Monomer Containing At Least Two Carboxylic Acid Ester Groups Patents (Class 526/321)
  • Patent number: 6528606
    Abstract: Disclosed is a method of preparing a stable composition of radically copolymerizable monomers, said composition containing firstly at least one monomer which has at least one urea function in its formula and secondly at least one monomer which does not have an isocyanate function in its formula, said method comprising preparing said monomer(s) having urea function(s) by reaction of two types of reagent: at least one radically copolymerizable monomer which has at least one isocyanate function in its formula with at least one amine selected from primary and secondary amines, and incorporating said monomer(s) which does(do) not have an isocyanate function in its(their) formula, prior to said reaction, together with one of said reagents, before adding the other of said reagents, and/or during the addition of said reagents, and/or after said reaction.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: March 4, 2003
    Assignee: Corning S.A.
    Inventors: Marie-Maud Bear, Xavier Lafosse
  • Patent number: 6525155
    Abstract: Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: February 25, 2003
    Inventors: John Larry Sanders, James Michael Kimmerly, Grigory Mazo
  • Patent number: 6518382
    Abstract: Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: February 11, 2003
    Inventors: John Larry Sanders, James Michael Kimmerly, Grigory Mazo
  • Patent number: 6515091
    Abstract: Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: February 4, 2003
    Inventors: John Larry Sanders, James Michael Kimmerly, Grigory Mazo
  • Patent number: 6515089
    Abstract: Provided are a method, upon radical copolymerization of a vinyl-containing porphyrin compound and a radically polymerizable monomer, thereby obtaining a porphyrin-nucleus introduced polymer, of controlling reactivity of the porphyrin-nucleus introduced polymer with a metal by selecting the radically polymerizable monomer; and a method for measuring a trace metal by measuring a change in absorbance caused by a complex forming reaction between a porphyrin-nucleus introduced polymer, which has been obtained by radical copolymerization of a vinyl-containing porphyrin compound and a radically polymerizable monomer, and a heavy metal ion, the radically polymerizable monomer being selected so as to heighten reaction selectivity of the porphyrin-nucleus introduced polymer to a metal to be measured.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: February 4, 2003
    Assignee: Kowa Co., Ltd.
    Inventors: Takaharu Asano, Hiroshi Nakao
  • Patent number: 6515092
    Abstract: Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.
    Type: Grant
    Filed: December 17, 2001
    Date of Patent: February 4, 2003
    Inventors: John Larry Sanders, James Michael Kimmerly, Grigory Mazo
  • Patent number: 6515090
    Abstract: Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: February 4, 2003
    Inventors: John Larry Sanders, James Michael Kimmerly, Grigory Mazo
  • Patent number: 6506535
    Abstract: Disclosed is a positive working photoresist composition comprising an acid-decomposable polymer containing at least a repeating unit represented by the following formula (I) and at least either one repeating unit represented by the following formula (IIa) or (IIb), and also disclosed is a positive working photoresist composition comprising (A) a compound capable of generating an acid upon irradiation with actinic rays or radiation, (B) an acid-decomposable polymer containing at least a repeating unit represented by the following formula (I) and at least either one repeating unit represented by the following formula (IIa) or (IIb), (C) at least one solvent capable of dissolving the components (A) and (B), (D) an organic basic compound and (E) at least one surfactant selected from fluorine-containing surfactants, silicon-containing surfactants and nonionic surfactants:
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: January 14, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuyoshi Mizutani, Kenichiro Sato, Kunihiko Kodama
  • Patent number: 6458174
    Abstract: Copolymers containing A) from 45 to 54 mol % of divalent structural units of the formula 1 in which a and b=0 or 1 and a+b=1, B) from 35 to 53 mol % of divalent structural units of the formula 2 —H2C—CHR2—  (2) and C) from 1 to 25 mol % of divalent structural units derived from polyolefins, where the polyolefins can be derived from monoolefins having 3 to 5 carbon atoms, wherein a) R1 is an alkyl or alkenyl radical having 10 to 40 carbon atoms or an alkoxyalkyl radical having 1 to 100 alkoxy units and 1 to 30 carbon atoms in the alkyl radical, and b) R2 is an alkyl radical having 10 to 50 carbon atoms, c) the alkylvinylidene content of the polyolefins on which the structural units C) are based is at least 50 mol %, and d) the number of carbon atoms in the polyolefin molecules on which the structural units C) are based is from 35 to 350.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: October 1, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Waltraud Nagel
  • Patent number: 6455653
    Abstract: The invention provides compositions for producing lenses by casting. The compositions are useful in producing ophthalmic lens by casting of a surface or layer onto a preform.
    Type: Grant
    Filed: May 8, 2000
    Date of Patent: September 24, 2002
    Assignee: Johnson & Johnson Vision Care, Inc.
    Inventors: Ivan Nunez, Venkat Sekharipuram, Michele Alton
  • Patent number: 6451950
    Abstract: A polymer dispersant for pigments based on a random copolymer wherein the copolymer has a weight average molecular weight of at least 3000 and comprises a polymeric backbone of primarily acrylic monomers wherein the backbone contains multiple pigment anchoring groups attached thereto including at least one amide group and one or more additional pigment anchoring groups selected from the group consisting of aromatic esters, aromatic amines, and quaternary ammonium salts. These materials disperse a wide variety of pigments and are useful in solvent borne coatings where they can provide improved efficiency of pigment use, lower paint viscosity, and reduced emission of volatile organic solvent.
    Type: Grant
    Filed: July 5, 2000
    Date of Patent: September 17, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Sheau-Hwa Ma
  • Patent number: 6451951
    Abstract: The present invention relates to an oligomer with a semi-telechelic nitrogen-functionality and at least one ethylenic unsaturation pendant to the backbone of the oligomer. In addition, a process is provided to prepare the semi-telechelic nitrogen-functional oligomer. The semi-telechelic nitrogen-functional oligomer is useful as a dispersant for pigments in radiation curable formulations.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: September 17, 2002
    Assignee: Rohm and Haas Company
    Inventors: Ronald Scott Beckley, Barry Clifford Lange, David William Whitman, Jo Ann Arceneaux, Michael Christopher Kramer, Peter Thomas Weissman
  • Publication number: 20020128342
    Abstract: New polymers, compositions comprising these polymers, and methods of using these compositions are provided. The polymers comprise styrene and maleic anhydride monomers with at least some of the maleic anhydride monomers having certain functional groups bonded thereto. Preferred functional groups include those derived from adhesion promoters (e.g., 2-aminophenol), photoinitiators (e.g., 4-aminoacetophenone), and solubilizers (e.g., 4-aminobenzoic acid). The polymers can be incorporated according to conventional processes into compositions which are then used to form a color filter to be used in a liquid crystal display. The final color filter has a high resolution, is highly resistant to solvents typically used in the color filter manufacturing process, is strongly adhered to the color filter substrate, has superior optical clarity, is highly soluble in a wide range of alkali developers, and has excellent heat and UV light stability.
    Type: Application
    Filed: February 25, 2002
    Publication date: September 12, 2002
    Inventors: Gu Xu, Dan W. Brewer, Timothy Limmer, Mike Stroder, Shelly Fowler, Jonathon Mayo
  • Patent number: 6448352
    Abstract: The present invention provides novel bicyclic photoresist monomers, and photoresist copolymer derived from the same. The bicyclic photoresist monomers of the present invention comprise both amine functional group and acid labile protecting group, and are represented by the formula: where m, n, R, V and B are those defined herein. The photoresist composition comprising the photoresist copolymer of the present invention has excellent etching resistance and heat resistance, and remarkably enhanced PED stability (post exposure delay stability).
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: September 10, 2002
    Assignee: Hyundai Electronics Industries Co., Ltd.
    Inventors: Min Ho Jung, Jae Chang Jung, Geun Su Lee, Ki Ho Baik
  • Patent number: 6437067
    Abstract: Provided are porphyrin-nucleus introduced polymers obtained by radical copolymerization of a radically polymerizable monomer with a porphyrin compound represented by formula (1) or (2): where R represents a hydrogen atom or a C1-6 alkyl group. Also provided are a trace metal measuring reagent and a trace metal removing agent, each containing the porphyrin-nucleus introduced polymer. The porphyrin-nucleus introduced polymer can be obtained as a compound having desired properties or reactivity by making use of easily available porphyrin compounds. The polymer is useful as a reagent for measuring or an agent for removing heavy metals.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: August 20, 2002
    Assignee: Kowa Co., Ltd.
    Inventors: Takaharu Asano, Hiroshi Nakao
  • Patent number: 6437069
    Abstract: A curable resin composition comprising (A) at least one aromatic diallyl compound, (B) at least one maleate diester and/or fumarate diester, (C) at least one (meth)allyl carbonate compound and (D) at least one radical chain transfer agent gives a cured material having excellent optical and mechanical properties.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: August 20, 2002
    Assignee: Daiso Co., Ltd.
    Inventor: Katsutoshi Yokoyama
  • Publication number: 20020107350
    Abstract: Polymerizable monomer compositions, transparent polymer substrates and optical and ophthalmic articles obtained.
    Type: Application
    Filed: November 28, 2001
    Publication date: August 8, 2002
    Applicant: Essilor International Compagnie Generale D'Optique
    Inventors: Gilles Widawski, Jean-Paul Cano, Jean-Francois Magne
  • Publication number: 20020103319
    Abstract: The invention provides water-soluble, &bgr;-hydroxy carbamate-functional materials and coating compositions, especially waterborne coating compositions, containing the carbamate-functional materials. The invention further provide a coating prepared from the coating composition and a coated substrate, especially an automotive substrate, having the coating thereon.
    Type: Application
    Filed: January 9, 2002
    Publication date: August 1, 2002
    Inventors: Walter H. Ohrbom, David J. Law, Patricia A. Herrel
  • Publication number: 20020086966
    Abstract: The invention provides an aqueous coating composition containing a dispersed, emulsified, or dissolved material (organic compound, resin, or polymer), in which the material is dispersed, emulsified, or dissolved with a water-soluble, carbamate-functional material. The invention further provides a coating prepared from the coating composition and a coated substrate, especially an automotive substrate, having the coating thereon.
    Type: Application
    Filed: January 30, 2002
    Publication date: July 4, 2002
    Inventors: Robert D. Weise, Walter H. Ohrbom, Patricia A. Herrel, David J. Law
  • Patent number: 6410671
    Abstract: The present invention relates to more or less substituted acrylamide or acrylate and zwitterion monomer hydrosoluble copolymers.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: June 25, 2002
    Assignee: Institute Francais du Petrole
    Inventors: Jean-François Argillier, Annie Audibert-Hayet, Pierre Le Perchec, Pierre Louis Carrette
  • Patent number: 6395852
    Abstract: A copolymer of the monomers of the following components A to C and, if required, D, the total amount by weight of which is 100 mol %: a: from 20 to 80 mol % of at least one ethylenically unsaturated dicarboxylic acid or of an anhydride, ester and/or amide thereof as component A, b: from 1 to 79 mol % of at least one diketene of the general formula (I)  where R1 and R2 independently are each hydrogen or C1-C30-alkyl, as component B, c: from 1 to 79 mol % of at least one vinyl ester, alkyl (meth)acrylate, (meth)acrylonitrile or mixtures thereof as component C and d: from 0 to less than 0.5 mol % or, if at least 20 mol % of component C are present, from 0 to 20 mol % of at least one further olefinically unsaturated monomer as component D, is used as a flow improver in mineral oil middle distillates.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: May 28, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Faul, Bernd Wenderoth, Gabriele Dralle-Voss, Gunnar Schornick
  • Patent number: 6395827
    Abstract: An aqueous crosslinkable coating composition suitable for the provision of thick coatings without incurring carbon dioxide bubble formation comprising: (A) an aqueous dispersion of at least one hydroxyl- and acid-functional vinyl polymer having a hydroxyl value of 8 to 250 mg KOH/g of polymer and an acid value of 2 to 55 mg KOH/g of polymer, where the contribution of at least 30% of the acid value results from a monocarboxylic acid(s) of formula: CH2—CR1—Q—CO2H  (1) where R1 is H or lower alkyl of 1 to 5 carbon atoms and Q is a spacer group of formula: [—C(═O)—X—(CH2)m—]k  (2) where X is —O— or —NH—, m is at least 1, preferably 2 or 3, and k is at least 1, preferably 2, 3, 4 or 5; and (B) at least one organic polyisocyanate. The acid of formula (1) preferably comprises &bgr;-carboxyethyl acrylate.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: May 28, 2002
    Assignee: Avecia Limited
    Inventors: David Alan Pears, Erik Hendrik Colstee, Gerardus Cornelis Overbeek, John Christopher Padget, Tijs Nabuurs
  • Patent number: 6387995
    Abstract: A process for producing a microporous oil sorbent polymer comprising the steps of: dissolving a polyunsaturated monomer in a silicone organic solvent to provide a monomer mixture containing more than 90% by weight polyunsaturated monomer; polymerizing said monomers by precipitation polymerization, under an inert atmosphere to precipitate microporous, micro-particles in the form of micro-particles, agglomerates and aggregates having a bulk density of about 0.02 gm/cm3 to about 0.01 gm/cm3 and capable of adsorbing at least about 20% by weight organic materials based on the total weight of polymer plus adsorbed organic material.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: May 14, 2002
    Assignee: AMCOL International Corporation
    Inventor: Milan F. Sojka
  • Patent number: 6376600
    Abstract: Aqueous dispersion of copolymers formed by the polymerization of a monomer mixture containing 0.05% to less than 4.5% by weight of certain terminally unsaturated oligomers are useful for improving the scrub resistance, corrosion resistance, opacifying capacity and/or efflorescence resistance of a coating.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: April 23, 2002
    Assignee: Rohm and Haas Company
    Inventors: Robert David Solomon, Bradley Keith Hageman, Leo Joseph Procopio, Margo Raate Schaefer, Gary David Greenblatt, Stephen Scott Edwards, Gary Robert Larson, Alvin Michael Maurice, Stewart Orlyn Williams, Patricia Marie Lesko, Peter Reeves Sperry
  • Patent number: 6359093
    Abstract: An amphipathic compound represented by any of the following Formulas: (R1 is a linear or branched, saturated hydrocarbon group having 6 to 48 carbon atoms, or a linear or branched, unsaturated hydrocarbon group containing 1 to 12 unsaturated double bond and having 6 to 48 carbon atoms; Y is NH, N—(CH2—CH═CH2), or O; Q is —CH2—C(R2)═CH2 or —R4—O—CO—C(R2)═CH2; and M is alkali metal, an ammonium group, or —(CH2CH2O)mH), a copolymer of the amphipatic compound with a copolymerizable ethylenically unsaturated compound and, a paper making additive containing a water soluble or dispersible high molecular compound as an active ingredient and processes for producing these high molecular compounds.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: March 19, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Toshihiko Takaki, Masaru Tanabe, Shoko Oyanagi
  • Publication number: 20020026020
    Abstract: The present invention provides a high temperature continuous polymerization and condensation process for preparing a polymeric product. The process includes continuously charging into a reaction zone: at least one radically-polymerizable monomer having a radically polymerizable group and at least one condensation reactive functionality; and at least one modifying agent having a functional group capable of reacting with the condensation reactive functionality. The reaction zone includes at least one primary reactor, but may, and preferably does, contain a secondary reactor. The process further includes maintaining an effective temperature in the primary reactor to cause polymerization of the monomer and to allow at least a portion of the condensation reactive functionality to react with the functional group of the modifying agent.
    Type: Application
    Filed: July 2, 1999
    Publication date: February 28, 2002
    Inventors: JOHN D. CAMPBELL, JON A. DEBLING, DOUGLAS J. DEYOUNG, IOANNIS GIANNAKITSAS, DEAN R. HELLWIG, DAVID D. SCHATZ, FOUAD TEYMOUR, MARCO A. VILLALOBOS
  • Patent number: 6346591
    Abstract: The &bgr;-hydroxy carbamate, ethylenically unsaturated monomer of the invention can be polymerized as a homopolymer or copolymerized with other monomers. The polymerization can be carried out in an aqueous medium. The &bgr;-hydroxy carbamate monomer is polymerized to form water-soluble homopolymers or, if polymerized as a mixture with one or more comonomers, copolymers that are soluble, emulsifiable, or dispersible in water. The &bgr;-hydroxy carbamate monomer can be used as a replacement monomer for acrylamide.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: February 12, 2002
    Assignee: BASF Corporation
    Inventors: Walter H Ohrbom, Patricia A. Herrel
  • Patent number: 6346590
    Abstract: The present invention provides a high temperature continuous polymerization and condensation process for preparing a polymeric product. The process includes continuously charging into a reaction zone: at least one radically-polymerizable monomer having a radically polymerizable group and at least one condensation reactive functionality; and at least one modifying agent having a functional group capable of reacting with the condensation reactive functionality. The reaction zone includes at least one primary reactor, but may, and preferably does, contain a secondary reactor. The process further includes maintaining an effective temperature in the primary reactor to cause polymerization of the monomer and to allow at least a portion of the condensation reactive functionality to react with the functional group of the modifying agent.
    Type: Grant
    Filed: July 2, 1999
    Date of Patent: February 12, 2002
    Assignee: S. C. Johnson Commercial Markets, Inc.
    Inventors: John D. Campbell, Jon A. Debling, Douglas J. DeYoung, Ioannis Giannakitsas, Dean R. Hellwig, David D. Schatz, Fouad Teymour, Marco A. Villalobos
  • Publication number: 20020007009
    Abstract: The invention provides functionalized copolymers in the form of their aqueous dispersions or water-redispersible powders, based on
    Type: Application
    Filed: May 7, 2001
    Publication date: January 17, 2002
    Applicant: Wacker-Chemie GmbH
    Inventors: Kurt Stark, Peter Tschirner, Peter Ball, Klaus Buppelmann, Udo Kotschi
  • Publication number: 20020004574
    Abstract: A polymerizable composition comprising an effective amount of at least one tetrafunctional acrylate monomer. In one embodiment of the invention, a polymerizable composition is a compound comprising of at least 50 percent by weight of at least one tetrafunctional acrylate monomer, from 5 to 20 percent by weight of at least one modified bisphenol A epoxy diacrylate monomer, from 0 to 25 percent by weight of at least one acrylate monomer selected from aliphatic difunctional and polyfunctional acrylates, from 0 to 3 percent by weight of at least one UV absorber, and a source of free radicals. The lens-forming material resulted from the polymerizable composition is introduced to a lens mold with a mold cavity having a configuration conforming to the optical lens to be molded. A radiation energy source is used to cure the lens-forming material in the filled mold. The radiation energy source comprises a U-shaped UV light.
    Type: Application
    Filed: July 16, 1999
    Publication date: January 10, 2002
    Inventors: WILLIAM M. HUNG, GUIGUI WANG
  • Patent number: 6335409
    Abstract: The invention is concerned with novel cross-linkable, photoactive polymer materials with 3-aryl-acrylic acid esters and amides as well as their use as orienting layers for liquid crystals and for the production of non-structured or structured optical elements and multi-layer systems.
    Type: Grant
    Filed: July 11, 2000
    Date of Patent: January 1, 2002
    Assignee: Rolic AG
    Inventors: Rolf-Peter Herr, François Herzog, Andreas Schuster
  • Patent number: 6326446
    Abstract: The present invention provides a macroporous hyperhydroxy polymer formed from a monomer mixture of substantially similar fractions of functional acrylic monomers which are combined to form a compound having a polymer skeleton which provides a high number of hydroxyl sites. The result is a material which, when hydrated, has a pore size relative to oxygen and water which provides a high ratio of free water to bound water. When formed into contact lenses, the material exhibits oxygen permeability approaching that of a static layer of tears of equal thickness and water contents of 95% or greater. The polymer is also suitable for use as burn dressings, bandages, soil hydratants, surface treatments, lubricants and coatings, absorbents, transport membranes and the like.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: December 4, 2001
    Inventor: James T Carter
  • Patent number: 6323360
    Abstract: The present invention discloses the synthesis of a novel crosslinker having the following structure: R1 is C(R8) (R9) wherein (R8) is H, or an alkyl group having 1-5 carbon atoms, and (R9) is H, or an alkyl group having 1-5 carbon atoms. R2 is H, or an alkyl group having 1-5 carbon atoms. R3 is H or an alkyl group having 1-5 carbon atoms. R4 is an alkyl group having 1-5 carbon atoms. R5 is H or an alkyl group having 1-5 carbon atoms. R6 is H or an alkyl group having 1-5 carbon atoms. R7 is C(R10) (R11) wherein (R10) is H, or an alkyl group having 1-5 carbon atoms, and (R11) is H, or an alkyl group having 1-5 carbon atoms. The crosslinker is stable in a basic environment, but decomposable in an acidic environment.
    Type: Grant
    Filed: November 14, 2000
    Date of Patent: November 27, 2001
    Assignee: The Research Foundation of State University of New York
    Inventors: Eli Ruckenstein, Hongmin Zhang
  • Publication number: 20010044514
    Abstract: The present invention provides a process for the direct synthesis of high melting polymers made from dimeric cyclic esters. In particular, the present invention provides a process for synthesis of polylactic acid (PLA) from racemic materials such as racemic lactide and polymandelide from mandelide. The process further provides racemic metal organic ligand catalysts such as racemic salbinap that catalyzes the polymerization of racemic dimeric cyclic ester monomers to a polylactide stereocomplex. Polymandelide and mixed dimeric cyclic esters are also prepared in the presence of low amounts of water.
    Type: Application
    Filed: December 13, 2000
    Publication date: November 22, 2001
    Applicant: Board of Trustees operating Michigan State University
    Inventors: Gregory L. Baker, Milton R. Smith
  • Patent number: 6316569
    Abstract: The objects of the present invention are: a self-light-stabilized photochromic thermoplastic or thermoreticulated polymer carrying non-cyclic tertiary amide-functionalized pendant groups; its preparation method; photochromic articles constituted, wholly or in part of such a polymer. Said polymer is obtained advantageously by radical co-polymerization of a composition containing an effective amount of at least one monomer of the formula: in which: R1 is hydrogen or a methyl group; n is 2 or 3; R2 and R3 are identical or different and represent independently a methyl or ethyl group; and are advantageously identical; said monomer providing said photostabilizing non-cyclic tertiary amine-functionalized pendant groups.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: November 13, 2001
    Assignee: Corning S.A.
    Inventors: David Henry, Xavier Lafosse
  • Patent number: 6313251
    Abstract: A cross-linkable polymeric casting composition including an effective amount of A: an acrylic or methacrylic monomer which provides high rigidity and low color dispersion (High Abbe number) to the final product; B: a di- or polythiol compound; C: a di- or polyvinyl monomer; and optionally D: a polymerizable comonomer.
    Type: Grant
    Filed: September 28, 1999
    Date of Patent: November 6, 2001
    Assignee: Sola International Holdings, Ltd.
    Inventors: Huan Kiak Toh, Ian Roger Bateman, David Robert Diggins, Bohdan Grzegorz Cieslinski
  • Patent number: 6312867
    Abstract: A novel ester compound having an exo-form 2-alkylbicyclo[2.2.1]heptan-2-yl group as the protective group is provided as well as a polymer comprising units of the ester compound. The polymer is used as a base resin to formulate a resist composition having a higher sensitivity, resolution and etching resistance than conventional resist compositions.
    Type: Grant
    Filed: November 1, 1999
    Date of Patent: November 6, 2001
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takeshi Kinsho, Tsunehiro Nishi, Hideshi Kurihara, Koji Hasegawa, Takeru Watanabe, Osamu Watanabe, Mutsuo Nakashima, Takanobu Takeda, Jun Hatakeyama
  • Patent number: 6310159
    Abstract: The present invention refers to a paper surface sizing composition comprising a copolymer having: a) structural units derived from ethylenically unsaturated hydrocarbons; structural units derived from monomers selected from esters of ethylenically unsaturated mono-carboxylic acids, half-esters of ethylenically unsaturated dicarboxylic acids, allylethers and vinylethers and mixtures thereof; optionally c) structural units derived from ethylenically unsaturated monomers selected from monocarboxylic acids as well as salts and amides thereof, dicarboxylic acids as well as salts, amides and half-amides thereof, and cyclic anhydrides and imides of dicarboxylic acids and mixtures thereof; and optionally d) structural units derived from alkyl or amino-substituted alkyl acrylates or methacrylates with the proviso, that if no structural units c) are present, the structural units b) are derived from monomers selected from half esters of ethylenically unsaturated dicarboxylic acids.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: October 30, 2001
    Assignee: The Dow Chemical Company
    Inventors: Jürgen Eiffler, Roger Carlsson, Jürgen Hermanns, Stephen Oliver
  • Patent number: 6310162
    Abstract: The invention relates to an ophthalmic lens comprising the cured product of a composition comprising: 60-99 wt % of a poly(allyl carbonate) of a polyhydroxy alcohol, said polyhydroxy alcohol having from 2 to 20 carbon atoms and from 2 to 6 hydroxy groups in the molecule; 0.01-10 wt % of at least one radical initiator; 0-20 wt % of comonomers; and a cyclohexyl diallyl ester oligomer in an amount of 0.05 to 60 wt %, having the formula I wherein X denotes a divalent hydrocarbon residue derived from a diol having 2-20 carbon atoms, optionally partly replaced by a residue derived from a polyol having 3 or more carbon atoms and 3-10 hydroxy groups, and n=1-100.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: October 30, 2001
    Assignee: Great Lakes Chemical Corporation
    Inventors: Willem Bos, Ricardo Henry Breeveld, Marjan Elisabeth Van Der Zanden
  • Patent number: 6291619
    Abstract: A photosensitive composition comprising a polyimide precursor, a photosensitive material having a structure represented by the following formula wherein A1 is an atom belonging to Group VI of the periodic table, in the molecule thereof and/or a photosensitive material having a structure represented by the following formula: wherein A2 is O, S or N atom, in the molecule thereof is suitable for formation of a positive tone pattern excellent in heat resistance, and applicable to electronic devices.
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: September 18, 2001
    Assignee: Hitachi Chemical Co., LTD
    Inventors: Yasunari Maekawa, Takao Miwa, Takumi Ueno, Yoshiaki Okabe
  • Publication number: 20010021727
    Abstract: Radiation-curable compositions are disclosed which, after cure, are substantially non-yellowing. The compositions are particularly tailored for coating and bundling of optical fibers. A first preferred composition is based on a polyether-type of oligomer diluted with reactive diluents. Isocyanurate structures are included in the composition to raise Tg. A second preferred composition is based on fatty oil comprising (meth)acrylate groups and bisphenol A derivatives comprising (meth)acrylate groups. Photoinitiators can be included to increase cure speed. The formulations do not include material amounts of ingredients which tend to cause yellowing or, in theory, extended conjugation in the cured compositions.
    Type: Application
    Filed: March 16, 2001
    Publication date: September 13, 2001
    Applicant: DSM N.V.
    Inventor: David Szum
  • Patent number: 6284856
    Abstract: Rubber articles are coated with a powder-free copolymer coating to provide improved mold release characteristics, improved donning characteristics, and improved tactile feel. The copolymer is formed by the polymerization of a low surface energy monomer, an alkyl acrylate, a hard monomer and a urethane oligomer. The copolymers are preferably formed by a sequential polymerization process.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: September 4, 2001
    Assignee: Avery Dennison Corporation
    Inventor: Ivan S. Lee
  • Patent number: 6280713
    Abstract: The invention relates to novel microgel-containing essentially organic solvent nail varnishes. The microgels are particularly acrylic microgels. The invention also relates to the use of these microgels for modifying the physical properties of an essentially organic solvent nail varnish composition, and/or the properties of the film obtained during the application of said composition.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: August 28, 2001
    Assignee: LVMH Recherche
    Inventors: Jean-François Tranchant, Henri-Gérard Riess, Alain Meybeck
  • Patent number: 6265511
    Abstract: A method is provided for producing hyperbranched polymers comprising heating a polymerizable reaction charge comprising (a) a monomer mixture comprising 50-99.1% by weight of at least one monoethylenically unsaturated monomer and 0.1-50% by weight of one or more multiethylenically unsaturated monomers and (b) if at least one ethylenically unsaturated monomer of the monomer mixture is not a thermally initiating monomer, a free radical polymerization initiator, to a temperature in the range from about 250° C. to about 400° C. in a continuous reactor which allows mixing of the reactor contents for a residence time of from about 2 minutes to about 60 minutes, provided that if the total amount of multiethylenically unsaturated monomer is less than 3% by weight of the monomer mixture than at least one of said one or more multiethylenically unsaturated monomers must be tri- or greater ethylenically unsaturated. The hyperbranched polymers prepared by this process are also described.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: July 24, 2001
    Assignee: S. C. Johnson Commerical Markets, Inc.
    Inventors: J. David Campbell, Fouad Teymour
  • Patent number: 6262211
    Abstract: Describes a polymerizable organic composition comprising a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and from 0.1 percent to 10 percent by weight, based on the total weight of the composition, of an allyl ester terminated nonaromatic polyester, e.g., diallyl 4-methyl-1,2-cyclohexanedicarboxylate oligomer with 1,4-butane diol. Polymerizates prepared from polymerizable organic compositions of the present invention have a refractive index of less than 1.53, e.g., from 1.49 to 1.50, and are substantially free of defects due to tinting failure.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: July 17, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Charles C. Clontz, Noriyuki Someki, Robert A. Smith, Michael O. Okoroafor
  • Patent number: 6211308
    Abstract: A method for coating a textile includes applying a substantially water-free, energy-curable, polymer-forming composition to the textile and exposing the textile and composition to a source of energy under such conditions as to generate chemically active sites on the surface of the textile and polymerize the composition. The resulting polymer is grafted onto the textile. Preferably, the energy is derived from electron beam radiation. The composition includes an epoxy oligomer having at least two ethylenically unsaturated moieties, and at least one alkoxylated polyol monomer having at least two ethylenically unsaturated moieties and capable of being copolymerized with the epoxy oligomer. Preferably, the composition also includes a surface active agent capable of rendering the uncured composition dispersible in water. Optionally, the composition can contain a colorant, and photoinitiator. The composition is especially suitable for use as a screen printing ink and coating material for textiles.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: April 3, 2001
    Assignee: Henkel Corporation
    Inventor: Marie-Esther Saint Victor
  • Patent number: 6201089
    Abstract: The present invention provides a macroporous hyperhydroxy polymer formed from a monomer mixture of substantially similar fractions of functional acrylic monomers which are combined to form a compound having a polymer skeleton which provides a high number of hydroxyl sites. The result is a material which, when hydrated, has a pore size relative to oxygen and water which provides a high ratio of free water to bound water. When formed into contact lenses, the material exhibits oxygen permeability approaching that of a static layer of tears of equal thickness and water contents of 95% or greater. The polymer is also suitable for use as burn dressings, bandages, soil hydratants, surface treatments, lubricants and coatings, absorbents, transport membranes and the like.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: March 13, 2001
    Inventor: James T Carter
  • Patent number: 6201088
    Abstract: Cyanoacrylate adhesives which have increased heat resistance, yet also exhibit good storage stability and acceptable cure times, are obtained by using 2-cyanopentadienoic acid esters in combination with alkylene bis-(2-cyanopentadienoates).
    Type: Grant
    Filed: March 30, 1999
    Date of Patent: March 13, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Werner Gruber, Yuri Gololobov, Hanns Misiak, Dagmar Behn
  • Patent number: 6197907
    Abstract: A polymer of a low molecular weight having a very little odor is produced by emulsion-polymerizing a radical-polymerizable unsaturated monomer at a temperature of 115° C. or higher in the presence or absence of a chain transfer agent.
    Type: Grant
    Filed: April 6, 1999
    Date of Patent: March 6, 2001
    Assignee: Nippon Carbide Kogyo Kabushiki Kaisha
    Inventors: Eiichi Yoshida, Manabu Ogawa, Hiroshi Masuda, Hiroshi Serizawa
  • Patent number: 6194531
    Abstract: A method for producing a cross-linked polymer manifesting a high absorption capacity and having a small content of soluble component by a convenient and expeditious process with high productivity is provided. An absorbent resin such that disposable diapers and other products incorporating the absorbent resin manifest outstanding qualities and a method for the production of the absorbent resin are proposed.
    Type: Grant
    Filed: June 3, 1997
    Date of Patent: February 27, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takumi Hatsuda, Toru Yanase, Yasuhiro Fujita, Kazuki Kimura