Nonaldehyde Or Nonaldehyde Derivative Heterocyclic Reactant Contains A Six Membered Ring Having Three Nitrogen And Three Carbon Atoms As Ring Members Patents (Class 528/254)
Sulfur-containing heterocyclic compound having three nitrogen and three carbon atoms (Class 528/255)
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Patent number: 10947335Abstract: The present invention relates to a triazine-precondensate-aldehyde condensation product obtainable by reacting a) at least one triazine compound of the general formulae (I), b) at least one aldehyde, and c) at least one triazine precondensate of the general formula (II). A method for obtaining a condensation product and a wood based panel are also disclosed.Type: GrantFiled: June 28, 2017Date of Patent: March 16, 2021Assignee: Borealis Agrolinz Melamine GmbHInventors: Herbert Gabriel, René Dicke, Helmut Puchinger
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Patent number: 10179829Abstract: This invention relates to products H made by reaction of a cyclic alkyleneurea U, at least one multifunctional aldehyde A2, and at least one of (a) an aminoplast former M that is not the same as the cyclic alkyleneurea U, and (b) a monofunctional aldehyde A1, which product H is optionally etherified by reaction of at least a part of the hydroxyl groups formed by addition reaction of N—H groups and aldehyde groups, with an alcohol having from one to ten carbon atoms, and wherein glyoxal is present in the at least one multifunctional aldehyde A2, to processes for their preparation, and to a method of use thereof in coating compositions.Type: GrantFiled: November 18, 2016Date of Patent: January 15, 2019Assignee: Allnex Netherlands B.V.Inventors: Ram B. Gupta, Urvee Y. Treasurer, Lawrence A. Flood, Barry A. Lawless
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Patent number: 9796805Abstract: This invention relates to aminoplast crosslinker resins compositions based on at least partially alkylated reaction products A of melamine, formaldehyde and an alkanol with the following parameters: the ratio of the amount of substance n(CH2O) of combined formaldehyde to the amount of substance n(Mel) of melamine is in the range of from 5.6 mol/mol to 6.2 mol/mol, the ratio of the amount of substance n(RO) of alkyl ether groups in the crosslinker resin to the amount of substance n(Mel) of melamine is in the range of from 5.0 mol/mol to 5.6 mol/mol, the mass fraction of monomer in the resin, calculated as the ratio of the mass of monomer m(1) to the mass m(A) of the reaction products A is between 35% and 55%, to a process for their preparation, and to a method of use thereof as crosslinker in combination with hydroxy-functional polymers for coating of heat-sensitive substrates.Type: GrantFiled: October 21, 2012Date of Patent: October 24, 2017Assignees: ALLNEX AUSTRIA GMBH, ALLNEX IP S.A.R.L.Inventors: Lon-Tang Wilson Lin, Kuang-Jong Wu, Katsumi Inagaki, Johann Billiani
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Patent number: 8969489Abstract: The invention is a thermosetting coating composition comprised of an aliphatic polycarbonate resin and a cross linker. The aliphatic polycarbonate resins are derived from hydroxyl containing compounds including 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) and 1,4-cyclohexane dimethanol (CHDM). The coatings made of these polycarbonates exhibit exceptional toughness; they possess a high degree of hardness while maintaining a high level of flexibility/impact resistance. These polycarbonate resins also exhibited better hydrolytic stability as compared to their polyester counterparts.Type: GrantFiled: August 8, 2011Date of Patent: March 3, 2015Assignee: Eastman Chemical CompanyInventors: Jianhui Zhou, Angela Jones Johnson
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Publication number: 20140326672Abstract: Described herein is a melamine-aldehyde polymer, wherein the polymer has a pore volume in the range of about 1.5 to 5 cm3/g.Type: ApplicationFiled: November 29, 2012Publication date: November 6, 2014Inventors: Yugen Zhang, Mei Xuan Tan, Jackie Y. Ying
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Publication number: 20140302241Abstract: This invention relates to aminoplast crosslinker resins compositions based on at least partially alkylated reaction products A of melamine, formaldehyde and an alkanol with the following parameters: the ratio of the amount of substance n(CH2O) of combined formaldehyde to the amount of substance n(Mel) of melamine is in the range of from 5.6 mol/mol to 6.2 mol/mol, the ratio of the amount of substance n(RO) of alkyl ether groups in the crosslinker resin to the amount of substance n(Mel) of melamine is in the range of from 5.0 mol/mol to 5.6 mol/mol, the mass fraction of monomer in the resin, calculated as the ratio of the mass of monomer m(1) to the mass m(A) of the reaction products A is between 35% and 55%, to a process for their preparation, and to a method of use thereof as crosslinker in combination with hydroxy-functional polymers for coating of heat-sensitive substrates.Type: ApplicationFiled: October 21, 2012Publication date: October 9, 2014Inventors: Lon-Tang Wilson Lin, Kuang-Jong Wu, Katsumi Inagaki, Johann Billiani
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Patent number: 8829150Abstract: The present invention discloses methods for polymerizing non-immunogenic haptens into immunogens, which then can be used to stimulate anti-hapten antibody production in animals. Specifically, haptens with amine and/or carboxylic groups are polymerized into macromolecules by using cross-linking reagents, and the derived haptenic polymers are used to immunize animals for the production of anti-hapten antibodies.Type: GrantFiled: September 19, 2013Date of Patent: September 9, 2014Assignee: National Taiwan Normal UniversityInventors: Che-Hsiung Lin, Yu-Chie Wang
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Patent number: 8802848Abstract: The present invention relates to Melamine based Mannich compounds of the general formulae (1)-(12) and a process for synthesizing melamine based Mannich-products comprising the steps of a) reacting at least one substituted melamine with at least one aldehyde, in particular formaldehyde, under basic conditions to form at least one OH-containing compound, b) reacting the at least one OH-containing compound in the presence of a catalyst to form at least one mannich-base, c1) reacting the at least one mannich-base with at least one enol-forming carbonyl compound, or c2) reacting the at least one mannich-base with at least one aromatic compound, and d) working up the reaction mixture. The invention relates further to precondensates obtainable from these products.Type: GrantFiled: November 17, 2010Date of Patent: August 12, 2014Assignee: Borealis Agrolinz Melamine GmbHInventors: René Dicke, Christoph Hahn, Martin Burger, Andreas Endesfelder, Katarina Rot, Clemens Schwarzinger, Klaus Bretterbauer, Heinrich Trischler, Harald Schmidt
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Patent number: 8748557Abstract: The present invention relates to an extreme low formaldehyde emission UF resin with a novel structure, and a process for its preparation. This UF resin is produced from formaldehyde, urea, a long chain multi-aldehyde prepolymer, and some modifiers. Its process follows three steps: weak caustic, weak acid and weak caustic. By using this prepolymer, the modified UF resin has stable alkyl ether structure, and the residual aldehyde groups on the UF polymer chain could accelerate cross-linking instead of dissociative formaldehyde. The UF resin made from this invention has extreme low dissociative formaldehyde and simple technology. The boards produced from this resin have good physical performance and water resistance. Moreover, the formaldehyde emission of the boards is extreme low, achieving Japan F???? grade, the average emission value ?0.3 mg/L.Type: GrantFiled: August 29, 2011Date of Patent: June 10, 2014Assignee: Beijing University of Chemical TechnologyInventors: Xiao-Yu Li, Jun Ye, Hai-Qiao Wang, Teng Qiu
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Patent number: 8741430Abstract: Amino-formaldehyde resins may be prepared using formulations including formaldehyde, glycerin and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof; under reaction conditions sufficient to prepare a resin, wherein; the amino-formaldehyde resin is prepared in a substantial absence of a sulfonating agent, ethylene glycol, and polyalkylene glycols. If the amino compound is urea, then the urea is present in a molar ratio of formaldehyde to urea ranging from 0.70 to 1.30; if the amino compound is melamine, then the melamine is present in a molar ratio of formaldehyde to melamine ranging from 1.3 to 2.2; and if the amino compound is a mixture of urea and melamine, then the mixture of urea and melamine is present in a molar ratio of formaldehyde to urea and melamine ranging from 0.35 to 1.3.Type: GrantFiled: June 25, 2008Date of Patent: June 3, 2014Assignee: Momentive Specialty Chemicals Inc.Inventors: Byung Young No, David M. Harmon, Todd R. Miller
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Publication number: 20140088286Abstract: The present invention discloses methods for polymerizing non-immunogenic haptens into immunogens, which then can be used to stimulate anti-hapten antibody production in animals. Specifically, haptens with amine and/or carboxylic groups are polymerized into macromolecules by using cross-linking reagents, and the derived haptenic polymers are used to immunize animals for the production of anti-hapten antibodies.Type: ApplicationFiled: September 19, 2013Publication date: March 27, 2014Applicant: National Taiwan Normal UniversityInventors: Che-Hsiung LIN, Yu-Chie WANG
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Patent number: 8541517Abstract: Stable, high performance polymer compositions including polybenzimidazole (PBI) and a melamine-formaldehyde polymer, such as methylated, poly(melamine-co-formaldehyde), for forming structures such as films, fibers and bulky structures. The polymer compositions may be formed by combining polybenzimidazole with the melamine-formaldehyde polymer to form a precursor. The polybenzimidazole may be reacted and/or intertwined with the melamine-formaldehyde polymer to form the polymer composition. For example, a stable, free-standing film having a thickness of, for example, between about 5 ?m and about 30 ?m may be formed from the polymer composition. Such films may be used as gas separation membranes and may be submerged into water for extended periods without crazing and cracking. The polymer composition may also be used as a coating on substrates, such as metal and ceramics, or may be used for spinning fibers. Precursors for forming such polymer compositions are also disclosed.Type: GrantFiled: March 10, 2011Date of Patent: September 24, 2013Assignee: Battelle Energy Alliance, LLCInventors: John R. Klaehn, Eric S. Peterson, Christopher J. Orme
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Patent number: 8178627Abstract: Provided is an oxymethylene copolymer composition for a stretched material having a high strength and a high elastic modulus, the composition including: an oxymethylene copolymer; and a crosslinkable compound to be blended with the oxymethylene copolymer in an amount of 0.001 to 0.05 part by mass with respect to 100 parts by mass of the oxymethylene copolymer. The present invention also relates to a stretched material obtained by using the oxymethylene copolymer composition. Further, the present invention relates to a structure obtained by the secondary processing of the above stretched material, and a structure obtained by using the above oxymethylene copolymer composition in a bonding layer of the structure. The present invention also relates to a method of producing a structure, the method including: using the oxymethylene copolymer composition in a bonding layer of the structure; and removing a polyalkylene glycol component with water or a solvent.Type: GrantFiled: December 3, 2007Date of Patent: May 15, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Akira Okamura, Satoshi Nagai
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Publication number: 20120115994Abstract: Methods for making and using amino-aldehyde resins. The method for making an amino-aldehyde resin can include mixing an intermediate amino-aldehyde reaction product having a total aldehyde compound to total amino compound molar ratio ranging from about 1.4:1 to about 3:1 with a first aldehyde compound and a first amino compound to produce an amino-aldehyde resin having a total aldehyde compound to total amino compound molar ratio ranging from about 0.5:1 to about 1.2:1. The concentration of the first aldehyde compound mixed with the intermediate reaction product can be about 1.9 wt % or more based on a combined solids weight of the aldehyde compounds and the amino compounds in the amino-aldehyde resin.Type: ApplicationFiled: November 9, 2011Publication date: May 10, 2012Applicant: GEORGIA-PACIFIC CHEMICALS LLCInventors: Robert A. Breyer, Richard M. Rammon, Clinton L. Mills
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Patent number: 8119700Abstract: Disclosed is an organic aerogel including a polymer obtained from reaction an aryl alcohol compound, an aldehyde compound, and a polyol compound, a composition for forming the same, and a method of preparing the same.Type: GrantFiled: September 3, 2009Date of Patent: February 21, 2012Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-Ho Park, Myung-Dung Cho, Kwang-Hee Kim, Sung-Woo Hwang
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Patent number: 8114953Abstract: The invention relates to melamine-formaldehyde condensates with thermoplastic properties that can be produced from formaldehyde and melamine derivatives, wherein at least one of the melamine derivatives organic radicals R have been used to substitute at least four of the total of six hydrogen atoms of the three melamine amino groups, and wherein the organic radicals R are mutually identical or different. The invention also relates to a process for production of the melamine-formaldehyde condensates, use thereof, and an analytical method for determining the constitution of the melamine-formaldehyde condensates.Type: GrantFiled: February 22, 2007Date of Patent: February 14, 2012Assignee: AMI Agrolinz Melamine International GmbHInventors: Helmut Puchinger, Andreas Endesfelder, Martin Burger, Clemens Schwarzinger, Manuela Leidl, Werner Huber, Harald Schmidt
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Patent number: 7989575Abstract: A composition is disclosed, which comprises a hydroxyaromatic-aldehyde resole resin comprising an aldehyde and a hydroxyaromatic compound, modified with a urea-aldehyde condensate. The hydroxyaromatic-aldehyde resole resin is prepared without ammonia or a primary amine and the composition does not contain a triazone or a substituted triazone compound. The composition has improved premix stability, improved cure efficiency, comparable tensile strength, and lower volatiles than the hydroxyaromatic-aldehyde resole resin unmodified with a urea-aldehyde condensate. Also disclosed are articles prepared therefrom.Type: GrantFiled: December 14, 2007Date of Patent: August 2, 2011Assignee: Momentive Specialty Chemicals Inc.Inventor: Stephen W. Arbuckle
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Publication number: 20110014487Abstract: A system and method for the continuous production of an aqueous amino formaldehyde resin solution including the steps of (a) preparing a reaction mixture of an amino compound and an aqueous formaldehyde, (b) adding a catalyst to the reaction mixture, (c) condensation reacting the reaction mixture in the presence of the catalyst in a continuous plug flow, wherein in step (a) the amino compound and the formaldehyde are added as a concentrated aqueous solution or as a solid to a total solid content in the reaction mixture of 40-85 wt % (dry weight relative to the total weight of the reaction mixture), and in step (b) the catalyst is continuously added and finely dispersed into the reaction mixture through one or more addition points and optionally adding an amount of amino compound after condensation and/or removing water to reach a higher solid content.Type: ApplicationFiled: June 21, 2010Publication date: January 20, 2011Applicant: Dynea OYInventors: Michael GANN, Marianne Tveter
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Publication number: 20100273975Abstract: Disclosed herein is a polyol (A) based on modified amino resins, prepared by reacting: an amino resin (B) comprising three acetalized or etherified N-methylol groups of the general formula (I)>N—CHR—OR1, wherein R is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or an aryl group of 6 to 10 carbon atoms and R1 is an alkyl group of 1 to 6 carbon atoms; with a polyol (C) of the general formula (II) R2(—OH)n, wherein n is a number from 2 to 6 and R2 is a divalent to hexavalent organic radical; wherein an equivalent ratio of the acetalized or etherified N-methylol groups to the polyol (C) is 0.5:1 to 1.2:1; with elimination of at least 50 mol % of a monoalcohol (D) of the general formula R1—OH, wherein R1 is as defined above, from the amino resin (B).Type: ApplicationFiled: February 9, 2007Publication date: October 28, 2010Applicant: BASF COATINGS AKTIENGESELLSCHAFTInventors: Gunther Ott, Ulrike Rockrath, Bjorn Feldmann, Ulrike Clausen-Meiring, Karl-Heinz Joost
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Publication number: 20100113693Abstract: The invention relates to a process for preparing polymethylolated melamine and polymethylolated melamine compounds polyetherified with alkanol, wherein the methylolation reaction is carried out in a kneading reactor.Type: ApplicationFiled: January 13, 2005Publication date: May 6, 2010Applicant: BASF AktiengesellschaftInventors: Jörg Schneider, Günter Scherr, Rainer Erhardt, Andreas Eichfelder, Martin Reif, Stefan Hirsch, Hans Schupp, Christel Hittinger, Alain Robert
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Publication number: 20090326166Abstract: Amino-formaldehyde resins may be prepared using formulations including formaldehyde, glycerin and at least one amino compound selected from the group consisting of urea, melamine, and mixtures thereof; under reaction conditions sufficient to prepare a resin, wherein; the amino-formaldehyde resin is prepared in a substantial absence of a sulfonating agent, ethylene glycol, and polyalkylene glycols. If the amino compound is urea, then the urea is present in a molar ratio of formaldehyde to urea ranging from 0.70 to 1.30; if the amino compound is melamine, then the melamine is present in a molar ratio of formaldehyde to melamine ranging from 1.3 to 2.2; and if the amino compound is a mixture of urea and melamine, then the mixture of urea and melamine is present in a molar ratio of formaldehyde to urea and melamine ranging from 0.35 to 1.Type: ApplicationFiled: June 25, 2008Publication date: December 31, 2009Inventors: Byung Young No, David M. Harmon, Todd R. Miller
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Patent number: 7595116Abstract: A process for improving the durability, dimensional stability and surface hardness of a wood body is described, in which an untreated wood body is impregnated with an aqueous solution of A) an impregnating agent from the group consisting of 1,3-bis(hydroxymethyl)-4,5-dihydroxyimidazolidin-2-one, 1,3-bis(hydroxymethyl)-4,5-dihydroxyimidazolidin-2-one modified with a C1-5-alcohol, a polyol or mixtures thereof, 1,3-dimethyl-4,5-dihydroxyimidazolidin-2-one, dimethylolurea, bis(methoxymethyl)urea, tetramethylolacetylenediurea, 1,3-bis(hydroxymethyl)imidazolidin-2-one, methylolmethylurea or mixtures thereof and B) a catalyst from the group consisting of metal or ammonium salts, organic or inorganic acids and mixtures thereof, and wood and impregnating agent are then caused to react while maintaining humid conditions at elevated temperature.Type: GrantFiled: October 1, 2003Date of Patent: September 29, 2009Assignee: BASF AktiengesellschaftInventors: Andreas Krause, Holger Militz
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Publication number: 20090239978Abstract: The invention relates to melamine resin, wherein it is, in essence, linearly synthesized and is dependent upon the viscosity of the rate of shear. The invention also relates to a method for producing the melamine resin and to the use thereof.Type: ApplicationFiled: June 19, 2006Publication date: September 24, 2009Applicant: AMI AGROLINZ MELAMINE INTERNATIONAL GMBHInventors: Steffen Pfeiffer, Werner Deutschbauer, Roland Raninger
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Publication number: 20090163694Abstract: The invention relates to a process for the continuous production of an aqueous amino formaldehyde resin solution, preferably melamine formaldehyde resin (MF) or urea formaldehyde resin (UF), comprising the steps of a) preparing a reaction mixture of an amino compound and an aqueous formaldehyde, b) adding a catalyst to the reaction mixture, and c) condensation reacting the reaction mixture in the presence of the catalyst, wherein in step a) the amino compound and the formaldehyde are added as a concentrated aqueous solution or as a solid to a total solid content in the reaction mixture of 40-85 wt % (dry weight relative to the total weight of the reaction mixture), wherein in step c) the condensation reaction takes place in a continuous plug flow of the reaction mixture and wherein in step b) the catalyst is continuously added and finely dispersed into the reaction mixture through one or more addition points.Type: ApplicationFiled: December 21, 2007Publication date: June 25, 2009Inventor: Michael Gann
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Publication number: 20090098805Abstract: An abrasive product includes a plurality of abrasive particles and a resin binder cured from a resin composition that includes an aqueous dispersion of melamine methylol having a melamine-to-formaldehyde molar equivalent ratio of between about 1:1 and about 1:3.2, wherein the aqueous dispersion has a pH in a range of between about 8 and about 10. The composition also includes a formaldehyde-based resins, such as a urea-formaldehyde resin or phenol-formaldehyde resin. The melamine methylol comprises between about 1 wt % and about 50 wt % of the combined weight of the formaldehyde-based resin and the melamine methylol.Type: ApplicationFiled: September 19, 2008Publication date: April 16, 2009Applicants: Saint-Gobain Abrasives, Inc., Saint-Gobain AbrasifsInventors: Abdul Habid Pullichola, Adiseshaiah K. Seshu, Kottotil Mohan Das
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Publication number: 20090099323Abstract: A melamine-formaldehyde resin solution having a formaldehyde/melamine ratio smaller than or equal to 1.5, at which it possesses a water compatibility ranging from 0.15 to 4.0 at 20° C., and a stability of at least 5 hours at a F/M ratio of 1.0, a stability of at least 6 hours at a F/M ratio of 1.1, a stability of at least 13 hours at a F/M ratio of 1.2, a stability of at least 24 hours at a F/M ratio of 1.3, a stability of at least 50 hours at a F/M ratio of 1.4, and a stability of at least 200 hours at a F/M ratio of 1.5, the stability of the resin solution being linearly dependent, within the range boundaries 1.0<F/M<1.1, 1.1<F/M<1.2, 1.2<F/M<1.3, 1.3<F/M<1.4, 1.4<F/M<1.5, upon the stabilities of the corresponding F/M range boundaries.Type: ApplicationFiled: May 10, 2006Publication date: April 16, 2009Applicant: AMI-AGROLINZ MELAMINE INTERNATIONAL GMBHInventors: Frank Schroder, Christian Furst, Daniel Jocham, Oliver Katzenberger, Katarina Rot, Johannes Fellner
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Publication number: 20090054616Abstract: The invention relates to melamine-formaldehyde condensates with thermoplastic properties that can be produced from formaldehyde and melamine derivatives, wherein at least one of the melamine derivatives organic radicals R have been used to substitute at least four of the total of six hydrogen atoms of the three melamine amino groups, and wherein the organic radicals R are mutually identical or different. The invention also relates to a process for production of the melamine-formaldehyde condensates, use thereof, and an analytical method for determining the constitution of the melamine-formaldehyde condensates.Type: ApplicationFiled: February 22, 2007Publication date: February 26, 2009Applicant: AMI AGROLINZ MELAMINE INTERNATIONLA GMBHInventors: Helmut Puchinger, Andreas Endesfelder, Martin Burger, Clemens Schwarzinger, Manuela Leidl, Werner Huber, Harald Schmidt
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Patent number: 7494718Abstract: A process for the production of a wood body having increased surface hardness, in which an untreated wood body is impregnated with an aqueous solution of A) an impregnating agent consisting of a 1,3-bis(hydroxymethyl)-4,5-dihydroxyimidazolidin-2-one modified with a C1-5-alcohol, a polyol or mixtures thereof, and B) a catalyst from the group consisting of ammonium or metal salts, organic or inorganic acids or mixtures thereof, dried and then hardened at elevated temperature is described.Type: GrantFiled: October 1, 2003Date of Patent: February 24, 2009Assignee: BASF AktiengesellschaftInventors: Andreas Krause, Holger Militz
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Patent number: 7399529Abstract: Resin compositions, methods of forming such resin compositions, methods of using such resin compositions and substrates treated with such resin compositions are disclosed. One of such resin compositions contains no formaldehyde and is useful as a binder. Such resin composition comprises the reaction product of: a—melamine, b—at least one aldehyde of formula (1) as defined in the specification, c—a cross linking agent, wherein the cross linking agent is glyoxylic acid, and d—at least one polyol having 2 or more than 2 hydroxyl groups. The resin composition of the present invention can provide performance characteristics to which they are applied.Type: GrantFiled: December 15, 2006Date of Patent: July 15, 2008Assignee: Clariant (France)Inventors: Gregory J. Hopkins, William C. Floyd
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Publication number: 20080114097Abstract: The invention relates to an aqueous impregnating resin solution containing (A) between 77.5 and 99.8 wt. %, in relation to the impregnating resin solution, of aqueous condensates based on melamine and formaldehyde; (B) between 0.1 and 20 wt. %, in relation to the impregnating resin solution, of at least one specific quaternary ammonium compound; and (C) between 0.1 and 2.5 wt. %, in relation to the impregnating resin solution, of an aqueous hardener solution. The invention also relates to an aqueous impregnating resin solution consisting of constituents (A) and (B), and to an aqueous hardener mixture consisting of constituents (B) and (C). The invention further relates to an impregnating resin film containing fibrous substances containing cellulose and impregnated with the aqueous impregnating resin solution, and to the use of the aqueous impregnating resin solution, or impregnating resin film, for the antistatic finishing of coated materials.Type: ApplicationFiled: October 6, 2005Publication date: May 15, 2008Applicant: BASF AktiengesellschaftInventors: Ralph Lunkwitz, Alain Robert, Jakob Decher, Tilo Horstmann, Martin Reif, Christof Jackh
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Patent number: 7354987Abstract: The invention relates to a compound of formula I: where: X is equal to NR5; R4 is equal to a C1-C12 alkyl group, aryl group, aralkyl group or cycloalkyl group. R1, R2, R3, R5 are equal to an H, alkyl, cycloalkyl, aryl of heterocyclic group; where R1, R2, and R5 or R1, R2, and R3 may together form a heterocyclic group. The invention also relates to a method for the preparation of this compound by reaction of an amino compound with an alkanol hemiacetal. The invention also relates to amino-aldehyde resins containing this compound and the application of these resins in adhesive compositions, laminates, shaped articles and transparent coatings.Type: GrantFiled: February 20, 2007Date of Patent: April 8, 2008Assignee: DSM IP Assets B.V.Inventors: Rudolfus Antonius Theodorus Maria Van Benthem, Renier Henricus Maria Kierkels, Jacobus Adriaan Antonius Vermeulen
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Patent number: 7326765Abstract: A melamine ring containing copolymer and a method of manufacturing a melamine ring containing copolymer are described. The method includes mixing melamine and cashew nut shell liquid, heating the mixture, and reacting the mixture for about 4 to 6 hours. The melamine ring containing copolymer can have a dynamic viscosity of about 0.5×104 P to about 3×104 P or a viscosity that continues to increase upon heating.Type: GrantFiled: August 18, 2003Date of Patent: February 5, 2008Assignee: Palmer International, Inc.Inventors: Gregory P. Tzap, Perry Springsted
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Patent number: 7323534Abstract: A composition is disclosed, which comprises a hydroxyaromatic-aldehyde resole resin comprising an aldehyde and a hydroxyaromatic compound, modified with a urea-aldehyde condensate. The composition has improved premix stability, improved cure efficiency, comparable tensile strength, and lower volatiles than the hydroxyaromatic-aldehyde resole resin unmodified with a urea-aldehyde condensate. Also disclosed are articles prepared therefrom.Type: GrantFiled: October 12, 2005Date of Patent: January 29, 2008Assignee: Hexion Specialty Chemicals, Inc.Inventor: Stephen W. Arbuckle
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Publication number: 20080006960Abstract: A melamine utensil and a manufacturing method thereof are disclosed. Melamine powder/granule is mixed with a granular/fragmentary secondary material of melamine that has been hot-pressed in a certain weight ratio to form a composite material. Then through a process of hot pressing, shapes and colors of the granular/fragmentary secondary material of melamine are shown on appearance of the utensil clearly so as to increase decorative effect and added value of the melamine utensils.Type: ApplicationFiled: July 6, 2006Publication date: January 10, 2008Inventor: Kwo-Chin Chen
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Patent number: 7267845Abstract: The present invention provides a crosslinker for organic coatings having an amino resin core with substituents including more than one olefin functional group, a silicon-containing group, and at least one alkoxyalkyl or alkylol group. Coating compositions containing the crosslinker can be cured with radiation, especially ultraviolet radiation. The crosslinker can be included in a coating composition with one or more curable resins, applied onto a substrate and cured to form the cured coating of the invention.Type: GrantFiled: December 22, 2000Date of Patent: September 11, 2007Assignee: BASF CorporationInventors: Swaminathan Ramesh, Paul Lessek, Paul J. Harris
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Patent number: 7214758Abstract: This invention relates to an adhesive composition comprising: an elastomeric latex; a phenol, an aldehyde and an alkylated melamine-formaldehyde resin suitable for use in the adhesion of textile material to rubber. This invention also relates to a method of promoting the adhesion of a textile material to rubber comprising the step of contacting the textile material with an adhesive composition comprising an elastomeric latex; a phenol; an aldehyde; and an alkylated melamine-formaldehyde resin. The adhesive composition of this invention provides equal or better retention of adhesive strength after heat aging.Type: GrantFiled: April 23, 2004Date of Patent: May 8, 2007Assignee: Cytec Technology Corp.Inventor: Andrei Winkler
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Patent number: 7199209Abstract: The invention relates to a compound of formula I: where: X is equal to NR5; R4 is equal to a C1–C12 alkyl group, aryl group, aralkyl group or cycloalkyl group, R1, R2, R3, R5 are equal to an H, alkyl, cycloalkyl, aryl of heterocyclic group; where R1, R2, and R5 or R1, R2, and R3 may together form a heterocyclic group. The invention also relates to a method for the preparation of this compound by reaction of an amino compound with an alkanol hemiacetal. The invention also relates to amino-aldehyde resins containing this compound and the application of these resins in adhesive compositions, laminates, shaped articles and transparent coatings.Type: GrantFiled: May 28, 2003Date of Patent: April 3, 2007Assignee: DSM I.P. Assets B.V.Inventors: Rudolfus Antonius Theodorus Maria Van Benthem, Renier Henricus Maria Kirkels Van Duin, Jacobus Andriaan Antonius Vermeulen
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Patent number: 7169881Abstract: Resin compositions, methods of forming such resin compositions, methods of using such resin compositions and substrates treated with such resin compositions are disclosed. One of such resin compositions contains no formaldehyde and is useful as a binder. Such resin composition comprises the reaction product of: a—melamine, b—at least one aldehyde of formula (1) as defined in the specification, c—a cross linking agent, wherein the cross linking agent is glyoxylic acid, and d—at least one polyol having 2 or more than 2 hydroxyl groups. The resin composition of the present invention can provide performance characteristics to which they are applied.Type: GrantFiled: October 29, 2004Date of Patent: January 30, 2007Assignee: Clariant (France)Inventors: Gregory J. Hopkins, William C. Floyd
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Patent number: 7087683Abstract: A crosslinking agent that is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin such that the crosslinking agent is essentially free of functional groups reactive with an aminoplast resin and has a glass transition temperature of at least 10° C. is disclosed. Compound (b) is, more specifically, a monofunctional sulfonamide having only one active hydrogen. Methods for preparing crosslinking agents are also disclosed. Further provided is a curable powder coating composition including a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and the present crosslinking agent; a multilayer composite coating compositions and substrates coated therewith are also disclosed. Methods for modifying aminoplasts are also disclosed.Type: GrantFiled: December 5, 2002Date of Patent: August 8, 2006Assignee: PPG Industries Ohio, Inc.Inventors: Shengkui Hu, Anthony M. Chasser, William H. Retsch, Ronald R. Ambrose
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Patent number: 6992149Abstract: A powder coating composition comprising at least about 0.1% by weight of a reaction product of an aminoplast and a compound having one carbamate group has improved smoothness.Type: GrantFiled: February 12, 2004Date of Patent: January 31, 2006Assignee: BASF CorporationInventors: Walter H. Ohrbom, Thomas S. Richards, Timothy S. December, James A. Laugal
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Patent number: 6962730Abstract: The invention provides coating compositions comprising a reactive component (a) which is substantially free of any heteratoms and is a not a crystalline solid at room temperature and which comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups, and (b) a crosslinking agent comprising a plurality of functional groups (iii) reactive with the functional groups (ii) of compound (a), wherein functional groups (ii) and (iii) are selected such that reaction there between produces a thermally irreversible chemical linkage. The coating compositions of the invention provide improved solids, chip resistance, flexibility and/or scratch & mar resistance while maintaining desirable and/or improved performance characteristics with regard to environmental etch, relative humidity, QCT, chip resistance, thermoshock resistance, cold crack resistance, adhesion and the like.Type: GrantFiled: January 23, 2003Date of Patent: November 8, 2005Assignee: BASF CorporationInventors: Walter H. Ohrbom, John A. Gilbert, Patricia A. Herrel, Marvin L. Green, Joanne Casale, Thomas G. Savino
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Patent number: 6881817Abstract: Adhesive composition consisting of an aminoplast resin with a free formaldehyde-like compound being present. In particular an adhesive composition consisting of a melamine-urea-formaldehyde resin to which a free formaldehyde-like compound has been added so that F/(NH2)2 is equal to 0.8-1.6. The adhesive is in particular suitable for the preparation of board material by combining in a press cellulose-containing materials with the adhesive according to the invention and in this press manufacturing board material at elevated temperature and pressure.Type: GrantFiled: August 19, 2002Date of Patent: April 19, 2005Assignee: DSM IP Assets B.V.Inventors: Adriaan Cornelis Lambertus Maria Van Der Waals, Gerard Evert Oosting, Jozef Maria Johannes Mattheij
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Patent number: 6818729Abstract: This invention provides a thermosetting resin and a method for producing the same, in which 5% to 95% by weight of an aminoplast resin and 5% to 95% by weight of a polyalkylene glycol are subjected to a condensation reaction under alkaline conditions, the resulting reaction product is methoxylated with methanol, and pH of the methoxylated product is controlled in a range from 10 to 11. The thermosetting resin for impregnation of resins or for use in building materials obtained according to the invention is highly stable, can be diluted with water, has excellent workability, stiffness, chemical resistance, water resistance, moisture resistant strength, and adhesion in water, exhibits improved brittleness and has satisfactory flexibility and impact resistance.Type: GrantFiled: January 28, 2003Date of Patent: November 16, 2004Assignee: Showa Highpolymer Co., Ltd.Inventors: Fumitoshi Tsukiyama, Tadahiro Inada
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Patent number: 6818726Abstract: Polymers are prepared from A) 60 to 95 percent by weight of a mixture including A1) 20 to 70 percent by weight of hydroxyalkyl amino triazines and A2) 30 to 80 percent by weight of bis(hydroxyalkyl) amino triazines B) 5 to 40 percent by weight of polyfunctional compounds selected from one or more of B1) polyisocyanates and/or oligomeric polyesters or polyethers with isocyanate end groups, B2) aliphatic dicarboxylic acids, esters, chlorides or anhydrides, or aromatic polybasic acids, esters, chlorides or anhydrides, B3) aliphatic or aromatic diglycidal compounds or triglycidyl compounds, and, optionally, C) 1 to 20 percent by weight of aliphatic, cycloaliphatic or aromatic dihydroxy compounds, polyalkylene glycols and aliphatic aldehydes.Type: GrantFiled: July 25, 2002Date of Patent: November 16, 2004Assignee: Agrolinz Melamin GmbHInventors: Manfred Rätzsch, Martin Burger, Manfred Arnold, Willy Frank
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Patent number: 6812297Abstract: The present invention provides a crosslinker for organic coatings having an amino resin core with substituents including more than one olefin functional group, a silicon-containing group, and at least one alkoxyalkyl or alkylol group. Coating compositions containing the crosslinker can be cured with radiation, especially ultraviolet radiation. The crosslinker can be included in a coating composition with one or more curable resins, applied onto a substrate and cured to form the cured coating of the invention.Type: GrantFiled: August 9, 2002Date of Patent: November 2, 2004Assignee: BASF CorporationInventors: Swaminathan Ramesh, Paul Lessek, Paul J. Harris
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Patent number: 6812316Abstract: The curable coating compositions of the invention comprise a particulate component having at least one binder component (a) which is a solid at 75° F./24° C., and an additive component (b). The curable coating compositions further comprise a crosslinking component (c) reactive with the at least one binder component (a). Additive component (b) has from 12 to 72 carbon atoms, is substantially free of any heteroatoms, is not a crystalline solid at 75° F./24° C. and comprises a mixture of two or more structures selected from the group consisting of aliphatic structures for additive component (b), aromatic-containing structures for additive component (b), cycloaliphatic-containing structures for additive component (b), and mixtures thereof, wherein at least one of the two or more structures is either a cycloaliphatic-containing structure or an aromatic-containing structure.Type: GrantFiled: September 30, 2002Date of Patent: November 2, 2004Assignee: BASF CorporationInventors: Walter H. Ohrbom, David J. Law, Robert D. Weise
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Patent number: 6809161Abstract: A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.Type: GrantFiled: July 1, 2003Date of Patent: October 26, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Ronald R. Ambrose, Anthony M. Chasser, Shengkui Hu
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Patent number: 6761970Abstract: A poly(lactic acid) fiber has a strength at 90° C. of equal to or more than 0.8 cN/dtex and exhibits significantly satisfactory mechanical properties at high temperatures as compared with conventional poly(lactic acid) fibers.Type: GrantFiled: July 29, 2002Date of Patent: July 13, 2004Assignee: Toray Industries, Inc.Inventors: Takashi Ochi, Takaaki Sakai, Yuhei Maeda
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Patent number: 6723825Abstract: The invention relates to a process for preparing a liquid melamine urea formaldehyde resin that has long term stability. The invention also relates to a liquid MUF resin with a high formaldehyde and melamine content. The invention further relates to a liquid suspension hardener including a catalyst, a thickener, a filler, and water. The invention also relates to a adhesive composition for use in wood bonding that is made by adding a hardener to the resin.Type: GrantFiled: February 25, 2003Date of Patent: April 20, 2004Assignee: Cytec Technology Corp.Inventors: Huide Dennis Zhu, William Jacobs, III, Robert G. Lees, Luis Mendonca, Roger C. Rasch
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Patent number: 6706856Abstract: Multicrystalline melamine powder having a specific area of from 0.7-5 m2/g, content of oxygen-containing components of less than 0.7 wt %, an APHA colour less than 17 and a melam content higher than 1.5 wt %. The multicrystalline melamine powder may be used in amino-formaldehyde resins.Type: GrantFiled: May 2, 2002Date of Patent: March 16, 2004Assignee: DSM N.V.Inventors: Veronika M. L. J. Aarts, Tjay T. Tjioe, Koert Liekelema