Abstract: Radiation-curable coating compositions are disclosed which contain one or more amide acrylate compounds of the general formula: ##STR1## wherein X, Y and Z may each independently be H, alkyl, aryl, acrylyloxyalkyl, acrylyloxy aliphatic ester or acrylyloxy aliphatic ether, provided that X, Y and Z together have two, three or four acrylyloxy groups. The compositions are highly radiation-sensitive and very fast curing and form mar-resistant protective and decorative film coatings which are particularly useful as UV-cured overprint varnishes.
Type:
Grant
Filed:
October 5, 1977
Date of Patent:
October 14, 1980
Assignee:
PPG Industries, Inc.
Inventors:
Byron M. Humke, Gerald W. Gruber, Rostyslaw Dowbenko, Charles B. Friedlander
Abstract: A photographic element particularly for the color diffusion transfer process having a support and an image pattern receiving layer which comprises a polymer containing at least 10 mole percent of a repeating unit of the formula: ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; R.sub.2, R.sub.3 and R.sub.4 each represent an alkyl group, an aralkyl group, a cycloalkyl group or a cycloalkylalkyl group; and X.sup..sym. represents a monovalent anion.
Abstract: Overcoats for electrophotographic elements are provided. The overcoats comprise a polymer having recurring units of the structure: ##STR1## in which R represents phenyl, tolyl, xylyl, or a ##STR2## group; R.sub.1, R.sub.5 and R.sub.6, which may be the same or different represent hydrogen or methyl;R.sub.2 represents alkyl or aryl;R.sub.3 represents carboxyl, alkyl ester, aryl ester, alkylamide or arylamide group having at least one carboxyl or hydroxyl or carboxylic anhydride substituent;R.sub.4 represents a group containing an active methylene group;a is about 29 to about 96 weight percent of said polymer;b is about 2 to about 25 weight percent of said polymer; andc is about 2 to about 46 weight percent of said polymer.
Abstract: Polymers containing laterally substituted isocyanate groups, prepared from acyl azide monomers and at least one other vinyl monomer, and their preparation are provided. Utilization of the acyl azide monomers avoids the problems in handling and storage of the moisture sensitive and toxic isocyanate monomers.
Type:
Grant
Filed:
July 8, 1976
Date of Patent:
July 3, 1979
Assignee:
Technion Research and Development Foundation, Ltd.
Abstract: Self-inverting emulsion polymers and their use as drainage aids, retention aids, saveall flotation aids and process water flocculants. The polymers are copolymers and homopolymers based on acrylamide, polymerized in the presence of water, an inert hydrophobic liquid, free radical catalyst and an emulsifier having a HLB of at least 7.
Type:
Grant
Filed:
November 21, 1977
Date of Patent:
April 3, 1979
Assignee:
Calgon Corporation
Inventors:
Sim K. Lim, Arnold E. Bloomquist, Raymond J. Schaper
Abstract: A film-forming and thermocurable vinyl alcohol-substituted acrylamide copolymer consisting essentially of(1) 0 to 20 mole% of a unit of the formula ##STR1## wherein R represents a group selected from the class consisting of alkyl groups with 1 to 7 carbon atoms and aryl groups with 6 to 7 carbon atoms, and n is 0 or 1,(2) 30 to 70 mole% of a unit of the formula ##STR2## wherein n is as defined above, (3) 0 TO 20 MOLE% OF A UNIT OF THE FORMULA ##STR3## wherein R' represents a hydrogen atom or a lower alkyl group, and R is as defined above, and(4) 30 to 70 mole% of a unit of the formula ##STR4## wherein R' is as defined above, R" represents a group selected from the class consisting of alkyl groups with 1 to 18 carbon atoms, cycloalkyl groups with 5 to 6 carbon atoms, hydroxyalkyl groups with 2 to 4 carbon atoms and aryl groups with 6 to 7 carbon atoms, and R"' represents a group selected from the class consisting of a hydrogen atom and the group R",the amount of each unit being based on the total amount in mol
Abstract: In the production of a water-soluble, cationic high polymer of (A) at least one of acrylamide and methacrylamide and (B) at least one of ammonium type monomers of either one of the formulas: ##STR1## wherein R.sub.1 is a hydrogen atom or a methyl group, R.sub.2 and R.sub.3 are each a lower alkyl group, R.sub.4 is a hydrogen atom, a lower alkyl group, an aryl group, a hydroxy(lower)alkyl group, a benzyl group or a group of the formula: --CH.sub.2 COO(CH.sub.2).sub.m CH.sub.3 (m being an integer of 0 or 1), R.sub.5 .crclbar. is a group of either one of the formulas: --(CH.sub.2).sub.2 COO.crclbar. and --(CH.sub.2).sub.3 SO.sub.3 .crclbar.
Abstract: Polymers in which the side branches contain optically active 2-(4-methyl-cyclohex-3-en-1-yl)-propyl groups, and their preparation. The new polymers are used for the production of moldings, coatings and adhesives, and for finishing paper or textiles. They have K values of from 20 to 140.
Abstract: Novel phthalic acid diesters or ester-amides substituted by alkenylamino groups, processes for their preparation and hot-curable mixtures which are stable on storage and contain at least one phthalic acid diester according to the invention or a phthalic acid ester-amide according to the invention and a polyimide which has at least two groupings containing a C.dbd.C double bond are described. These hot-curable mixtures which are stable on storage are distinguished by improved processing characteristics, in particular a prolonged pot life, and are suitable for the production of various mouldings and especially also for the production of complicated castings.
Abstract: In the production of a water-soluble, cationic high polymer of (A) at least one of acrylamide and methacrylamide and (B) at least one of ammonium type monomers of either one of the formulas: ##STR1## wherein R.sub.1 is a hydrogen atom or a methyl group, R.sub.2 and R.sub.3 are each a lower alkyl group, R.sub.4 is a hydrogen atom, a lower alkyl group, an aryl group, a hydroxy(lower)alkyl group, a benzyl group or a group of the formula: --CH.sub.2 COO(CH.sub.2).sub.m CH.sub.3 (m being an integer of 0 or 1), R.sub.5.sup.- is a group of either one of the formulas: --(CH.sub.2).sub.2 COO.sup.- and -(CH.sub.2).sub.3 SO.sub.3.sup.
Abstract: Sunscreening agents having improved adhesion to human skin comprising a polymeric material having a sunscreening group, e.g., a salicylate, aminobenzoate or a para-carboxy succinanilic acid group and having a substrate-binding group, e.g., a thioacetate, mercaptan, guanidyl or biguanidyl group. A representative species is a copolymer of vinylthioacetate and vinyl salicylate.
Type:
Grant
Filed:
February 28, 1973
Date of Patent:
January 18, 1977
Assignee:
Colgate-Palmolive Company
Inventors:
John Fred Gerecht, Morton Batlan Epstein