Abstract: Storage stability of one-component elastomers prepared from constituents having alkoxysilyl end groups is enhanced by employing bin compounds having a coordination number of 5 or 6 in which tin is coordinately bonded to a P?O group as at least one condensation catalyst.

Abstract: The invention relates to silicone compositions that are used in the production of varnishes that can be applied to supports in order to reduce the friction coefficient. The inventive composition comprises at least one polyorganosiloxane A (POS) which can be cationically and radically cross-linked by functional cross-linking groups (GFR) and a primer C chosen from onium borates, characterized in that the inventive composition also comprises molecules (POS D) which are substituted by secondary functional groups (GFS) carried by silicon atoms and selected from those that include at least one alkoxy and/or epoxy and/or carboxy motif and optionally a charge (e.g. silica). The invention can be used with anti-friction varnishes for RTV silicone coatings for material used in air bags, thermal transfer ribbons or packing films.

Abstract: A silicone gel composition is characterized by excellent storage stability in a non-cured state and by high adhesion to a substrate and long-term stability of consistency at elevated temperatures after curing. The silicone gel composition comprises: a polyorganosiloxane (A), which consists of polyorganosiloxane (A-1) that contains R(CH3)2SiO2/2 units, RsiO3/2 units R(CH3)2SiO1/2 units, and polydiorganosiloxane (A-2) that contains R(CH3)2SiO2/2 units and R(CH3)2SiO1/2 units, and R(CH3) which contains in one molecule two silicon-bonded hydrogen atoms; an addition-reaction platinum catalyst (C); an organosilicon compound (D) selected from silane of the general formula (R1O)nSiR24-n or a partially hydrolyzed condensate thereof; and an organic titanium compound (E).

Abstract: There is provided a transparent silicone film-forming composition which forms an ultraviolet-absorbing and infrared-screening film exhibiting a film hardness of 6H to 9H or more after curing on a transparent substrate such as glass and plastic. The transparent silicone film-forming composition contains a reaction product of an alkoxysilane having an epoxy group and alkoxysilane having an amino group with an active hydrogen, an acid catalyst, a finely ground ITO cocatalyst and at least one solvent selected from organic solvents. The transparent silicone film-forming composition can also contain a reaction product of an alkoxysilane having an epoxy group and alkoxysilane having an amino group with an active hydrogen as well as tri- or dialkyloxysilane mixed with monoalkoxysilane and/or glycidesilane, an acid catalyst, a finely ground ITO cocatalyst and at least one solvent selected from organic solvents.

Abstract: The invention relates to a method for producing a sealed impregnation and/or release coating of flat joints, in particular of cylinder-head gaskets such as composite seals, metallic joints and multi-layered steel joints. The invention uses a silicone composition including at least a polyorganosiloxane A crosslinkable by a cationic and/or radical process by appropriate crosslinking functional groups, for example, of the alkenyl ether, acrylic, acrylate, epoxide and/or oxethane type; at least an initiator salt B selected among onium borates or an organometallic complex; and at least a reactive diluent C including a nonorganosilicon or organosilicon compound comprising in its structure at least a crosslinking functional group and optionally a secondary functional group different from the crosslinking functional group but capable of chemically reacting with a crosslinking functional group, for example of the hydroxyl, alkoxy and/or carboxyl type.

Abstract: The present invention provides novel “hybrid” silyl-terminated polymers that contain at least two different reactive end-capping groups. The “hybrid” silyl-terminated polymers of the present invention are produced by a novel single multi-step end-capping reaction of at least one silanol-terminated polymer with at least two silanes in the presence of a catalyst.

Abstract: The invention relates to silicone rubber formulations comprising organopolysiloxanes and hydrophobicized silicas, which possess an extremely high level of whiteness.

Abstract: This invention provides for compositions, which can be crosslinked by radiation to give elastomeric coatings, which comprises: (a) high-molecular weight siloxanes with multiple (meth)acrylate functional groups; and (b) reinforcing fillers selected from the group consisting of silicone resins and silicone dioxide fillers, wherein the siloxanes (a) have the general structure: [R3SiO1/2]a[(Z)nG—Ym—R2SiO1/2]a?[R2SiO2/2]b[(Z)nG—Ym—RSiO2/2]b?[RSiO3/2]c[SiO4/2]d.

Abstract: A moisture-curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, where the polyether segments have a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.

Abstract: Crosslinkable compositions employing organosilicon compounds having at least two hydrolyzable groups, optionally a crosslinker, and optionally a compound containing basic nitrogen, include a crosslinking catalyst which is a reaction product of a phosphorus compound, a sulfur compound, and a tin compound. The compositions exhibit improved shelf life.

Abstract: The invention is an adhesive composition comprising a) i) a trialkoxysilane functional polyether or polyurethane wherein the polyether or polyurethane has a weight average molecular weight of 6000 or greater and a dialkyltin carboxylate or dialkyltin alcoholate; or ii) a dialkoxysilane functional polyether or polyurethane and a dialkyltin alcoholate; and b) a primary or secondary amino straight chain alkyl trialkoxysilane; wherein the dialkyltin carboxylate or dialkyltin alcoholate is present in an effective amount to facilitate bonding of the adhesive to a substrate of from about 0.1 to about 1.0 percent by weight based on the weight of the adhesive and the primary or secondary amino straight chained alkyl trialkoxysilane is present in an amount which is effective to facilitate bonding of the adhesive to a substrate wherein the amount is from about 0.5 to about 1.2 percent by weight.

Abstract: A Process for the preparation of materials crosslinkable with elimination of alcohols to give elastomers, wherein

Abstract: An organopolysiloxane copolymer, comprising (i) R1SiO3/2 units, (ii) random R22SiO2/2 units, and (iii) linear (R32SiO)n units, wherein R1 is independently hydrocarbyl or halogen-substituted hydrocarbyl, R2 and R3 are independently R1 or H, n has an average value of from 5 to 500, the mole ratio of R1SiO3/2 units to R22SiO2/2 units is from 1 to 30, and the mole ratio of R1SiO3/2 units and R22SiO2/2 units combined to (R32SiO)n units is from 3 to 600 when the copolymer contains aliphatic unsaturation or from 1 to 600 when the copolymer is free of aliphatic unsaturation; and a method of preparing the organopolysiloxane copolymer.

Abstract: Condensation curable poly(fluoroorgano)siloxane-poly(silarylene)siloxane block copolymer compositions having a glass transition temperature not exceeding about −54° C. and excellent solvent resistance have been found useful as sealants. Polyalkoxysilylorgano compounds, such as 1,4-bis[trimethoxysilyl(ethyl)]benzene have been found to be effective as cross-linkers.

Abstract: The polymeric composition for friction elements comprises a co-polymer between (I) a resin containing phenolic groups and a reticulation agent, and (II) an organopolysiloxane resin containing terminal silanol groups. A part at least of the phenolic groups is bound to the terminal silanol groups. A process of the preparation of the above polymeric composition may comprise the following steps: a) mixing (I) a resin containing the phenolic groups and the reticulation agent, (II) containing the terminal silanol groups, and (III) an epoxy resin or the epoxidisesd organopolysiloxane; b) curing the mixture for a period of time sufficient to complete substantially the reaction between the phenolic groups and the terminal silanol groups, c) post-heating the product obtained under b).

Abstract: The specification describes preparation of materials comprising selected boron anions and processes using them as catalysts for condensation reaction of compounds having silicon-bonded hydroxy or alkoxy groups. Preferred anion compounds comprise borates incorporating quadri-substituted boron in which the substituents include highly halogenated hydrocarbon groups for example pentafluorinated phenyl groups or bis (trifluoromethyl) phenyl groups. Preferred anions are {B(C6F5)4}− and {B(C6(CF3)2H3)4}−.

Abstract: The present invention relates to compositions for preparing coatings having a release effect, to substrates coated therewith, and to a process for preparing the compositions.

Abstract: The invention provides a curing agent for two-pack type curable composition use having excellent storage stability, and also provides a curing agent composition which comprises a hydrolyzable silyl group-containing compound (a), a non-phthalic acid ester based plasticizer (b) having no phthalic acid ester structure in its molecule, and a bivalent tin based curing catalyst (c), that satisfies all of mechanical properties, recoverability and adhesiveness to substrate, can be mixed easily when used and has excellent storage stability, and a two-pack type curable composition which hardens when a base resin composition comprising a curable organic polymer (d) having in its molecule a functional group crosslinkable by a reaction catalyzed by a bivalent tin based curing catalyst (c), an epoxy group-containing silane compound (f) and an epoxy compound (g) is mixed with the above curing agent composition.

Abstract: An organopolysiloxane composition is provided including: (A) an organopolysiloxane with hydroxyl groups at both terminals of the molecular chain; (B) an organosilicon compound represented by the general formula shown below: wherein, R2 represents a hydrogen atom, a phenyl group or a halogenated phenyl group, R3 represents a hydrogen atom or a methyl group, R4 represents a monovalent hydrocarbon group, X represents a hydrolysable group, Z1 represents —R5—, —R5O— or —R5(CH3)2SiO— (wherein R5 represents a bivalent hydrocarbon group), Z2 represents an oxygen atom or a bivalent hydrocarbon group, m represents 0, 1 or 2, and n represents 0, 1 or 2; (C) a condensation curing catalyst; and (D) a photopolymerization initiator.

Abstract: The present invention relates generally to condensation cure moldmaking compositions that produce useful, curable molds and/or coatings that can be sprayed, trowled or poured, and to a method of making said molds. More particularly, the present invention relates to the use of hindered amine siloxanes to create a desirable thixotropy and cure rate in said moldmaking applications as compared to current technologies.

Abstract: A curable resin composition comprising an oxyalkylene base copolymer having at least one silicone atom containing group to the silicone atom of which a hydroxyl group and/or hydrolyzable group is attached and which is cross-linked through formation of a siloxane bond.

Abstract: The present invention provides a moisture-curing one-pack urethane adhesive composition which has a good adhesive property to a painted steel. The moisture-curing one-pack urethane adhesive composition according to the present invention contains an isocyanate group-terminated urethane prepolymer as a main component, and also contains (1) a silane coupling agent as an adhesive promoter, and (2) (a) 2,2′-dimorpholinodiethyl ether and/or di(2,6-dimethylmorpholinoethyl)ether, and (b)dibutyltin diacetylacetonate, as curing catalysts. The moisture-curing one-pack urethane adhesive composition according to the present invention is particularly suitable for bonding automotive window glasses to automotive bodies.

Abstract: This invention relates to silane functional adhesive composition and to a method of bonding a window to a painted substrate using the adhesive without the need for a primer for the painted substrate. In one embodiment, the invention is a method of bonding glass to a painted substrate, such as a window in a vehicle. The process comprises applying to the glass or the unprimed painted substrate an adhesive as described herein; contacting the glass with the unprimed painted substrate wherein the adhesive is located between the window and the substrate; and allowing the adhesive to cure.

Abstract: The object of the present invention is to provide a novel acrylic-modified silyl-terminated polyether resin composition which is advantageous not only in terms of the availability of raw materials and the ease of synthetic reaction, but also in fast-curing, good storage stability, good weatherability, high adhesiveness, thus promising high potentials of industrial utilization. Further, the object of the present invention is also to develop an environment-friendly curable composition which is a major social consideration. The composition is a curable composition comprising an oxyalkylene polymer (A) containing silyl functional group capable of crosslinking by forming a siloxane bond and a copolymer (B) having a molecular chain comprising alkyl acrylate and/or alkyl methacrylate monomer units and containing silyl functional group capable of crosslinking by forming a siloxane bond, said copolymer (B) having both dialkoxysilyl and trialkoxysilyl groups as said silyl functional group.

Abstract: Elastomer-modified Epoxy-polysiloxane compositions of this invention are prepared by combining a silicone intermediate, with an epoxy resin, an elastomeric resinous intermediate, a polyfunctional amine, an optional organometallic catalyst, and optional fillers, pigments, and processing agents. The composition is prepared using a sufficient amount of water to promote hydrolysis of the polysiloxane and the polycondensation of the silanols produced by such hydrolysis. In its cured form, the epoxy-polysiloxane composition exists as a uniformly dispersed arrangement of linear epoxy chain fragments that are cross-linked with a continuous polysiloxane polymer chain, wherein either or both of the epoxy and/or polysiloxane polymers are elastomer modified to provide coatings and floorings having significantly improved properties of impact resistance, flexibility, crack resistance, and abrasion resistance with compared to conventional epoxy systems.

Abstract: Described is the use of nanoscale metal oxide particles as catalysts for the thermal and/or photochemical polymerization of species having at least one polymerizable carbon-carbon multiple bond and/or at least one carbon containing ring capable of undergoing a ring opening polymerization.

Abstract: In one embodiment the invention is An adhesive composition comprising a) a polymer having a flexible backbone and a reactive moiety capable of cross-linking, b) a particle comprising an active agent encapsulated in an encapsulating agent wherein the active agent comprises a catalyst for cross-linking of the reactive moiety, a curing agent for the reactive moiety, an accelerator for the curing reaction or a mixture thereof; and the encapsulating agent comprises a side chain crystallizable polymer wherein the active agent is not substantially extractable from the particle at ambient conditions in a first extraction after particle formation.

Abstract: The present invention provides for an etch and mar resistant low VOC clear coating composition most suitable for use as a top clear coat in multi-layered OEM or refinish automative coatings. The coating composition includes isocyanate, silane and melamine components. The isocyanate component includes an aliphatic polyisocyanate. The composition may be formulated as a two-pack or one-pack coating composition, wherein the isocyanante functionalities are blocked with a blocker such as a mono-alcohol.

Abstract: A polyorganosiloxane compound obtained by allowing a polyorganosiloxane having silicone resin structure to react with a polyorganosiloxane having silicone oil structure in the presence of a hydrosilylation catalyst, and having the both structures in the molecule. Also disclosed is a coating composition including the polyorganosiloxane compound, a silane or silicone resin having an RO—Si group, and a curing catalyst. The former polyorganosiloxane compound is compatible with silicone resins. The latter coating composition can provide coatings improved in flexibility without lowering the curability, surface hardness and weatherability inherent in silicone resins.

Abstract: Disclosed herein is a composition comprising: A) a moisture curable polymer selected from the group consisting of silylated polyurethanes, silylated polyethers, and mixtures thereof, and B) a silicone oligomer of the formula: [R3SiO1/2]m[O1/2Si(R)2O1/2]n[SiO3/2R]o[SiO4/2]p  (I) wherein: each R is independently selected from the group consisting of B, R1, —OR2, R3, and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by a Si—C bond; each R1 is independently a saturated or aromatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1 or an acyl group; each R3 is independently a monovalent organic group containing an aliphatic unsaturated hydrocarbon group; each R4 is a monovalent organic group linked to the Si atom of the siloxane oligomer backbone by a Si—C bond that does not include an aliphatic unsaturated hydrocarbon group and that has there

Abstract: This invention provides a curable composition capable of giving cured products drastically improved in resilience. This composition includes (A) an oxypropylene polymer having at least one silicon atom-containing group with a hydroxyl group or a hydrolyzable group bound to the silicon atom and having an Mw/Mn ratio of not more than 1.6 and a number average molecular weight of not less than 6,000, (B) an organic carboxylic acid salt of divalent tin and (C) an organic amine compound.

Abstract: A nonsagging and extrudable room temperature curable silicone rubber composition with excellent adherence to a variety of substrates comprising (A) diorganopolysiloxane having silicon-bonded alkoxy in molecular chain terminal position, (B) surface-hydrophobicized dry method silica, (C) non-surface-hydrophobicized dry method silica, (D) alkoxysilane, (E) an organotitanium compound, and (F) light stabilizer and/or UV absorber.

Abstract: A one part moisture curable room temperature vulcanizable silicone composition comprising an alkylalkoxyacyloxysilane selected from the group consisting of

Abstract: Room temperature vulcanizable silicone rubber compositions comprising: hydroxyl endblocked polyorganosiloxane, at least one phenyl-substituted tris-functional ketoximino silane and an aminofunctional silane adhesion promoter characterized as having less than three hydrolyzable alkoxy groups attached to the silicon are provided.

Abstract: A stain-proofing agent comprising a compound represented by the formula (1): and non-aqueous composition for paints comprising the stain-proofing agent, resin, curing agent and/or curing catalyst and being capable of forming a coating film remarkably excellent in stain-proofing property.

Abstract: Symmetric and asymmetric cyclic silalkylenesiloxane monomers and copolymers thereof, as well as crosslinked and/or reinforced silalkylenesiloxane copolymers, medical devices containing such materials, and methods of preparation.

Abstract: A silicone composition for preparing a silicone adhesive, the composition prepared by mixing (A) an organopolysiloxane containing an average of at least two silicon-bonded hydroxy groups per molecule; (B) a crosslinking agent in an amount sufficient to cure the composition; wherein the agent is selected from (i) at least one silane having the formula R2nSiX4−n wherein each R2 is independently selected from monovalent hydrocarbon and monovalent halogenated hydrocarbon groups having from 1 to about 8 carbon atoms, n is 0 or 1, and X is —OR2 or —OCH2CH2OR2; (ii) a partial hydrolyzate of (i), and (iii) mixtures comprising (i) and (ii); (C) an electrically conductive filler in an amount sufficient to impart electrical conductivity to the silicone adhesive, wherein the filler comprises particles having at least an outer surface of a metal selected from the group consisting of silver, gold, platinum, palladium, and alloys thereof; (D) an effective amount of a hydroxy-functional organic compound hav

Abstract: An oligomer of the formula: [R3SiO½]m[O½Si(R2)O½]n[SiO{fraction (3/2)}R]o[SiO{fraction (4/2)}]p  (I) wherein each R is selected individually from the group consisting of R1, —OR2 and —OR3; each R1 is independently a substituted or unsubstituted hydrocarbon group; each R2 is a C1-C6 alkyl group or an acyl group; and each R3 is a independently an alkyl or alkenyl group having at least 8 carbon atoms; with the provisos that if R3 is alkenyl, there is no unsaturation within two carbon atoms adjacent to the oxygen atom of the —OR3 group; at least one R group is —OR3; at least one quarter of all R groups are —OR2 or —OR3; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10. The oligomer is a useful component of in insulation formulations for wire and cable used in underground locations.

Abstract: A fluorosilicone crosslinker and method for making is provided. Reaction is effected between a silanol terminated polyfluoroalkyl silicone fluid and a polyalkoxysilane in the presence of a Platinum Group Metal catalyst. The fluorosilicone crosslinker can be used in combination with a silanol terminated fluoroalkyl substituted polydiorganosiloxane to formulate a neutral, condensation curable, solvent resistant sealant.

Abstract: Among other things, a silicone composition curing by condensation at room temperature is prepared from a base dough containing filler and polyorganosiloxane having hydroxy groups, as well as from an activator component containing crosslinker and a catalyst of an organometallic compound, which is characterized in that the activator component additionally contains a polyether having at most one alkoxysilyl group and/or a polyaddition product based on polyether and having at most one alkoxysilyl group.

Abstract: The present invention has its object to provide a curable composition insuring a reduced stress without sacrificing restoring force and other physical properties and having a sufficient degree of adhesiveness. The present invention is related to a curable composition comprising comprising an oxyalkylene polymer having at least one reactive silicon group per molecule (A-1), an acid (B), an amine (C), and a tin-series curing catalyst (D). This composition optionally contains a vinyl polymer having at least one reactive silicon group.

Abstract: A silicone composition prepared by mixing (A) 100 parts by weight of an organopolysiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, (B) an organohydrogenpolysiloxane containing an average of at least two silicon-bonded hydrogen atoms per molecule in a concentration sufficient to cure the composition, (C) 0.5 to 50 parts by weight of a hydroxy-functional organic compound having a molecular weight up to about 1000 and containing at least one hydroxy group and at least one aliphatic carbon-carbon multiple bond per molecule, (D) 1 to 10 parts by weight of a titanium chelate, and (E) a catalytic amount of a hydrosilylation catalyst; and a cured product formed from the composition.

Abstract: A fluorosilicone crosslinker and method for making is provided. Reaction is effected between a silanol terminated polyfluoroalkyl silicone fluid and a polyalkoxysilane in the presence of a Platinum Group Metal catalyst. The fluorosilicone crosslinker can be used in combination with a silanol terminated fluoroalkyl substituted polydiorganosiloxane to formulate a neutral, condensation curable, solvent resistant sealant.

Abstract: A tracking resistant electrical insulating material or article suitable for medium to high voltage applications comprising a silane-modified polyolefin, and a heat-shrinkable article prepared therefrom. Said material or article is preferably prepared by a process comprising: (a) reacting polyolefin with a silane in the presence of a free-radical initiator to form a silane-grafted polyolefin, or copolymerising a polyolefin with silane; (b) preparing a mixture of one or more silane-modified polyolefins prepared in (a) with optionally one or more non silane-modified polyolefins, antitrack ingredients, and a silanol condensation catalyst; (c) forming the insulating material or article by melt extruding or moulding said mixture; and (d) crosslinking the insulating material or article by exposing it to moisture, preferably at elevated temperature.

Abstract: An organopolysiloxane composition is provided including: (A) an organopolysiloxane with hydroxyl groups at both terminals of the molecular chain; (B) an organosilicon compound represented by the general formula shown below: 1

Abstract: A moisture-crosslinkable polyolefin material, comprising a silane-grafted polyolefin blend, and coatings or insulations, including heat-shrinkable coatings and insulations, prepared therefrom. The coating material is formed by a process comprising: (a) reacting a pre-blended mixture of polyolefin and polypropylene, or higher polyolefin, resins and optional compatibilizing agent, with an appropriate silane and silane-grafting initiator to produce a silane-modified polyolefin blend composition; (b) forming the coating or insulating material by melt processing the composition produced in step (a) with a silanol condensation catalyst; and (c) crosslinking the formed coating or insulating material by exposing it to moisture, preferably at an elevated temperature.

Abstract: A primer composition showing good adhesion to the surface of a substrate, such as a glass substrate, and excellent in weather resistance and water resistance as well as a method of effecting adhesion is provided. The primer composition is characterized by comprising a saturated hydrocarbon polymer having at least one silicon-containing group which has hydroxyl or hydrolyzable group bound to the silicon atom and capable of crosslinking under formation of a siloxane bond.

Abstract: The present invention relates to dual curing silicone compositions which are capable of cross-linking when subjected to ultraviolet (“UV”) or visible (“VIS”) light and/or by a moisture condensation method. When cured, these compositions have excellent adhesion to a variety of substrates. These are particularly useful in potting and coating applications.

Abstract: Condensation curable poly(fluoroorgano)siloxane-poly(silarylene)siloxane block copolymer compositions having a glass transition temperature not exceeding about −54° C. and excellent solvent resistance have been found useful as sealants. Polyalkoxysilylorgano compounds, such as 1,4-bis[trimethoxysilyl(ethyl)]benzene have been found to be effective as cross-linkers.

Abstract: The present invention has its object to provide a curable composition showing a controlled initial curing rate and, hence, offering good workability by introducing a methyl group into the neighborhood of the reactive silicon group within an oligomer to indirectly lower the reactivity of the reactive silicon group within the oligomer.