Ethylenically Unsaturated Reactant Patents (Class 528/205)
  • Patent number: 6518390
    Abstract: A precursor of a polybenzoxazole resin which comprises a crosslinking group in a molecule and has a specific structure, a polybenzoxazole resin obtained from the precursor by the condensation reaction and the crosslinking reaction, an insulating film comprising the polybenzoxazole resin and a semiconductor device comprising an insulating interlayer film in multi-layer wiring or a film for protecting surfaces which comprises the above insulating film. The precursor exhibits excellent processability due to excellent solubility in solvents and, after the ring closure, excellent heat stability in applications. The resin exhibits excellent electric, physical and mechanical properties and is advantageously used for insulating interlayer films of semiconductor devices and the like applications.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: February 11, 2003
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Masako Okanuma, Tatsuhiro Yoshida, Hidenori Saito, Nobuhiro Higashida, Masanori Fujimoto, Tadahiro Ishikawa
  • Patent number: 6511786
    Abstract: A pattern formation material of this invention contains a polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 2, and an acid generator: wherein R1 and R2 are the same or different and selected from the group consisting of an alkyl group, a chlorine atom and an alkyl group including a chlorine atom; R3, R4, R5 and R6 are a hydrogen atom or a fluorine atom, at least one of which is a fluorine atom; and R7 is a protecting group released by an acid.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: January 28, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Shinji Kishimura, Masayuki Endo, Masaru Sasago, Masamitsu Shirai, Masahiro Tsunooka
  • Patent number: 6469123
    Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: October 22, 2002
    Assignee: Honeywell International Inc.
    Inventors: Kreisler S. Lau, Feng Quan Liu, Boris A. Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Patent number: 6465567
    Abstract: The invention relates to pigment preparation having (a) at least one organic pigment, (b) at least one optionally ionically modified phenol-styrene polyglycol ether, and (c) at least one surface-active agent that is (i) an oxalkylated acetylene glycol of formula (I)  wherein n is 0 to 14, m is 0 to 14, and m+n is 0 to 14, and/or (ii) compounds having the formulas (II), (III), and (IV)  wherein R is C6-C18-alkyl. R1 independently denotes H or C1-C4-alkyl, p is from 3 to 60, R2 is R or optionally C1-C18-alkyl-substituted phenyl, X is —SO3−, —SO2−, —PO3═, or —CO—(R3)—COO−; R3 is a divalent aliphatic or aromatic radical, and Kat is a cation.
    Type: Grant
    Filed: May 15, 2000
    Date of Patent: October 15, 2002
    Assignee: Bayer Akgiengesellschaft
    Inventors: Michael Grobe, Peter-Roger Nyssen, Michael Krause, Karina Kutschkau, Dirk Pfützenreuter
  • Patent number: 6423811
    Abstract: A low dielectric constant material has a polymeric network that is fabricated from a first and a second component. The first component comprises a polymeric strand, and the second component comprises a molecule having a central portion with at least three arms extending from the central portion, wherein each of the arms includes a backbone with a reactive group. The first component and the second component form the polymeric network in a reaction that involves at least one of the reactive groups when the first and second components are thermally activated. Contemplated low dielectric constant materials are advantageously employed in the fabrication of electronic devices, and particularly contemplated devices include integrated circuits.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: July 23, 2002
    Assignee: Honeywell International Inc.
    Inventors: Kreisler S. Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Patent number: 6417274
    Abstract: The invention relates to a novel process for preparing functionalized PPE, the process comprising oxidative coupling in a reaction solution at least one monovalent phenol species using an oxygen containing gas and a complex metal catalyst to produce a PPE; and functionalizing the PPE prior to and/or during at least one isolation step for devolatilization of the reaction solvent. The invention also relates to the polyphenylene ether resin made by the process as well as blends and articles containing the polyphenylene ether resin made by the process.
    Type: Grant
    Filed: February 5, 1999
    Date of Patent: July 9, 2002
    Assignee: General Electric Co.
    Inventors: Adrianus J. F. M. Braat, Rene de Jongh, Juraj Liska
  • Publication number: 20020077447
    Abstract: The present invention provides a curable polyphenylene ether (PPE) resin, a composition made therefrom, and a process for preparing the resin. The process involves introducing a vinyl group-containing functional group to the terminal end of PPE by modifying the hydroxy and ester groups on the terminal end. Thus, a curable thermosetting PPE resin including a vinyl group on the terminal end can be obtained. Since the dehydrogenation of side chain methyl using n-BuLi is not conducted in the process of the present invention, the process is much easier, and the cost can be decreased.
    Type: Application
    Filed: May 3, 2001
    Publication date: June 20, 2002
    Applicant: Industrial Technology Research Institute
    Inventors: Gue-Wuu Hwang, Chien-Ting Lin, Chingchen S. Chiu
  • Patent number: 6407150
    Abstract: A process for producing phenol resin having good color tone, which process comprises reacting hydroxyl group-containing aromatic compound and unsaturated cyclic hydrocarbon under the condition that the moisture is 100 ppm or less and the concentration of Friedel-Crafts catalyst is 0.07 mass % or less in a reaction system and a process for producing epoxy resin having good color tone, which process comprises reacting the obtained phenol resin and epihalohydrin in the presence of base catalyst, removing remaining catalyst and further removing unreacted epihalohydrin.
    Type: Grant
    Filed: August 10, 2000
    Date of Patent: June 18, 2002
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Satoshi Mori, Fumiaki Oshimi, Masato Hattori
  • Patent number: 6399224
    Abstract: Conjugated polymers and copolymers with strong luminescent properties and balanced charge transporting/injection properties are disclosed. Methods of manufacturing such polymers and copolymers and optoelectronic devices fabricated with such polymers and copolymers are disclosed. A conjugated luminescent polymer with tunable charge transport is prepared according to the following polymerization reaction: mM1+nM2→(M1)m(M2)n wherein M1 is a monomer having at least two reactive functional groups and at least one chemically bonded charge transporting chromophore group possessing electron-withdrawing character and M2 is a monomer having at least two reactive functional groups and at least one chemically bonded charge transporting chromophore group possessing electron-donating character, wherein m and n are stoichiometric quantities of the monomers M1 and M2, respectively, wherein m and n are varied to tune the charge transport property of the conjugated luminescent polymer.
    Type: Grant
    Filed: February 29, 2000
    Date of Patent: June 4, 2002
    Assignee: Canon Kabushiki Kaisha
    Inventor: Xiao-Chang Charles Li
  • Patent number: 6383665
    Abstract: The invention relates to poly(phenylene vinylene) polymers substituted with dendritic sidechains to enhance main-chain separation in the solid state. The polymers are synthesized by the Heck polymerization and have a weight-average molecular weight of 20,000 to 60,000 Daltons. The polymers are self-ordering in the solid state and have thermotropic liquid crystalline phases. The polymers show enhanced photoconductivity, better charge transport capability and improved polarized light emission.
    Type: Grant
    Filed: August 19, 1999
    Date of Patent: May 7, 2002
    Assignee: Lucent Technologies Inc.
    Inventors: Zhenan Bao, Karl R. Amundson, Xiaochen Linda Chen
  • Patent number: 6352782
    Abstract: A capped poly(phenylene ether) resin composition is formed from (1) a poly(phenylene ether) compound (PPE) in which at least a portion, preferably substantially all of the hydroxyl groups have been reacted with a compound containing ethylenic unsaturation (carbon-carbon double bonds) which is further reactive with unsaturated monomers (reactively endcapped PPE) and (2) a curable unsaturated monomer composition. The composition optionally contains a polymerization catalyst; a flame-retardant compound; and fibrous reinforcement. The composition can be cured to form a laminate, and clad with copper to form a circuit board.
    Type: Grant
    Filed: December 1, 1999
    Date of Patent: March 5, 2002
    Assignee: General Electric Company
    Inventors: Gary W. Yeager, Robert E. Colborn
  • Publication number: 20020022708
    Abstract: In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    Type: Application
    Filed: July 5, 2001
    Publication date: February 21, 2002
    Applicant: Honeywell International Inc.
    Inventors: Kreisler Lau, Feng Quan Liu, Boris Korolev, Emma Brouk, Ruslan Zherebin, David Nalewajek
  • Patent number: 6310030
    Abstract: Provided are an unsaturated carboxylic acid polymer having a degree of calcium-sequestering ability of at least 150 mg CaCO3/g, a degree of 28-day biodegradability of at least 40%, and a number-average molecular weight of from 500 to 1,000,000; a process for producing the unsaturated carboxylic acid polymer by copolymerizing an unsaturated carboxylic acid or its salt with a quinone in the presence of a polymerization initiator; a builder comprising the polymer; a detergent composition comprising the builder and a surfactant; and a dispersant comprising the polymer. The polymer has good calcium ion-sequestering ability and good biodegradability, and is highly useful as a material for builders.
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: October 30, 2001
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Shigeru Matsuo, Yoshikatsu Seino
  • Patent number: 6291077
    Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: September 18, 2001
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
  • Patent number: 6291723
    Abstract: A catalyst composition comprising trifluoromethanesulfonic acid (also referred to as triflic acid) and a sufficient quantity of a substance (also referred to as a retarder) to decrease but not eliminate the catalytic activity of the acid is disclosed. Also disclosed, is a method and composition for condensing a hydroxyaryl with a diene by use of the catalyst composition. The method is capable of producing condensates having: a mole ratio of 1 mole of the diene to one mole of the hydroxyaryl; one mole of diene to two moles of the hydroxyaryl as well as higher molecular weight products such as resins by changes in temperature, time of reaction, type and quantity of retarder and other variables.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: September 18, 2001
    Assignee: Borden Chemical, Inc.
    Inventor: Arthur H. Gerber
  • Patent number: 6288206
    Abstract: Chiral organic polymers doped with or appended by nonlinear optical dyes are disclosed. The use of chiral polymers produces a more stable noncentrosymmetric environment for the dye molecules resulting in unexpectedly long relaxation times as compared with previously used organic polymers. In addition, the NLO/chiral polymer materials exhibit high electro-optical coefficients (r33), high nonlinear optical coefficients (d33), improved long-term thermal stability, and at the same time retain the processing advantages associated with organic polymers. Thus, the present NLO/chiral polymer materials are extremely well-suited for use in second-order nonlinear optical and optoelectronics devices.
    Type: Grant
    Filed: November 2, 1999
    Date of Patent: September 11, 2001
    Assignee: Molecular OptoElectronics Corporation
    Inventors: Kevin R. Stewart, Janet L. Gordon, Kwok Pong Chan, David G. Gascoyne, Feng Pan
  • Patent number: 6284863
    Abstract: A polymer having an O-substituted vinylphenol unit represented by the following formula (I) wherein R1, R2 and R3 represent an alkyl; or R1 and R2, R1 and R3 or R2 and R3 are bound together and respectively form an alkylene; or R2 is methylidyne wherein one bond in the methylidyne is bound to R1, the other bond is bound to R3, and R1 and R3 represent alkylene, and a resist composition comprising the polymer are provided.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: September 4, 2001
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Yoshiteru Ohta, Sang-tae Kim, Masumi Suetsugu
  • Patent number: 6284868
    Abstract: In functionalized linear alternating carbon monoxide copolymers of carbon monoxide and at least one 1-alkene (A), compound (A) is an aryl derivative substituted with at least one terminal allyl and/or homoallyl moiety and containing one or more polar groups, with the proviso that 4-allylanisole is excluded.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: September 4, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Geprägs, Joachim Queisser, Bernhard Rieger, Roland Wursche
  • Patent number: 6273543
    Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with water-solubility- or water-dispersability-imparting substituents and at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula wherein x is an integer of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units. In one embodiment, a single functional group imparts both photosensitivity and water solubility or dispersability to the polymer. In another embodiment, a first functional group imparts photosensitivity to the polymer and a second functional group imparts water solubility or dispersability to the polymer.
    Type: Grant
    Filed: February 9, 1999
    Date of Patent: August 14, 2001
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 6265490
    Abstract: The invention relates to novolac resins obtained by condensation (A) of an aromatic compound containing at least two hydroxyl groups and (B) of an unconjugated diene in an (A)/(B) molar ratio of between 0.7 and 1.75 in the presence of an acidic catalyst, which are characterized in that the content of free aromatic compound is lower than 5% by weight. Also disclosed are a process for the preparation of the resins, and rubber-based compositions including from 0.5 to 20 parts by weight of the above mentioned novolac resins per 100 parts by weight of rubber. The invention also relates to the use of the resins or rubber-based compositions in the field of vulcanization, especially of tires and of conveyor belts.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: July 24, 2001
    Assignee: Ceca, S.A.
    Inventors: Christophe Morel-Fourrier, Thierry Dreyfus, Messaoud Bekhiekh, Bonnie L. Stuck
  • Patent number: 6191317
    Abstract: Polyalkyl hydroxyaromatics may be prepared from polyalkylenes and hydroxyaromatics in the presence of an acid catalyst and an organic solvent having a boiling point range with an initial boiling point value of below or about the boiling point of the selected hydroxyaromatic reactants and final boiling point of above or equal to about the boiling point of alkylhydroxyaromatic by-product of the reaction. Using this method, accumulation of undesirable alkylhydroxyaromatic by-product/s in a reaction vessel may be minimized, and/or viscosity of polyalkyl hydroxyaromatic product reduced, allowing for increased ease of transfer and transportation.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: February 20, 2001
    Assignee: Huntsman Petrochemical Corporation
    Inventor: Wei-Yang Su
  • Patent number: 6172181
    Abstract: A (2,3,4,5,6-pentafluorobenzoyl)diphenyl ether compound represented by the formula (I): wherein R stands for a hydroxyl group or a group represented by ether ketone polymer represented by the formula (II): wherein n stands for a degree of polymerization, m is an integer of 0 or 1, and R1 stands for a group represented by the formula (III): wherein p is an integer 0 or 1 and R2 stands for
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: January 9, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kunio Kimura, Yuhiko Yamashita, Patrick E. Cassidy, John W. Fitch, III, V. Sreenivasulu Reddy
  • Patent number: 6166151
    Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: December 26, 2000
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
  • Patent number: 6160083
    Abstract: The specification discloses a method for making low softening point modified terpene-phenol resins having improved properties. In the process, phenol is reacted in an organic solvent containing a Lewis acid catalyst with an acyclic mono-unsaturated olefin and terpene under reaction conditions sufficient to produce an alkyl-modified terpene-phenol resin at a relatively high yield having a softening point in the range of from about 70.degree. to about 110.degree. C., a Gardner color below about 6 and a polydispersity index below about 1.5. Due to its relatively low Gardner color number, the resin may be used substantially as produced avoiding additional decoloration steps which result in reduced product yield and increased cost. The product contains less volatile components and has improved compatibility with A-B and A-B-A copolymers as compared with many conventional modified terpene-phenol resins.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: December 12, 2000
    Assignee: Arizona Chemical Company
    Inventors: Kerry L. Thompson, Abhay K. Deshpande
  • Patent number: 6153721
    Abstract: Novel polyindanebisphenols or PIBPs for the preparation of new and improved thermosetting polymers having the general formula of ##STR1## are provided. Also disclosed are thermoplastic or thermoset compositions prepared using the novel compounds of the invention, as well as methods of making and using the same. When copolymerized or reactive with other commercial resins such as, e.g., epoxy compounds, PIBP based polymers are characterized by high glass transition temperature ("Tg"), low dielectric constant, low moisture absorption, low coefficient of expansion, low cost, and can be processed on equipment typically used for the production of epoxy based laminates.
    Type: Grant
    Filed: February 26, 1998
    Date of Patent: November 28, 2000
    Assignee: Honeywell International Inc.
    Inventors: Thomas F. McCarthy, David B. Schwind, Gordon C. Smith
  • Patent number: 6127491
    Abstract: Phenolic resin polyols are disclosed. The polyols, which contain aliphatic or mixed phenolic and aliphatic hydroxyl groups, are the reaction products of aralkylated phenols or phenol aralkylation polymers with an oxyalkylating agent selected from alkylene oxides and alkylene carbonates. The phenolic resin polyols are versatile intermediates for many polymer systems, including urethanes, epoxies, alkyds, acrylates, and polyesters.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: October 3, 2000
    Assignee: Gerorgia-Pacific Resins, Inc.
    Inventors: David C. Dehm, David A. Hutchings, Alan K. Randall, Mark A. Peters
  • Patent number: 6127511
    Abstract: A preparation process of phenol aralkyl resin from phenol compound and aralkyl compound by controlling the temperature of reaction mass in the range of 70 to 240.degree. C. and simultaneously controlling the temperature of vapor phase potion and vapor-liquid interface portion of manufacturing equipment so as to keep the wall surface of the vapor phase portion and vapor-liquid interface portion in a wet state. The invention can prevent scale adhesion to the interior of manufacturing equipment, remarkably reduce the number of washing and scale removing procedures on the manufacturing equipment, and enable efficient manufacture of phenol aralkyl resin. When the phenol aralkyl resin obtained is used for a molding material, molded articles having excellent heat resistance and high reliability can be provided.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: October 3, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomoyuki Kawabata, Yuzo Ono, Teruo Yuasa, Yukio Fukui
  • Patent number: 6124425
    Abstract: Provided herein are novel polymeric coating materials for direct digital imaging by laser. More specifically the novel coating materials are thermally reactive near infrared absorption polymers designed for use with near infrared laser imaging devices. This invention further extends to the preparation and methods of use of the novel materials. The invention is particularly useful in the preparation of lithographic printing plates for computer-to-plate and digital-offset-press technologies. The invention extends to photoresist applications, to rapid prototyping of printed circuit boards and to chemical sensor development.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: September 26, 2000
    Assignee: American Dye Source, Inc.
    Inventor: My T. Nguyen
  • Patent number: 6087414
    Abstract: Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3##
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: July 11, 2000
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Crandall
  • Patent number: 5945502
    Abstract: A polymer including mers of the formulas: ##STR1## and copolymers or mixtures thereof.
    Type: Grant
    Filed: November 13, 1997
    Date of Patent: August 31, 1999
    Assignee: Xerox Corporation
    Inventors: Bing R. Hsieh, Yuan Yu
  • Patent number: 5945500
    Abstract: Methods for preparing low free resorcinol resins are disclosed. These methods generally comprise reacting a resin with an aromatic olefinic compound; suitable resins include one or more resins selected from the group consisting of a dihydric phenol, a polyhydric phenol, a dihydric phenolic novolak resin and a polyhydric phenolic novolak resin; the addition product of at least one of these resins and at least one compound selected from the group consisting of a monooxirane compound and a polyoxirane compound; and a phenol or alkyl or aralkyl substituted mono- or dihydric phenol modified form of these resins. The resins produced by this method are also disclosed, as are rubber compositions utilizing the resin produced by this method.
    Type: Grant
    Filed: August 6, 1998
    Date of Patent: August 31, 1999
    Assignee: Indspec Chemical Corp.
    Inventors: Raj B. Durairaj, Alex Peterson, Jr.
  • Patent number: 5936056
    Abstract: Methods for preparing low free resorcinol resins are disclosed. These methods generally comprise reacting a resin with an aromatic olefinic compound; suitable resins include one or more resins selected from the group consisting of a dihydric phenol, a polyhydric phenol, a dihydric phenolic novolak resin and a polyhydric phenolic novolak resin; the addition product of at least one of these resins and at least one compound selected from the group consisting of a monooxirane compound and a polyoxirane compound; and a phenol or alkyl or aralkyl substituted mono- or dihydric phenol modified form of these resins. The resins produced by this method are also disclosed, as are rubber compositions utilizing the resin produced by this method.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: August 10, 1999
    Assignee: Indspec Chemical Corporation
    Inventors: Raj B. Durairaj, Alex Peterson, Jr.
  • Patent number: 5889137
    Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.
    Type: Grant
    Filed: January 10, 1997
    Date of Patent: March 30, 1999
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
  • Patent number: 5844063
    Abstract: The present invention relates to a resinous copolymer comprising monomer units of each of the groups of phenol compounds (I) and olefinically unsaturated non-acid terpene compounds (II), characterized in that the copolymer contains monomer units from the group of polyunsaturated olefin compounds (III), the monomer units of compound (III) being 1 to 70% by weight of the total of the monomer units of compounds (II) and (III), the monomer units of compounds (II) and (III) being at least 50% by weight of the total of monomer units of compounds (I), (II) and (III). The melting point of the copolymer is at least 130.degree. C. The copolymers are particularly useful in printing ink formulations.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: December 1, 1998
    Assignee: Arizona Chemical, S.A.
    Inventors: Jacques Salvetat, Ronald Wind
  • Patent number: 5776374
    Abstract: The present invention relates to crosslinkable thermoplastic compositions comprising a plurality of crosslinkable moieties, capable of undergoing addition polymerization, incorporated by functionalization of the precursor poly(hydroxy ethers). The poly(hydroxy ethers) comprise recurring moieties derived from aromatic dihydroxy compounds. The crosslinkable polymeric compositions are crosslinked to obtain crosslinked thermoset polymeric compositions of the invention. The polymeric compositions of the inventions can be suitably used either as an active guiding layer, and/or as a NLO active upper and lower cladding layers in an electro-optic device. The polymeric compositions can also be used as non-NLO polymers for the upper and lower cladding layers, prior to orientation by the application of an electric field.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: July 7, 1998
    Assignee: The Dow Chemical Company
    Inventors: Mark D. Newsham, Michael N. Mang, Robert J. Gulotty, Jr., Dennis W. Smith, Jr.
  • Patent number: 5773552
    Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: June 30, 1998
    Assignee: Georgia-Pacific Resins Inc.
    Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
  • Patent number: 5756642
    Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: May 26, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
  • Patent number: 5744125
    Abstract: Disclosed are cosmetic melanins of different colors produced by procedures involving oxidative polymerization of monomeric precursors of melanin and/or co-monomers that enhance substantivity or adherence of the melanins to the skin and hair. Also disclosed are methods for preparing cosmetic melanins and methods for using these compositions topically to produce a natural-appearing tan and to prevent damage to skin caused by UV exposure.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: April 28, 1998
    Assignee: Yale University
    Inventors: John M. Pawelek, James T. Platt
  • Patent number: 5739259
    Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin. In addition to the introduced to produce a product with particular properties.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: April 14, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
  • Patent number: 5723566
    Abstract: The present invention relates to a resinous copolymer comprising monomer units of each of the groups of phenol compounds (I) and olefinically unsaturated non-acidic terpene compounds (II), characterized in that the copolymer contains monomer units from the group of polyunsaturated olefin compound (III), the monomer units of compound (III) being 1 to 70% by weight of the total of the monomer units of compounds (II) and (III), the monomer units of compounds (II) and (III) being at least 50% by weight of the total of the monomer units of compounds (I), (II) and (III). The melting point of the copolymer is at least 130.degree. C.The copolymers can be used in printink inks.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: March 3, 1998
    Assignee: Arizona Chemical S.A.
    Inventors: Jacques Salvetat, Ronald Wind
  • Patent number: 5674970
    Abstract: The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: October 7, 1997
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David A. Hutchings, Jeffrey L. Mills, Kenneth Bourlier
  • Patent number: 5670603
    Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electon donating group substituted to different phenyl rings of the fluorene moiety.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: September 23, 1997
    Assignee: AlliedSignal Inc.
    Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
  • Patent number: 5589424
    Abstract: Applicants have discovered an improved photodefined dielectric materials comprising poly(aromatic diacetylenes). The preferred poly(aromatic diacetylenes) are copolymers of aromatic diacetylenes. Specific examples are 1) a copolymer of 4,4'-diethynyldiphenyl ether and m-diethynyl benzene and 2) a copolymer of 4,4'-diethynyldiphenyl ether and 4,4'-bis(3-ethynylphenoxy)-2,2',3,3',5,5',6,6'-octafluorobiphenyl. These copolymers can be photochemically crosslinked in patterns with exposure of 30 mJ/cm.sup.2 .mu.m and 60 mJ/cm.sup.2 .mu.m, respectively, and patterns have been produced in 10 .mu.m thick films with features as small as 12 .mu.m.
    Type: Grant
    Filed: October 17, 1995
    Date of Patent: December 31, 1996
    Assignee: Lucent Technologies Inc.
    Inventors: Elizabeth W. Kwock, Timothy M. Miller
  • Patent number: 5589565
    Abstract: A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: December 31, 1996
    Assignee: The Regents of the University of California
    Inventors: Fred Wudl, Alan Heeger
  • Patent number: 5552503
    Abstract: Applicants have discovered an improved photodefined dielectric materials comprising poly(aromatic diacetylenes). The preferred poly(aromatic diacetylenes) are copolymers of aromatic diacetylenes. Specific examples are 1) a copolymer of 4,4'-diethynyldiphenyl ether and m-diethynyl benzene and 2) a copolymer of 4,4'-diethynyldiphenyl ether and 4,4'-bis(3-ethynylphenoxy)-2,2',3,3',5,5',6,6'-octaflurorbiphenyl. These copolymers can be photochemically crosslinked in patterns with exposure of 30 mJ/cm.sup.2 .mu.m and 60 mJ/cm.sup.2 .mu.m, respectively, and patterns have been produced in 10 .mu.m thick films with features as small as 12 .mu.m.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: September 3, 1996
    Assignee: AT&T Corp.
    Inventors: Elizabeth W. Kwock, Timothy M. Miller
  • Patent number: 5548059
    Abstract: Unsaturated linear polymers have repeating units of a reaction product of a first monomer, a second monomer, a third monomer and optionally a fourth monomer. The linear polymers have a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C. The first monomer should have a weight average molecular weight less than 200. The second monomer may be a dicarboxylic acid or diester which is different than the third monomer. A concentration of second residues of the polymer, derived from the second monomer, ranges from about 3 wt. % to about 15 wt. %, based on the total weight of the polymer. The third monomer is an aromatic dicarboxylic acid or an ester thereof. In the polymer, a concentration of third residues, derived from the third monomer, ranges from about 40 wt. % to about 55 wt. %, based on the total weight of the polymer. The fourth monomer is a diol having a higher molecular weight than the first monomer.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: August 20, 1996
    Assignee: Xerox Corporation
    Inventors: Robert D. Bayley, Carol A. Fox, Thomas R. Hoffend, Hadi K. Mahabadi, Enno E. Agur, Guerino Sacripante, Michael S. Hawkins
  • Patent number: 5527876
    Abstract: The invention relates to a process for the production of plastics containing amide groups with elimination of CO.sub.2 by reaction of polyfunctional isocyanates, carboxylic acids and, optionally, alcohols in the presence of tertiary amines, more particularly heteroaromatic amines. The heteroaromatic amines preferably contain another heteroatom and/or substituents having +I and/or +M effects. The reaction preferably starts at room temperature. Fine-cell foams having an acid value of less than 40 and a density of at most 150 g/l can be produced in short reaction times at room temperature without any need for additional blowing agents.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: June 18, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hermann Kluth, Peter Daute, Johann Klein, Roland Gruetzmacher, Wolfgang Klauck
  • Patent number: 5525686
    Abstract: A process for preparing a polyvalent metal salt of a salicylic acid resin which comprises the steps of reacting salicylic acid or its derivative with styrene or its derivative at a temperature of -20.degree. C. or higher but lower than 40.degree. C. in the presence of sulfuric acid, and then reacting the resulting reaction product with a polyvalent metal compound; an aqueous dispersion in which the polyvalent metal salt of the resin is dispersed in water; and a developing sheet in which the polyvalent metal salt of the salicylic acid resin is used.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshimitsu Tanabe, Jotaro Kida, Kiyoharu Hasegawa, Masakatsu Nakatsuka, Masayuki Furuya, Takeshi Nishimura
  • Patent number: 5494964
    Abstract: Polyester resins suitable as binders for electrophotographic toners and for acceptor layers for the thermal diffusion printing process based on hydroxyl-containing prepolymers of olefinically unsaturated monomers obtained by(1) polymerization of a mixture of(a) from 60 to 90% by weight of styrene or of a styrene derivative,(b) from 0 to 40% by weight of one or more C.sub.1 -C.sub.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: February 27, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Georg Meichsner, Thomas Wuensch, Rainer Dyllick-Brenzinger
  • Patent number: 5474854
    Abstract: The invention is a polyester composition containing crosslinked polymer particles with ester bonds at the main chain. The particles are excellent in affinity to polyesters, and so the films formed from the polyester compositions do not have the particles falling off during high speed running, and do not have flaws in the film surfaces. The invention can prevent the generation of white powder and the flaws of magnetic faces caused by falling-off particles, and prevent the contamination in the production of films, even though these are problems caused when various conventional particles are added, and is especially suitable for use as products such as magnetic films.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: December 12, 1995
    Assignee: Toray Industries, Inc.
    Inventors: Nobuyuki Kagami, Masatoshi Aoyama, Masaru Suzuki, Keisuke Oshima