Contains Oxygen Atom Bonded To A Carbon Atom Patents (Class 526/312)
  • Patent number: 5407996
    Abstract: A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 independently represent a hydrogen atom or methyl;X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, C.sub.1 -C.sub.6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group --CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R.sup.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: April 18, 1995
    Assignee: Showa Denko K.K.
    Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Yoshikazu Hosoda
  • Patent number: 5408019
    Abstract: The invention relates to a cross-linked, water-absorbent polymer obtainable by the polymerization of a mixture consisting of a) 60-99%-wt. unsaturated, polymerizable monomers with acid groups which are neutralized to the extent of at least 30 mol-%, b) 0-37%-wt. monomers copolymerizable with a), c) 0.1-3.0%-wt. of a cross-linking agent and d) 0-10%-wt. of a water-soluble polymer, in which polymerization is conducted with a redox catalyst system containing formamidine sulfinic acid as reducing agent. The polymer is distinguished by a retention of greater than or equal to 28 g 0.9% aqueous NaCl-solution per 1 g of polymer, an absorption of greater than or equal to 26 g 0.9% aqueous NaCl-solution per 1 g of polymer at a load of 20 g/cm.sup.2 and a residual monomer content of less than 700 ppm, and preferably less than 500 ppm. The invention also relates to the use of this polymer in the production of hygiene articles.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: April 18, 1995
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Richard Mertens, Kurt Dahmen, Helmut Brehm
  • Patent number: 5408023
    Abstract: Addition polymers of ethylenically unsaturated monomers are provided comprising a 5-, 6- or 7-membered polymer unit formed from a copolymerizable, unsaturated, chain transfer agent containing a labile hydrogen and capable of forming by means of a hydrogen shift mechanism a free radical having 5, 6 or 7 atoms between and including the .alpha.-carbon of the ethylenically unsaturated group and the labile hydrogen.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: April 18, 1995
    Assignee: The Dow Chemical Company
    Inventors: Duane B. Priddy, Brian R. Maurer
  • Patent number: 5393853
    Abstract: Hydrogels presented in the form of pellets which are capable of regulating, without dissolving, any pH of an aqueous solution so as to convert it to a pH of 7. These pellets can be removed from the solution at any time without this modifying the pH, and once washed, can be used again. The velocity of buffering depends on the initial pH and can be controlled by modifying the mass and the composition of the pellets. They are obtained by copolymerization of a vinyl-heterocyclic comonomer and a divinyl comonomer in an aqueous solution at a temperature of close to 60.degree. C., in an inert atmosphere. By adjusting the proportion of crosslinking agent and the concentrations of comonomers, the crosslinking of the hydrogel is regulated in accordance with the intended use of the product.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: February 28, 1995
    Assignee: Universidad Nacional de Educacion A Distancia
    Inventors: Ma Rosa Gomez Anton, Ines F. de Pierola, Elena Morales Lujan, Ma Jesus Molina Lorenzo
  • Patent number: 5391669
    Abstract: A water swellable crosslinked polymer of essentially balanced charge is obtained by polymerizing a polymer-forming composition comprising a cationic-anionic pair of ethylenically unsaturated monomers and a non-ionic ethylenically unsaturated hydrophilic and/or hydrophobic monomer. Contact lenses formed from the polymer exhibit little if any tendency to attract soils, e.g., proteinaceous debris, to their surfaces.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: February 21, 1995
    Assignees: Hydron Limited, Ceskoslovenska akademie ved.
    Inventors: Jiri Sulc, Zuzana Krcova, Patrick Chen, Qi-Bin Bao
  • Patent number: 5385996
    Abstract: A process for the production of polymers by free radical polymerization, characterized in that there is added to the polymerization system one or more compounds of the general formula (A). ##STR1## where R.sup.1 is hydrogen or a group capable activating the vinylic carbon towards free radical addition;Y is OR.sup.2 or CH.sub.2 X(R.sup.2).sub.nwhere R.sup.2 is an optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, or optionally substituted saturated, unsaturated or aromatic, aromatic carbocyclic or heterocyclic ring;X is an element other than carbon selected from Groups IV, V, VI or VII of the Periodic Table or a group consisting of an element selected from Groups IV, V, or VI to which is attached one or more oxygen atoms; andn is a number from 0 to 3, such that the valency of the group X is satisfied and, when n is greater than 1, the groups represented by R.sup.2 may be identical or different.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: January 31, 1995
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Ezio Rizzardo, Gordon F. Meijs, San H. Thang
  • Patent number: 5384378
    Abstract: Copolymers with non-linear optical properties, which contain or are composed of repeating units of the formula (I) ##STR1## where D is an electron donor,A is an electron acceptor,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be the same as or different from one another, and are each H, alkyl, cycloalkyl, or R.sup.3 and R.sup.4 are each CN, NO.sub.2 or CHO, or R.sup.1 forms with R.sup.2, or R.sub.3 forms with R.sup.4, a fused-on ring,X is CH and/or N,m is an integer from 2 to 11, andR is hydrogen or methyl,and repeating units of at least one of the formulae (II), (III) and (IV) ##STR2## are suitable for the production of optical components.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: January 24, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Stefan Beckmann, Oskar Nuyken, Peter Strohriegl, Harry Mueller
  • Patent number: 5378765
    Abstract: A polymer useful for preparing shaped articles comprises essentially repeat units of the formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or methyl, andR.sup.3 is C.sub.6 -C.sub.14 -aryl, which may be monosubstituted, disubstituted or trisubstituted by radicals selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and halogen,and is obtainable by reacting a polymer based on C.sub.1 -C.sub.20 -alkyl esters of metharcylic acid or of arcylic acid or mixtures of such esters with an aromatic amine of the general formula IIR.sup.3 NH.sub.2 IIin the presence of an amine having a pK.sub.b value .ltoreq.9.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: January 3, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Siegmund Besecke, Andreas Deckers, Harald Lauke
  • Patent number: 5376306
    Abstract: High molecular weight buffering compositions and polymeric buffering compositions incorporating such compositions are described. The compositions are useful in applications where lower molecular weight buffers are unsatisfactory because of their tendency to leak out of an encapsulating membrane. Methods of making such compositions are described, as well as a particular application in a fiber optic carbon dioxide physiological probe.
    Type: Grant
    Filed: November 5, 1993
    Date of Patent: December 27, 1994
    Assignee: Abbott Laboratories
    Inventors: Lokanathan M. Iyer, Kenneth S. Lyon, Vince Brotherton
  • Patent number: 5369176
    Abstract: The present invention relates to a reaction injection molding process, to a composition utilized therein as well as to a kit of parts from which the composition can be obtained. In particular, the process includes the use of a composition which contains at least 70% of low molecular weight compounds which are capable of forming a crosslinked polymer. The first component of the composition is a compound with at least an ethylenic unsaturation and an isocyanate-reactive group. The second component of the composition contains an ethylenically unsaturated monomer capable of copolymerizing with the first component. The third component of the composition is a polyisocyanate. Polymerization of the first and second components takes places prior to the reaction between the first and third components.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: November 29, 1994
    Assignee: DSM N.V.
    Inventor: Adrianus De Koning
  • Patent number: 5369142
    Abstract: Glass ionomer cements for dental restoratives with improved physical properties are produced by the present invention. Acryloyl and methacryloyl derivatives of amino acids are used in the invention to copolymerize with acrylic acid, methacrylic acid or various acrylic acid-comonomer mixtures to produce water soluble polycarboxylic acids.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: November 29, 1994
    Assignee: The Ohio State University
    Inventors: Billy M. Culbertson, Elizabeth C. Kao
  • Patent number: 5360881
    Abstract: Diallyloxyacetic acid and its basic addition salts, their preparation process and their application as cross-linking agents.Diallyloxyacetic acid and its basic addition salts, preparation process and application as cross-linking agents.
    Type: Grant
    Filed: May 24, 1993
    Date of Patent: November 1, 1994
    Assignee: Societe Francaise Hoechst
    Inventors: Paul Mallo, Christian Sidot, Alain Blanc, Yani Christidis
  • Patent number: 5354825
    Abstract: A fiber optic sensing device for measuring a chemical or physiological parameter of a body fluid or tissue is provided. To one end of the fiber is attached a polymer including a plurality of photoactive moieties selected from the group consisting of chromophores and lumophores, the photoactive moieties spaced apart so as to minimize chemical or physical interaction therebetween while optimizing the density of photoactive moieties. In one embodiment, a polymer chain is covalently bound to photoactive moieties through functional groups such as esters, amides, or the like. In a second embodiment, a polymer chain is inherently fluorescent and is formed from at least one monomeric unit. These devices are particularly useful as pH and oxygen sensors.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: October 11, 1994
    Inventors: Stanley M. Klainer, David R. Walt, Amos J. Gottlieb
  • Patent number: 5342901
    Abstract: The invention provides a film-formable, chelate-forming resin having, per 1000 g of the resin, about 0.2 to about 3.5 moles of chelate-forming group represented by the formula [1], [2], [3] or [4]: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and each represents a hydrogen atom, a halogen atom, a nitro group, a nitroso group, a cyano group, a hydrocarbon group having up to 18 carbon atoms, or an alkoxyalkyl group having up to 12 carbon atoms, and a process for preparing the resin.The invention also provides a metal surface treating composition and a corrosion preventive coating composition both containing the above chelate-forming resin, and a chelate-forming resin composition comprising the resin and a crosslinking agent.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: August 30, 1994
    Assignee: Kansai Paint Company, Limited
    Inventors: Hideo Kogure, Heihachi Murase, Masafumi Kume
  • Patent number: 5338816
    Abstract: A hydrophobic polyelectrolyte copolymer which is useful in the removal of color in paper mill waste water. The copolymer preferably comprises diallyldimethylammonium chloride and a hydrophobic monomer selected from the group consisting of quaternized dimethylaminoethylacrylates and quaternized dimethylaminoethylmethacrylates.
    Type: Grant
    Filed: October 7, 1993
    Date of Patent: August 16, 1994
    Assignee: Nalco Chemical Company
    Inventors: Manian Ramesh, John W. Sparapany, Martha R. Finck, Kristine S. Siefert, Chandrashekar S. Shetty
  • Patent number: 5334679
    Abstract: The present invention is directed to a method for production of a water-soluble cationic polymer comprising polymerizing a cationic vinyl monomer; either a cationic acrylate monomer alone or a mixture of said monomer and another monomer copolymerizable therewith, in dispersion medium in the presence of a surfactant by suspension polymerization method. The present invention offers an industrially advantageous method to obtain the water-soluble cationic polymer with a high degree of cationization and a high viscosity in water solution which can be used for flocculants, antistatic agents, retention aids for paper manufacturing and other purposes.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: August 2, 1994
    Assignee: Sumitomo Seika Chemicals Co., Ltd.
    Inventors: Takushi Yamamoto, Hiroari Hara, Nobuhiro Maeda, Morio Nakamura
  • Patent number: 5326814
    Abstract: A binder for use in high gloss latex paints comprises water, a copolymer, and less than about 1 weight percent surfactant. The copolymer comprises about 25 to about 60 weight percent soft monomer, about 40 to about 75 weight percent hard monomer, and about 1 to about 3 weight percent olefinic carboxylic acid monomer. In addition, the copolymer comprises about 0.5 to about 3 weight percent copolymerizable surfactant monomer and/or (i) about 0.5 to about 4 weight percent additional monomer selected from the group consisting of cyanoacetoxy-containing monomers and acetoacetoxy-containing monomers and (ii) about 0.5 to about 3 weight percent ethyleneureido-containing monomer.
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: July 5, 1994
    Assignee: Rohm and Haas Company
    Inventor: John Biale
  • Patent number: 5322753
    Abstract: An electrophotographic photoconductor is composed of a substrate and a photoconductive layer formed thereon. The photoconductive layer is composed of a polymer including an acrylic acid ester moiety of formula (I) as repeat unit: ##STR1## wherein R.sup.1 represents hydrogen or a methyl group; R.sup.2, R.sup.3, and R.sup.4 each represent an alkyl group having 1 to 4 carbon atoms, a benzyl group, a phenyl group, a phenoxyl group, chlorine or bromine; n is an integer of 1 to 4; m is 0 or 1; and k is 0 or 1.The polymer and the monomer from which the polymer is prepared are synthesized.
    Type: Grant
    Filed: July 13, 1992
    Date of Patent: June 21, 1994
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Tamura, Toshio Fukagai, Naoshi Mishima, Masaomi Sasaki
  • Patent number: 5322632
    Abstract: A lubricating oil viscosity index improvement additive with dispersant and ntioxidant properties of general formula: ##STR1## where R' is hydrogen or an alkyl, R.sub.a and R.sub.b are alkyl radicals, R.sub.c is a nitrogenated alkyl radical and x, y and z represent relative quantities. The invention also relates to the process for preparing said additive and lubricating oil compositions which contain it.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: June 21, 1994
    Assignee: Ministero Dell `Universita` E Della Ricerca Scientific e Technologica
    Inventors: Paola Gambini, Paolo Koch, Alberto Santambrogio
  • Patent number: 5319045
    Abstract: A copolymer having repeating units of the following formula (I) and repeating units of the formula (II), wherein the ration of (I) to (II) is within a range of from 10:90 to 90:10 by weight ratio, and the number average molecular weight is at least 1,000, or the intrinsic viscosity .eta..sub.inh is at least 0.02: ##STR1## wherein A is a polyester unit having a polymerization degree of from 2 to 200, R.sup.3 is a bivalent organic group having an ester, urethane or ketone bond, and R.sup.4 is a hydrogen atom or a methyl group, ##STR2## wherein R.sup.5 is a hydrogen atom or a methyl group, and X is a substituent having functionality.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: June 7, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takayuki Ohta, Hiroaki Yamaoka, Junichi Gotoh, Shiho Sano
  • Patent number: 5319046
    Abstract: A novel synthesis of N-acryloyl-tris-(hydroxymethyl)aminomethane (NAT) is described. The polymerization kinetics and transparency of the poly(NAT) gels crosslinked by a crosslinker (CL) e.g. N,N'-methylenebisacrylamide (Bis), i.e. poly(NAT+Bis) polymer, are shown. Poly(NAT+Bis) gradient (4-24%) gels were prepared and found to resolve native proteins according to their size. The exclusion limit of these gels is over 3.times.10.sup.6 Da. This is more than threefold higher than the exclusion limit of the polyacrylamide gradient gel of the same concentration. Therefore poly(NAT+CL) gels are better than polyacrylamide gels for the resolution of large proteins. It was demonstrated that poly(NAT+CL)-polyacrylamide composite gels could be prepared. The poly(NAT+CL) gels were found to be advantageous also for isoelectric focussing in carrier ampholytes or immobilized pH gradients. Poly(NAT+CL) gels are also very good for separation of nucleic acids.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: June 7, 1994
    Assignee: Elchrom, Ltd.
    Inventors: Branko Kozulic, Klaus Mosbach
  • Patent number: 5314975
    Abstract: The present invention provides novel fluorinated acrylamide silane monomers which are useful as adhesion promoting agents in optical fiber cladding compositions. Polymerization of the novel monomers, optionally in the presence compatible ethylenically-unsaturated monomers, provides homopolymers and copolymers which are useful as non-wetting agents.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: May 24, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Stefan A. Babirad, Dean M. Moren, Steven M. Heilmann, Larry R. Krepski, Jerald K. Rasmussen
  • Patent number: 5312897
    Abstract: Electroactive polymers are provided which contain alternating phenyl rings and nitrogen atoms, and which contain both quinoid mer units and benzenoid mer units. The polymers are formed by poly(condensation) of N-phenylhydroxylamine or derivatives thereof under anhydrous conditions in the presence of a Lewis acid catalyst. Methods for producing films, fibers and shaped articles of the polymers are provided as well.
    Type: Grant
    Filed: August 11, 1992
    Date of Patent: May 17, 1994
    Assignee: Neste Oy
    Inventor: Floyd Klavetter
  • Patent number: 5310837
    Abstract: The invention relates to liquid crystalline polymers which form exclusively nematic liquid crystalline phases. The liquid crystalline polymers are comprised of units of at least trinuclear liquid crystalline azo dye monomers M with lateral asymmetry.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: May 10, 1994
    Assignee: Roehm GmbH Chemische Fabrik
    Inventor: Michael May
  • Patent number: 5302460
    Abstract: A support material for photosensitive substances, useful in the production of offset-printing plates, is disclosed. The support material comprises mechanically, chemically or electrochemically roughened aluminum or an aluminum alloy in the form of a sheet, a foil or a web, and which is coated on at least one side with a hydrophilic polymer which comprises (a) at least 2 mol% of units having acidic side groups and (b) at least 2 mol% of units having basic side groups which are capable of being protonated.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: April 12, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Engelbert Pliefke, Raimund J. Faust
  • Patent number: 5300606
    Abstract: A liquid absorption agent for water or organic solvents comprising, as a main component, a crosslinked N-vinylcarboxylic acid amide resin comprising the backbone chain of a homopolymer or copolymer comprising repeating units of the formula shown below crosslinked with a crosslinking agent: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 independently represent a hydrogen atom or methyl;X represents a group --COOY, wherein Y represents a hydrogen atom, an alkali metal, C.sub.1 -C.sub.6 alkyl, or lower alkyl substituted with hydroxyl, dialkylamino or quaternary ammonium group; a group --CONHZ, wherein Z represents a hydrogen atom or lower alkyl substituted with a dialkylamino group, quaternary ammonium group, sulfonic acid or an alkali metal salt thereof; cyano, 2-ketopyrrolidinyl, lower alkoxy, lower acyl, lower acyloxy or lower alkyl substituted with sulfonic acid or an alkali metal salt thereof, with a proviso that when R.sup.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: April 5, 1994
    Assignee: Showa Denko K.K.
    Inventors: Toshiyuki Aizawa, Hitoshi Nakamura, Yoshikazu Hosoda
  • Patent number: 5294693
    Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral or organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: March 15, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5294692
    Abstract: Novel mono- and multi-functional non-ionic urethane monomers are prepared from surfactants comprising poly(ethylene oxide)(butylene oxide) copolymers, preferably C.sub.1 -C.sub.4 alkoxy-terminated, monohydric, ethylene oxide/butylene oxide block polymers and monoethylenically unsaturated aliphatic isocyanates. When polymerized with, e.g. acrylic acid or alkyl acrylates, these monomers provide copolymers exhibiting greatly enhanced thickening efficiency.
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: March 15, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Milagros C. Barron, John M. Wilkerson, III, Daniel W. Verstrat
  • Patent number: 5290892
    Abstract: High refractive index copolymers comprised of monomers having the formula: ##STR1## wherein X is H or CH.sub.3 ;m is 0-10;Y is nothing, O, S, or NR wherein R is H, CH.sub.3, C.sub.n H.sub.2n+1 ; (n=114 10) iso OC.sub.3 H.sub.7, C.sub.6 H.sub.5, or CH.sub.2 C.sub.6 H.sub.5 ;Ar is an aromatic ring which is unsubstituted or substituted with H, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, OCH.sub.3, C.sub.6 H.sub.11, Cl, Br, C.sub.6 H.sub.5 or CH.sub.2 C.sub.6 H.sub.5 ;and n is 1-5; anda cross linking monomer having a plurality of polymerizable ethylenically unsaturated groups are disclosed. Intraocular lenses made of the copolymers which can be inserted into an aphakic eye through a relatively small incision are also disclosed.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: March 1, 1994
    Assignee: Nestle S.A.
    Inventors: Farhad H. Namdaran, Albert R. LeBoeuf
  • Patent number: 5283306
    Abstract: A hydrophobic polyelectrolyte copolymer which is useful in the removal of color in paper mill waste water. The copolymer preferably comprises diallyldimethylammonium chloride and a hydrophobic monomer selected from the group consisting of quaternized dimethylaminoethylacrylates and quaternized dimethylaminoethylmethacrylates.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: February 1, 1994
    Assignee: Nalco Chemical Company
    Inventors: Manian Ramesh, John W. Sparapany, Martha R. Finck, Kristine S. Siefert, Chandrashekar S. Shetty
  • Patent number: 5281631
    Abstract: An ion exchange resin for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene disphosphonic acid with styrene, acrylonitrile and divinylbenzene.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: January 25, 1994
    Assignee: Arch Development Corp.
    Inventors: E. Philip Horwitz, Spiro D. Alexandratos, Ralph C. Gatrone, Ronato Chiarizia
  • Patent number: 5280093
    Abstract: The present invention relates to chiral polymers and to their uses for operations of asymmetric synthesis, deracemization and optical inversion.These polymers are characterized in that they comprise:a chiral unita functionalizing unitan optional crosslinking unitApplication to chiral organic synthesis.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: January 18, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventors: Robert Jacquier, Monique Calmes, Jacques Daunis
  • Patent number: 5277739
    Abstract: Adhesive component formulations containing (meth)acrylic acid esters, containing formamide groups, and optionally an initiator, which are used as an adhesive component for the treatment of collagen-containing materials.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: January 11, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Bernd Alker
  • Patent number: 5274045
    Abstract: A self-crosslinkable resin useful as, for example, adhesive compositions and coating compositions. The resin contains complementary reactive groups, that is, a blocked isocyanate group and a hydroxyl group, in the same molecule. The resin is prepared by reacting a hydroxy-containing vinyl monomer with some isocyanate groups on the skeleton of a vinyl polymer having at least two isocyanate groups in the molecule so to introduce a polymerizable double bond into the polymer, and subsequently completely blocking the isocyanate group(s) remaining on the polymer skeleton with a blocking agent, or vice versa. Thereafter an unsaturated monomer component consisting essentially of a hydroxyl-containing vinyl monomer is polymerized with the polymerizable double bond introduced.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: December 28, 1993
    Assignee: Kansai Paint Company, Limited
    Inventors: Yoshiyuki Yukawa, Motoshi Yabuta, Yasushi Nakao
  • Patent number: 5272002
    Abstract: An optical article is disclosed comprised of an organic layer unit exhibiting a second order polarization susceptibility greater than 10.sup.-9 esu and means for providing an optical input to and an optical output from the layer unit. The organic layer unit exhibits a transmission attenuation of less than 2 dB/cm and is comprised of a Y type Langmuir-Blodgett assembly having superimposed oriented monomolecular layers of first and second polymeric amphiphiles each containing repeating units comprised of a hydrophilic moiety and a lipophilic moiety. Repeating units of one or both of the first and second amphiphiles each contain an organic molecular dipole, and repeating units of one or both of the first and second amphiphiles each contains a branched lipophilic moiety of up to 9 carbon atoms.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: December 21, 1993
    Assignee: Eastman Kodak Company
    Inventors: Thomas L. Penner, Douglas R. Robello, Nancy J. Armstrong, David J. Williams, Matthew C. Ezenyilimba
  • Patent number: 5270415
    Abstract: A water swellable crosslinked polymer of essentially balanced charge is obtained by polymerizing a polymer-forming composition comprising a cationic-anionic pair of ethylenically unsaturated monomers and a nonionic ethylenically unsaturated hydrophilic and/or hydrophobic monomer. Contact lenses formed from the polymer exhibit little if any tendency to attract soils, e.g., proteinaceous debris, to their surfaces.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: December 14, 1993
    Assignees: Allergan Inc., Ceskoslovenska akademie ved
    Inventors: Jiri Sulc, Zuzana Krcova, Patrick Chen, Qi-Bin Bao
  • Patent number: 5268437
    Abstract: This invention relates to high temperature aqueous processes for the polymerization of monoethylenically unsaturated carboxylic monomers to produce low molecular weight, water-soluble polymer products useful as detergent additives, scale inhibitors, dispersants and crystal growth modifiers. Suitable monomers include acrylic acid, methacrylic acid, maleic acid, maleic anhydride, crotonic acid, and itaconic acid. The reactions are run at temperatures ranging from about 130.degree. C. to 240.degree. C., preferably from about 140.degree. C. to about 230.degree. C. The process can be continuous, semi-continuous, or batch.
    Type: Grant
    Filed: January 22, 1992
    Date of Patent: December 7, 1993
    Assignee: Rohm and Haas Company
    Inventors: Norman L. Holy, Newman M. Bortnick, Graham Swift, Kathleen A. Hughes
  • Patent number: 5264507
    Abstract: Azo dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where D is the radical of a heterocyclic diazo component,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, and R.sup.2 may also be C.sub.1 -C.sub.4 -alkanoylamino,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each substituted or unsubstituted C.sub.2 -C.sub.10 -alkylene,W is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino,and have an average molecular weight of from 1,000 to 100,000.
    Type: Grant
    Filed: September 23, 1992
    Date of Patent: November 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Wiesenfeldt, Sabine Gruettner-Merten, Ruediger Sens, Karl-Heinz Etzbach, Heike Kilburg
  • Patent number: 5258478
    Abstract: Polymers containing covalently-bonded, low self-absorbing, scintillating chromophores, polymerizable chromophores of the formula: ##STR1## wherein R.sub.1 is vinyl, .alpha.-methyl vinyl, vinyl phenyl, or vinyl benzyl, and R.sub.2 and R.sub.3 are independently hydrogen, alkyl, aryl, cyano, nitro, halo, or ether, and a process for the preparation of polymers containing low self-absorbing, scintillating chromophores.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: November 2, 1993
    Assignee: Florida State University
    Inventors: Joseph B. Schlenoff, Jayesh Dharia, Kurtis F. Johnson
  • Patent number: 5256746
    Abstract: Monoalkyl phosphinate and monoalkyl phosphonate derivatives of low molecular weight water soluble polymers are preferentially prepared by copolymerizing hypophosphorous acid, monoethylenically unsaturated monocarboxylic acid(s) and an effective amount of a C.sub.3 -C.sub.8 monoethylenically unsaturated dicarboxylic acid.
    Type: Grant
    Filed: April 25, 1991
    Date of Patent: October 26, 1993
    Assignee: Rohm and Haas Company
    Inventors: Robert M. Blankenship, Scott L. Egolf
  • Patent number: 5256315
    Abstract: Gellable compositions containing:(a) water;(b) a water-soluble organic polymer bearing special chelating functional groups;(c) a multi-valent metal ion capable of causing the polymer to crosslink,are useful to recover oil from a oil field.Said compositions make it possible gels to be obtained which are endowed with improved physical properties and show a higher stability under the conditions prevailing in the oil field.
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: October 26, 1993
    Assignees: Eniricerche S.p.A., AGIP S.p.A.
    Inventors: Thomas P. Lockhart, Fabrizio Bonaccorsi
  • Patent number: 5254650
    Abstract: A process for the copolymerization of styrene or .alpha.-methylstyrene with an unsaturated acid derivative is disclosed. The process is carried out in the presence of a tetrafunctional organic peroxide and produces copolymeric products having significantly improved properties.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: October 19, 1993
    Assignee: Kayaku Akzo Corporation
    Inventor: Takumi Fukumura
  • Patent number: 5252251
    Abstract: A mesomorphic polymer comprises recurring units of the following formula (I): ##STR1## wherein U denotes a polymer main chain unit; V denotes --(CH.sub.2).sub.m -- or --((CH.sub.2).sub.2 --O).sub.m -- each capable of having a substituent selected from alkyl group, halogen atom, amino group or carbonyl group substituting one or more of the hydrogen atoms wherein m is an integer of 0-30; W denotes a single bond, --O--, --OCO--, --COO--, CONR.sup.1 --, --CO-- or --NR.sup.1 -- wherein R.sup.1 denotes hydrogen atom or alkyl group; X denotes a mesogen unit comprising at least two rings selected from aromatic carbon rings, aromatic heterocyclic rings and alicyclic rings each capable of having a substituent and connected with a single bond, --O--, --OCO--, --COO--, --(CH.sub.2).sub.n --, --N.dbd.N--, --(CH.dbd.CH).sub.m --, --CH.dbd.N--, --N.dbd.CH--, --(C.ident.C).sub.n 13 , --CONR.sup.1, --(CO).sub.n -- or NR.sup.1 -- wherein R.sup.1 is the same as defined above and n is an integer of 1-10; Y denotes --COOCH.sub.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: October 12, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Yutaka Kurabayashi, Kazuo Yoshinaga, Yomishi Toshida
  • Patent number: 5248749
    Abstract: A homopolymer or a copolymer comprises a polymerizable compound represented by formula (I):A--X--COCOOR.sub.1 (I)whereinR.sub.1 represents a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group or an aryl group;X represents an oxygen atom, a sulfur atom, --COO-- or --NR.sub.5 --whereinR.sub.5 is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group;A represents a C.sub.3 -C.sub.18 alkenyl, alkynyl, alkenylaryl or alkenylaralkyl group, or a group represented by: ##STR1## wherein R.sub.2 and R.sub.3, which may be the same or different, independently represent a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group;Y represents an oxygen atom or --NR.sub.4 -- wherein R.sub.4 represents a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group; n is an integer of 1 to 5; m is an integer of 1 to 10; and l is 0 or an integer of 1 to 20;with the proviso that if Y is present, X is not --NR.sub.5 --. Additionally, disclosed are processes of preparing the homopolymer or copolymer as well as the polymerizable compound.
    Type: Grant
    Filed: April 1, 1992
    Date of Patent: September 28, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Urano Satoshi, Aoki Kei, Tomita Nobuaki, Mori Hirohiko
  • Patent number: 5248757
    Abstract: Compounds containing at least one cyanate group, at least one maleimide group and at least one rodlike mesogenic moiety are prepared by reacting one or more aminophenols containing one or more rodlike mesogenic moieties with a stoichiometric quantity of a maleic anhydride per amine group of said aminophenol and then cyanating the resulting phenolic functional maleimide.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: September 28, 1993
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5248758
    Abstract: Compounds containing at least one cyanate group, at least one maleimide group and at least one rodlike mesogenic moiety are prepared by reacting one or more aminophenols containing one or more rodlike mesogenic moieties with a stoichiometric quantity of a maleic anhydride per amine group of said aminophenol and then cyanating the resulting phenolic functional maleimide.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: September 28, 1993
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5247035
    Abstract: At least 95% tetrahydrofuran soluble polymers are obtainable by copolymerization of a monomer mixture ofA) from 1 to 99% by weight of at least one at least 98% pure monomer of the general formula ICH.sub.2 .dbd.C(E)CH.sub.2 --O--CH.sub.2 C(E').dbd.CH.sub.2 Iwhere E and E' have been selected from the group consisting of --COOR.sup.1, --COR.sup.1, --CONR.sup.2 R.sup.3 and --CN and R.sup.1, R.sup.2 and R.sup.3 are each defined as follows:R.sup.1 =H, alkyl, cycloalkyl, cycloalkylalkyl, wherein the cycloalkyl rings may be alkyl- or alkoxy-monosubstituted, -disubstituted or -trisubstituted, hydroxyalkyl, aminoalkyl, alkylaminoalkyl, dialkylaminoalkyl, aryl, arylalkyl, wherein the aryl groups may carry up to three of the following groups: halogen, alkyl, alkoxy, carboxyl, alkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, nitrilo, nitro, amino, alkylamino, dialkylamino;R.sup.2, R.sup.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: September 21, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Siegmund Besecke, Andreas Deckers, Harald Lauke
  • Patent number: 5247042
    Abstract: This invention provides novel side chain polymers which exhibit nonlinear optical response, and which have utility as a transparent optical component in all-optical and electrooptical light switch and light modulator devices.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: September 21, 1993
    Assignee: Hoechst Celanese Corp.
    Inventors: Diane E. Allen, Ronald N. DeMartino, Hyun-Nam Yoon
  • Patent number: 5247038
    Abstract: Disclosed herein is a polybutylene glycol dimethacrylate which provides various kinds of plastics having good flexibility and low water absorption. Disclosed also herein is a resin composition for cast polymerization which provides molded products which have high heat resistance, good flexibility, and low water absorption, without sacrificing impact resistance and surface hardness. They will find use as optical materials, lenses, etc.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: September 21, 1993
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hiroshi Fukushima, Akira Motonaga, Eriko Suda, Susumu Sugitani
  • Patent number: 5244988
    Abstract: Copolymers of aliphatic monoethylenically unsaturated dicarboxylic acids and unsaturated monomers have been formed by gradually and simultaneously adding monomers and initiator, in the presence of a metal salt activator, to a reaction vessel initially containing water at a temperature suitable for polymerization. These copolymers have consistent compositions and superior properties as antiscalants, dispersants and incrustation inhibitors.
    Type: Grant
    Filed: March 30, 1990
    Date of Patent: September 14, 1993
    Assignee: Rohm and Haas Company
    Inventors: Kathleen A. Hughes, Graham Swift