Fluorine-containing Monomer Contains A Sulfur Atom Patents (Class 526/243)
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Patent number: 11920102Abstract: A deposition composition includes a solvent comprising a hydrofluorothioether compound represented by the following general formula (I): Rf—S—Rh where Rf is a fluorinated or perfluorinated group having 2-9 carbon atoms and optionally includes one or more catenated heteroatoms or chlorine atoms, and Rh is a non-fluorinated hydrocarbon group having 1-3 carbon atoms. The deposition composition further includes a coating material that is soluble or dispersible in said solvent.Type: GrantFiled: January 21, 2021Date of Patent: March 5, 2024Assignee: 3M INNOVATIVE PROPERTIES COMPANYInventors: Jason M. Kehren, David J. Lundberg, Zai-Ming Qiu, Michael G. Costello, Michael J. Bulinski, Alexandre R. Monteil
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Patent number: 11131926Abstract: The present invention provides a resist composition, including: (A) a sulfonium salt containing an anion and a cation, the cation including a partial structure shown by the following general formula (A1); and (B) a polymer compound containing a repeating unit shown by the following general formula (B1). The present invention provides a resist composition that causes few defects and is excellent in lithography performance, having regulated acid diffusion, in photolithography using a high energy beam as a light source, and a resist patterning process using this resist composition.Type: GrantFiled: June 19, 2018Date of Patent: September 28, 2021Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Takahiro Suzuki, Daisuke Domon, Masaaki Kotake, Keiichi Masunaga, Satoshi Watanabe
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Patent number: 10995215Abstract: The present disclosure relates to novel fluoromonomer and fluorooligomer compounds, a photopolymerizable composition including these compounds, methods for producing these compounds, and a hydrophobic film using the photopolymerizable composition.Type: GrantFiled: July 11, 2018Date of Patent: May 4, 2021Assignee: EWHA UNIVERSITY—INDUSTRY COLLABORATION FOUNDATIONInventors: Myung Hwa Kim, Won-Suk Kim, Hye Su Jang, Yejung Lee, Ye-Seul Yun, Yong-Ju Kwon, Saeah Kim
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Patent number: 10876041Abstract: A method of treating a material to achieve at least one of reducing surface wettability of the material or reducing fluid transport through the material includes exposing the material to a composition including a solution of a polymer portion and carbon dioxide for a period of time. The polymer portion includes at least one of a polyfluoroacrylate or a copolymer of a fluoroacrylate and a comonomer. A pressure of the composition is maintained above the cloud point of the polymer portion at a concentration thereof in the carbon dioxide for the period of time.Type: GrantFiled: April 12, 2019Date of Patent: December 29, 2020Assignee: University of Pittsburgh—Of the Commonwealth System of Higher EducationInventor: Robert M. Enick
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Patent number: 10844037Abstract: Acid generators comprising a carbocyclic aryl or heteroaromatic group substituted with at least one acetate moiety are provided. These acid generators are particularly useful as a photoresist composition component.Type: GrantFiled: February 24, 2016Date of Patent: November 24, 2020Assignee: Rohm and Haas Electronic Materials LLCInventor: Paul J. Labeaume
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Patent number: 10793659Abstract: The present invention provides a water-soluble silicone macromer. The water-soluble silicone macromer has a general formula: E-(M1)x-(M2)y, wherein M1 is a repeating unit which is derived from a silicone containing monomer, M2 is a repeating unit which is derived from a first hydrophilic monomer, and E is an ethylenically unsaturated group. The amount of M1 is in a range of 30-60 wt % based on the total weight of the water-soluble silicone macromer, and the amount of M2 is in a range of 40-70 wt % based on the total weight of the water-soluble silicone macromer. A silicone hydrogel composition containing the water-soluble silicone macromer and a silicone hydrogel lens made of the silicone hydrogel composition are also provided herein.Type: GrantFiled: February 5, 2018Date of Patent: October 6, 2020Assignee: PEGAVISION CORPORATIONInventors: Yu-Chin Lai, Ting-Chun Kuan, Hsiang-Ho Kung, Min-Tzung Yeh, Ching-Wen Yang, Tsung-Kao Hsu
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Patent number: 10726967Abstract: The present invention provides: a biological electrode composition formable a living body contact layer for a biological electrode which is excellent in conductivity and biocompatibility, as well as light in the weight thereof and producible at a low cost, and in addition, which does not cause a significant decrease in the conductivity thereof regardless of under a water-wet condition and a dry condition; a polymer compound which can be suitably used for the biological electrode composition; a polymerizable monomer suitable as a raw material of the polymer compound; a biological electrode having a living body contact layer formed of the biological electrode composition; and a method for producing the same; and wherein, the polymerizable monomer is represented by the following general formula (1).Type: GrantFiled: December 29, 2017Date of Patent: July 28, 2020Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Osamu Watanabe, Motoaki Iwabuchi, Takayuki Fujiwara
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Patent number: 10471396Abstract: Disclosed are a copolymer, porous membranes made from the copolymer, and a method of treating fluids using the porous membranes to remove metal ions, for example, from fluids originating in the microelectronics industry, wherein the copolymer includes polymerized monomeric units I and II, wherein monomeric unit I is of the formula A-X—CH2—B, wherein A is Rf—(CH2)n, Rf is a perfluoro alkyl group of the formula CF3—(CF2)x—, wherein x is 3-12, n is 1-6, X is O or S, and B is vinylphenyl, the monomeric unit II is haloalkyl styrene, and optionally wherein the halo group of haloalkyl is replaced with an optional substituent, for example, ethylenediamine tetra acetic acid, iminodiacetic acid, or iminodisuccinic acid.Type: GrantFiled: August 15, 2016Date of Patent: November 12, 2019Assignee: Pall CorporationInventors: Frank Okezie Onyemauwa, Hassan Ait-Haddou
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Patent number: 10343122Abstract: Disclosed are a copolymer, porous membranes made from the copolymer, and a method of treating fluids using the porous membranes to remove metal ions, for example, from fluids originating in the microelectronics industry, wherein the copolymer includes polymerized monomeric units I and II, wherein monomeric unit I is of the formula A-X—CH2—B, wherein A is Rf—(CH2)n, Rf is a perfluoro alkyl group of the formula CF3—(CF2)x—, wherein x is 3-12, n is 1-6, X is O or S, and B is vinylphenyl, the monomeric unit II is haloalkyl styrene, and optionally wherein the halo group of haloalkyl is replaced with an optional substituent, for example, ethylenediamine tetra acetic acid, iminodiacetic acid, or iminodisuccinic acid.Type: GrantFiled: August 15, 2016Date of Patent: July 9, 2019Assignee: Pall CorporationInventors: Frank Okezie Onyemauwa, Hassan Ait-Haddou
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Patent number: 9956447Abstract: New high molecular weight fluoropolymers (fluoropolymer surfactants) are provided that are useful in compositions for use as fire extinguishing concentrates. The fluoropolymers contain C4-C6 perfluoroalkyl groups, and substantially lack perfluoroalkyl groups containing more than 6 fluorine-substituted carbon atoms.Type: GrantFiled: September 25, 2013Date of Patent: May 1, 2018Assignee: TYCO FIRE & SECURITY GMBHInventors: Thomas Joseph Martin, Ming Li
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Patent number: 9879110Abstract: An AB-type block copolymer for use in printed circuit board (PCB) fabrication is provided having a structure represented by the following formula: wherein R1 is a silane pendant group that includes a silicon-containing moiety capable of bonding to a glass surface, and wherein R2 is a matrix-reactive pendant group that includes at least one moiety (e.g., a vinyl-, allyl-, amine-, amide- or epoxy-containing moiety) capable of reacting with a base polymer.Type: GrantFiled: November 21, 2014Date of Patent: January 30, 2018Assignee: International Business Machines CorporationInventors: Dylan J. Boday, Joseph Kuczynski, Timothy C. Mauldin
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Patent number: 9777170Abstract: The present invention comprises a composition and method of use for providing cleanability to paint comprising an aqueous emulsion of Formula (I) wherein the composition of Formula (I) is a random copolymer; wherein said composition of formula (I) further comprises residue from a hydrophilic chain transfer agent. The compositions of the present invention provide durability to coating compositions, while also providing surface effects such as increased water and oil contact angles, enhanced dirt pickup resistance, and enhanced cleanability to the coating films. For these reasons, the composition of the present invention is particularly suitable for use as additives to exterior coatings and paints.Type: GrantFiled: February 23, 2015Date of Patent: October 3, 2017Assignee: THE CHEMOURS COMPANY TT, LLCInventors: Anilkumar Raghavanpillai, Timothy Pellenbarg, Hau-Nan Lee, James J. Hughes, Kai Qi, John Russell Crompton, Jr., Brad M Rosen
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Patent number: 9464384Abstract: A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): CH2?C(—X)—C(?O)—Y—Z—Rf (where X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like; Y is —O— or —NH—; Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like; and Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms), and (b) a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound. Also disclosed is a method for treating paper, a treated paper and a composition for treating paper containing the water-resistant/oil resistant agent.Type: GrantFiled: March 14, 2013Date of Patent: October 11, 2016Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Tetsuya Uehara, Kayo Kusumi, Michio Matsuda
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Patent number: 9340648Abstract: A coating material including a perfluorocarbon sulfonic acid resin which is a copolymer including a polymerization unit represented by —(CF2—CFZ)—, in the formula, Z being H, Cl, F, or a C1-C3 perfluoroalkyl group, and a polymerization unit represented by —(CF2—CF(—O—(CF2)m—SO3H))—, in the formula, m being an integer of 1 to 12, and the perfluorocarbon sulfonic acid resin has an equivalent weight EW of 200 to 1000. Also disclosed is a laminate including a base material and a hydrophilic layer formed from the coating material.Type: GrantFiled: January 31, 2011Date of Patent: May 17, 2016Assignees: ASAHI KASEI E-MATERIALS CORPORATION, DAIKIN INDUSTRIES, LTD.Inventors: Yuko Iizuka, Naoto Miyake, Tadashi Ino, Masahiro Kondo, Katsuhiko Imoto
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Patent number: 9206113Abstract: To provide a fluorinated compound having an RF group with at most 6 carbon atoms, whereby a fluorinated polymer having a highly durable water/oil repellency can be produced, and an environmental load is little, and a fluorinated polymer having a highly durable water/oil repellency and presenting little environmental load, obtainable by polymerizing such a fluorinated compound. A fluorinated compound represented by the following formula (I) and its polymer: CH2?C(CH3)COO(CH2)nPhXCrF2r+1??(I) (in the formula (I), n is an integer of from 0 to 2, Ph is a phenylene group, X is a single bond or a C1-4 alkylene group containing an etheric oxygen atom, and r is an integer of from 2 to 6).Type: GrantFiled: March 5, 2012Date of Patent: December 8, 2015Assignee: Asahi Glass Company, LimitedInventor: Taiki Hoshino
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Patent number: 9182662Abstract: A copolymer comprising the polymerized product of an electron-sensitizing acid deprotectable monomer, such as the monomer having the formula (XX), and a comonomer: wherein Ra is H, F, —CN, C1-10 alkyl, or C1-10 fluoroalkyl; Rx and Ry are each independently a substituted or unsubstituted C1-10 alkyl group or C3-10 cycloalkyl group; Rz is a substituted or unsubstituted C6-20 aromatic-containing group or C6-20 cycloaliphatic-containing group; wherein Rx and Ry together optionally form a ring; and wherein at least one of Rx, Ry and Rz is halogenated. A photoresist and coated substrate comprising the copolymer, and a method of making an electronic device using the photoresist, are also disclosed.Type: GrantFiled: January 29, 2013Date of Patent: November 10, 2015Assignee: ROHM AND HAAS ELECTRONIC MATERIALS LLCInventors: Owendi Ongayi, James W. Thackeray
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Patent number: 9115234Abstract: To provide a water/oil repellent composition which can give water/oil repellency to a surface of an article and has excellent durability (wash durability and heavy-rain durability), a method for producing such a composition, and an article which has water/oil repellency and is less susceptible to deterioration of water/oil repellency when it is washed or in heavy rain. A water/oil repellent composition which comprises a copolymer having polymerized units derived from monomer (a), polymerized units derived from monomer (b) and polymerized units derived from monomer (c). Here, monomer (a) is a compound represented by the formula: (Z—Y)nX; wherein Z is a C1-6 perfluoroalkyl group or the like; Y is a bivalent organic group or a single bond; n is 1 or 2; and X is a polymerizable unsaturated group; monomer (b) is a (meth)acrylate having no polyfluoroalkyl group and having an C20-30 alkyl group; and monomer (c) is vinylidene chloride.Type: GrantFiled: September 8, 2009Date of Patent: August 25, 2015Assignee: Asahi Glass Company, LimitedInventors: Minako Shimada, Kazunori Sugiyama, Yuuichi Oomori
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Patent number: 9104101Abstract: A resist composition including a resin component which generates acid upon exposure and exhibits changed solubility in a developing solution under the action of acid, the resin component including a resin component having a structural unit represented by a general formula (a0-0-1) shown below in which R represents a hydrogen atom, an alkyl group of 1 to 5 carbon atoms or a halogenated alkyl group of 1 to 5 carbon atoms, R0-1 represents a single bond or a divalent linking group, each of R2, R3 and R4 independently represents a linear, branched or cyclic alkyl group which may have a non-aromatic substituent, or R3 and R4 may be bonded to each other to form a ring together with the sulfur atom, and X represents a non-aromatic divalent linking group or a single bond.Type: GrantFiled: February 22, 2012Date of Patent: August 11, 2015Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Kensuke Matsuzawa, Jun Iwashita, Yoshitaka Komuro, Masatoshi Arai
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Publication number: 20150147698Abstract: A negative resist composition comprising a polymer comprising recurring units (a) of formula (1) and having a Mw of 1,000-500,000 as base resin is provided. R1 is H or methyl, X is a single bond or —C(?O)—O—R4—, R2 is a single bond or C1-C4 alkylene, R3 is C2-C8 alkylene, R4 is a single bond or C1-C4 alkylene, and 0<a?1.0. The composition exhibits a high resolution due to controlled acid diffusion and forms a resist film which is unsusceptible to swell in the developer and hence to pattern collapse.Type: ApplicationFiled: November 25, 2014Publication date: May 28, 2015Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Jun Hatakeyama, Masayoshi Sagehashi
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Patent number: 9040596Abstract: An ion conducting membrane for fuel cells involves coupling a compound having a sulfonic acid group with a polymeric backbone. Each of the compounds having a sulfonic acid group and the polymeric backbone are first functionalized with a halogen.Type: GrantFiled: December 28, 2011Date of Patent: May 26, 2015Assignee: GM Global Technology Operations LLCInventors: Timothy J. Fuller, Lijun Zou, Michael R. Schoeneweiss
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Publication number: 20150132688Abstract: There is provided an actinic ray-sensitive or radiation-sensitive resin composition comprising (P) a resin having (a) a repeating unit represented by the specific formula; a resist film formed using the actinic ray-sensitive or radiation-sensitive resin composition; a pattern forming method comprising (i) a step of forming a film by using the actinic ray-sensitive or radiation-sensitive resin composition, (ii) a step of exposing the film, and (iii) a step of developing the exposed film by using a developer to form a pattern; a method for manufacturing an electronic device, comprising the pattern forming method; and an electronic device manufactured by the manufacturing method of an electronic device.Type: ApplicationFiled: January 26, 2015Publication date: May 14, 2015Applicant: FUJIFILM CorporationInventors: Natsumi YOKOKAWA, Shuji HIRANO, Hiroo TAKIZAWA, Wataru NIHASHI
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Patent number: 9029471Abstract: Various fluoropolymers have been proposed for imparting oil and water repellency to leather. Commonly, these fluoropolymers are amphiphilic; i.e., they are made from at least one monomer which is hydrophobic and at least one monomer which is hydrophilic. The present invention identifies and remedies disadvantages associated with the ability of amphiphilic fluoropolymers to impart oil and water repellency to leather. Contrary to conventional thinking, it has now been discovered that the incorporation of hydrophilic groups in a fluoropolymer undesirably reduces its ability to impart water resistance to leather. Correspondingly, it has also been discovered that a fluoropolymer incorporating fewer or no hydrophilic groups imparts superior oil and water repellency to leather when compared to fluoropolymers incorporating more hydrophilic groups. Therefore, this invention provides fluoropolymers which incorporate reduced levels of hydrophilic groups.Type: GrantFiled: September 30, 2008Date of Patent: May 12, 2015Assignee: E I du Pont du Nemours and CompanyInventors: Romain Severac, Agnes Ibos, Lamia Heuze, Renaud Laloux-Walther
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Patent number: 9023581Abstract: A resist composition which can form a very fine resist pattern with excellent lithography properties, a new polymeric compound useful for the resist composition, and a compound useful as a monomer for the polymeric compound. The resist composition contains a polymeric compound containing a structural unit (a0) represented by general formula (a0) shown below. In the formula (a0), A is an anion represented by the general formula (1) or (2).Type: GrantFiled: June 14, 2011Date of Patent: May 5, 2015Assignee: Tokyo Ohka Kogyo Co., LtdInventors: Akiya Kawaue, Kazushige Dohtani, Yoshiyuki Utsumi, Jun Iwashita, Kenri Konno, Daiju Shiono, Daichi Takaki
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Publication number: 20150118628Abstract: Provided is an actinic-ray- or radiation-sensitive resin composition including a resin (P) comprising any of repeating units (A) of general formula (I) below, each of which contains an ionic structural moiety that when exposed to actinic rays or radiation, is decomposed to thereby generate an acid in a side chain of the resin.Type: ApplicationFiled: December 23, 2014Publication date: April 30, 2015Applicant: FUJIFILM CORPORATIONInventors: Takeshi KAWABATA, Hideaki TSUBAKI, Hiroo TAKIZAWA, Natsumi YOKOKAWA
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Patent number: 9017924Abstract: A resist composition which generates acid upon exposure and exhibits changed solubility in a developing solution under action of acid, including a base component (A) which exhibits changed solubility in a developing solution under action of acid, the base component (A) including a polymeric compound (A1) containing a structural unit (a0) represented by general formula (a0-1) shown below. In the formula, W1 represents a group which is formed by polymerization reaction of a group containing a polymerizable group; Y1 and Y2 each independently represents a divalent linking group; Y3 represents a carbonyl group or an alkylene group; R2 and R3 each independently represents a fluorine atom or a fluorinated alkyl group; Mm+ represents an organic cation having a valency of m; and m represents an integer of 1 or more.Type: GrantFiled: March 4, 2014Date of Patent: April 28, 2015Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Daichi Takaki, Yoshiyuki Utsumi
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Patent number: 9017931Abstract: A negative pattern is formed by coating a resist composition comprising a polymer comprising recurring units having a tertiary ester type acid labile group having a plurality of methyl or ethyl groups on alicycle and an acid generator onto a substrate, prebaking, exposing to high-energy radiation, baking, and developing in an organic solvent developer so that the unexposed region of resist film is dissolved away and the exposed region of resist film is not dissolved. The resist composition exhibits a high dissolution contrast during organic solvent development and forms a fine hole or trench pattern of dimensional uniformity.Type: GrantFiled: August 16, 2013Date of Patent: April 28, 2015Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Koji Hasegawa, Jun Hatakeyama, Masayoshi Sagehashi, Teppei Adachi
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Publication number: 20150112036Abstract: The present invention relates to a polymer comprising the reaction product of: (a) a compound of Formula (3), or a mixture thereof: defined herein and (b) at least one ethylenically unsaturated monomer having a functional group. The present invention also relates to a polymer having at least one carbamate linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (2): defined herein and (ii) optionally reacting with (c) water, a linking agent, or a mixture thereof. The polymers are useful as additives in coating compositions and film forming foams, which impart surface effects to substrates coated with such compositions and to film forming foams.Type: ApplicationFiled: October 17, 2013Publication date: April 23, 2015Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Roman B. LARICHEV, Michael Henry OBER, John SINICROPI
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Patent number: 9005874Abstract: There are provided a novel compound, a polymeric compound, a resist composition, an acid generator and a method of forming a resist pattern the compound represented by general formula (1-1): wherein each of R1 and R3 independently represents a single bond or a divalent linking group; A represents a divalent linking group; each of R2 and R4 independently represents a hydroxyl group, a hydrocarbon group which may have a substituent, or a group represented by general formula (1-an1), (1-an2) or (1-an3), provided that at least one of R2 and R4 represents a group represented by general formula (1-an1), (1-an2) or (1-an3); and n0 is preferably 0 or 1, and wherein Y1 represents a single bond or —SO2—; R5 represents a linear or branched monovalent hydrocarbon group of 1 to 10 carbon atoms, cyclic monovalent hydrocarbon group of 3 to 20 carbon atoms or monovalent hydrocarbon group of 3 to 20 carbon atoms having a cyclic partial structure which may be substituted with a fluorine atom; and M+ represents an organic caType: GrantFiled: April 18, 2012Date of Patent: April 14, 2015Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Yoshitaka Komuro, Yoshiyuki Utsumi, Akiya Kawaue, Masatoshi Arai
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Patent number: 8993713Abstract: A n-type ladder copolymer including, a n-type ladder copolymer formed with alternating perylene and pyridine units having chemical structure A having two end groups, where perylene units having at least one solubilizing group attaching at position(s) 1, 6, 7, and/or 12, where R1, R2, R3, and R4 solubilizing group(s) are each independently selected from the group consisting of aryl, alkyl aryl, alkoxy aryl, and aryloxy aryl, and where n repeat units ranging from about 4 to about 400Type: GrantFiled: May 16, 2013Date of Patent: March 31, 2015Assignee: The United States of America as represented by the Secretary of the NavyInventors: William W. Lai, Alfred Baca
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Patent number: 8993682Abstract: The present invention provides an electrolyte having high conductivity even under high-temperature low-humidification conditions (e.g. at a temperature of 100 to 120° C. and a humidity of 20 to 50% RH) and thereby makes it possible to realize a higher performance fuel cell. The present invention is a fluoropolymer electrolyte having an equivalent weight (EW) of not less than 250 but not more than 700 and a proton conductivity of not lower than 0.10 S/cm as measured at a temperature of 110° C. and a relative humidity of 50% RH and comprising a COOZ group- or SO3Z group-containing monomer unit, wherein Z represents an alkali metal, an alkaline earth metal, hydrogen atom or NR1R2R3R4 in which R1, R2, R3 and R4 each independently represents an alkyl group containing 1 to 3 carbon atoms or hydrogen atom.Type: GrantFiled: March 12, 2009Date of Patent: March 31, 2015Assignees: Asahi Kasei E-Materials Corporation, Daikin Industries, Ltd.Inventors: Kohei Kita, Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Noriyuki Shinoki, Masaharu Nakazawa, Masahiro Kondo, Takashi Yoshimura
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Publication number: 20150086912Abstract: There is provided an actinic ray-sensitive or radiation-sensitive resin composition comprising (P) a resin having a repeating unit (A) represented by the specific formula (I) capable of generating an acid on the side chain of the resin upon irradiation with an actinic ray or radiation, and a resist film formed with the actinic ray-sensitive or radiation-sensitive resin composition, and a pattern forming method comprising: exposing the resist film, and developing the exposed resist film, and a method for manufacturing a semiconductor device, containing the pattern forming method, and a semiconductor device manufactured by the manufacturing method of the semiconductor device.Type: ApplicationFiled: November 26, 2014Publication date: March 26, 2015Applicant: FUJIFILM CORPORATIONInventors: Takeshi KAWABATA, Hideaki TSUBAKI, Hiroo TAKIZAWA, Natsumi YOKOKAWA
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Patent number: 8980526Abstract: Disclosed are a hydrophilic photoacid generator prepared by copolymerization of a first (meth)acrylic acid ester having a structure represented by the following Formula 1 or 2, with a polymerizable monomer selected from the group consisting of a second (meth)acrylic acid ester, an olefin-based compound and a mixture thereof, each of which contains a functional group selected from the group consisting of a hydroxyl group, a carboxyl group, a lactone group, a nitrile group and a halogen group: wherein respective substituents are defined in the specification, and a resist composition comprising the same. The hydrophilic photoacid generator is uniformly dispersed in a resist film, thus improving a line edge roughness of resist patterns.Type: GrantFiled: December 13, 2012Date of Patent: March 17, 2015Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Dae Kyung Yoon, Kyoung Jin Ryu, Sung Jae Lee, Hyun Sang Joo
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Publication number: 20150060744Abstract: The present disclosure relates to a blue dye compound for a color filter and a coloring resin composition for a color filter containing the same. Since the blue resin composition according to the present disclosure, which contains the novel triarylmethane blue dye compound or the polymer dye compound obtained using the same as a monomer, has superior solubility in an organic solvent such as propylene glycol monomethyl ether acetate (PGMEA), cyclohexanone, etc. as well as superior miscibility with another pigment and high brightness, it can be used to prepare a color filter exhibiting superior heat resistance, light resistance and brightness.Type: ApplicationFiled: February 27, 2013Publication date: March 5, 2015Inventors: Soonhyun Park, Jeong Gi Kim, Jung Rok Kim, Do Kyung Lee, Heon Park
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Publication number: 20150045524Abstract: A functional TFE copolymer fine powder is described, wherein the TFE copolymer is a polymer of TFE and at least one functional comonomer, and wherein the TFE copolymer has functional groups that are pendant to the polymer chain. The functional TFE copolymer fine powder resin is paste extrudable and expandable. Methods for making the functional TFE copolymer are also described. The expanded functional TFE copolymer material may be post-reacted after expansion.Type: ApplicationFiled: October 24, 2014Publication date: February 12, 2015Inventors: Ping Xu, Jack J. Hegenbarth, Xin Kang Chen
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Patent number: 8951710Abstract: A polymer comprising 0.5-10 mol % of recurring units having acid generating capability and 50-99.5 mol % of recurring units providing for dissolution in alkaline developer is used to formulate a chemically amplified negative resist composition. When used in a lithography process, the composition ensures an effective sensitivity, makes more uniform the distribution and diffusion of the acid generating component in a resist film, and suppresses deactivation of acid at the substrate interface. The pattern can be formed to a profile which is improved in LER and undercut.Type: GrantFiled: August 4, 2014Date of Patent: February 10, 2015Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Keiichi Masunaga, Daisuke Domon, Satoshi Watanabe
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Patent number: 8951599Abstract: A wound dressing and a method of making the wound dressing is described herein. The wound dressing is formed of an absorbent substrate formed of one or more layers and a low-adherence layer disposed on the substrate. The low-adherence layer can be disposed within at least a portion of the substrate. The low-adherence layer is formed of a mixture of at least one highly fluorinated polymer and at least one acidic polymer. The at least one highly fluorinated polymer has a fluorine content greater than the fluorine content of the at least one acidic polymer.Type: GrantFiled: November 15, 2012Date of Patent: February 10, 2015Assignee: International Business Machines CorporationInventors: Robert D. Allen, Christopher E. Bannister, Jere J. Brophy, Richard A. DiPietro
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Patent number: 8945814Abstract: Acid generator compounds are provided that are particularly useful as photoresist composition components. Preferred acid generators include cyclic sulfonium compounds that comprise a covalently linked acid-labile group.Type: GrantFiled: September 16, 2013Date of Patent: February 3, 2015Assignee: Rohm and Haas Electronic Materials LLCInventors: James F. Cameron, Vipul Jain, Paul J. LaBeaume, Jin Wuk Sung, James W. Thackeray
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Patent number: 8940846Abstract: A process for reducing the amount of soluble polymeric fractions in a sulfonyl fluoride polymer. The process comprises contacting the sulfonyl fluoride polymer with a fluorinated fluid followed by separation of the polymer from the fluid. The fluorinated fluid is selected from hydrofluoroethers and hydrofluoropolyethers. The invention further relates to sulfonyl fluoride polymers obtainable by the process and having a heat of fusion not exceeding 4 J/g and containing less than 15% by weight of polymeric fractions having an average content of monomeric units comprising a sulfonyl functional group exceeding 24 mole %. The sulfonyl fluoride polymers so obtained are particularly suitable for the preparation of ionomeric membranes for use in electrochemical devices.Type: GrantFiled: June 22, 2011Date of Patent: January 27, 2015Assignee: Solvay Specialty Polymers Italy S.p.A.Inventors: Luca Merlo, Alessandro Veneroni, Elvira Pagano, Claudio Oldani
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Publication number: 20150010857Abstract: There is provided an actinic ray-sensitive or radiation-sensitive resin composition containing a resin (P) having a repeating unit represented by the following Formula (A) and having at least two of a repeating unit represented by the following Formula (B), a repeating unit represented by the following Formula (C), a repeating unit represented by the following Formula (D) and a repeating unit represented by the following Formula (E).Type: ApplicationFiled: September 4, 2014Publication date: January 8, 2015Applicant: FUJIFILM CORPORATIONInventors: Natsumi YOKOKAWA, Hiroo TAKIZAWA, Hideaki TSUBAKI
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Publication number: 20150005456Abstract: The present invention pertains to semi-crystalline fluoropolymer [polymer (F)] comprising: —recurring units derived from vinylidene fluoride (VDF); —from 10% to 50% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from trifluoroethylene (TrFE); and—from 0.01% to 10% by moles [with respect to the total moles of recurring units of polymer (F)] of recurring units derived from at least one monomer comprising an azide group [monomer (Az)], to a process for its manufacture, to a crosslinkable composition comprising the same, to a process for crosslinking the same and to a method for manufacturing one of electrical and electronic devices using the same.Type: ApplicationFiled: December 6, 2012Publication date: January 1, 2015Inventors: Alessio Marrani, Ivan Wlassics, Vito Tortelli, Ivan Falco
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Publication number: 20140377707Abstract: A composition for forming a liquid immersion upper layer film includes a polymer component including a polymer having a structural unit represented by a formula (1); and a solvent. R1 represents a carboxy group or a group represented by a formula (2); X represents a single bond, a divalent hydrocarbon group having 1 to 20 carbon atoms or a divalent fluorinated hydrocarbon group having 1 to 20 carbon atoms; R2 represents a hydrocarbon group having 1 to 20 carbon atoms and a valency of (n+1), a fluorinated hydrocarbon group having 1 to 20 carbon atoms and a valency of (n+1), or one of these groups each including between adjacent two carbon atoms thereof —CO—, —COO—, —O—, —NR?—, —CS—, —S—, —SO—, —SO2— or a combination thereof; and R3 represents a hydrogen atom or a monovalent organic group having 1 to 20 carbon atoms.Type: ApplicationFiled: September 20, 2013Publication date: December 25, 2014Applicant: JSR CORPORATIONInventors: Shinya MINEGISHI, Kiyoshi TANAKA, Kazunori KUSABIRAKI
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Patent number: 8916058Abstract: It has been discovered by in present invention that, compared with a fluorosurfactant having only one betaine group per molecule, a fluorosurfactant having a plurality of betaine groups per molecule is superior in its ability to undergo electrostatic interaction with other components of a fire fighting composition thereby improving the performance of the fire fighting composition. Previously known fluorosurfactants comprise only one betaine group per molecule. In contrast, the present invention provides for a fluorobetaine copolymer containing a plurality of betaine groups.Type: GrantFiled: March 14, 2008Date of Patent: December 23, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Romain Severac, Martial Jean-Jacques Pabon, Isabelle Deguerry, Guillaume Gamblin
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Publication number: 20140357822Abstract: Described herein is an oligomer according to formula I: (I) wherein Y is an anionic group selected from the group consisting of: sulfates, carboxylates, phosphate, phosphonate, and sulfonate, wherein each X1, X2, and X3 are independently selected from F, Cl, H, and CF3; R is a linking group; each Z1 and Z2 is independently selected from F and CF3; m is at least 2; and R1 and R2 are end groups, wherein the oligomer comprises substantially no pendant functional groups, except those selected from the group consisting of: sulfates, carboxylates, phosphate, phosphonate, and sulfonate.Type: ApplicationFiled: December 4, 2012Publication date: December 4, 2014Inventors: Zai-Ming Qiu, Miguel A. Guerra
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Publication number: 20140329970Abstract: This invention pertains to fluoroallylsulfonyl azide compounds of formula: CF2?CF—CF2—Rf—SO2N3 formula (I) wherein Rf is a divalent (per)fluorinated group, optionally comprising one or more than one ethereal oxygen atom [monomer (Az)], which are useful as functional monomers in fluoropolymers, to the fluoropolymers which comprise recurring units derived from such fluoroallylsulfonyl azide compounds, to a process for their manufacture, to a curable compound comprising the same and to a method for crosslinking the same.Type: ApplicationFiled: December 6, 2012Publication date: November 6, 2014Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Ivan Wlassics, Vito Tortelli, Alessio Marrani
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Patent number: 8877424Abstract: A polymer is prepared from an adamantane methacrylate monomer whose alcoholic hydroxyl group is protected with an alicyclic-containing tertiary alkyl group. A photoresist composition comprising the polymer displays a high sensitivity and a high dissolution contrast during both alkaline development and organic solvent development.Type: GrantFiled: February 8, 2013Date of Patent: November 4, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masayoshi Sagehashi, Jun Hatakeyama, Koji Hasegawa, Kazuhiro Katayama
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Patent number: 8871882Abstract: A method for the preparation of a fluoropolymer by means of emulsion polymerization of a reaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; b) an emulsion stabilizer combination comprising: i) an anionic surfactant; and, ii) a cationic surfactant or a non-ionic surfactant; and, c) a free-radical initiator.Type: GrantFiled: February 14, 2012Date of Patent: October 28, 2014Assignee: Akron Polymer Systems, Inc.Inventors: Xiaoliang Zheng, Dong Zhang, Jiaokai Jing, Ted Calvin Germroth, Frank W. Harris, Thauming Kuo, Bin Wang, Douglas Stephens McWilliams
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Publication number: 20140306157Abstract: Subject It is to provide a polymerizable compound having a high polymerization reactivity, a high conversion yield and a high solubility in a liquid crystal composition, a polymerizable composition including the compound, a liquid crystal composite prepared from the composition and a liquid crystal display device containing this composite. Means for Solving the Subject A compound represented by formula (1). In this formula, for example, P1 and P2 are —SCO—CH?CH2; Sp1 and Sp2 are a single bond; ring A1, ring A2, ring A3 and ring A4 are 1,4-phenylene; Z1, Z2 and Z3 are a single bond; and a is 1, and b and c is 0.Type: ApplicationFiled: April 2, 2014Publication date: October 16, 2014Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATIONInventors: Yasuyuki GOTOH, Masakazu YANO
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Patent number: 8859071Abstract: A curable composition for imprints, which is excellent in patternability and in line edge roughness, is provided. The curable composition for imprints comprises at least one kind of polymerizable monomer (A) and at least one kind of photopolymerization initiator (B). The polymerizable monomer (A) comprises at least two fluorine-containing groups selected from a fluoroalkyl group and a fluoroalkylether group and each of two of the fluorine-containing groups is connected with each other through a linking group having at least two carbon atoms.Type: GrantFiled: March 8, 2010Date of Patent: October 14, 2014Assignee: FUJIFILM CorporationInventor: Kunihiko Kodama
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Publication number: 20140287359Abstract: According to the present invention, there is provided a fluorine-containing sulfonate resin having a repeating unit of the following general formula (3). In order to prevent deficiency such as roughness after pattern formation or failure in pattern formation, the fluorine-containing sulfonate resin incorporates therein a photoacid generating function and serves as a resist resin in which “a moiety capable of changing its developer solubility by the action of an acid” and “a moiety having a photoacid generating function” are arranged with regularity.Type: ApplicationFiled: June 10, 2014Publication date: September 25, 2014Inventors: Kazunori MORI, Satoru NARIZUKA, Fumihiro AMEMIYA, Masaki FUJIWARA
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Publication number: 20140287200Abstract: To provide a curable composition which has favorable insulating property and liquid repellency, and from which a cured film having liquid repellency capable of being sufficiently converted to be liquid-philic even by irradiation with ultraviolet light having a wavelength of at least 300 nm, can be formed; an article having a cured film obtained by curing the curable composition and its production process. A cured film is formed by using a curable composition comprising a polymer having units (u1) based on a compound represented by the following formula (m1): wherein R1=a hydrogen atom, a methyl group or the like; R2=a bivalent organic group or the like; Cf=a C1-20 fluoroalkyl group or the like, X?O, S, N or NH; m=1 to 2; n=0 to 4; k=0 to 1; and Z=a (meth)acryloyl group or the like.Type: ApplicationFiled: June 5, 2014Publication date: September 25, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: MASAHIRO ITO, KAORI TSURUOKA, YASUHIRO KUWANA, YUSUKE NAGAI, MIYAKO SASAKI