved viscosification agents for an aqueous or brine solutions. Typically, the viscosification agents are tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide wherein said tetrapolymers have the formula: ##STR1## wherein w is about 1 to about 80 mole percent, more preferably about 5 to about 75 mole percent, and most preferably about 10 to about 70 mole percent; x is about 10 to about 90 mole percent, more preferably about 20 to about 80 mole percent, and most preferably about 30 to about 70 mole percent; and y is about 0.1 to about 10.0 mole percent, more preferably about 0.15 to about 5.0 mole percent; and most preferably about 0.2 to about 3.0 mole percent; z is about 1.0 to about 30.0 mole percent, more preferably about 2.0 to about 25.0 mole percent, and most preferably about 5.0 to about 20.
    Type: Grant
    Filed: December 30, 1985
    Date of Patent: May 5, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Donald N. Schulz, Enock Berluche, John J. Maurer, Jan Bock
  • Patent number: 4658003
    Abstract: The invention is (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof.In another aspect, the invention is a polymeric composition which comprises the reaction product of:(a) between about 0.5 and 100 percent by weight of a (hydroxy)-phosphinylalkyl acrylate, (hydroxy)-phosphinylalkyl methacrylate or an alkali metal, alkaline earth metal or ammonium salt thereof; and(b) between about 0 and 99.5 weight percent of a compound containing a polymerizable 1,2-ethylenically unsaturated moiety.
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: April 14, 1987
    Assignee: The Dow Chemical Company
    Inventors: Donald L. Schmidt, Gerald K. McEwen
  • Patent number: 4654395
    Abstract: An addition polymer of a water insoluble soft monomer, a water soluble anionic monomer and, optionally, a water soluble nonionic monomer and water insoluble hard monomer is neutralized to at least about 75%, and formed into a sheet. A laundry care additive, as a bleach, may be stored between a pair of opposed heat sealed sheets to provide a laundry care product adapted to be introduced into a laundry wash.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: March 31, 1987
    Assignee: S. C. Johnson & Son, Inc.
    Inventors: Gerald O. Schulz, Thomas D. Gueldenzopf
  • Patent number: 4654393
    Abstract: A process is disclosed for preparing a solid, water absorbing, cross-linked polyacrylate resin including combining potassium acrylate and a polyvinyl monomer, such as N,N-methylene bisacrylamide, with water in an amount of 55 to 80 combined weight percent of potassium acrylate and polyvinyl monomer based on the total weight of potassium acrylate, polyvinyl monomer and water to form a monomer mixture, and adding a polymerization initiator to the monomer mixture to initiate polymerization of the monomer mixture. The monomer mixture then is polymerized without external heating by utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form the cross-linked polyacrylate resin having a water content sufficiently low (i.e. 15% or less) to be powdered, such as by pulverization, without an intermediate drying step.
    Type: Grant
    Filed: May 6, 1985
    Date of Patent: March 31, 1987
    Assignee: American Colloid Company
    Inventors: Muneharu Mikita, Shozo Tanioku, Takayasu Touda
  • Patent number: 4649183
    Abstract: A water-soluble, charged, random copolymer of acrylamide and an alkali metal salt of an acrylamido-alkanoic acid such as alkali metal 3-acrylamido-3-methylbutanoate, having an average molecular weight of greater than about 50,000, has been found to maintain unusually stable and effective viscosities in the presence of salts such as NaCl and CaCl.sub.2 when added to water in minor amounts, thus making it a highly effective mobility control agent for secondary and tertiary oil recovery methods. Also within the scope of the invention are the acid form of the polymer, as well as terpolymers which additionally contain olefinically unsaturated monomers such as acrylic acid or sodium acrylate.
    Type: Grant
    Filed: December 10, 1985
    Date of Patent: March 10, 1987
    Assignee: University of Southern Mississippi
    Inventors: Charles L. McCormick, Kenneth P. Blackmon
  • Patent number: 4634651
    Abstract: This invention relates to a non-aqueous type resinous composition obtained by polymerizing a polymerizable composition containing at least monomer A represented by the general formula (I), ##STR1## (wherein R represents --H or --CH.sub.3, X representing --COOC.sub.n H.sub.2n+1 or --O--CO--C.sub.n H.sub.2n+1, and n representing an integer of 6-20) and monomer B represented by the general formula (II), ##STR2## (wherein R represents --H or --CH.sub.3, n representing an integer of 1-20, and M representing --H, Na, K, Mg, Mn, Ca, Li, Al or Co) in the presence of a polymerization initiator in an aliphatic hydrocarbon solvent.
    Type: Grant
    Filed: August 23, 1985
    Date of Patent: January 6, 1987
    Assignee: Ricoh Co., Ltd.
    Inventors: Makoto Okawara, Kazuo Tsubuko
  • Patent number: 4622373
    Abstract: Polymers of (1) from about 5% to about 50% by weight of 2-acrylamido-2-methylpropane sulfonic acid and (2) from about 95% to about 50% by weight of a second component, there being from 100% to about 80% by weight acrylic acid and from 0% to about 20% by weight of itaconic acid in the second component and having a weight average molecular weight of between about 50,000 to about 1,000,000 and which are at least water dispersible are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium ions and muds containing chloride ions such as seawater muds. An example is a copolymer of 10% by weight 2-acrylamido-2-methylpropane sulfonic acid and 90% by weight acrylic acid in its sodium salt form.
    Type: Grant
    Filed: May 10, 1984
    Date of Patent: November 11, 1986
    Assignee: Diamond Shamrock Chemicals Company
    Inventor: Dinshaw F. Bardoliwalla
  • Patent number: 4622370
    Abstract: Copolymers of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid and having a weight average molecular weight of between about 50,000 to about 1,000,000, preferably between about 100,000 to about 500,000, and which are at least water dispersible, are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium and muds containing chloride ions such as seawater muds. An example is a copolymer of 95% by weight acrylic acid and 5% by weight itaconic acid in its sodium salt form.
    Type: Grant
    Filed: May 1, 1984
    Date of Patent: November 11, 1986
    Assignee: Diamond Shamrock Chemicals Company
    Inventors: Dinshaw F. Bardoliwalla, Jose L. Villa
  • Patent number: 4618448
    Abstract: The instant invention is directed to a process for inhibiting corrosion and the formation and deposition of scale and iron oxide in aqueous systems, comprising adding to the system at least 0.1 ppm of a water-soluble polymer having an intrinsic viscosity of 0.05 to 2.5 dl/g, prepared from:(a) 35 to 90%, by weight, of an unsaturated carboxylic acid, or its salt;(b) 5 to 40%, by weight of an unsaturated sulfonic acid, or its salt; and(c) 5 to 40%, by weight, of an unsaturated, polyalkylene oxide compound, the total of (a), (b) and (c) being 100% weight of the polymer.
    Type: Grant
    Filed: September 4, 1985
    Date of Patent: October 21, 1986
    Assignee: Calgon Corporation
    Inventors: Charles Y. Cha, Richard G. Varsanik, Shih-Ruey T. Chen
  • Patent number: 4608424
    Abstract: A latex composition having utility in articles such as photographic elements is disclosed. The composition comprises loadable polymer particles having recurring units a, b and c wherein:component a is 10 to 100 weight percent of a tetrahydrofurfuryl monomer having the structure: ##STR1## in which R.sub.1 represents O or NH; andR.sub.2 represents H or lower alkyl of about 1 to 6 carbon atoms;component b is 0 to 20 weight percent of a hydrophilic monomer andcomponent c is 0 to 90 weight percent of a hydrophobic monomer.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: August 26, 1986
    Assignee: Eastman Kodak Company
    Inventors: James W. Brown, Tsang J. Chen, Michael A. Schen
  • Patent number: 4608425
    Abstract: The present invention relates to improved viscosification agents for a variety of aqueous solutions which comprise a family of intramolecular polymeric complexes (i.e., polyampholytes) which are copolymers of metal styrene sulfonate/methacrylamidoproplytrimethylammonium chloride (MAPTAC). The metal styrene sulfonate is an anionic monomer, while MAPTAC is cationically charged. These polyampholytes have approximately 1 to about 99 mole % of the anionic monomer and approximately 1 to about 99 mole % of the cationic moiety present within the macromolecular structure. These groups are not necessarily present in an equimolar charge ratio. The excess undissociated charge allows for facile dispensability or solubility of the polyampholytes into low ionic strength aqueous solutions.
    Type: Grant
    Filed: June 21, 1985
    Date of Patent: August 26, 1986
    Assignee: Exxon Research and Engineering Co.
    Inventors: Dennis G. Peiffer, Robert D. Lundberg
  • Patent number: 4605718
    Abstract: Water-soluble monomers and water-soluble polymers derived therefrom are disclosed. These materials can be used with other vinyl monomers to form water-soluble polymers which are reactive with cellulosic substrates to obtain drastically improved strength, particularly when applied in paper manufacture. The polymers contain at least two mole percent of a monomer represented by the chemical structure: ##STR1## wherein R is H, CH.sub.3, or C.sub.2 H.sub.5 ; andA is O, or N(R.sub.1); andB is CH.sub.2, CH.sub.2 CH.sub.2 O, ##STR2## and D is ##STR3## and wherein R.sub.1 is H, CH.sub.3, C.sub.2 H.sub.5, (CH.sub.2 CH.sub.2 O).sub.n H, or (B).sub.q D, and wherein q is from 1-6, except when B contains nitrogen in which case q is always one; and wherein R.sub.2 is H, CH.sub.3, C.sub.2 H.sub.5, or (CH.sub.2 CH.sub.2 O).sub.n H; and wherein R.sub.4 and R.sub.5 may be the same or different and are, for each individual occurrence, H, CH.sub.3, C.sub.2 H.sub.5 ; and wherein Z is from the group Cl, Br, I, NO.sub.3, SO.sub.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: August 12, 1986
    Assignee: Nalco Chemical Company
    Inventors: Roger H. Jansma, Karen R. Sandberg
  • Patent number: 4604414
    Abstract: An acrylic resin composition having excellent permanent antistatic properties, which comprises a copolymer of an acrylic monomer comprising predominantly methyl methacrylate with a specific sulfonate and optionally a specific alkylene oxide and/or acidic phosphate, and a method for the production thereof. The acrylic resin composition of the invention shows excellent antistatic properties without losing the excellent properties of methacrylic resin, such as excellent transparency, mechanical properties, heat resistance, etc., and is useful for various utilities, such as preparation of advertising displays, lighting fixtures, covers, nameplates, and various decorations.
    Type: Grant
    Filed: March 21, 1984
    Date of Patent: August 5, 1986
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuyuki Kato, Masahiro Yuyama, Masahiko Moritani, Mikio Futagami
  • Patent number: 4600521
    Abstract: An electron-beam reactive magnetic coating composition for use in magnetic recording media comprising a magnetic powder and a polymer resin as a binder therefor, the polymer resin containing vinyl chloride as a main component and having at least one hydrophilic group selected from the group of COOM, SO.sub.3 M, SO.sub.4 M, PO.sub.3 M.sub.2 and PO.sub.4 M.sub.2 (wherein M represents hydrogen, an alkali metal or ammonium) and not more than 10,000 double bond equivalents of an unsaturated acid ester group.
    Type: Grant
    Filed: October 4, 1985
    Date of Patent: July 15, 1986
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Eitaro Nakamura, Kotaro Hata, Makoto Yamamoto
  • Patent number: 4599390
    Abstract: A high molecular weight, water-soluble polymer, water-in-oil emulsions thereof and a flocculating process using same are disclosed. The polymer may be represented by the formula: ##STR1## wherein A represents a repeating unit derived from a hydrophobic vinyl monomer having a water-solubility of less than about 5 weight %; R.sub.1 and R.sub.3 are each hydrogen atom or a methyl group; R.sub.4 and R.sub.5 are each a hydrogen atom, a methyl group or an ethyl group; R.sub.2 represents a divalent hydrocarbon group having from 2 to 13 carbon atoms; X represents a monovalent cation; B represents a repeating unit derived from an ethylenically-unsaturated carboxylic acid or a salt thereof; m is about 0.1-10 mole %, n is about 1-40 mole %, p is about 20-98.9 mole %, and q is about 0-40 mole % with the proviso that m+n+p+q=100 mole % and r is a large positive integer.
    Type: Grant
    Filed: September 18, 1985
    Date of Patent: July 8, 1986
    Assignee: Union Carbide Corporation
    Inventors: You-Ling Fan, George L. Brode, Meyer R. Rosen