From Silicon-containing Reactant Having At Least One Polyvalent Atom Other Than Carbon, Oxygen, Or Nitrogen Patents (Class 528/30)
  • Publication number: 20130171265
    Abstract: A curable composition of ionic silicones includes a silicone having the formula M1aM2bM3cD1dD2eD3fT1gT2hT3iQj having ionic groups and crosslinking functional groups. The composition can further include polyorganosiloxane having the average compositional formula R26nR27o(OH)pSiO(4-n-o-p)/2, organohydrogenoligosiloxane or organohydrogenpolysiloxane that has the average compositional formula HqR28rSiO(4-q-r)/2 a transition metal catalyst and other components such as UV stabilizer, cure accelerator, pigment, dye, antimicrobial agent, biocide, surfactant, functional or non-functional filler, conductive filler, finely divided surface treated/untreated metal oxides, clay, plasticizers, tackifiers, mold release agents, adhesion promoters, compatibilizers, pharmaceutical excipients, surfactants or antistatic agents.
    Type: Application
    Filed: December 20, 2012
    Publication date: July 4, 2013
    Applicant: Momentive Performance Materials Inc.
    Inventor: Momentive Performance Materials Inc.
  • Publication number: 20130172419
    Abstract: A polymer composite composition wherein at least one of the constituents is a silicone ionomer and the other constituent is polymer.
    Type: Application
    Filed: December 20, 2012
    Publication date: July 4, 2013
    Applicant: Momentive Performance Materials Inc.
    Inventor: Momentive Performance Materials Inc.
  • Patent number: 8475912
    Abstract: A coating composition for forming a low-refractive-index layer includes a first fluorine compound represented by Formula 1 below, (CH2?CR1COO)2Rf??Formula 1 and a reactive silicon compound, a (meth)acrylate compound, a polymerization initiator, and a solvent. The first fluorine compound represented by Formula 1, the reactive silicon compound, the (meth)acrylate compound, the polymerization initiator, and the solvent may each be different from one another, and in Formula 1, Rf may be a C1-19 perfluoro group, and R1 may be a hydrogen atom or a methyl group.
    Type: Grant
    Filed: April 16, 2009
    Date of Patent: July 2, 2013
    Assignee: Cheil Industries, Inc.
    Inventors: Yun Jeong Seong, Kyoung Ku Kang, Hyoung Tae Lim, Young Cheol Lee
  • Patent number: 8466252
    Abstract: An optical film that is excellent not only in transparency and heat resistance but also in solubility in an organic solvent and linear thermal expansion coefficient. Also, a product or a member which meets high demands for heat resistance and low linear thermal expansion coefficient with the use of the optical film, more specifically a transparent substrate using the optical film, and an image display device and a solar cell including the optical film or the transparent substrate. The optical film contains a polyimide having a specific structure in which a repeating unit of a chain of a polymer has both an amide group and an imide group and the polymer has a fluorine atom. The polyimide is obtained by mixing a dehydrating agent and an imidizing agent with a polyamic acid solution so as to imidize the polyamic acid.
    Type: Grant
    Filed: October 8, 2010
    Date of Patent: June 18, 2013
    Assignee: Kaneka Corporation
    Inventor: Masatoshi Hasegawa
  • Publication number: 20130149520
    Abstract: A phosphosiloxane resin comprises a plurality of covalently bonded monomer units selected from phosphosiloxane units SiR23—O—P(?O)(R1)(OR3)q(O1/2—)p, and organosiloxane units R2m(OR3)nSiO(4-m-n)/2. R1 and each R2 are independently selected from the group consisting of hydrogen, C1 to C10 hydrocarbyl, and C1 to C10 hydrocarbylene; each R3 is independently selected from the group consisting of hydrogen and C1 to C10 hydrocarbyl; p is 0 or 1; q=1?p; m is 0, 1, 2, 3, or 4; n is 0, 1, or 2; and m+n is 0, 1, 2, 3, or 4. Curable silicone compositions comprise a phosphosiloxane resin having greater than one silicon-bonded alkenyl group, an organosilicon compound having at least two silicon-bonded hydrogen atoms, and a hydrosilylation catalyst. Fiber-reinforced free-standing films may comprise fibers dispersed in a cured product of the silicone composition. Laminated substrates comprise at least one fiber-reinforced free-standing film.
    Type: Application
    Filed: August 23, 2011
    Publication date: June 13, 2013
    Applicant: Dow Corning Corporation
    Inventor: Bizhong Zhu
  • Patent number: 8455582
    Abstract: It is an object of the present invention to provide a tire rubber composition excellent in performances such as silica dispersibility and processability. The present invention relates to a tire rubber composition, comprising: a rubber component; silica; and a silane coupling agent, wherein the silica has a CTAB specific surface area of 180 m2/g or more and a BET specific surface area of 185 m2/g or more, and the silane coupling agent is a copolymer comprising units A represented by formula (1) and units B represented by formula (2), and the proportion of the units B is 1 to 70 mol % of the total molar amount of the units A and the units B.
    Type: Grant
    Filed: December 8, 2010
    Date of Patent: June 4, 2013
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Takayuki Hattori, Ai Matsuura, Michio Hirayama, Kenichi Uesaka
  • Patent number: 8445551
    Abstract: Disclosed are a solid electrolyte membrane for fuel cells, which is characterized by that there has been used a silicone resin obtained by subjecting a methide series siloxane compound having a specific, strong acid bis(perfluoroalkanesulfonyl)methide moiety, a specific polysiloxane compound, and a specific silane compound to a cross-linking reaction, and its production process. This membrane has heat resistance, is superior in chemical stability, has a good proton conductivity even under a low water content condition, and has a low methanol permeability.
    Type: Grant
    Filed: August 19, 2010
    Date of Patent: May 21, 2013
    Assignee: Central Glass Company, Ltd.
    Inventors: Yoshihiko Obara, Katsutoshi Suzuki, Toru Tanaka, Haruhiko Komoriya
  • Publication number: 20130101942
    Abstract: A resist pattern-forming method capable of forming a resist pattern excellent in pattern collapse resistance in the case of development with the organic solvent in multilayer resist processes. The method has the steps of: (1) providing a resist underlayer film on a substrate using a composition for forming a resist underlayer film; (2) providing a resist film on the resist underlayer film using a photoresist composition; (3) exposing the resist film; and (4) developing the exposed resist film using a developer solution containing no less than 80% by mass of an organic solvent, in which the composition for forming a resist underlayer film contains (A) a component that includes a polysiloxane chain and that has a carboxyl group, a group that can generate a carboxyl group by an action of an acid, an acid anhydride group or a combination thereof.
    Type: Application
    Filed: September 28, 2012
    Publication date: April 25, 2013
    Applicant: JSR CORPORATION
    Inventor: JSR CORPORATION
  • Patent number: 8404877
    Abstract: Compounds of formula I may be hydrolyzed to produce metal oxides wherein M is Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Cd, In, Sn, Sb, La, Hf, Ta, W, Re, Os, Ir, Pt, Hg, Tl, Pb, Bi, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, or Pu; X is O1/2 or OR; R is alkyl; R1, R2, R3, R4, R5, R6, and R7 are independently H, alkoxy, C1-C10 alkyl, phenyl or R10, R11, R12, R13, R14, and R15 are independently C1-C10 alkyl or phenyl; n is equal to the value of the oxidation state of M minus q; m and p are independently 0 or an integer from 1 to 5; and q is 0, 1, 2, or 4; with the proviso that when q is 1, X is OR; and when q is 2, X is O1/2, and M is V, Cr, Mn, Fe, As, Nb, Mo, Tc, Ru, Sb, Ta, W, Re, Os, Ir, Pt, Bi, Th, U, or Pu; and when q is 4, X is O1/2, and M is Cr, Mo, W, Ru, Re, Os, U, or Pu.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: March 26, 2013
    Assignee: General Electric Company
    Inventors: Sergei Kniajanski, Aharon Yakimov
  • Patent number: 8399591
    Abstract: An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.
    Type: Grant
    Filed: July 18, 2011
    Date of Patent: March 19, 2013
    Assignee: Dow Corning Corporation
    Inventors: Peter Hupfield, Avril Surgenor
  • Patent number: 8394909
    Abstract: A silane-terminated polyurethane composition is the reaction product of a silane-terminated polyurethane prepolymer component, a silane-terminated monomeric diisocyanate, and optionally at least one multifunctional trisilane or tetrasilane component. A method for making a composition includes (a) providing a silane-terminated polyurethane prepolymer component, a silane-terminated monomeric diisocyanate component, and optionally at least one multifunctional trisilane or tetrasilane component, and (b) combining the prepolymer component, monomeric component, and optional multifunctional silane component to form a silane-terminated polyurethane reaction product with a tensile strength of about 4 MPa or greater and an elongation of about 200% or greater.
    Type: Grant
    Filed: December 29, 2008
    Date of Patent: March 12, 2013
    Assignee: Construction Research & Technology GmbH
    Inventors: Michael J. Porsch, Kelly A. Kuznia Freudenberg
  • Patent number: 8378489
    Abstract: A semiconductor device of this invention has a copper wiring layer, of which a layer, to which a composition including at least one substance selected from the group consisting of ammonia and organic bases is applied, and a silicon-containing insulating film are sequentially superimposed on the copper wiring layer. Accordingly, semiconductor devices having insulating layers which adheres well to the copper serving as the wiring material can be obtained.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: February 19, 2013
    Assignee: Fujitsu Limited
    Inventors: Shiro Ozaki, Yoshihiro Nakata, Yasushi Kobayashi, Ei Yano
  • Patent number: 8372937
    Abstract: The present invention discloses a two-component adhesion promoter composition for surface pretreatment, comprising two components, the first component, K1, comprising at least one hydrolyzable adhesion promoter substance A which is selected from the group comprising organosilicon compounds, organotitanium compounds, organozirconium compounds, and mixtures thereof; and the second component, K2, comprising at least one compound B which reacts with the adhesion promoter substance A or triggers or catalyzes condensation of the adhesion promoter substance A, and the first and the second components in the unopened state being present in two compartments (1, 2) separated from one another by at least one dividing wall (3).
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: February 12, 2013
    Assignee: Sika Technology AG
    Inventors: Gerald Trabesinger, Gerhard Zingerle, Wolf-Rüdiger Huck, Stefan Junge
  • Patent number: 8354489
    Abstract: The present invention relates to novel methods for the salt-free polymerization of borosilylamines, which comprise the structural feature Si—N—B and borosilyl hydrocarbons, which comprise the structural feature Si—X—B, wherein X may be a methylene group or a hydrocarbon chain CxHy or a cyclic hydrocarbon unit, by reaction thereof with disilazanes R3Si—NR—SiR3.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: January 15, 2013
    Assignee: Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.
    Inventors: Markus Weinmann, Martin Jansen
  • Publication number: 20130004137
    Abstract: A low index of refraction hybrid optical cladding may be formed from a fluorinated sol-gel. An electro-optic device may include a poled organic chromophore-loaded modulation layer (electro-optic polymer) and at least one adjacent fluorinated hybrid sol-gel cladding layer.
    Type: Application
    Filed: March 28, 2012
    Publication date: January 3, 2013
    Applicant: Gigoptix, Inc.
    Inventors: Danliang Jin, Guomin Yu, Hui Chen, Baoquan Chen
  • Patent number: 8343474
    Abstract: The invention relates to new compounds of Formula 1: [(O3/2)Si CH2CH2SX]a [Si(O4/2)]b[Si(O3/2V)]c. The compounds are useful as scavengers for the removal of unwanted organic and inorganic compounds, for solid phase extraction, for solid phase synthesis, for acid and metal mediated heterogeneous catalysis, for metal ion abstraction and for the immobilization of bio-molecules.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: January 1, 2013
    Assignee: Phosphonics Ltd.
    Inventors: John Robert Howe Wilson, Alice Caroline Sullivan, Siud Pui Man
  • Patent number: 8337551
    Abstract: Biomedical devices such as silicone hydrogels formed from a polymerization product of a mixture comprising (a) a siloxane-containing homopolymer which has only one thio carbonyl thio fragment of a reversible addition fragmentation chain transfer (RAFT) agent; and (b) one or more biomedical device-forming comonomers are disclosed.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: December 25, 2012
    Assignee: Bausch & Lomb Incorporated
    Inventors: Jeffrey G. Linhardt, Ivan M. Nunez, Joseph A. McGee, Jennifer Hunt, Michele Alton, Drazen Pavlovic, Devon A. Shipp
  • Patent number: 8314201
    Abstract: Ceramic oxide aerogels incorporating periodically dispersed flexible linkages are provided. The flexible linkages impart greater flexibility than the native aerogels without those linkages, and have been shown to reduce or eliminate the need for supercritical CO2-mediated drying of the corresponding wet gels. The gels may also be polymer cross-linked via organic polymer chains that are attached to and extend from surface-bound functional groups provided or present over the internal surfaces of a mesoporous ceramic oxide particle network via appropriate chemical reactions.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: November 20, 2012
    Assignees: The United States of America as represented by the Administration of the National Aeronautics and Space Administration, Ohio Aerosapce Institute
    Inventors: Mary Ann B. Meador, Baochau N. Nguyen
  • Patent number: 8293407
    Abstract: An electrode which can be used in a fuel cell having improved power generation performance and high durability, and a fuel cell having such an electrode, are provided. An electrode having catalyst layers arranged on both surfaces of an electrolyte membrane, wherein the electrode is characterized in that an electrode binder used for constituting the catalyst layers contains a cross-linked compound (X) having a silicon-oxygen bond, a polymer material (Y) containing an acid group, and an aqueous dispersion (Z) containing a thermoplastic resin.
    Type: Grant
    Filed: March 13, 2008
    Date of Patent: October 23, 2012
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Yoshiharu Konno, Toshihito Miyama, Hideyasu Nakajima, Masashi Kanoh
  • Patent number: 8268951
    Abstract: Present invention provides a fluorine-containing organopolysiloxane composition comprising a fluorine-containing silicone polymer having a three-dimensional, cross-linked structure, prepared by addition polymerizing the following (A), (B) and (C) and containing 10 to 30 mass % of the fluorine atoms, relative to a total mass of (A) to (C), (A) a vinyl group-containing organopolysiloxane represented by the following formula (1): (B) an organohydrogenpolysiloxane represented by the following formula (2): and (C) an organopolysiloxane having a reactive group on one end alone and represented by the following formula (3), and further comprising (D) a low viscosity silicone oil with a dynamic viscosity of 50 mm2/s or less at 25 degrees C.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: September 18, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hiromasa Yamaguchi, Teruki Ikeda
  • Patent number: 8263185
    Abstract: The invention relates to compositions comprising or consisting of a reaction product obtained from a reaction mixture of aminosilane of formula (I), a mecaptosilane of formula (II) and an epoxysilane of formula (III). Said compositions are suitable as bonding agents, especially in the form of primers. The compositions are highly adhesive and especially suitable for low-temperature applications and especially for sticking glass together.
    Type: Grant
    Filed: November 20, 2006
    Date of Patent: September 11, 2012
    Assignee: Sika Technology AG
    Inventor: Wolf-Rudiger Huck
  • Patent number: 8263723
    Abstract: A curable organopolysiloxane composition comprising: (A) an novel organopolysiloxane represented by the following average structural formula: R1aSiO(4-a)/2 {wherein R1 represents a substituted or non-substituted monovalent hydrocarbon group, an alkoxy group, a hydroxyl group, or an organopolysiloxane residue of the following general formula: —X—(SiR2O)mSiR23 (wherein R2 are the same or different, substituted or unsubstituted monovalent hydrocarbon groups; X represents oxygen atoms or a bivalent hydrocarbon group; and ‘m’ is an integer equal to or greater than 1); however, at least one R1 in one molecule is the aforementioned organopolysiloxane residue, at least one R1 is a monovalent hydrocarbon group having aliphatic carbon-carbon double bonds, and ‘a’ is a positive number that satisfies the following condition: 0<a<2)}; (B) an organic silicon compound having in one molecule at least two silicon-bonded hydrogen atoms; and (C) a hydrosilylation catalyst; is capable of forming a cured product of high fle
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: September 11, 2012
    Assignee: Dow Corning Toray Company, Ltd.
    Inventors: Yoshitsugu Morita, Michitaka Suto
  • Patent number: 8258251
    Abstract: Ceramic oxide aerogels having improved flexibility are disclosed. Preferred embodiments exhibit high modulus and other strength properties despite their improved flexibility. The gels may be polymer cross-linked via organic polymer chains to further improve strength properties, without substantially detracting from the improved flexibility. Methods of making such aerogels are also disclosed.
    Type: Grant
    Filed: May 7, 2010
    Date of Patent: September 4, 2012
    Assignees: The United States of America, as represented by the Administrator of the National Aeronautics and Space Administration, Ohio Aerospace Institute
    Inventors: Mary Ann B. Meador, Baochau N. Nguyen, Haiquan Guo
  • Patent number: 8247514
    Abstract: A silylated polyurethane composition containing polyester based polyurethane prepolymer. The silylated polyurethane composition when partially silylated is especially useful for pressure sensitive adhesives where it imparts superior adhesive and cohesive performance thereto.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: August 21, 2012
    Assignee: Momentive Performance Materials Inc.
    Inventor: Roy M. Griswold
  • Patent number: 8241707
    Abstract: This invention pertains to silsesquioxane resins useful in antireflective coatings wherein the silsesquioxane resin is comprised of the units (Ph(CH2)rSiO(3?x)/2(OR?)x)m (HSiO(3?x)/2(OR?)x)n (MeSiO(3?x)/2(OR?)x)o (RSiO(3?x)/2(OR?)x)p (R1SiO(3?x)/2(OR?)x)q where Ph is a phenyl group, Me is a methyl group; R? is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R is selected from a hydroxyl producing group; and R1 is selected from substituted phenyl groups, ester groups, polyether groups; mercapto groups, and reactive or curable organic functional groups; and r has a value of 0, 1, 2, 3, or 4; x has a value of 0, 1 or 2; wherein in the resin m has a value of 0 to 0.95; n has a value of 0.05 to 0.95; o has a value of 0.05 to 0.95; p has a value of 0.05 to 0.5; q has a value of 0 to 0.5; and m+n+o+p+q?1.
    Type: Grant
    Filed: February 3, 2009
    Date of Patent: August 14, 2012
    Assignee: Dow Corning Corporation
    Inventors: Peng-Fei Fu, Eric Scott Moyer
  • Patent number: 8236918
    Abstract: The present invention provides a linear, cyclic or branched polyether-functional siloxane or a mixture of polyether-functional siloxanes of the general formula (I) R[—O(3-h)/2Si(R1)(OR)h]x[—O(3-i-j)/2Si(R2)(R3)i(OR)j]y, (II) in which groups R are identical or different and R is essentially H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-methoxyethyl or 2-hydroxyethyl or, in the case of cyclic siloxanes, may be a silyl radical of the silyl units of the formula (I), groups R1 are identical or different and R1 is a terminally blocked polyether group of the formula (II), R4—O[—R5—O]n[(—R6)m]— (II) and groups R2 are identical or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having 1 to 18 carbon atoms or a mercaptoalkyl group or an alkenyl group having 2 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms or an aminoalkyl group or the general formula (III) H2N(CH2)d[(NH)e(CH2)f]g—(CH2)3— (III) The
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: August 7, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Ekkehard Mueh, Peter Jenkner, Max Preisenberger, Burkhard Standke
  • Publication number: 20120178893
    Abstract: Substituted 3,4-propylenedioxythiophene monomers may be prepared by reacting 3-allyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine or 3,3-diallyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine with a thiol having a hydrocarbyl moiety optionally containing one or more heteroatom-containing functional groups under radical addition conditions under radical addition conditions. Such monomers may be used in homo- or copolymerization processes to obtain thiophene-type polymers containing substituents (which may bear functional groups such as silane, thiol, hydroxyl, carboxylic acid, amine, sugar groups, polyoxyalkylene, and the like). Crosslinkers useful for introducing crosslinking into thiophene-type polymers may be prepared by reacting 3-allyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine with a compound having two or more thiol groups under radical addition conditions.
    Type: Application
    Filed: August 23, 2011
    Publication date: July 12, 2012
    Applicant: University of Delaware
    Inventors: David C. Martin, Kathleen E. Feldman
  • Publication number: 20120168055
    Abstract: An apparatus for making and using a fastener suitable for use in airplane manufacture or repair that is coated with a pre-mixed moisture cure sealant. The sealant layer is coated with a frangible moisture barrier that will break apart when the fastener is installed, thus exposing the sealant to a moisture source. Once exposed to moisture, the sealant will begin to cure. Preferred embodiments also provide a premature cure indicator that provides a visual indication that the outer moisture resistant layer has been damaged.
    Type: Application
    Filed: November 2, 2011
    Publication date: July 5, 2012
    Applicant: SYSTEMS AND MATERIALS RESEARCH CORPORATION
    Inventors: ALAN V. BRAY, DENISE DEPPE, LESLIE SCHMIDT, DAVID J. IRVIN
  • Patent number: 8198390
    Abstract: A water soluble functional polyethylene glycol-grafted polysiloxane polymer comprising a polysiloxane backbone and polyethylene glycol side chains is provided having the general formula: wherein A is selected from the group consisting of hydrogen, methyl, methoxy and functional polyethylene glycol based chains, B is a functional group for binding biologically-sensitive materials, D is a functional group for binding to a substrate, m is from 3 to 5, v is from 0 to 5, w is from 4 to 11, x is from 0 to 35 and z is from 1 to 33. In order to be water soluble, the polysiloxane polymer h the following properties: x+y+z is from 8 to 40, n is from 8 to 30, and y is from 7 to 35.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: June 12, 2012
    Assignee: IMEC
    Inventors: Cheng Zhou, Gustaaf Borghs, Wim Laureyn
  • Publication number: 20120142791
    Abstract: Disclosed are a solid electrolyte membrane for fuel cells, which is characterized by that there has been used a silicone resin obtained by subjecting a methide series siloxane compound having a specific, strong acid bis(perfluoroalkanesulfonyl)methide moiety, a specific polysiloxane compound, and a specific silane compound to a cross-linking reaction, and its production process. This membrane has heat resistance, is superior in chemical stability, has a good proton conductivity even under a low water content condition, and has a low methanol permeability.
    Type: Application
    Filed: August 19, 2010
    Publication date: June 7, 2012
    Applicant: Central Glass Company, Limited
    Inventors: Yoshihiko Obara, Katsutoshi Suzuki, Toru Tanaka, Haruhiko Komoriya
  • Publication number: 20120123050
    Abstract: A liquid crystal polyimide, containing: repeating units of formula (I) and having liquid crystallinity, wherein A1 and A2 are each independently a tetravalent residue of a tetracarboxylic acid, B1 is a residue of a bis(amino)polysiloxane of formula (II), and C1 is a residue of an organic diamine, wherein R1 to R6 are each independently a lower alkyl group, x is from 0 to 10, D1 is an alkylene group, y is 0 or 1, and Z1 is selected from the group consisting of —H, —CH3, CF3, —F, —CN and —NO2. In addition, a liquid crystal resin composition and a resin film for a semiconductor element containing the liquid crystal polyimide.
    Type: Application
    Filed: November 10, 2011
    Publication date: May 17, 2012
    Applicant: Mitsubishi Chemical Corporation
    Inventors: Mitsuru UEDA, Yu Shoji, Fumikazu Mizutani, Tomohide Murase
  • Patent number: 8163863
    Abstract: A polysilane having excellent functionalities (e.g., solubility in a solvent and reactivity) is obtained by introducing a structural unit of the following formula (1) to a polysilane through a reaction of a dihalosilane having a Si—H bond and adding a hydrosilylatable compound (e.g., a compound having a carbon-carbon unsaturated bond) to the Si—H bond, wherein R1 represents a hydrogen atom, an organic group, or a silyl group; and “n” denotes an integer of not less than 1.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: April 24, 2012
    Assignee: Osaka Gas Co., Ltd.
    Inventors: Hiroki Sakamoto, Hiroaki Murase, Tsuyoshi Fujiki, Shingo Osawa, Yoshiyuki Morita, Tetsuya Hosomi, Nobuaki Aoki
  • Patent number: 8153748
    Abstract: A thermosetting composition containing an aluminosiloxane, a silicone oil containing silanol groups at both ends, and a silicone alkoxy oligomer. The thermosetting composition of the present invention can be used for, for example, encapsulating materials, coating materials, molding materials, surface-protecting materials, adhesive agents, bonding agents, and the like. Especially, in a case where the thermosetting composition of the present invention is used as an encapsulating material, the thermosetting composition is suitably used for, for example, photosemiconductor devices mounted with blue or white LED elements (backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like).
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: April 10, 2012
    Assignee: Nitto Denko Corporation
    Inventor: Hiroyuki Katayama
  • Patent number: 8138297
    Abstract: A moisture-curable silylated resin possessing improved storage stability and short cure time is obtained by reacting a prepolymer with a silylating reactant comprising silane (i) possessing three methoxy groups, silane (ii) possessing three alkoxy groups independently containing from 2 to 4 carbon atoms, and, optionally, silane (iii) possessing two methoxy groups and one alkoxy group of from 2 to 4 carbon atoms and/or silane (iv) possessing one methoxy group and two alkoxy groups independently containing from 2 to 4 carbon atoms.
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: March 20, 2012
    Assignee: Momentive Performance Materials Inc.
    Inventors: Misty Weiyu Huang, Christine Lacroix
  • Publication number: 20120062883
    Abstract: The present invention provides a method of making highly charged, monodisperse particles which do not absorb deep ultraviolet (UV) light and a method of making crystalline colloidal array (CCA) deep UV narrow band radiation filters by using these highly charged monodisperse particles. The CCA filter rejects and/or selects particular regions of the electromagnetic spectrum while transmitting adjacent spectral regions. The filtering devices of the present invention are wavelength tunable over significant spectral intervals by changing the incident angle of the CCA filter relative to the light. Larger wavelength changes can be obtained by changing the concentrations of particles in the CCAs. The present invention also includes applications of the CCA filter to hyperspectral imaging and Raman imaging devices.
    Type: Application
    Filed: September 7, 2011
    Publication date: March 15, 2012
    Inventors: Sanford A. Asher, Luling Wang, David Tuschel
  • Patent number: 8129567
    Abstract: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH??Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
    Type: Grant
    Filed: April 25, 2011
    Date of Patent: March 6, 2012
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Sheng Peng, Stephen James Getty, Timothy Edward Hopkins, Ying Wang
  • Publication number: 20120027917
    Abstract: Silsesquioxane resins useful in antireflective coatings wherein the silsesquioxane resin has the formula: (PhSiO(3?x)/2(OR?)x)m(HSiO(3?x)/2(OR?)x)n(MeSiO(3?x)/2(OR?)x)o(RSiO(3?x)/2(OR?)x)p(R2SiO(3?x)/2OR?)x)q where Ph is a phenyl group, Me is a methyl group; R is selected from a sulfur-containing organic functional group; R? is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R2 is selected from ester groups, polyether groups; and polyethylene oxide groups; x has a value of 0, 1 or 2; m has a value of 0.01 to 0.97; n has a value of 0.01 to 0.97; o has a value of 0.01 to 0.97; p has a value of 0.01 to 0.97; q has a value of 0 to 0.96; and m+n+o+p+q?1.
    Type: Application
    Filed: December 5, 2008
    Publication date: February 2, 2012
    Inventor: Akihiko Shirahata
  • Publication number: 20120012821
    Abstract: The present invention relates to silyl- and heteroatom-substituted compounds selected from carbazoles, dibenzofurans, dibenzothiophenes and disilylbenzophospholes of the formula (I) or (I*), to the use of the compounds of the formula (I) or (I*) in organic electronics applications, preferably in organic light-emitting diodes, to an organic light-emitting diode comprising at least one compound of the formula (I) or (I*), to a light-emitting layer comprising at least one compound of the formula (I) or (I*), to a blocking layer for holes/excitons comprising at least one compound of the formula (I) or (I*), and to an apparatus selected from the group consisting of stationary visual display units, mobile visual display units, illumination units, keyboards, items of clothing, furniture and wallpaper, comprising at least one inventive organic light-emitting diode.
    Type: Application
    Filed: December 14, 2009
    Publication date: January 19, 2012
    Applicants: BASF SE, KONINKLIJKE PHILIPS ELECTRONICS N.V., OSRAM OPTO SEMICONDUCTORS GMBH
    Inventors: Nicolle Langer, Christian Schildknecht, Soichi Watanabe, Evelyn Fuchs, Gerhard Wagenblast, Christian Lennartz, Oliver Molt, Korinna Dormann, Chuanjie Loh, Arvid Hunze, Ralf Krause, Guenter Schmid, Karsten Heuser, Volker van Elsbergen, Herbert Friedrich Boerner, Stefan Kirsch
  • Patent number: 8084549
    Abstract: A composition is provided for use with an unsaturated elastomer. The composition may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in elastomer compositions.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: December 27, 2011
    Assignee: Continental AG
    Inventors: Norberto Silvi, Robert James Perry, Ben Purushotam Patel, Paul Burchell Glaser, Brennan Alexander Smith
  • Patent number: 8043369
    Abstract: Biomedical devices such as silicone hydrogels formed from a polymerization product of a mixture comprising (a) a siloxane-containing homopolymer comprising one or more thio carbonyl thio fragments of a reversible addition fragmentation chain transfer (RAFT) agent; and (b) one or more biomedical device-forming monomers are disclosed.
    Type: Grant
    Filed: June 16, 2009
    Date of Patent: October 25, 2011
    Assignee: Bausch & Lomb Incorporated
    Inventors: Jeffrey G. Linhardt, Ivan M. Nunez, Joseph A. McGee, Jennifer Hunt, Michele Alton, Drazen Pavlovic, Devon A. Shipp
  • Patent number: 8030430
    Abstract: A chemical composition comprises one or more urethane oligomers of at least two polymerized units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers, wherein said oligomers comprise the reaction product of (a) one or more polyfunctional isocyanate compounds, (b) one or more polyols, (c) one or more monoalcohols selected from the group consisting of fluorocarbon monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof, (d) one or more silanes, and (e) one or more stabilizers comprising one or more reactive groups.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: October 4, 2011
    Assignee: 3M Innovative Properties Company
    Inventors: Wayne W. Fan, Nathaniel P. Langford, Richard M. Fischer, Jr., Amy S. Barnes
  • Patent number: 8017696
    Abstract: Vulcanizable elastomeric compositions and vulcanizates are prepared by employing a titanium compound. The titanium compound is believed to enhance the reaction between a silica particle and a silica-reactive compound.
    Type: Grant
    Filed: January 13, 2006
    Date of Patent: September 13, 2011
    Assignee: Bridgestone Corporation
    Inventors: Chenchy Jeffrey Lin, Christine Rademacher, Shunji Araki
  • Patent number: 8017211
    Abstract: A composition, etc. are provided, which can enhance hardness and afford abrasion resistance even in a thin film as well as excellent antifouling property and durability of the antifouling property. An organic polymer, is provided, which comprises 5 to 30 weight percent of a radical polymerizable monomer having a perfluoroalkyl group, 0.01 to 5 weight percent of ?,?-dimercaptopolysiloxane, 5 to 40 weight percent of a radical polymerizable monomer having a cationic photo polymerizable epoxy group, and 25 to 75 weight percent of the other radical polymerizable monomer copolymerizable therewith, said organic polymer having a structure corresponding to a radical polymerizable copolymer of a mixture of the monomers in which a molar ratio of the mercapto group to the epoxy group is 0.0001 to 0.025, and/or a structure obtained by reacting the epoxy groups of the radical polymerizable copolymer with (meth) acrylic acid.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: September 13, 2011
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Makoto Terauchi
  • Publication number: 20110213090
    Abstract: Inherently radiopaque side-chain crystallizable polymers (IRSCCP's) are useful in various medical applications. An example of a IRSCCP is a polymer that comprises a main chain, a plurality of crystallizable side chains, and a plurality of heavy atoms attached to the polymer, the heavy atoms being present in an amount that is effective to render the polymer radiopaque. A polymeric material that includes a IRSCCP may be fabricated into a medical device useful for at least partially occluding a body cavity. For example, such a medical device may be an embolotherapy product.
    Type: Application
    Filed: May 5, 2011
    Publication date: September 1, 2011
    Applicant: REVA Medical, Inc.
    Inventors: Donald K. Brandom, Joan Zeltinger, Eric V. Schmid, Joseph J. Mallon
  • Publication number: 20110212050
    Abstract: Inherently radiopaque side-chain crystallizable polymers (IRSCCP's) are useful in various medical applications. An example of a IRSCCP is a polymer that comprises a main chain, a plurality of crystallizable side chains, and a plurality of heavy atoms attached to the polymer, the heavy atoms being present in an amount that is effective to render the polymer radiopaque. A polymeric material that includes a IRSCCP may be fabricated into a medical device useful for at least partially occluding a body cavity. For example, such a medical device may be an embolotherapy product.
    Type: Application
    Filed: May 5, 2011
    Publication date: September 1, 2011
    Applicant: REVA Medical, Inc.
    Inventors: Donald K. Brandom, Joan Zeltinger, Eric V. Schmid, Joseph J. Mallon
  • Patent number: 8003746
    Abstract: An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.
    Type: Grant
    Filed: May 8, 2006
    Date of Patent: August 23, 2011
    Assignee: Dow Corning Corporation
    Inventors: Peter Hupfield, Avril Surgenor
  • Publication number: 20110184141
    Abstract: A polymer production process comprising reacting a compound represented by the following formula (1) in the presence of a binuclear metal complex represented by the following formula (2). R4-nMHn??(1) (in the formula (1), R is a monovalent organic group, M is a silicon atom or a germanium atom, and n is 2 or 3.) [CpM(?-CH2)]2??(2) (in the formula (2), Cp is a cyclopentadienyl-based ligand, M is a metal atom selected from Rh and Ir, and the bond between M's is a double bond.
    Type: Application
    Filed: July 9, 2009
    Publication date: July 28, 2011
    Applicants: National Univ. Corp. Kanazawa University, JSR CORPORATION, JAPAN SCIENCE AND TECHNOLOGY AGENCY
    Inventors: Tatsuya Shimoda, Ryo Kawajiri, Kiyoshi Isobe, Hidetaka Nakai, Yasuo Matsuki
  • Patent number: 7956124
    Abstract: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH??Formula (I) ?wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: June 7, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Sheng Peng, Stephen James Getty, Timothy Edward Hopkins, Ying Wang
  • Patent number: 7955782
    Abstract: Bottom antireflective coating (BARC) that exhibit enhanced wet strip rates, BARC compositions for fabricating such BARCs, and methods for manufacturing such BARC compositions are provided. According to one exemplary embodiment, a bottom antireflective coating (BARC) composition comprises an inorganic-based compound, an absorbing material, and a wet strip-rate modifier combination. The wet strip-rate modifier composition comprises a combination of a short chain linear alcohol and dipropylene glycol (DPG), a combination of the short chain linear alcohol and tetraethylene glycol (TEG), a combination of DPG and TEG, or a combination of the short chain linear alcohol, DPG, and TEG.
    Type: Grant
    Filed: September 22, 2008
    Date of Patent: June 7, 2011
    Assignee: Honeywell International Inc.
    Inventors: Sudip Mukhopadhyay, Joseph Kennedy, Yamini Pandey, Jelena Sepa
  • Patent number: 7939616
    Abstract: The present Invention relates to a mixture comprising catenary, branched and for cyclic siloxanes of the general formula (I) where x is 1, 2 or 3, the substituents R are (i) organofunctional groups selected from —CH2—SH, —CH2—S—(CO)—R?, —CH2—(O—C2H4)a—OH with a=1 to 10, —CH2(O—C2H4)b—OR? with b=1 to 40, —(CH2)—NH2, —(CH2)—NHR?, —(CH2)—NR?2, —(CH2)—NH(CH2)2—NH2, —(CH2)—N[(CH2)2—NH2]2 and —(CH2)—NH(CH2)2—NH(CH2)2—NH2, In which R? is a linear, branched or cyclic alkyl group having 1 to 18 carbon atoms or an aryl group having 6 to 12 carbon atoms, (ii) hydroxyl, methoxy, ethoxy, 2-methoxyethoxy, isopropoxy, n-propoxy, isobutoxy and for n-butoxy groupe, and (iii) where appropriate, alkyl, alkenyl, isoalkyl, cycloalkyl or fluorcalkyl groups having 1 to 18 carbon atoms or aryl groups having 6 to 12 carbon atoms, whit the proviso that not more than one organofunctional group (i) is attached per silicon atom, the quotient of the molar ratio of the moiety (ii) to silicon le from I to 2, and the degree of oligornerizati
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: May 10, 2011
    Assignee: Evonik Degussa GmbH
    Inventors: Dieter Barfurth, Helmut Mack