Ethylenically Unsaturated Reactant Patents (Class 528/205)
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Patent number: 6518390Abstract: A precursor of a polybenzoxazole resin which comprises a crosslinking group in a molecule and has a specific structure, a polybenzoxazole resin obtained from the precursor by the condensation reaction and the crosslinking reaction, an insulating film comprising the polybenzoxazole resin and a semiconductor device comprising an insulating interlayer film in multi-layer wiring or a film for protecting surfaces which comprises the above insulating film. The precursor exhibits excellent processability due to excellent solubility in solvents and, after the ring closure, excellent heat stability in applications. The resin exhibits excellent electric, physical and mechanical properties and is advantageously used for insulating interlayer films of semiconductor devices and the like applications.Type: GrantFiled: March 28, 2001Date of Patent: February 11, 2003Assignee: Sumitomo Bakelite Company, Ltd.Inventors: Masako Okanuma, Tatsuhiro Yoshida, Hidenori Saito, Nobuhiro Higashida, Masanori Fujimoto, Tadahiro Ishikawa
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Patent number: 6511786Abstract: A pattern formation material of this invention contains a polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 2, and an acid generator: wherein R1 and R2 are the same or different and selected from the group consisting of an alkyl group, a chlorine atom and an alkyl group including a chlorine atom; R3, R4, R5 and R6 are a hydrogen atom or a fluorine atom, at least one of which is a fluorine atom; and R7 is a protecting group released by an acid.Type: GrantFiled: August 8, 2001Date of Patent: January 28, 2003Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Shinji Kishimura, Masayuki Endo, Masaru Sasago, Masamitsu Shirai, Masahiro Tsunooka
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Patent number: 6469123Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.Type: GrantFiled: July 19, 2000Date of Patent: October 22, 2002Assignee: Honeywell International Inc.Inventors: Kreisler S. Lau, Feng Quan Liu, Boris A. Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
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Patent number: 6465567Abstract: The invention relates to pigment preparation having (a) at least one organic pigment, (b) at least one optionally ionically modified phenol-styrene polyglycol ether, and (c) at least one surface-active agent that is (i) an oxalkylated acetylene glycol of formula (I) wherein n is 0 to 14, m is 0 to 14, and m+n is 0 to 14, and/or (ii) compounds having the formulas (II), (III), and (IV) wherein R is C6-C18-alkyl. R1 independently denotes H or C1-C4-alkyl, p is from 3 to 60, R2 is R or optionally C1-C18-alkyl-substituted phenyl, X is —SO3−, —SO2−, —PO3═, or —CO—(R3)—COO−; R3 is a divalent aliphatic or aromatic radical, and Kat is a cation.Type: GrantFiled: May 15, 2000Date of Patent: October 15, 2002Assignee: Bayer AkgiengesellschaftInventors: Michael Grobe, Peter-Roger Nyssen, Michael Krause, Karina Kutschkau, Dirk Pfützenreuter
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Patent number: 6423811Abstract: A low dielectric constant material has a polymeric network that is fabricated from a first and a second component. The first component comprises a polymeric strand, and the second component comprises a molecule having a central portion with at least three arms extending from the central portion, wherein each of the arms includes a backbone with a reactive group. The first component and the second component form the polymeric network in a reaction that involves at least one of the reactive groups when the first and second components are thermally activated. Contemplated low dielectric constant materials are advantageously employed in the fabrication of electronic devices, and particularly contemplated devices include integrated circuits.Type: GrantFiled: July 19, 2000Date of Patent: July 23, 2002Assignee: Honeywell International Inc.Inventors: Kreisler S. Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
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Patent number: 6417274Abstract: The invention relates to a novel process for preparing functionalized PPE, the process comprising oxidative coupling in a reaction solution at least one monovalent phenol species using an oxygen containing gas and a complex metal catalyst to produce a PPE; and functionalizing the PPE prior to and/or during at least one isolation step for devolatilization of the reaction solvent. The invention also relates to the polyphenylene ether resin made by the process as well as blends and articles containing the polyphenylene ether resin made by the process.Type: GrantFiled: February 5, 1999Date of Patent: July 9, 2002Assignee: General Electric Co.Inventors: Adrianus J. F. M. Braat, Rene de Jongh, Juraj Liska
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Publication number: 20020077447Abstract: The present invention provides a curable polyphenylene ether (PPE) resin, a composition made therefrom, and a process for preparing the resin. The process involves introducing a vinyl group-containing functional group to the terminal end of PPE by modifying the hydroxy and ester groups on the terminal end. Thus, a curable thermosetting PPE resin including a vinyl group on the terminal end can be obtained. Since the dehydrogenation of side chain methyl using n-BuLi is not conducted in the process of the present invention, the process is much easier, and the cost can be decreased.Type: ApplicationFiled: May 3, 2001Publication date: June 20, 2002Applicant: Industrial Technology Research InstituteInventors: Gue-Wuu Hwang, Chien-Ting Lin, Chingchen S. Chiu
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Patent number: 6407150Abstract: A process for producing phenol resin having good color tone, which process comprises reacting hydroxyl group-containing aromatic compound and unsaturated cyclic hydrocarbon under the condition that the moisture is 100 ppm or less and the concentration of Friedel-Crafts catalyst is 0.07 mass % or less in a reaction system and a process for producing epoxy resin having good color tone, which process comprises reacting the obtained phenol resin and epihalohydrin in the presence of base catalyst, removing remaining catalyst and further removing unreacted epihalohydrin.Type: GrantFiled: August 10, 2000Date of Patent: June 18, 2002Assignee: Nippon Petrochemicals Company, LimitedInventors: Satoshi Mori, Fumiaki Oshimi, Masato Hattori
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Patent number: 6399224Abstract: Conjugated polymers and copolymers with strong luminescent properties and balanced charge transporting/injection properties are disclosed. Methods of manufacturing such polymers and copolymers and optoelectronic devices fabricated with such polymers and copolymers are disclosed. A conjugated luminescent polymer with tunable charge transport is prepared according to the following polymerization reaction: mM1+nM2→(M1)m(M2)n wherein M1 is a monomer having at least two reactive functional groups and at least one chemically bonded charge transporting chromophore group possessing electron-withdrawing character and M2 is a monomer having at least two reactive functional groups and at least one chemically bonded charge transporting chromophore group possessing electron-donating character, wherein m and n are stoichiometric quantities of the monomers M1 and M2, respectively, wherein m and n are varied to tune the charge transport property of the conjugated luminescent polymer.Type: GrantFiled: February 29, 2000Date of Patent: June 4, 2002Assignee: Canon Kabushiki KaishaInventor: Xiao-Chang Charles Li
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Patent number: 6383665Abstract: The invention relates to poly(phenylene vinylene) polymers substituted with dendritic sidechains to enhance main-chain separation in the solid state. The polymers are synthesized by the Heck polymerization and have a weight-average molecular weight of 20,000 to 60,000 Daltons. The polymers are self-ordering in the solid state and have thermotropic liquid crystalline phases. The polymers show enhanced photoconductivity, better charge transport capability and improved polarized light emission.Type: GrantFiled: August 19, 1999Date of Patent: May 7, 2002Assignee: Lucent Technologies Inc.Inventors: Zhenan Bao, Karl R. Amundson, Xiaochen Linda Chen
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Patent number: 6352782Abstract: A capped poly(phenylene ether) resin composition is formed from (1) a poly(phenylene ether) compound (PPE) in which at least a portion, preferably substantially all of the hydroxyl groups have been reacted with a compound containing ethylenic unsaturation (carbon-carbon double bonds) which is further reactive with unsaturated monomers (reactively endcapped PPE) and (2) a curable unsaturated monomer composition. The composition optionally contains a polymerization catalyst; a flame-retardant compound; and fibrous reinforcement. The composition can be cured to form a laminate, and clad with copper to form a circuit board.Type: GrantFiled: December 1, 1999Date of Patent: March 5, 2002Assignee: General Electric CompanyInventors: Gary W. Yeager, Robert E. Colborn
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Publication number: 20020022708Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.Type: ApplicationFiled: July 5, 2001Publication date: February 21, 2002Applicant: Honeywell International Inc.Inventors: Kreisler Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
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Patent number: 6310030Abstract: Provided are an unsaturated carboxylic acid polymer having a degree of calcium-sequestering ability of at least 150 mg CaCO3/g, a degree of 28-day biodegradability of at least 40%, and a number-average molecular weight of from 500 to 1,000,000; a process for producing the unsaturated carboxylic acid polymer by copolymerizing an unsaturated carboxylic acid or its salt with a quinone in the presence of a polymerization initiator; a builder comprising the polymer; a detergent composition comprising the builder and a surfactant; and a dispersant comprising the polymer. The polymer has good calcium ion-sequestering ability and good biodegradability, and is highly useful as a material for builders.Type: GrantFiled: September 7, 2000Date of Patent: October 30, 2001Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Shigeru Matsuo, Yoshikatsu Seino
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Patent number: 6291077Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.Type: GrantFiled: August 28, 2000Date of Patent: September 18, 2001Assignee: Georgia-Pacific Resins, Inc.Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
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Patent number: 6291723Abstract: A catalyst composition comprising trifluoromethanesulfonic acid (also referred to as triflic acid) and a sufficient quantity of a substance (also referred to as a retarder) to decrease but not eliminate the catalytic activity of the acid is disclosed. Also disclosed, is a method and composition for condensing a hydroxyaryl with a diene by use of the catalyst composition. The method is capable of producing condensates having: a mole ratio of 1 mole of the diene to one mole of the hydroxyaryl; one mole of diene to two moles of the hydroxyaryl as well as higher molecular weight products such as resins by changes in temperature, time of reaction, type and quantity of retarder and other variables.Type: GrantFiled: September 2, 1999Date of Patent: September 18, 2001Assignee: Borden Chemical, Inc.Inventor: Arthur H. Gerber
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Patent number: 6288206Abstract: Chiral organic polymers doped with or appended by nonlinear optical dyes are disclosed. The use of chiral polymers produces a more stable noncentrosymmetric environment for the dye molecules resulting in unexpectedly long relaxation times as compared with previously used organic polymers. In addition, the NLO/chiral polymer materials exhibit high electro-optical coefficients (r33), high nonlinear optical coefficients (d33), improved long-term thermal stability, and at the same time retain the processing advantages associated with organic polymers. Thus, the present NLO/chiral polymer materials are extremely well-suited for use in second-order nonlinear optical and optoelectronics devices.Type: GrantFiled: November 2, 1999Date of Patent: September 11, 2001Assignee: Molecular OptoElectronics CorporationInventors: Kevin R. Stewart, Janet L. Gordon, Kwok Pong Chan, David G. Gascoyne, Feng Pan
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Patent number: 6284863Abstract: A polymer having an O-substituted vinylphenol unit represented by the following formula (I) wherein R1, R2 and R3 represent an alkyl; or R1 and R2, R1 and R3 or R2 and R3 are bound together and respectively form an alkylene; or R2 is methylidyne wherein one bond in the methylidyne is bound to R1, the other bond is bound to R3, and R1 and R3 represent alkylene, and a resist composition comprising the polymer are provided.Type: GrantFiled: April 28, 2000Date of Patent: September 4, 2001Assignee: Sumitomo Chemical Company, Ltd.Inventors: Yoshiteru Ohta, Sang-tae Kim, Masumi Suetsugu
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Patent number: 6284868Abstract: In functionalized linear alternating carbon monoxide copolymers of carbon monoxide and at least one 1-alkene (A), compound (A) is an aryl derivative substituted with at least one terminal allyl and/or homoallyl moiety and containing one or more polar groups, with the proviso that 4-allylanisole is excluded.Type: GrantFiled: December 13, 1999Date of Patent: September 4, 2001Assignee: BASF AktiengesellschaftInventors: Michael Geprägs, Joachim Queisser, Bernhard Rieger, Roland Wursche
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Patent number: 6273543Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with water-solubility- or water-dispersability-imparting substituents and at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula wherein x is an integer of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units. In one embodiment, a single functional group imparts both photosensitivity and water solubility or dispersability to the polymer. In another embodiment, a first functional group imparts photosensitivity to the polymer and a second functional group imparts water solubility or dispersability to the polymer.Type: GrantFiled: February 9, 1999Date of Patent: August 14, 2001Assignee: Xerox CorporationInventors: Ram S. Narang, Timothy J. Fuller
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Patent number: 6265490Abstract: The invention relates to novolac resins obtained by condensation (A) of an aromatic compound containing at least two hydroxyl groups and (B) of an unconjugated diene in an (A)/(B) molar ratio of between 0.7 and 1.75 in the presence of an acidic catalyst, which are characterized in that the content of free aromatic compound is lower than 5% by weight. Also disclosed are a process for the preparation of the resins, and rubber-based compositions including from 0.5 to 20 parts by weight of the above mentioned novolac resins per 100 parts by weight of rubber. The invention also relates to the use of the resins or rubber-based compositions in the field of vulcanization, especially of tires and of conveyor belts.Type: GrantFiled: March 28, 1997Date of Patent: July 24, 2001Assignee: Ceca, S.A.Inventors: Christophe Morel-Fourrier, Thierry Dreyfus, Messaoud Bekhiekh, Bonnie L. Stuck
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Patent number: 6191317Abstract: Polyalkyl hydroxyaromatics may be prepared from polyalkylenes and hydroxyaromatics in the presence of an acid catalyst and an organic solvent having a boiling point range with an initial boiling point value of below or about the boiling point of the selected hydroxyaromatic reactants and final boiling point of above or equal to about the boiling point of alkylhydroxyaromatic by-product of the reaction. Using this method, accumulation of undesirable alkylhydroxyaromatic by-product/s in a reaction vessel may be minimized, and/or viscosity of polyalkyl hydroxyaromatic product reduced, allowing for increased ease of transfer and transportation.Type: GrantFiled: August 31, 1999Date of Patent: February 20, 2001Assignee: Huntsman Petrochemical CorporationInventor: Wei-Yang Su
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Patent number: 6172181Abstract: A (2,3,4,5,6-pentafluorobenzoyl)diphenyl ether compound represented by the formula (I): wherein R stands for a hydroxyl group or a group represented by ether ketone polymer represented by the formula (II): wherein n stands for a degree of polymerization, m is an integer of 0 or 1, and R1 stands for a group represented by the formula (III): wherein p is an integer 0 or 1 and R2 stands forType: GrantFiled: July 16, 1999Date of Patent: January 9, 2001Assignee: Nippon Shokubai Co., Ltd.Inventors: Kunio Kimura, Yuhiko Yamashita, Patrick E. Cassidy, John W. Fitch, III, V. Sreenivasulu Reddy
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Patent number: 6166151Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.Type: GrantFiled: June 22, 1999Date of Patent: December 26, 2000Assignee: Georgia-Pacific Resins, Inc.Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
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Patent number: 6160083Abstract: The specification discloses a method for making low softening point modified terpene-phenol resins having improved properties. In the process, phenol is reacted in an organic solvent containing a Lewis acid catalyst with an acyclic mono-unsaturated olefin and terpene under reaction conditions sufficient to produce an alkyl-modified terpene-phenol resin at a relatively high yield having a softening point in the range of from about 70.degree. to about 110.degree. C., a Gardner color below about 6 and a polydispersity index below about 1.5. Due to its relatively low Gardner color number, the resin may be used substantially as produced avoiding additional decoloration steps which result in reduced product yield and increased cost. The product contains less volatile components and has improved compatibility with A-B and A-B-A copolymers as compared with many conventional modified terpene-phenol resins.Type: GrantFiled: May 19, 1998Date of Patent: December 12, 2000Assignee: Arizona Chemical CompanyInventors: Kerry L. Thompson, Abhay K. Deshpande
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Patent number: 6153721Abstract: Novel polyindanebisphenols or PIBPs for the preparation of new and improved thermosetting polymers having the general formula of ##STR1## are provided. Also disclosed are thermoplastic or thermoset compositions prepared using the novel compounds of the invention, as well as methods of making and using the same. When copolymerized or reactive with other commercial resins such as, e.g., epoxy compounds, PIBP based polymers are characterized by high glass transition temperature ("Tg"), low dielectric constant, low moisture absorption, low coefficient of expansion, low cost, and can be processed on equipment typically used for the production of epoxy based laminates.Type: GrantFiled: February 26, 1998Date of Patent: November 28, 2000Assignee: Honeywell International Inc.Inventors: Thomas F. McCarthy, David B. Schwind, Gordon C. Smith
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Patent number: 6127491Abstract: Phenolic resin polyols are disclosed. The polyols, which contain aliphatic or mixed phenolic and aliphatic hydroxyl groups, are the reaction products of aralkylated phenols or phenol aralkylation polymers with an oxyalkylating agent selected from alkylene oxides and alkylene carbonates. The phenolic resin polyols are versatile intermediates for many polymer systems, including urethanes, epoxies, alkyds, acrylates, and polyesters.Type: GrantFiled: November 27, 1995Date of Patent: October 3, 2000Assignee: Gerorgia-Pacific Resins, Inc.Inventors: David C. Dehm, David A. Hutchings, Alan K. Randall, Mark A. Peters
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Patent number: 6127511Abstract: A preparation process of phenol aralkyl resin from phenol compound and aralkyl compound by controlling the temperature of reaction mass in the range of 70 to 240.degree. C. and simultaneously controlling the temperature of vapor phase potion and vapor-liquid interface portion of manufacturing equipment so as to keep the wall surface of the vapor phase portion and vapor-liquid interface portion in a wet state. The invention can prevent scale adhesion to the interior of manufacturing equipment, remarkably reduce the number of washing and scale removing procedures on the manufacturing equipment, and enable efficient manufacture of phenol aralkyl resin. When the phenol aralkyl resin obtained is used for a molding material, molded articles having excellent heat resistance and high reliability can be provided.Type: GrantFiled: December 3, 1998Date of Patent: October 3, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Tomoyuki Kawabata, Yuzo Ono, Teruo Yuasa, Yukio Fukui
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Thermally reactive near infrared absorption polymer coatings, method of preparing and methods of use
Patent number: 6124425Abstract: Provided herein are novel polymeric coating materials for direct digital imaging by laser. More specifically the novel coating materials are thermally reactive near infrared absorption polymers designed for use with near infrared laser imaging devices. This invention further extends to the preparation and methods of use of the novel materials. The invention is particularly useful in the preparation of lithographic printing plates for computer-to-plate and digital-offset-press technologies. The invention extends to photoresist applications, to rapid prototyping of printed circuit boards and to chemical sensor development.Type: GrantFiled: March 18, 1999Date of Patent: September 26, 2000Assignee: American Dye Source, Inc.Inventor: My T. Nguyen -
Patent number: 6087414Abstract: Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3##Type: GrantFiled: December 23, 1998Date of Patent: July 11, 2000Assignee: Xerox CorporationInventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Crandall
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Patent number: 5945502Abstract: A polymer including mers of the formulas: ##STR1## and copolymers or mixtures thereof.Type: GrantFiled: November 13, 1997Date of Patent: August 31, 1999Assignee: Xerox CorporationInventors: Bing R. Hsieh, Yuan Yu
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Patent number: 5945500Abstract: Methods for preparing low free resorcinol resins are disclosed. These methods generally comprise reacting a resin with an aromatic olefinic compound; suitable resins include one or more resins selected from the group consisting of a dihydric phenol, a polyhydric phenol, a dihydric phenolic novolak resin and a polyhydric phenolic novolak resin; the addition product of at least one of these resins and at least one compound selected from the group consisting of a monooxirane compound and a polyoxirane compound; and a phenol or alkyl or aralkyl substituted mono- or dihydric phenol modified form of these resins. The resins produced by this method are also disclosed, as are rubber compositions utilizing the resin produced by this method.Type: GrantFiled: August 6, 1998Date of Patent: August 31, 1999Assignee: Indspec Chemical Corp.Inventors: Raj B. Durairaj, Alex Peterson, Jr.
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Patent number: 5936056Abstract: Methods for preparing low free resorcinol resins are disclosed. These methods generally comprise reacting a resin with an aromatic olefinic compound; suitable resins include one or more resins selected from the group consisting of a dihydric phenol, a polyhydric phenol, a dihydric phenolic novolak resin and a polyhydric phenolic novolak resin; the addition product of at least one of these resins and at least one compound selected from the group consisting of a monooxirane compound and a polyoxirane compound; and a phenol or alkyl or aralkyl substituted mono- or dihydric phenol modified form of these resins. The resins produced by this method are also disclosed, as are rubber compositions utilizing the resin produced by this method.Type: GrantFiled: March 7, 1997Date of Patent: August 10, 1999Assignee: Indspec Chemical CorporationInventors: Raj B. Durairaj, Alex Peterson, Jr.
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Patent number: 5889137Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.Type: GrantFiled: January 10, 1997Date of Patent: March 30, 1999Assignee: Georgia-Pacific Resins, Inc.Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
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Patent number: 5844063Abstract: The present invention relates to a resinous copolymer comprising monomer units of each of the groups of phenol compounds (I) and olefinically unsaturated non-acid terpene compounds (II), characterized in that the copolymer contains monomer units from the group of polyunsaturated olefin compounds (III), the monomer units of compound (III) being 1 to 70% by weight of the total of the monomer units of compounds (II) and (III), the monomer units of compounds (II) and (III) being at least 50% by weight of the total of monomer units of compounds (I), (II) and (III). The melting point of the copolymer is at least 130.degree. C. The copolymers are particularly useful in printing ink formulations.Type: GrantFiled: October 20, 1997Date of Patent: December 1, 1998Assignee: Arizona Chemical, S.A.Inventors: Jacques Salvetat, Ronald Wind
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Patent number: 5776374Abstract: The present invention relates to crosslinkable thermoplastic compositions comprising a plurality of crosslinkable moieties, capable of undergoing addition polymerization, incorporated by functionalization of the precursor poly(hydroxy ethers). The poly(hydroxy ethers) comprise recurring moieties derived from aromatic dihydroxy compounds. The crosslinkable polymeric compositions are crosslinked to obtain crosslinked thermoset polymeric compositions of the invention. The polymeric compositions of the inventions can be suitably used either as an active guiding layer, and/or as a NLO active upper and lower cladding layers in an electro-optic device. The polymeric compositions can also be used as non-NLO polymers for the upper and lower cladding layers, prior to orientation by the application of an electric field.Type: GrantFiled: November 7, 1995Date of Patent: July 7, 1998Assignee: The Dow Chemical CompanyInventors: Mark D. Newsham, Michael N. Mang, Robert J. Gulotty, Jr., Dennis W. Smith, Jr.
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Patent number: 5773552Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.Type: GrantFiled: January 3, 1997Date of Patent: June 30, 1998Assignee: Georgia-Pacific Resins Inc.Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
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Patent number: 5756642Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.Type: GrantFiled: January 3, 1997Date of Patent: May 26, 1998Assignee: Georgia-Pacific Resins, Inc.Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
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Patent number: 5744125Abstract: Disclosed are cosmetic melanins of different colors produced by procedures involving oxidative polymerization of monomeric precursors of melanin and/or co-monomers that enhance substantivity or adherence of the melanins to the skin and hair. Also disclosed are methods for preparing cosmetic melanins and methods for using these compositions topically to produce a natural-appearing tan and to prevent damage to skin caused by UV exposure.Type: GrantFiled: February 23, 1995Date of Patent: April 28, 1998Assignee: Yale UniversityInventors: John M. Pawelek, James T. Platt
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Patent number: 5739259Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin. In addition to the introduced to produce a product with particular properties.Type: GrantFiled: January 3, 1997Date of Patent: April 14, 1998Assignee: Georgia-Pacific Resins, Inc.Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
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Patent number: 5723566Abstract: The present invention relates to a resinous copolymer comprising monomer units of each of the groups of phenol compounds (I) and olefinically unsaturated non-acidic terpene compounds (II), characterized in that the copolymer contains monomer units from the group of polyunsaturated olefin compound (III), the monomer units of compound (III) being 1 to 70% by weight of the total of the monomer units of compounds (II) and (III), the monomer units of compounds (II) and (III) being at least 50% by weight of the total of the monomer units of compounds (I), (II) and (III). The melting point of the copolymer is at least 130.degree. C.The copolymers can be used in printink inks.Type: GrantFiled: August 10, 1995Date of Patent: March 3, 1998Assignee: Arizona Chemical S.A.Inventors: Jacques Salvetat, Ronald Wind
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Patent number: 5674970Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.Type: GrantFiled: July 12, 1995Date of Patent: October 7, 1997Assignee: Georgia-Pacific Resins, Inc.Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
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Patent number: 5670603Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electon donating group substituted to different phenyl rings of the fluorene moiety.Type: GrantFiled: March 8, 1993Date of Patent: September 23, 1997Assignee: AlliedSignal Inc.Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
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Patent number: 5589424Abstract: Applicants have discovered an improved photodefined dielectric materials comprising poly(aromatic diacetylenes). The preferred poly(aromatic diacetylenes) are copolymers of aromatic diacetylenes. Specific examples are 1) a copolymer of 4,4'-diethynyldiphenyl ether and m-diethynyl benzene and 2) a copolymer of 4,4'-diethynyldiphenyl ether and 4,4'-bis(3-ethynylphenoxy)-2,2',3,3',5,5',6,6'-octafluorobiphenyl. These copolymers can be photochemically crosslinked in patterns with exposure of 30 mJ/cm.sup.2 .mu.m and 60 mJ/cm.sup.2 .mu.m, respectively, and patterns have been produced in 10 .mu.m thick films with features as small as 12 .mu.m.Type: GrantFiled: October 17, 1995Date of Patent: December 31, 1996Assignee: Lucent Technologies Inc.Inventors: Elizabeth W. Kwock, Timothy M. Miller
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Patent number: 5589565Abstract: A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.Type: GrantFiled: March 8, 1993Date of Patent: December 31, 1996Assignee: The Regents of the University of CaliforniaInventors: Fred Wudl, Alan Heeger
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Patent number: 5552503Abstract: Applicants have discovered an improved photodefined dielectric materials comprising poly(aromatic diacetylenes). The preferred poly(aromatic diacetylenes) are copolymers of aromatic diacetylenes. Specific examples are 1) a copolymer of 4,4'-diethynyldiphenyl ether and m-diethynyl benzene and 2) a copolymer of 4,4'-diethynyldiphenyl ether and 4,4'-bis(3-ethynylphenoxy)-2,2',3,3',5,5',6,6'-octaflurorbiphenyl. These copolymers can be photochemically crosslinked in patterns with exposure of 30 mJ/cm.sup.2 .mu.m and 60 mJ/cm.sup.2 .mu.m, respectively, and patterns have been produced in 10 .mu.m thick films with features as small as 12 .mu.m.Type: GrantFiled: December 22, 1993Date of Patent: September 3, 1996Assignee: AT&T Corp.Inventors: Elizabeth W. Kwock, Timothy M. Miller
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Patent number: 5548059Abstract: Unsaturated linear polymers have repeating units of a reaction product of a first monomer, a second monomer, a third monomer and optionally a fourth monomer. The linear polymers have a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C. The first monomer should have a weight average molecular weight less than 200. The second monomer may be a dicarboxylic acid or diester which is different than the third monomer. A concentration of second residues of the polymer, derived from the second monomer, ranges from about 3 wt. % to about 15 wt. %, based on the total weight of the polymer. The third monomer is an aromatic dicarboxylic acid or an ester thereof. In the polymer, a concentration of third residues, derived from the third monomer, ranges from about 40 wt. % to about 55 wt. %, based on the total weight of the polymer. The fourth monomer is a diol having a higher molecular weight than the first monomer.Type: GrantFiled: January 3, 1995Date of Patent: August 20, 1996Assignee: Xerox CorporationInventors: Robert D. Bayley, Carol A. Fox, Thomas R. Hoffend, Hadi K. Mahabadi, Enno E. Agur, Guerino Sacripante, Michael S. Hawkins
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Patent number: 5527876Abstract: The invention relates to a process for the production of plastics containing amide groups with elimination of CO.sub.2 by reaction of polyfunctional isocyanates, carboxylic acids and, optionally, alcohols in the presence of tertiary amines, more particularly heteroaromatic amines. The heteroaromatic amines preferably contain another heteroatom and/or substituents having +I and/or +M effects. The reaction preferably starts at room temperature. Fine-cell foams having an acid value of less than 40 and a density of at most 150 g/l can be produced in short reaction times at room temperature without any need for additional blowing agents.Type: GrantFiled: July 29, 1994Date of Patent: June 18, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hermann Kluth, Peter Daute, Johann Klein, Roland Gruetzmacher, Wolfgang Klauck
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Patent number: 5525686Abstract: A process for preparing a polyvalent metal salt of a salicylic acid resin which comprises the steps of reacting salicylic acid or its derivative with styrene or its derivative at a temperature of -20.degree. C. or higher but lower than 40.degree. C. in the presence of sulfuric acid, and then reacting the resulting reaction product with a polyvalent metal compound; an aqueous dispersion in which the polyvalent metal salt of the resin is dispersed in water; and a developing sheet in which the polyvalent metal salt of the salicylic acid resin is used.Type: GrantFiled: December 13, 1994Date of Patent: June 11, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Yoshimitsu Tanabe, Jotaro Kida, Kiyoharu Hasegawa, Masakatsu Nakatsuka, Masayuki Furuya, Takeshi Nishimura
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Patent number: 5494964Abstract: Polyester resins suitable as binders for electrophotographic toners and for acceptor layers for the thermal diffusion printing process based on hydroxyl-containing prepolymers of olefinically unsaturated monomers obtained by(1) polymerization of a mixture of(a) from 60 to 90% by weight of styrene or of a styrene derivative,(b) from 0 to 40% by weight of one or more C.sub.1 -C.sub.Type: GrantFiled: September 30, 1994Date of Patent: February 27, 1996Assignee: BASF AktiengesellschaftInventors: Georg Meichsner, Thomas Wuensch, Rainer Dyllick-Brenzinger
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Patent number: 5474854Abstract: The invention is a polyester composition containing crosslinked polymer particles with ester bonds at the main chain. The particles are excellent in affinity to polyesters, and so the films formed from the polyester compositions do not have the particles falling off during high speed running, and do not have flaws in the film surfaces. The invention can prevent the generation of white powder and the flaws of magnetic faces caused by falling-off particles, and prevent the contamination in the production of films, even though these are problems caused when various conventional particles are added, and is especially suitable for use as products such as magnetic films.Type: GrantFiled: August 9, 1994Date of Patent: December 12, 1995Assignee: Toray Industries, Inc.Inventors: Nobuyuki Kagami, Masatoshi Aoyama, Masaru Suzuki, Keisuke Oshima