At Least Four Carbon Atoms Patents (Class 526/348.6)
  • Patent number: 7915358
    Abstract: Copolymers when used as lubricating oil viscosity modifiers enable lubricating oils to show excellent low-temperature properties. Processes for producing the copolymers are disclosed. Lubricating oil viscosity modifiers and lubricating oil compositions contain the copolymers. A copolymer includes structural units derived from ethylene and structural units derived from a C3-20 ?-olefin and satisfies the following requirements (1) to (8): (1) the melting point (Tm) according to DSC is in the range of 0 to 60° C.; (2) the melting point (Tm) and the density D (g/cm3) satisfy the equation: Tm?1073×D?893; (3) Mw/Mn according to GPC is from 1.6 to 5.0; (4) the half-value width (?Thalf) of a melting peak measured by DSC is not more than 90° C.; (5) the half-value width (?Thalf) and the melting point (Tm) satisfy the equation: ?Thalf??0.71×Tm+101.4; (6) the heat of fusion (?H) as measured by DSC is not more than 60 J/g; (7) the crystallization temperature (Tc) measured by DSC is not more than 70° C.
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: March 29, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Satoshi Ikeda, Akihiro Matsuda, Yoshiki Shimokawatoko, Junichi Mohri, Toshiyuki Shimazaki, Hiroshi Terao, Koji Takeda
  • Patent number: 7910679
    Abstract: Provided are bulk homogeneous polymerization processes for producing ethylene propylene random copolymers. The process includes contacting in a reactor or in a series of reactors propylene monomer, ethylene comonomer with one or more catalyst systems and optional solvent (present at less than 40 wt %), wherein the reactor train is at a temperature of between 65° C. and 180° C.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: March 22, 2011
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gabor Kiss, Robert Patrick Reynolds, Jr., John W. Chu, Steven P. Rucker, James Richardson Lattner
  • Patent number: 7902308
    Abstract: A complex compound comprising the skeletal unit of Formula A, wherein the ring represented by C(R1)-A1-A2-(A3)x-C(R2)—C— has delocalised unsaturation and is optionally substituted via one or more of A1, A2 and A3 with atoms or groups selected from hydrogen, alkyl, aryl, halogen, or heterocyclic groups containing at least one N, S or O in a carbon ring; A1, A2 and A3 are selected from carbon, nitrogen or oxygen, R1 and R2 are each selected from chlorine, bromine or iodine; x is zero or 1, O is oxygen, E is nitrogen, phosphorus or arsenic, Q represents a divalent bridging group comprising one or more Group 14 atoms; M is a metal selected from Groups 3 to 7; X represents a monovalent atom or group covalently or ionically bonded to M; L is a mono- or bidentate molecule datively bound to M, y satisfies the valency of M and z is from 0 to 5. The complex can be used to polymerise olefins optionally with organo-A1 or -B compounds as activator.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: March 8, 2011
    Assignee: Ineos Europe Limited
    Inventors: Vernon Charles Gibson, Daniel Charles Howard Oakes
  • Patent number: 7897710
    Abstract: Film formed from a polyethylene resin composition which obeys a dynamic rheological relationship at 190° C. between melt storage modulus G?, measured in Pa and at a dynamic frequency where the loss modulus G?=3000 Pa, and dynamic complex viscosity ?*100, measured in Pa·s at 100 rad/s, such that (a) G?(G?=3000)>?0.86?*100+z where z=3800, and at the same time (b) G?(G?=3000)>0.875?*100?y where y=650, and having an impact strength (DDT) of at least 250 g, measured on 15 ?m thick film (blown under conditions with BUR=5:1 and Neck Height=8×D) conditioned for 48 hours at 20°-25° C., according to ASTM D1709.
    Type: Grant
    Filed: August 12, 2005
    Date of Patent: March 1, 2011
    Assignee: Ineos Manufacturing Belgium NV
    Inventors: John Amos, Choon Kooi Chai, Luc Marie Ghislain Dheur
  • Patent number: 7893180
    Abstract: A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provide is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: February 22, 2011
    Assignee: Westlake Longview Corp.
    Inventors: Randal Ray Ford, Richard Kingsley Stuart, Jr.
  • Publication number: 20110034657
    Abstract: A process for the polymerization of olefin's, including: introducing an olefin and a polymerization catalyst into a polymerization reactor to form a polyolefin, the polymerization reactor including: a fluidized bed region having a top and a bottom; and a motive bed region; wherein a first end of the motive bed region is fluidly connected to the top of the fluidized bed region; and wherein a second end of the motive bed region is fluidly connected to the bottom of the fluidized bed region; and wherein a diameter of the fluidized bed region is greater than a diameter of the motive bed region; circulating at least a portion of the olefin, the catalyst, and the polyolefin through the fluidized bed region and the motive bed region; maintaining a dense-phase fluidized bed within the fluidized bed region; recovering polyolefin from the fluidized bed region, is provided. A reactor system directed to the process is also provided.
    Type: Application
    Filed: April 21, 2009
    Publication date: February 10, 2011
    Applicant: UNIVATION TECHNOLOGIES, LLC
    Inventors: Fathi D. Hussein, Ping Cai, Jose F. Cevallos-Candau, Ian D. Burdett, W. Scott Hamilton, Daniel N. Thomas, JR.
  • Publication number: 20110034658
    Abstract: 1-butene/ethylene/propylene terpolymer containing: c) from 4 to 10 wt % of ethylene derived units, and d) from 2 to 10 wt % of propylene derived units; the said terpolymer having the following properties: distribution of molecular weights (Mw/Mn) measured by GPC lower than 3; no melting point detectable at the DSC; melting enthalpy, measured after 10 days of aging at room temperature, from 12 to 20 J/g.
    Type: Application
    Filed: March 18, 2009
    Publication date: February 10, 2011
    Inventors: Giampaolo Pellegatti, Stefano Spataro, Tiziana Caputo
  • Publication number: 20110015363
    Abstract: Embodiments of the invention provide a class of propylene/?-olefin block interpolymers. The propylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block propylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the propylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.
    Type: Application
    Filed: January 30, 2009
    Publication date: January 20, 2011
    Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
  • Patent number: 7872086
    Abstract: Disclosed herein is a polymer composition, its manufacture and use, said composition may comprise greater than about 90 mole % propylene monomer, and having a unique combination of properties, including one or more of the following: a heat of fusion of more than about 108 J/g, a melting point of 165° C. or higher, a Melt Flow Rate so low that it is essentially not measurable and a molecular weight of greater than about 1.5×106. Further disclosed herein are blends or mixtures of the present novel polymer composition and products, such as, for example, microporous film structures and the like comprising same.
    Type: Grant
    Filed: January 17, 2008
    Date of Patent: January 18, 2011
    Assignee: Tonen Chemical Corporation
    Inventors: Patrick Brant, Jeffrey L. Brinen, Zerong Lin, Koichi Kono, Kohtaro Kimishima, Hiroyuki Ozaki
  • Publication number: 20110009580
    Abstract: A copolymer of ethylene and an alpha-olefin, said copolymer having a (a) density>0.930 g/cm3, (b) melt index (g/10 min)>4, (c) molecular weight distribution (MWD)>3.0, and (d) FNCT>250 hours., and is described suitable for use in rotomoulding applications. In particular the novel copolymers result in improved impact strength, improved permeation resistance and improved environmetal stress crack resistance and may suitably be prepared by use of metallocene catalysts.
    Type: Application
    Filed: August 27, 2010
    Publication date: January 13, 2011
    Applicant: Ineos Europe Limited
    Inventor: Choon Kooi Chai
  • Publication number: 20110003939
    Abstract: A 1-butene propylene ethylene terpolymer having a content of propylene derived units ranging from 0.1-10% by weight and an ethylene derived units content ranging from 0.1 to 3% by weight having the following properties: a) distribution of molecular weight Mw/Mn measured by GPC lower than 3.5; b) melting point (DSC) comprised between 60° C. and 120° C.; c) Content of 1-butene units in the form of isotactic pentads (mmmm) higher than 95%.
    Type: Application
    Filed: February 23, 2009
    Publication date: January 6, 2011
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: Stefano Spataro, Giampaolo Pellegatti, Tiziana Caputo
  • Patent number: 7858723
    Abstract: Ethylene-based resin, which exhibits a satisfactorily high melt tension and can provide a molded object excellent in mechanical strength, the ethylene-based resin characterized in simultaneously satisfying the requirements [1] to [5] described below: [1] melt flow rate (MFR) under a loading of 2.16 kg at 190° C. is in the range of 0.1 to 100 g/10 minutes; [2] density (d) is in the range of 875 to 970 kg/m3; [3] ratio [MT/?*(g/P)] of melt tension [MT(g)] at 190° C. to shearing viscosity [?*(P)] at 200° C. at an angular velocity of 1.0 rad/sec. is in the range of 1.50×10?4 to 9.00×10?4; [4] sum [(A+B)(/1000C)] of the number of methyl branches [A(/1000C)] and the number of ethyl branches [B(/1000C)] per 1000 carbon atoms measured by 13C-NMR is 1.8 or less; and [5] zero shear viscosity [?0(P)] at 200° C. and weight-average molecular weight (Mw) measured by GPC-viscosity detector method (GPC-VISCO) satisfy the following relational expression (Eq-1): 0.01×10?13×Mw3.4??0?4.5×10?13×Mw3.4??(Eq-1).
    Type: Grant
    Filed: January 31, 2006
    Date of Patent: December 28, 2010
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yasuo Satoh, Hideki Bando, Yoshiho Sonobe, Masao Suzuki, Daisuke Tanifuji, Chiaki Tomata, Makoto Mitani
  • Patent number: 7858718
    Abstract: Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-aryl-8-anilinoquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
    Type: Grant
    Filed: July 22, 2009
    Date of Patent: December 28, 2010
    Assignee: Equistar Chemicals, LP
    Inventors: Sandor Nagy, Linda N. Winslow, Shahram Mihan, Reynald Chevalier, Lenka Lukesova, Ilya E. Nifant'ev, Pavel V. Ivchenko, Michael W. Lynch
  • Publication number: 20100324242
    Abstract: Provided are a highly-pure, terminal-unsaturated olefin polymer which is produced through homopolymerization or copolymerization of one or more ?-olefins having from 3 to 28 carbon atoms, or copolymerization of at least one ?-olefin having from 3 to 28 carbon atoms and ethylene, in the presence of a catalyst, and which satisfies the following (1) to (4); and a method of efficiently producing the olefin polymer having a high degree of terminal unsaturation degree and containing little catalyst residue. (1) The content of the transition metal derived from the catalyst is at most 10 ppm by mass, the content of aluminium is at most 300 ppm by mass, and the content of boron is at most 10 ppm by mass; (2) The polymer has from 0.5 to 1.0 vinylidene group/molecule as the terminal unsaturated group; (3) The polymer has an intrinsic viscosity [?], as measured in decalin at 135° C., of from 0.01 to 2.5 dl/g; (4) The polymer has a molecular weight distribution (Mw/Mn) of at most 4.
    Type: Application
    Filed: October 18, 2007
    Publication date: December 23, 2010
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Ryo Aburatani, Takenori Fujimura, Takehiro Tsuda, Yutaka Minami
  • Publication number: 20100323937
    Abstract: This disclosure relates to substantially atactic polymers of at least one of propylene, 1-butene or 1-pentene, processes for making such polymers and compositions including the polymers. The polymers may be used as lubricants or may be combined with low viscosity base stocks to form lubricants. The polymers may be made in the presence of a metallocene catalyst with a non-coordinating anion activator and optionally with hydrogen.
    Type: Application
    Filed: May 13, 2008
    Publication date: December 23, 2010
    Inventors: Margaret M. Wu, Ernestine W. Hill, Liehpao Oscar Farng, Andrew Jackson
  • Publication number: 20100324244
    Abstract: A copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, preferably at least 1-octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C8-C12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C8-C12 alpha-olefin molar content fulfil the following relationship: 0<TmIK?6.5×C+104 wherein C is the molar content of C8-C12 alpha-olefin derived units and TmII is the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135° C. comprised between 0.8 and 5 dL/g; and c) isotactic pentads mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentads rmmr not detectable at 13C NMR.
    Type: Application
    Filed: February 23, 2009
    Publication date: December 23, 2010
    Applicant: Basell Poliolefine Italia s.r.l.
    Inventors: Luigi Resconi, Davide Balboni, Simona Esposito
  • Publication number: 20100324238
    Abstract: A terpolymer of 1-butene, ethylene and a at least a C8-C12 alpha-olefin derived units, containing from 0.1% to 5% by mole of ethylene derived units and from 1 from 20% by mol of C8-C12 alpha-olefin derived units, endowed with the following properties: i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135° C. comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C8-C12 alpha-olefin content fulfil the following relationship: TmI<130×C?0.3 wherein C is the molar content of C8-C12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.
    Type: Application
    Filed: February 27, 2009
    Publication date: December 23, 2010
    Applicant: Basell Poliolefine Italia s.r.l
    Inventors: Luigi Resconi, Davide Balboni, Simona Esposito
  • Patent number: 7855263
    Abstract: A process for obtaining thermoformed articles, comprising the following steps: a) forming a sheet comprising a propylene resin; b) thermoforming the sheet obtained in step a); wherein said propylene resin has the following characteristics: a) distribution of molecular weight Mw/Mn lower than 4; preferably lower than 3; b) 2,1 insertions measured with by 13C-NMR lower than 0.50%; preferably lower than 0.40%; c) eta* and the frequency ? meet the following relation for ? comprised between 0.1 ad 1: eta*>3700?(?0 13) d) melt flow rate (MFR) (ISO 1133) lower than 5; preferably lower than 4; more preferably lower than 3; wherein the polypropylene resin comprises: (i) from 10 to 100% by weight of a propylene homopolymer or a propylene copolymer containing from 0.1% to 10% by mol of derived units of ethylene or an alpha-olefin of formula CH2?CHZ wherein Z is a linear or branched C2-C20 radical; and (ii) from 0 to 90% by weight of a propylene copolymer containing from 0.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: December 21, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: Friederike Morhard, Gabriella Sartori, Alexander Fuchs, Claus Gabriel
  • Publication number: 20100305531
    Abstract: The invention relates to a hot-melt adhesive substance for sticking together fibrous materials such as matted nonwovens or woven textiles with smooth substrate surfaces, such as plastic or metal films, and for laminating said materials. Said substance is characterized in that it contains at least one polyolefin which has been produced by polymerization in the presence of metallocene as a catalyst and has a ring/ball softening point of between 50 and 165° C. and a melting viscosity, measured at a temperature of 170° C., of between 20 and 40,000 mPa·s. The hot-melt adhesive substance can also contain at least one adhesive component and is used in a quantity of between 3 and 6 g/m2, preferably between 4 and 5.5 g/m2, for sticking a film to a nonwoven material during the production of hygiene items such as disposable nappies, baby nappies, incontinence products, panty liners and/or sanitary towels.
    Type: Application
    Filed: October 6, 2007
    Publication date: December 2, 2010
    Applicant: Clariant Finance (BVI) Limited
    Inventors: Sebastijan Bach, Gerd Hohner
  • Publication number: 20100305292
    Abstract: An ethylene-?-olefin copolymer wherein the copolymer has a monomer unit based on ethylene and a monomer unit based on an ?-olefin having 3 to 20 carbon atoms, the density (d) is 860 to 950 kg/m3, the melt flow rate (MFR) is 1 to 100 g/10 min, the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is 4 to 30, the ratio (Mz/Mw) of the Z average molecular weight (Mz) to the weight average molecular weight (Mw) is 2 to 5, the swell ratio (SR) is 1.8 or more, and the characteristic relaxation time (?) obtained by linear viscoelasticity measurement is 0.01 to 10 seconds.
    Type: Application
    Filed: November 27, 2008
    Publication date: December 2, 2010
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Yoshinobu Nozue, Naoko Ochi, Yasutoyo Kawashima
  • Patent number: 7842763
    Abstract: This invention relates to the field of olefin polymerization catalyst compositions, and methods for the polymerization and copolymerization of olefins, including polymerization methods using a supported catalyst composition. In one aspect, the present invention encompasses a catalyst composition comprising the contact product of a first metallocene compound, a second metallocene compound, at least one chemically-treated solid oxide, and at least one organoaluminum compound. The new resins were characterized by useful properties in impact, tear, adhesion, sealing, extruder motor loads and pressures at comparable melt index values, and neck-in and draw-down.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: November 30, 2010
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Michael D. Jensen, Max P. McDaniel, Joel L. Martin, Elizabeth A. Benham, Randy Muninger, Gary Jerdee, Ashish M. Sukhadia, Qing Yang, Matthew G. Thorn
  • Publication number: 20100298515
    Abstract: Embodiments of the invention provide a class of ethylene/?-olefin block interpolymers. The ethylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.
    Type: Application
    Filed: January 30, 2009
    Publication date: November 25, 2010
    Applicant: Dow Global Technologies Inc.
    Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Philip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
  • Publication number: 20100298517
    Abstract: The present invention provides a process for producing an ?-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher a-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.
    Type: Application
    Filed: August 6, 2010
    Publication date: November 25, 2010
    Applicant: Mitsui Chemicals, Inc.
    Inventor: Tooru TANAKA
  • Patent number: 7838611
    Abstract: An object of the present invention relates to provide an ethylene polymer having excellent mechanical strength and excellent molding processability in a wide molding processing temperature range. The invention relates to use an ethylene polymer comprising a repeating unit derived from ethylene, or a repeating unit derived from ethylene and a repeating unit derived from a C3-8 ?-olefin, the ethylene polymer being satisfied with the following (A) to (F). (A) Density (d (kg/m3)) is from 910 to 970, (B) MFR (g/10 min)) is from 0.01 to 50, (C) terminal vinyl number is 0.2 or less per 1,000 carbon atoms, (D) melt strength (MS160 (mN)) measured at 160° C. and MFR are satisfied with MS160>90?130×log(MFR), (E) melt strength (MS190 (mN)) measured at 190° C. and MS160 are satisfied with MS160/MS190<1.8, and (F) fluidized activation energy (Ea (kJ/mol)) and d are satisfied with 127?0.107d<Ea<88?0.060d.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: November 23, 2010
    Assignee: Tosoh Corporation
    Inventors: Satoru Yamada, Kei Inatomi, Yasutake Wakabayashi, Shigehiko Abe, Morihiko Sato, Masao Tanabiki, Satoshi Hamura, Ryuji Ikeda
  • Publication number: 20100292424
    Abstract: This invention discloses an improved process which employs mixed alpha-olefins as feed over activated metallocene catalyst systems to provide essentially random liquid polymers particularly useful in lubricant components or as functional fluids.
    Type: Application
    Filed: July 14, 2006
    Publication date: November 18, 2010
    Inventors: Margaret M. Wu, Norman Yang, Phil Surana, Anura Patil, Steven P. Rucker, Kuangnan Qian, Shakeel Tirmizi, Mark P. Hagemeister
  • Publication number: 20100280206
    Abstract: This application relates to an ethylene polymer having a weight average molecular weight of at least 120,000 including 1-50 tertiary double bonds per 10,000 carbon atoms.
    Type: Application
    Filed: October 11, 2007
    Publication date: November 4, 2010
    Applicant: BOREALIS TECHNOLOGY OY
    Inventors: Ariid Follestad, Petar Doshev, Anne Britt Bjaland, Bernt-Ake Sultan, Magnus Palmlof, Morten Lundquist
  • Publication number: 20100279033
    Abstract: The present invention relates to the use of polyolefins having atactic structural elements in floor coverings, in particular in carpets or artificial lawns.
    Type: Application
    Filed: January 22, 2009
    Publication date: November 4, 2010
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Hinnerk Gordon Becker, Marlies Vey, Lutz Mindach
  • Publication number: 20100273692
    Abstract: Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include less than about 80 wt. % of units derived from ethylene and one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers have a melting peak (Tm), as measured by DSC, of 80° C. or less, and a polydispersity index of about 2.8 or less. In some embodiments, the ethylene-based copolymers have an intramolecular composition distribution of about 50 wt. % or less and/or an intermolecular composition distribution of about 50 wt. % or less.
    Type: Application
    Filed: April 16, 2010
    Publication date: October 28, 2010
    Inventors: Rainer Kolb, Sudhin Datta, Liehpao Oscar Farng, Vera Minak-Bernero, Eric B. Sirota, Thomas Tungshi Sun, Mun Fu Tse
  • Publication number: 20100267908
    Abstract: [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties.
    Type: Application
    Filed: March 18, 2010
    Publication date: October 21, 2010
    Inventors: Kenji Michiue, Mitsuhiko Onda, Shigekazu Matsui, Sadahiko Matsuura, Koji Endo, Makoto Mitani, Terunori Fujita
  • Publication number: 20100267917
    Abstract: The present invention relates to processes for making synthetic polyisoprene latex and synthetic polyisoprene condoms. A process for making a compounded synthetic polyisoprene latex suitable for making a latex film comprises (a) compounding a synthetic polyisoprene latex with suitable compounding ingredients, (b) maturing the latex and optionally (c) storing the latex; characterised in that steps (a), (b) and (c) if included are carried out at a low temperature so as to minimise prevulcanisation of the latex. Condoms can be made from latexes produced according to the process of the invention.
    Type: Application
    Filed: March 12, 2007
    Publication date: October 21, 2010
    Applicant: LRC PRODUCTS LIMITED
    Inventors: Julie Attrill, Melissa Jane Ballard, Eman Alsaffar
  • Publication number: 20100255240
    Abstract: Providing a non-silicone release sheet that has a good release property and in which blocking does not occur even after long periods of storage in a wound roll-like shape. A release sheet 10 is constructed by laminating an undercoat layer 12 and a release agent layer 13 on a release sheet base 11. The release agent layer 13 is formed of a polyolefin resin composition containing a polyolefin thermoplastic resin having density of 0.800 to 0.905 g/cm3 and polymerized with a multi-site catalyst. In the release agent layer 13, an average modulus of elasticity of the release agent layer at 23° C. in 50 to 1000 nm depths from the surface thereof, as measured by Nano Indentation Method, is 0.1 to 0.3 GPa, and a roughness is formed on the surface so that the surface roughness Ra1 thereof is 100 to 700 nm.
    Type: Application
    Filed: October 30, 2008
    Publication date: October 7, 2010
    Applicant: LINTEC CORPORATION
    Inventors: Shiori Beppu, Naoki Taya, Toshio Sugizaki
  • Publication number: 20100256318
    Abstract: The present invention relates to a propylene random copolymer, comprising comonomers selected from the group consisting of ethylene, C4 to C20 alpha-olefins, and any combination thereof, wherein the propylene random copolymer (a) has a comonomer content of at least 3.5 wt.-%, based on the weight of the propylene random copolymer, (b) has a randomness of at least 30%, and (c) is prepared in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (c1) have a specific surface area of less than 20 m2/g, (c2) comprise a transition metal compound which is selected from one of the groups 4 to 10 of the periodic table or a compound of actinide or lanthanide, (c3) comprise a metal compound which is selected from one of the groups 1 to 3 of the periodic table, and (c4) comprise inclusions not having catalytically active sites.
    Type: Application
    Filed: November 26, 2008
    Publication date: October 7, 2010
    Inventors: Peter Denifl, Timo Leinonen, Anssi Haikarainen, Torvald Vestberg
  • Patent number: 7807768
    Abstract: A polyolefin which contains the following monomer units: a) not more than 25% by weight of units which are derived from ethene, b) not more than 75% by weight of units which are derived from propene and c) from 5 to 100% by weight of units which are derived from an ?-olefin having 4 to 20 carbon atoms, the polyolefin having the following parameters: d) a weight-average molecular weight in the range of from 70 000 to 10 000 000 g/mol, e) a polydispersity in the range of from 4 to 60, f) a melt viscosity, measured by oscillation rheometry at a shear rate of 1 Hz at 190° C., in the range of from 100 000 to 100 000 000 mPa·s, g) a needle penetration in the range of from 3 to 70·0.1 mm, h) an enthalpy of fusion in the range of from 2 to 100 J/g, i) a glass transition temperature Tg in the range of from ?15° C. to ?80° C. and j) a final melting point of the crystalline fraction in the range of from 85 to 175° C.
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: October 5, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Hinnerk Gordan Becker, Hans Guenther Wey, Wolfgang Kilian, Thomas Stojetzki, Marion Vornholt, Marlies Vey, Juergen Derks, Hans-Dieter Zagefka
  • Patent number: 7803728
    Abstract: A fiber is obtainable from or comprises an ethylene/?-olefin interpolymer characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle and a density, d, in grams/cubic centimeter, wherein the elastic recovery and the density satisfy the following relationship: Re>1481?1629(d). Such interpolymer can also be characterized by other properties. The fibers made therefrom have a relatively high elastic recovery and a relatively low coefficient of friction. The fibers can be cross-linked, if desired. Woven or non-woven fabrics can be made from such fibers.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: September 28, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Benjamin C. Poon, Yunwa W. Cheung, Shih-Yaw Lai, Ashish Sen, Hongyu Chen, Yuen-Yuen D. Chiu, Rajen M. Patel, Andy C. Chang, Antonios K. Doufas, Hong Peng
  • Patent number: 7799871
    Abstract: A 1-butene polymer composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene-based polymer, having the following features: distribution of molecular weight Mw/Mn equal to or lower than 4; rr triads, measured by 13C-NMR comprised between 5% and 50%; no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.85 dl/g and 5.0 dl/g; and infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene-based polymer having the following features: isotactic pentads (mmmm) measured by 13C-NMR, higher than 80%; melting point higher than 80° C.; and intrinsic viscosity (IV) measured in tetrahydronaphtalene (THN) at 135° C. comprised between 0.1 dl/g and 5 dl/g.
    Type: Grant
    Filed: June 10, 2005
    Date of Patent: September 21, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: Luigi Resconi, Anteo Pelliconi, Stefano Spataro, Gilberto Moscardi
  • Patent number: 7799877
    Abstract: Methods of monitoring and controlling polymerization reactions are disclosed. The ratio of concentrations of two reactor components are determined in a gas stream of a reactor to obtain a leading indicator function L. The value of L or a function of L, such as a rescaled value or a reciprocal, is compared to a target value, and at least one reactor parameter is adjusted in response to a deviation between L or the function of L and the target value. Monitoring of the leading indicator permits rapid diagnosis of reactor problems, and rapid adjustments of reactor parameters, compared to laboratory analysis of samples of polymer properties.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: September 21, 2010
    Assignee: Univation Technologies, LLC
    Inventors: Kenneth G. Schurzky, Robert L. Santana, Fred D. Ehrman, Pradeep P. Shirodkar
  • Patent number: 7795366
    Abstract: The present invention relates to a composition comprising more than 25 weight % (based on the weight of the composition) of one or more ethylene polymers having an Mw of 20,000 g/mole or more and at least 0.1 weight % of a liquid hydrocarbon modifier where the modifier has: 1) a viscosity index of 120 or more, and 2) an kinematic viscosity of 3 to 3000 cSt at 100° C., and 3) a pour point of ?10° C. or less, and 4) a flash point of 200° C. or more; and wherein the modifier contains less than 5 weight % of functional groups selected from hydroxide, aryls, substituted aryls, halogens, alkoxys, carboxylates, esters, acrylates, oxygen, nitrogen, and carboxyl, based upon the weight of the modifier.
    Type: Grant
    Filed: January 17, 2006
    Date of Patent: September 14, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Henry W. Yang, Bryan R. Chapman, David J. Lohse, Bruce R. Lundmark, Anthony Poloso, Sandra D. Schregenberger, Manika Varma-Nair, Wen Li
  • Patent number: 7795365
    Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.
    Type: Grant
    Filed: October 1, 2003
    Date of Patent: September 14, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. Vanderlende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
  • Patent number: 7790826
    Abstract: The invention relates to formulated compositions which can be easily formed into bottle caps, without the need for a liner, while still maintaining pressure requirements, such as for carbonated beverages. The compositions may include an ethylene polymer having a density in the range of from about 0.947 to 0.962 g/cm3, a melt index of from about 1 to about 10 g/10 min., and another ethylene polymer having a density in the range of from about 0.912 to 0.932 g/cm3, a melt index of from about 0.25 to about 6 g/10 min., wherein the two ethylene polymers have a density difference of equal to or greater than 0.03 g/cm3. In other cases, the composition may include a single component resin with a density in the 0.935-0.955 g/cm3 range with a melt index in the range of 0.3-1.2 g/10 minutes, and wherein the resin comprises a polyethylene polymer.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: September 7, 2010
    Assignee: DowGlobal Technologies Inc.
    Inventors: Debra R. Wilson, William James Michie, Jr., Spyro Petsalis
  • Publication number: 20100216958
    Abstract: Isobutene, isoprene, and butadiene are obtained from mixtures of C4 and/or C5 olefins by dehydrogenation. The C4 and/or C5 olefins can be obtained by dehydration of C4 and C5 alcohols, for example, renewable C4 and C5 alcohols prepared from biomass by thermochemical or fermentation processes. Isoprene or butadiene can be polymerized to form polymers such as polyisoprene, polybutadiene, synthetic rubbers such as butyl rubber, etc. in addition, butadiene can be converted to monomers such as methyl methacrylate, adipic acid, adiponitrile, 1,4-butadiene, etc. which can then be polymerized to form nylons, polyesters, polymethylmethacrylate etc.
    Type: Application
    Filed: February 24, 2010
    Publication date: August 26, 2010
    Inventors: Matthew W. Peters, Joshua D. Taylor, Leo E. Manzer, David E. Henton
  • Patent number: 7776986
    Abstract: Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [?] measured in tetraline at 135° C. from 1 to 3 dL/g; content of xylene insoluble fraction at 0° C. from 3 to 60%; and a ratio ES2/ES1?1, where ES1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: August 17, 2010
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Dino Bacci, Friederike Morhard, Fabrizio Piemontesi, Maria Silvia Tonti, Gianni Vitale, Giampiero Morini, Anteo Pelliconi
  • Patent number: 7776978
    Abstract: A process for producing a 1-butene polymer comprising the step of polymerizing 1-butene in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (Ia) in the meso or meso-like form: wherein M is an atom of a transition metal p is an integer from 0 to 3, X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group.
    Type: Grant
    Filed: June 10, 2005
    Date of Patent: August 17, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: Maria Silvia Tonti, Luigi Resconi
  • Patent number: 7767774
    Abstract: This invention relates to a novel polymerization initiator capable of introducing an active amino proton into a polymerization starting terminal without losing polymerization activity, and a novel modified conjugated diene polymer being excellent in the interaction with a filler and capable of improving a low heat buildup of a rubber composition, and more particularly to a polymerization initiator being a diamine compound in which one amino group is protected with a silylating agent and an active proton of the other amino group is replaced with an alkali metal or an alkaline earth metal, and a modified conjugated diene polymer which can be produced by using such a polymerization initiator and is a homopolymer of a conjugated diene compound or a copolymer of a conjugated diene compound and an aromatic vinyl compound and has a residue derived from a diamine compound at its polymerization starting terminal.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: August 3, 2010
    Assignee: Bridgestone Corporation
    Inventors: Eiju Suzuki, Yoichi Ozawa
  • Publication number: 20100179295
    Abstract: [Object] The present invention provides a 4-methyl-1-pentene polymer having excellent balance between heat resistance and rigidity, a process for producing the polymer, and a film and a LED mold formed from the polymer. [Means for Solving the Problem] The 4-methyl-1-pentene polymer comprises 50 to 100% by mass of a constituting unit derived from 4-methyl-1-pentene and 0 to 50% by mass of a constituting unit derived from at least one of olefins having 2 to 20 carbon atoms excluding 4-methyl-1-pentene, wherein the 4-methyl-1-pentene polymer is obtainable by continuously feeding a monomer forming the 4-methyl-1-pentene polymer and an organic solvent to a polymerization reactor and continuously extracting a polymerization reaction mixture containing the resulting 4-methyl-1-pentene polymer from the polymerization reactor.
    Type: Application
    Filed: July 7, 2008
    Publication date: July 15, 2010
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Kazuaki Yasuda, Tooru Tanaka
  • Patent number: 7750104
    Abstract: Shear-thinning ethylene/?-olefin and ethylene/?-olefin/diene monomer interpolymers that do not include a traditional branch-inducing monomer such as norbornadiene are prepared at an elevated temperature in an atmosphere that has little or no hydrogen using a constrained geometry complex catalyst and an activating cocatalyst.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: July 6, 2010
    Assignee: Dow Global Technologie Inc.
    Inventors: Larry D. Cady, Morgan M. Hughes, Michael K. Laughner, Larry A. Meiske, Deepak R. Parikh
  • Patent number: 7741407
    Abstract: The present invention is directed to golf balls having at least one layer which comprises a polymer produced by a process wherein one or more monomers are contacted with a composition comprising the admixture or reaction product resulting from combining (A) a first olefin polymerization catalyst, (B) a second olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by the first olefin polymerization catalyst under equivalent polymerization conditions, and (C) a chain shuttling agent. Golf balls of the present invention include one-piece, two-piece, and multi-layer golf balls. In two-piece and multi-layer golf balls of the present invention, the polymer may be present in a core layer, a cover layer, an intermediate layer (in the case of multi-layer balls), or a combination thereof.
    Type: Grant
    Filed: December 13, 2006
    Date of Patent: June 22, 2010
    Assignee: Acushnet Company
    Inventors: Brian Comeau, David A. Bulpett, Kevin M. Harris, Murali Rajagopalan
  • Publication number: 20100151172
    Abstract: The present invention concerns a propylene copolymer composition, a molded article comprising the composition and the use of the propylene copolymer composition for preparing molded articles, preferably pipes.
    Type: Application
    Filed: April 10, 2008
    Publication date: June 17, 2010
    Applicant: BOREALIS TECHNOLOGY OY
    Inventors: Juergen Emig, Karl Ebner, Franz Ruemer
  • Patent number: 7737239
    Abstract: A propylene elastomer (PBER) comprising (a) 50 to 85 mol % of units derived from propylene, (b) 5 to 25 mol % of units derived from 1-butene and (c) 10 to 25 mol % of units derived from ethylene, and having a molar ratio of propylene content to ethylene content of from 89/11 to 70/30, and a modulus in tension (YM), as measured in accordance with JIS 6301, of not more than 40 Mpa.
    Type: Grant
    Filed: August 4, 2008
    Date of Patent: June 15, 2010
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Shigenobu Ikenaga, Ryoji Mori
  • Publication number: 20100144998
    Abstract: The invention relates to a process for preparing 1-butenic fractions having less than 2000 ppm of isobutene in relation to 1-butene from technical mixtures of C4 hydrocarbons I which contain at least 1-butene and 2000 ppmw to 8% by mass of isobutene based on the 1-butene, with or without n-butane, isobutane and/or 2-butenes.
    Type: Application
    Filed: February 12, 2010
    Publication date: June 10, 2010
    Applicant: OXENO OLEFINCHEMIE GMBH
    Inventors: Silvia SANTIAGO-FERNANDEZ, Armin RIX, Jochen PRAEFKE, Dirk ROETTGER, Markus WINTERBERG, Wilfried BUESCHKEN
  • Publication number: 20100137505
    Abstract: The present invention relates to a process for producing a propylene terpolymer comprising comonomer units derived from ethylene and from one alpha-olefin selected from the group of C4-C8 alpha-olefins and being characterized by a total content of comonomer units not less than 8% wt and a value of the ratio of ethylene to the C4-C8 alpha-olefins ranging from 0.1 to 0.8, said process being carried out in a gas-phase reactor comprising two interconnected polymerization zones. The present invention further relates to the propylene terpolymer obtained by said process particularly suitable to be used as films such as cast films, bi- or mono-oriented films and heat-sealable films having good optical properties and excellent sealing properties combined with good shrinkage properties and softness.
    Type: Application
    Filed: July 29, 2008
    Publication date: June 3, 2010
    Inventors: Claudio Cavalieri, Camillo Cagnani, Alessandro Guidicini