At Least Six Carbon Atoms Patents (Class 526/348.2)
-
Publication number: 20010039320Abstract: Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula H2C═CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex. The produced copolymer has a density of from 0.870 to 0.Type: ApplicationFiled: May 16, 1997Publication date: November 8, 2001Inventors: GRANT B. JACOBSEN, FUMIO MATSUSHITA, LEE SPENCER, PETER L. WAUTERAERTS
-
Patent number: 6310154Abstract: Solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.Type: GrantFiled: January 7, 1998Date of Patent: October 30, 2001Assignee: Eastman Chemical CompanyInventors: Laura M. Babcock, Dennis G. Morrell
-
Patent number: 6310150Abstract: Supported heterometallocene catalysts wherein the support is a particulate polymeric material are provided. The catalysts have a transition metal complex containing at least one anionic, polymerization stable heteroatomic ligand associated with the transition metal and a boron activator compound deposited on the support. Polymeric supports used for the heterometallocene catalysts of the invention are homopolymers of ethylene and copolymers of ethylene and C3-8 &agr;-olefins.Type: GrantFiled: June 12, 2001Date of Patent: October 30, 2001Assignee: Equistar Chemicals, L.P.Inventors: Karen E. Meyer, Mark K. Reinking
-
Patent number: 6310166Abstract: A method of making a sterile adhesive composition includes placing a mixture of a polymerizable adhesive monomer and a thickening agent in a container, sealing the container, and sterilizing the mixture and the container. The method provides superior viscosity for the monomer composition. The sterile adhesive composition is particularly useful as a medical adhesive and can comprise 1,1-disubstituted ethylene monomers, such as &agr;-cyanoacrylates.Type: GrantFiled: August 12, 1999Date of Patent: October 30, 2001Assignee: Closure Medical CorporationInventors: Timothy Hickey, Ubonwan A. Stewart
-
Publication number: 20010031842Abstract: Disclosed is a process for producing high molecular weight ethylene-&agr;-olefin copolymers with the aid of a specific catalyst which is higher in conversion rate of comonomers and is capable of inhibiting reduction of molecular weight at the time of copolymerization.Type: ApplicationFiled: December 7, 1998Publication date: October 18, 2001Inventors: SAKAE KAMIYAMA, YUKIKO HANE, SHIGEHARU YAMAMOTO, TSUTOMU USHIODA, JUN SAITO, YOSHIYUKI OHGI
-
Patent number: 6303713Abstract: A graft modified ethylene/&agr;-olefin copolymer obtained by graft polymerizing an ethylene/&agr;-olefin of 3 to 20 carbon atoms copolymerizing with a polar monomer in the presence of a catalyst for olefin polymerization comprising an organoaluminum oxy-compound (a) and at least two kinds of transition metal compounds (b). This ethylene/&agr;-olefin copolymer has high melt tension and high flowability. An ethylene copolymer composition comprising the above-mentioned graft modified ethylene/&agr;-olefin copolymer and polyolefin. The graft modified ethylene/&agr;-olefin copolymer of the invention is excellent in heat stability and moldability. From this copolymer, a film having a high transparency and good adhesion to highly polar materials can be produced. The ethylene copolymer composition of the invention is excellent in heat stability and moldability. From this composition, a film having high transparency and good adhesion to highly polar materials can be produced.Type: GrantFiled: August 20, 1999Date of Patent: October 16, 2001Assignee: Mitsui Chemicals INCInventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo, Seiji Ohta, Hajime Inagaki
-
Patent number: 6303709Abstract: A continuous process for obtaining propylene polymers in the presence of a catalytic system of the Ziegler-Natta type containing a catalytic solid comprising chlorine, magnesium and titanium atoms and at least one electron-donor compound, called internal donor, a cocatalyst which is an organoaluminium compound, and optionally an electron-donor compound, called external donor, comprising the following successive stages: (a) polymerization of propylene in liquid propylene to form, per g of titanium in the catalytic solid, from 11000 to 28000 g of a prepolymer chosen from among the homopolymers of propylene, and (b) gas-phase polymerization of propylene in one or more successive fluidized-bed reactors and in the presence of the prepolymer (a), of propylene, optionally in the presence of one or more other monomers chosen from among the &agr;-olefins containing from 2 to 12 carbon atoms to produce a final propylene polymer whose fraction of particles of diameter smaller than 125 &mgr;m (FP) is at most 10 wt %.Type: GrantFiled: January 18, 2000Date of Patent: October 16, 2001Assignee: Solvay Polyolefins Europe-Belgium (Societe Anonyme)Inventor: Marc Jauniaux
-
Patent number: 6300438Abstract: The present invention relates to a Group 15 containing hafnium catalyst compound, a catalyst system and a supported catalyst system thereof and to a process for polymerizing olefin(s) utilizing them.Type: GrantFiled: October 22, 1999Date of Patent: October 9, 2001Assignee: Univation Technolgies, LLCInventor: David H. McConville
-
Patent number: 6300432Abstract: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with at least one Ziegler-Natta catalyst comprising a component comprising at least one transition metal and a co-catalyst comprising at least one organometallic compound and at least one compound comprising at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)m—R3 in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.Type: GrantFiled: August 31, 1999Date of Patent: October 9, 2001Assignee: Eastman Chemical CompanyInventors: Randal Ray Ford, Kenneth Alan Dooley, Jeffrey James Vanderbilt, Roxanna Lea Whitfield, Alan George Wonders
-
Patent number: 6300431Abstract: A process for catalytic recovery in a phase transfer process wherein heterogeneous reactions in a liquid-liquid two phase reaction systems using a phase transfer catalyst is improved by separating the two liquid phases with a membrane which retains the catalyst while passing the aqueous polar liquid thereby allowing easy recovery of the phase transfer catalyst. The reaction is carried out between reactants selectively soluble in the different phases, one of the reactants being transferred into the other phase by means of a phase transfer catalyst which is soluble in said polar liquid phase with the one reactant. The phases are separated after completion of the reactions by adding water to the two-phase reaction system to dissolve out the polar liquid phase containing the phase transfer catalyst into an aqueous phase.Type: GrantFiled: December 17, 1999Date of Patent: October 9, 2001Assignee: ExxonMobil Chemical Patents Inc.Inventors: Hsien-Chang Wang, Chia Shian Chee, W. S. Winston Ho
-
Patent number: 6300430Abstract: A process is described for copolymerizing ethylene with vinyl esters and, if desired, with further vinylic comonomers in a tube reactor at pressures of from 500 to 4000 bar and at not more than 220° C., which comprises initiating the free-radical polymerization at at least two locations of the tube reactor by adding a catalyst/initiator and adjusting the temperature profile within the reactor such that the temperature maxima downstream of the initiation locations are from 150 to 220° C. and differ by less than ±10° C. from one another.Type: GrantFiled: March 14, 2000Date of Patent: October 9, 2001Assignee: BASF AktiengesellschaftInventors: Andreas Deckers, Wilhelm Weber, Ulrich Annen
-
Patent number: 6300433Abstract: The invention is directed to olefin polymerization processes using bridged hafnocene catalyst complexes that are surprisingly stable under high temperature olefin polymerization processes such that olefin copolymers can be prepared with high molecular weights and catalyst activities. More specifically, the invention is a polymerization process for ethylene copolymers having a melt index of about 0.850 to about 0.930 comprising contacting, under homogeneous polymerization conditions at a reaction temperature at or above 60° C. to 250° C.Type: GrantFiled: October 21, 1999Date of Patent: October 9, 2001Assignee: ExxonMobil Chemical Patents Inc.Inventors: George Rodriguez, Donna J. Crowther
-
Patent number: 6297333Abstract: The olefin polymerization catalyst of the invention is formed from a Group IVB transition metal compound represented by the following formula (I) and an organoaluminum oxy-compound or a compound which reacts with the transition metal compound to form an ion pair.Type: GrantFiled: May 20, 1999Date of Patent: October 2, 2001Assignee: Mitsui Chemicals IncInventors: Junichi Imuta, Masayasu Yoshida, Yasushi Tohi
-
Patent number: 6297338Abstract: Polyolefins made preferably only from ethylene using a selected ethylene oligomerization catalyst to form &agr;-olefins and a polymerization catalyst which can copolymerize ethylene and &agr;-olefins produces a novel polymer which advantageous rheological properties.Type: GrantFiled: September 29, 1999Date of Patent: October 2, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Patricia Metzger Cotts, William Howard Tuminello, Lin Wang, Joel David Citron
-
Publication number: 20010025089Abstract: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta catalyst comprising at least one transition metal compound and at least one organometallic co-catalyst compound and tetrahydrofuran in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.Type: ApplicationFiled: March 27, 2001Publication date: September 27, 2001Inventors: Randal Ray Ford, Kenneth Alan Dooley, Jeffrey James Vanderbilt, Roxanna Lea Whitfield, Alan George Wonders
-
Publication number: 20010025091Abstract: The invention provides a polymer of ethylene as a first component or monomer, with a branched olefin as a second component or monomer, and at least one different olefin as a third component or monomer. The olefins can be obtained from a Fischer-Tropsch process.Type: ApplicationFiled: March 12, 2001Publication date: September 27, 2001Applicant: SASOL TECHNOLOGY (PROPRIETARY) LIMITEDInventors: Ioan Tincul, Dawid Johannes Joubert, Desmond Austin Young
-
Publication number: 20010021754Abstract: Injection molded plastic parts (such as containers for ice cream or margarine, lids for the containers and crates) are made from a polyethylene resin having a controlled but narrow molecular weight distribution and a uniform comonomer distribution. The combination of narrow molecular weight distribution and uniform comonomer distribution allows the parts to be more easily molded whilst still maintaining a surprisingly high level of physical properties in the finished parts. The polyethylene resin is prepared in a dual reactor polymerization process.Type: ApplicationFiled: February 1, 2001Publication date: September 13, 2001Applicant: NOVA Chemicals (International) S.A.Inventors: Mark Weber, Christopher John Brooke Dobbin
-
Patent number: 6288189Abstract: Microspheres comprise a polymer including one or more of 1) a plurality of C3 or larger alpha-olefin units wherein the C3 or larger alpha-olefin units are incorporated into the polymer so as to give an average number of less than one branch point per C3 or larger alpha-olefin unit, 2) a plurality of C2 alpha-olefin units wherein the C2 alpha-olefin units are incorporated so as to give an average number of branch points greater than 0.01 per C2 alpha-olefin unit, and 3) cyclopentene or substituted cyclopentene, the microspheres having an average diameter in the range of 1 to 300 micrometers. Optionally, the polymer of the microspheres can be crosslinked. The microspheres can be prepared by suspension or dispersion polymerization processes using aqueous or organic reaction media. Powder coatings can be prepared from the microspheres.Type: GrantFiled: May 23, 1997Date of Patent: September 11, 2001Assignee: 3M Innovative Properties CompanyInventors: Katherine A. Brown, Michael R. Kesti, Edward G. Stewart, Joseph M. McGrath
-
Publication number: 20010018505Abstract: The present invention relates to a process for the polymerization of monomers utilizing a bulky ligand hafnium transition metal metallocene-type catalyst compound, to the catalyst compound itself and to the catalyst compound in combination with an activator.Type: ApplicationFiled: March 14, 2001Publication date: August 30, 2001Inventors: Moses Olukayode Jejelowo, Sun Chueh Kao
-
Patent number: 6281309Abstract: Fluorinated solid acids and supported fluorinated solid acids are used as catalysts for the polymerization of a feed stream containing at least one of pure monomer, C5 monomers, and C9 monomers to produce hydrocarbon resins. Freely-associated water may be removed from the fluorinated solid acid catalyst and/or supported fluorinated solid acid catalyst prior to use. Resins with softening points (Ring and Ball) in the range of about 5° C. to 170° C. can be prepared. These catalysts offer advantages over the traditional Friedel-Crafts polymerization catalysts since the acid sites are an integral part of the solid. The fluorinated solid acid catalysts and supported fluorinated solid acid catalysts are relatively nonhazardous, reusable catalysts which eliminate or at least reduce contamination of the resulting resin products with acid residues or by-products.Type: GrantFiled: January 7, 1998Date of Patent: August 28, 2001Assignee: Eastman Chemical CompanyInventors: Laura M. Babcock, Dennis G. Morrell, John N. Kostas, Andrew Bell
-
Publication number: 20010016632Abstract: Polyethylene film having a combination of a high melt strength and a high dart impact strength is prepared from a linear low density polyethylene resin having a melt index, (“I2”), of from 0.4 to 1.5 g/10 minutes, a broad molecular weight distribution (of from 3.5 to 7) and a quasi homogeneous comonomer distribution (as evidenced by a copolymer/homopolymer ratio of from 3 to 19). The polyethylene resin is prepared in a dual reactor polymerization process. The film is especially useful for industrial and “heavy duty” packaging applications such as the manufacture of plastic packages used to contain goods for the construction, gardening and agricultural businesses. Examples of such goods include peat moss, fertilizer, soil, sand, salt, fiberglass insulation and crushed stone.Type: ApplicationFiled: March 12, 2001Publication date: August 23, 2001Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.Inventor: Peter Sipos
-
Publication number: 20010016639Abstract: The co-polymerization reaction of one or more olefin monomers, such as propylene, with &agr;,&ohgr;-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of &agr;,&ohgr;-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations.Type: ApplicationFiled: December 11, 2000Publication date: August 23, 2001Inventors: Pawan Kumar Agarwal, Weiqing Weng, Aspy Keki Mehta, Armenag Hagop Dekmezian, Christopher Ross Davey, Charlie Y. Lin, Michael Chia-Chao Chen, Galen Charles Richeson
-
Patent number: 6274683Abstract: An improvement in a method for evaluating the efficiency of polymerization inhibitors is disclosed, wherein the improvement comprises: A) producing dissolved polymer in a solution comprising monomer and at least one inhibitor by means of any test known in the art to be useful for evaluating polymerization inhibitors, B) collecting the polymer-containing solution, C) measuring the degree of polymerization of the monomer in the collected solution, and D) re-subjecting the polymer-containing solution to the test conditions of A).Type: GrantFiled: June 30, 1999Date of Patent: August 14, 2001Assignee: Uniroyal Chemical Company, Inc.Inventors: Brigitte Benage, Brendan J. Geelan, Gerald J. Abruscato
-
Patent number: 6274684Abstract: Catalyst compositions and methods, useful in polymerization processes, utilizing at least two metal compounds are disclosed. At least one of the metal compounds is a Group 15 containing metal compound and the other metal compound is preferably a bulky ligand metallocene-type catalyst. The invention also discloses a new polyolefin, generally polyethylene, particularly a multimodal polymer and more specifically, a bimodal polymer, and its use in various end-use applications such as film, molding and pipe.Type: GrantFiled: October 22, 1999Date of Patent: August 14, 2001Assignee: Univation Technologies, LLCInventors: Donald R. Loveday, David H. McConville, John F. Szul, Kersten Anne Erickson, Simon Mawson, Tae Hoon Kwack, Frederick J. Karol, David James Schreck
-
Patent number: 6271323Abstract: The present invention relates to mixed catalyst compositions of a Group 15 containing hafnium catalyst compound and a bulky ligand metallocene-type catalyst compound, a unsupported and supported catalyst systems thereof and to a process for polymerizing olefin(s) utilizing them.Type: GrantFiled: October 28, 1999Date of Patent: August 7, 2001Assignee: Univation Technologies, LLCInventors: Donald R. Loveday, David H. McConville
-
Publication number: 20010009953Abstract: An olefin polymer of an alkenyl hydrocarbon having 5 or more carbon atoms, wherein said olefin polymer is an amorphous polymer having a Mn of 300,000 and a Mw/Mn of 2.40 or less, and substantially not having a melting point, and a process for producing said olefin polymer which comprises polymerizing an alkenyl hydrocarbon having 5 or more carbon atoms with an olefin polymerization catalyst obtained by contacting: a specific transition metal compound(A), an organoaluminumoxy compound (B) soluble in an aromatic solvent and water (C).Type: ApplicationFiled: March 13, 2001Publication date: July 26, 2001Applicant: Sumitomo Chemical Company, Limited.Inventors: Masayuki Fujita, Tatsuya Miyatake
-
Patent number: 6265505Abstract: The present invention relates to a catalyst system of a Group 15 containing metal catalyst compound and a Lewis acid aluminum containing activator and to a supported catalyst system thereof and to a process for polymerizing olefin(s) utilizing them.Type: GrantFiled: November 18, 1999Date of Patent: July 24, 2001Assignee: Univation Technologies, LLCInventors: David H. McConville, Matthew W. Holtcamp
-
Publication number: 20010008925Abstract: A polymerizable composition comprises an alpha-olefin hydrocarbon monomer, an effective amount of an organometallic catalyst of a Group VIII metal, preferably Ni or Pd, and at least one of water and air. Novel catalysts for polymerizing alpha-olefin hydrocarbon monomers provide improved processes and products. Methods of the invention include polymerizing the composition in open air and in the presence of water to provide novel polymers.Type: ApplicationFiled: February 8, 2001Publication date: July 19, 2001Inventors: Katherine A. Brown, William M. Lamanna, Allen R. Siedle, Edward G. Stewart, Penelope J. Swanson
-
Patent number: 6262215Abstract: Elastomeric ethylene/propylene or ethylene/propylene/polyene copolymers containing small amounts of one or more &agr;-olefins are prepared by a slurry process wherein the polymerization reaction is carried out in a mixture of liquid propylene and alpha-olefin.Type: GrantFiled: February 7, 2000Date of Patent: July 17, 2001Assignee: Montell Technology Company bvInventors: Maurizio Galimberti, Enrico Albizzati
-
Publication number: 20010007896Abstract: The co-polymerization reaction of one or more olefin monomers, such as propylene, with &agr;,&ohgr;-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of &agr;,&ohgr;)-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations.Type: ApplicationFiled: December 11, 2000Publication date: July 12, 2001Inventors: Pawan Kumar Agarwal, Weiqing Weng, Aspy Keki Mehta, Armenag Hagop Dekmezian, Christopher Ross Davey, Charlie Y. Lin, Michael Chia-Chao Chen, Galen Charles Richeson, Rajan K. Chudgar, Main Chang
-
Patent number: 6255425Abstract: A syndiotactic polypropylene copolymer is disclosed which comprises 70 to 99.9 mole % of propylene and 0.1 to 30 mole % of an olefin other than propylene; in the 13C-NMR spectrum of the syndiotactic polypropylene copolymer, a ratio of the intensity of a peak at about 20.2 ppm to the sum of the intensities of the total peaks attributable to methyl groups in propylene units at about 19-22 ppm being 0.3 or more. Also disclosed are extrusion-molded high-transparency articles, especially films and sheets and blown films, obtained by the extrusion of a polypropylene substantially having a syndiotactic structure.Type: GrantFiled: January 18, 1994Date of Patent: July 3, 2001Assignee: Mitsui Chemicals, Inc.Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Nobutaka Uchikawa, Tateyo Sasaki, Osamu Uchida, Tutomu Iwatani, Shigeru Kimura, Takeo Inoue
-
Patent number: 6255426Abstract: A polymer of ethylene and at least one alpha olefin having at least 5, carbon atoms obtainable by a continuous gas phase polymerization using supported catalyst of an activated molecularly discrete catalyst such as a metallocene in the substantial absence of an aluminum alkyl based scavenger which polymer has a Melt Index (MI) as herein defined of from 0.1 to 15; a Compositional Distribution Breadth Index (CDBI) as defined herein of at least 70%, a density of from 0.910 to 0.930 g/ml; a Haze value as herein defined of less than 20%; a Melt Index ratio (MIR) as herein defined of from 35 to 80; an averaged Modulus (M) as herein defined of from 20 000 to 60 000 psi (pounds per square inch) and a relation between M and the Dart Impact Strength in g/mil (DIS) complying with the formula: DIS≧0.8×[100+e(11.71−0.000268×M+2.183×10−9×M2)].Type: GrantFiled: March 26, 1998Date of Patent: July 3, 2001Assignee: Exxon Chemical Patents, Inc.Inventors: Ching-Tai Lue, Natalie A. Merrill, Michael E. Muhle, George Alan Vaughan
-
Publication number: 20010004662Abstract: A semicrystalline propylene polymer composition with good suitability for producing biaxially oriented films and prepared by polymerizing propylene, ethylene and/or C4-C18-1-alkenes, where at least 50 mol % of the monomer units present arise from the polymerization of propylene,Type: ApplicationFiled: December 18, 2000Publication date: June 21, 2001Inventors: Wolfgang Bidell, Roland Hingmann, Franz Langhauser, Dieter Lilge, Volker Rauschenberger, Gunther Schweier, Florian Stricker, Jurgen Suhm
-
Patent number: 6242395Abstract: A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alpha olefin monomers with a catalyst system, which includes a catalyst and an activator (co-catalyst) in a reactant mixture. The catalyst is a transition metal catalyst, preferably titanium trichloride, and the co-catalyst may include an alkylaluminoxane, alone or in combination, with a dialkylaluminum halide or a halohydrocarbon. The polymerization of the alpha olefin monomers produces a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of at least 10 dL/g.Type: GrantFiled: September 15, 1999Date of Patent: June 5, 2001Assignee: Energy & Environmental International, L.C.Inventors: Gerald B. Eaton, Michael J. Monahan, Robert J. Tipton
-
Publication number: 20010002389Abstract: A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alpha olefin monomers with a catalyst system. which includes a catalyst and an activator (co-catalyst) in a reactant mixture. The catalyst is a transition metal catalyst, preferably titanium trichloride, and the co-catalyst may include an alkylaluminoxane, alone or in combination, with a dialkylaluminum halide or a halohydrocarbon. The polymerization of the alpha olefin monomers produces a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of at least 10 dL/g.Type: ApplicationFiled: January 16, 2001Publication date: May 31, 2001Inventors: Gerald B. Eaton, Michael J. Monahan, Robert J. Tipton
-
Patent number: 6235822Abstract: Gaskets comprising either at least one homogeneously branched ethylene polymer or at least one elastic substantially linear ethylene polymer, at least one ethylene/carboxylic acid interpolymer; and at least one slip agent are disclosed. These gaskets may also contain enhanced polyethylenes produced by the direct polymerization of various combinations of novel elastic substantially linear olefin polymers in multiple reactors using either single or multiple catalysts. These gaskets may also be comprised of at least one ethylene polymer and at least one ionomer. The above mentioned gaskets may also contain slip agents and/or foaming agents. The gaskets are particularly useful for sealing food and liquid containers and do not contribute to taste and/or odor of the packaged product, which is especially useful in food-stuff applications.Type: GrantFiled: July 26, 1999Date of Patent: May 22, 2001Assignee: The Dow Chemical CompanyInventors: Alan R. Whetten, Ronald P. Markovich, Steve M. Hoenig, Edward E. Greene
-
Patent number: 6225410Abstract: Ethylene/C6-8 alpha-olefin copolymers are characterized by melt tension, flow activation energy and haze. The copolymers have excellent moldability and produce films of excellent transparency and mechanical strength.Type: GrantFiled: December 23, 1998Date of Patent: May 1, 2001Assignee: Mitsui ChemicalsInventors: Kenji Sugimura, Ken Yoshitsugu, Mamoru Takahashi, Takashi Nakagawa
-
Publication number: 20010000258Abstract: A molded or extruded article made from a propylene, &agr;-olefin copolymer, where the &agr;-olefin has 5 or more carbon atoms (higher alpha-olefins (HAO)), where the copolymer is made with a metallocene catalyst system, provides substantially higher cold flow resistance and resiliency than when the propylene copolymer contains an &agr;-olefin of 4 or less carbon atoms. Other properties such as ultimate tensile strength and impact strength are substantially higher as well. Such polymers can be used to advantage in extruded profiles and molded parts either alone or in a thermoplastic olefin (TPO). Parts made from the propylene HAO copolymers or compounds made from them show improved creep resistance than propylene ethylene copolymers.Type: ApplicationFiled: December 8, 2000Publication date: April 12, 2001Applicant: Exxon Chemical Patents Inc.Inventors: James John McAlpin, Aspy Keki Mehta, Jean Philippe Autran
-
Patent number: 6214952Abstract: A propylene random copolymer and a film laminate thereof is described having excellent blocking resistance and transparency and substantially maintaining favorable low-temperature heat-sealing properties after corona discharge treatment. The propylene random copolymer of the invention includes a propylene component and an &agr;-olefin component having 4 to 10 carbon atoms, wherein the content of the &agr;-olefin component is in the range of about 6% to about 40% by weight, the intrinsic viscosity [&eegr;] measured in tetralin at 135° C. is not lower than about 0.45 dl/g and not higher than about 5.0 dl/g, and the melting point (Tm) measured by a differential scanning calorimeter and the content of 20° C. xylene soluble fraction (CSX) fulfill a relationship of Tm≦140−35.693 log10(CXS).Type: GrantFiled: March 11, 1998Date of Patent: April 10, 2001Assignee: Sumitomo Chemical Co., Ltd.Inventors: Hajime Sadatoshi, Makoto Satoh, Naofumi Naga
-
Patent number: 6201078Abstract: Ethylene polymer having a die swell ratio (RB) of at least 1.4, a resistance to crazing under stress (ESCR) of at least 55 h and a melt index (MI5) of at least 0.2 g/10 min. Processes for obtaining this ethylene polymer using different catalytic systems, the first based on titanium and zirconium used in a polymerization in two reactors; the second consisting of a mixture of a titanium catalyst and a titanium and zirconium catalyst, used in a polymerization in two reactors; the third based on chromium on a support comprising at least two constituents chosen from silica, alumina and aluminum phosphates, used in a polymerization in a single or in two reactors.Type: GrantFiled: April 18, 1996Date of Patent: March 13, 2001Assignee: Solvay Polyolefins Europe-BelgiumInventors: Jacques Breulet, Benoît Koch, Michel Promel, Jiang Bian, Olivier LHost
-
Patent number: 6197899Abstract: A process is disclosed for the particle form polymerization of olefins. The process employs a titanium-containing having hydrocarbon soluble titanium components. The resulting catalyst is pretreated with an organometallic reducing agent prior to the introduction of the catalyst into the polymerization zone to give a catalyst which can be used satisfactorily in a loop reactor with lower levels of cocatalyst.Type: GrantFiled: February 27, 1995Date of Patent: March 6, 2001Assignee: Phillips Petroleum CompanyInventors: Kent E. Mitchell, Max P. McDaniel, M. Bruce Welch, Elizabeth A. Benham, Grover W. Cone
-
Patent number: 6197900Abstract: Multiphase homo- or copolymers of C2-C10-alk-1-enes are prepared by a process in which polymerization is effected in the presence of two different catalyst systems in one reaction zone, one of the catalyst systems containing, as active components, a metallocene complex of the general formula (I) or (II) where M1 is a metal of group IVb, Vb or VIb of the Periodic Table, R1 and R2 are identical or different and are each hydrogen, C1-C10-alkyl, C1-C10-alkoxy, C6-C10-aryl, C6-C10-aryloxy, C2-C10-alkenyl, C7-C40-arylalkyl, C7-C40-alkylaryl, C8-C40-arylalkenyl or halogen, R3 and R4 are identical or different and are each hydrogen, halogen, C1-C10-alkyl which may be halogenated, C6-C10-aryl or an —NR210, —SR10, —OSiR310, —SiR310 or —PR210 radical, where R10 is halogen, C1-C10-alkyl or C6-C10-aryl, and R5 and R6 are identical or different and have the meanings stated for R3 and R4, with the proviso that R5 and R6 are not hydrogen.Type: GrantFiled: May 2, 1997Date of Patent: March 6, 2001Assignee: BASF AktiengesellschaftInventors: Stefan Seelert, Franz Langhauser, Jürgen Kerth, Patrik Müller, David Fischer, Günther Schweier
-
Patent number: 6197909Abstract: Biaxially stretched, heat shrinkable monolayer and multilayer films comprising very low density polyethylene terpolymers of monomers (a), (b) and (c), where (a) comprises ethylene, (b) comprises a C6-C8 alpha-olefin and (c) comprises 1-butene or 1-hexene, have a very good combination of physical properties and processability including high shrinkage values and puncture resistance.Type: GrantFiled: May 12, 1993Date of Patent: March 6, 2001Assignee: Curwood, Inc.Inventors: Edwin Rogers Smith, Jeffrey Michael Schuetz, Stanley Lustig
-
Patent number: 6191245Abstract: The present invention relates to &agr;-olefin/vinyl aromatic monomer interpolymers with characteristic signals in their carbon 13 NMR spectra. In particular, ethylene/styrene copolymers of the present invention have peaks in the carbon 13 NMR spectra which appear in the chemical shift range 43.70-44.25 ppm, preferably from 43.75-44.25 ppm and 38.0-38.5 ppm, said peaks being at least three times the peak to peak noise. The interpolymers are prepared by polymerizing the appropriate mixture of monomers in the presence of a catalyst such as racemic-(dimethylsilanediyl(2-methyl-4-phenylindenyl)) zirconium dichloride. The polymers of the present invention posses increased modulus as determined from both tensile stress/strain and dynamic mechanical data at comparable vinyl aromatic monomer levels.Type: GrantFiled: March 2, 1999Date of Patent: February 20, 2001Assignee: The Dow Chemical CompanyInventors: Richard E. Campbell, Jr., Mark H. McAdon, Peter N. Nickias, Jasson T. Patton, Oscar D. Redwine, Francis J. Timmers
-
Patent number: 6187882Abstract: The invention relates to a process for the polymerization of olefins, which comprises polymerizing an olefin or mixture thereof in presence of a solvent, a supported metallocene and an aluminoxane as cocatalyst in a hydrocarbon medium, at a temperature in the range of 50 to 150° C., at a pressure ranging between 1 to 20 bar, for a period of 10 minutes to 10 hours, scavenging the reaction mixture by addition of an organoaluminum compound to remove the last traces of impurities of solvent, separating the polymer by conventional methods like precipitating, filtering, washing the polymer with an organic solvent, drying the polymer to remove the solvent to obtain the product.Type: GrantFiled: May 14, 1997Date of Patent: February 13, 2001Assignee: Council of Scientific & Industrial ResearchInventors: Soumen Sensarma, Swaminathan Sivaram
-
Patent number: 6184308Abstract: A hydrocarbon resin is prepared by (1) thermally polymerizing a mixture consisting essentially of (a) about 40% to 90% by weight based on total monomers of a cyclic diolefin component comprising at least about 50% by weight dicyclopentadiene, and (b) about 60% to 10% by weight based on total monomers of a specified vinyl aromatic component, preferably alpha-methylstyrene; para-methyl-&agr;-methylstyrene; 2,4-diphenyl-4-methyl-1-pentene, or mixtures thereof, and (2) recovering a product having a Ring and Ball softening point of about 70° to about 150° C. Hydrogenation of this resin produces light colored, thermally stable products that are useful as tackifiers in adhesives.Type: GrantFiled: February 3, 1998Date of Patent: February 6, 2001Assignee: Hercules IncorporatedInventors: Norman Edward Daughenbaugh, Dane George Goodfellow, Deborah Ann Riedl
-
Patent number: 6177527Abstract: A process for the preparation of (i) polyethylene or (ii) polypropylene, which is essentially isotactic or a mixture of atactic and isotactic polypropylenes comprising contacting ethylene or propylene per se, or in admixture with one or more alpha-olefins, under polymerization conditions, with a catalyst system comprising: (a) a precatalyst comprising a mixture of racemic and meso stereoisomers of a metallocene catalyst containing two cycloalkadienyl ligands joined by a bridging linkage, said ligands complexed to a metal atom; and (b) (1) to obtain polyethylene catalyzed by the rac epimer only, a cocatalyst selected from the group consisting of tris(perfluorophenyl)borane and isobutyl alumoxane; (2) to obtain polyethylene catalyzed by both the rac and the meso epimers, a cocatalyst selected from the group consisting of dimethylanilinium tetrakis(perfluorophenyl)borate and triphenylmethyl tetrakis(perfluorophenyl)borate; (3) to obtain polypropylene, which is essentially isotactic, a cocatalystType: GrantFiled: September 8, 1998Date of Patent: January 23, 2001Assignee: Union Carbide Chemical & Plastics Technology CorporationInventors: Purna Chand Sishta, Xinmin Yang, Frederick John Karol
-
Patent number: 6174981Abstract: Polymerization processes for ethylene and at least one mono-1-olefin comonomer having from about three to eight carbon atoms per molecule in the presence of a catalyst system comprising chromium supported on a silica-titania support and a trialkylboron compound is provided. Novel ethylene copolymers also are produced.Type: GrantFiled: December 17, 1998Date of Patent: January 16, 2001Assignee: Phillips Petroleum CompanyInventors: Joseph J. Bergmeister, Al R. Wolfe, Steven J. Secora, Elizabeth A. Benham, William R. Coutant, Max P. McDaniel
-
Patent number: 6172173Abstract: A polymer produced by a transition metal containing catalyst useful for the polymerization of &agr;-olefins is prepared by (A) forming in an inert atmosphere which excludes oxygen and moisture a slurry of (1) a porous inorganic oxide support material selected from the group consisting of silica, alumina, or a combination of silica and alumina, said support material containing not greater than about 5 millimoles of hydroxyl groups per gram of support material and a particle size not greater than about 10 microns and a surface area of from about 50 to about 800 m2/g in an inert organic liquid medium; (B) mixing said slurry with (2) an alkoxide and stirring the resultant mixture at a temperature of from about −20° C. to about 120° C.Type: GrantFiled: October 8, 1997Date of Patent: January 9, 2001Assignee: The Dow Chemical CompanyInventors: Lee Spencer, Brian W. S. Kolthammer, Miriam P. Ripplinger, Jeffrey J. Wooster, Pak-Wing S. Chum, Jacquelyn A. deGroot