From Metal Containing Monomer Patents (Class 526/240)
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Patent number: 5510436Abstract: The water-soluble copolymer comprises 5-90% by weight of groups of the formula ##STR1## in which R.sup.1 is hydrogen or methyl, R.sup.2 is C.sub.2 -C.sub.10 -alkylene, and Me is ammonium or an alkali metal, 5-90% by weight of groups of the formula--CH.dbd.CH--CH.sub.2 --N.sup.+ R.sup.3 R.sup.4 --CH.sub.2 --CH.dbd.CH-- X.sup.- IIin which X is a halogen, R.sup.3 and R.sup.4, independently of one another, are C.sub.1 -C.sub.6 -alkyl, 0-60% by weight of groups of the formula ##STR2## in which R.sup.5 and R.sup.6 together are a propylene group which with inclusion of the radical ##STR3## forms a pyrrolidone radical, and 0-30% by weight of groups of the formula--CHR.sup.7 --CHR.sup.8 -- IVin which R.sup.7 is hydrogen or methyl and R.sup.8 is CONH.sub.2, CON(CH.sub.3).sub.2, cyano, SO.sub.3 H, SO.sub.3 Me, C.sub.6 H.sub.4 SO.sub.3 H, C.sub.6 H.sub.4 SO.sub.3 Me, CH.sub.2 SO.sub.3 H, CH.sub.2 SO.sub.3 Me, COOH, COOMe, or carboxy-C.sub.1 -C.sub.Type: GrantFiled: June 15, 1994Date of Patent: April 23, 1996Assignee: Hoechst AktiengesellschaftInventors: Martin Hille, Heinz Wittkus, Jurgen Tonhauser, Fritz Engelhardt, Ulrich Riegel
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Patent number: 5506319Abstract: Disclosed are: a vinyl-substituted benzylorganotin compound represented by the following general formula A: ##STR1## wherein R.sup.1 R.sup.2 C.dbd.CR.sup.3 --, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are each a group bonded to the benzene ring and R.sup.1 to R.sup.7 are each one of a hydrogen atom and a hydrocarbon group having 1 to 30 carbon atoms which is one of aliphatic, alicyclic and aromatic hydrocarbon groups, R.sup.8 to R.sup.10 are each a hydrocarbon group having 1 to 30 carbon atoms which is one of aliphatic, alicyclic and aromatic hydrocarbon groups and R.sup.1 to R.sup.Type: GrantFiled: March 2, 1994Date of Patent: April 9, 1996Assignee: Bridgestone CorporationInventor: Toshiki Takizawa
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Patent number: 5504162Abstract: Salts of copolymers of ethylenically unsaturated carboxylic acids and ethylenically unsaturated fatty acid derivatives.Type: GrantFiled: January 4, 1994Date of Patent: April 2, 1996Assignee: Hoechst AktiengesellschaftInventors: Herbert Friedrich, Bernhard Mees, Richard Gruber
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Patent number: 5504160Abstract: There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance, said rubbery polymer being comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40% 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) acrylonitrile, (d) styrene, (e) a half ester maleate soap, and (f) a crosslinking agent.Type: GrantFiled: May 12, 1995Date of Patent: April 2, 1996Assignee: The Goodyear Tire & Rubber CompanyInventors: Hung D. Ngoc, Mariano Salazar
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Patent number: 5472993Abstract: An anti-fouling paint using self-polishing copolymer which contains n-[(N-isothiazolonyl)-alkyl] acrylate as one of the monomers has improved anti-fouling property and can reduce environmental hazard by reduction of the leaching amount of biocide like organotin and of additional biocide like copper compound. The paint can control the rate of dissolution and prolong the effectiveness of the paint.Type: GrantFiled: December 30, 1994Date of Patent: December 5, 1995Assignee: Korea Chemical Co., Ltd.Inventors: Bum S. Kim, Chang K. Seo, Chang J. You
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Patent number: 5464916Abstract: The invention relates to pressure-sensitive adhesive (PSA) structured bead, which has a distinct morphology, which is comprised of a copolymer which is characterized as aa two-phase system wherein more rigid, thermoplastic segments (hydrophilic segments formed from the polymerization of water soluble monomer in the water-in-oil emulsion particles) provide discrete reinforcing micro-domains within a predominating continuous matrix formed by rubbery, viscoelastic polymer segments (formed from the polymerization of the ester and the polar monomer). The invention also relates to a method of making the beads via a polymerization of a water-in-oil emulsion in a water suspension.Type: GrantFiled: December 15, 1994Date of Patent: November 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Chung I. Young, Ying-Yuh Lu
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Patent number: 5463005Abstract: Novel perfluorinated sulfonyl monomers and polymers and membranes made therefrom are provided. The fluorocarbon monomers have the general formula: ##STR1## wherein X is CH or N, I is H, K, Na, or a Group I or II metal, R.sub.f is one or more fluorocarbon group, including fluorocarbon ethers and/or sulfonyl groups and/or perfluoro-non-oxy acid groups, R.sub.f, is C.sub.n F.sub.2n+1 (n=0,1,2, . . .), Y is C.sub.n F.sub.2n+1 (n=0,1,2, . . .) and m is 0 or 1. The monomers are made from the non-oxy superacid groups ##STR2## Copolymers of the above monomers with other monomeric material such as tetrafluoroethylene are also provided. These copolymers may then be cast into ionomer membranes and other structures for use in electrochemical processing.Type: GrantFiled: August 11, 1993Date of Patent: October 31, 1995Assignee: Gas Research InstituteInventor: Darryl D. Desmarteau
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Patent number: 5462993Abstract: There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance, said rubbery polymer being comprised of repeat units which are comprised of (a) butyl acrylate, or optionally a mixture of butyl acrylate and 2-ethylhexyl acrylate containing up to about 40% 2-ethylhexyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate, and ethyl acrylate, (c) acrylonitrile, (d) styrene, (e) a half ester maleate soap, and (f) a crosslinking agent.Type: GrantFiled: May 15, 1995Date of Patent: October 31, 1995Assignee: The Goodyear Tire & Rubber CompanyInventors: Hung D. Ngoc, Mariano Salazar
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Patent number: 5457172Abstract: These compounds are denoted by the following formula (I): ##STR1## in which: Z denotes H or a linear or branched alkyl radical,X denotes O or S,each of A and B independently denotes an alkylene radical, it being possible for this radical to be substituted,R denotes H or an alkali metal, or else a linear or branched alkyl radical,x has the value of 0 or 1, andy has the value of 0, 1 or 2,the radical A not existing if x and y are both equal to 0, X being incapable of denoting O when R=alkyl and when R=H with x=y=0, and B being incapable of denoting optionally substituted methylene when X=S, x=y=0 and R=alkyl.According to the invention, different simple and efficient processes are proposed for preparing these new compounds, which can be applied to the preparation of new polymers and copolymers.Type: GrantFiled: February 17, 1993Date of Patent: October 10, 1995Assignee: Elf Atochem S.A.Inventors: Michele Curci, Jean-Luc Mieloszynski, Daniel Paquer
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Patent number: 5451618Abstract: Triorganotin toxicants are disclosed that are made of mixed saturated and unsaturated four-carbon chains with double bonds at C-1 and C-3. Incorporation of these compounds into random 50:50 copolymers of methacrylic acid and methylmethacrylate produces copolymer compositions that may be used as antifouling coatings for ship hulls. Methods for manufacturing the triorganotin toxicants and the copolymer compositions are also disclosed.Type: GrantFiled: December 30, 1993Date of Patent: September 19, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Carol A. Dooley, Elek Lindner
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Patent number: 5449725Abstract: This invention presents a series of polyfunctional polymers useful as deinking agents. The polymers, which generally have molecular weights in the 2,000-100,000 range, can be used to effectively separate and remove ink in a variety of deinking processes, including flotation, wash, and mechanical, resulting in fibers of superior brightness.Type: GrantFiled: November 27, 1991Date of Patent: September 12, 1995Assignee: Huntsman CorporationInventors: Ratana Kanluen, Brigitte H. Licht
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Patent number: 5439993Abstract: A process for producing a highly water absorptive polymer, including the step of polymerizing an acrylic monomer including as the main component acrylic acid and/or an alkali metal salt thereof in the presence of a salt of a metal selected from the,group consisting of Fe(II), Fe(III), Cu(II), Mn(II), VO(II), Co(II) and Ni(II).Type: GrantFiled: March 31, 1994Date of Patent: August 8, 1995Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Kiichi Ito, Shinji Tsunoi, Tetsuya Yamamoto
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Patent number: 5439997Abstract: Carboxylic polymers useful in detergent compositions contain keto structural units incorporated into the polymer backbone. The units may be introduced by means of the compound 2,2'-diphenyl-4-methylene-1,3-dioxolane. The polymers show better biodegradability than the acrylic and acrylic/maleic polymers commonly used in detergent compositions, while the detergency building (calcium binding) is comparable or better.Type: GrantFiled: April 7, 1993Date of Patent: August 8, 1995Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Stephen G. Hales, Ezat Khoshdel, Robert Polywka
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Patent number: 5436292Abstract: This invention relates to processes for preparing aqueous polymer emulsions useful as thickening agents in aqueous compositions in which plating and/or grit formation is reduced in said processes. This invention also relates to methods for reducing plating and/or grit formation in processes for preparing aqueous polymer emulsions useful as thickening agents in aqueous compositions. This invention further relates to polymers which are soluble in, or swelled by, an aqueous alkaline medium to provide thickeners for use in aqueous coating compositions, especially latex paints.Type: GrantFiled: November 18, 1994Date of Patent: July 25, 1995Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Richard D. Jenkins, David R. Bassett, Ralph A. Sterlen, Jr., Wendy B. Daniels
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Patent number: 5432239Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers obtained by polymerization and/or copolymerization of acrylic and/or vinyl monomers containing acid groups, and in which the active acid sites are completely or partially neutralized to a degree of 40% to 60%, including terminals, using a neutralizing agent containing magnesium ions, and to a degree of up to 60% using a neutralizing agent containing monovalent ions is disclosed.A procedure for grinding in an aqueous suspension using said agent, as well as the aqueous suspensions produced using said procedure and their applications to the fields of weight fillers, paper coating, paints, and plastics is also disclosed.Type: GrantFiled: November 10, 1992Date of Patent: July 11, 1995Assignee: Coatex S.A.Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet
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Patent number: 5432238Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers having a specific viscosity of between 0.3 and 0.8 and obtained by treatment, using one or several solvents, of a polymer and/or copolymer resulting from polymerization and/or copolymerization of acrylic and/or vinyl monomers comprising acid groups whose active acid sites are partially or completely neutralized to a degree of neutralization of 40 to 60%, including terminals, of the active acid sites using a neutralizing agent containing magnesium ions, and a degree of neutralization reaching 60% using a neutralizing agent containing sodium ions is disclosed.Type: GrantFiled: November 10, 1992Date of Patent: July 11, 1995Assignee: Coatex S.A.Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet
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Patent number: 5430114Abstract: The present invention provide water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.Type: GrantFiled: November 29, 1994Date of Patent: July 4, 1995Assignee: Rohm and Haas CompanyInventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
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Patent number: 5430116Abstract: Polymeric and oligomeric bile acids are described which can be prepared by polymerization of monomeric bile acids of the formula IG--X--A (I)in which G, X and A have the given meanings or by copolymerization with a monomer of the formula IV ##STR1## in which R.sup.9 and R.sup.10 have the given meanings, or by copolymerization with N-vinylpyrrolidone or its derivatives,and/or by copolymerization with ethylenically unsaturated dicarboxylic anhydrides and ethylenically unsaturated dicarboxylic acids each having 2 to 6 carbon atoms; their esters or half esters, alkyl esters having 1-6 carbon atoms, cycloalkyl esters having 5 to 8 carbon atoms, benzyl esters or phenyl esters being understood as esters. They can be used as pharmaceuticals, foodstuff additives, formulation auxiliaries and detergents.Type: GrantFiled: December 17, 1992Date of Patent: July 4, 1995Assignee: Hoechst AktiengesellschaftInventors: Werner Kramer, Stefan Mullner, Matthias Gutweiler, Matthias Kroggel
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Patent number: 5424381Abstract: A polymer, including alkyl substituted poly(2,2 '-bipyridine-5,5 '-diyl) having chemical formulae as follows: ##STR1## wherein R and R' are H or an alkyl group having not less than 1 carbon atom, except that at least one of R and R' is an alkyl group having not less than 3 carbons, `n` is a degree of polymerization and is not less than 10. The polymer may be used as a material for a device selected from the group consisting of a battery, an electrochromic device, an electronic device, a n-type conductor and an electroluminescence device, and may be used as polymer ligand to a metal element.Type: GrantFiled: September 29, 1993Date of Patent: June 13, 1995Assignee: Tokyo Institute of TechnologyInventors: Takakazu Yamamoto, Tsukasa Maruyama
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Patent number: 5424058Abstract: Stabilizer compositions including specific mixed partial salts of a lower alkyl vinyl ether-maleic acid copolymer, the partial salts containing from about 15% to about 40% free acid, are disclosed. The cationic salt function is from about 0.1% to about 9.9% zinc or strontium cations, and from about 20% to about 67% calcium cations of the total initial carboxyl groups are reacted. Also disclosed are denture stabilizing compositions including a safe and adhesively effective amount of two or more denture adhesive components where one of the denture adhesive components is the above mixed partial salt.Type: GrantFiled: April 15, 1994Date of Patent: June 13, 1995Assignee: The Proctor & Gamble CompanyInventors: Jayanth Rajaiah, Bao K. Ha, Abel Saud, Bruce J. MacKay
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Patent number: 5407996Abstract: A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 independently represent a hydrogen atom or methyl;X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, C.sub.1 -C.sub.6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group --CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R.sup.Type: GrantFiled: February 17, 1994Date of Patent: April 18, 1995Assignee: Showa Denko K.K.Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Yoshikazu Hosoda
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Patent number: 5408019Abstract: The invention relates to a cross-linked, water-absorbent polymer obtainable by the polymerization of a mixture consisting of a) 60-99%-wt. unsaturated, polymerizable monomers with acid groups which are neutralized to the extent of at least 30 mol-%, b) 0-37%-wt. monomers copolymerizable with a), c) 0.1-3.0%-wt. of a cross-linking agent and d) 0-10%-wt. of a water-soluble polymer, in which polymerization is conducted with a redox catalyst system containing formamidine sulfinic acid as reducing agent. The polymer is distinguished by a retention of greater than or equal to 28 g 0.9% aqueous NaCl-solution per 1 g of polymer, an absorption of greater than or equal to 26 g 0.9% aqueous NaCl-solution per 1 g of polymer at a load of 20 g/cm.sup.2 and a residual monomer content of less than 700 ppm, and preferably less than 500 ppm. The invention also relates to the use of this polymer in the production of hygiene articles.Type: GrantFiled: February 1, 1994Date of Patent: April 18, 1995Assignee: Chemische Fabrik Stockhausen GmbHInventors: Richard Mertens, Kurt Dahmen, Helmut Brehm
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Patent number: 5395905Abstract: The present invention provides water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.Type: GrantFiled: January 12, 1993Date of Patent: March 7, 1995Assignee: Rohm and Haas CompanyInventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
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Patent number: 5391666Abstract: A shading and light-responsive plate or film is composed or a transparent polymer containing a novel phthalic acid derivative metal salt and further near infrared ray shading plate or film is composed of a transparent polymer containing the aforesaid phthalic acid derivative copper salt or lead salt and a near infrared absorbing coloring material formed from a thioamide derivative or thiourea derivative.Type: GrantFiled: August 26, 1993Date of Patent: February 21, 1995Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Tomoaki Nagai, Hiroshi Fukui, Miyuki Yokoyama, Akio Sekine
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Patent number: 5385996Abstract: A process for the production of polymers by free radical polymerization, characterized in that there is added to the polymerization system one or more compounds of the general formula (A). ##STR1## where R.sup.1 is hydrogen or a group capable activating the vinylic carbon towards free radical addition;Y is OR.sup.2 or CH.sub.2 X(R.sup.2).sub.nwhere R.sup.2 is an optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, or optionally substituted saturated, unsaturated or aromatic, aromatic carbocyclic or heterocyclic ring;X is an element other than carbon selected from Groups IV, V, VI or VII of the Periodic Table or a group consisting of an element selected from Groups IV, V, or VI to which is attached one or more oxygen atoms; andn is a number from 0 to 3, such that the valency of the group X is satisfied and, when n is greater than 1, the groups represented by R.sup.2 may be identical or different.Type: GrantFiled: June 7, 1993Date of Patent: January 31, 1995Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Ezio Rizzardo, Gordon F. Meijs, San H. Thang
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Patent number: 5376731Abstract: Phosphonic (co) telomers of the type described in U.S. Pat. Nos. 4,046,707 and 4,681,686 and European Patent Application 360746 may be produced by an aqueous process comprising (a) reacting hypophosphorous acid with a carbonyl compound which is preferably an aldehyde, a ketone or an imine, (b) reacting the product of (a) with an olefin or olefins in the presence of a suitable initiator especially a free radical initiator, and (c) converting the product obtained from (b) to a phosphonic (co) telomer, e.g., by reaction with hypochlorite. The (co) telomer products are useful as scale inhibitors in aqueous systems.Type: GrantFiled: May 22, 1992Date of Patent: December 27, 1994Assignee: FMC Corporation (UK) LimitedInventors: Elizabeth A. Kerr, Jan Rideout
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Patent number: 5371159Abstract: An improved solution polymerization process is provided wherein vinyl monomers are polymerized in the presence of at least one reactive modifier which is a substituted alpha-olefin that incorporates at least three ether groups, is hydrophilic, and has a molecular weight of at least about 200. The modified vinyl polymers so produced are characterized by various improved physical properties including, in particular, electrical characteristics such as antistatic capacity.Type: GrantFiled: February 2, 1993Date of Patent: December 6, 1994Assignee: Asahi Denka Kogyo K.K.Inventors: Masahide Tsuzuki, Kaoru Komiya
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Patent number: 5369198Abstract: Copolymers which are composed essentially of the structural elements ##STR1## and, if necessary, ##STR2## The copolymers can be employed as dispersing agents for inorganic or organic substances, especially as a plasticiser for hydraulic binders.Type: GrantFiled: February 1, 1994Date of Patent: November 29, 1994Assignees: Chemie Linz Gesellschaft m.b.H, Holderchem Holding AGInventors: Gerhard Albrecht, Hubert Leitner, Rudolf Lindenberger, Richard Siedl, Christian Werenka, Willi Suter
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Patent number: 5369199Abstract: A shading and light-responsive plate or film is composed of a transparent polymer containing a novel phthalic acid derivative metal salt and further a near infrared ray shading plate or film is composed of a transparent polymer containing the aforesaid phthalic acid derivative copper salt or lead salt and a near infrared absorbing coloring material formed from a thioamide derivative or thiourea derivative.Type: GrantFiled: August 2, 1991Date of Patent: November 29, 1994Assignee: Jujo Paper Co., Ltd.Inventors: Toshimi Satake, Tomoaki Nagai, Hiroshi Fukui, Miyuki Yokoyama, Akio Sekine
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Patent number: 5362829Abstract: Cement dispersion agents composed of water-soluble vinyl copolymers obtained by aqueous solution radical polymerization of five specified kinds of monomers at a ratio within a specified range can provide improved fluidity to high-strength hardened concrete and mortar with extremely low water-to-cement ratio.Type: GrantFiled: September 17, 1993Date of Patent: November 8, 1994Assignee: Takemoto Yushi Kabushiki KaishaInventors: Mitsuo Kinoshita, Yoshimasa Miura, Takeshi Arashima
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Patent number: 5360881Abstract: Diallyloxyacetic acid and its basic addition salts, their preparation process and their application as cross-linking agents.Diallyloxyacetic acid and its basic addition salts, preparation process and application as cross-linking agents.Type: GrantFiled: May 24, 1993Date of Patent: November 1, 1994Assignee: Societe Francaise HoechstInventors: Paul Mallo, Christian Sidot, Alain Blanc, Yani Christidis
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Patent number: 5350820Abstract: A conjugated diene sulfonation product represented by the formula (I): ##STR1## wherein R.sup.1 to R.sup.6, which may be the same or different represent hydrogen atoms, alkyl groups having 1 to 8 carbon atoms, aryl groups having 6 to 20 carbon atoms or --SO.sub.3 X groups (X represents a hydrogen atom, a metal atom, an ammonium group or a quaternary ammonium group), at least one of said R.sup.1 to R.sup.6 being the --SO.sub.3 X group, a polymer of the conjugated diene sulfonation product or a copolymer of the conjugated diene sulfonation product with a monomer copolymerizable therewith. The sulfonation product, the polymer and the copolymer are useful as a dispersing agent for preparing a solid fuel dispersion, a cement dispersion, a dye and/or pigment dispersion or a metal oxide dispersion or as a water-treating agent, a fiber-treating agent, a plating bath additive and an excavation-muddy water-viscosity-adjusting agent.Type: GrantFiled: October 14, 1992Date of Patent: September 27, 1994Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Hisao Ono, Katsumi Ito, Tatuo Uekawa, Katsuhiro Ishikawa
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Patent number: 5346974Abstract: This invention provides polyether polycarboxylate compositions selected from the group consisting of polyether polycarboxylates which may be prepared by oxidizing copolymers of furan and maleic anhydride, and other polyether polycarboxylate compositions prepared by oxidizing novel, intermediate polymers of furan, maleic anhydride, and at least one copolymerizable comonomer, selected from the group consisting of furan, alkenyl alkyl ethers, alkyl acrylates, alkenyl carboxyalkyl ethers, vinyl esters of carboxylic acids, unsaturated carboxylic acids, unsaturated dicarboxylic acids and their anhydrides and esters, and olefins. This invention also provides novel, unoxidized terpolymer intermediates comprising furan, maleic anhydride, and at least one copolymerizable comonomer, other than furan and maleic anhydride, selected from the above group, as well as a process for oxidizing these polymers and the furan and maleic anhydride copolymers.Type: GrantFiled: September 17, 1992Date of Patent: September 13, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: Carmine P. Iovine, Rama S. Chandran, John C. Leighton
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Patent number: 5338815Abstract: A fine particulate crosslinked type N-vinylcarboxylic acid amide resin having an average particle size of 10 .mu.m or less comprising backbone chains of a homopolymer or copolymer comprising repeating units (A) or (A) and (B) of the formulae: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each independently represent a hydrogen atom or methyl group; X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, a C.sub.1 -C.sub.Type: GrantFiled: November 30, 1993Date of Patent: August 16, 1994Assignee: Showa Denko K.K.Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Tetsuhiko Yamaguchi
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Patent number: 5338810Abstract: A method for the production of an acrylate by the neutralization reaction of acrylic acid and a basic substance, comprising sequentially (A) a step of supplying acrylic acid and said basic substance to water thereby subjecting them to a neutralization reaction while constantly retaining the neutralization ratio of acrylic acid within the neutralization reaction system in the range of 75 to 100 mol %, (B) a step of adjusting the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.1 to 110 mol % by supplying said basic substance to said neutralization reaction system, (C) a step of retaining the neutralization ratio of acrylic acid within said neutralization reaction system in the range of 100.Type: GrantFiled: March 8, 1993Date of Patent: August 16, 1994Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Tadao Shimomura, Yoshio Irie, Hitoshi Takahashi, Katsuhiro Kajikawa, Jyunichi Saga, Teruaki Fujiwara, Takumi Hatsuda
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Patent number: 5317053Abstract: A method for producing a high solids aqueous slurry of particulate calcium carbonate having highly stable aging characteristics, comprising dispersing in water at at least 70% by weight solids, a finely divided particulate calcium carbonate, utilizing as a dispersing agent from 20 to 34 lbs/ton of dry mineral (expressed as 40% actives), of a copolymer of acrylic acid and a sulfonated vinyl monomer, which is converted to the salt form by from about 30 to 50% of its carboxylic acid sites being neutralized with a polyvalent cation, and substantially the balance of said carboxylic sites being neutralized with a monovalent cation.Type: GrantFiled: July 31, 1992Date of Patent: May 31, 1994Assignee: ECC International Inc.Inventors: Alan J. Brown, Michael S. Darsillo, O. Wayne Bentley, Jr.
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Patent number: 5304616Abstract: Disclosed are stabilizer compositions comprising specific mixed partial salts of a lower alkyl vinyl ether-maleic acid copolymer wherein said partial salts containing from about 15% to about 40% free acid, and as the cationic salt function:(a) from about 0.1% to about 80% strontium cations; and(b) from about 0.1% to about 65% zinc cationsof the total initial carboxyl groups reacted. Also disclosed are denture stabilizing compositions comprising these mixed partial salts, as well as denture stabilizing compositions comprising a safe and adhesively effective amount of two or more denture adhesive components wherein one of said denture adhesive components is the mixed partial salt(s) of the present invention.Type: GrantFiled: October 22, 1992Date of Patent: April 19, 1994Assignee: The Procter & Gamble CompanyInventors: Jayanth Rajaiah, Abel Saud, Bruce J. MacKay
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Patent number: 5302677Abstract: The invention relates to alkenylaminoalkane-1,1-diphosphonic acid derivatives of the formula I ##STR1## in which R.sup.1 to R.sup.5, a, b, and Z have the meaning given in the description and to processes for their preparation. The invention furthermore relates to copolymers comprising 0.1-50 mol %, preferably 1-15 mol %, of at least one alkenylaminoalkane-1,1-diphosphonate unit of the formula I and 99.9-50 mol %, preferably 99-85 mol %, of at least one carboxylic acid unit of the formula IIR.sup.6 R.sup.7 C=CR.sup.8 Y (II)in which R.sup.6, R.sup.7, R.sup.8 and Y have the meaning given in the description and to processes for their preparation. These copolymers are used as scale inhibitors, as alkaline earth metal and heavy metal complexing agents and/or sequestering agents and as builders or co-builders in detergents.Type: GrantFiled: March 26, 1993Date of Patent: April 12, 1994Assignee: Hoechst AktiengesellschaftInventors: Matthias Krull, Christoph Naumann, Herrmann Hoffmann
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Patent number: 5300606Abstract: A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 independently represent a hydrogen atom or methyl;X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, C.sub.1 -C.sub.6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group --CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R.sup.Type: GrantFiled: March 11, 1993Date of Patent: April 5, 1994Assignee: Showa Denko K.K.Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Yoshikazu Hosoda
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Patent number: 5298569Abstract: A bioactive substance control-releasing resinous composition comprising a resin having main chain and side chains, at least one side chain bearing at the end portion thereof an organic acid moiety having a biological activity, through a metal ester bonding. The resin is hydrolyzed in an ionic atmosphere at a controlled rate to generate a bioactive substance as well as metal ions and is useful in various fields and especially as a resinous vehicle for a coating composition.Type: GrantFiled: January 7, 1993Date of Patent: March 29, 1994Assignee: Nippon Paint Co.Inventors: Naoki Yamamori, Hiroharu Ohsugi, Yoshio Eguchi, Junji Yokoi
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Patent number: 5294689Abstract: The present invention provides an aqueous process for preparing water-soluble addition copolymers of containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof, and (b) from about 5 to about 97 percent by weight of one or more monomers C.sub.4 -C.sub.6 monoethylenically unsaturated dicarboxylic acids and the alkali metal and ammonium salts thereof. These copolymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.Type: GrantFiled: January 12, 1993Date of Patent: March 15, 1994Assignee: Rohm and Haas CompanyInventors: Thomas F. McCallum, III, Barry Weinstein
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Patent number: 5280079Abstract: A water absorbent water insoluble polymeric element, such as a fibre, film, coating, bonding layer or foam, is made by forming a substantially linear polymer by polymerisation of water soluble ethylenically unsaturated monomer blends comprising carboxylic and hydroxylic monomers and then reacting the carboxylic and hydroxylic monomers in the linear polymer to form internal cross links within the polymer.Type: GrantFiled: May 18, 1992Date of Patent: January 18, 1994Assignee: Allied Colloids LimitedInventors: Adrian S. Allen, David Farrar, Peter Flesher
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Patent number: 5278267Abstract: Certain ethylenically unsaturated polymerizable monomers having a reactive carboxy group are useful for preparing homo- and copolymers for a variety of uses, including diagnostic assays. The polymers can be supplied as latex particles in aqueous compositions. The monomers are represented by the structure: ##STR1## wherein: R is hydrogen, halo or alkyl of 1 to 3 carbon atoms,M is hydrogen, an alkali metal ion or an ammonium ion, andL is a linking group having from 8 to 50 atoms in its linking chain, and comprises two or more divalent hydrocarbon groups connected or terminated with one or more nitrogen, oxygen or sulfur atoms, or with one or more groups containing such atoms in the linking chains, provided L has at least one arylene which is not directly connected to the terminal ##STR2## group, and further provided that none of the hydrocarbon groups has non-aromatic unsaturated.Type: GrantFiled: December 21, 1992Date of Patent: January 11, 1994Assignee: Eastman Kodak CompanyInventors: Ignazio S. Ponticello, Richard C. Sutton
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Patent number: 5278244Abstract: A new class of macromolecular monomers (hereinafter called "macromonomers") comprises the polymerized product of at least one of an ethenylarene and a conjugated diene monomer, the product having a terminal omega-alkenyl group of at least four carbon atoms. The novel macromonomer can be copolymerized with ethylene and alpha-olefin monomers to form graft copolymers having pendant side-chains. The graft copolymers are useful as coating and molding compositions. The macromonomers can be useful as coatings on chromatographic supports for analytical and preparative separation of chemical mixtures.Type: GrantFiled: December 16, 1992Date of Patent: January 11, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventor: Gaddam N. Babu
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Patent number: 5274027Abstract: It has been found that monovinylidene aromatic/conjugated diene/ethylenically unsaturated acid copolymer compositions are provided with good combinations of physical properties when a sulfoalkyl monomer is employed in minor amounts in such polymer in place of emulsifying additive(s). In particular, the combinations of wet and dry pick resistance have been shown to be maintained or improved when paper coating formulations are prepared from latex polymer compositions according to this invention. Sulfoalkyl (meth)acrylate salts and 2-acrylamido-2-methylpropane sulfonic acid salts are shown to be suitable sulfoalkyl monomers for this purpose.Type: GrantFiled: December 26, 1991Date of Patent: December 28, 1993Assignee: The Dow Chemical CompanyInventors: Jean-Luc Guillaume, Stephen M. Oliver, Chiu-Kwan Lam
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Patent number: 5270382Abstract: Polymer compositions and their applications in hostile environments for oil field operations are disclosed. The compositions contains a polymer which is copolymerized by (a) an ampholytic monomer having the formula of: ##STR1## where one and only one of the substituted groups R.sub.1, R.sub.2, R.sub.3 and R.sub.4 must be a vinyl group, the rest can be the same or different and can be hydrogen or a C.sub.1 -C.sub.3 alkyl group; R.sub.5 is a phenyl group; n is .gtoreq.1 and .ltoreq.6; and q is 0 or 1; (b) at least one comonomer having an ethylenic linkage. The compositions further contain crosslinking agents, such as phenol and formaldehyde, for reducing permeability in a high temperature subterranean formation; and water for use in well treating fluids.Type: GrantFiled: April 24, 1992Date of Patent: December 14, 1993Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Henry L. Hsieh, Ahmad Moradi-Araghi, Bharat Patel
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Patent number: 5262246Abstract: A material for spacecrafts pertaining to this invention is made of a compound containing the group IV b elements, as a material of which proof for oxygen atom is absolutely necessary. The application of this material, in the form of a shield part (a resin layer) for covering at least a portion of material used in a structural part of the spacecraft enables a long use (from several months to several decades or more) in the oxygen atom environment in the space, which was impossible in the part.Type: GrantFiled: December 21, 1990Date of Patent: November 16, 1993Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Takao Nishikawa, Katsumi Sonoda, Yoshiko Aiba, Hiroshi Adachi
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Patent number: 5260391Abstract: A unique tetrapolymer and an additive package for reducing water loss from cement comprising a tetrapolymer, base, and electrolyte, at least one surfactant, and water is disclosed. A process for producing cement slurries with improved water loss properties, as well as an improved method for cementing gas and oil wells is also disclosed.Type: GrantFiled: March 15, 1991Date of Patent: November 9, 1993Inventor: Michael Stephens
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Patent number: 5250642Abstract: A composition of a superabsorbent polymer and a process for using the polymer to absorb an aqueous electrolyte solution are disclosed.Type: GrantFiled: May 20, 1992Date of Patent: October 5, 1993Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Henry L. Hsieh
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Patent number: 5244763Abstract: Reducing agents for oxidized developing agents and light sensitive elements containing the reducing agents wherein the reducing agents comprise a polymer having gallic acid or gallic acid derivative moieties.Type: GrantFiled: January 11, 1993Date of Patent: September 14, 1993Assignee: Eastman Kodak CompanyInventors: Ralph B. Nielsen, Lan B. Thai, Hwei-ling Yau