Abstract: A method of manufacturing an analytical sample by a secondary ion mass spectrometry method is provided, which comprises a step of forming a separation layer over a substrate, a step of forming one of a thin film and a thin-film stack body to be analyzed over the separation layer, a step of forming an opening portion in one of the thin film and the thin-film stack body, a step of attaching a supporting body to one of a surface of the thin film and a surface of a top layer of the thin-film stack body, and a step of separating one of the thin film and the thin-film stack body from the substrate.

Abstract: A method of using metallized and nonmetallized nanoscopic silicon containing agents for physical property control, radiation absorption, and in situ formation of nanoscopic glass layers on material surfaces. Because of their tailorable compatibility with polymers, metals, composites, ceramics, glasses and biological materials, nanoscopic silicon containing agents can be readily and selectively incorporated into materials at the nanometer level by direct mixing processes. Properties improved include gas and liquid barrier, stain resistance, resistance to environmental degradation, radiation absorption, adhesion, printability, time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and abrasion resistance, electrical and thermal conductivity, and fire resistance.

Abstract: A linear polymer comprising carborane, siloxane, and acetylene units, which may be cross-linked to a cured polymer and/or pyrolyzed to a ceramic.

Abstract: A phosphorus-containing silsesquioxane is represented by the formula [R13SiO1/2]m[R2SiO3/2]n[R3SiO3/2]p[(R4O)2PO(CH2)xSiO3/2]q wherein each of R1, R2, R3, and R4 independently represents a hydrocarbyl group; x represents an integer of from 1 to 8; m is a positive number less than 1.5; n and q are positive numbers greater than 0 and less than 1; and p is a number greater than or equal to 0 and less than 1. Further, (n+p)/q is in a range of from 0.5 to 99, and (n+p+q)=1. Curable and cured compositions comprising the phosphorus-containing silsesquioxane are disclosed.

Abstract: The present invention provides a process for the preparation of poly(silyl ester)s comprising a structural unit of the formula (I) wherein the process comprises the step of reacting a polyacid of formula (II) with a polyacyloxysilyl derivative of formula (III) while removing the formed acid group(s) of formula R7Z(O)OH (IV). R9Z(O)OH (V), and R8Z(O)OH (VI) from the system.

Abstract: The present invention is a release liner including a film formed of a thermoplastic polymer and a non-migratory silicone additive. The additive is formed with a siloxane polymer that can be added directly to the thermoplastic polymer prior to compounding the thermoplastic polymer into an extrudable release liner film. The additive provides the desired release properties to the film, and due to bonds formed between the siloxane polymer and a binding component added to the siloxane polymer during formation of the additive, as well as the high molecular weight of the siloxane polymer, is non-migratory.

Abstract: Sulfonate functional siloxane compositions, methods of their preparation, emulsion compositions containing them are disclosed. The compositions are useful in a variety of personal, household, healthcare formulations, as well as fabric and textile treatments.

Abstract: A hydrophilic organopolysiloxane composition of the hydrosilylation reaction cure type for use as dental impression material is characterized by comprising as essential components (A) a diorganopolysiloxane having at least 0.1 silicon-bonded alkenyl group in a molecule, (B) a liquid or solid organopolysiloxane having average compositional formula (1), comprising SiO2 units and R3SiO1/2 units (R is a monovalent hydrocarbon, alkoxy or hydroxyl group) and having a viscosity of at least 10 mPa-s at 23° C., (C) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule, (D) a hydrosilylation catalyst, and (E) a polyether having average compositional formula (2).

Abstract: A silsesquioxane resin comprised of the units (Ph(CH2)rSiO(3-x)/2(OR?)x)m, (HSiO(3-x)/2(OR?)x)n?(MeSiO(3-x)/2(OR?)x)o?(RSiO(3-x)/2(OR?)x)p, (R1SiO(3-x)/2(OR?)x)q where Ph is a phenyl group, Me is a methyl group; R? is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R is selected from an aryl sulfonate ester group; and R1 is selected from substituted phenyl groups, ester groups, polyether groups; mercapto groups, and reactive or curable organic functional groups; and r has a value of 0, 1, 2, 3, or 4; x has a value of 0, 1 or 2; wherein in the resin m has a value of 0 to 0,95; n has a value of 0.05 to 0.95; o has a value of 0.05 to 0.95; p has a value of 0.05 to 0.5; q has a value of 0 to 0.5; and m+n+o+p+q=1.

Abstract: A composition of matter comprises a polymer network, including silicon atoms and oxygen atoms, a first organic side-chain attached to at least some silicon atoms within the polymer network comprising a flexible linking group and a terminal group, the terminal group including at least one atom providing a lone pair of electrons. The composition of matter can be used to form a proton-conducting membrane. In illustrative examples, the polymer network can be an organic-inorganic hybrid network and the terminal group can includes a nitrogen-containing heterocycle.

Abstract: The present invention provides curable materials, medical devices incorporating such materials, wherein the curable materials are capable of releasing hydrolyzable leaving agents upon hydrolysis that can form agents (e.g., pharmaceutically active agents), and methods of making and using such materials and devices.

Abstract: A method of manufacturing an analytical sample by a secondary ion mass spectrometry method is provided, which comprises a step of forming a separation layer over a substrate, a step of forming one of a thin film and a thin-film stack body to be analyzed over the separation layer, a step of forming an opening portion in one of the thin film and the thin-film stack body, a step of attaching a supporting body to one of a surface of the thin film and a surface of a top layer of the thin-film stack body, and a step of separating one of the thin film and the thin-film stack body from the substrate.

Abstract: Ceramic oxide aerogels having improved flexibility are disclosed. Preferred embodiments exhibit high modulus and other strength properties despite their improved flexibility. The gels may be polymer cross-linked via organic polymer chains to further improve strength properties, without substantially detracting from the improved flexibility. Methods of making such aerogels are also disclosed.

Abstract: Disclosed is a nanocomposite composition, comprising transparent nanoparticles, a matrix polymer including a polydimethylsiloxane resin and an epoxy group-containing polydimethylsiloxane resin, and a siloxane dispersant including a head part having an affinity for the transparent nanoparticles and a tail part having an affinity for the polydimethylsiloxane resin. The nanocomposite composition of this invention can be effectively used in the encapsulation layer of a light emitting diode or in an optical film.

Abstract: An object of the present invention is to solve the problems with conventional polymer electrolyte fuel cells and provide a proton conducting membrane which exhibits an excellent heat resistance and an excellent protonic conductivity and a high dimensional stability even at high temperatures, a method for producing the same and a fuel cell using the same. The proton conducting membrane of the present invention is a proton conducting membrane having particles 1 comprising a metal-oxygen crosslinked structure and the particles 1 have an acid group such as sulfonic acid group incorporated in the surface thereof and form a continuity. The gap 2 between the particles is communicated from the main surface to the opposite surface of the proton conducting membrane to form a proton conducting channel.

Abstract: This invention relates to thermoplastic elastomers comprising at least one silicone ionomer. These thermoplastic elastomers may be reprocessed and/or recycled.

Abstract: A light filter or an array of filters can be either one or two dimensional. The filter or filters use multiple beam interference by varying an optical path length between semi-reflective surfaces. The optical path length between the semi-reflective surfaces is varied by changing a thickness of a polymer film in response to an electric field formed between two semi-transparent electrodes. The filter can be configured in either a transmissive or reflective mode.

Abstract: A glue for packaging a light emitting diode (LED) is described and includes a first set of compositions and a second set of compositions mixed based on a predetermined weight ratio. The first set of compositions is poly(dimethyl siloxane), and the second set of compositions includes a copolymer of dimethyl siloxane, methyl hydrogen siloxane, and vinyl siloxane. The copolymer in the second set of compositions has a weight percentage from about 94% to 99%, dimethyl siloxane in the copolymer has a weight percentage from about 84% to 90%, methyl hydrogen siloxane in the copolymer has a weight percentage from about 4% to 9%, and vinyl siloxane in the copolymer has a weight percentage from about 2% to 7%. A use of the glue for packaging a LED is also described.

Abstract: The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain hydrophilic monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices. The polymeric compositions comprise polymerized hydrophilic siloxanyl monomers.

Abstract: A modified polyaluminosiloxane obtained by treating a polyaluminosiloxane with a silane coupling agent represented by the formula (I): wherein each of R1, R2 and R3 is independently an alkyl group or an alkoxy group; X is a methacryloxy group, a glycidoxy group, an amino group, a vinyl group or a mercapto group, with proviso that at least two of R1, R2 and R3 are alkoxy groups. The photosemiconductor element encapsulating material of the present invention is suitably used for, for example, photosemiconductor devices mounted with blue or white LED elements (backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like).

Abstract: A tire composition is provided that may include a sulfur-functional linear polyorganosiloxane and an unsaturated elastomer. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group, which includes a thiocarbamate, a dithiocarbamate, or a derivative or analog of thiocarbamate or dithiocarbamate. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in tire compositions.

Abstract: A crosslinkable binder consisting of a base polymer selected from poly(meth)acrylates, polyesters, polyurethanes, polyamides, polyolefins, polyethers, copolymers of vinyl esters, silicones, wherin the binder has number-average molecular weight (MN) between 500 g/mol and 1 000 000 g/mol and contains at least one crosslinkable thiophene or pyrrole group in covalently bonded form.

Abstract: The present invention relates to a thermosetting silicone resin composition including a condensation reactable substituent group-containing silicon compound and an addition reactable substituent group-containing silicon compound; a silicone resin; a silicone resin sheet obtained from the thermosetting silicone resin composition or the silicone resin, and a use thereof.

Abstract: A water soluble functional polyethylene glycol-grafted polysiloxane polymer comprising a polysiloxane backbone and polyethylene glycol side chains is provided having the general formula: wherein A is selected from the group consisting of hydrogen, methyl, methoxy and functional polyethylene glycol based chains, B is a functional group for binding biologically-sensitive materials, D is a functional group for binding to a substrate, m is from 3 to 5, v is from 0 to 5, w is from 4 to 11, x is from 0 to 35 and z is from 1 to 33. In order to be water soluble, the polysiloxane polymer h the following properties: x+y+z is from 8 to 40, n is from 8 to 30, and y is from 7 to 35.

Abstract: A method of manufacturing an analytical sample by a secondary ion mass spectrometry method is provided, which comprises a step of forming a separation layer over a substrate, a step of forming one of a thin film and a thin-film stack body to be analyzed over the separation layer, a step of forming an opening portion in one of the thin film and the thin-film stack body, a step of attaching a supporting body to one of a surface of the thin film and a surface of a top layer of the thin-film stack body, and a step of separating one of the thin film and the thin-film stack body from the substrate.

Abstract: An adhesive composition comprising: 100 parts by weight of (A) a phenoxy resin having, per molecule, at least one alkoxy silane residue represented by the following formula (I) wherein R1 may be the same with or different from each other and is a substituted or unsubstituted C1-4 alkyl group, and R2 is a substituted or unsubstituted C1-9 monovalent group comprising a moiety selected from the group consisting of amino, cyanato, glycidoxy and thiol groups; 5 to 200 parts by weight of (B) an epoxy resin; a catalytic amount of (C) catalyst for curing the epoxy resin; and (D) an inorganic filler in an amount of from 33 to 300 parts by weight per total 100 parts by weight of the components (A), (B) and (C).

Abstract: A low index of refraction hybrid optical cladding may be formed from a fluorinated sol-gel. An electro-optic device may include a poled organic chromophore-loaded modulation layer and at least one adjacent fluorinated hybrid sol-gel clad.

Abstract: To provide a hardly colored curable composition having an excellent storage stability while maintaining fast curing properties. A curable composition which comprises a polymer (P) having a polyoxyalkylene chain and a group of the following formula (1) and a compound (S) having a mercapto group and a group of the following formula (2), and which contains from 0.01 to 0.50 part by mass of the compound (S) per 100 parts by mass of the polymer (P): —Si(—X1)3??(1) —Si(—X2)m(—Y2)3-m??(2) wherein symbols have the following meanings: X1 and X2: each independently a C1-6 alkoxy group, Y2: a C1-6 alkyl group, and m: 1, 2 or 3.

Abstract: A manufacturing method of ladder-like phosphorus-containing polysilsesquioxanes nanocomposite material is disclosed. The method uses a reaction between ladder-like phosphorus-containing polysilsesquioxanes and modified epoxy. Besides improved char yield and limiting oxygen index, thermal degradation rate of the nanocomposite material is lowered dramatically so that the nanocomposite material possesses excellent flame retardance and thermal stability. Moreover, optical transparency of the nanocomposite material according to the present invention is still good, not being reduced by increased amount of polysilsesquioxanes. Thus the nanocomposite material is applied to decorative paints or protective paints.

Abstract: A thermosetting composition containing an aluminosiloxane, a silicone oil containing silanol groups at both ends, and a silicone alkoxy oligomer. The thermosetting composition of the present invention can be used for, for example, encapsulating materials, coating materials, molding materials, surface-protecting materials, adhesive agents, bonding agents, and the like. Especially, in a case where the thermosetting composition of the present invention is used as an encapsulating material, the thermosetting composition is suitably used for, for example, photosemiconductor devices mounted with blue or white LED elements (backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like).

Abstract: The present invention concerns ?-silyl terminated polydiorganosiloxanes, a method of making the ?-silyl terminated polydiorganosiloxanes, and sealant compositions containing said compounds and a method of using such sealant compositions.

Abstract: The present invention relates to the in situ silyl end group functionalization of polymer chains which have been prepared by means of atom transfer radical polymerization and the simultaneous removal of transition metals from polymer solutions.

Abstract: A composition is provided that may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with an unsaturated elastomer. The invention may include embodiments that relate to method of making and using the sulfur-functional linear polyorganosiloxane.

Abstract: A linear polymer comprising carborane, siloxane, and acetylene units, which may be cross-linked to a cured polymer and/or pyrolyzed to a ceramic.

Abstract: This invention describes novel chemical compounds whose structures are hybrids between sulfur-containing and non-sulfur-containing silanes wherein the two types of silanes are linked by siloxane bonds. The invention includes methods of preparation for the hybrid silanes as well as their use in filled rubbers as coupling agents. The hybrid silanes described are unique in that a certain amount of water in their preparation leads to superior performance in their intended application, and that they can thus be produced more efficiently and safely than coupling agents currently used in the art, from readily available hydrated raw materials.

Abstract: Provided herein are hardmask compositions that include an organosilane polymer prepared by the reaction of one or more compounds of Formula (I) Si(OR1)(OR2)(OR3)R4 wherein R1, R2 and R3 may each independently be alkyl acetoxy or oxime; and R4 may be hydrogen, alkyl, aryl or arylalkyl; and wherein the organosilane polymer has a polydispersity in a range of about 1.1 to about 2.

Abstract: A light filter or an array of filters can be either one or two dimensional. The filter or filters use multiple beam interference by varying an optical path length between semi-reflective surfaces. The optical path length between the semi-reflective surfaces is varied by changing a thickness of a polymer film in response to an electric field formed between two semi-transparent electrodes. The filter can be configured in either a transmissive or reflective mode.

Abstract: Provided is a siloxane dispersant having a structure including a head part having an affinity for nanoparticles and a tail part having an affinity for a polydimethylsiloxane (PDMS) resin, and a nanoparticle paste composition comprising the same. The dispersant significantly improves dispersion efficiency of a polydimethylsiloxane resin system which is used in preparation of high-output light sources such as UV LEDs and the like.

Abstract: A silane-terminated polyurethane composition is the reaction product of a silane-terminated polyurethane prepolymer component, a silane-terminated monomeric diisocyanate, and optionally at least one multifunctional trisilane or tetrasilane component. A method for making a composition includes (a) providing a silane-terminated polyurethane prepolymer component, a silane-terminated monomeric diisocyanate component, and optionally at least one multifunctional trisilane or tetrasilane component, and (b) combining the prepolymer component, monomeric component, and optional multifunctional silane component to form a silane-terminated polyurethane reaction product with a tensile strength of about 4 MPa or greater and an elongation of about 200% or greater.

Abstract: A modified polyaluminosiloxane obtained by treating a polyaluminosiloxane with a silane coupling agent represented by the formula (I): wherein each of R1, R2 and R3 is independently an alkyl group or an alkoxy group; X is a methacryloxy group, a glycidoxy group, an amino group, a vinyl group or a mercapto group, with proviso that at least two of R1, R2 and R3 are alkoxy groups. The photosemiconductor element encapsulating material of the present invention is suitably used for, for example, photosemiconductor devices mounted with blue or white LED elements (backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like).

Abstract: A silicone resin containing boron, aluminum, and/or titanium, and having silicon-bonded branched alkoxy groups; a silicone composition containing a silicone resin; and a method of preparing a coated substrate comprising applying a silicone composition on a substrate to form a film and pyrolyzing the silicone resin of the film.

Abstract: The invention relates to new compounds of Formula 1: [(O3/2)Si CH2CH2SX]a [Si(O4/2)]b[Si(O3/2V)]C wherein X is selected from CH2A,[CH2CH2NR1]pR2, CHCOX1CH2COX2,(CH2)eCO Y[(CH2)eSCH2CH2Si(O3/2)]m[CO2(CH2)eSH]n wherein A is the residue of an amino acid or derivative or salt of an amino acid of formula CHNR1R2COX3; R1 and R2 are independently selected from hydrogen, C1-20alkyl, and C1-20alkylaryl C1-12acyl R is selected from hydrogen, metal ion, C1-5alkyl, P is 1 to 100 and e is 1 or 2; X1 and X2 are independently selected from OR and NR1R2; X3 is selected from OR, NR1R2 or known amino acids and proteins or derivatives thereof; and Y is the residue of polyol having z or fewer hydroxyl groups substituted and m+n+1 is less than or equal to z; the free valences of the silicate oxygen atoms are saturated by one or more of silicon atoms of other groups of Formula 1, hydrogen, a linear or branched C1-12-alkyl group or by end groups R33M1O1/2 or by cross-linking bridge members or by polymer chains R3qM1(OR4)gOk/2 or AI

Abstract: Silicone hydrogel contact lenses having ophthalmically acceptable surface wettabilities are obtained from pre-extracted polymerized silicone hydrogel contact lens products having relatively large amounts of removable or extractable materials. The silicone hydrogel contact lenses can be obtained from non-polar resin based contact lens molds and without surface treatments or an interpenetrating polymeric network of a polymeric wetting agent. Related lens products, polymerizable compositions, and methods are also described.

Abstract: Terminated silane polymers obtained by addition reactions between an organic silicon derivative and the terminal functional groups of linear or branched polymers obtained by Michael polyaddition reactions of sulphydric acid (H2S) with organic compounds which have at least two alkylenic double bonds activated by the presence, in the alpha position with respect to each alkylenic bond, of an electronegative group.

Abstract: A polysilane having excellent functionalities (e.g., solubility in a solvent and reactivity) is obtained by introducing a structural unit of the following formula (1) to a polysilane through a reaction of a dihalosilane having a Si—H bond and adding a hydrosilylatable compound (e.g., a compound having a carbon-carbon unsaturated bond) to the Si—H bond, wherein R1 represents a hydrogen atom, an organic group, or a silyl group; and “n” denotes an integer of not less than 1.

Abstract: Phosphono-substituted siloxanes suitable as interlayer material in lithographic substrates and for post-treating developed lithographic printing plates, obtainable by reacting (a) a first organosilicon compound of the general formula (I) and (b) a second organosilicon compound of the general formula (II).

Abstract: Hybrid silica polymer applicable to electrochemical elements and a method for economical production thereof, the former excelling in thermal stability, mechanical stability, solvent resistance, and proton conductivity at low humidity is provided. The method includes a step of heating a mixture of 3-mercaptopropyltrialkoxylsilane, surfactant, water, and base or acid for their reaction with one another at 25 to 180° C., thereby providing a hybrid thiol group-containing silica polymer, and an optional step of oxidizing said hybrid thiol group-containing silica polymer with a peroxide, thereby giving a hybrid silica polymer which is composed of hybrid (thiol group-containing and/or sulfonic group-containing) silica polymer. The resulting silica polymer is used as a proton conducting material for electrochemical elements such as fuel cells, capacitors, and electrolytic cells.

Abstract: The invention relates to new compounds of Formula 1: wherein R, R1, are each independently hydrogen, a linear or branched C1-40 alkyl, C2-40-alkenyl or C2-40-alkynyl group, an aryl or C1-40-alkylaryl group; X is H, OH, O(MnN)1/n or R4 where M is a metal ion derived from a lanthanide, actinide, main group or transition metal and V is a substituted C1-40-alkyl, C2-40-alkenyl or C2-40-alkynyl group or an aryl group or C1-40-alkylaryl sulfide, sulfoxide, sulfone, amine or a polyalkyl amine or phosphine or other phosphorous containing group; R4 is a linear or branched C1-40-alkyl, C2-40-alkenyl or C2-40-alkynyl group, an aryl or C1-40-alkylaryl group; e is an integer from 0 to 2; f is an integer from 1 to 100; n is an integer from 1 to 4: the free valences of the silicate oxygen atoms are saturated by one or more of: silicon atoms of other groups of Formula 1, hydrogen, a linear or branched C1-12-alkyl group or by cross-linking bridge members or by polymer chains (R2)2Si(OR3)1O1/2 or (R2)2SiO2/2 or (R2)3SiO1/2

Abstract: An organopolysiloxane containing both an amino functional organic group and a mercapto functional organic group is disclosed. A method of making such amino-mercapto functional organopolysiloxanes is by reacting (A) a silanol-functional polysiloxane, (B) an amino functional alkoxy silane, and (C) a mercapto functional alkoxy silane, via a condensation reaction. The amino-mercapto functional organopolysiloxanes products are useful in textile and fabric treatments.

Abstract: Phosphone ester modified organosilicon compounds are prepared by reacting phosphonic ester-functionalized alkoxysilane with a silanol-functional organosilicon compound. The product is produced in high yield and purity.