Six-membered Heterocycle Is Other Than Melamine Per Se Or Methylol Derivative Thereof Patents (Class 528/258)
  • Patent number: 8153752
    Abstract: Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I) >N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: April 10, 2012
    Assignee: BASF Coatings GmbH
    Inventors: Gunther Ott, Ulrike Rockrath, Bjorn Feldmann, Ulrike Clausen-Meiring, Karl-Heinz Joost
  • Patent number: 7342085
    Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links HO—Ar2O—Ar1—O—Ar2nOH.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: March 11, 2008
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Teddy M Keller, Matthew Laskoski
  • Patent number: 7087683
    Abstract: A crosslinking agent that is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin such that the crosslinking agent is essentially free of functional groups reactive with an aminoplast resin and has a glass transition temperature of at least 10° C. is disclosed. Compound (b) is, more specifically, a monofunctional sulfonamide having only one active hydrogen. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating compositions and substrates coated therewith are also disclosed. Methods for modifying aminoplasts are also disclosed.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: August 8, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shengkui Hu, Anthony M. Chasser, William H. Retsch, Ronald R. Ambrose
  • Patent number: 6809161
    Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: October 26, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
  • Publication number: 20040152855
    Abstract: A composition, comprising, in an appropriate medium, at least one polymer with a highly specific ordered structure is disclosed. These compositions find a specific application in the field of make-up and are capable of being applied to keratinous fibres, in particular to the nails, eyelashes, eyebrows and hair. In particular, these compositions can make it possible to obtain a film which exhibits good resistance to chipping, to impacts, to rubbing movements, to scratches and/or to pressing actions.
    Type: Application
    Filed: January 17, 2003
    Publication date: August 5, 2004
    Applicant: L'Oreal
    Inventor: Nathalie Mougin
  • Patent number: 6720392
    Abstract: An aqueous amino resin blend comprises aliphatic linear, branched or cyclic amines A containing at least one primary, secondary or tertiary amino group, at least one hydroxyl group and 2 to 20 carbon atoms, and amino resins B, and is used as an impregnating resin in the production of finished foils and edgings.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: April 13, 2004
    Assignee: Solutia Germany GmbH & Co. KG
    Inventors: Frank Scholl, Johann Wonner, Wolfgang Scholz
  • Patent number: 6635724
    Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: October 21, 2003
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
  • Publication number: 20030135004
    Abstract: A composition, comprising, in an appropriate medium, at least one polymer with a highly specific ordered structure is disclosed. These compositions find a specific application in the field of make-up and are capable of being applied to keratinous fibres, in particular to the nails, eyelashes, eyebrows and hair. In particular, these compositions can make it possible to obtain a film which exhibits good resistance to chipping, to impacts, to rubbing movements, to scratches and/or to pressing actions.
    Type: Application
    Filed: January 17, 2003
    Publication date: July 17, 2003
    Applicant: L'Oreal
    Inventor: Nathalie Mougin
  • Patent number: 6552146
    Abstract: A composition, comprising, in an appropriate medium, at least one polymer with a highly specific ordered structure is disclosed. These compositions find a specific application in the field of make-up and are capable of being applied to keratinous fibers, in particular to the nails, eyelashes, eyebrows and hair. In particular, these compositions can make it possible to obtain a film which exhibits good resistance to chipping, to impacts, to rubbing movements, to scratches and/or to pressing actions.
    Type: Grant
    Filed: April 5, 2000
    Date of Patent: April 22, 2003
    Assignee: L'Oreal S.A.
    Inventor: Nathalie Mougin
  • Patent number: 6518387
    Abstract: The present invention relates to a soybean-based adhesive resin including a soybean flour and a cross-linking agent. The cross-linking agent is reacted with the functional groups in the soybean flour to form an adhesive resin. The present invention also relates to a method of making a soybean-based adhesive resin. This method involves providing an aqueous solution of soybean flour and adding a cross-linking agent to the solution under conditions effective to cross-link the soybean flour so that an adhesive resin is formed. Also disclosed is a composite product which includes particulate plant material and the soybean-based adhesive resin. The adhesive is prepared by reacting the cross-linking agent with the functional groups in the soybean flour. The present invention also relates to a method of making a composite product by providing particulate plant material and applying the soybean-based adhesive resin to the particulate plant material.
    Type: Grant
    Filed: September 4, 2001
    Date of Patent: February 11, 2003
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Monlin Kuo, Deland J. Myers, Howard Heemstra, Daniel Curry, Daniel O. Adams, Douglas D. Stokke
  • Publication number: 20020137876
    Abstract: A process for producing amino resin particles includes: a reaction process for obtaining a reaction solution containing an amino resin precursor which is obtained by a reaction of an amino compound with formaldehyde, and having a viscosity in a range of from 2×10−2 Pa.s to 5.8×10−2 Pa.s at a temperature in a range of from 95° C. to 98° C.; an emulsion process for obtaining an emulsion by emulsifying the reaction solution; and a curing process for curing the amino resin precursor in the emulsion state by adding a catalyst to the emulsion. With this producing process, it is possible to readily produce amino resin particles with an essentially uniform particle size (narrow particle size distribution).
    Type: Application
    Filed: December 28, 2001
    Publication date: September 26, 2002
    Applicant: Nippon Shokubai Co., Ltd.
    Inventors: Yasuhiro Yamamoto, Shuji Shimizu, Masafumi Inoue, Hideki Oishi
  • Patent number: 6258898
    Abstract: A crosslinking agent comprising one or more carbamate groups or groups convertible to carbamate and two or more polyfunctional amino moieties having the formula wherein L is selected from the group consisting of alkyl or aryl, cycloalkyl and alkylaryl having a carbon chain length between 1 and 6 carbon atoms and N is a polyfunctional amino moiety. L may also have additional bridging groups such as esters, ethers, ureas, or urethanes groups. Also included is a method of making the crosslinker, a coating composition containing the crosslinker and a method for coating a substrate with the composition.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: July 10, 2001
    Assignee: BASF Corporation
    Inventors: John W. Rehfuss, Walter H. Ohrbom, Donald L. St. Aubin
  • Patent number: 6136200
    Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein: A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH).sbsp.p.sup.(SO.sbsp.4.sup.).sbsp.y.sup.(Aci) (2m+3n)-p-2y].sub.rwhere r=1 to 98% bw; u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ =(PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al--Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.
    Type: Grant
    Filed: March 11, 1994
    Date of Patent: October 24, 2000
    Assignee: Polymer Research Corporation
    Inventor: John J. Waldmann
  • Patent number: 5998573
    Abstract: A novel amino resin composition produced by reacting one of or a mixture of more than two triazine derivatives of Formula I: ##STR1## wherein, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent an independent substituent, and one to five substituents thereof represent a C.sub.1 -.sub.20 alkyl group, a C.sub.2-20 alkenyl group (the alkyl group or alkenyl group may optionally have an alicyclic structure of phenyl group), or a phenyl group, and the remaining substituent or substituents represent a hydrogen atom with formaldehyde; a novel amino composition produced by reacting a mixture of one of or a mixture of more than two of said triazine derivatives and melamine or urea with formaldehyde; and an amino composition comprising a novel amino composition produced by reacting a mixture of one of or a mixture of more than two triazine derivatives with formaldehyde and a melamine-formaldehyde resin and a melamine/urea-formaldehyde resin or a urea-formaldehyde resin.
    Type: Grant
    Filed: March 16, 1998
    Date of Patent: December 7, 1999
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Makoto Takakura, Hiroyuki Uehara, Keisuke Nakayama, Yuko Furuya
  • Patent number: 5895802
    Abstract: The invention concerns redispersible polymer powders characterized by a proportion of 3 to 30% by wt relative to the polymer weight of condensation products of amino-s-triazine/formaldehyde/sulfite with molar ratios of amino-s-triazine to formaldehyde to sulfite of 1/1.3-6.0/0.3-1.5 and with a low free formaldehyde content. These condensation products of amino-s-triazine/formaldehyde/sulfite are exceedingly effective protective colloids when spray-drying polymer dispersions and can be combined in problem-free manner with casein.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: April 20, 1999
    Assignee: SKW Trostberg Aktiengescellchaft
    Inventors: Josef Weichmann, Alfred Kern
  • Patent number: 5891983
    Abstract: Water-soluble formaldehyde-free polycondensation products based on amino-s-triazines with at least two amino groups and glyoxylic acid, which contain as further component at least one amino compound and where the molar ratio of amino-s-triazine to glyoxylic acid to amino compound is 1:0.5 to 6.0:0.1 to 2.0. These polycondensation products are excellently suited as additives for aqueous suspensions of inorganic binders, especially cement, lime and gypsum. Building material mixtures which contain these polycondensation products remain workable for a considerably longer time and, in spite of this, also set more quickly.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: April 6, 1999
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Gerhard Albrecht, Manfred Schuhbeck, Christian Huber, Josef Weichmann, Alfred Kern
  • Patent number: 5789526
    Abstract: Disclosed is a highly viscous condensation product containing sulfonic acid groups based on amino-s-triazines with at least 2 amino groups and formaldehyde which has a viscosity of 500 to 100,000 cp at 20.degree. C. and a pH value of 8.0 to 13.0 as an aqueous solution with a solids content of 20% by weight. The product is obtainable by (a) condensation of amino-s-triazine, formaldehyde and sulfite in a molar ratio of 1:1.9 to 2.9:0.7 to 1.3 in aqueous solution at a pH value of 9.0 to 12.0 and a temperature of 50.degree. to 90.degree. C. until the sulfite is no longer detectable, and (b) subsequent further condensation at a pH value of 2.0 to 5.0 and a temperature of 50.degree. to 100.degree. C. until the viscosity exhibits the desired value.
    Type: Grant
    Filed: February 22, 1996
    Date of Patent: August 4, 1998
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Josef Weichmann, Franz Wolfertstetter, Herbert Winkelmann, Alfred Kern
  • Patent number: 5750634
    Abstract: Disclosed is a soluble polycondensation product based on amino-s-triazines with at least two amino groups and forma ehyde, a process for making the product and the use thereof as an additive for an aqueous binding agent suspension.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: May 12, 1998
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Gerhard Albrecht, Josef Weichmann, Ludwig Eibl, Christian Huber, Alfred Kern
  • Patent number: 5648446
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: July 15, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5646240
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: July 8, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
  • Patent number: 5558709
    Abstract: Disclosed is a flow improving agent for binder suspensions containing cement which is composed of a) amino-s-triazine-formaldehyde-sulfite condensation products having a molar ratio of amino-s-triazine:formaldehyde:sulfite of 1:1.3 to 6.0: 0.3 to 1.5 and a low content of free formaldehye as well as b) casein. The flow improving agents have the advantage that the flowability is considerably improved compared to casein (alone) for example and the increased flowability remains constant even over a longer time period.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: September 24, 1996
    Assignee: SKW Trostberg
    Inventors: Josef Weichmann, Aloisia Stadler, Alfred Kern
  • Patent number: 5545702
    Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: August 13, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
  • Patent number: 5380815
    Abstract: Condensation compounds obtained by means of the polymerization of polyami compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: January 10, 1995
    Assignee: Ministero Dell `Universita` E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5328978
    Abstract: The present invention relates to a triazine/formaldehyde resin which contains a compound of the general formula I ##STR1## wherein R.sup.1 and R.sup.2 are defined as stated in claim 1, a process for its preparation and its use as a curing agent in surface coating systems.
    Type: Grant
    Filed: October 28, 1993
    Date of Patent: July 12, 1994
    Assignee: Cassella AG
    Inventors: Manfred Schon, Jurgen Ott, Uwe Kubillus, Elif Tas
  • Patent number: 5294352
    Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: March 15, 1994
    Inventor: John J. Waldmann
  • Patent number: 5215828
    Abstract: Curable binders obtained by simultaneous reaction ofA) urethanes or ureas,B) acrylic or methacrylic compounds containing hydroxyl groups,C) paraformaldehyde andD) if appropriate, polyols,wherein, in the case where no polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger, and in the case where a polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger or a strong acid.These binders are suitable as coating compositions which can be cured by electron beams or by UV light.
    Type: Grant
    Filed: August 19, 1992
    Date of Patent: June 1, 1993
    Assignee: Hoechst AG
    Inventors: Gerhard Brindoepke, Inge Kurth, Michael Schwab, Gerd Walz
  • Patent number: 5162462
    Abstract: Process for the production of aminoplast resins. The process entailing the addition of ureido-2-diamino-4,6-triazine-1,3,5, and optionally melamine, to aminoplast resin. Preferably the triazine is added in a proportion of at least 10% by weight. The resultant aminoplasts can be used to make panels from particles.
    Type: Grant
    Filed: August 20, 1991
    Date of Patent: November 10, 1992
    Assignee: Norsolor (Orkem Group)
    Inventors: Jeanine Barthomieux, Roger Garrigue, Jack Lalo
  • Patent number: 5071945
    Abstract: A process for the production of sulphonic acid group-containing condensation products based on amino-s-triazines with at least two amino groups and formaldehyde with a low content of free formaldehyde, whereina) an amino-s-triazine, formaldehyde and sulphite is condensed in a mole ratio of 1:1.3 to 6:0.3 to 1.5 in aqueous solution at a pH value of 9.0 to 12.0 and at a temperature of 50.degree. to 90.degree. C. until sulphite is no longer detectable.b) subsequently, further condensation is carried out at a pH value of 2.0 to 7.0 and at a temperature of 50.degree. to 90.degree. C. until the viscosity of the solution is 4 to 1000 mm.sup.2 /s at 80.degree. C. andc) thereafter the condensation product is subjected to an after-treatment in a strongly alkaline range of pH.sqroot.11.0 and at an elevated temperature.
    Type: Grant
    Filed: August 1, 1990
    Date of Patent: December 10, 1991
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Josef Weichmann, Manfred Bichler, Alfred Kern, Hans-Gunter Rosenbauer
  • Patent number: 5049645
    Abstract: A continuous preparation method of an amino resin particulate having a maximum particle size of 40 .mu.m or less and an average particle size of from 5 to 15 .mu.m is described. The method comprises the steps of reacting amino compounds with aldehydes in the presence of an acid catalyst in an aqueous solution to form a solid product and classifying said solid product in the form of a slurry with a combination of at least two grinders and at least two classifiers.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: September 17, 1991
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Muneo Nagaoka, Saburo Hayano
  • Patent number: 4983710
    Abstract: A method for the production of methylolaminotriazine condensate by the reaction of cyclohexanecarboguanamine (A) and formaldehyde (B), which method comprises preparing a solution of formaldehyde (B) or a solution containing cyclohexanecarboguanamine (A) and formaldehyde (B) in such amounts that the molar ratio of (A)/(B) will be not more than 1/2.5, keeping the temperature of said solution in the range of 55.degree. to 150.degree. C. and, at the same time, gradually supplying cyclohexanecarboguanaimine (A) thereto.
    Type: Grant
    Filed: August 10, 1989
    Date of Patent: January 8, 1991
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Hidetaka Yatagai, Jiro Iriguchi, Souichi Yamada, Tsuguo Takaya
  • Patent number: 4931537
    Abstract: Curable epoxy systems comprising polyglycidamides and epoxy reactants. The polyglycidamides are hydroxy functional polyglycidamides derived from amino resins. The epoxy systems can be used as laminating, encapsulating and coating resins. When the epoxy reactant is an anhydride, cure under ambient conditions is obtained.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: June 5, 1990
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 4931536
    Abstract: Hydroxy functional acrylamido amino resins comprising hydroxy-hydrocarbyl groups. The resins are produced by reaction of alkoxymethyl amino resins with acrylamide to introduce acrylamidomethyl groups and then with a polyol to introduce hydroxy functionality. The hydroxy functional acrylamido amino resins may be epoxidized to form polyglycidamides which can then be formulated with epoxy reactants to provide curable epoxy systems.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: June 5, 1990
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 4764585
    Abstract: Cationic fixing agents based on the reaction products of(a) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups and(b) cyanamide, dicyandiamide, guanidine or bisguanidinegive improved results when the reaction takes place in the presence of a catalyst (K) selected from metals, metal salts and heterocyclic nitrogen-containing organic bases, particularly zinc chloride.
    Type: Grant
    Filed: September 15, 1987
    Date of Patent: August 16, 1988
    Assignee: Sandoz Ltd.
    Inventors: Jurg Heller, Bruno Kissling, Curt Muller, Tibor Robinson, Salvatore Valenti
  • Patent number: 4696959
    Abstract: A composition of matter contains as a principal component a material which acts as an ultraviolet light stabilizer. The ultraviolet light stabilizer is formed from the reaction of (a) a methylol or alkoxy alkyl-containing material, and (b) an alkyl substituted piperidine containing material which is represented by the following structural formula: ##STR1## R" is hydrogen or C.sub.1 to C.sub.6 alkyl, R.sub.10 is hydrogen or methyl,Y is a radical derived from a material selected from the group consisting of amino substituted triazines, ureas, glycolurils, phenols, and amides of the formula ##STR2## R' is hydrogen or C.sub.1 to C.sub.12 alkyl and R is an aliphatic, cycloaliphatic, or olefinic radical, or an acrylic polymer moiety having at least one group selected from hydroxyl, carboxyl, amido, and ureido, said reaction proceeding between a methylol or alkoxy alkyl group of (a) and the group selected from hydroxyl, carboxyl, amido and ureido of (b).
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: September 29, 1987
    Assignee: PPG Industries, Inc.
    Inventors: Wen-Hsuan Chang, Michael M. Chau, Robert Piccirilli
  • Patent number: 4677159
    Abstract: Stable, water soluble, sulfonated melamine-formaldehyde and sulfonated melamine-urea-formaldehyde resin solutions are prepared in a four stage procedure, wherein (1) melamine or melamine and urea are condensed with formaldehyde in an aqueous medium at a relative low temperature and a pH of 10-13, followed by (2) the addition of a sulfonating agent, such as sodium metabisulfite, and continued reaction without pH adjustment, followed by (3) lowering the temperature of the reaction medium to 40.degree.-60.degree. C., adjusting the pH to 2.5-4 and continuing the reaction for about 5-150 minutes, and finally followed by (4) adjusting the pH to 6.5-9, heating the reaction medium to 70.degree.-100.degree. C. for 30-180 minutes, adjusting the final solids content to a predetermined value, such as 20%, and adjusting the pH to 8-11. The resulting aqueous solutions are suitable for use as superplasticizer additives to hydraulically settable cementitious materials.
    Type: Grant
    Filed: October 16, 1985
    Date of Patent: June 30, 1987
    Assignee: Kuwait Institute for Scientific Research
    Inventors: Shawqui Lahalih, Ma'mun Absi-Halabi
  • Patent number: 4668785
    Abstract: N,N',N"-tris-(2-hydroxyethyl)-melamine, if required, as a mixture with N-mono- and N,N'-bis-(2-hydroxyethyl)-melamine, is prepared by reacting melamine with ethanolamine in the presence of an acidic catalyst by a method in which the reaction is carried out at from 120.degree. to 250.degree. C. using an excess of ethanolamine, and the molar ratio of free ethanolamine to the sum of free and converted melamine is not permitted to fall below 4:1 during the entire reaction time, and the stated (2-hydroxyethyl)-melamines are used as modifiers in the prepartion of aminoplast resins which are suitable for laminating surfaces.
    Type: Grant
    Filed: June 13, 1985
    Date of Patent: May 26, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Ebel, Wolfgang Reuther, Wolfram Weiss, Ludwig Lelgemann
  • Patent number: 4663387
    Abstract: Thermally stable water soluble resins are prepared in a multistep process by reacting the waste solids from the mother liquor waste stream of a melamine manufacturing plant with an aldehyde and a sulfonating agent under controlled conditions of pH and temperature. The resin compositions are useful, for example, as superplasticizing agents for concrete mixtures, as mud drilling additives, and in the paper and textile industry. The process not only provides useful resin compositions, but also recovers solid wastes which are considered to be a major contributor to the pollution problems of melamine manufacturing plants.
    Type: Grant
    Filed: April 2, 1985
    Date of Patent: May 5, 1987
    Assignee: Kuwait Institute for Scientific Research
    Inventors: Shawqui Lahalih, Ma'mun Absi-Halabi
  • Patent number: 4631320
    Abstract: A thermosettable coating composition comprises a hydroxy group-containing polyurethane, polyurea or polyurethane/polyurea polymer, an amino cross-linker and optionally, a catalyst and/or solvent. The polymer is obtained by self condensation of an hydroxyalkyl carbamate compound or condensation of such compound with a polyol and/or a polyamine. An applied coating of the composition is cured by heating to an elevated temperature, e.g., from about 200.degree. to about 400.degree. F. (about 93.degree. to 204.degree. C.).
    Type: Grant
    Filed: February 17, 1984
    Date of Patent: December 23, 1986
    Assignee: American Cyanamid Company
    Inventors: Girish G. Parekh, Werner J. Blank
  • Patent number: 4591613
    Abstract: A method for the production of hydroxyalkylmelamine containing resins wherein melamine, formaldehyde and a hydroxyalkylmelamine are reacted under conditions such that a resin is produced which, when incorporated into a decorative laminate, enhances the post-forming thereof, the resin per se, paper sheets containing said resin, a method for the production of laminates and the laminates per se, are disclosed.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: May 27, 1986
    Assignee: American Cyanamid Company
    Inventors: Fouad T. Karam, Jack I. Sibalis
  • Patent number: 4578450
    Abstract: There is disclosed the reaction product of an N-(substituted oxymethyl)melamine and a 2-mercaptoarylthiazole and its use as an adhesion promoter to improve rubber to metal wire adhesion.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: March 25, 1986
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: William W. Schloman, Jr.
  • Patent number: 4564667
    Abstract: A solid urea-formaldehyde resin is provided, having a degree of condensation of 25% to 45%.A process for making the resin is also described and includes several steps. Urea and formaldehyde is first reacted with a molar ratio of U:F of 1:2.5 or more then concentrated. Further urea is added to reduce the ratio to the range 1:1.1 to 1:2 and further concentration is achieved without precipitation of solid resin by the use of a stabilization agent.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: January 14, 1986
    Assignee: BIP Chemicals Limited
    Inventor: David Taylor
  • Patent number: 4489027
    Abstract: A process for preparing a thermoplastic poly(imidesulfone) is disclosed. This resulting material has thermoplastic properties which are generally associated with polysulfones but not polyimides, and solvent resistant which is generally associated with polyimides but not polysulfones. This system is processable in the 250.degree.-350.degree. C. range for molding, adhesive and laminating applications. This unique thermoplastic poly(imidesulfone) is obtained by incorporating an aromatic sulfone moiety into the backbone of an aromatic linear polyimide by dissolving a quantity of a 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) in a solution of 3,3'-diaminodiphenylsulfone and bis(2-methoxyethyl)ether, precipitating the reactant product in water, filtering and drying the recovered poly(amide-acid sulfone) and converting it to the poly(imidesulfone) by heating.
    Type: Grant
    Filed: May 6, 1983
    Date of Patent: December 18, 1984
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Terry L. St. Clair, David A. Yamaki
  • Patent number: 4475918
    Abstract: Aftertreatment of dyeings on cotton or nylon with (A) a polybasic compound which is the product of reacting a primary or secondary amine with cyanamide, dicyandiamide, guanidine or biguanidine and, sequentially or simultaneously (B) a precondensate formed by reacting a compound of type (A) with an N-methylol derivative gives wet fastness properties superior to those given by either (A) or (B) used alone.
    Type: Grant
    Filed: August 24, 1983
    Date of Patent: October 9, 1984
    Assignee: Sandoz Ltd.
    Inventors: Bruno Kissling, Tibor Robinson
  • Patent number: 4451620
    Abstract: Diethanolammonium sulphamate is a curing agent for modified aminoplast resins.
    Type: Grant
    Filed: May 5, 1983
    Date of Patent: May 29, 1984
    Assignee: Cassella Aktiengesellschaft
    Inventors: Steffen Piesch, Peter Dorries
  • Patent number: 4443223
    Abstract: The fastness of direct dyes on cellulose substrates is improved by after-treatment with the reaction product of a quaternary polyalkylene polyamine with an N-methylol resin precursor, and heat curing in the presence of a catalyst. The unfixed portion of reactive dyes substantive to cellulose may also be given improved wet and light fastness by this treatment.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: April 17, 1984
    Assignee: Sandoz Ltd.
    Inventors: Bruno Kissling, Walter Knobel, Tibor Robinson
  • Patent number: 4382873
    Abstract: Dispersant and biodegradant formulations are manufactured by admixing at least one melamine derivative with at least one compound having a hydroxy function, at least one phosphorus compound and at least one surfactive agent. Aqueous emulsions obtained from these formulations are also provided.
    Type: Grant
    Filed: December 19, 1980
    Date of Patent: May 10, 1983
    Assignee: Institut Francais du Petrole
    Inventors: Claude Gatellier, Andree Plessis, Patrick Gateau, Jean-Pierre Durand
  • Patent number: 4365053
    Abstract: A thermosetting synthetic crosslinking resin containing selected ethers of the reaction product of an isoadipoguanamine mixture and formaldehyde can be incorporated into a variety of coating compositions to provide finishes that are characterized by hardness, flexibility, durability, excellent adhesion, and commercially-acceptable cure temperatures.
    Type: Grant
    Filed: August 8, 1980
    Date of Patent: December 21, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Francis E. Schweitzer
  • Patent number: 4351935
    Abstract: A thermosetting coating composition contains an acid-curable amino resin and from 0.1 to 10 percent by weight of a blocked sulphonic acid calculated on the weight of amino resin. In order to reduce the electric conductivity of the composition after a prolonged pot-life, a sulphonic acid oximate is used as the blocked acid.The compositions are advantageous for coating a substrate by electrostatic spraying.
    Type: Grant
    Filed: July 14, 1981
    Date of Patent: September 28, 1982
    Assignee: Akzo N.V.
    Inventors: Johan B. Reesink, Hendrik J. Hageman, Ulfert E. Wiersum
  • Patent number: 4349660
    Abstract: A process for the production of an air-drying, modified amino-resin, which process comprises co-polycondensing one or more dialkyl ether compounds, which are dialkyl ether of the dimethylol derivatives of compounds containing two primary amido groups or similar groups, with at least one compound containing an auto-oxidative group, or polycondensing the said one or more dialkyl ether compounds and reacting the compound containing an auto-oxidative group with the condensate; the alcohol released being removed from the mixture. The auto-oxidative groups are typically supplied by allyl ethers and the dialkyl ether compound is e.g. bismethoxymethylene urea. The modified resins rapidly form hard films when exposed to atmospheric oxygen in the presence of drying agents.
    Type: Grant
    Filed: December 8, 1980
    Date of Patent: September 14, 1982
    Assignee: Kemira Oy
    Inventor: Hannu J. Toivonnen
  • Patent number: 4316005
    Abstract: A cationic adsorption agent which is obtained by reaction of(a) an amino compound which contains at least one amino group and at least one free or methylolated carboxamide group, with(b) an aminoplast precondensate which does not contain amino groups.The novel adsorption agent is suitable in particular for removing anionic substances, such as acid dyes or reactive dyes, from aqueous solutions, especially from wastewaters.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: February 16, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf F. Wurster, Jurg Merz