Three Or More Nitrogen Atoms In A Single Ring Patents (Class 526/261)
  • Patent number: 5178646
    Abstract: A coatable, thermally curable binder precursor solution, the solution including a 30-95% solids solution of a thermally curable resin and a reactive diluent. The reactive diluent may be selected form urea derivatives, alkylsubstituted 2-aminoalcohols, .beta.-ketoalkylamides, nitro alkanes, and poly(oxyalkylene) compounds, and has at least one functional group independently reactive with methylol groups of the resin and with aldehydes. The thermally curable resin may include up to 50% (wt of total resin) of an ethylenically unsaturated monomer. Method of making abrasive articles are also presented.
    Type: Grant
    Filed: June 4, 1992
    Date of Patent: January 12, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Loren L. Barber, Jr., Todd J. Christianson, Jay B. Preston
  • Patent number: 5164464
    Abstract: Thermosettable vinyl ester resin compositions are prepared from polyepoxide compounds, optionally, monoepoxide compounds, at least one of which contains a mesogenic or rigid rodlike moiety and a monounsaturated monocarboxylic acid. These vinyl ester resins can be mixed with polymerizable ethylenically unsaturated monomers which can, if desired, contain a mesogenic or rigid rodlike moiety.
    Type: Grant
    Filed: June 7, 1991
    Date of Patent: November 17, 1992
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls, Paul M. Puckett
  • Patent number: 5147955
    Abstract: Copolymers ofa) phosphonic acid derivatives corresponding to formula (I) ##STR1## wherein Y represents H or CH.sub.3,X represents a single bond or --CH.sub.2 --,R represents an aryl or alkyl,b) maleic anhydride andc) a polymerizable compound containing two or more allyl or methally groups in the molecule.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: September 15, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Siegfried Korte
  • Patent number: 5116935
    Abstract: A preferred class of polyimide oligomers include (1) linear, difunctional crosslinking oligomers prepared by condensing an imidophenylamine end cap with a lower alkylene diamine or a polyaryldiamine such as 3,3'-phenoxyphenylsulfone diamine and with a dianhydride, particularly 4,4'-phenoxyphenylsulfone dianhydride; and (2) multidimensional, crosslinking, polyimide oligomers having an aromatic hub and at least two radiating arms connected to the hub, each arm including a crosslinking imidophenylamine end cap at its distal end and at least two imide linkages.Blends, prepregs, and composites can be prepared from the oligomers.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: May 26, 1992
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5110886
    Abstract: A compatibilizing agent for improving the compatibility between different polymers which are poorly compatible with each other, comprising a polymer having at least one heterocyclic ring structure containing a >C.dbd.N.sup..sym. < bond in the molecule and a polymer blend composition comprising different polymers which are poorly compatible with each other and such a compatibilizing agent.
    Type: Grant
    Filed: February 5, 1991
    Date of Patent: May 5, 1992
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shizuo Kitahara, Tetuya Toyoshima
  • Patent number: 5084538
    Abstract: The present invention relates to a high surface hardness transparent resin having excellent scratch resistance, heat resistance and chemical resistance, a glazing material, a protective cover for display devices, an optical lens and a hard coat material comprising the aforesaid resin, and a novel polymerizable monomer which is useful as a raw material of the above-mentioned resin.The monomer is represented by the formula (I) ##STR1## (wherein R is an aliphatic residue having or not having an halogen atom, an oxygen atom, an alicyclic ring, a heterocyclic ring or an aromatic ring, an alicyclic residue, or a heterocyclic residue, n is an integer of 1 to 4, when n=1, X is oxygen or sulfur, when n.gtoreq.2, X's are all oxygen or all sulfur, one X is oxygen while the other X or X's are sulfur, one X is sulfur while the other X or X's are oxygen, or two X's are oxygen while the other X's are sulfur).
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: January 28, 1992
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Toshiyuki Suzuki, Katsuyoshi Sasagawa, Masao Imai, Yoshinobu Kanemura
  • Patent number: 5084537
    Abstract: There are provided extended-wear lenses formed by polymerizing an organosilicon monomer, a fluoroorgano monomer, a hydrophilic monomer, and a crosslinking agent. The product includes a benzotriazole and/or a benzophenone UV-absorbing agent and is is easily machinable to any prescription, permitting continuous wear, with oxygen permeability in excess of 50.times.50.sup.-11 (cm.sup.2 /sec)(ml O.sub.2 .times.mm Hg) and a receding contact angle of less than 45.degree. C. The bulk of the monomer content is the fluoorgano monomer and/or organosilicon monomer, which content is limited to 35 parts by weight, with lesser amounts being preferred.
    Type: Grant
    Filed: September 30, 1988
    Date of Patent: January 28, 1992
    Assignee: Bausch & Lomb, Incorporated
    Inventor: Nick Stoyan
  • Patent number: 5077380
    Abstract: Compounds containing at least one cyanate group, at least one maleimide group and at least one mesogenic or rodlike moiety are prepared by reacting one or more aminophenols containing one or more mesogenic or rodlike moieties with a stoichimetric quantity of a maleic anhydride per amine group of said aminophenol and then cyanating the resulting phenolic functional maleimide.
    Type: Grant
    Filed: October 11, 1990
    Date of Patent: December 31, 1991
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5063048
    Abstract: A UV light-absorbing skin-protecting composition which comprises an acrylic copolymer comprising (A) a compound of the formula: ##STR1## wherein R.sup.1 is a hydrogen atom or a methyl group, X is a group of the formula: ##STR2## in which R.sup.2 is a hydroxy group, R.sup.3 is a hydrogen atom or hydroxy group, R.sup.4 and R.sup.5 are the same or different and each is a hydrogen atom, a lower alkyl group, a lower alkoxy group, a halogen atom, a nitro group, a carboxyl group, a sulfonic acid group or a sulfonamide group and R.sup.6 is a single bond or a methylene group,Y is --O--, --NH-- or a group of the formula: ##STR3## in which R.sup.7 is a hydrogen atom or a lower alkyl group, R.sup.8 is a hydrogen atom or a hydroxy group, and m and n are the same or different and is each 0 or 1, (B) 40 to 75% by weight of an alkyl acrylate, (C) 10 to 40% by weight of an alkyl methacrylate, and (D) 5 to 30% by weight of a monoethylenically unsaturated monomer having a carboxyl group; and a medium.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: November 5, 1991
    Assignees: Shionogi & Co., Ltd., Nisshin Chemical Industry Co., Ltd.
    Inventors: Izumi Saitoh, Yoshio Sasaki
  • Patent number: 5059663
    Abstract: A liquid composition stable during storage and polymerizable radically into organic glasses having a high refractive index, containing:(A) from 20 to 80% wt of a mixture of monomer and oligomers of a carbonic allyl derivative representable by the formula (I): ##STR1## where: X=halogen (except fluorine);a and be independently assume the values 1 or 2;n assumes values from 1 to 5 on condition that at least 10% by weight of the mixture consists of carbonic allyl oligomer derivatives (n>1); and(B) from 80 to 20% by weight of a liquid monomer copolymerizable with the component (A) and chosen from diallyl isophthalate, diallyl terephthalate, triallyl cyanurate and triallyl isocyanurate.
    Type: Grant
    Filed: August 2, 1990
    Date of Patent: October 22, 1991
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Franco Rivetti, Fiorenzo Renzi
  • Patent number: 5032657
    Abstract: Benzotriazole compounds having the formula: ##STR1## wherein R.sub.1 is H, Cl, or OCH.sub.3 ; R.sub.2 is a hydroxynaphthyl group; and R.sub.3 is a vinyl unsaturated polymerizable group. Homopolymers or copolymers thereof are effective as UV light stabilizers and absorbers.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: July 16, 1991
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Peter M. Gomez, Hermann H. Neidlinger
  • Patent number: 5026803
    Abstract: The invention relates to crosslinked polymers based on triazines of the general formula I ##STR1## wherein R denotes hydrogen, CH.sub.3 or C.sub.2 H.sub.5, andat least one vinylmonomer.The polymers are suitable as crosslinking agents for the preparation of duromers or elastomers.
    Type: Grant
    Filed: June 25, 1990
    Date of Patent: June 25, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Karl-Erwin Piejko
  • Patent number: 4988786
    Abstract: A hydrophobic crosslinked copolymer havng a pendant group selected from ##STR1## wherein R.sup.1 represents at least one hydrophobic group having a hydrophobic fragmental constant of at least 1.5, which copolymer has a high crosslinking monomer units content, a specific surface area and a specific acetonitrile regain value. The hydrophobic crosslinked copolymer has a high rigidity as well as an excellent mechanical strength and an excellent chemical stability so that the copolymer is useful as a packing for liquid chromatography, particularly reversed phase partition chromatography. This hydrophobic crosslinked copolymer can be advantageously produced by a method in which a crosslinked copolymer having a side chain of small length is first produced, and then a substitution reaction to introduce a hydrophobic group of large length is effected with respect to the side chain of small length.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: January 29, 1991
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Takateru Uchida
  • Patent number: 4980436
    Abstract: A thermosetting resin composition comprising (i) a polymaleimide compound having at least two maleimide groups in the molecule and (ii) an s-triazine compound having at least two alkenylaryloxy groups in the molecule; a resin-composition for encapsulant comprising said polymaleimide compound, said triazine compound, and an inorganic filler as essential components; and said s-triazine compound.
    Type: Grant
    Filed: January 12, 1990
    Date of Patent: December 25, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuhisa Saito, Kunimasa Kamio, Shuichi Kanagawa, Yutaka Shiomi
  • Patent number: 4977197
    Abstract: A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing at least one carboxylic acid monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOY group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOZ group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.3 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and each of X, Y and Z is a hydrogen atom, NH.sub.4 or an alkali metal atom; or the formula: ##STR2## wherein each of R.sub.4 and R.sub.5 is a hydrogen atom, a C.sub.1 -C.sub.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: December 11, 1990
    Assignee: Mitsubishi Rayon Company Limited
    Inventors: Isao Sasaki, Nobuhiro Mukai, Hitoshi Ige
  • Patent number: 4973635
    Abstract: New compositions, useful as viscosity additives, having dispersing properties in various hydrocarbon oils, are disclosed, which comprise:recurrent units derived from one or more acrylic or methacrylic esters (e.g. 55-99.8% by weight),recurrent units derived from one or more nitrogenous vinyl monomers obtained by reacting triallylcyanurate with aliphatic amines or polyamines (e.g. 0.2-10% by weight), and optionallyrecurrent units derived from one or more vinyl aromatic monomers (e.g. 0-35% by weight).These copolymer compositions generally have a weight average molecular weight from 30,000 to 800,000 and a polydispersity generally lower than 5. They can be prepared by any radical copolymerization process using for example azoic or peroxydic initiators.The copolymer compositions considered are used as additives for improving the rheological properties of hydrocarbon oils. In addition, they exhibit good dispersing properties.
    Type: Grant
    Filed: December 15, 1988
    Date of Patent: November 27, 1990
    Assignee: Institut Francais du Petrole
    Inventors: Jacques Jarrin, Magali Robine, Jean-Pierre Durand
  • Patent number: 4962163
    Abstract: Thermosettable vinyl ester compositions are prepared from an advanced epoxy resin containing a mesogenic or rodlike moiety and a monounsaturated monocarboxylic acid and, optionally, a monoepoxide compound. These vinyl ester compounds can be mixed with polymerizable ethylenically unsaturated monomers which can, if desired, contain a mesogenic or rigid rodlike moiety.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: October 9, 1990
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls, Paul M. Puckett
  • Patent number: 4962168
    Abstract: A flame-retardant TAIC is polymerized in the presence of a polymerization modifier and a polymerization initiator. As the polymerization modifier, 6H-dibenz [c,e] [1,2] oxaphosphorine-6-oxide is used in an amount of 1 to 200% by weight on the basis on the weight of triallyl isocyanurate.
    Type: Grant
    Filed: January 2, 1990
    Date of Patent: October 9, 1990
    Assignee: 501 Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Satoshi Hiratsuna, Hiroshi Hotta, Hayashi Tomomi, Hayashi Tomomi
  • Patent number: 4959431
    Abstract: An optical material formed of a copolymer is disclosed. The copolymer is obtained by polymerizing a monomer composition composed of a particular N-substituted trifunctional monomer having a triazine ring structure and a monomer copolymerizable with the isocyanurate. Where the copolymerizable monomer is a specific aliphatic bifunctional monomer, the monomer composition additionally contains a further monomer which is copolymerizable with the aforementioned components and contains at least one ethylenically-unsaturated group.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: September 25, 1990
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Nobuhiro Watanabe, Teruo Sakagami
  • Patent number: 4948854
    Abstract: A transparent optical article is constituted of an optical resin. The optical resin in obtained by polymerizing a feed monomer containing at least a diester of unsaturated dicarboxylic acid selected from the group consisting of itaconic acid, citraconic acid and mesaconic acid. The ester group forming the diester is ##STR1## or R, wherein X represents a halogen atom, m represents zero or an integer of 1 to 5 and R represents an alkyl group having 1 to 12 carbon atoms, an alkenyl group having 1 to 12 carbon atoms or a cycloalkyl group having 3 to 12 carbon atoms. At least one of the ester groups has an aromatic ring defined above.
    Type: Grant
    Filed: October 3, 1989
    Date of Patent: August 14, 1990
    Inventors: Naoyuki Amaya, Keizo Anan, Yoshishige Murata, Takao Mogami, Yoshio Sano, Haruhiro Ikebe, Rumiko Seita
  • Patent number: 4939220
    Abstract: Adhesive compositions having a Tg of -45.degree. to -25.degree. C. suitable for application to plasticized polyvinyl chloride comprising 25 to 40% by weight of an vinyl ester of a alkanoic acid; 10-30% by weight ethylene; 20 to 30% by weight of di-2-ethylhexyl maleate or fumarate; 20 to 30% by weight of 2-ethylhexyl acrylate; and 1 to 10% by weight of a mono-carboxylic acid.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: July 3, 1990
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Paul R. Mudge
  • Patent number: 4933376
    Abstract: A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing a sulfonic acid or sulfonate monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.20 alkyl group, a phenyl group or a derivative thereof, or a halogen atom; ##STR2## wherein each of R.sub.2 and R.sub.3 is a hydrogen atom or a C.sub.1 -C.sub.15 alkyl group, R.sub.4 is a C.sub.1 -C.sub.15 alkylene group, m is an integer of from 1 to 20 and n is an integer of from 0 to 20; and Y is a hydrogen atom, NH.sub.4 or an alkali metal atom, and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein X is ##STR4## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.
    Type: Grant
    Filed: April 22, 1988
    Date of Patent: June 12, 1990
    Assignee: Mitsubishi Rayon Company Limited
    Inventors: Isao Sasaki, Nobuhiro Mukai, Hitoshi Ige
  • Patent number: 4927431
    Abstract: An abrasive product comprising abrasive grains bonded to at least one major surface of a backing sheet by a binder formed from a blend comprising radiation curable monomer and a thermally curable resinous material. The radiation curable monomer can be selected from the group consisting of isocyanurate derivatives having at least one terminal or pendant acrylate group, isocyanate derivatives having at least one terminal or pendant acrylate group, and multifunctional acrylate monomers. The thermally curable resinous material is preferably a member selected from the group consisting of phenolic resins, urea-formaldehyde resins, melamine-formaldehyde resins, and epoxy resins. The binder can be used to form the make coat, size coat, both make and size coats, or as a backing treatment for a coated abrasive product. The binder can also be used in fibrous nonwoven abrasive products. The binder can also be used in embodiments where only a single-coat binder is employed.
    Type: Grant
    Filed: September 8, 1988
    Date of Patent: May 22, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Scott Buchanan, Eric G. Larson, Jon R. Pieper, Thomas E. Boettcher
  • Patent number: 4882404
    Abstract: New compositions, useful as viscosity additives, having dispersing properties in various hydrocarbon oils, are disclosed, which comprise:recurrent units derived from one or more acrylic or methacrylic esters (e.g. 55-99.8% by weight),recurrent units derived from one or more nitrogenous vinyl monomers obtained by reacting triallylcyanurate with aliphatic amines or polyamines (e.g. 0.2-10% by weight), and optionallyrecurrent units derived from one or more vinyl aromatic monomers (e.g. 0-35% by weight).These copolymer compositions generally have a weight average molecular weight from 30,000 to 800,000 and a polydispersity generally lower than 5. They can be prepared by any radical copolymerization process using for example azoic or peroxydic initiators.The copolymer compositions considered are used as additives for improving the rheological properties of hydrocarbon oils. in addition, they exhibit good dispersing properties.
    Type: Grant
    Filed: June 12, 1987
    Date of Patent: November 21, 1989
    Assignee: Institut Francais du Petrole
    Inventors: Jacques Jarrin, Magali Robine, Jean-Pierre Durand
  • Patent number: 4855334
    Abstract: A curable resin composition comprising an isocyanuric ring-containing urethane-modified radical-polymerizable compound. The composition can give a protective coating having excellent surface mar resistance and improved secondary adhesion.
    Type: Grant
    Filed: June 3, 1985
    Date of Patent: August 8, 1989
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Osamu Maruyama, Hidenobu Ishikawa, Nobuo Takahashi
  • Patent number: 4855374
    Abstract: According to the invention, there are provided an optical resin and a process for preparing such a resin. The optical resin is obtained by polymerizing a feed monomer comprising at least a diester of dicarboxylic acid represented by the general formula (1) of: ##STR1## wherein R.sub.1 and R.sub.2 each represent the same or different groups and stand for an alkyl or alkenyl group having 1 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms or an ester residue having at least one aromatic ring.
    Type: Grant
    Filed: June 22, 1988
    Date of Patent: August 8, 1989
    Assignee: Nippon Oil and Fats Co., Ltd.
    Inventors: Yoshishige Murata, Yasumi Koinuma, Naoyuki Amaya, Takayuki Otsu, Masafumi Nisimura
  • Patent number: 4853438
    Abstract: Disclosed are new copolymers which are useful as adhesion mediating agents. The copolymers of the invention are prepared by the copolymerization of vinyl silanes, vinyl esters of alpha-halogen fatty acids and fatty acid vinyl esters, which are then reacted with tertiary amines. The new polymers are soluble in water and in such solutions they can be used as adhesion mediating agents between silicatic and other materials and polymers.
    Type: Grant
    Filed: January 7, 1988
    Date of Patent: August 1, 1989
    Inventors: Gunther Bernhardt, Horst Hanisch
  • Patent number: 4829139
    Abstract: Permanently tacky pressure sensitive adhesives comprise terpolymers consisting essentially of 35-50% by weight of a vinyl ester of an alkanoic acid, 15-30% by weight ethylene and 35-50% by weight of di-2-ethylhexyl maleate or the corresponding fumarate.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: May 9, 1989
    Assignee: National Starch and Chemical Corporation
    Inventor: Paul R. Mudge
  • Patent number: 4826938
    Abstract: Permanently tacky pressure sensitive adhesives comprise terpolymers consisting essentially of 35-50% by weight of a vinyl ester of an alkanoic acid, 15-30% by weight ethylene and 35-50% by weight of di-2-ethylhexyl maleate or the corresponding fumarate.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: May 2, 1989
    Assignee: National Starch and Chemical Corporation
    Inventor: Paul R. Mudge
  • Patent number: 4820607
    Abstract: A photosolubilizable composition containing (a) a first compound capable of producing an acid by irradiation with actinic rays and (b) a high molecular weight compound, whose solubility in a developing solution is increased by the action of an acid, and a photosolubilizable composition containing (c) a high molecular weight compound whose solubility in a developing solution is increased by irradiation with actinic radiation, are disclosed. These compositions exhibit high photosensitivity, broad development latitude, and high stability with time.
    Type: Grant
    Filed: August 14, 1986
    Date of Patent: April 11, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiaki Aoai
  • Patent number: 4812545
    Abstract: Substitutes for optical glasses are obtained by submitting to polymerization, in the presence of a free-radical initiator and in bulk, a polymerizable liquid composition containing:a monomer of diethyleneglycol bis(allylcarbonate);oligomers of diethyleneglycol bis(alllycarbonate);a monomer of tris(hydroxyethyl)isocyanurate tris(allylcarbonate); andat least one free-radical initiator.
    Type: Grant
    Filed: May 15, 1986
    Date of Patent: March 14, 1989
    Assignee: Enichem Sintesi S.p.A.
    Inventors: Fiorenzo Renzi, Franco Rivetti, Ugo Romano, Claudio Gagliardi
  • Patent number: 4812547
    Abstract: Permanently tacky pressure sensitive adhesives comprise terpolymers consisting essentially of 35-50% by weight of a vinyl ester of an alkanoic acid, 15-30% by weight ethylene and 35-50% by weight of di-2-ethylhexyl maleate or di-n-octyl maleate or a corresponding fumerate.
    Type: Grant
    Filed: December 11, 1985
    Date of Patent: March 14, 1989
    Assignee: National Starch & Chemical Corp.
    Inventor: Paul R. Mudge
  • Patent number: 4806607
    Abstract: Disclosed are nadimido-substituted cyclophosphazene derivatives and thermosets thereof. The thermosets are useful as high temperature, flame resistant matrices for composites and as metal adhesives.
    Type: Grant
    Filed: February 11, 1988
    Date of Patent: February 21, 1989
    Assignee: Hercules Incorporated
    Inventor: Alexander Lukacs, III
  • Patent number: 4806606
    Abstract: Disclosed are nadimido-substituted cyclophosphazene derivatives and thermosets thereof. The thermosets are useful as high temperature, flame resistant matrices for composites and as metal adhesives.
    Type: Grant
    Filed: February 16, 1988
    Date of Patent: February 21, 1989
    Assignee: Hercules Incorporated
    Inventor: Alexander Lukacs, III
  • Patent number: 4803254
    Abstract: Vinylsilylalkoxy arylbenzotriazol monomers such as 2-[3'-t-butyl-5'-(3-"-dimethylvinylsilylpropoxy)-2'-hydroxy-phenyl]-5-meth oxybenzotriazole are disclosed. These monomers can be incorporated in optically clear silicone polymers to form intraocular lenses, contact lenses, and the like, which have UV absorbing properties.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: February 7, 1989
    Assignee: Iolab Corporation
    Inventors: Gary B. Dunks, Akira Yamada, Namassivaya Doddi, Charles D. Beard
  • Patent number: 4791183
    Abstract: Disclosed herein is a new monomer as represented by the following formula (1): ##STR1## wherein R.sub.1 is hydrogen or a C.sub.1-10 hydrocarbon group, particularly a hydrogen atom, a methyl group or an ethyl group; and X.sub.1 and X.sub.2 are halogen atoms, particularly bromine atoms.This new monomer is produced by reacting divinylbenzene or a substituted product thereof with a halogenating agent in which halogen molecules are inactivated, or halogen molecule under specific reaction conditions.Also disclosed herein is a linear or crosslinked polymer produced from the monomer, as well as method of producing such polymers. The polymers are very useful in the preparation of functional polymers such as those having a chelating ability.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: December 13, 1988
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Takafumi Yamamizu
  • Patent number: 4785064
    Abstract: Inherently highly abrasion-resistant cast articles are prepared by polymerizing a composition comprising (I) as a first component from 0 to 100 parts of urethane polyacrylic ester and (II) as a second component, correspondingly from 100 to 0 parts of a composition containing (A) 30 to 60% by weight of a polyacrylic ester having 4 to 10 acryloyloxy groups, (B) 20 to 70% by weight of a polymerization shrinkage modifier, and (C) 0 to 30% of a diluent monomer. A source of free-radicals may be added to the composition.
    Type: Grant
    Filed: November 3, 1986
    Date of Patent: November 15, 1988
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Ramon F. Hegel
  • Patent number: 4772635
    Abstract: The invention relates to new bead-shaped crosslinked macroporous copolymers containing epoxide groups and basic amino groups, which are obtainable by reacting polymerizable glycidyl compounds, before or during free radical bead polymerization, which is carried out in the presence of agents which impart porosity and, if appropriate, with the addition of polyvinyl compounds which can be polymerized by free radical polymerization, with amines which are capable of reacting with at least two epoxide groups, a process for their preparation and their use, for example, for binding biologically active substances, for the preparation of strongly basic anion exchangers and hydrophilic chromatography resins for biomaterials.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: September 20, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alfred Mitschker, Peter M. Lange, Wolfgang Kreiss
  • Patent number: 4771112
    Abstract: Oligomeric and prepolymeric organic compounds with aldehyde, epoxide, isocyanate, or halotriazine groups and polymerizable groups. Compounds of this type and mixtures thereof have outstanding adhesion properties, especially in relation to biological substrates, can be copolymerized with composites based on unsaturated monomers, and are especially appropriate in dentistry and medicine as adhesion promoters, adhesive fillers, or adhesive cement.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: September 13, 1988
    Assignee: Ernst Muhlbauer KG
    Inventor: Jurgen Engelbrecht
  • Patent number: 4769432
    Abstract: The methyl chloride or dimethyl sulfate quaternary ammonium salt of 1-acryloyl-4-methyl piperazine and polymers thereof.
    Type: Grant
    Filed: December 3, 1986
    Date of Patent: September 6, 1988
    Assignee: Nalco Chemical Company
    Inventor: Dodd W. Fong
  • Patent number: 4752641
    Abstract: A thermosetting resin composition comprising (a) a polyfunctional maleimide, (b) at least one member selected from the group consisting of alkenylphenols and alkenylphenol ethers, and (c) an allyl ester of polyvalent carboxylic acid, or cyanuric or isocyanuric acid and a prepolymer obtained by preliminarily heating the thermosetting resin composition can be used as a solventless type varnish for impregnating, e.g. electric windings, or for preparing a prepreg, and can give a cured product with heating at 120.degree.-250.degree. C. having excellent heat resistance of class C (180.degree. C. or higher) and electrical insulating properties.
    Type: Grant
    Filed: April 24, 1987
    Date of Patent: June 21, 1988
    Assignee: Hitachi, Ltd.
    Inventors: Toru Koyama, Hiroko Ohayashi, Junichi Katagiri, Motoyo Wajima, Junji Mukai
  • Patent number: 4719248
    Abstract: Novel ultraviolet absorbing compounds useful in contact lenses and methods for curing contact lenses containing UV absorbers are disclosed.
    Type: Grant
    Filed: August 8, 1985
    Date of Patent: January 12, 1988
    Assignee: Bausch & Lomb Incorporated
    Inventors: Ronald E. Bambury, Joon S. Park, Dong J. Choo
  • Patent number: 4716209
    Abstract: An essentially isocyanate-free polyurethane polyurea polyethylenic oligomer is disclosed which is unusually strong and elastic. This oligomer is the reaction product of: (1) organic diisocyanate; (2) a stoichiometric deficiency of difunctional materials reactive therewith and consisting essentially of: (A) diol component selected from polycarbonate diol and polyoxyalkylene glycol, this diol component having a molecular weight of from 200 to 2000; (B) dihydric bisphenol-based alkylene oxide adduct containing from 2-10 alkylene groups per molecule; and (C) a diprimary diamine component selected from alkylene diamine and polyoxyalkylene diamine, this diamine component having a molecular weight of from about 70 to 800. Components (A) and (B) are present in a weight ratio of from 1:4 to 9:1 and component (C) is present to supply from 30 to 60 equivalent percent of the total equivalents of component (2).
    Type: Grant
    Filed: January 23, 1986
    Date of Patent: December 29, 1987
    Assignee: DeSoto, Inc.
    Inventors: Steven R. Schmid, Robert E. Ansel, Kevin P. Murray
  • Patent number: 4686268
    Abstract: Copolymers of average molecular weight within the range from about 1,000 to about 50,000, preferably from about 1,000 to about 10,000, are provided containing the repeating polymeric unit having the formula (I) and the repeating polymeric unit having the formula (II): ##STR1##
    Type: Grant
    Filed: June 11, 1986
    Date of Patent: August 11, 1987
    Assignee: Morisawa & Co., Ltd.
    Inventor: Seoh Won Kang
  • Patent number: 4680356
    Abstract: Essentially colorless, hydrophilic ligand-releasing polymers are prepared from ethylenically unsaturated polymerizable monomers represented by the structure: ##STR1## wherein R' is hydrogen or lower alkyl, COUP is a photographic color coupling moiety, LINK is a coupling-off group which can be cleaved by an oxidized developer composition, and LIG is a ligand capable of complexing with metal ions, while joined to the polymer, to form a dye. These polymers also have recurring units which impart hydrophilicity to the polymer. These polymers form metal complex dyes in unexposed areas of photographic elements only, while the ligand is cleaved from the polymer in the exposed areas and washed out of the element.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: July 14, 1987
    Assignee: Eastman Kodak Company
    Inventors: William N. Washburn, Kenneth R. Hollister
  • Patent number: 4678849
    Abstract: Heat-curable mixtures comprising(a) at least one compound of the formula ##STR1## (b) at least one compound of the formula ##STR2## (c) at least one alkenyl phenol or alkenyl phenol ether, and (d) triallylisocyanurate, said mixtures being suitable for the preparation of molded articles such as prepregs and composites, coatings and the like.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: July 7, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Marie W. Liu, Victor Ho
  • Patent number: 4652274
    Abstract: A coated abrasive product comprising abrasive granules adherently bonded to at least one major surface of a backing sheet by a radiation curable resinous binder material. The binder material can be used to form the make coat, size coat, or both coats. Alternatively, the binder material can be used in embodiments where only a single binder coat is employed. The radiation curable resinous binder material comprises a copolymer formed from a mixture comprising (1) at least one monomer selected from the group consisting of isocyanurate derivatives having at least one terminal or pendant acrylate group and isocyanate derivatives having at least one terminal or pendant acrylate group, and (2) at least one aliphatic or cycloaliphatic monomer having at least one terminal or pendant acrylate group.
    Type: Grant
    Filed: August 7, 1985
    Date of Patent: March 24, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Thomas E. Boettcher, Victor P. Thalacker
  • Patent number: 4650845
    Abstract: Inherently highly abrasion-resistant cast articles are prepared by polymerizing a composition comprising (I) as a first component from 0 to 100 parts of urethane polyacrylic ester and (II) as a second component, correspondingly from 100 to 0 parts of a composition containing (A) 30 to 60% by weight of a polyacrylic ester having 4 to 10 acryloyloxy groups, (B) 20 to 70% by weight of a polymerization shrinkage modifier, and (C) 0 to 30% of a diluent monomer. A source of free-radicals may be added to the composition.
    Type: Grant
    Filed: July 10, 1984
    Date of Patent: March 17, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Ramon F. Hegel
  • Patent number: 4644025
    Abstract: Compositions each comprising a copolymer of a specific allylic or (meth)acrylic compound of an iodine-substituted benzoic acid derivative and a comonomer have a refractive index n.sub.D.sup.20 of at least 1.58 and an Abbe's number of at least 28 and are excellent starting materials for the production of high quality lenses.
    Type: Grant
    Filed: June 19, 1985
    Date of Patent: February 17, 1987
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Teruo Sakagami, Yasufumi Fujii, Naohiro Murayama
  • Patent number: 4607068
    Abstract: Radiation curable coating compositions, and especially electron beam-curable coating compositions, are disclosed in which magnetizable particles are dispersed in a liquid vehicle comprising a polyethylenically unsaturated polyurethane oligomer which includes a polycarbonate diol, and from 5% to 50%, based on the total weight of unsaturated material, of a polyethylenically unsaturated isocyanurate, such as a triacrylate of tris(2-hydroxyethyl) isocyanurate.
    Type: Grant
    Filed: June 3, 1985
    Date of Patent: August 19, 1986
    Assignee: DeSoto, Inc.
    Inventor: Robert E. Ansel