Ten Or More Carbon Atoms Patents (Class 526/348.3)
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Patent number: 8293859Abstract: Embodiments of the invention provide a class of butene/?-olefin block interpolymers. The butene/?-olefin inter-polymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: GrantFiled: January 30, 2009Date of Patent: October 23, 2012Assignee: Dow Global Technologies, LLCInventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Li Pi Shan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Patent number: 8283428Abstract: This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g?)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.Type: GrantFiled: June 19, 2009Date of Patent: October 9, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick Brant, Andrew G. Narvaez, Jr., Donna J. Crowther
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Publication number: 20120245310Abstract: This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.Type: ApplicationFiled: March 25, 2011Publication date: September 27, 2012Inventors: Donna J. CROWTHER, Matthew W. Holtcamp, John R. Hagadorn, Charles J. Ruff, George Rodriguez, Patrick Brant
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Publication number: 20120245312Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.Type: ApplicationFiled: March 25, 2011Publication date: September 27, 2012Inventors: Matthew W. Holtcamp, Charles J. Ruff, Donna J. Crowther, John R. Hagadorn, Patrick Brant
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Publication number: 20120245271Abstract: Elastomeric interpolymers comprising at least two, or more, cyclic olefin monomers that are prepared by ring opening metathesis polymerization, and that are characterized by having no crystallinity, a glass transition temperature (Tg) of less than ?80° C., and a number average molecular weight (Mn) of at least 40 kg/mole, and functionalized products thereof. A ring opening metathesis polymerization process for producing the elastomeric interpolymers having no crystallinity. Uses of the elastomeric interpolymers in applications such as rubber compounds, tires, and the like. Cores of golf balls that are prepared by using metathesis polymerization produced elastomeric interpolymers having 0 to about 30% crystallinity.Type: ApplicationFiled: June 6, 2012Publication date: September 27, 2012Inventors: James Pawlow, Christopher Robertson, Daniel Graves, Mitch Barry
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Publication number: 20120238720Abstract: Polyethylene films having a good balance of optical and mechanical properties are disclosed. The films are derived from ethylene copolymer compositions made with a suitably substituted phosphinimine catalyst. The ethylene copolymers have very narrow molecular weight distributions and broadened comonomer distributions.Type: ApplicationFiled: February 27, 2012Publication date: September 20, 2012Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.Inventors: Patrick Lam, Victoria Ker, Charles Ashton Garret Carter, Benjamin Milton Shaw, Cliff Robert Baar, Alexei Kazakov, Ian Douglas McKay, Dusan Jeremic
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Publication number: 20120214954Abstract: A polymer having a density of from about 0.94 g/cm3 to about 0.96 g/cm3 and a primary structure parameter 2 (PSP2 value) of greater than about 8.5, wherein an article formed from the polymer has an environmental stress crack resistance of equal to or greater than about 1000 hours when measured in accordance with ASTM D 1693 condition A. A polymer having at least one lower molecular weight component and at least one higher molecular weight component and having a PSP2 value of equal to or greater than about 8.5, wherein an article formed from the polymer has an environmental stress crack resistance of greater than about 1000 hours when measured in accordance with ASTM D 1693 condition A.Type: ApplicationFiled: February 21, 2011Publication date: August 23, 2012Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Richard M. BUCK, Albert P. MASINO, Qing YANG, Paul J. DESLAURIERS, Steven J. SECORA, Elizabeth M. LANIER, Guylaine ST. JEAN, Jon D. RATZLAFF, Christopher E. WITTNER
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Publication number: 20120172548Abstract: A polyolefin has 1) a density in the range of 0.93 to 0.97 g/cm3, 2) a BOCD (Broad Orthogonal Co-monomer Distribution) index defined by a given equation in the range of 1 to 5, and 3) a molecular weight distribution (weight average molecular weight/number average molecular weight) in the range of 4 to 10. A supported hybrid metallocene catalyst comprises a first metallocene compound represented by a first given formulae, a second metallocene compound represented by one of three given formulae, and a support.Type: ApplicationFiled: December 27, 2011Publication date: July 5, 2012Applicant: LG CHEM, LTD.Inventors: Joon-Hee CHO, Ki-Soo LEE, Yong-Gyu HAN, Dae-Sik HONG, Heon-Yong KWON, Jong-Sang PARK, Seon Kyoung KIM
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Publication number: 20120149834Abstract: A novel polyethylene is devised which polyethylene is particularly advantageous for manufacturing rotomoulded articles.Type: ApplicationFiled: August 20, 2010Publication date: June 14, 2012Applicant: BASELL POLYOLEFINE GMBHInventors: Gerd Mannebach, Heinz Vogt, Fabiana Fantinel, Shahram Mihan, Peter Bisson, Cees Besems, Gerhardus Meier, Ulf Schüller, Barbara Gall, Iakovos Vittorias, Manfred Hecker, Michael Olmscheid
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Patent number: 8178635Abstract: Provided is an ?-olefin polymer having an excellent balance between a molecular weight and a melting point, which is a polymer of one or more kinds of ?-olefins having 20 to 40 carbon atoms, and which meets the following requirements (1) to (4): (1) the ?-olefin polymer has a molecular weight distribution (Mw/Mn) determined from its weight average molecular weight (Mw) and number average molecular weight (Mn) in terms of polystyrene measured by a GPC method of 2 or less, and has an Mw of 5,000 or less; (2) measurement of a melting point (Tm) of the ?-olefin polymer with DSC shows one melting peak, a melting heat absorption (AH) calculated from an area of the melting peak is 20 J/g or more, and the melting peak has a half value width of 10° C. or less; (3) when the Mw falls within a range of 1,000 to 5,000 and an average number of carbon atoms (Cn) of the ?-olefins falls within a range of 20 to 40, the Mw, the Cn, and the Tm measured with the DSC satisfy the relationship, 0.0025×Mw+(Cn×3.3812?29.5)?Tm?0.Type: GrantFiled: February 18, 2008Date of Patent: May 15, 2012Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takenori Fujimura, Masami Kanamaru, Yutaka Minami, Takuji Okamoto
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Publication number: 20120101235Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.Type: ApplicationFiled: October 18, 2011Publication date: April 26, 2012Inventors: Donna J. CROWTHER, David M. Fiscus
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Publication number: 20120070596Abstract: Provided is an ethylene copolymer having improved hygienic property. More particularly, the ethylene copolymer satisfies a correlation between a density thereof and an extract content. The ethylene copolymer having improved hygienic property can be applied in injection molding, rotation molding, or blow molding.Type: ApplicationFiled: September 8, 2011Publication date: March 22, 2012Applicant: SK INNOVATION CO., LTD.Inventors: Seung Bum KWON, Se Won OH, Hyeong Taek HAM, Choon Sik SHIM, Sung Seok CHAE, Dae Ho SHIN
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Publication number: 20120065346Abstract: An ethylene-?-olefin copolymer comprising monomer units derived from ethylene and monomer units derived from an ?-olefin having 3 to 20 carbon atoms, having a density (d) of 860 to 950 kg/m3, having a melt flow rate (MFR) of 0.01 to 100 g/10 min, having a bimodal molecular weight distribution, and having a single melting peak measured by a differential scanning calorimeter (DSC).Type: ApplicationFiled: May 27, 2010Publication date: March 15, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshinobu Nozue, Naoko Ochi
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Publication number: 20120065351Abstract: An ethylene-?-olefin copolymer comprising monomer units derived from ethylene and monomer units derived from an ?-olefin having 3 to 20 carbon atoms, having a density (d) of 850 to 970 kg/m3, having a melt flow rate (MFR) of 0.01 to 100 g/10 min, having a bimodal molecular weight distribution, and having a ratio (Mw/Mn) of the weight average molecular weight (Mw) thereof to the number average molecular weight (Mn) thereof of 31 to 70, wherein the number (NLCB) of branches having 5 or more carbon atoms measured by 13C-NMR is from 0.7 to 1.0 per 1000 carbon atoms. This copolymer is superior in a balance between a melt tension, an extrusion load at extruding, and a mechanical strength.Type: ApplicationFiled: May 27, 2010Publication date: March 15, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshinobu Nozue, Naoko Ochi
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Patent number: 8129489Abstract: The present invention provides an ethylene polymer that has excellent fluidity and moldability as well as gives a molded product having excellent mechanical strength. The ethylene polymer of the present invention contains 0.02 to 1.50 mol % of a constitutional unit derived from ?-olefin having 6 to 10 carbon atoms, and has the density of 945 to 975 kg/m3, which satisfies both of the following requirements [1] and [2] simultaneously: [1] in CFC, all the components having a molecular weight of 100,000 or more are eluted at a temperature of 85° C. or higher; and [2] the components eluted at a temperature of 80° C. or lower account for up to 5% of all the components eluted in CFC.Type: GrantFiled: August 12, 2005Date of Patent: March 6, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Masahiko Okamoto, Tetsuji Kasai, Yasushi Tohi, Koji Endo, Shiro Otsuzuki, Takahiro Akashi, Kenji Iwamasa, Yoshiyuki Hirase, Keiko Fukushi, Shinichi Nagano
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Patent number: 8124709Abstract: Embodiments of the invention provide a class of mesophase separated ethylene/?-olefin block interpolymers with controlled block sequences. The ethylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: GrantFiled: January 30, 2009Date of Patent: February 28, 2012Assignee: Dow Global Technologies LLCInventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20120022223Abstract: An alkene interpolymer is prepared by polymerizing at least one 3-substituted C4-10 alkene and at least one C2-8 alkene in a gas phase polymerization using a polymerization catalyst system.Type: ApplicationFiled: January 12, 2010Publication date: January 26, 2012Applicant: Evonik Oxeno GmbHInventors: Michael Grass, Ted Pettijohn, Stefan Buchholz, Gerhard Ellermann, Pal Bentzrod, Tore Dreng, Jarmo Lindroos
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Publication number: 20120010354Abstract: A film, comprising: an interpolymer of ethylene; and a 3-substituted C4-10 alkene, wherein said interpolymer is prepared using a catalyst system comprising a single site catalyst.Type: ApplicationFiled: January 12, 2010Publication date: January 12, 2012Applicant: Evonik Oxeno GmbHInventors: Michael Grass, Ted M. Pettijohn, Stefan Buchholz, Gerhard Ellermann, Tore Dreng, Arild Follestad, Jarmo Lindroos
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Publication number: 20110313119Abstract: A catalyst composition comprising one or more metal complexes of a multifunctional Lewis base ligand comprising a bulky, planar, aromatic- or substituted aromatic-group and polymerization processes employing the same, especially continuous, solution polymerization of one or more ?-olefins at high catalyst efficiencies are disclosed.Type: ApplicationFiled: April 24, 2007Publication date: December 22, 2011Inventors: Wayde V Konze, Daniel D. VanderLende
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Patent number: 8067652Abstract: The invention relates to a process for forming a polyalphaolefin, the process comprising the step of polymerizing at least one C8-C12 monomer, preferably a decene such as 1-decene, in the presence of an aluminoxane, an activator and a metallocene to form the polyalphaolefin, wherein the molar ratio of the aluminoxane to the metallocene is less than 250:1. The invention also relates to a process for forming a polyalphaolefin having a desired kinematic viscosity from at least one monomer in the presence of an aluminoxane, an organoboron compound and a metallocene. The process comprises the steps of, inter alia, providing a correlation between (i) the molar ratio of the aluminoxane to at least one of the organoboron compound and the metallocene, and (ii) the kinematic viscosity of the polyalphaolefin to form polyalphaolefins having predictable viscosities.Type: GrantFiled: August 13, 2009Date of Patent: November 29, 2011Assignee: Chemtura CorporationInventors: Willie C. Bburton, E. Brian Fox
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Patent number: 8067319Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.Type: GrantFiled: July 19, 2010Date of Patent: November 29, 2011Assignee: Dow Global Technologies LLCInventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
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Publication number: 20110281195Abstract: A fuel cell adhesive comprises a polyolefin adhesive having a bonding strength sufficient to adhere two fuel cell stack components together. The bonding strength of the polyolefin adhesive is less than the cohesive strength of any of the fuel cell stack components such that two adhesively bonded fuel cell stack components can be easily separated and re-joined without causing any mechanical damages to the fuel cell stack components. The polyolefin adhesive may be prepared by polymerizing at least an ?-olefin monomer in the presence of a molecular weight controlling agent.Type: ApplicationFiled: May 12, 2010Publication date: November 17, 2011Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INCInventors: Timothy J. Fuller, Vindo Kumar
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Patent number: 8058379Abstract: The present invention provides a 4-methyl-1-pentene polymer having excellent balance between heat resistance and rigidity, a process for producing the polymer, and a film and a LED mold formed from the polymer. The 4-methyl-1-pentene polymer comprises 50 to 100% by mass of a constituting unit derived from 4-methyl-1-pentene and 0 to 50% by mass of a constituting unit derived from at least one of olefins having 2 to 20 carbon atoms excluding 4-methyl-1-pentene, wherein the 4-methyl-1-pentene polymer is obtainable by continuously feeding a monomer forming the 4-methyl-1-pentene polymer and an organic solvent to a polymerization reactor and continuously extracting a polymerization reaction mixture containing the resulting 4-methyl-1-pentene polymer from the polymerization reactor.Type: GrantFiled: July 7, 2008Date of Patent: November 15, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Kazuaki Yasuda, Tooru Tanaka
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Patent number: 8058372Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.Type: GrantFiled: April 9, 2008Date of Patent: November 15, 2011Assignee: Exxonmobil Chemical Patents Inc.Inventors: Gregory Adam Solan, Christopher James Davies
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Patent number: 8048976Abstract: Provided herein are polyfarnesenes such as farnesene homopolymers derived from a farnesene and farnesene interpolymers derived from a farnesene and at least a vinyl monomer; and the processes of making and using the polyfarnesenes. The farnesene homopolymer can be prepared by polymerizing the farnesene in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: GrantFiled: September 1, 2009Date of Patent: November 1, 2011Assignee: Amyris, Inc.Inventor: Derek James McPhee
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Publication number: 20110251360Abstract: New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5 s?1, at 150° C.), branching index g? equal or lower than 0.9 (at Mw of 2·106 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100° C., for a time of at least 10 minutes.Type: ApplicationFiled: November 30, 2009Publication date: October 13, 2011Applicant: BASELL POLYOLEFINE GMBHInventors: Eleonora Ciaccia, Iakovos Vittorias, Shahram Mihan, Lenka Lukesova, Dieter Lilge, Maclovio Herrara Salinas, Gerhardus Meier, Gerd Mannebach
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Publication number: 20110218308Abstract: The purpose of the invention is to provide an ethylene-?-olefin copolymer, which has a high melt tension but a small neck-in, and a molded object produced by extrusion molding of the copolymer. An ethylene-?-olefin copolymer having a monomer unit based on ethylene and a monomer unit based on an ?-olefin having 3 to 20 carbon atoms, which has a melt flow rate (MFR) of 0.1 to 100 g/10 min, a density (d) of 850 to 940 kg/m3, a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) of 2 to 12, and a value g* defined by the following formula (I) of 0.50 to 0.75: g*=[?]/([?]GPC×gSCB*)??(I).Type: ApplicationFiled: November 10, 2009Publication date: September 8, 2011Inventors: Yoshinobu Nozue, Yasutoyo Kawashima, Naoko Ochi, Takuya Ogane
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Publication number: 20110217499Abstract: A polyethylene for IM having excellent processing properties in terms of spiral flow testing is devised.Type: ApplicationFiled: August 27, 2009Publication date: September 8, 2011Applicant: Basell Polyolefine GmbHInventors: Gerd Mannebach, Harald Schmitz, Shahram Mihan, Rainer Karer, Manfred Hecker, Guido Funk, Adrian Popa
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Publication number: 20110217537Abstract: A novel PE material is devised showing excellent mechanical/optical properties and process ability, e.g. for film extrusion. The polyethylene of the invention is produced in one single e.g. gas phase reactor.Type: ApplicationFiled: September 22, 2009Publication date: September 8, 2011Applicant: BASELL POLYOLEFINE GMBHInventors: Fabiana Fantinel, Gerd Mannebach, Shahram Mihan, Gerhardus Meier, Iakovos Vittorias
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Patent number: 8013088Abstract: A polymerization reaction mixture for the cationic polymerization of unsaturated biological oils (e.g. vegetable oils and animals oils) based on the cationic reaction of double bonds initiated by superacids is provided. The polymerized oils have a viscosity about 10 to 200 times higher than the initial oil and relatively high unsaturation (only about 10-30% lower than that of initial oils).Type: GrantFiled: March 9, 2009Date of Patent: September 6, 2011Assignee: Pittsburg State UniversityInventors: Mihail Ionescu, Zoran S. Petrovic
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Patent number: 8008403Abstract: A polyethylene which comprises ethylene homopolymers and/or copolymers of ethylene with 1-alkenes and has a molar mass distribution width Mw/Mn of from 5 to 30, a density of from 0.92 to 0.955 g/cm3, a weight average molar mass Mw of from 50000 g/mol to 500 000 g/mol and has from 0.01 to 20 branches/1000 carbon atoms and a z-average molar mass Mz of less than 1 million g/mol, a process for its preparation, catalysts suitable for its preparation and also films in which this polyethylene is present.Type: GrantFiled: April 25, 2005Date of Patent: August 30, 2011Assignee: Basell Polyolefine GmbHInventors: Jennifer Kipke, Shahram Mihan, Rainer Karer, Dieter Lilge
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Publication number: 20110207637Abstract: This invention relates to an ethylene copolymer for lubricating oil, comprising: ethylene; at least one alpha-olefin having 3 or more carbon atoms; and at least one vicinally substituted olefin having 2 to 40 carbon atoms, wherein: the copolymer has a weight-average molecular weight (Mw) of about 50,000 to about 500,000; and an intensity ratio of S?? to S?? insertions, as determined by a 13C-NMR spectrum of less than 0.5.Type: ApplicationFiled: December 29, 2010Publication date: August 25, 2011Inventors: Sudhin Datta, Smita Kacker, Mun F. Tse, Thomas T. Sun, Eric B. Sirota, Vera Minak-Bernero, Liehpao O. Farng
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Publication number: 20110201766Abstract: In an embodiment, a method is disclosed to increase the activity of an ionic liquid catalyst comprising emulsifying the ionic liquid catalyst with one or more liquid components. In an embodiment, a method is disclosed comprising introducing into a reaction zone a monomer feed and a reduced amount of ionic liquid catalyst and controlling an amount of shear present in the reaction zone to maintain a desired conversion reaction of the monomer. In an embodiment, a catalyzed reaction system is disclosed comprising a reactor configured to receive one or more liquid components and ionic liquid catalyst; a device coupled to the reactor for adding high shear to the liquid components and ionic liquid catalyst; and a controller coupled to the device for adding high shear and configured to control the amount of shear added to a catalyzed reaction zone to maintain a conversion reaction.Type: ApplicationFiled: April 25, 2011Publication date: August 18, 2011Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Lee H. BERGMAN, Kenneth D. HOPE, Elizabeth A. BENHAM, Donald A. STERN
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Patent number: 7985817Abstract: Disclosed is a homogeneous catalyst system for producing an ethylene homopolymer or an ethylene copolymer with ?-olefin. Specifically, this invention pertains to a transition metal catalyst which has stability under high temperature solution polymerization at 120˜250° C., in which a cyclopentadiene derivative and an electron donating substituent, both of which are bonded to a Group IV transition metal acting as a central metal, are crosslinked through a silyl derivative substituted with a cyclohexyl, to a catalyst system including such a transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and to a method of producing an ethylene homopolymer or an ethylene copolymer with ?-olefin, having high molecular weight, using the catalyst system under conditions of high-temperature solution polymerization.Type: GrantFiled: September 8, 2006Date of Patent: July 26, 2011Assignee: SK Energy Co., Ltd.Inventors: Tae Woo Woo, Myung Ahn Ok, Jong Sok Hahn, Sang Ook Kang, Jae Ho Jung
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Publication number: 20110177313Abstract: Copolymers of ethylene and ?-olefins having C7—C12 carbon atoms having: (a) a density (D) in the range 0.900-0.940 g/cm3, (b) a melt index MI2 (2.16 kg, 190° C.) in the range of 0.01-50 g/10 min, (c) a melt elastic modulus G? (G?=500 Pa) in the range 20 to 150 Pa, and (d) a tear strength (MD) of ?220 g, a tear strength (TD) of ?470 g, and a Dart Drop Impact (DDI) of ?1800 g of a blown film having a thickness of 25 ?m produced from the copolymer; where MD is referred to the machine direction and TD is the transverse direction of the blown film are suitably prepared in the gas phase by use of a supported metallocene catalyst system. Particularly suitable are copolymers of ethylene and 1-octene and the resultant blown films show improved processability and exhibit an improved balance of film properties of dart impact and tear strength.Type: ApplicationFiled: October 9, 2009Publication date: July 21, 2011Inventors: Choon Kooi Chai, Claudine Viviane Lalanne-Magne, Eric Osmont
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Publication number: 20110165416Abstract: [Object] To provide a resin composition with excellent mold releasability and blocking resistance. [Solution] A resin composition containing a 4-methyl-1-pentene polymer includes 0.01 to 10 parts by mass of a 4-methyl-1-pentene polymer (B) per 100 parts by mass of at least one resin (A) selected from the group consisting of thermoplastic resins and thermosetting resins, wherein the 4-methyl-1-pentene polymer (B) has (B1) an intrinsic viscosity [?] of 0.01 or more but less than 0.50 dl/g measured at 135° C. in a decalin solvent.Type: ApplicationFiled: January 10, 2011Publication date: July 7, 2011Inventors: Kuniaki KAWABE, Masayoshi Sutou, Toshiyuki Itou, Mai Kurihara, Akinori Etoh, Shinichirou Asao, Kenji Sugimura, Hiroshi Hoya, Koji Matsunaga, Yoji Hayakawa, Kunihiko Mizumoto
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Publication number: 20110165357Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 937 to 950 kg/m3, a melt index MFR5 of from 0.3 to 3.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 30.Type: ApplicationFiled: May 25, 2009Publication date: July 7, 2011Applicant: BOREALIS AGInventors: Mats Backman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlof, Tarja-Tuulikki Turpeinen, John Severn
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Publication number: 20110160420Abstract: The present invention provides a process for the production of a degassed polymer powder, which process comprises a) feeding i) a principal monomer, and ii) one or more comonomers fed in an amount of at least 5000 ppmw relative to the principal monomer feed rate, and iii) optionally one or more added alkanes having 2 to 10 carbon atoms, fed in an amount of at least 1000 ppmw relative to the principal monomer feed rate; into a polymerisation reactor wherein the monomer and comonomers react to form a polymer comprising residual hydrocarbons comprising one or more hydrocarbons having 3 to 10 carbon atoms, and b) passing the polymer to a degassing step wherein it is contacted with a purge gas to remove at least some of the residual hydrocarbons, characterised in that: 1) the G/P ratio in the degassing step is higher than a minimum G/P ratio, G being the purge gas mass flow rate in the degassing step and P being the polymer throughput of the degassing step, and 2) the purge gas has a concentration of critical hydrType: ApplicationFiled: September 21, 2009Publication date: June 30, 2011Inventors: Jean-Louis Chamayou, Daniel Marissal
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Patent number: 7951889Abstract: In an embodiment, a method is disclosed to increase the activity of an ionic liquid catalyst comprising emulsifying the ionic liquid catalyst with one or more liquid components. In an embodiment, a method is disclosed comprising introducing into a reaction zone a monomer feed and a reduced amount of ionic liquid catalyst and controlling an amount of shear present in the reaction zone to maintain a desired conversion reaction of the monomer. In an embodiment, a catalyzed reaction system is disclosed comprising a reactor configured to receive one or more liquid components and ionic liquid catalyst; a device coupled to the reactor for adding high shear to the liquid components and ionic liquid catalyst; and a controller coupled to the device for adding high shear and configured to control the amount of shear added to a catalyzed reaction zone to maintain a conversion reaction.Type: GrantFiled: November 1, 2004Date of Patent: May 31, 2011Assignee: Chevron Phillips Chemical Company LPInventors: Lee H. Bergman, Kenneth D. Hope, Elizabeth A. Benham, Donald A. Stern
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Patent number: 7947797Abstract: Embodiments of the present invention relate to operating a gas-phase reactor at or near maximum production rates and to measuring and controlling polymer stickiness in a gas phase reactor polymerization. In particular, embodiments relate to monitoring acoustic emissions in a reactor during gas phase polymerization to determine the onset of reactor stickiness and possibly discontinuity events such as chunking and sheeting resulting from that stickiness. Embodiments also relate to monitoring acoustic emissions to determine the need for effective control of parameters that minimize reactor stickiness and thereby preventing discontinuity events. The emissions are processed by arithmetic averaging.Type: GrantFiled: September 14, 2005Date of Patent: May 24, 2011Assignee: Univation Technologies, LLCInventors: Michael E. Muhle, Robert O. Hagerty
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Patent number: 7947793Abstract: Embodiments of the invention provide a class of ethylene/?-olefin block interpolymers. The ethylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: GrantFiled: January 30, 2009Date of Patent: May 24, 2011Assignee: Dow Global Technologies LLCInventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Patent number: 7943807Abstract: The invention relates to a polyalphaolefin formed from a decene and propene and having a branch level greater than 19% and to a process for forming such polyalphaolefins. The invention also relates to a process for forming a polyalphaolefin from at least two monomers, the two monomers comprising a decene and propene, the process comprising the steps of, inter alia, providing a correlation between the total amount of propene used to form the polyalphaolefin and at least one of branch level or viscosity of the polyalphaolefin to make polyalphaolefins comprising decene and propene with predictable branch levels and viscosities.Type: GrantFiled: February 6, 2008Date of Patent: May 17, 2011Assignee: Chemtura CorporationInventors: Willie Charles Burton, E. Brian Fox
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Publication number: 20110108121Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 935 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI27/210 of from 2 to 50.Type: ApplicationFiled: May 25, 2009Publication date: May 12, 2011Applicant: BOREALIS AGInventors: Mats Backman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlöf
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Publication number: 20110091674Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 960 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 50. The compositions further have a level of volatile compounds of at most 100 ppm by weight and/or a homogeneity rating of at most 3.Type: ApplicationFiled: May 25, 2009Publication date: April 21, 2011Applicant: BOREALIS AGInventors: Mats Backman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlof
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Publication number: 20110086993Abstract: Articles made of and/or including ultrahigh molecular weight polyethylene (UMWPE) having increased strength and/or wear resistance, such as high yield strength, high tensile strength, high load strength, and/or high impact strength. Some embodiments of articles made of and/or including UHMWPE having increased strength and/or wear resistance, such as that listed above, include UHMWPE having co-monomers.Type: ApplicationFiled: December 20, 2010Publication date: April 14, 2011Applicant: SMITH & NEPHEW ORTHOPAEDICS AGInventors: Paul Smith, Jeroen Visjager, Theo Tervoort
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Patent number: 7915358Abstract: Copolymers when used as lubricating oil viscosity modifiers enable lubricating oils to show excellent low-temperature properties. Processes for producing the copolymers are disclosed. Lubricating oil viscosity modifiers and lubricating oil compositions contain the copolymers. A copolymer includes structural units derived from ethylene and structural units derived from a C3-20 ?-olefin and satisfies the following requirements (1) to (8): (1) the melting point (Tm) according to DSC is in the range of 0 to 60° C.; (2) the melting point (Tm) and the density D (g/cm3) satisfy the equation: Tm?1073×D?893; (3) Mw/Mn according to GPC is from 1.6 to 5.0; (4) the half-value width (?Thalf) of a melting peak measured by DSC is not more than 90° C.; (5) the half-value width (?Thalf) and the melting point (Tm) satisfy the equation: ?Thalf??0.71×Tm+101.4; (6) the heat of fusion (?H) as measured by DSC is not more than 60 J/g; (7) the crystallization temperature (Tc) measured by DSC is not more than 70° C.Type: GrantFiled: February 13, 2009Date of Patent: March 29, 2011Assignee: Mitsui Chemicals, Inc.Inventors: Satoshi Ikeda, Akihiro Matsuda, Yoshiki Shimokawatoko, Junichi Mohri, Toshiyuki Shimazaki, Hiroshi Terao, Koji Takeda
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Patent number: 7910679Abstract: Provided are bulk homogeneous polymerization processes for producing ethylene propylene random copolymers. The process includes contacting in a reactor or in a series of reactors propylene monomer, ethylene comonomer with one or more catalyst systems and optional solvent (present at less than 40 wt %), wherein the reactor train is at a temperature of between 65° C. and 180° C.Type: GrantFiled: November 14, 2008Date of Patent: March 22, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Robert Patrick Reynolds, Jr., John W. Chu, Steven P. Rucker, James Richardson Lattner
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Publication number: 20110034656Abstract: The invention is directed an alpha-olefin homo- or copolymer composition comprising at least one (i) alpha-olefin homo- or copolymer component, wherein the alpha-olefin homo- or copolymer composition comprises a decreased amount of C6-C15-oligomers.Type: ApplicationFiled: October 18, 2010Publication date: February 10, 2011Applicant: BOREALIS TECHNOLOGY OYInventors: Torvald Vestberg, Peter Denifl, Timo Leinonen
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Publication number: 20110015363Abstract: Embodiments of the invention provide a class of propylene/?-olefin block interpolymers. The propylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block propylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the propylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: ApplicationFiled: January 30, 2009Publication date: January 20, 2011Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20110015354Abstract: Embodiments of the invention provide a class of mesophase separated propylene/?-olefin block interpolymers with controlled block sequences. The propylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block propylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (“TREF”), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the propylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: ApplicationFiled: January 30, 2009Publication date: January 20, 2011Applicant: Dow Global Technologies Inc.Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts