Abstract: To provide an amorphous fluorinated polymer which is soluble in a fluorinated solvent having a boiling point of at most 70° C., and a fluorinated polymer composition containing it. An amorphous fluorinated polymer characterized by having a fluorine content of at least 50 mass % and an intrinsic viscosity of at least 0.03 g/dL and less than 0.05 dL/g as measured in perfluoro(2-butyltetrahydrofuran) at 30° C.

Abstract: The invention provides novel siloxane monomers useful in a variety of adhesive applications. In one aspect, the siloxane compounds described herein can be used as Diels-Alder type curatives for bismaleimide or poly-maleimide monomers. The unsaturated resins shown here are attractive for use as maleimide curatives due to their poly-functionality. Each substituted styrenyl residue can react with two maleimide functional groups. Thus, an invention adhesive composition typically contains an excess of bismaleimide monomers.

Abstract: A method for the polymerization of free radically polymerizable vinyl monomers involves polymerizing free radically (co)polymerizable vinyl monomers in a batch reaction under essentially adiabatic conditions, and utilizing scavenger monomer to reduce undesirable residual monomer.

Abstract: A method for the polymerization of free radically polymerizable vinyl monomers involves polymerizing free radically (co)polymerizable vinyl monomers in a batch reaction under essentially adiabatic conditions in the presence of an non-reactive diluent that can remain in the polymer product.

Abstract: The present invention provides a multibranched polymer represented by the following formula (I), and a method for producing the multibranched polymer: wherein A represents an organic group having 3 or more branched chains, Xa represents a linking group containing any atom of Groups 14 to 16 in the Periodic Table, Y represents a functional group having a structure capable of having an active halogen atom, Q represents an arm moiety having a repeating unit derived from a polymerizable unsaturated bond, m1 represents any integer of 1 to the number of branched chains of A, m2 represents the number of branched chains of A, n1 represents an integer of 0 or 1 or more, and Ra represents an organic group which is not associated with the polymerization reaction.

Abstract: A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to form a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.

Abstract: Copolymers prepared in aqueous medium from macromonomers and one or more ethylenically unsaturated monomers are disclosed. The copolymers are useful for sound and vibration dampening applications.

Abstract: Provided are a photoreactive polymer that includes a multi-cyclicmulticyclic compound at as its main chain and a method of preparing the same. The photoreactive polymer exhibits excellent thermal stability since it includes a multi-cyclicmulticyclic compound having a high glass transition temperature at as its main chain. In addition, the photoreactive polymer has a relatively large vacancy so that a photoreactive group can move relatively freely in the main chain therein. As a result, a slow photoreaction rate, which is a disadvantage of a conventional polymer material used to form an alignment layer for a liquid crystal display device, can be overcome.

Abstract: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising the steps of: a) preparing a catalyst mixture including i) a precatalyst; ii) a first cocatalyst; and iii) a second cocatalyst; and b) subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, wherein the product yield of the prepared polymer is 50% by weight or more based on the total weight of the monomer.

Abstract: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.

Abstract: Polyalkenyl ether is produced by polymerizing alkenyl ether represented by the following general formula (I): CHR1?CH(OR2)??(I) wherein R1 represents a hydrogen atom or a methyl group, R2 represents a monovalent organic group, and R2 contains a silicon atom or at least one atom selected from the group consisting of elements from group 15 to group 17, in the presence of a halide of an element other than Al, or an organometallic compound of an element other than Al, and a nonionic oxygen-containing or nonionic nitrogen-containing organic compound.

Abstract: The object of the present invention is to provide antifoams which have a good antifoam effect in aqueous dispersions of polymeric organic substances, cause no wetting defects when these dispersions are applied to a surface and at the same time retain their antifoam activity even after prolonged storage at temperatures down to the freezing point.

Abstract: Compositions and methods for transport or release of therapeutic and diagnostic agents or metabolites or other analytes from cells, compartments within cells, or through cell layers or barriers are described. The compositions include a membrane barrier transport enhancing agent and are usually administered in combination with an enhancer and/or exposure to stimuli to effect disruption or altered permeability, transport or release. In a preferred embodiment, the compositions include compounds which disrupt endosomal membranes in response to the low pH in the endosomes but which are relatively inactive toward cell membranes (at physiologic pH, but can become active toward cell membranes if the environment is acidified below ca. pH 6.8), coupled directly or indirectly to a therapeutic or diagnostic agent. Other disruptive agents can also be used, responsive to stimuli and/or enhancers other than pH, such as light, electrical stimuli, electromagnetic stimuli, ultrasound, temperature, or combinations thereof.

Abstract: Disclosed herein is a composition comprising a crosslinked organic polymer; wherein the composition has a coefficient of friction that is in a range of ±30% of a coefficient of friction for a composition comprising the same organic polymer that is not crosslinked; and wherein the composition has a lower K factor than a K factor of the composition comprising the same organic polymer that is not crosslinked; the coefficient of friction and the K factor being measured in a thrust washer apparatus as per ASTM D-3702, where the counter stationary surface in the thrust washer apparatus comprises carbon steel having a Rockwell C hardness of 18 to 22 and a 12 to 16 micro-inch surface finish.

Abstract: The present invention relates to the use of a copolymer comprising, in polymerized form, (a) from 80 to 99.9 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer A which in each case comprises a heterocycle having at least 1 nitrogen atom and composed of from 3 to 10 ring members and a C2-C6-alkenyl group bonded to a carbon or nitrogen ring atom of the heterocycle; and (b) from 0.1 to 20 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer B copolymerizable with monomer A, said monomer B having a monoethylenically unsaturated double bond and also a linear or branched poly-C2-C4-alkylene oxide group having on average from 4 to 500 C2-C4-alkylene oxide units, in liquid and in solid detergent formulations. In addition, the invention relates to a process for preparing such a copolymer, and also to a liquid or solid detergent formulation comprising at least one such copolymer.

Abstract: The present invention provides a novel base material for a dry solid dispersion, a solid dispersion containing the base material, and a composition containing the dispersion; the solid dispersion of the present invention, which contains a poorly soluble component with improved dissolvability, can be obtained by mixing a polyvinyl alcohol-based copolymer, as a base material for the dry solid dispersion, with a poorly soluble component, and then heating it.

Abstract: Polyolefin waxes bearing (meth)acrylate groups, process for preparing them and their use.

Abstract: Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.

Abstract: The present invention provides a polymerization-curable composition comprising at least one kind of a cationically polymerizable compound having in the molecule at least one cationically polymerizable functional group selected from the group consisting of an alicyclic epoxy group, a vinylether group and an oxetane group, and at least one kind of a thermally latent polymerization initiator, characterized in that the polymerization-curable composition is allowed to undergo an exothermic polymerization reaction by applying primary thermal energy to a portion of the polymerization-curable composition, and then the entire polymerization-curable composition is polymerization-cured by secondary thermal energy generated as a result of the exothermic polymerization reaction; a method for polymerization-curing thereof; and a polymerization-cured resin composition.

Abstract: The present invention relates to a stimulus responsive composition, which includes a polymer complex that a polymer including repeated units of polyvinyl ether structure is chemically bonded to a functional substance, and a solvent. It is desirable that a solvent is water and that the polymer in the composition contains a polyvinyl ether structure. The present invention also relates to an ink composition including the above composition, an image forming method and image forming device using the above composition, and recording medium contains a stimulating material or composition which stimulates the above composition.

Abstract: A material having properties required for a chromatic aberration-free lens and excellent in moldability and impact resistance, which material is an amorphous fluoropolymer containing a carbon atom chain as a main chain and containing a fluorinated atom-bonded carbon atom as a carbon atom of the main chain, wherein vd>75, ?gF>0.50, and ??gF>0.03, where vd represents an Abbe number, ?gF represents a relative partial dispersion of a g-F line, and ??gF represents a deviation from a standard line of the relative partial dispersion of the g-F line.

Abstract: The present invention is to provide a method for producing a copolymer for a cement admixture, which enables to easily produce a blend of a plurality of copolymers with different monomer compositions in one polymerization operation, and is superior in water reducing performance and/or slump retention ability. Disclosed is a method for producing a copolymer for a cement admixture, which comprises a step of polymerizing monomer components comprising unsaturated polyalkylene glycol ether-based monomer (A) and unsaturated organic acid-based monomer (B), wherein the unsaturated polyalkylene glycol ether-based monomer (A) is added into a reactor in advance and the unsaturated organic acid-based monomer (B) is added thereto with an addition rate thereof changed at least one time.

Abstract: This invention relates to semi-batch type copolymerization processes. More specifically, the processes of the present invention are directed to the production of compositionally uniform copolymers, including the production of such copolymers from dissimilar monomers, e.g., from monomers with significantly different reactivity ratios.

Abstract: A photopolymerizable and photocleavable (P&P) resin monomer is derived from a reactive photoresponsible moiety via various linkages to form photopolymerizable monomers and/or oligomers.

Abstract: Polyether represented by R(—O—Xn—Zm—Y)p {R is a monovalent hydrocarbyl group that contains no more than 20 carbon atoms and that may contain an aliphatically unsaturated bond or is a group comprising the preceding group having an ether linkage therein; n is 1 to 200; m is 0 to 200; 0<n/(n+m)?1; X is a group provided by the ring-opening polymerization of a glycidyl ether; Z is an alkyleneoxy group having 2 to 6 carbon atoms; p is 1 to 6; Y is H or is a monovalent hydrocarbyl group, acyl group that contains no more than 20 carbon atoms and that may contain an aliphatically unsaturated bond or glycidyl group; and the configuration of the X and Z groups may be, inter alia, random} wherein either R or Y contains or both R and Y contain an aliphatically unsaturated bond and the molecular weight distribution (polydispersity) determined versus a polystyrene standard is 1.25 to 1.00.

Abstract: The claimed invention relates to a powder coating composition containing a fluorinated copolymer (X) having a glass transition point of at least 50° C. and a number average molecular weight of from 10,000 to 22,000, and a curing agent (Y), wherein the fluorinated copolymer (X) is a copolymer obtained by polymerization of a monomer mixture containing (A) from 45 to 55 mol % of chlorotrifluoroethylene and/or tetrafluoroethylene, (B) from 2 to 40 mol % of a vinyl ether which has a C4 or 5 alkyl group containing a tertiary carbon atom, (C) from 5 to 20 mol % of a vinyl ether having a crosslinkable functional group, and (E) from 1 to 32 mol % of a vinyl ester which has a C3-5 alkyl group containing a tertiary or higher carbon atom, wherein the total content of (B) and (E) is from 30 to 50 mol %, and the curing agent (Y) is reactive with the crosslinkable functional group.

Abstract: The invention provides a block polymer compound enabling satisfactory dispersion of a colorant in a solvent, and an ink composition containing such block polymer compound. The block polymer compound of the invention is a block polymer compound having at least three block segments, comprising block segments A, B and C arranged in succession, wherein the block segment C is most solvent attractive while the block segment A is most solvent repulsive, and at least either one of the block segments includes an ionic group or an acidic group.

Abstract: Synthesis methods for creating polymeric compounds comprising dihydroxyphenyl derivatives (DHPD), or DHPp i.e. polymers modified with DHPD, with desired surface active effects are described. The polymer backbone of DHPp has structural or performance features that can be tailored to control physical properties of DHPp, allowing it to be useful for different applications i.e. tissue adhesives or sealants, adhesion promoting coatings, and antifouling coatings.

Abstract: There is provided a toner having favourable development characteristics and favourable stability and a method for production thereof. The toner comprises at least a graft copolymer and a coloring material, wherein the graft copolymer is formed by graft polymerization of a polymerizable monomer with a block copolymer having a polymerizable functional group on a side chain. The method for producing the toner has a step of subjecting a reaction mixture comprising at least a block copolymer having a polymerizable functional group in a side chain and having a polyalkenyl ether repeating unit structure, a polymerizable monomer, and a coloring material to suspension polymerization or emulsion polymerization, to produce a graft copolymer in which a polymer of the polymerizable monomer is grafted to the side chain of the block copolymer.

Abstract: Disclosed are nondegradable hydrogels used to coat or form at least a portion of a medical device. The hydrogels may be formed from functionalized PEG based macromers. These hydrogels are easy to sterilize, transport and store. Methods of forming these hydrogels as described herein are included.

Abstract: A reactive polymeric surfactant that contains: (a) at least two hydrophilic monomeric units per molecule, each independently according to formula (I): wherein R1 is alkylene or oxyalkylene, R2 is H, methyl, or ethyl, R3 is H, and n is greater than about 5, (b) one or more hydrophobic monomeric units per molecule, each independently according to formula (II) wherein R4 is H or methyl, R5 is a hydrophobic group, is useful in stabilizing aqueous emulsions and aqueous dispersions.

Abstract: A flow improver comprising a plurality of core-shell particles that can be formed by emulsion polymerization. The core of the core-shell particles can include a drag reducing polymer, while the shell of the particles can include repeat units of a hydrophobic compound and an amphiphilic compound. The flow improver can demonstrate increased pumping stability over conventionally prepared latex flow improvers.

Abstract: Compositions of fluoroelastomers containing copolymerized units of tetrafluoroethylene, propylene, a first cure site selected from the group consisting of i) trifluoroethylene, ii) 3,3,3-trifluoropropene-1, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene, and a second cure site selected from the group consisting of i) copolymerized units of a brominated cure site monomer, ii) copolymerized units of an iodinated cure site monomer, iii) copolymerized units of a chlorinated cure site monomer, iv) brominated endgroups, v) iodinated endgroups and vi) a combination of any of i)-v) are readily curable with polyhydroxy curing systems. The resulting cured articles have a combination of excellent resistance to alkaline fluids, superior tensile properties and compression set resistance, and excellent adhesion to metal substrates. Optionally, the fluoroelastomers may be dual cured by both a polyhydroxy system and an organic peroxide system.

Abstract: Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and are described. In certain embodiments, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described. Novel copolymers comprising a least one polymeric branch or polymeric block with a gradient monomer structure are described. Additionally, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly periodic monomer sequence are also described. Novel copolymers having a water soluble backbone and at least two hydrophobic polymeric branches grafted to the water soluble backbone are also described.

Abstract: Disclosed herein is a copolymer (A) of olefinically unsaturated monomers (a), prepared by single-stage or multistage controlled free-radical copolymerization in an aqueous medium of monomers comprising: (a1) an olefinically unsaturated monomer comprising a chelate-forming group; and (a2) an olefinically unsaturated monomer different from the olefinically unsaturated monomer (a1), and selected from the group consisting of: (a21) monomers of the general formula I: R1R2C?CR3R4 (I), wherein R1, R2, R3, and R4 are independently hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of R1, R2, R3, and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals; (a22) an olefinically unsaturated terpene hydrocarbon; and (a23) a dimeric alpha-alkylvinylaromatic.

Abstract: A fluorine-containing copolymer, which comprises a hydroxyl-terminated fluorine-containing vinyl ether, represented by the following general formula: CF2?CFORfCH2OH (where Rf is a fluoroalkylene group, a fluoroalkyl ether group, or a fluoroalkoxyfluoroalkyl ether group, having 1-25 carbon atoms), and at least one of other fluorine-containing unsaturated monomers, where a high-molecular weight fluorine-containing copolymer having a melt viscosity (230° C.) of 0.1-100 g/10 min. is insoluble in a solvent, and can be used suitably for melt molding, whereas a low-molecular weight fluorine-containing copolymer having a glass transition temperature Tg of 20° C., or higher, and a number average molecular weight Mn of 1,000, or more is soluble in a solvent, and can be used suitably for coating agents, etc.

Abstract: The present invention relates to a modified colored pigment comprising a colored pigment having an attached organic group. The organic group is attached to the colored pigment via at least one carbon atom of a C—C single bond or double bond, wherein the C—C single bond or double bond is not a component of an aromatic system. The organic group further comprises at least one activating group on at least one carbon atom of the C—C single bond or double bond. A method of preparing a modified colored pigment is also disclosed, as are aqueous and non-aqueous dispersions, e.g., including ink jet inks, comprising the modified colored pigments.

Abstract: The present invention is directed to a class of membrane active polymers useful for cellular delivery of compounds. Conjugation of the described membrane active polymers to targeting, anti-opsonization, and anti-aggregation agents provides polymers suitable for in vivo delivery. The use of multiple reversible linkages connecting component parts provides for physiologically responsive activity modulation.

Abstract: The present invention relates to polyvinyl ethers and to their use as supports for synthetic methods (organic synthesis, peptide synthesis, oligonucleotide synthesis, oligosaccharide synthesis or any other synthetic procedure) and to their use for chromatographic applications (such as affinity chromatography), immobilisation of enzymes, reagents or catalysts.

Abstract: A process for polymerizing unsaturated monomers is disclosed. The process comprises polymerizing, in the presence of a late transition metal catalyst (LTMC), a variety of unsaturated monomers which are traditionally, some of which are exclusively, made by free radical polymerizations. The LTMC polymerization provides the polymer with improved properties such as no free radical residue and narrow molecular weight distribution.

Abstract: A noble alicyclic unsaturated compound represented by the general formula (1): wherein at least one of R1 and R2 is a fluorine atom or a fluorinated alkyl group; a polymer formed by the polymerization of a polymer precursor comprising the alicyclic compound. The polymer is useful, in the lithography using a light having a wavelength of 190 nm or less, as a chemically amplified resist which exhibits excellent transparency with respect to the light for use in exposure and also is excellent in the adhesion to a substrate and the resistance to dry etching.

Abstract: Dendritic amphiphilic polymers are contemplated. Most preferably, such polymers will be fabricated in a single step to the final product that may further be derivatized with, among others, biological relevant molecules. In alternative aspects, precursors of such molecules are prepared in a single step, and the precursors are then reacted to the dendritic amphiphilic polymers.

Abstract: This invention provides the use of a polymer comprising a hyperbranched polyether polyol such as hyperbranched polyglycerol as a serum albumin substitute. Also provided are high molecular weight hyperbranched polyglycerol polymers suitable for a variety of medical and non-medical uses including methods for making such high molecular weight polymers.

Abstract: A coating having an adhesive hydrophilic polymer and an amphiphilic additive. The amphiphilic additive has a hydrophilic chain, a biocidal functional group bonded to the hydrophilic chain, and a hydrophobic moiety bonded to the hydrophilic chain or to the biocidal functional group. A method of forming a biocidal surface by providing an article, and coating the article with the above coating. A compound having the formula: Y—(O—CH2—CH2)n—R—(CH2)m—CH3. Y is CH3 or H. R is X is a halogen, and m and n are independently selected positive integers.

Abstract: The invention relates to the use of copolymers with styrene-oxide-based, vinyl-functionalized polyethers for preparing aqueous pigment preparations.

Abstract: The present invention relates to a stimuli-responsive composition that comprises a polymer, a solvent and a substance having a predetermined function. One embodiment of the present invention is a composition comprising a block polymer, a solvent and a substance having a predetermined function. The present invention also relates to an ink composition containing the composition, an image-forming method and an image-forming apparatus using the composition, and a recording medium applying the composition. Further, the present invention relates to an ABC type block polymer compound wherein the polymer is an ABC type triblock polymer, and wherein at least one of the blocks in the triblock polymer changes in nature from solvophilic to solvophobic or from solvophobic to solvophilic in response to stimuli, and more preferably, the A component, then the B component, and finally the C component respond to the stimuli.

Abstract: Disclosed is a technology for the production of polyvinyl ethers having a reactive silicon-containing functional or atomic group at the terminal thereof. The polyvinyl ether as expressed by the formula (VII) is prepared by allowing, in the presence of a catalyst composed of a polynuclear ruthenium-carbonyl complex in which carbonyl groups coordinate with two to four ruthenium atoms, a vinylether compound expressed by the formula (III) to react with a silane compound expressed by the formula (IV). In the formulae, R1, R2 and R3 each represents a hydrogen atom or a hydrocarbon group having 1 to 8 carbon atoms, R4 represents an alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, or a silyl group, and X1, X2 and X3 each represents a hydrogen atom, a halogen atom, an amino group, an alkyl group, an alkoxy group, a thioalkyl group, an alkylamino group, an aryl group, an arylamino group, an aralkyl group a vinyl group, or a heterocyclic group.

Abstract: Film-forming materials include resins having a covalently bonded phosphorous atom, the phosphorous atom having at least one covalently bonded oxygen atom. Film-forming resins containing phosphorous can include epoxy, acrylic, polyurethane, polycarbonate, polysiloxane, polyvinyl, polyether, aminoplast, and polyester resins. A process to produce a film-forming resin includes reacting various polymers to incorporate a pendent group comprising a covalently bonded phosphorous atom.

Abstract: It is an object of the present invention to provide a polycarboxylic acid polpolymer which improves the water reducing capacity and workability of cement compositions and the like and making them easier to handle when the fluidity and water reducing capacity are at the same levels, a method of producing the copolymer, and a cement additive and a cement composition comprising the copolymer. The present invention is further to provide a polycarboxylic acid copolymer and a cement additive which are capable of improving the strength and durability of hardening products of cement compositions, hence can advantageously be used in ultrahigh strength concrete. The present invention is polycarboxylic acid copolymers having high water reducing capacity, reducing the viscosity of cement compositions and improving the workability in applying cement.

Abstract: The present invention relates to (meth)acrylamide monomers of the formula: wherein R is H or CH3, R1 is selected from H, substituted and unsubstituted alkyl groups having 1 to 8 carbon atoms, substituted and unsubstituted benzene and toluene groups and and R2, R3 and R4 are independently selected from alkyl groups having 1 to 8 carbon atoms, substituted and unsubstituted benzene and toluene groups, and —OSiR5R6R7 wherein R5, R6 and R7 are independently selected from the group consisting of straight or branched alkyl groups having 1 to 4 carbon atoms. Polymers made therefrom are also disclosed.