Abstract: Disclosed is a carbamate-functional acrylic polymer having an epsilon-caprolactone moiety beta to a carbamate group and a coating composition containing the acrylic polymer of the invention. The coating composition is particularly useful as a refinish coating and in refinish coating methods.
Type:
Grant
Filed:
December 19, 2000
Date of Patent:
January 28, 2003
Assignee:
BASF Corporation
Inventors:
Walter H. Ohrbom, John C. Goan, Lawrence E. Thieben
Abstract: A stimuli-responsive polymer derivative utilizing keto-enol tautomerization. Also disclosed are a simple process for producing an N-acyl(meth)acrylamide derivative which can be used as a monomer for the stimuli-responsive polymer, a process for the production of an intermediate thereof, and an intermediate thus produced.
Abstract: A novel method for making improved cement fluid loss additives comprising copolymers of acrylamide having desirable viscosity and fluid loss control properties. The method combines (1) the use of oxygenated make-up water to dissolve acrylamide monomers, derivatives or mixtures thereof to form a reaction mixture for polymerization of the monomers with (2) a second “condition” or set of conditions. The second “condition” or set of conditions is either (a) using of two heating stages to induce polymerization, or (b) adding a small amount of acrylic acid to the reaction mixture before exposing the reaction mixture to a temperature sufficient to polymerize the monomers. The two heating stages of (a) involve (i) an initial, lower temperature stage followed by (ii) a higher temperature stage.
Abstract: A copolymer of acrylamide or of an acrylamide derivative and of trialkylammonium salts which is a radical polymerization product, in the presence of an initiator,
of at least a first monomer chosen from acrylamide and its derivatives of formula
H2C═CH—(CH2)n″—CONH2
in which n″ is an integer which can vary from 1 to 5,
and of a second monomer chosen from trialkylammonium salts corresponding to the following formula (I)
(H2C═C(R1)—(CH2)n—A—(CH2)n′—N+(R2)(R3)(R4))X− (I)
in which,
R1 represents H or an alkyl group having from 1 to 3 carbon atoms,
R2, R3 and R4, which are identical or different, each represents an alkyl group having from 1 to 3 carbon atoms,
n and n′ each represents, independently of one another, a non-zero integer at most equal to 15,
A represents a divalent carboxyl or amide functional group, and
X− represents a counterion.
Abstract: The present invention relates to a process for the preparation, of thermoprecipitating affinity polymers useful in the enhanced recovery of enzymes. The process comprises polymerising a monomer comprising a spacer and a co-monomer with a polymerisation initiator and a polymerisation accelerator at ambient temperature and pressure for a period ranging between 2 to 24 hours to obtain a polymer and then linking an inhibitor to pendant carboxyl groups of the spacers in the polymer to obtain an affinity polymer.
Type:
Grant
Filed:
March 6, 2000
Date of Patent:
July 16, 2002
Assignee:
Council of Scientific and Industrial Research
Abstract: Disclosed is a process for preparing a polymer solution having a reduced unreacted unsaturated monomer content, comprising radically polymerizing at least one unsaturated monomer in a solvent in the presence of a radical polymerization initiator, the at least one unsaturated monomer having a lower boiling point than that of the solvent, wherein the weight ratio of the total amount of the unsaturated monomers to the solvent is from 1/9 to 7/3, the polymerization is carried out until the conversion of the unsaturated monomer having the lowest conversion of all the other unsaturated monomers whose boiling point is lower than that of the solvent reaches at least 85%, and, after completion of the polymerization, the reaction mixture is rectified to remove the unreacted unsaturated monomer or monomers.
Abstract: Additives for mineral building materials made of water-soluble or water-dispersible polymers containing a carboxyl group, optionally in latent form, and at least one side chain of formula I:
—X—Y—[O—(Alk—O)n—R]k (I)
wherein
k is 1, 2, 3 or 4;
Y is a C1-C4-alkylene unit, or a single bond if X is a carbonyl group, or when k≠1, can also be
X is
wherein R′ is hydrogen, C1-C20-alkyl, C5-C10-cycloalkyl, C6-C20-aryl, C1-C20-alkanoyl, C7-C21-aroyl, (Alk-O)n—R or -Alk′-O(Alk-O)n—R;
Alk is C2-C4-alkylene;
Alk′ is C1-C4-alkylene optionally having an OH group;
n is a number in the range from 15 to 300; and
R is hydrogen, C1-C20-alkyl, C5-C8-cycloalkyl, C6-C20-aryl, C1-C20-alkanoyl or C7-C21-aroyl; are obtained by polymerization of ethylenically unsaturated monomers in the presence of phosphorus-containing compounds and, if appropriate, subsequent polymer-analogous conversion.
Type:
Grant
Filed:
June 21, 1999
Date of Patent:
May 7, 2002
Assignee:
BASF Aktiengesellschaft
Inventors:
Axel Kistenmacher, Paul Klingelhofer, Johannes Perner, Markus Hartmann, Alfred Ruland
Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
Type:
Application
Filed:
January 10, 2001
Publication date:
April 11, 2002
Inventors:
Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
Type:
Application
Filed:
October 10, 2001
Publication date:
March 28, 2002
Inventors:
Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
Type:
Grant
Filed:
February 4, 1999
Date of Patent:
November 6, 2001
Assignee:
The Dow Chemical Company
Inventors:
Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
Abstract: A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions. Specifically, the dispersant viscosity improvers of this invention are nitrogen-containing copolymers comprising units derived from
(A) from about 5% to about 75% by weight of alkyl acrylate ester monomers containing from 1 to 11 carbon atoms in the alkyl group;
(B) from about 25% to about 95% by weight of alkyl acrylate ester monomers containing from 12 to about 24 carbon atoms in the alkyl group; and
(C) from about 0.1% to about 20% by weight of at least one nitrogen containing monomer selected from the group consisting of vinyl substituted nitrogen heterocyclic monomers, N,N-dialkylaminoalkyl acrylate monomers, N,N-dialkylaminoalkyl acrylamide monomers and tertiary-alkyl acrylamides, provided that the total equals 100%. Processes for preparing the compositions, additive concentrates and lubricating oil compositions are described.
Type:
Grant
Filed:
May 14, 1999
Date of Patent:
September 25, 2001
Assignee:
The Lubrizol Corporation
Inventors:
Charles P. Bryant, Bryan A. Grisso, Robert Cantiani
Abstract: The invention concerns a polyacrylamide-containing composition which is characterized in that it has a molecular weight of between 2,000 and 8,000 g/mol, determined by means of gel permeation chromatography (GPC), and as a 15% aqueous solution still has a Brookfield viscosity of between 100 and 500 mPas at 25° C. The invention further concerns the use of this polyacrylamide-containing composition for the flat bonding of water absorbent and hard surfaces and for equipping plastic surfaces with non-slip protection.
Type:
Grant
Filed:
February 13, 1998
Date of Patent:
January 30, 2001
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Norbert Huebner, Wolf-Ruediger Mueller, Bernd Willi Peters, Ludwig Schieferstein