Three Or More Nitrogen Atoms In A Single Ring Patents (Class 526/261)
  • Patent number: 4599389
    Abstract: Photographic elements and diffusion transfer assemblages described which contain a novel mordant comprising a polymeric backbone having appended thereto nitrogen-coordinating ligands having the formula: ##STR1## wherein D.sup.1, D.sup.2, and D.sup.3 each independently represents the atoms necessary to complete an aromatic heterocyclic nucleus having at least one ring of 5 to 7 atoms.In a preferred embodiment, the mordant comprises recurring units having the formula: ##STR2## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen or an alkyl or substituted alkyl group having from 1 to about 6 carbon atoms;Link represents a bivalent linking group; andLIG represents a nitrogen-coordinating ligand as described above.
    Type: Grant
    Filed: October 24, 1985
    Date of Patent: July 8, 1986
    Assignee: Eastman Kodak Company
    Inventors: James A. Reczek, Ignazio S. Ponticello, Philip S. Bryan
  • Patent number: 4576973
    Abstract: The crosslinked, porous copolymer in the form of beads and containing 50 to 99.9% by weight of recurring units of a heterocyclic 5-membered ring compound which contains a polymerizable olefinic group and which has at least one protonizable nitrogen atom in the ring, 0.1 to 50% by weight of units of a crosslinking agent, 0 to 25% by weight of units of a polymerizable organoboron or organosilicon compound and, relative to 100% by weight of the sum of the abovementioned units, 5 to 350% by weight of units of an N-vinylamide of the general formula I CH.sub.2 .dbd.CH--N(R.sup.1)--C(R.sup.2).dbd.O wherein R.sup.1 denotes hydrogen, methyl or ethyl and R.sup.2 denotes hydrogen or C.sub.1 -C.sub.3 -alkyl, or several such N-vinylamides and 0 to 40% by weight of units of another polymerizable compound or several such compounds, is prepared by inverted suspension polymerization and is used, for example, as a sorbent for acid substances from solutions thereof, preferably aqueous solutions.
    Type: Grant
    Filed: June 22, 1984
    Date of Patent: March 18, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl-Heinz Keil, Fritz Engelhardt, Ulrich Greiner, Klaus Kuhlein, Reinhold Keller, Merten Schlingmann, Gerhard Hess
  • Patent number: 4540728
    Abstract: Polymers of diallyl-1,3,5-triazino-4-(2,2,6,6-tetramethyl piperidyl) amines are provided, having a molecular weight within the range from about 800 to about 20,000, and derived from the monomer: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen; oxyl; alkyl and hydroxyalkyl having from one to about eighteen carbon atoms; alkylaryl having from seven to about eighteen carbon atoms; epoxy alkyl having from three to about eighteen carbon atoms; and acyl having from two to about eighteen carbon atoms;Y is selected from the group consisting of ##STR2## where R.sub.2 and R.sub.3 are hydrogen or alkyl having from one to about eight carbon atoms and n is 0 or 1;Z is selected from the group consisting of ##STR3## in which R.sub.4, R.sub.5 and R.sub.
    Type: Grant
    Filed: September 9, 1983
    Date of Patent: September 10, 1985
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Yutaka Nakahara, Ryoji Kimura
  • Patent number: 4533678
    Abstract: Novel benzimidazolyl compounds which are basic compounds and have high polymerizability are disclosed. The basic compound of the present invention is prepared by reacting a vinylbenzaldehyde with an o-phenylenediamine compound, and can be used, for example, as a monomer for polymers. The benzimidazolylstyrene compounds are readily homopolymerized or copolymerized to provide linear homopolymers, linear copolymers or cross-linked copolymers having pendant benzimidazolylphenyl groups. These polymers have greater resistance to oxidation and chemicals than the homologues, and are useful as ion exchange resins, and as extractants of metals.
    Type: Grant
    Filed: March 13, 1984
    Date of Patent: August 6, 1985
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Kunihiko Takeda
  • Patent number: 4526920
    Abstract: In a curable coating composition comprising an acryloyl or methacryloyl cyanurate or isocyanurate compound, an acrylic or methacrylic ester compound and a polymerization initiator capable of curing said components; the improvement wherein said composition is composed of(A) 100 parts by weight of an acryloyl- or methacryloyl-oxyalkyl cyanurate or isocyanurate compound of the following formula (I) or (I)' ##STR1## wherein X.sup.1, X.sup.2, X.sup.3, R.sup.1, R.sup.2 and R.sup.3 are defined in claim 1(B) more than 0 to 1,000 parts by weight of a component selected from the group consisting of (b.sub.1) a polyacrylate or polymethacrylate with a number average molecular weight of about 240 to about 3,000 of an oxy- or polyoxy-alkanepolyol containing 1 or more ether linkages and 3 or more hydroxyl groups per molecule, and (b.sub.2) a poly(meth)acrylate of an alkanepolyol having 4 or more hydroxyl groups per molecule.(C) 0.
    Type: Grant
    Filed: August 2, 1983
    Date of Patent: July 2, 1985
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takeshi Sakashita, Hajime Inagaki, Akira Todo, Takayuki Nakano
  • Patent number: 4521577
    Abstract: A polymerizable liquid composition is disclosed, intended for preparing polymerizates having outstanding optical and physical properties, said composition consisting of a bis (allylcarbonate) of a dihydric alcohol oligomer, a bis (allylcarbonate) monomer of a dihydric or a trihydric alcohol, or an allyl ester, or a triallyl cyanurate or isocyanurate, and an acrylic or vinylic monomer, said composition being polymerized in bulk with the aid of at least one radicalic initiator. Highly transparent articles are obtained, which are very useful for fine optical applications.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: June 4, 1985
    Assignee: Enichimica S.p.A.
    Inventors: Ugo Romano, Fiorenzo Renzi, Franco Rivetti, Claudio Gagliardi
  • Patent number: 4515934
    Abstract: Vinyl ester resin compositions containing triazine groups or both triazine and oxazoline groups are prepared by reacting (a) a polyepoxide containing triazine groups, or (b) a polyepoxide containing both triazine and oxazoline groups, or (c) a mixture of (a) and (b) above with (d) about 0.75 to about 1, preferably from about 0.9 to about 1, moles of a monounsaturated monocarboxylic acid or mixture of monounsaturated monocarboxylic acids per epoxide group in the presence of (e) a suitable quantity of a suitable catalyst.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: May 7, 1985
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4497951
    Abstract: Acetylene terminated s-triazine oligomers are disclosed which polymerize into stable high temperature resins. The oligomers of this invention are readily prepared from off-the-shelf starting materials, they are soluble in conventional low boiling solvents and exhibit low melting points which facilitate ease of processing.
    Type: Grant
    Filed: April 21, 1983
    Date of Patent: February 5, 1985
    Assignee: Hughes Aircraft Company
    Inventor: Thomas W. Giants
  • Patent number: 4492776
    Abstract: A process is disclosed for the preparation of hydrogel contact lenses having improved mechanical properties, said process comprising polymerizing, in the presence of an azo type initiator, a monomer mixture comprising from 25% to 50% by weight of N-vinyl pyrrolidone, up to 5% by weight of methacrylic or acrylic acid, 0.1 to 1% by weight of 1,3,5-tris(propenoxy)-2,4,6-triazine (TPT), or perhydro-2,4,6,-triketo-1,3,5,-tris (propene-2)-1,3,5-triazine (T.T.P.T.), as a cross-linking monomer, the balance being essentially hydroxy alkyl acrylate or methacrylate, wherein the alkyl group is ethyl or propyl.
    Type: Grant
    Filed: April 12, 1984
    Date of Patent: January 8, 1985
    Assignee: CooperVision, Inc.
    Inventors: Ivor B. Atkinson, Barry C. Holdstock
  • Patent number: 4463147
    Abstract: A mixture consisting of a polymaleimide and a copolymerizable monomer or a prepolymer formed from these two compounds contains, as the polymerization catalyst, an ethane which is substituted by aromatic groups and hydroxyl groups or halogen (cf. formula II), such as benzpinacol. The mixture is stable on storage and heat-curable. It can be cured, while at the same time being shaped to give mouldings, sheet-like structures, laminates, adhesive bonds or foams, for example by casting or compression moulding.
    Type: Grant
    Filed: December 13, 1982
    Date of Patent: July 31, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann Diethelm, Abdul-Cader Zahir
  • Patent number: 4463169
    Abstract: Polymerizable compositions comprise(a) a compound containing(i) at least one acryloyloxy or methacryloyloxy group,(ii) at least one allyl, methallyl, or 1-propenyl group attached, either directly, or through an oxygen atom or an oxycarbonyl group, to a carbon atom which forms part of an aromatic or cycloaliphatic nucleus,(b) a compound containing in the molecule both(iii) at least one acryloyloxy or methacryloyloxy group and(iv) at least one --COOH group, and(c) a compound containing at least two mercaptan groups directly attached to aliphatic carbon atoms.Examples of (a) are 2,2-bis(3-allyl-4-(3-(methacryloyloxy)-2-(2-carboxyethylcarbonyloxy)propox y)phenyl)propane, 1-(allyloxycarbonyl)-2,4-bis(3-(methacryloyloxy)-2-(2-carboxyethylcarbonyl oxy)propoxycarbonyl)benzene, and diallyl bis(3-methacryloyloxy)-2-(2-carboxyethylcarbonyloxy)propyl) esters of benzophenone-3,4,3',4'-tetracarboxylic acid. Examples of (b) are acrylic acid and 2-(methacryloyloxy)ethyl 5-carboxycyclohex-1-ene-4-carboxylate.
    Type: Grant
    Filed: September 13, 1982
    Date of Patent: July 31, 1984
    Assignee: Ciba-Geigy Corporation
    Inventor: Edward Irving
  • Patent number: 4463080
    Abstract: Photographic elements and diffusion transfer assemblages are described which contain a novel polymeric mordant comprising recurring units having the formula ##STR1## wherein A represents recurring units derived from an .alpha.,.beta.-ethylenically unsaturated monomer;B represents recurring units derived from a monomer containing at least two ethylenically unsaturated groups;QN.sup..sym. represents a moiety containing a quaternized nitrogen group;R.sup.1 represents an alkoxy group having from 1 to about 8 carbon atoms or an alkylenedioxy group having from 1 to about 4 carbon atoms, the group being appended to an aromatic group of A;R.sup.2 represents an alkoxy group having from 1 to about 8 carbon atoms or an alkylenedioxy group having from 1 to about 4 carbon atoms, the group being appended to an aromatic group of QN.sup..sym.
    Type: Grant
    Filed: July 6, 1983
    Date of Patent: July 31, 1984
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Snow, Gerald W. Klein
  • Patent number: 4451630
    Abstract: A process is disclosed for the preparation of hydrogel contact lenses having improved mechanical properties, said process comprising polymerizing, in the presence of an azo type initiator, a monomer mixture comprising from 25% to 50% by weight of N-vinyl pyrrolidone, up to 5% by weight of methacrylic or acrylic acid, 0.1 to 1% by weight of 1,3,5-tris(propenoxy)-2,4,6-triazine (TPT), or perhydro-2,4,6,-triketo-1,3,5,-tris (propene-2)- 1,3,5 - triazine (T.T.P.T.), as a cross-linking monomer, the balance being essentially hydroxy alkyl acrylate or methacrylate, wherein the alkyl group is ethyl or propyl.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: May 29, 1984
    Inventors: Ivor B. Atkinson, Barry C. Holdstock
  • Patent number: 4443366
    Abstract: A mixture of water-soluble substances, particularly a mixture of proteins, a mixture of enzymes or a mixture of water-soluble vitamins, is fractionated by subjecting an aqueous solution of said mixture of water-soluble substances to gel chromatography through a filter bed of a cross-linked gel copolymer of vinylpyrrolidone and a cross-linking agent having a triazine ring system of the formula (I) or (II): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are the same or different and each radical is selected from the group consisting of --CH.sub.2 --CH.dbd.CH.sub.2, --CH.sub.2 --C.tbd.CH and --CH.sub.2 --C(CH).sub.2, in a diluent.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: April 17, 1984
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Teruo Sakagami, Noriyuki Arakawa, Naohiro Murayama
  • Patent number: 4443495
    Abstract: This invention relates to a heat curing process and to a solventless screen printable, heat curable conductive ink composition comprising(1) an ethylenically unsaturated member of the group consisting of(a) a liquid, ethylenically, unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(b) a polythiol in combination with (a) supra,(c) a polythiol in combination with a liquid ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR2## wherein R.sub.2 is H or CH.sub.3, R.sub.3 is an organic moiety and n is at least 2, and(d) mixtures of (a), (b) and (c),(2) a thermal initiator, and(3) an electrically conductive material.Heating of the composition in a desired pattern on a substrate results in a printed electric circuit.
    Type: Grant
    Filed: May 5, 1983
    Date of Patent: April 17, 1984
    Assignee: W. R. Grace & Co.
    Inventors: Charles R. Morgan, Arthur D. Ketley
  • Patent number: 4442278
    Abstract: Acetylene terminated s-triazine oligomers are disclosed which polymerize into stable high temperature resins. The oligomers of this invention are readily prepared from off-the-shelf starting materials, they are soluble in conventional low boiling solvents and exhibit low melting points which facilitate ease of processing.
    Type: Grant
    Filed: December 3, 1981
    Date of Patent: April 10, 1984
    Assignee: Hughes Aircraft Company
    Inventor: Thomas W. Giants
  • Patent number: 4435555
    Abstract: Polymers based upon a monomer of the formula ##STR1## wherein R or R.sup.1 contain a polymerizable double bond are useful as ultraviolet light stabilizers for polymers.
    Type: Grant
    Filed: February 16, 1983
    Date of Patent: March 6, 1984
    Assignee: American Cyanamid Company
    Inventors: Frank F. Loffelman, Thomas E. Brady
  • Patent number: 4420597
    Abstract: This invention is directed to esters of isocyanuric acid derivatives. More particularly, this invention is directed to acrylates or methacrylates of isocyanuric acid derivatives containing hydroxyl groups, the preparation of said compounds, and their use in adhesives.
    Type: Grant
    Filed: September 29, 1981
    Date of Patent: December 13, 1983
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Werner Gruber
  • Patent number: 4418181
    Abstract: The compositions described herein comprise polyimides having bis-maleimide terminal groups and having the formula: ##STR1## wherein Q is a trivalent aromatic radical, Ar is a divalent aromatic radical, Ar" is a tetravalent aromatic radical and n has a value of 0-20. Derivatives may be made of these compounds by homopolymerization, copolymerization with other copolymerizable materials and by reaction with Diels-Alder reactable materials.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: November 29, 1983
    Assignee: Plastics Engineering Company
    Inventor: Walter J. Monacelli
  • Patent number: 4417043
    Abstract: A polymer capable of forming an anisotropic melt characterized in that the polymer chain includes residues of cross-linking reactants at a concentration sufficient to give a polymer with a melt viscosity of not greater than 10.sup.7 Nsec/m.sup.2 measured by capillary rheometry at a shear rate of 10.sup.4 N/m.sup.2. The polymers exhibit favorable shear dependent viscosity characteristics in that the viscosity is high under low shear conditions and is low under high shear conditions, as judged by the viscosity characteristics of polymers of the same composition but not containing the residues of cross-linking reactants.
    Type: Grant
    Filed: January 5, 1981
    Date of Patent: November 22, 1983
    Assignee: Imperial Chemical Industries PLC
    Inventors: Frederic N. Cogswell, Brian P. Griffin, Clive P. Smith
  • Patent number: 4406826
    Abstract: This invention relates to a heat curing process and to a solventless screen printable, heat curable conductive ink composition comprising(1) an ethylenically unsaturated member of the group consisting of(a) a liquid, ethylenically, unsaturated monomer, oligomer or prepolymer of the formula: ##STR1## wherein R is H or CH.sub.3, R.sub.1 is an organic moiety and n is at least 2,(b) a polythiol in combination with (a) supra,(c) a polythiol in combination with a liquid ethylenically unsaturated monomer, oligomer or prepolymer of the formula: ##STR2## wherein R.sub.2 is H or CH.sub.3, R.sub.3 is an organic moiety and n is at least 2, and(d) mixtures of (a), (b) and (c),(2) a thermal initiator, and(3) an electrically conductive material.Heating of the composition in a desired pattern on a substrate results in a printed electric circuit.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: September 27, 1983
    Assignee: W. R. Grace & Co.
    Inventors: Charles R. Morgan, Arthur D. Ketley
  • Patent number: 4393184
    Abstract: A lens having a high refractive index with a low dispersion produced by copolymerizing a polyfunctional allyl monomer with at least one monomer selected from the group represented by the general formula A: ##STR1## X: H, CH.sub.3, Cl Y: H, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, OCH.sub.3, C.sub.6 H.sub.11, Cl, Br, CH.sub.2 Cl, CH.sub.2 Br, C.sub.6 H.sub.5, CH.sub.2 C.sub.6 H.sub.5, SCH.sub.3m=0, 1, 2n=0, 1, 2, 3, 4, 5.This lens is excellent in its transmittance, pencil hardness, impact resistance, dyeability, coating adhesion, solvent resistance, workability, etc.
    Type: Grant
    Filed: October 26, 1981
    Date of Patent: July 12, 1983
    Assignee: Hoya Lens Corporation
    Inventors: Niro Tarumi, Shigeo Komiya, Mitsuo Sugimura
  • Patent number: 4373076
    Abstract: A high refractive lens of a terpolymer produced by the polymerization of ternary monomers comprising diethylene glycol bisallyl carbonate, triallylisocyanurate, and benzyl methacrylate. This lens is considerably improved in its physical properties necessary for lens such as superficial hardness, transmittance, and adhesion strength of glass film coated on the surface, as well as having a high refractive index.
    Type: Grant
    Filed: October 26, 1981
    Date of Patent: February 8, 1983
    Assignee: Hoya Lens Corporation
    Inventors: Niro Tarumi, Mitsuo Sugimura, Shigeo Komiya, Makoto Tsuchiya
  • Patent number: 4356287
    Abstract: Polymers of the following monomer ##STR1## wherein R and/or R.sup.1 contains a polymerizable double bond are disclosed as light stabilizers for polymers.
    Type: Grant
    Filed: July 20, 1981
    Date of Patent: October 26, 1982
    Assignee: American Cyanamid Company
    Inventors: Frank F. Loffelman, Thomas E. Brady
  • Patent number: 4348456
    Abstract: A thermoplastic resin film laminate. A thermoplastic film is made abrasion-resistant by coating or laminating (A) one or both sides of a thermoplastic resin film with (B) a vinyl polymer composed mainly of a cyanurate ring-containing (meth)cyanurate having a structure corresponding to the condensation product of 1 mole of cyanuric acid with 3 moles, on the average, of a hydroxyl group-containing (meth)acrylate represented by the formula C H.sub.2 .dbd.CR--COO--R.sup.10 --OH (wherein R is hydrogen atom or methyl group; and R.sup.10 is an alkylene group having a carbon number of 2 to 4), or a cyanurate ring-containing (meth)acrylate having a structure corresponding to the condensation product of 1 mole of cyanuric acid with 2 moles or more and less than 3 moles, on the average, of the above hydroxyl group-containing (meth)acrylate and not more than 0.5 mole, on the average, of a polyhydric alcohol of the formula R.sup.20 --(--OH).sub.y (wherein R.sup.
    Type: Grant
    Filed: December 17, 1980
    Date of Patent: September 7, 1982
    Assignee: Teijin Limited
    Inventors: Yoshihiko Imanaka, Yoichi Saito, Akihiro Horike
  • Patent number: 4336311
    Abstract: An electronic component is coated with an ultraviolet light cured composition to make it humidity and salt water resistant. The composition contains a urethane, at least one acrylate, a wet adhesion monomer, a photoinitiator, and optionally a thixotropic agent.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: June 22, 1982
    Assignee: Sprague Electric Company
    Inventor: Michael F. Lucey
  • Patent number: 4323662
    Abstract: Disclosed is a thermosetting resin composition comprising (a) a bismaleimide and/or a polymaleimide and (b) at least one member selected from alkenylaniline derivatives, linear dimers thereof, and polymers thereof. In addition to components (a) and (b), this resin composition can contain (c) a polymerizable unsaturated substance.
    Type: Grant
    Filed: July 8, 1980
    Date of Patent: April 6, 1982
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masayuki Oba, Motoo Kawamata, Hikotada Tsuboi, Nobuhito Koga
  • Patent number: 4316835
    Abstract: This invention involves a curable liquid mixture comprising (a) a polyester of the following formula: ##STR1## wherein n has an average value between about 1.
    Type: Grant
    Filed: April 16, 1980
    Date of Patent: February 23, 1982
    Assignee: Union Carbide Corporation
    Inventor: Hugh C. Gardner
  • Patent number: 4313859
    Abstract: The invention comprises a polymerizable liquid mixture of (a) a half ester characterized by the following empirical formula: ##STR1## wherein n is a number having an average value of about 1.5 to less than about 4, m is equal to the free valence of R less the average value of n, R is the hydroxyl-free residue of an organic polyol which contained from 2 to 4, inclusive, hydroxyl groups, OH, in formula (I) (b) maleic anhydride, (c) an epoxide containing two or more 1,2-epoxide radicals, (d) an ethylenically unsaturated monomer which forms a liquid homogeneous mixture with the half ester, maleic anhydride and epoxide, and (e) a basic compound.
    Type: Grant
    Filed: July 28, 1980
    Date of Patent: February 2, 1982
    Assignee: Union Carbide Corporation
    Inventor: Hugh C. Gardner
  • Patent number: 4297468
    Abstract: The invention relates to new cross-linked copolymers containing carboxyl groups and especially useful as thickening agents for aqueous and organic solvents, which copolymers contain(A) 20 to 100% by weight of olefinically unsaturated carboxylic acids,(B) 0 to 80% by weight of at least one mono-olefinically unsaturated monomer copolymerizable with the components A and C, and(C) 0.1 to 4% by weight, calculated on the total quantity of monomers, of allyl monomer of the general formula ##STR1## in which n=0, 1 or 2,m=1, 2 or 3, wherein n+m=3,R.sub.1 =hydrogen, or an alkyl, alkoxyalkyl, haloalkyl, cycloalkyl, aryl, alkaryl, aralkyl or alkenyl radical, andR.sub.2 and R.sub.3, which may be the same or different, each represents hydrogen or an allyl, alkyl, cycloalkyl, aryl, aralkyl or alkaryl radical,wherein at least two of the radicals R.sub.1, R.sub.2 and R.sub.3 must be an allyl radical or a substituted allyl radical.
    Type: Grant
    Filed: May 16, 1979
    Date of Patent: October 27, 1981
    Assignee: Chemische Fabrik Stockhausen & Cie
    Inventors: Miroslay Chmelir, Kurt Dahmen
  • Patent number: 4243788
    Abstract: Isocyanurate polymers having improved physical properties are disclosed. Unsaturated isocyanates are prepared by reacting a polyisocyanate with a monohydric alcohol containing a vinylidene group to form an isocyanate-containing urethane and then reacting the isocyanate-containing urethane with tris(2-hydroxyethyl)isocyanurate to form an unsaturated isocyanurate. The unsaturated isocyanurate may be homopolymerized or copolymerized with ethylenically unsaturated compounds to form isocyanurate polymers having an excellent combination of physical properties.
    Type: Grant
    Filed: January 29, 1979
    Date of Patent: January 6, 1981
    Assignee: ICI Americas Inc.
    Inventor: Erich Kuehn
  • Patent number: 4233430
    Abstract: An anti-solar polymer has in the macromolecular chain thereof at least one unit of the formula ##STR1## wherein F is a residue derived from an aromatic compound. The anti-solar polymer can also be one having in the macromolecular chain thereof at least one unit of the formula ##STR2## wherein F.sub.1 is ##STR3## These polymers have the ability to absorb wave lengths of light in the range of about 280-315 millimicrons. The polymers are employed in a cosmetic composition.
    Type: Grant
    Filed: May 1, 1979
    Date of Patent: November 11, 1980
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Christos Papantoniou, Pierre Dufaure, Claude Mahieu
  • Patent number: 4230550
    Abstract: A radiation curable barrier coating having chemical resistance to many solvents, flexibility when cured, selective gloss and excellent abrasion resistance at a coating thickness provided by lithographic printing methods comprises acrylated melamine resin in combination with silica fillers and photoinitiators.
    Type: Grant
    Filed: August 6, 1979
    Date of Patent: October 28, 1980
    Assignee: Hewlett-Packard Company
    Inventor: Kent D. Vincent
  • Patent number: 4225693
    Abstract: Controlled release pesticide-polymer systems are prepared by the polymerization of vinyl monomers containing pendant pesticides. The vinyl monomers are prepared by reacting an acrylic acid derivative with a pesticide or a pesticide derivative having an active hydrogen. The pesticide-polymer systems prepared from the pesticide vinyl monomers release the active pesticide material by hydrolysis or chemical depolymerization under conditions of use.
    Type: Grant
    Filed: August 10, 1978
    Date of Patent: September 30, 1980
    Inventor: Charles L. McCormick
  • Patent number: 4221895
    Abstract: Thermally resistant thermoset polymers are formed by heating a thermosetting aromatic prepolymer having at least two pendant alkynyl groups, e.g., a thermosetting prepolymer represented by the formula: ##STR1## The resulting thermoset polymers are sufficiently resistant to heat to be usefully employed as engine parts in the internal combustion engines of automobiles and the like.
    Type: Grant
    Filed: April 18, 1978
    Date of Patent: September 9, 1980
    Assignee: The Dow Chemical Company
    Inventor: Edmund P. Woo
  • Patent number: 4216134
    Abstract: Single component, shelf stable, anaerobic curing, adhesive compositions displaying high strength and resistance to water, heat and radiation are produced using triallylcyanurate or triallylisocyanurate as a reaction component.
    Type: Grant
    Filed: October 12, 1977
    Date of Patent: August 5, 1980
    Inventor: Walter Brenner
  • Patent number: 4203220
    Abstract: New alkenylamino dihalo triazines are used as bridging molecules to facilitate bonding of clinically tolerated acrylic and similar resins to biological tissue such as teeth and bone.
    Type: Grant
    Filed: July 8, 1976
    Date of Patent: May 20, 1980
    Assignee: National Research Development Corporation
    Inventor: Peter J. Cranfield
  • Patent number: 4200721
    Abstract: Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by:(1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of:(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2,(C.sub.6 H.sub.5 O).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2,(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 and(C.sub.6 H.sub.5)C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or(2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2.
    Type: Grant
    Filed: May 19, 1978
    Date of Patent: April 29, 1980
    Inventors: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Kazimiera J. L. Paciorek
  • Patent number: 4196271
    Abstract: An adhesive composition comprising a 2-cyanoacrylate and at least one member selected from the group consisting of substituted or unsubstituted aliphatic carboxylic acids having three or more carboxyl groups, anhydrides thereof, partial esters thereof, aromatic polycarboxylic acids having three or more carboxyl groups and anhydrides thereof. This composition has a high impact strength, is suitable for bonding metallic substrates to one another and is also excellent in resistance to heat, weather, and water.
    Type: Grant
    Filed: December 22, 1976
    Date of Patent: April 1, 1980
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Akira Yamada, Kaoru Kimura
  • Patent number: 4195146
    Abstract: Disclosed are unsaturated isocyanurates of monourethanes of an aromatic polyisocyanate and a vinylidene carbonyl oxy alkanol characterized by one of the following formulae: ##STR1## wherein R.sub.1 is hydrogen or an alkyl group containing from one to four carbon atoms, R.sub.2 is hydrogen, alkyl containing from 1 to 12 carbon atoms, or a chlorinated, brominated, or fluorinated alkyl group containing from 1 to 12 carbon atoms, R.sub.3 is hydrogen, alkyl containing from 1 to 12 carbon atoms, or a chlorinated, brominated, or fluorinated alkyl group containing from 1 to 12 carbon atoms, R.sub.4 is hydrogen, methyl or ethyl, and n is from one to four, with the proviso that R.sub.2 and R.sub.3 on adjacent carbon atoms are not both alkyl or chlorinated, brominated, or fluorinated alkyl. The unsaturated isocyanurates may be homopolymerized or copolymerized with ethylenically unsaturated compounds to form isocyanurate polymers having excellent physical properties at high temperatures.
    Type: Grant
    Filed: July 10, 1978
    Date of Patent: March 25, 1980
    Assignee: ICI Americas Inc.
    Inventors: Kenneth H. Markiewitz, Alfred J. Restaino
  • Patent number: 4184992
    Abstract: Provided is a cross-linked polymer composition which can be in a transparent polymeric gel form having an equilibrium water content of at least 60 wt.% for use in soft contact lenses. The cross-linked polymer composition is prepared by polymerizing, using a bulk polymerization procedure, a monomer mixture comprising an alkyl methacrylate and an N-vinyllactam in the presence of a cross-linking agent comprising at least one compound selected from vinyl acrylate, vinyl methacrylate, triallyl isocyanurate and vinyl carboxylates expressed by the formula:R--COOCH.dbd.CH.sub.2).sub.nwhere R is a hydrocarbon radical having 1 to 10 carbon atoms and n is an integer of 2, 3 or 4.
    Type: Grant
    Filed: November 3, 1977
    Date of Patent: January 22, 1980
    Assignee: Toray Industries, Inc.
    Inventor: Shuntaro Hosaka
  • Patent number: 4183796
    Abstract: A radiation curable oligomer which cures to provide a combination of improved elongation and tensile strength is constituted by a selected hydroxy functional polyester having its active hydrogen atoms end-capped by reaction with ethylenically unsaturated monoisocyanate. This polyester is the reaction product of one mole of tris (2-hydroxyethyl) isocyanurate with three moles of saturated dicarboxylic acid and three moles of diol, these proportions being variable within the limits of .+-.20%, the polyester reaction product having an acid value of less than 20, preferably less than 5, and providing hydroxyl-terminated branches having an average length corresponding to a calculated molecular weight of 100-1500.
    Type: Grant
    Filed: February 9, 1978
    Date of Patent: January 15, 1980
    Assignee: DeSoto, Inc.
    Inventors: Robert E. Ansel, John C. Graham
  • Patent number: 4174428
    Abstract: A heavy metal ion adsorbent represented by the following general formula: ##STR1##wherein l, m, and n are 2 or 3, respectively; R is an alkyl group containing 4 to 6 carbon atoms which is substituted by an amino group in the .omega.-position; and A is hydrogen or a synthetic resin.
    Type: Grant
    Filed: January 30, 1978
    Date of Patent: November 13, 1979
    Assignee: Iwao Tabushi
    Inventors: Iwao Tabushi, Hidefumi Kato, Yoichi Taniguchi, Yasuhisa Kuroda
  • Patent number: 4159376
    Abstract: Isocyanurate polymers having improved physical properties are disclosed. Unsaturated isocyanates are prepared by reacting a polyisocyanate with a monohydric alcohol containing a vinylidene group to form an isocyanate-containing urethane and then reacting the isocyanate-containing urethane with tris(2-hydroxyethyl)isocyanurate to form an unsaturated isocyanurate. The unsaturated isocyanurate may be homopolymerized or copolymerized with ethylenically unsaturated compounds to form isocyanurate polymers having an excellent combination of physical properties.
    Type: Grant
    Filed: July 27, 1977
    Date of Patent: June 26, 1979
    Assignee: ICI Americas Inc.
    Inventor: Erich Kuehn
  • Patent number: 4136246
    Abstract: Thermoplastic polymeric compositions having high heat-distortion temperatures and good processability and handling characteristics which function as gas and vapor barrier materials which are composed of an olefinically unsaturated nitrile, such as acrylonitrile, indene and a polyolefinic monomer, such as divinyl benzene, are described.
    Type: Grant
    Filed: October 29, 1976
    Date of Patent: January 23, 1979
    Assignee: The Standard Oil Company
    Inventor: George S. Li
  • Patent number: 4120831
    Abstract: A process for producing carboxyl cationites which comprises dissolution of comonomers such as methacrylic or acrylic acid and a vinyl-containing amide such as hexahydro-1,3,5-triacryloyltriazine, N, N'-methylenediacrylamide, N, N'-ethylenedimethacrylamide or N, N'-hexamethylenedimethacrylamide as well as an initiator of radical polymerization in a 5-50% acetic acid. Weight ratio between the unsaturated carboxylic acid and vinyl-containing amide is varied from 3:1 to 12:1; concentration of said comonomers in a 5-50% acetic acid is varied within the range of from 10 to 30%. The resulting reaction mixture is dispersed in polyethylsiloxane or polymethylphenylsiloxane liquid at a weight ratio between the reaction mixture and said silicone liquid ranging from 1:3 to 1:5 respectively. Thereafter, copolymerization is effected in a suspension at a temperature ranging from 20.degree. to 100.degree. C.
    Type: Grant
    Filed: June 2, 1977
    Date of Patent: October 17, 1978
    Inventors: Nadezhda Nikolaevna Kuznetsova, Georgy Vasilievich Samsonov, Klavdia Pavlovna Papukova, Galina Vladimirovna Bilibina, Larisa Konstantinovna Shataeva, Aida Alexandrovna Selezneva, Nina Petrovna Kuznetsova, Oyar Ansovich Vitols, Anite Ansovna Shtrausa, Lev Romanovich Gudkin, Rimma Nikodimovna Mishaeva, Karina Moiseevna Rozhetskaya
  • Patent number: 4106941
    Abstract: Interpolymers from monomers containing optical brightening moieties and solubilizing groups are useful in optical brightening compositions. Photographic elements containing these optical brightening compositions have excellent light stability.
    Type: Grant
    Filed: July 17, 1974
    Date of Patent: August 15, 1978
    Assignee: Eastman Kodak Company
    Inventors: Peter W. Scullard, John Figueras, Carl F. Holtz
  • Patent number: 4107122
    Abstract: Copolymers are prepared from .omega.-bromoalkyl esters of acyclic unsaturated dicarboxylic acids and compounds copolymerizable therewith. The copolymers are useful as flame retardant plasticizers for polymers.
    Type: Grant
    Filed: June 3, 1976
    Date of Patent: August 15, 1978
    Assignee: Monsanto Company
    Inventors: Albert W. Morgan, Charles S. Shull, William Vanderlinde
  • Patent number: 4105648
    Abstract: Crosslinked polyacrylamides containing silyl groups are disclosed which are prepared in a simple and economical manner by polymerizing silylated acrylic acid amides in the presence of a crosslinking agent such as 1,4-butanediol-diacrylate. The resultant crosslinked silylated polyacrylamides are insoluble in customary solvents and are useful for the transfer of silyl groups to compounds which contain at least one mobile hydrogen atom. They may be employed, e.g., in gas chromatography, mass spectroscopy and chemical syntheses (for instance for the introduction of protective silyl groups).
    Type: Grant
    Filed: March 17, 1977
    Date of Patent: August 8, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Urs Gruber, Gerd Greber, Hans-Peter Kriemler
  • Patent number: 4101491
    Abstract: Ethylenically unsaturated blocked aromatic diisocyanates are prepared which readily polymerize to form homopolymers and interpolymers with copolymerizable vinylidene monomers. Polymers can be prepared via emulsion polymerization, and exhibit excellent stability to hydrolysis when stored in latex form. The polymers cure at temperatures as low as 80.degree. C., and under acidic, neutral, or basic pH conditions. Homopolymers and interpolymers of the defined diisocyanates are useful as adhesives, and interpolymers of the ethylenically unsaturated blocked aromatic diisocyanates with acrylate monomers are particularly useful as binders for nonwoven fibers.
    Type: Grant
    Filed: October 22, 1976
    Date of Patent: July 18, 1978
    Assignee: The B. F. Goodrich Company
    Inventor: Harold A. Tucker