Contains Oxygen Atom Bonded To A Carbon Atom Patents (Class 526/312)
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Patent number: 6133392Abstract: An insoluble, only slight swellable, polymer having modified amino groups, which contain units of the formulae: ##STR1## or both (I) and (II), wherein R.sup.1, R.sup.2, R.sup.3 and Me are as defined herein.Type: GrantFiled: March 11, 1999Date of Patent: October 17, 2000Assignee: BASF AktiengesellschaftInventors: Jens Utecht, Martin Rubenacker, Claudia Nilz, Rainer Rahm
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Patent number: 6133390Abstract: The present invention relates to a photochromic polymer for photo recording purposes comprising polymethacrylate, and having the following general formula: ##STR1## wherein R is --(CH.sub.2).sub.o --X--C.sub.6 H.sub.4 --Z--C.sub.6 H.sub.4 --R.sub.1,wherein R.sub.1 is an electron acceptor, such as cyano, alkoxy having 1 to 8 carbon atoms, halosubstituted alkoxy having 1 to 8 carbon atoms, halogen (F, Cl), hydroxy, esters of the formula--OOC--C.sub.n H.sub.2n-1, --CO--C.sub.n H.sub.2n-1, wherein n is 1 to 8, preferably 4 to 6, but excluding nitro, Br, I, and --SO.sub.3 H,X is selected from the group consisting of --O--, and --COO--,Z is selected from the group consisting of --N.dbd.N--, --CH.dbd.N--, or --CH.dbd.CH--, wherein --CH.dbd. of the --CH.dbd.N-- group is bound to the main part of the structure,R.sub.2 is C.sub.m H.sub.2m+1, wherein m is an integer 4 to 7,o is a number of 7 to 12, preferably 10, anda is number providing for a photo chromic polymer.Type: GrantFiled: April 21, 1998Date of Patent: October 17, 2000Inventors: Mikhael Kozlovski, Kent Skarp
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Patent number: 6117961Abstract: The present invention provides a process for producing a crosslinkable styrene or styrene derivative polymer having narrow molecular weight distribution by radical polymerization of a styrene or styrene derivative monomer and other comonomer, wherein the polymerization is conducted in the presence of a catalyst system composed of a free radical compound and a radical polymerization initiator. With the present process, a heat- or photo-crosslinkable styrene or styrene derivative polymer having excellent rheology controlling ability and excellent reaction efficiency of a functional group can be obtained.Type: GrantFiled: April 25, 1997Date of Patent: September 12, 2000Assignee: Kansai Paint Co., Ltd.Inventor: Tetsuo Ogawa
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Patent number: 6117960Abstract: The invention concerns water-soluble cross-linkable copolymers having a molecular weight of .ltoreq.500000 and comprising a) between 20 and 95 wt. % sulphonic-acid- or sulphonate-group-containing monomer units; b) between 4 and 80 wt. % N-methylol- or N-alkoxymethyl-group containing monomer units; and c) between 0.1 and 20 wt. % hydrophobic monomer units selected from the group comprising water-insoluble ethylenically unsaturated compounds and hydrophobic end groups of initiator radicals or regulator molecules, the portions in wt. % being relative to the total weight of the copolymer. The portion of sulphonic-acid- or sulphonate-group-containing monomer units can optionally be substituted by up to 50 wt. %, relative to the portion by weight of monomer units a), by carboxyl-group-containing monomer units d) or amide-group-containing monomer units e).Type: GrantFiled: September 4, 1998Date of Patent: September 12, 2000Assignee: Wacker-Chemie GmbHInventors: Klaus Kohlhammer, Gerhard Koegler, Peter Ball, Monika Rockinger, Walter Dobler
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Patent number: 6114484Abstract: A method for the removal of metal cyanides or oxoanions from aqueous streams such as waste water streams with compounds containing 1,4-diazabicyclo[2.2.2]octane. Preferred compounds are polymers formed by free radical polymerization of N-4-vinyl benzyl-N.sup.1 -1,4-diazabicyclo[2.2.2]octane dichloride (VBBD) such as copolymers poly (VBBD/acrylamide) and poly (VBBD/dimethyl amino ethyl acrylate benzyl chloride quaternary salt. Poly(1,4-dimethylbenzyl-1,4-diazabicyclo[2.2.2]octane dichloride) for the same purposes is also disclosed.Type: GrantFiled: November 16, 1998Date of Patent: September 5, 2000Assignee: Nalco Chemical CompanyInventor: William J. Ward
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Patent number: 6111045Abstract: This invention provides a diene rubber composed of 40 to 99.99% by weight of conjugated diene units, 0.05 to 20% by weight of amino-containing vinyl monomer units, 0.05 to 20% weight of hydroxyl-containing vinyl monomer units, and 0 to 50% by weight of other copolymerizable monomer units, and having a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 10 to 200. This diene rubber yields a vulcanized rubber showing improvements in heat build-up, tensile strength, abrasion resistance and processability.Type: GrantFiled: June 29, 1998Date of Patent: August 29, 2000Assignee: Nippon Zeon Co. Ltd.Inventors: Yukio Takagishi, Masao Nakamura
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Patent number: 6111053Abstract: The invention relates to olefinically unsaturated polyisocyanates containing allophanate groups and having an NCO content of 6 to 20% by weight, an iodine value of 15 to 150, a content of hydrocarbon chains containing 12 to 30 carbon atoms of 100 to 700 mg/g and a content of allophanate groups of 10 to 300 mg/g, to a process for their production by reaction of a polyisocyanate component containing urethane groups with excess polyisocyanates, and to a one-component coating composition containing these olefinically unsaturated polyisocyanates as binders.Type: GrantFiled: May 8, 1995Date of Patent: August 29, 2000Assignee: Bayer AktiengesellschaftInventors: Martin Brahm, Eberhard Arning, Lutz Schmalstieg, Harald Mertes, Jurgen Schwindt
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Patent number: 6107410Abstract: The invention provides a cinnamic acid derivative having a novel spacer introduced into cinnamic acid which is photodimerizable, a cinnamic acid-polysaccharide derivative photocurable with high sensitivity and efficiency obtainable by introducing the above cinnamic acid derivative into a host polysaccharide such as a glycosaminoglycan, and a photocrosslinked cinnamic acid-polysaccharide derivative obtainable by exposing the same cinnamic acid-polysaccharide derivative to ultraviolet light irradiation.Type: GrantFiled: December 22, 1998Date of Patent: August 22, 2000Assignee: Seikagaku CorporationInventors: Michinori Waki, Kenji Miyamoto, Yoshihiro Motani
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Patent number: 6100312Abstract: A radiation sensitive colored composition comprising (A) a copolymer having, as constitutional repeating units, at least ((1) a monofuctional macromonomer having the specified structure and weight-average molecular weight of 3.times.10.sup.4 or below, (2) a monomer having the specified structure and (3) a quaternary ammonium salt monomer; (B) a radiation sensitive compound; and (C) a pigment: which can provide a color filter having excellent pattern reproducibility because of its high suitablity for dispersion of fine-grain pigment and its high storage stability.Type: GrantFiled: November 7, 1997Date of Patent: August 8, 2000Assignees: Fuji Photo Co., Ltd., Fujifilm Olin Co., Ltd.Inventors: Nobuo Suzuki, Naoki Kato
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Patent number: 6096848Abstract: Biscyanoacrylates in solution are prepared by reacting 2-cyanoacrylic acids or their alkyl esters with diols in the presence of sulfonic acids as catalysts. The reaction mixture is processed by substituting an aliphatic solvent for the aromatic solvent and is then subjected twice to fractional crystallization. The thus obtained biscyanoacrylates are very pure. They are therefore useful for producing storage stable cyanoacrylate adhesives. Their admixture increases the thermal resistance of the adhesives, which is particularly important in the case of electric and electronic components.Type: GrantFiled: March 5, 1997Date of Patent: August 1, 2000Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Yuri Gololobov, Werner Gruber, Christian Nicolaisen
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Patent number: 6087462Abstract: Polymers of one or more radical polymerisable monomers which polymer has pendant groups bearing a centre of permanent positive charge and other pendant groups capable of stably binding the polymer to a surface are useful in the treatment of surfaces to render them biocompatible. The polymers may contain pendant groups which bind the polymer to a surface by physisorption, covalent bonding or ionic interactions. Additionally reactive groups in the polymer may serve as points for attachment of ligands to the polymer when coated on a surface.Type: GrantFiled: May 12, 1998Date of Patent: July 11, 2000Assignee: Biocompatibles LimitedInventors: Roderick W J Bowers, Stephen A Jones, Peter W Stratford, Stephen A Charles
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Patent number: 6075108Abstract: Carbamate-functional allyl monomers and methods for making them are disclosed. The monomers, which are easy to prepare, readily polymerize with common ethylenic monomers to give low-molecular-weight resins without the need for solvents or chain-transfer agents. Coatings made from the resins should have good durability, good acid etch resistance, good mar resistance, high gloss, and high DOI.Type: GrantFiled: October 6, 1998Date of Patent: June 13, 2000Assignee: Arco Chemical Technology, L.P.Inventor: Shao Hua Guo
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Patent number: 6063488Abstract: The acrylic copolymer and the acrylic resin particles of the invention have a recurring unit derived from a nitrogen-containing acrylic monomer having, in its molecule, at least one CH.sub.2 .dbd.CR.sup.1 --CO-- group (R.sup.1 is a hydrogen atom, methyl or ethyl) and at least one --N.sup.+ R.sup.2.sub.3.X.sup.- group (R.sup.2 is H--, an alkyl group of 1 to 5 carbon atoms or an alkylol group of 1 to 5 carbon atoms, and X is a halogen atom) and a recurring unit derived from an acrylic monomer represented by the formula CH.sub.2 .dbd.CR.sup.3 --CO--Q wherein R.sup.3 is H--, CH.sub.3 -- or C.sub.2 H.sub.5 --, and Q is --NH.sub.2, --NH--R.sup.4 --OH (R.sup.4 is an alkylene group of 1 to 5 carbon atoms) or --R.sup.5 (R.sup.5 is H-- or an alkoxy group of 1 to 20 carbon atoms), and further have a crosslinked structure. The ink-jet recording medium of the invention contains the acrylic resin particles in its ink-receiving layer. The acrylic resin particles have good water resistance though they are hydrophilic.Type: GrantFiled: July 29, 1998Date of Patent: May 16, 2000Assignee: Soken Chemical & Engineering Co., Ltd.Inventors: Masahiro Sato, Masayuki Yamagishi
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Patent number: 6063961Abstract: A process for preparing cocondensates of aspartic acid and amines by heating aspartic acid and amines in the presence of acidic catalysts comprises supplying the feed region of the extruder with particulate aspartic acid and a downstream metering zone with at least one amine and at least one acidic catalyst, condensing the resulting mixture to such an extent by heating that the downstream end of the extruder discharges a precondensate which contains at least 20-95% by weight of the starting aspartic acid in condensed form, and then completing the condensation of the precondensate. The cocondensates are useful as incrustation inhibitors in detergents.Type: GrantFiled: December 10, 1998Date of Patent: May 16, 2000Assignee: BASF AktiengesellschaftInventor: Matthias Kroner
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Patent number: 6057412Abstract: An amphipathic compound represented by any of the following Formulas: ##STR1## (R.sub.1 is a linear or branched, saturated hydrocarbon group having 6 to 48 carbon atoms, or a linear or branched, unsaturated hydrocarbon group containing 1 to 12 unsaturated double bond and having 6 to 48 carbon atoms; Y is NH, N--(CH.sub.2 --CH.dbd.CH.sub.2), or O; Q is --CH.sub.2 --C(R.sub.2).dbd.CH.sub.2 or --R.sub.4 --O--CO--C(R.sub.2).dbd.CH.sub.2 ; and M is alkali metal, an ammonium group, or --(CH.sub.2 CH.sub.2 O).sub.m H), a copolymer of the amphipatic compound with a copolymerizable ethylenically unsaturated compound and, a paper making additive containing a water soluble or dispersible high molecular compound as an active ingredient and processes for producing these high molecular compounds.Type: GrantFiled: July 17, 1998Date of Patent: May 2, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Toshihiko Takaki, Masaru Tanabe, Hiroshi Itoh, Masayuki Yanagi, Shoko Oyanagi, Hiroyoshi Watanabe
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Patent number: 6048587Abstract: Radiation-curable resins as well as thermal and electron-beam-curable resins are provided comprising a polymeric backbone having acrylate or vinyl ether substituents and an ionically bonded neutralizing agent such as an aminoacrylate. These resins are hydrophilic and water-dispersible before curing, but resistant to most solvents including water after curing while preserving a hard, strong, adhesive character which makes them suitable for use as coatings and fabrication of three-dimensional structures in a wide variety of applications.Type: GrantFiled: October 1, 1998Date of Patent: April 11, 2000Assignee: Ricon Resins, Inc.Inventor: Tanya Estrin
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Patent number: 6046290Abstract: The invention provides an optical method which permits, with the aid of 6 simple measurements, a conclusion regarding the suitability of antennas (groups which can absorb electromagnetic radiation) for incorporation into photoaddressable polymers.Type: GrantFiled: August 4, 1997Date of Patent: April 4, 2000Assignee: Bayer AktiengesellschaftInventors: Horst Berneth, Uwe Claussen, Serguei Kostromine, Ralf Neigl, Joachim Rubner, Ralf Ruhmann
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Patent number: 6043329Abstract: Copolymers which are obtainable by reacting acrylic monomers with monomers of the following formula:R.sub.4 --O--R.sub.5 --CO--NH--R.sub.6wherein R.sub.4 represents H or a group of the following formulae: ##STR1## R.sub.5 represents an oxyalkenyl group of the following formulae:--(CHR.sub.1 --CH.sub.2 --O).sub.m -- or --(CHR.sub.1 --CH.sub.2 --O).sub.m1 --(CH.sub.2 --CH.sub.2 --O).sub.n --R.sub.6 represents a C.sub.1 - to C.sub.8 -alkyl group, a C.sub.5 - to C.sub.7 -cycloalkyl group, or a phenyl group. The copolymers are very useful as additives or admixtures for improving the properties of construction materials and of dispersions.Type: GrantFiled: April 7, 1998Date of Patent: March 28, 2000Assignee: Cement Intellectual Property Ltd. (CIP)Inventors: Agostino Lepori, Stefan Pieh, Manfred Akstinat, Fritz Burkhardt
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Patent number: 6025444Abstract: The invention provides a cinnamic acid derivative having a novel spacer introduced into cinnamic acid which is photodimerizable, a cinnamic acid-polysaccharide derivative photocurable with high sensitivity and efficiency obtainable by introducing the above cinnamic acid derivative into a host polysaccharide such as a glycosaminoglycan, and a photocrosslinked cinnamic acid-polysaccharide derivative obtainable by exposing the same cinnamic acid-polysaccharide derivative to ultraviolet light irradiation.Type: GrantFiled: May 27, 1997Date of Patent: February 15, 2000Assignees: Seikagaku Kogyo Kabushiki Kaisha (Seikagaku Corporation), Fuji Photo Film Co., Ltd.Inventors: Michinori Waki, Kenji Miyamoto, Yoshihiro Motani
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Patent number: 5998535Abstract: A polymeric dispersant, the dispersant being especially adapted for dispersing pigments therein and being compatible with a variety of film-forming polymers, said dispersant being the free radical addition polymerization reaction product of a mixture of monomers consisting essentially of:(a) from about 10% to about 40% by weight styrene; and(b) from about 10% to about 55% by weight of at least one alkyl methacrylate monomer having 1 to 8 carbon atoms in the alkyl group; and(c) from about 10% to about 55% by weight of at least one alkyl methacrylate monomer having greater than 8 carbon atoms in the alkyl group; and(d) from about 5% to about 25% by weight of at least one alkyl acrylate monomer having from 1 to 18 carbon atoms in the alkyl group; and(e) from about 7% to about 25% by weight of at least one hydroxy-functional ethylenically unsaturated monomer; and(f) from about 0.Type: GrantFiled: September 22, 1997Date of Patent: December 7, 1999Assignee: The Sherwin-Williams CompanyInventor: Gautam S. Haldankar
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Patent number: 5994430Abstract: The present invention relates to an antireflective coating composition comprising a novel polymer in a solvent composition. The invention further comprises processes for using the antireflective coating composition in photolithography. The antireflective coating composition comprises a novel polymer and a solvent composition, where the novel polymer of the antireflective coating comprises at least one unit containing a dye that absorbs from about 180 nm to about 450 nm and at least one unit that contains no aromatic funtionality. The solvent may be organic, preferrably, a solvent of low toxicity, or it may be water, which may additionally contain other water miscible organic solvents.Type: GrantFiled: April 30, 1997Date of Patent: November 30, 1999Assignee: Clariant Finance BVI) LimitedInventors: Shuji Ding, Ping-Hung Lu, Dinesh N. Khanna, Jianhui Shan, Dana L. Durham, Ralph R. Dammel, M. Dalil Rahman
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Patent number: 5969068Abstract: A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions. Specifically, the dispersant viscosity improvers of this invention are nitrogen-containing copolymers comprising units derived from(A) from about 5% to about 75% by weight of alkyl acrylate ester monomers containing from 1 to 11 carbon atoms in the alkyl group;(B) from about 25% to about 95% by weight of alkyl acrylate ester monomers containing from 12 to about 24 carbon atoms in the alkyl group; and(C) From about 0.1% to about 20% by weight of at least one nitrogen containing monomer selected from the group consisting of vinyl substituted nitrogen heterocyclic monomers, N,N-dialkylaminoalkyl acrylate monomers, N,N-dialkylaminoalkyl acrylamide monomers and tertiary-alkyl acrylamides, provided that the total equals 100%. Processes for preparing the compositions, additive concentrates and lubricating oil compositions are described.Type: GrantFiled: June 19, 1995Date of Patent: October 19, 1999Assignee: The Lubrizol CorporationInventors: Charles P. Bryant, Bryan A. Grisso, Robert Cantiani
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Patent number: 5945495Abstract: The present invention relates to the use of surfactants for improving the drying properties of hydrophilic, highly swellable hydrogels in the course of drying with the aid of contact dryers.Type: GrantFiled: January 17, 1997Date of Patent: August 31, 1999Assignee: BASF CorporationInventors: Thomas Daniel, Norbert Herfert, Gustav Remmel, Ulrich Riegel, Uwe Stuven, Fritz Engelhardt
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Patent number: 5939514Abstract: The present invention relates to the preparation of water based coating compositions having extended storage stability. The composition includes separately stored polymeric binder component and a crosslinking component.These components are mixed prior to application over surfaces, such as, road surfaces. The polymeric binder component includes an anionically stabilized binder polymer having at least one reactive functional pendent moiety, or a blend of the binder polymer with a polyfunctional amine. The pot mix of the coating composition has extended storage stability. The waterborne road marking paints of the present invention exhibit improved wear resistance on road surfaces in terms of paint remaining on the road longer than waterborne road marking paints based on the storage stable component alone. The present invention provides road marking paints that can be applied by conventional road striping equipment and do not require special two component spray equipment.Type: GrantFiled: August 5, 1997Date of Patent: August 17, 1999Assignee: Rohm and Haas CompanyInventors: Ward Thomas Brown, Donald Craig Schall, Francis Joseph Landy, Ann Robertson Hermes
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Patent number: 5905099Abstract: A heat-activatable adhesive comprising an acrylic copolymer, which copolymer comprises a monomer consisting of an acrylate or methacrylate ester of a non-tertiary alkyl alcohol having a Tg of about 0.degree. C. or lower; a monomer consisting of an acrylate or methacrylate ester of an alcohol having a Tg of at least about 5.degree. C.; and a functional monomer. Selected embodiments include a retroreflective article comprising a film having a substantially flat surface and a structured surface, the structured surface comprising a plurality of precisely shaped projections, a colored layer disposed on the structured surface and adhered thereto in a plurality of discrete locations, and a heat-activatable adhesive layer disposed on the colored layer.Type: GrantFiled: November 6, 1995Date of Patent: May 18, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Albert I. Everaerts, Yoshinori Araki, Michiru Hata
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Patent number: 5905127Abstract: Mesogens are provided based on substituted unsaturated carboxylic acids such as acrylic and methacrylic acid. Substitution of a variety of hydrophobic tails onto the carboxylic acid or acid derivative via the vinyl carbon proximal to the carbonyl of the carboxylic acid results in mesogens that are capable of forming thermotropic and single-phase lyotropic mesophases over a broad range of compositions. The mesophases can be polymerized to lock in the ordered phases.Type: GrantFiled: April 8, 1997Date of Patent: May 18, 1999Assignee: The University of Southern MississippiInventors: Robert Y Lochhead, Lon J Mathias
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Patent number: 5883212Abstract: An electrically conductive polymeric material useful in electrographic imaging elements is disclosed. The material comprises, in polymerized form: (1) a polymerizable, conductivity exalting comonomer selected from the group consisting of interpolymerizable acids with an acid number between 100 and 900, hydroxyalkyl esters of acrylic or methacrylic acid, cyanoalkyl esters of acrylic or methacrylic acid, and combinations thereof; (2) a polymerizable, ethylenically unsaturated ammonium precursor; and, optionally, (3) other polymerizable precursors. A layer of the material has an apparent surface resistivity of 1.times.10.sup.4 to 1.times.10.sup.7 .OMEGA./.quadrature..Type: GrantFiled: May 8, 1996Date of Patent: March 16, 1999Assignee: Rexam Graphics, Inc.Inventor: Everett Wyman Bennett
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Patent number: 5874511Abstract: A process for the production of polymers by free radical polymerization, characterized in that there is added to the polymerization system one or more compounds of the general formula (A). ##STR1## where R.sup.1 is hydrogen or a group capable of activating the vinylic carbon towards free radical addition;Y is OR.sup.2 or CH.sub.2 X(R.sup.2).sub.nwhere R.sup.2 is an optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, or optionally substituted saturated, unsaturated or aromatic carbocyclic or heterocyclic ring;X is an element other than carbon selected from Groups IV, V, VI or VII of the Periodic Table or a group consisting of an element selected from Groups IV, V, or VI to which is attached one or more oxygen atoms; andn is a number from 0 to 3, such that the valency of the group X is satisfied and, when n is greater than 1, the groups represented by R.sup.2 may be identical or different.Type: GrantFiled: June 24, 1996Date of Patent: February 23, 1999Assignees: E. I. du Pont de Nemours and Company, Commonwealth Scientific and Industrial Research OrganisationInventors: Ezio Rizzardo, Gordon Francis Meijs, San Hoa Thang
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Patent number: 5872200Abstract: A paper coating formulation and a process for making a paper coating formulation having an improved strength and blister resistance including an aqueous medium having dispersed therein a functionally effective amount of a finely divided mineral filler and a latex binder containing copolymerized acid functional and amine functional monomers in each polymer molecule.Type: GrantFiled: July 31, 1997Date of Patent: February 16, 1999Assignee: GenCorp Inc.Inventors: Satish C. Sharma, Charles M. Kausch, Ronald D. Mohan, Raymond J. Weinert
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Patent number: 5854303Abstract: A polymeric material incorporating a polyvalent cation chelating agent in an amount effective to inhibit the growth of an ocular pathogen, particularly a protozoan, can be used to produce eye care products such as contact lens cases and containers for containing eye care solutions and contact lenses.Type: GrantFiled: January 27, 1998Date of Patent: December 29, 1998Assignee: Allergan Sales, Inc.Inventors: Charles Hayes Powell, David C. Rupp
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Patent number: 5849047Abstract: This invention concerns the utilization of polymeric compounds generated from Mannich base macromonomers as lubricant oil and fuel additives or intermediates to such additives. Requisite macromonomers are generated via Mannich reaction of high molecular weight alkyl phenols and unsaturated amines. Homopolymers of the Mannich base macromonomers or copolymers with activated unsaturated monomers, such as maleic anhydride, are of particular interest as crankcase dispersants. For example, functionalization of Mannich base macromonomer/maleic anhydride copolymers with amines affords effective crankcase dispersants. Such polymeric dispersants are designed to impart superior sludge protection and improved viscometrics to lubricant oils.Type: GrantFiled: November 1, 1996Date of Patent: December 15, 1998Assignee: Ethyl CorporationInventors: Daniel Y. F. Yu, Carl A. Mike
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Patent number: 5783626Abstract: Provided are allyl-functional polymers having pendant enamine moieties and preferably also possessing pendant methacrylate groups. The presence of such groups in the polymer allows for a free-radical crosslinking reaction to take place during film formation and provides coatings having superior solvent resistance. Amino-containing waterborne particles can be prepared by reacting propylene imine with carboxylic acid-containing latexes. The amino-functionalized latexes are subsequently reacted at room temperature with for example acetoacetoxyethyl methacrylate. During ambient and thermal cure studies, clear films exhibited significant increases in solvent resistance, gel fraction, and crosslink density.Type: GrantFiled: March 15, 1996Date of Patent: July 21, 1998Inventors: James Wayne Taylor, Martha Jean Collins
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Patent number: 5783650Abstract: Polymers of one or more radical polymerisable monomers which polymer has pendant groups bearing a centre of permanent positive charge and other pendant groups capable of stably binding the polymer to a surface are useful in the treatment of surfaces to render them biocompatible. The polymers may contain pendant groups which bind the polymer to a surface by physisorption, covalent bonding or ionic interactions. Additionally reactive groups in the polymer may serve as points for attachment of ligands to the polymer when coated on a surface.Type: GrantFiled: June 7, 1995Date of Patent: July 21, 1998Assignee: Biocompatibles LimitedInventors: Roderick W. J. Bowers, Stephen A. Jones, Peter W. Stratford, Stephen A. Charles
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Patent number: 5756625Abstract: Stabilized microsphere adhesive composition comprising: a plurality of polymeric, elastomeric microspheres wherein the microspheres are the reaction product of reactants comprising polymerizable starting materials comprising at least one C.sub.4 -C.sub.14 alkyl (meth)acrylate monomer and optionally at least one comonomer, at least one vinyl-unsaturated additive having both an ionic moiety and a hydrophobic moiety and containing at least 5 but not more than 40 carbon atoms in an amount about 0.1 to 3 parts by weight of the microspheres; optionally, a polymeric stabilizer in an amount of between about 0.Type: GrantFiled: October 11, 1996Date of Patent: May 26, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Michael D. Crandall, Michael R. Kesti
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Patent number: 5747635Abstract: Modified polyaspartic acids useful as detergent and cleaner additives, as water treatment agents and as scale inhibitors in the evaporation of sugar juice are obtainable by polycondensation of(a) from 1 to 99.9 mol % of aspartic acid with(b) from 99 to 0.1 mol % of fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugarcarboxylic acids and/or non-proteinogenic aminocarboxylic acidsor by polymerizing monoethylenically unsaturated monomers in the presence of polyaspartic acids in the manner of a free-radically initiated graft polymerization.Type: GrantFiled: January 3, 1995Date of Patent: May 5, 1998Assignee: BASF AktiengesellschaftInventors: Matthias Kroner, Heinrich Hartmann, Dieter Boeckh, Angelika Funhoff, Richard Baur, Alexander Kud, Volker Schwendemann, Birgit Potthoff-Karl, Karl-Heinz Buechner
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Patent number: 5738806Abstract: Use of azo dyes having a diazo component derived from an aminothienothiophene and a coupling component of the aniline series in nonlinear optics, polymers derived from these azo dyes, the use thereof in nonlinear optics, and novel phenylthienothienylazoanilines.Type: GrantFiled: May 8, 1996Date of Patent: April 14, 1998Assignee: BASF AktiengesellschaftInventors: Stefan Beckmann, Karl-Heinz Etzbach, Ruediger Sens
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Patent number: 5739178Abstract: A polymeric material incorporating a polyvalent cation chelating agent in an amount effective to inhibit the growth of an ocular pathogen, particularly a protozoan, can be used to produce eye care products such as contact lens cases and containers for containing eye care solutions and contact lenses.Type: GrantFiled: May 15, 1995Date of Patent: April 14, 1998Assignee: AllerganInventors: Charles Hayes Powell, David C. Rupp
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Patent number: 5733714Abstract: The present invention relates to a novel antireflective coating solution and a process for its use in photolithography. The antireflective coating solution comprises a novel polymer and an organic solvent or a mixture of organic solvents, where the novel polymer comprises a unit containing a dye that absorbs from about 180 nm to about 450 nm and a unit containing a crosslinking group.Type: GrantFiled: September 30, 1996Date of Patent: March 31, 1998Assignee: Clariant Finance (BVI) LimitedInventors: Iain McCulloch, Ralph R. Dammel, Anthony J. Corso, Shuji Ding, Dana L. Durham, Ping-Hung Lu, Ming Kang, Dinesh N. Khanna
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Patent number: 5717048Abstract: The present invention provides a cation-modified linear copolymer which comprises, within the molecule thereof, 95 to 85 mole % of an ethylene structural unit, 0.1 to 10 mole % of an ester structural unit represented by general formula (II), 0.1 to 6 mole % of an acrylic or methacrylic acid structural unit and 1 to 12 mole % of an amide structural unit represented by general formula (IV). The copolymer has a weight-average molecular weight of 1,000 to 100,000. When incorporated in thermoplastic resins, it shows good compatibility and results in good mechanical properties.Type: GrantFiled: December 1, 1995Date of Patent: February 10, 1998Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Takayuki Tsubaki, Hideyuki Sumi, Hiroshi Hotta
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Patent number: 5714304Abstract: Organosilicon polymers, including crosslinked polymers and crosslinkable prepolymers, of cyclic polysiloxanes, organic dyes, and, optionally, polyenes. The dyes include those with delocalized Pi electron systems linking electron donor groups and electron acceptor groups, and with at least two carbon--carbon double bond-containing pendant groups attached to at least two different sites from among the indicated delocalized Pi electron systems, donor groups, and acceptor groups.Type: GrantFiled: June 2, 1995Date of Patent: February 3, 1998Assignee: Hercules IncorporatedInventors: Wayne M. Gibbons, Robert Paul Grasso, Michael Kevin O'Brien, Paul Joseph Shannon, Shao-Tang Sun
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Patent number: 5714558Abstract: Polyaspartic acid is prepared by polymerization of aspartic acid, maleic acid anhydride, maleic acid or fumaric acid in a solvent at from 130.degree. C. to 300.degree. C., optionally in the presence of ammonia.Type: GrantFiled: September 7, 1995Date of Patent: February 3, 1998Assignee: Bayer AGInventors: Torsten Groth, Winfried Joentgen, Nikolaus Muller
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Patent number: 5705583Abstract: Polymers of one or more radical polymerisable monomers which polymer has pendant groups bearing a center of permanent positive charge and other pendant groups capable of stably binding the polymer to a surface are useful in the treatment of surfaces to render them biocompatible. The polymers may contain pendant groups which bind the polymer to a surface by physisorption, covalent bonding or ionic interactions. Additionally reactive groups in the polymer may serve as points for attachment of ligands to the polymer when coated on a surface.Type: GrantFiled: June 7, 1995Date of Patent: January 6, 1998Assignee: Biocompatibles LimitedInventors: Roderick W. J. Bowers, Stephen A. Jones, Peter W. Stratford, Stephen A. Charles
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Patent number: 5693732Abstract: A paper coating formulation and a process for making a paper coating formulation having an improved strength and blister resistance including an aqueous medium having dispersed therein a functionally effective amount of a finely divided mineral filler and a latex binder containing copolymerized acid functional and amine functional monomers in each polymer molecule.Type: GrantFiled: January 8, 1996Date of Patent: December 2, 1997Assignee: GenCorp. Inc.Inventors: Satish C. Sharma, Charles M. Kausch, Ronald D. Mohan, Raymond J. Weinert
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Patent number: 5693744Abstract: An amorphous polyamide represented by the formula(2) ##STR1## in which each R is at least one alkylene radical having 1 to 10 carbon atoms, R' is an electron acceptor group represented by the formula(3), ##STR2## wherein Y is --C.tbd.N, --NO.sub.2, --SO.sub.2 --R(R.dbd.C.sub.n H.sub.2n+1, n=1 to 20 alkyl derivatives), ##STR3## R" is at least one aliphatic or aromatic divalent group having 2 to 20 carbon atoms, and n is an integer of more than 3, having second order nonlinear optical property, and a method for preparing the polymer by the polycondensation of dicarboxylic acid derivative, having second order nonlinear optical property in its side chain, with diamine are disclosed.Type: GrantFiled: June 21, 1995Date of Patent: December 2, 1997Assignee: Korea Research Institute of Chemical TechnologyInventors: Kil Yeong Choi, Moon Young Jin, Young Wun Kim
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Patent number: 5688906Abstract: A method for forming a polyamic acid having nonlinear optical (NLO) or pre-NLO side chains, which method includes the steps of:(1) providing a bis-(aromatic dicarboxylic acid anhydride) containing at least one NLO or pre-NLO side chain having the structure represented by:D-R-Awherein D, R and A form a delocalized resonance configuration in which R is a pi-conjugated non-centrosymmetric moiety, A is hydrogen or an electron withdrawing moiety and D is an electron donating moiety covalently linked to the bis-(aromatic dicarboxylic acid anhydride); and(2) reacting the bis-(aromatic dicarboxylic acid anhydride) with an aromatic diamine to form a polyamic acid having NLO or pre-NLO side chains. Methods for preparing polyamic acids having NLO or pre-NLO side chains by reacting aromatic diamines having NLO or pre-NLO side chains with bis-(aromatic dicarboxylic acid anhydrides) are also disclosed. Methods of forming the polyamic acids into polyimides having NLO side chains are also included.Type: GrantFiled: August 7, 1995Date of Patent: November 18, 1997Assignee: Enichem S.p.A.Inventors: Kwan-Yue Alex Jen, Kevin Joel Drost
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Patent number: 5684108Abstract: An ethylene-based copolymer which is suitable as a flow improver for mineral oil middle distillates and is composed ofa) from 50 to 94% by weight of ethylene;b) from 3 to 30% by weight of one or more vinyl esters of C.sub.2 -C.sub.6 -monocarboxylic acids;c) from 3 to 20% by weight of one or more aminoalkyl acrylates of the formula I ##STR1## which R.sup.1 is hydrogen or methyl, R.sup.2 and R.sup.3 are identical or different and are each hydrogen or C.sub.1 -C.sub.6 -alkyl and A.sup.1 is straight-chain or branched C.sub.2 -C.sub.10 -alkylene; andd) from 0 to 10% by weight of one or more monomers which are copolymerizable with the monomers a) to c), wherein copolymers containing vinyl acetate as monomer b) and having a number average molecular weight of from 5,000 to 50,000 are excluded from the scope of the copolymer.Type: GrantFiled: April 2, 1996Date of Patent: November 4, 1997Assignee: BASF AktiengesellschaftInventors: Hans-Joachim Muller, Bernd Wenderoth, Albin Berger, Dieter Littmann, Roger Klimesch, Knut Oppenlander, Bernd Lothar Marczinke, Thomas Ruhl, Marc Heider
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Patent number: 5677406Abstract: The invention relates to a difunctional perfluoropolyether oil, prepared by reacting a perfluoropolyether diol oil having a weight average molecular weight (Mw) of 1500 to 3000 with a chain lengthener selected from the group consisting of diacid chlorides and difunctional diisocyanates, and to perfluoropolyether rubbers prepared from these chain-lengthened oils.Type: GrantFiled: October 23, 1996Date of Patent: October 14, 1997Assignee: Oce-Nederland, B.V.Inventors: Frans W. Tazelaar, Peter R. Markies, Johannes A. van den Reek, Cornelius J.M. van der Stappen
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Patent number: 5674960Abstract: High refractive index copolymers comprised of monomers having the formula: ##STR1## wherein X is H or CH.sub.3 ; m is 0-10;Y is nothing, O, S, or NR wherein R is H, CH.sub.3, C.sub.n H.sub.2n+1 (n=1-10) iso OC.sub.3 H.sub.7, C.sub.6 H.sub.5, or CH.sub.2 C.sub.6 H.sub.5 ;Ar is an aromatic ring which is unsubstituted or substituted with H, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, OCH.sub.3, C.sub.6 H.sub.11, Cl, Br, C.sub.6 H.sub.5 or CH.sub.2 C.sub.6 H.sub.5 ; and n is 1-5; anda cross linking monomer having a plurality of polymerizable ethylenically unsaturated groups are disclosed. Intraocular lenses made of the copolymers which can be inserted into an aphakic eye through a relatively small incision are also disclosed.Type: GrantFiled: January 30, 1996Date of Patent: October 7, 1997Assignee: Nestle S.A.Inventors: Farhad Hod Namdaran, Albert Raymond LeBoeuf
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Patent number: 5663259Abstract: A network polymer that contains:(a) a plurality of polymer chains which are derived from one or more ethylenically-unsaturated monomer(s), and(b) at least one linking group which links the polymer chains and which contains anhydride, carbonate, or uretidinedione moieties.The network polymer and other network polymers which contain similar dissociating groups are useful in curable formulations which contain a curable compound that contains:(a) a central moiety, and(b) a plurality of reactive groups which are bonded to the central moiety and which react with acid, hydroxyl, or isocyanate moieties liberated by dissociation of the anhydride, carbonate, or uretidinedione moieties.The curable composition builds viscosity more slowly and more controllably during curing than equivalent systems which do not contain the network polymer. It is useful in coatings and other uses for curable compositions.Type: GrantFiled: May 31, 1995Date of Patent: September 2, 1997Assignee: The Dow Chemical CompanyInventors: Duane S. Treybig, Clinton J. Boriack
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Patent number: 5663262Abstract: The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.Type: GrantFiled: November 8, 1989Date of Patent: September 2, 1997Assignee: Nippon Paint Co., Ltd.Inventors: Shinsuke Shirakawa, Kazunori Kanda, Mitsuo Yamada, Kei Aoki, Satoshi Urano, Nobuaki Tomita