Six-membered Heterocycle Is Other Than Melamine Per Se Or Methylol Derivative Thereof Patents (Class 528/258)
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Patent number: 8153752Abstract: Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I) >N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).Type: GrantFiled: February 9, 2007Date of Patent: April 10, 2012Assignee: BASF Coatings GmbHInventors: Gunther Ott, Ulrike Rockrath, Bjorn Feldmann, Ulrike Clausen-Meiring, Karl-Heinz Joost
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Patent number: 7342085Abstract: A cyanate ester system is disclosed. An aryl ether oligomer may be made from a dihydroxyaromatic compound and a dihaloaromatic compound in the presence of a base. The oligomer is then reacted with a cyanide compound in the presence of a base to form the cyanate ester shown below. The cyanate ester may then be cross-linked to a thermoset having triazine ring cross-links HO—Ar2O—Ar1—O—Ar2nOH.Type: GrantFiled: June 22, 2006Date of Patent: March 11, 2008Assignee: The United States of America as represented by the Secretary of the NavyInventors: Teddy M Keller, Matthew Laskoski
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Patent number: 7087683Abstract: A crosslinking agent that is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin such that the crosslinking agent is essentially free of functional groups reactive with an aminoplast resin and has a glass transition temperature of at least 10° C. is disclosed. Compound (b) is, more specifically, a monofunctional sulfonamide having only one active hydrogen. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating compositions and substrates coated therewith are also disclosed. Methods for modifying aminoplasts are also disclosed.Type: GrantFiled: December 5, 2002Date of Patent: August 8, 2006Assignee: PPG Industries Ohio, Inc.Inventors: Shengkui Hu, Anthony M. Chasser, William H. Retsch, Ronald R. Ambrose
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Patent number: 6809161Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.Type: GrantFiled: July 1, 2003Date of Patent: October 26, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
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Publication number: 20040152855Abstract: A composition, comprising, in an appropriate medium, at least one polymer with a highly specific ordered structure is disclosed. These compositions find a specific application in the field of make-up and are capable of being applied to keratinous fibres, in particular to the nails, eyelashes, eyebrows and hair. In particular, these compositions can make it possible to obtain a film which exhibits good resistance to chipping, to impacts, to rubbing movements, to scratches and/or to pressing actions.Type: ApplicationFiled: January 17, 2003Publication date: August 5, 2004Applicant: L'OrealInventor: Nathalie Mougin
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Patent number: 6720392Abstract: An aqueous amino resin blend comprises aliphatic linear, branched or cyclic amines A containing at least one primary, secondary or tertiary amino group, at least one hydroxyl group and 2 to 20 carbon atoms, and amino resins B, and is used as an impregnating resin in the production of finished foils and edgings.Type: GrantFiled: May 6, 2002Date of Patent: April 13, 2004Assignee: Solutia Germany GmbH & Co. KGInventors: Frank Scholl, Johann Wonner, Wolfgang Scholz
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Patent number: 6635724Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.Type: GrantFiled: July 31, 2001Date of Patent: October 21, 2003Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
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Publication number: 20030135004Abstract: A composition, comprising, in an appropriate medium, at least one polymer with a highly specific ordered structure is disclosed. These compositions find a specific application in the field of make-up and are capable of being applied to keratinous fibres, in particular to the nails, eyelashes, eyebrows and hair. In particular, these compositions can make it possible to obtain a film which exhibits good resistance to chipping, to impacts, to rubbing movements, to scratches and/or to pressing actions.Type: ApplicationFiled: January 17, 2003Publication date: July 17, 2003Applicant: L'OrealInventor: Nathalie Mougin
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Patent number: 6552146Abstract: A composition, comprising, in an appropriate medium, at least one polymer with a highly specific ordered structure is disclosed. These compositions find a specific application in the field of make-up and are capable of being applied to keratinous fibers, in particular to the nails, eyelashes, eyebrows and hair. In particular, these compositions can make it possible to obtain a film which exhibits good resistance to chipping, to impacts, to rubbing movements, to scratches and/or to pressing actions.Type: GrantFiled: April 5, 2000Date of Patent: April 22, 2003Assignee: L'Oreal S.A.Inventor: Nathalie Mougin
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Patent number: 6518387Abstract: The present invention relates to a soybean-based adhesive resin including a soybean flour and a cross-linking agent. The cross-linking agent is reacted with the functional groups in the soybean flour to form an adhesive resin. The present invention also relates to a method of making a soybean-based adhesive resin. This method involves providing an aqueous solution of soybean flour and adding a cross-linking agent to the solution under conditions effective to cross-link the soybean flour so that an adhesive resin is formed. Also disclosed is a composite product which includes particulate plant material and the soybean-based adhesive resin. The adhesive is prepared by reacting the cross-linking agent with the functional groups in the soybean flour. The present invention also relates to a method of making a composite product by providing particulate plant material and applying the soybean-based adhesive resin to the particulate plant material.Type: GrantFiled: September 4, 2001Date of Patent: February 11, 2003Assignee: Iowa State University Research Foundation, Inc.Inventors: Monlin Kuo, Deland J. Myers, Howard Heemstra, Daniel Curry, Daniel O. Adams, Douglas D. Stokke
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Publication number: 20020137876Abstract: A process for producing amino resin particles includes: a reaction process for obtaining a reaction solution containing an amino resin precursor which is obtained by a reaction of an amino compound with formaldehyde, and having a viscosity in a range of from 2×10−2 Pa.s to 5.8×10−2 Pa.s at a temperature in a range of from 95° C. to 98° C.; an emulsion process for obtaining an emulsion by emulsifying the reaction solution; and a curing process for curing the amino resin precursor in the emulsion state by adding a catalyst to the emulsion. With this producing process, it is possible to readily produce amino resin particles with an essentially uniform particle size (narrow particle size distribution).Type: ApplicationFiled: December 28, 2001Publication date: September 26, 2002Applicant: Nippon Shokubai Co., Ltd.Inventors: Yasuhiro Yamamoto, Shuji Shimizu, Masafumi Inoue, Hideki Oishi
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Patent number: 6258898Abstract: A crosslinking agent comprising one or more carbamate groups or groups convertible to carbamate and two or more polyfunctional amino moieties having the formula wherein L is selected from the group consisting of alkyl or aryl, cycloalkyl and alkylaryl having a carbon chain length between 1 and 6 carbon atoms and N is a polyfunctional amino moiety. L may also have additional bridging groups such as esters, ethers, ureas, or urethanes groups. Also included is a method of making the crosslinker, a coating composition containing the crosslinker and a method for coating a substrate with the composition.Type: GrantFiled: December 23, 1996Date of Patent: July 10, 2001Assignee: BASF CorporationInventors: John W. Rehfuss, Walter H. Ohrbom, Donald L. St. Aubin
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Patent number: 6136200Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein: A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH).sbsp.p.sup.(SO.sbsp.4.sup.).sbsp.y.sup.(Aci) (2m+3n)-p-2y].sub.rwhere r=1 to 98% bw; u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ =(PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al--Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.Type: GrantFiled: March 11, 1994Date of Patent: October 24, 2000Assignee: Polymer Research CorporationInventor: John J. Waldmann
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Patent number: 5998573Abstract: A novel amino resin composition produced by reacting one of or a mixture of more than two triazine derivatives of Formula I: ##STR1## wherein, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent an independent substituent, and one to five substituents thereof represent a C.sub.1 -.sub.20 alkyl group, a C.sub.2-20 alkenyl group (the alkyl group or alkenyl group may optionally have an alicyclic structure of phenyl group), or a phenyl group, and the remaining substituent or substituents represent a hydrogen atom with formaldehyde; a novel amino composition produced by reacting a mixture of one of or a mixture of more than two of said triazine derivatives and melamine or urea with formaldehyde; and an amino composition comprising a novel amino composition produced by reacting a mixture of one of or a mixture of more than two triazine derivatives with formaldehyde and a melamine-formaldehyde resin and a melamine/urea-formaldehyde resin or a urea-formaldehyde resin.Type: GrantFiled: March 16, 1998Date of Patent: December 7, 1999Assignee: Nissan Chemical Industries, Ltd.Inventors: Makoto Takakura, Hiroyuki Uehara, Keisuke Nakayama, Yuko Furuya
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Patent number: 5895802Abstract: The invention concerns redispersible polymer powders characterized by a proportion of 3 to 30% by wt relative to the polymer weight of condensation products of amino-s-triazine/formaldehyde/sulfite with molar ratios of amino-s-triazine to formaldehyde to sulfite of 1/1.3-6.0/0.3-1.5 and with a low free formaldehyde content. These condensation products of amino-s-triazine/formaldehyde/sulfite are exceedingly effective protective colloids when spray-drying polymer dispersions and can be combined in problem-free manner with casein.Type: GrantFiled: September 21, 1995Date of Patent: April 20, 1999Assignee: SKW Trostberg AktiengescellchaftInventors: Josef Weichmann, Alfred Kern
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Patent number: 5891983Abstract: Water-soluble formaldehyde-free polycondensation products based on amino-s-triazines with at least two amino groups and glyoxylic acid, which contain as further component at least one amino compound and where the molar ratio of amino-s-triazine to glyoxylic acid to amino compound is 1:0.5 to 6.0:0.1 to 2.0. These polycondensation products are excellently suited as additives for aqueous suspensions of inorganic binders, especially cement, lime and gypsum. Building material mixtures which contain these polycondensation products remain workable for a considerably longer time and, in spite of this, also set more quickly.Type: GrantFiled: July 9, 1997Date of Patent: April 6, 1999Assignee: SKW Trostberg AktiengesellschaftInventors: Gerhard Albrecht, Manfred Schuhbeck, Christian Huber, Josef Weichmann, Alfred Kern
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Patent number: 5789526Abstract: Disclosed is a highly viscous condensation product containing sulfonic acid groups based on amino-s-triazines with at least 2 amino groups and formaldehyde which has a viscosity of 500 to 100,000 cp at 20.degree. C. and a pH value of 8.0 to 13.0 as an aqueous solution with a solids content of 20% by weight. The product is obtainable by (a) condensation of amino-s-triazine, formaldehyde and sulfite in a molar ratio of 1:1.9 to 2.9:0.7 to 1.3 in aqueous solution at a pH value of 9.0 to 12.0 and a temperature of 50.degree. to 90.degree. C. until the sulfite is no longer detectable, and (b) subsequent further condensation at a pH value of 2.0 to 5.0 and a temperature of 50.degree. to 100.degree. C. until the viscosity exhibits the desired value.Type: GrantFiled: February 22, 1996Date of Patent: August 4, 1998Assignee: SKW Trostberg AktiengesellschaftInventors: Josef Weichmann, Franz Wolfertstetter, Herbert Winkelmann, Alfred Kern
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Patent number: 5750634Abstract: Disclosed is a soluble polycondensation product based on amino-s-triazines with at least two amino groups and forma ehyde, a process for making the product and the use thereof as an additive for an aqueous binding agent suspension.Type: GrantFiled: March 18, 1996Date of Patent: May 12, 1998Assignee: SKW Trostberg AktiengesellschaftInventors: Gerhard Albrecht, Josef Weichmann, Ludwig Eibl, Christian Huber, Alfred Kern
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Patent number: 5648446Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 30, 1995Date of Patent: July 15, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
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Patent number: 5646240Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: March 21, 1996Date of Patent: July 8, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Jin Suzuki, Kouhei Ohkawa, Hiroshi Ono
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Patent number: 5558709Abstract: Disclosed is a flow improving agent for binder suspensions containing cement which is composed of a) amino-s-triazine-formaldehyde-sulfite condensation products having a molar ratio of amino-s-triazine:formaldehyde:sulfite of 1:1.3 to 6.0: 0.3 to 1.5 and a low content of free formaldehye as well as b) casein. The flow improving agents have the advantage that the flowability is considerably improved compared to casein (alone) for example and the increased flowability remains constant even over a longer time period.Type: GrantFiled: August 22, 1995Date of Patent: September 24, 1996Assignee: SKW TrostbergInventors: Josef Weichmann, Aloisia Stadler, Alfred Kern
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Patent number: 5545702Abstract: Provided by the present invention are novel diguanamine derivatives, led by 2,5/2,6-bis(4,6-diamino-1,3,5-triazin-2-yl)-bicyclo[2.2.1]heptanes and 1,3/1,4-bis(4,6-diamino-1,3,5-triazin-2-yl)-cyclohexanes, and derivatives thereof, applications of these compounds in fields such as adhesives and paints, utilization of these compounds in flame-retarding, thermal stabilization and compatibilization methods of resins, thermosetting molding compositions and thermosetting expansion-molding compositions making use of these compounds, as well as polymeric microspheres also using these compounds. These compounds are expected to find wide spread industrial utility as various excellent properties can be obtained by using them.Type: GrantFiled: October 3, 1995Date of Patent: August 13, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Hiroshi Ozawa, Minato Karasawa, Masamitsu Inomata, Izumi Mega, Atsuyoshi Yamauchi, Kazunori Kamada, Shigeru Nakahata, Katsumi Sakamoto, Tatsunobu Nakashima, Akito Watanabe, Jin Suzuki, Kouhei Ohkawa, Satoshi Furusawa, Hiroshi Ono, Kazuo Sugazaki
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Patent number: 5380815Abstract: Condensation compounds obtained by means of the polymerization of polyami compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.Type: GrantFiled: November 13, 1992Date of Patent: January 10, 1995Assignee: Ministero Dell `Universita` E Della Ricerca Scientifica E TecnologicaInventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
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Patent number: 5328978Abstract: The present invention relates to a triazine/formaldehyde resin which contains a compound of the general formula I ##STR1## wherein R.sup.1 and R.sup.2 are defined as stated in claim 1, a process for its preparation and its use as a curing agent in surface coating systems.Type: GrantFiled: October 28, 1993Date of Patent: July 12, 1994Assignee: Cassella AGInventors: Manfred Schon, Jurgen Ott, Uwe Kubillus, Elif Tas
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Patent number: 5294352Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.Type: GrantFiled: April 15, 1993Date of Patent: March 15, 1994Inventor: John J. Waldmann
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Patent number: 5215828Abstract: Curable binders obtained by simultaneous reaction ofA) urethanes or ureas,B) acrylic or methacrylic compounds containing hydroxyl groups,C) paraformaldehyde andD) if appropriate, polyols,wherein, in the case where no polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger, and in the case where a polyol D) is also reacted, the reaction is carried out in the presence of an acid ion exchanger or a strong acid.These binders are suitable as coating compositions which can be cured by electron beams or by UV light.Type: GrantFiled: August 19, 1992Date of Patent: June 1, 1993Assignee: Hoechst AGInventors: Gerhard Brindoepke, Inge Kurth, Michael Schwab, Gerd Walz
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Patent number: 5162462Abstract: Process for the production of aminoplast resins. The process entailing the addition of ureido-2-diamino-4,6-triazine-1,3,5, and optionally melamine, to aminoplast resin. Preferably the triazine is added in a proportion of at least 10% by weight. The resultant aminoplasts can be used to make panels from particles.Type: GrantFiled: August 20, 1991Date of Patent: November 10, 1992Assignee: Norsolor (Orkem Group)Inventors: Jeanine Barthomieux, Roger Garrigue, Jack Lalo
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Patent number: 5071945Abstract: A process for the production of sulphonic acid group-containing condensation products based on amino-s-triazines with at least two amino groups and formaldehyde with a low content of free formaldehyde, whereina) an amino-s-triazine, formaldehyde and sulphite is condensed in a mole ratio of 1:1.3 to 6:0.3 to 1.5 in aqueous solution at a pH value of 9.0 to 12.0 and at a temperature of 50.degree. to 90.degree. C. until sulphite is no longer detectable.b) subsequently, further condensation is carried out at a pH value of 2.0 to 7.0 and at a temperature of 50.degree. to 90.degree. C. until the viscosity of the solution is 4 to 1000 mm.sup.2 /s at 80.degree. C. andc) thereafter the condensation product is subjected to an after-treatment in a strongly alkaline range of pH.sqroot.11.0 and at an elevated temperature.Type: GrantFiled: August 1, 1990Date of Patent: December 10, 1991Assignee: SKW Trostberg AktiengesellschaftInventors: Josef Weichmann, Manfred Bichler, Alfred Kern, Hans-Gunter Rosenbauer
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Patent number: 5049645Abstract: A continuous preparation method of an amino resin particulate having a maximum particle size of 40 .mu.m or less and an average particle size of from 5 to 15 .mu.m is described. The method comprises the steps of reacting amino compounds with aldehydes in the presence of an acid catalyst in an aqueous solution to form a solid product and classifying said solid product in the form of a slurry with a combination of at least two grinders and at least two classifiers.Type: GrantFiled: March 12, 1990Date of Patent: September 17, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Muneo Nagaoka, Saburo Hayano
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Patent number: 4983710Abstract: A method for the production of methylolaminotriazine condensate by the reaction of cyclohexanecarboguanamine (A) and formaldehyde (B), which method comprises preparing a solution of formaldehyde (B) or a solution containing cyclohexanecarboguanamine (A) and formaldehyde (B) in such amounts that the molar ratio of (A)/(B) will be not more than 1/2.5, keeping the temperature of said solution in the range of 55.degree. to 150.degree. C. and, at the same time, gradually supplying cyclohexanecarboguanaimine (A) thereto.Type: GrantFiled: August 10, 1989Date of Patent: January 8, 1991Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Hidetaka Yatagai, Jiro Iriguchi, Souichi Yamada, Tsuguo Takaya
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Patent number: 4931536Abstract: Hydroxy functional acrylamido amino resins comprising hydroxy-hydrocarbyl groups. The resins are produced by reaction of alkoxymethyl amino resins with acrylamide to introduce acrylamidomethyl groups and then with a polyol to introduce hydroxy functionality. The hydroxy functional acrylamido amino resins may be epoxidized to form polyglycidamides which can then be formulated with epoxy reactants to provide curable epoxy systems.Type: GrantFiled: May 27, 1988Date of Patent: June 5, 1990Assignee: Monsanto CompanyInventor: William F. Pfohl
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Patent number: 4931537Abstract: Curable epoxy systems comprising polyglycidamides and epoxy reactants. The polyglycidamides are hydroxy functional polyglycidamides derived from amino resins. The epoxy systems can be used as laminating, encapsulating and coating resins. When the epoxy reactant is an anhydride, cure under ambient conditions is obtained.Type: GrantFiled: May 27, 1988Date of Patent: June 5, 1990Assignee: Monsanto CompanyInventor: William F. Pfohl
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Patent number: 4764585Abstract: Cationic fixing agents based on the reaction products of(a) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups and(b) cyanamide, dicyandiamide, guanidine or bisguanidinegive improved results when the reaction takes place in the presence of a catalyst (K) selected from metals, metal salts and heterocyclic nitrogen-containing organic bases, particularly zinc chloride.Type: GrantFiled: September 15, 1987Date of Patent: August 16, 1988Assignee: Sandoz Ltd.Inventors: Jurg Heller, Bruno Kissling, Curt Muller, Tibor Robinson, Salvatore Valenti
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Patent number: 4696959Abstract: A composition of matter contains as a principal component a material which acts as an ultraviolet light stabilizer. The ultraviolet light stabilizer is formed from the reaction of (a) a methylol or alkoxy alkyl-containing material, and (b) an alkyl substituted piperidine containing material which is represented by the following structural formula: ##STR1## R" is hydrogen or C.sub.1 to C.sub.6 alkyl, R.sub.10 is hydrogen or methyl,Y is a radical derived from a material selected from the group consisting of amino substituted triazines, ureas, glycolurils, phenols, and amides of the formula ##STR2## R' is hydrogen or C.sub.1 to C.sub.12 alkyl and R is an aliphatic, cycloaliphatic, or olefinic radical, or an acrylic polymer moiety having at least one group selected from hydroxyl, carboxyl, amido, and ureido, said reaction proceeding between a methylol or alkoxy alkyl group of (a) and the group selected from hydroxyl, carboxyl, amido and ureido of (b).Type: GrantFiled: September 26, 1983Date of Patent: September 29, 1987Assignee: PPG Industries, Inc.Inventors: Wen-Hsuan Chang, Michael M. Chau, Robert Piccirilli
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Patent number: 4677159Abstract: Stable, water soluble, sulfonated melamine-formaldehyde and sulfonated melamine-urea-formaldehyde resin solutions are prepared in a four stage procedure, wherein (1) melamine or melamine and urea are condensed with formaldehyde in an aqueous medium at a relative low temperature and a pH of 10-13, followed by (2) the addition of a sulfonating agent, such as sodium metabisulfite, and continued reaction without pH adjustment, followed by (3) lowering the temperature of the reaction medium to 40.degree.-60.degree. C., adjusting the pH to 2.5-4 and continuing the reaction for about 5-150 minutes, and finally followed by (4) adjusting the pH to 6.5-9, heating the reaction medium to 70.degree.-100.degree. C. for 30-180 minutes, adjusting the final solids content to a predetermined value, such as 20%, and adjusting the pH to 8-11. The resulting aqueous solutions are suitable for use as superplasticizer additives to hydraulically settable cementitious materials.Type: GrantFiled: October 16, 1985Date of Patent: June 30, 1987Assignee: Kuwait Institute for Scientific ResearchInventors: Shawqui Lahalih, Ma'mun Absi-Halabi
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Patent number: 4668785Abstract: N,N',N"-tris-(2-hydroxyethyl)-melamine, if required, as a mixture with N-mono- and N,N'-bis-(2-hydroxyethyl)-melamine, is prepared by reacting melamine with ethanolamine in the presence of an acidic catalyst by a method in which the reaction is carried out at from 120.degree. to 250.degree. C. using an excess of ethanolamine, and the molar ratio of free ethanolamine to the sum of free and converted melamine is not permitted to fall below 4:1 during the entire reaction time, and the stated (2-hydroxyethyl)-melamines are used as modifiers in the prepartion of aminoplast resins which are suitable for laminating surfaces.Type: GrantFiled: June 13, 1985Date of Patent: May 26, 1987Assignee: BASF AktiengesellschaftInventors: Klaus Ebel, Wolfgang Reuther, Wolfram Weiss, Ludwig Lelgemann
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Patent number: 4663387Abstract: Thermally stable water soluble resins are prepared in a multistep process by reacting the waste solids from the mother liquor waste stream of a melamine manufacturing plant with an aldehyde and a sulfonating agent under controlled conditions of pH and temperature. The resin compositions are useful, for example, as superplasticizing agents for concrete mixtures, as mud drilling additives, and in the paper and textile industry. The process not only provides useful resin compositions, but also recovers solid wastes which are considered to be a major contributor to the pollution problems of melamine manufacturing plants.Type: GrantFiled: April 2, 1985Date of Patent: May 5, 1987Assignee: Kuwait Institute for Scientific ResearchInventors: Shawqui Lahalih, Ma'mun Absi-Halabi
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Patent number: 4631320Abstract: A thermosettable coating composition comprises a hydroxy group-containing polyurethane, polyurea or polyurethane/polyurea polymer, an amino cross-linker and optionally, a catalyst and/or solvent. The polymer is obtained by self condensation of an hydroxyalkyl carbamate compound or condensation of such compound with a polyol and/or a polyamine. An applied coating of the composition is cured by heating to an elevated temperature, e.g., from about 200.degree. to about 400.degree. F. (about 93.degree. to 204.degree. C.).Type: GrantFiled: February 17, 1984Date of Patent: December 23, 1986Assignee: American Cyanamid CompanyInventors: Girish G. Parekh, Werner J. Blank
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Patent number: 4591613Abstract: A method for the production of hydroxyalkylmelamine containing resins wherein melamine, formaldehyde and a hydroxyalkylmelamine are reacted under conditions such that a resin is produced which, when incorporated into a decorative laminate, enhances the post-forming thereof, the resin per se, paper sheets containing said resin, a method for the production of laminates and the laminates per se, are disclosed.Type: GrantFiled: April 26, 1985Date of Patent: May 27, 1986Assignee: American Cyanamid CompanyInventors: Fouad T. Karam, Jack I. Sibalis
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Patent number: 4578450Abstract: There is disclosed the reaction product of an N-(substituted oxymethyl)melamine and a 2-mercaptoarylthiazole and its use as an adhesion promoter to improve rubber to metal wire adhesion.Type: GrantFiled: September 4, 1984Date of Patent: March 25, 1986Assignee: The Goodyear Tire & Rubber CompanyInventor: William W. Schloman, Jr.
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Patent number: 4564667Abstract: A solid urea-formaldehyde resin is provided, having a degree of condensation of 25% to 45%.A process for making the resin is also described and includes several steps. Urea and formaldehyde is first reacted with a molar ratio of U:F of 1:2.5 or more then concentrated. Further urea is added to reduce the ratio to the range 1:1.1 to 1:2 and further concentration is achieved without precipitation of solid resin by the use of a stabilization agent.Type: GrantFiled: February 22, 1985Date of Patent: January 14, 1986Assignee: BIP Chemicals LimitedInventor: David Taylor
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Patent number: 4489027Abstract: A process for preparing a thermoplastic poly(imidesulfone) is disclosed. This resulting material has thermoplastic properties which are generally associated with polysulfones but not polyimides, and solvent resistant which is generally associated with polyimides but not polysulfones. This system is processable in the 250.degree.-350.degree. C. range for molding, adhesive and laminating applications. This unique thermoplastic poly(imidesulfone) is obtained by incorporating an aromatic sulfone moiety into the backbone of an aromatic linear polyimide by dissolving a quantity of a 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) in a solution of 3,3'-diaminodiphenylsulfone and bis(2-methoxyethyl)ether, precipitating the reactant product in water, filtering and drying the recovered poly(amide-acid sulfone) and converting it to the poly(imidesulfone) by heating.Type: GrantFiled: May 6, 1983Date of Patent: December 18, 1984Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Terry L. St. Clair, David A. Yamaki
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Patent number: 4475918Abstract: Aftertreatment of dyeings on cotton or nylon with (A) a polybasic compound which is the product of reacting a primary or secondary amine with cyanamide, dicyandiamide, guanidine or biguanidine and, sequentially or simultaneously (B) a precondensate formed by reacting a compound of type (A) with an N-methylol derivative gives wet fastness properties superior to those given by either (A) or (B) used alone.Type: GrantFiled: August 24, 1983Date of Patent: October 9, 1984Assignee: Sandoz Ltd.Inventors: Bruno Kissling, Tibor Robinson
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Patent number: 4451620Abstract: Diethanolammonium sulphamate is a curing agent for modified aminoplast resins.Type: GrantFiled: May 5, 1983Date of Patent: May 29, 1984Assignee: Cassella AktiengesellschaftInventors: Steffen Piesch, Peter Dorries
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Patent number: 4443223Abstract: The fastness of direct dyes on cellulose substrates is improved by after-treatment with the reaction product of a quaternary polyalkylene polyamine with an N-methylol resin precursor, and heat curing in the presence of a catalyst. The unfixed portion of reactive dyes substantive to cellulose may also be given improved wet and light fastness by this treatment.Type: GrantFiled: August 30, 1982Date of Patent: April 17, 1984Assignee: Sandoz Ltd.Inventors: Bruno Kissling, Walter Knobel, Tibor Robinson
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Patent number: 4382873Abstract: Dispersant and biodegradant formulations are manufactured by admixing at least one melamine derivative with at least one compound having a hydroxy function, at least one phosphorus compound and at least one surfactive agent. Aqueous emulsions obtained from these formulations are also provided.Type: GrantFiled: December 19, 1980Date of Patent: May 10, 1983Assignee: Institut Francais du PetroleInventors: Claude Gatellier, Andree Plessis, Patrick Gateau, Jean-Pierre Durand
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Patent number: 4365053Abstract: A thermosetting synthetic crosslinking resin containing selected ethers of the reaction product of an isoadipoguanamine mixture and formaldehyde can be incorporated into a variety of coating compositions to provide finishes that are characterized by hardness, flexibility, durability, excellent adhesion, and commercially-acceptable cure temperatures.Type: GrantFiled: August 8, 1980Date of Patent: December 21, 1982Assignee: E. I. Du Pont de Nemours and CompanyInventor: Francis E. Schweitzer
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Patent number: 4351935Abstract: A thermosetting coating composition contains an acid-curable amino resin and from 0.1 to 10 percent by weight of a blocked sulphonic acid calculated on the weight of amino resin. In order to reduce the electric conductivity of the composition after a prolonged pot-life, a sulphonic acid oximate is used as the blocked acid.The compositions are advantageous for coating a substrate by electrostatic spraying.Type: GrantFiled: July 14, 1981Date of Patent: September 28, 1982Assignee: Akzo N.V.Inventors: Johan B. Reesink, Hendrik J. Hageman, Ulfert E. Wiersum
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Patent number: 4349660Abstract: A process for the production of an air-drying, modified amino-resin, which process comprises co-polycondensing one or more dialkyl ether compounds, which are dialkyl ether of the dimethylol derivatives of compounds containing two primary amido groups or similar groups, with at least one compound containing an auto-oxidative group, or polycondensing the said one or more dialkyl ether compounds and reacting the compound containing an auto-oxidative group with the condensate; the alcohol released being removed from the mixture. The auto-oxidative groups are typically supplied by allyl ethers and the dialkyl ether compound is e.g. bismethoxymethylene urea. The modified resins rapidly form hard films when exposed to atmospheric oxygen in the presence of drying agents.Type: GrantFiled: December 8, 1980Date of Patent: September 14, 1982Assignee: Kemira OyInventor: Hannu J. Toivonnen
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Patent number: 4316005Abstract: A cationic adsorption agent which is obtained by reaction of(a) an amino compound which contains at least one amino group and at least one free or methylolated carboxamide group, with(b) an aminoplast precondensate which does not contain amino groups.The novel adsorption agent is suitable in particular for removing anionic substances, such as acid dyes or reactive dyes, from aqueous solutions, especially from wastewaters.Type: GrantFiled: June 23, 1980Date of Patent: February 16, 1982Assignee: Ciba-Geigy CorporationInventors: Rudolf F. Wurster, Jurg Merz