With Monomer Containing Oxygen Patents (Class 526/307.4)
  • Patent number: 6512069
    Abstract: Disclosed is a carbamate-functional acrylic polymer having an epsilon-caprolactone moiety beta to a carbamate group and a coating composition containing the acrylic polymer of the invention. The coating composition is particularly useful as a refinish coating and in refinish coating methods.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: January 28, 2003
    Assignee: BASF Corporation
    Inventors: Walter H. Ohrbom, John C. Goan, Lawrence E. Thieben
  • Publication number: 20020188084
    Abstract: A stimuli-responsive polymer derivative utilizing keto-enol tautomerization. Also disclosed are a simple process for producing an N-acyl(meth)acrylamide derivative which can be used as a monomer for the stimuli-responsive polymer, a process for the production of an intermediate thereof, and an intermediate thus produced.
    Type: Application
    Filed: June 25, 2002
    Publication date: December 12, 2002
    Inventors: Noriyuki Ohnishi, Kazumi Aoshima, Kazunori Kataoka, Katsuhiko Ueno
  • Patent number: 6448311
    Abstract: A novel method for making improved cement fluid loss additives comprising copolymers of acrylamide having desirable viscosity and fluid loss control properties. The method combines (1) the use of oxygenated make-up water to dissolve acrylamide monomers, derivatives or mixtures thereof to form a reaction mixture for polymerization of the monomers with (2) a second “condition” or set of conditions. The second “condition” or set of conditions is either (a) using of two heating stages to induce polymerization, or (b) adding a small amount of acrylic acid to the reaction mixture before exposing the reaction mixture to a temperature sufficient to polymerize the monomers. The two heating stages of (a) involve (i) an initial, lower temperature stage followed by (ii) a higher temperature stage.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: September 10, 2002
    Assignee: Baker Hughes Incorporated
    Inventor: Michael L. Walker
  • Patent number: 6444770
    Abstract: A copolymer of acrylamide or of an acrylamide derivative and of trialkylammonium salts which is a radical polymerization product, in the presence of an initiator, of at least a first monomer chosen from acrylamide and its derivatives of formula H2C═CH—(CH2)n″—CONH2  in which n″ is an integer which can vary from 1 to 5, and of a second monomer chosen from trialkylammonium salts corresponding to the following formula (I) (H2C═C(R1)—(CH2)n—A—(CH2)n′—N+(R2)(R3)(R4))X−  (I)  in which, R1 represents H or an alkyl group having from 1 to 3 carbon atoms, R2, R3 and R4, which are identical or different, each represents an alkyl group having from 1 to 3 carbon atoms, n and n′ each represents, independently of one another, a non-zero integer at most equal to 15, A represents a divalent carboxyl or amide functional group, and X− represents a counterion.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: September 3, 2002
    Assignee: Atofina
    Inventors: Isabelle Descheres, Gilbert Boulon
  • Patent number: 6420487
    Abstract: The present invention relates to a process for the preparation, of thermoprecipitating affinity polymers useful in the enhanced recovery of enzymes. The process comprises polymerising a monomer comprising a spacer and a co-monomer with a polymerisation initiator and a polymerisation accelerator at ambient temperature and pressure for a period ranging between 2 to 24 hours to obtain a polymer and then linking an inhibitor to pendant carboxyl groups of the spacers in the polymer to obtain an affinity polymer.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: July 16, 2002
    Assignee: Council of Scientific and Industrial Research
    Inventors: Alankar Arun Vaidya, Bhalchandra Shripad Lele, Mohan Gopalkrishna Kulkarni, Raghunath Anant Mashelkar
  • Patent number: 6403731
    Abstract: Disclosed is a process for preparing a polymer solution having a reduced unreacted unsaturated monomer content, comprising radically polymerizing at least one unsaturated monomer in a solvent in the presence of a radical polymerization initiator, the at least one unsaturated monomer having a lower boiling point than that of the solvent, wherein the weight ratio of the total amount of the unsaturated monomers to the solvent is from 1/9 to 7/3, the polymerization is carried out until the conversion of the unsaturated monomer having the lowest conversion of all the other unsaturated monomers whose boiling point is lower than that of the solvent reaches at least 85%, and, after completion of the polymerization, the reaction mixture is rectified to remove the unreacted unsaturated monomer or monomers.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: June 11, 2002
    Assignee: Mitsubishi Chemical America, Inc.
    Inventors: Yukio Saitou, Shigeoki Kawaguchi, Kouhei Sawa, Tadahiko Kondou, Kazuhide Hayama
  • Publication number: 20020055559
    Abstract: Water-soluble or water-dispersible polymers which contain carboxyl groups, possibly in latent form, and side chains of the formula I,
    Type: Application
    Filed: June 21, 1999
    Publication date: May 9, 2002
    Inventors: AXEL KISTENMACHER, PAUL KLINGELHOFER, JOHANNES PERNER, MARKUS HARTMANN, ALFRED RULAND
  • Patent number: 6384111
    Abstract: Additives for mineral building materials made of water-soluble or water-dispersible polymers containing a carboxyl group, optionally in latent form, and at least one side chain of formula I: —X—Y—[O—(Alk—O)n—R]k  (I) wherein k is 1, 2, 3 or 4; Y is a C1-C4-alkylene unit, or a single bond if X is a carbonyl group, or when k≠1, can also be  X is  wherein R′ is hydrogen, C1-C20-alkyl, C5-C10-cycloalkyl, C6-C20-aryl, C1-C20-alkanoyl, C7-C21-aroyl, (Alk-O)n—R or -Alk′-O(Alk-O)n—R; Alk is C2-C4-alkylene; Alk′ is C1-C4-alkylene optionally having an OH group; n is a number in the range from 15 to 300; and R is hydrogen, C1-C20-alkyl, C5-C8-cycloalkyl, C6-C20-aryl, C1-C20-alkanoyl or C7-C21-aroyl; are obtained by polymerization of ethylenically unsaturated monomers in the presence of phosphorus-containing compounds and, if appropriate, subsequent polymer-analogous conversion.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: May 7, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Axel Kistenmacher, Paul Klingelhofer, Johannes Perner, Markus Hartmann, Alfred Ruland
  • Publication number: 20020042488
    Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
    Type: Application
    Filed: January 10, 2001
    Publication date: April 11, 2002
    Inventors: Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
  • Publication number: 20020037988
    Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
    Type: Application
    Filed: October 10, 2001
    Publication date: March 28, 2002
    Inventors: Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
  • Publication number: 20020035222
    Abstract: A water-soluble polymeric adhesion promoter is represented by the following formula (I): 1
    Type: Application
    Filed: January 18, 2001
    Publication date: March 21, 2002
    Inventors: Se Yong Oh, Chan Eon Park, Sang Min Song
  • Patent number: 6313252
    Abstract: Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: November 6, 2001
    Assignee: The Dow Chemical Company
    Inventors: Ray E. Drumright, Robert H. Terbrueggen, Kenneth A. Burdett, Francis J. Timmers, Stephen F. Hahn
  • Patent number: 6294628
    Abstract: A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions. Specifically, the dispersant viscosity improvers of this invention are nitrogen-containing copolymers comprising units derived from (A) from about 5% to about 75% by weight of alkyl acrylate ester monomers containing from 1 to 11 carbon atoms in the alkyl group; (B) from about 25% to about 95% by weight of alkyl acrylate ester monomers containing from 12 to about 24 carbon atoms in the alkyl group; and (C) from about 0.1% to about 20% by weight of at least one nitrogen containing monomer selected from the group consisting of vinyl substituted nitrogen heterocyclic monomers, N,N-dialkylaminoalkyl acrylate monomers, N,N-dialkylaminoalkyl acrylamide monomers and tertiary-alkyl acrylamides, provided that the total equals 100%. Processes for preparing the compositions, additive concentrates and lubricating oil compositions are described.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: September 25, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Charles P. Bryant, Bryan A. Grisso, Robert Cantiani
  • Patent number: 6180705
    Abstract: The invention concerns a polyacrylamide-containing composition which is characterized in that it has a molecular weight of between 2,000 and 8,000 g/mol, determined by means of gel permeation chromatography (GPC), and as a 15% aqueous solution still has a Brookfield viscosity of between 100 and 500 mPas at 25° C. The invention further concerns the use of this polyacrylamide-containing composition for the flat bonding of water absorbent and hard surfaces and for equipping plastic surfaces with non-slip protection.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: January 30, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Norbert Huebner, Wolf-Ruediger Mueller, Bernd Willi Peters, Ludwig Schieferstein