Ten Or More Carbon Atoms Patents (Class 526/348.3)
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Patent number: 12142395Abstract: Coated conductors having a conductor at least partially surrounded by a polymeric composition. The polymeric composition contains a broad-molecular-weight-distribution high-density ethylene-based polymer and a narrow-molecular-weight-distribution linear-low-density ethylene-based polymer, and has a density of at least 0.95 g/cm3. Also disclosed are processes for preparing the polymeric composition and for making the coated conductors. Further disclosed are articles of manufacture containing the same.Type: GrantFiled: May 20, 2019Date of Patent: November 12, 2024Assignee: Dow Global Technologies LLCInventors: Mohamed Esseghir, Anurima Singh
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Patent number: 12030964Abstract: A biaxially-oriented film for thermoforming is disclosed including at least 75% by weight polyethylene and at least 95% by weight polyolefins, based on the total mass of the film. The polyethylene has an elongation at break of at least 7 in the stress-strain diagram, wherein the stress-strain diagram is measured at a temperature of 10° C. below the melting point of the polyethylene and the melting point is determined by differential scanning calorimetry using a heating rate of 10° C. per minute. A process for producing such films and to the use thereof are disclosed. A process for producing shaped bodies from such films and to the shaped bodies themselves are disclosed.Type: GrantFiled: September 19, 2022Date of Patent: July 9, 2024Assignee: BRÜCKNER MASCHINENBAU GmbHInventors: Michael Pecher, Andrei Douzhyk, Ilja Müller, Jan Barth
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Patent number: 11969718Abstract: Supported chromium catalysts with an average valence less than +6 and having a hydrocarbon-containing or halogenated hydrocarbon-containing ligand attached to at least one bonding site on the chromium are disclosed, as well as ethylene-based polymers with terminal alkane, aromatic, or halogenated hydrocarbon chain ends. Another ethylene polymer characterized by at least 2 wt. % of the polymer having a molecular weight greater than 1,000,000 g/mol and at least 1.5 wt. % of the polymer having a molecular weight less than 1000 g/mol is provided, as well as an ethylene homopolymer with at least 3.5 methyl short chain branches and less than 0.6 butyl short chain branches per 1000 total carbon atoms.Type: GrantFiled: February 10, 2023Date of Patent: April 30, 2024Assignee: Chevron Phillips Chemical Company LPInventors: Masud M. Monwar, Carlos A. Cruz, Jared L. Barr, Max P. McDaniel
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Patent number: 11972878Abstract: A support for a busbar including two parts each having two surfaces substantially planar and perpendicular to one another and arranged to form, together with the two surfaces of the other part from the two parts, a through-cavity or a passage, a base including a hole or a fastener, and, a shape complementary to a shape of the other of the two parts, the shape being arranged to form, together with the shape of the other of the two parts, an attachment between the two parts. Advantageously, it is possible to obtain a support for a busbar, the support being robust, reliable, and inexpensive and able to be mounted in an easy and rapid manner.Type: GrantFiled: August 30, 2022Date of Patent: April 30, 2024Assignee: Airbus Operations (S.A.S.)Inventor: Sébastien Forasacco
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Patent number: 11905397Abstract: A composition comprising at least the following components: A) an ethylene-based polymer; B) a cycloolefin inter-polymer comprising, in polymerized form, ethylene and at least one bridged cyclic olefin selected from Structures a-d, as described herein, or any combination of Structures a-d; and wherein component A is present in an amount ?50 wt %, based on the weight of the composition, and wherein component B is present in an amount from 5 to 12 wt %, based on the sum weight of components A and B.Type: GrantFiled: August 22, 2018Date of Patent: February 20, 2024Assignee: Dow Global Technologies LLCInventors: Juan C. Tuberquia, Karla M. Sperati
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Patent number: 11674026Abstract: Microporous polymer films and methods of making same are disclosed. The microporous polymer film comprises: (a) 50 to 95 weight percent of polypropylene copolymer comprising (i) polypropylene homopolymer chain segments in total amount of from 50-82 wt. %, and (ii) ethylene-containing copolymer chain segments in total amount of from 18-50 wt. %; wherein at least a portion of the ethylene-containing copolymer chain segments comprise polymerized units of ethylene in an amount of at least 45 wt. % of the ethylene-containing copolymer chain segments; and (b) 5 to 50 weight percent of ethylene-propylene elastomer, wherein at least 45 weight percent of the polymerized units in the ethylene-propylene elastomer are units of ethylene.Type: GrantFiled: March 18, 2021Date of Patent: June 13, 2023Assignee: DDP SPECIALTY ELECTRONIC MATERIALS US, LLCInventors: Wenyi Huang, William Ripmeester
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Publication number: 20150099679Abstract: Disclosed are processes for forming an oligomer product by contacting a feedstock olefin containing trisubstituted olefins with a solid acid catalyst. The oligomer product can be formed at an oligomerization temperature in a range from ?20° C. to 40° C. Polyalphaolefins produced from the oligomer product can have reduced viscosities at low temperatures.Type: ApplicationFiled: December 12, 2014Publication date: April 9, 2015Inventors: Hu Yang, Kenneth D. Hope, Jeff C. Gee
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Patent number: 9000115Abstract: The present description relates to olefin block copolymers having excellent elasticity and processability in conjunction with enhanced heat resistance, and to a preparation method thereof. The olefin block copolymers comprise a plurality of blocks or segments that comprise ethylene or propylene repeating units and ?-olefin repeating units at different mole fractions from one another, wherein the block copolymer shows peaks at the 2? of 21.5±0.5° and 23.7±0.5° in a wide-angle x-ray diffraction (WAXD) pattern, and the peak ratio defined by (the peak area at 21.5±0.5°)/(the peak area at 23.7±0.5°) is no more than 3.0.Type: GrantFiled: January 26, 2012Date of Patent: April 7, 2015Assignee: LG Chem, Ltd.Inventors: Yong Ho Lee, Manseong Jeon, Heon-Yong Kwon, Min-Seok Cho, Seon Kyoung Kim, Dae-Sik Hong, Se Hui Sohn, Ki-Soo Lee, Kyoung-Chan Lim
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Patent number: 8907035Abstract: A multimodal ethylene copolymer having the following properties: i) density comprised in the range from 0.880 to 0.955 g/cm3; ii) total comonomer content ranging from 6% to 25% by weight; iii) content of 1-butene derived units ranging from 0 to 2% by weight; iv) Mw/Mn comprised from 4 to 20; v) intrinsic viscosity (decalin at 135° C. as determined according to EN ISO 1628-312003) comprised between 1.0 and 4.0 dL/g; said multimodal ethylene copolymer comprises from 10% to 80% by weight of a first polyethylene component and being detected at the Crystaf® apparatus at a temperature higher than 75° C. and from 90% to 20% by weight of a second polyethylene component being a copolymer being detected at a Crystaf® apparatus at a temperature lower than 75° C.; wherein said multimodal ethylene copolymer being fractionated into 12 fractions by means of the Holtrup analysis, the fractions containing more than 2% by weight of the total amount of material meet the following relationship: Cf/HDPE>?0.0075HDPE+0.Type: GrantFiled: January 13, 2010Date of Patent: December 9, 2014Assignee: Basell Polyolefine GmbHInventors: Fabiana Fantinel, Shahram Mihan, Gerd Mannebach, Volker Dolle
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Publication number: 20140343241Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher ?-olefin (s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.Type: ApplicationFiled: August 4, 2014Publication date: November 20, 2014Applicant: MITSUI CHEMICALS, INC.Inventor: Tooru TANAKA
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Patent number: 8889200Abstract: A chewing gum contains a water-insoluble gum base portion containing a polyolefin thermoplastic elastomer; a water-soluble bulk portion; and at least one flavor component, which is cud-forming and chewable at mouth temperature.Type: GrantFiled: September 12, 2008Date of Patent: November 18, 2014Assignee: Wm. Wrigley Jr. CompanyInventors: Chungsea Shen, Joo H. Song, Bruno Padovani, David W. Record
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Patent number: 8889808Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.Type: GrantFiled: May 25, 2012Date of Patent: November 18, 2014Inventor: Derek James McPhee
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Publication number: 20140309151Abstract: Provided are an ?-olefin copolymer useful as a high-viscosity lubricant oil excellent in viscosity characteristics, low-temperature characteristics and oxidation stability, and a lubricant oil containing the copolymer. The ?-olefin copolymer is a 1-octene/1-decene copolymer produced by the use of a doubly bridged metallocene catalyst.Type: ApplicationFiled: July 18, 2012Publication date: October 16, 2014Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Hitomi Shimizu, Kiyokazu Katayama, Hideaki Noda, Masaki Okano
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Patent number: 8841397Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.Type: GrantFiled: September 27, 2012Date of Patent: September 23, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Matthew W. Holtcamp, Charles J. Ruff, Donna J. Crowther, John R. Hagadorn, Patrick Brant
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Patent number: 8835588Abstract: The present invention provides dual catalyst systems containing a metallocene catalyst and a hydrogen scavenging catalyst, and polymerization processes employing these dual catalyst systems. Due to a reduction in hydrogen levels in the polymerization processes, olefin polymers produced from these polymerization processes may have a higher molecular weight, a lower melt index, and higher levels of unsaturation.Type: GrantFiled: June 26, 2013Date of Patent: September 16, 2014Assignee: Chevron Phillips Chemical Company LPInventors: Rex E. Murray, William B. Beaulieu, Qing Yang, Errun Ding, Gary L. Glass, Alan L. Solenberger, Steve J. Secora
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Publication number: 20140256901Abstract: An ethylene alpha-olefin copolymer having (a) a density of from about 0.910 g/cc to about 0.940 g/cc; (b) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol; and (c) a melt index at a load of 2.16 kg of from about 0.01 dg/10 min. to about 0.5 dg/min.; wherein a 1 mil blown film formed from the polymer composition is characterized by (i) a Dart Impact strength greater than about 175 g/mil; (ii) an Elmendorf machine direction tear strength greater than about 20 g/mil; and (iii) an Elmendorf transverse direction tear strength greater than about 475 g/mil.Type: ApplicationFiled: March 11, 2013Publication date: September 11, 2014Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Ashish M. SUKHADIA, Guylaine ST. JEAN, Qing YANG, Max P. MCDANIEL
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Publication number: 20140248488Abstract: [Object] To provide a resin composition with excellent mold releasability and blocking resistance. [Solution] A resin composition containing a 4-methyl-1-pentene polymer includes 0.01 to 10 parts by mass of a 4-methyl-1-pentene polymer (B) per 100 parts by mass of at least one resin (A) selected from the group consisting of thermoplastic resins and thermosetting resins, wherein the 4-methyl-1-pentene polymer (B) has (B1) an intrinsic viscosity [?] of 0.01 or more but less than 0.50 dl/g measured at 135° C. in a decalin solvent.Type: ApplicationFiled: May 9, 2014Publication date: September 4, 2014Applicant: Mitsui Chemicals, Inc.Inventors: Kuniaki KAWABE, Masayoshi Sutou, Toshiyuki Itou, Mai Kurihara, Akinori Etoh, Shinichirou Asao, Kenji Sugimura, Hiroshi Hoya, Koji Matsunaga, Yoji Hayakawa, Kunihiko Mizumoto
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Patent number: 8816034Abstract: A method for producing an ?-olefin oligomer including: polymerizing in the presence of a catalyst one or more ?-olefins having 6 to 20 carbon atoms to produce an ?-olefin oligomer; and deactivating the catalyst by a deactivator from which oxygen is removed. A method for producing an ?-olefin oligomer including: polymerizing in the presence of a catalyst one or more ?-olefins having 6 to 20 carbon atoms to produce an ?-olefin oligomer; and passing the reaction solution containing the ?-olefin oligomer through a bag filter.Type: GrantFiled: January 11, 2012Date of Patent: August 26, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hideki Sato, Yushi Matsuda, Jun Kohiruimaki, Masao Aida, Kana Minamimoto, Jun Mase
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Patent number: 8802797Abstract: Vinyl-terminated macromonomer oligomerization, namely, a process to produce polymacromonomers comprising contacting a vinyl-terminated macromonomer with a catalyst system capable of oligomerizing vinyl-terminated macromonomer, in the presence of an aluminum containing compound, a zinc containing compound, or a combination thereof, under polymerization conditions to produce a polymacromonomer, and polymacromonomers produced thereby. Also, polymacromonomers having a degree of polymerization greater than 10, a glass transition temperature Tg of less than 60° C., and an Mn of greater than or equal to about 5000 Da.Type: GrantFiled: September 27, 2012Date of Patent: August 12, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R Hagadorn, Patrick Brant, Robbert Duchateau, Rafael Sablong
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Patent number: 8772426Abstract: Copolymers of ethylene and ?-olefins having (a) a density (D) in the range 0.900-0.940 g/cm3, (b) a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-50 g/10 min, (c) a melt index MI2 (2.16 kg, 190° C.) and Dow Rheology Index (DRI) satisfying the equation [DRI/MI2]>2.65, and (d) a Dart Drop Impact (DDI) in g of a blown film having a thickness of 25 ?m produced from the copolymer satisfying the equation DDI?1900×{1?Exp [?750(D?0.908)2]}×{Exp [(0.919?D)/0.0045]}. The copolymers may be prepared using metallocene catalysis and are preferably prepared in multistage processes carried out in loop reactors in the slurry phase. The copolymers exhibit long chain branching as defined by Dow Rheology Index (DRI) and exhibit unexpected improvements in mechanical properties, in particular dart drop impact, when extruded into blown films.Type: GrantFiled: January 18, 2011Date of Patent: July 8, 2014Assignee: Ineos Manufacturing Belgium NVInventors: Choon Kooi Chai, Luc Marie Ghislain Dheur, Benoit Koch, Stefan Klaus Spitzmesser
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Patent number: 8765872Abstract: [Object] To provide a resin composition with excellent mold releasability and blocking resistance. [Solution] A resin composition containing a 4-methyl-1-pentene polymer includes 0.01 to 10 parts by mass of a 4-methyl-1-pentene polymer (B) per 100 parts by mass of at least one resin (A) selected from the group consisting of thermoplastic resins and thermosetting resins, wherein the 4-methyl-1-pentene polymer (B) has (B1) an intrinsic viscosity [?] of 0.01 or more but less than 0.50 dl/g measured at 135° C. in a decalin solvent.Type: GrantFiled: January 10, 2011Date of Patent: July 1, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Kuniaki Kawabe, Masayoshi Sutou, Toshiyuki Itou, Mai Kurihara, Akinori Etoh, Shinichirou Asao, Kenji Sugimura, Hiroshi Hoya, Koji Matsunaga, Yoji Hayakawa, Kunihiko Mizumoto
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Patent number: 8759460Abstract: New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5 s?1, at 150° C.), branching index g? equal or lower than 0.9 (at Mw of 2·106 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100° C., for a time of at least 10 minutes.Type: GrantFiled: November 30, 2009Date of Patent: June 24, 2014Assignee: Bassell Polyolefine GmbHInventors: Eleonora Ciaccia, Iakovos Vittorias, Shahram Mihan, Lenka Lukesova, Dieter Lilge, Maclovio Herrera Salinas, Gerhardus Meier, Gerd Mannebach
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Publication number: 20140135461Abstract: A method for producing an olefin polymer including: polymerizing one or more ?-olefins each having 6 to 20 carbon atoms in the presence of a metallocene catalyst to obtain an olefin polymer; deactivating and decalcifying the catalyst to obtain a decalcified polymerization reaction liquid; mixing the decalcified polymerization reaction liquid containing the olefin polymer with water; and washing the liquid with stirring at a stirring intensity of 0.1 kW/m3 or more for 1 minute or longer.Type: ApplicationFiled: June 28, 2012Publication date: May 15, 2014Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Jun Kohiruimaki, Masao Aida, Jun Mase, Kana Minamimoto
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Publication number: 20140114032Abstract: A method for producing an olefin polymer including: polymerizing one or more ?-olefins each having 6 to 20 carbon atoms in the presence of a metallocene catalyst to obtain an olefin polymer, and diluting a polymerization reaction liquid with a solvent before or simultaneously with deactivation of the catalyst, thereby to lower the liquid viscosity of the polymerization reaction liquid to 10 mPa·s or less to promote deactivation and decalcification of the catalyst.Type: ApplicationFiled: June 27, 2012Publication date: April 24, 2014Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Jun Kohiruimaki, Masao Aida, Jun Mase, Kana Minamimoto
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Publication number: 20140087984Abstract: This disclosure relates to vinyl terminated macromer (VTM) based synthetic basestocks and their methods of preparation, lubricant compositions, methods of lubrication and products so lubricated. The VTM based synthetic basestocks useful for fuels and lubricants include oligomerization or polymerization products of one or more allylic vinyl terminated macromers (VTMs) having a molecular weight from 84 to 10080. The one or more allylic VTMs are oligomerized or polymerized in the presence of a catalyst under oligomerization or polymerization conditions sufficient to give the VTM based synthetic basestock. The catalyst can be a metallocene catalyst or an acid catalyst, e.g., Lewis acid. The one or more allylic vinyl terminated macromers (VTMs) can be one or more allylic vinyl terminated atactic polypropylene macromers (VTM aPP) having a molecular weight from 84 to 2250 and having a terminal allylic vinyl olefin content of at least 90%.Type: ApplicationFiled: September 4, 2013Publication date: March 27, 2014Applicant: ExxonMobil Research and Engineering CompanyInventors: Abhimanyu Onkar Patil, Satish Bodige
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Publication number: 20140039143Abstract: A process for making propylene by dehydration of propanol can include gasifying a carbonaceous solid or liquid feedstock, or reforming a gaseous carbonaceous feedstock into synthesis gas. The synthesis gas can be fermented or co-fermented by means of a microorganism into propanol. The microorganism can be a wild strain having the natural capability to ferment synthesis gas into propanol. The microorganism can be a microorganism possessing the required nucleic acid sequence information to express the enzymes for the biosynthesis of C3-oxygenates modified with the required nucleic acid sequence information to express the enzymes of the Wood-Ljungdahl pathway. The microorganism can be a microorganism possessing the required nucleic acid sequence information to express the enzymes of the Wood-Ljungdahl pathway, modified with the required nucleic acid sequence information to express the enzymes for the biosynthesis of C3-oxygenates.Type: ApplicationFiled: December 15, 2011Publication date: February 6, 2014Applicant: TOTAL RESEARCH & TECHNOLOGY FELUYInventor: Walter Vermeiren
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Patent number: 8629220Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.9% by weight of a thermoplastic polyamide, B) from 0.1 to 20% by weight of a terpolymer obtainable via copolymerization of (B1) from 1 to 70% by weight of at least one electron-deficient olefin, (B2) from 0 to 85% by weight of at least one olefin which, at its olefinic double bond, bears only hydrogen atoms and/or carbon atoms without electron-withdrawing substituents, and (B3) from 1 to 99% by weight of at least one alkoxyvinylsilane, C) from 0 to 50% by weight of a fibrous or particulate filler or a mixture of these, D) from 0 to 50% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.Type: GrantFiled: January 17, 2012Date of Patent: January 14, 2014Assignee: BASF SEInventors: Manoranjan Prusty, Arno Lange, Claus Gabriel, Matthias Scheibitz
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Patent number: 8623983Abstract: The application provides a terpolymer obtainable by copolymerizing (A) 1% to 70% by weight of at least one electron-deficient olefin, an example being an anhydride of a monoethylenically unsaturated C4 to C6 dicarboxylic acid, (B) 1% to 85% by weight of at least one olefin which on its olefinic double bond carries only hydrogen atoms and/or carbon atoms without electron-withdrawing substituents, an example being an isobutene homopolymer or copolymer having a number-average molecular weight of 100 to 500 000, and (C) 1% to 70% by weight of at least one alkoxyvinylsilane, and also derivatives of this terpolymer that are obtainable by modification or crosslinking.Type: GrantFiled: September 2, 2011Date of Patent: January 7, 2014Assignee: BASF SEInventors: Arno Lange, Matthias Scheibitz, Manoranjan Prusty
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Publication number: 20130317166Abstract: An ?-olefin polymer satisfying the following (1) to (4): (1) the average carbon-atom number of ?-olefins constituting the polymer is 6.0 or more and 14 or less; (2) the molecular weight distribution (Mw/Mn)?2.0; (3) 3000?weight average molecular weight (Mw)?600000; and (4) (Log10 Mp-Log10M1)?(Log10M2-Log10Mp)?0.2; wherein, in a chart measured by gel permeation chromatography, M1 is the molecular weight at the starting point of the peak, Mp is the molecular weight at the peak top; and M2 is the molecular weight at the end point of the peak.Type: ApplicationFiled: November 24, 2011Publication date: November 28, 2013Applicant: Idemitsu Kosan Co., Ltd.Inventors: Masami Kanamaru, Takenori Fujimura, Yutaka Minami
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Publication number: 20130310527Abstract: An ?-olefin polymer has (A) a tacticity index(meso triad fraction)[mm] of 10 to 50 mol %, (B) a kinematic viscosity at 100° C. of 200 to 10,000 mm2/s, (C) a content of a dimer and a trimer is less than 2 mass %, and (D) an average number of carbon atoms of 4 to 30.Type: ApplicationFiled: September 1, 2011Publication date: November 21, 2013Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Takenori Fujimura, Minako Tsuji, Takuji Okamoto, Yutaka Minami
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Publication number: 20130296483Abstract: A method for producing an olefin oligomer mixture comprising: feeding a raw olefin oligomer mixture to a first evaporator; feeding a residue which is taken out from the first evaporator to a second evaporator, and returning a distillate which is distilled from the second evaporator to the first evaporator; taking a distillate out from the first evaporator; feeding a residue which is taken out from the second evaporator to a third evaporator; and taking a distillate out from the third evaporator.Type: ApplicationFiled: January 11, 2012Publication date: November 7, 2013Applicant: IDEMITSU KOSAN CO, LTD.Inventors: Tatsuyoshi Yokota, Shoichi Uchiyama, Hdeki Sato, Shinji Miyamoto
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Publication number: 20130296518Abstract: A method for producing an ?-olefin oligomer including: polymerizing in the presence of a catalyst one or more ?-olefins having 6 to 20 carbon atoms to produce an ?-olefin oligomer; and deactivating the catalyst by a deactivator from which oxygen is removed. A method for producing an ?-olefin oligomer including: polymerizing in the presence of a catalyst one or more ?-olefins having 6 to 20 carbon atoms to produce an ?-olefin oligomer; and passing the reaction solution containing the ?-olefin oligomer through a bag filter.Type: ApplicationFiled: January 11, 2012Publication date: November 7, 2013Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Hideki Sato, Yushi Matsuda, Jun Kohiruimaki, Masao Aida, Kana Minamimoto, Jun Mase
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Patent number: 8524260Abstract: The invention consists of a method for manufacturing an aqueous formulation containing at least one oil, and comprising the steps of mixing at least one associative polymer, one oil, and water, encapsulating the oil by increasing the pH to a value greater than 8, potentially precipitating the mixture by reducing the pH to a value less than 6, and potentially isolating the resulting particles by removing the water. The aqueous formulations, as with the aqueous dispersions, and the resulting solid particles constitute other objects of the invention.Type: GrantFiled: December 3, 2008Date of Patent: September 3, 2013Assignee: Coatex S.A.S.Inventors: Jean Moro, David Platel, Jean-Marc Suau, Olivier Guerret
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Publication number: 20130210996Abstract: A polyalphaolefin polymer, having a kinematic viscosity at 100° C. of 135 cSt or greater, is shear stable. The polymer either has not more than 0.5 wt % of the polymer having a molecular weight of greater than 60,000 Daltons, or after being subjected to twenty hours of taper roller bearing testing, the polymer has a kinematic viscosity loss of less than 9%. Such a shear stable polyalphaolefin is obtained by either mechanical breakdown of a high viscosity polyalphaolefin or by a selective catalyst system used in oligomerization or polymerization of the feedstock.Type: ApplicationFiled: June 30, 2011Publication date: August 15, 2013Applicant: ExxonMobil Chemical Company - Law TechnologyInventors: Margaret May-Som Wu, Kevin B. Stavens, Wenning W. Han, Abhimanyu O. Patil
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Patent number: 8497327Abstract: The present invention provides hydrogenated ?-pinene-based polymers with excellent heat resistance and light resistance, low absorptivity and high transparency, as well as molded articles thereof. The polymers of the present invention contain 50% by mass or more of ?-pinene units and are hydrogenated ?-pinene-based polymers where the ratio of the proton integral value at 6 to 8 ppm to the total proton integral value in a 1H-NMR spectrum is 2.3×10?5 or less or the p-phenylene group content is 0.0055% by mass or less, and the ratio of the proton integral value at 4.5 to 6 ppm to the total proton integral value is 2.8×10?4 or less or the cyclohexene-1,4-diyl group content is 0.29% by mass or less. The molded articles of the present invention contain the above hydrogenated ?-pinene-based polymers.Type: GrantFiled: April 9, 2009Date of Patent: July 30, 2013Assignee: Kuraray Co., Ltd.Inventors: Atsuhiro Nakahara, Jin Tokuyasu, Takashi Hori, Hiroyuki Ohgi
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Patent number: 8487026Abstract: The invention relates to a hot-melt adhesive substance for sticking together fibrous materials such as matted nonwovens or woven textiles with smooth substrate surfaces, such as plastic or metal films, and for laminating said materials. Said substance is characterized in that it contains at least one polyolefin which has been produced by polymerization in the presence of metallocene as a catalyst and has a ring/ball softening point of between 50 and 165° C. and a melting viscosity, measured at a temperature of 170° C., of between 20 and 40,000 mPa-s. The hot-melt adhesive substance can also contain at least one adhesive component and is used in a quantity of between 3 and 6 g/m2, preferably between 4 and 5.5 g/m2, for sticking a film to a nonwoven material during the production of hygiene items such as disposable nappies, baby nappies, incontinence products, panty liners and/or sanitary towels.Type: GrantFiled: October 6, 2007Date of Patent: July 16, 2013Assignee: Clariant Finance (BVI) LimitedInventors: Sebastijan Bach, Gerd Hohner
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Patent number: 8450437Abstract: The present techniques relate to catalyst compositions, methods, and polymers encompassing a Group 4 metallocene compound comprising bridging ?5-cyclopentadienyl-type ligands, typically in combination with a cocatalyst, and a activator. The compositions and methods presented herein include ethylene polymers with low melt elasticity.Type: GrantFiled: January 12, 2012Date of Patent: May 28, 2013Assignee: Chevron Phillips Chemical Company LPInventors: Qing Yang, Max P. McDaniel, Joel L. Martin, Youlu Yu, David C. Rohlfing, Michael D. Jensen
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Patent number: 8445618Abstract: A highly crystalline higher ?-olefin polymer that is excellent in compatibility with a thermoplastic resin, particularly a polyolefin, compatibility with a lubricant oil, a fuel oil and wax, mixing property with an inorganic filler, and secondary working property, and a process for production thereof are provided. The highly crystalline higher ?-olefin polymer is obtained by polymerizing a monomer containing 80% by mol or more of a higher ?-olefin having from 22 to 40 carbon atoms, and satisfies the following items (1) and (2). (1) The melting point (Tm), which is observed, by using a differential scanning calorimeter (DSC), from a melting endothermic curve obtained by maintaining a specimen at 190° C. for 5 minutes under a nitrogen atmosphere, cooling the specimen to ?10° C. at a rate of 5° C./min, maintaining at ?10° C. for 5 minutes, and then elevating a temperature thereof to 190° C. at a rate of 10° C./min, is from 55 to 100° C.Type: GrantFiled: November 29, 2006Date of Patent: May 21, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takenori Fujimura, Masami Kanamaru, Takuji Okamoto, Yutaka Minami
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Patent number: 8431660Abstract: The present invention provides a non-metallocene transition metal compound that is easily produced, includes a tetrazol group having the high polymerization activity and high temperature stability in the polymerization of olefins, and a catalytic composition that includes the transition metal compound and a cocatalyst. In addition, the present invention provides a method for efficiently producing an olefin homopolymer or copolymer by using the catalytic composition.Type: GrantFiled: December 5, 2008Date of Patent: April 30, 2013Assignee: LG Chem, Ltd.Inventors: Heon-Yong Kwon, Nicola Maggiarosa, Ki-Soo Lee, Min-Seok Cho, Jong-Sang Park, Joon-Hee Cho, Yong-Ho Lee, Byung-Ryul Lee, Seon-Kyoung Kim, Dae-Sik Hong
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Patent number: 8431662Abstract: This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g?)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.Type: GrantFiled: August 20, 2012Date of Patent: April 30, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick Brant, Andrew G. Narvaez, Jr., Donna J. Crowther
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Publication number: 20130085246Abstract: The present invention relates to an olefin-based polymer which exhibits superior processability and superior adhesive properties and therefore is desirably applicable to a hot-melt adhesive (HMA) or the like, and a preparation method thereof. The olefin-based polymer has a molecular weight distribution (Mw/Mn, PDI) of 2˜3, and a density of 0.85 to 0.88 g/cm3, and satisfies the relation of Tc?Tm>0, wherein Tc (° C.) is a crystallization temperature and Tm (° C.) is a melting point.Type: ApplicationFiled: July 1, 2011Publication date: April 4, 2013Applicant: LG Chem LtdInventors: Don-Ho Kum, Eun-Jung Lee, Jong-Joo Ha, Choong-Hoon Lee
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Patent number: 8409681Abstract: A process is disclosed for producing a multi-modal linear low density polyethylene in at least two staged reactors connected in series, comprising (i) polymerizing in a first slurry phase stage ethylene monomers with a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A); and (ii) polymerizing in a second gas or slurry phase stage ethylene monomers with a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B). The Ziegler-Natta polymerization catalyst system comprises: 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of formula (I) b) an aluminum compound of formula (II); and c) a vanadium compound and a titanium compound having a molar ratio (V:Ti) from 10:90 to 90:10; and 2) one or more organometallic cocatalvsts of formula (III). The linear low density polyethylene shows an improved comonomer composition distribution Formulas (I), (II), and (III) are described herein.Type: GrantFiled: February 22, 2010Date of Patent: April 2, 2013Assignee: Borealis AGInventors: Thomas Garoff, Paivi Waldvogel, Kalle Kallio, Virginie Eriksson, Aki Aittola, Esa Kokko
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Patent number: 8394506Abstract: A helical substituted polyacetylene structure including a substrate and a substituted polyacetylene with a periodic main chain having a helical periodic structure, wherein the substituted polyacetylene is disposed inclined on the surface of the substrate with the inclination angle between the main helical axis of the substituted polyacetylene and the surface of the substrate falling in a range of 60° or more and 90° or less. A device structure in which a first electrode, the substituted polyacetylene with the periodic main chain having a helical periodic structure and a second electrode are sequentially disposed on a substrate.Type: GrantFiled: March 3, 2008Date of Patent: March 12, 2013Assignee: Canon Kabushiki KaishaInventors: Takeyuki Sone, Akira Kuriyama, Otto Albrecht, Koji Yano
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Patent number: 8362184Abstract: Embodiments of the invention provide a class of mesophase separated butene/?-olefin block interpolymers with controlled block sequences. The butene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: GrantFiled: January 30, 2009Date of Patent: January 29, 2013Assignee: DOW Global Technologies, LLCInventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Li Pi Shan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20130023633Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.Type: ApplicationFiled: September 27, 2012Publication date: January 24, 2013Applicant: ExxonMobil Chemical Patents Inc.Inventor: ExxonMobil Chemical Patents Inc.
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Patent number: 8334354Abstract: Provided are ethylene copolymers with excellent impact resistance. More specifically, provided are ethylene copolymers satisfying certain correlation between the falling dart impact strength (F) or high rate impact resistant breakage energy (E) and Vicat softening point. The ethylene copolymers with improved impact properties are applicable to film, injection, compound, sheet, roto, pipe or blow molding.Type: GrantFiled: October 29, 2009Date of Patent: December 18, 2012Assignee: SK Innovation Co., Ltd.Inventors: Seungbum Kwon, Hyeongtaek Ham, Choonsik Shim, Sungseok Chae, Myungahn Ok, Daeho Shin
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Patent number: 8334353Abstract: Provided herein are polyfarnesenes such as farnesene homopolymers derived from a farnesene and farnesene interpolymers derived from a farnesene and at least a vinyl monomer; and the processes of making and using the polyfarnesenes. The farnesene homopolymer can be prepared by polymerizing the farnesene in the presence of a catalyst such as a Ziegler-Natta catalyst, a Kaminsky catalyst, a metallocene catalyst, an organolithium reagent or a combination thereof. In some embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: GrantFiled: February 2, 2012Date of Patent: December 18, 2012Assignee: Amyris, Inc.Inventor: Derek James McPhee
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Publication number: 20120302481Abstract: Provided are an ?-olefin (co)polymer useful as high-viscosity lubricant oil excellent in viscosity characteristics and low-temperature characteristics, and a lubricant oil containing the (co)polymer. The ?-olefin (co)polymer is produced by the use of a metallocene catalyst and satisfies the following (a?) and (b?). (a?) The 2,1-insertion ratio at the polymer terminal, as measured through 1H-NMR, is at least 30 mol % of the entire molecule, and (b?) the mesotriad fraction (mm), as measured through 13C-NMR, is at most 50 mol %. Preferably, a 1-octene/1-dodecene copolymer is provided, as produced by the use of a metallocene catalyst and satisfying the following (a) to (c). (a) The molar ratio of the 1-octene unit to the 1-dodecene unit is from 20/80 to 80/20, (b) the mesotriad fraction (mm), as measured through 13C-NMR, is at most 50 mol %, and (c) the kinematic viscosity at 100° C. is from 30 to 1000 mm2/sec.Type: ApplicationFiled: January 26, 2011Publication date: November 29, 2012Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Kiyokazu Katayama, Hideaki Noda, Hitomi Shimizu, Masaki Okano
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Patent number: 8318883Abstract: A polymer having a density of from about 0.960 g/cc to about 0.965 g/cc and a melt index of from about 0.2 g/10 min. to about 0.6 g/10 min. wherein an article formed from the polymer has an environmental stress crack resistance of equal to or greater than about 150 hours when measured in accordance with ASTM D 1693 condition B, 100% Igepal. A polymer having a density of from about 0.955 g/cc to about 0.960 g/cc and a melt index of from about 0.2 g/10 min. to about 0.6 g/10 min. wherein an article formed from the polymer has an environmental stress crack resistance of equal to or greater than about 500 hours when measured in accordance with ASTM D 1693 condition B, 100% Igepal.Type: GrantFiled: June 8, 2011Date of Patent: November 27, 2012Assignee: Chevron Phillips Chemical Company LPInventors: Qing Yang, Max P. McDaniel, William B. Beaulieu, Youlu Yu, Tony R. Crain
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Patent number: 8318873Abstract: Catalyst compositions comprising a first metallocene compound, a second metallocene compound, an activator-support, and an organoaluminum compound are provided. An improved method for preparing cyclopentadienyl complexes used to produce polyolefins is also provided.Type: GrantFiled: February 3, 2011Date of Patent: November 27, 2012Assignee: Chevron Phillips Chemical Company LPInventors: Kumudini C. Jayaratne, Michael D. Jensen, Qing Yang