Silicon Reactant Contains A Silicon-to-hydrogen Bond Patents (Class 528/31)
  • Publication number: 20150087791
    Abstract: This invention is a vinylcarbosiloxane resin that is the hydrosilation reaction product of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane and a hydride-terminated linear polysiloxane, siloxane, or silane, having two terminal Si—H hydrogens reactive with vinyl groups in a hydrosilation reaction, in the presence of a platinum catalyst. Suitable hydride-terminated linear polysiloxanes, siloxances, and silanes include those having the structures: In another embodiment, the vinylcarbosiloxane resin can be reacted with one or more other hydrido-silanes and hydrido-polysiloxanes in the presence of a platinum catalyst to form a curable composition.
    Type: Application
    Filed: December 8, 2014
    Publication date: March 26, 2015
    Inventors: Shengqian Kong, Liwei Zhang, Yong Zhang, Wentao Thomas Xing, Daniel J. Duffy
  • Patent number: 8987358
    Abstract: The invention provides an adhesion-imparting agent having heat-resistant transparency and a high refractive index best suited for an addition hardening type composition including a reaction product of silsesquioxane and organopolysiloxane. The invention relates to a compound obtained by allowing a hydrosilylation addition reaction of (A), (B), and when necessary, (C) as described below, and a compound including an organopolysiloxane or silsesquioxane skeleton including as an essential component an isocyanuric ring skeleton and an epoxy group, and having an SiH group residue: (A) a compound including an organopolysiloxane or silsesquioxane skeleton and having three or more SiH groups in one molecule; (B) an epoxy derivative having one aliphatic unsaturated group in one molecule; and (C) organopolysiloxane having two alkenyl groups in one molecule, and having a number average molecular weight of 100 to 500,000, or an isocyanurate compound having two alkenyl groups in one molecule.
    Type: Grant
    Filed: June 28, 2012
    Date of Patent: March 24, 2015
    Assignee: JNC Corporation
    Inventors: Kiichi Kawabata, Akio Tajima, Takashi Matsuo, Yoshiko Watanabe, Koichi Ayama
  • Patent number: 8987401
    Abstract: Methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule are provided.
    Type: Grant
    Filed: June 14, 2012
    Date of Patent: March 24, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Kamesh R. Vyakaranam, Ling Zhang, Venkat S. Minnikanti, Rajat Duggal, William A. Koonce, Amarnath Singh, Phillip S. Athey
  • Publication number: 20150076552
    Abstract: A silicone resin composition contains a polysiloxane containing at least one pair of condensable substituted groups capable of condensation by heating and at least one pair of addable substituted groups capable of addition by an active energy ray.
    Type: Application
    Filed: November 19, 2014
    Publication date: March 19, 2015
    Applicant: NITTO DENKO CORPORATION
    Inventors: Haruka ONA, Hiroyuki KATAYAMA, Sadahiro NAKANISHI
  • Patent number: 8980973
    Abstract: The invention relates to a composition for taking dental impressions, the composition comprising a siloxane component (A) comprising terminal vinyl groups, a siloxane component (B) comprising Si—H groups, a catalyst (C) being able to catalyze a curing reaction between components (A) and (B) and a silicone oil (D), wherein the silicone oil has a viscosity at 23 DEG C of at least about 600,000 mPa*s and is present in an amount from about 1 to about 20 wt.% with respect to the weight of the whole composition. The invention also relates to a method of producing such a composition and a method for adjusting the Shore hardness A of a composition.
    Type: Grant
    Filed: June 5, 2012
    Date of Patent: March 17, 2015
    Assignee: 3M Innovative Properties Company
    Inventors: Peter Uwe Osswald, Hyung-Min Shim, Johann Fetz, Joachim Wilhelm Zech, Bernd Kuppermann
  • Patent number: 8974775
    Abstract: There is provided herein a functionalized ionic silicone composition comprising a silicone of the formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj??(I) which contains a monovalent radical bearing ion-pairs and having the formula (II): -A-Ix?Mny+; where A is a spacing group having at least 2 spacing atoms selected from a divalent hydrocarbon or hydrocarbonoxy group, where I is an ionic group such as sulfonate —SO3?, carboxylate —COO?, phosphonate —PO32? group and phosphate —OPO32?, where M is hydrogen or a cation independently selected from alkali metals, alkali earth metals, transition metals, metals, quaternary ammonium and phosphonium groups; or, zwitterions having the formula (III): —R?—NR?2+—R??—I??(III) where I is defined as above, and where the subscript a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2?a+b+c+d+e+f+g+h+i+j?6000, b+e+h>0 and c+f+i>0.
    Type: Grant
    Filed: January 4, 2012
    Date of Patent: March 10, 2015
    Assignee: Momentive Performance Materials Inc.
    Inventors: Anubhav Saxena, Alok Sarkar, Sandip Tiwari
  • Publication number: 20150048356
    Abstract: Provided are an adhesive film, and an organic electronic device (OED) encapsulation product using the same. Dimensional stability, lifespan, and durability may be enhanced even when a panel of an organic electronic device is large-sized and formed as a thin film by controlling dimensional tolerance and edge angular tolerance of the adhesive film, thereby ensuring long-term reliability, and process yields may be enhanced when the adhesive film is applied to an automation process.
    Type: Application
    Filed: October 29, 2014
    Publication date: February 19, 2015
    Inventors: Seung Min LEE, Suk Ky CHANG, Hyun Jee YOO, Jung Sup SHIM, Yoon Gyung CHO, Kyung Yul BAE
  • Patent number: 8957165
    Abstract: An addition-curable silicone composition that provides a cured product having a particularly high transparency, an excellent light extraction efficiency and a favorable strength characteristic by subjecting the cured product to a lower refractive index by using a specific composition. The present invention was accomplished by an addition-curable silicone composition, including at least: (A) a linear organopolysiloxane having 2 or more aliphatic unsaturated groups bonded to a silicon atom and 1 or more CF3—(CF2)y—(CH2)z— groups bonded to a silicon atom in one molecule; (B) an organopolysiloxane having 2 or more aliphatic unsaturated groups bonded to a silicon atom and 1 or more CF3—(CF2)y—(CH2)z— groups bonded to a silicon atom in one molecule and having a branch structure of a siloxane unit represented by an SiO4/2 and/or an RSiO3/2; (C) an organosilicon compound represented by the following general formula (1); and (D) a platinum group metal-based catalyst.
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: February 17, 2015
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuhiro Iwata, Toshiyuki Ozai, Yukito Kobayashi
  • Patent number: 8946350
    Abstract: Provided are a curable composition and its use. The curable composition can exhibit excellent processibility and workability. The curable composition exhibits excellent light extraction efficiency, hardness, thermal and shock resistance, moisture resistance, gas permeability and adhesiveness, after curing. In addition, the curable composition can provide a cured product that exhibits long-lasting durability and reliability even under harsh conditions, and that does not cause whitening and surface stickiness.
    Type: Grant
    Filed: July 29, 2013
    Date of Patent: February 3, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Min Jin Ko, Jae Ho Jung, Bum Gyu Choi, Min A Yu
  • Patent number: 8946369
    Abstract: Branched polysiloxanes of formula (I) Ma1MHa2MVia3Db1DHb2DVib3Tc1THc2TVic3Qd??(I) wherein M=[R2R12SiO1/2], MH=[R12HSiO1/2], MVi=[R3R12SiO1/2], D=[R12SiO2/2], DH=[R1HSiO2/2], DVi=[R1R3SiO2/2], T=[R4SiO3/2], TH=[HSiO3/2], TVi=[R3SiO3/2], Q=[SiO4/2], R1 is mutually independently identical or different, linear or branched, saturated or unsaturated hydrocarbon moieties, R2 is mutually independently the same as R1, an alkoxy moiety or a hydroxy group, R3 is mutually independently identical or different, linear or branched, olefinically unsaturated hydrocarbon moieties, R4 is mutually independently R1 or identical or different linear, branched and/or cyclic, saturated or unsaturated hydrocarbon moieties comprising heteroatoms, a1=from 0 to 50, a2=from 1 to 50, a3=from 1 to 50, b1=from 10 to 5000, b2=from 0 to 30, b3=from 0 to 30, c1=from 0 to 50, c2=from 0 to 50 c3=from 0 to 50, d=from 0 to 50, with the proviso that the sum c1+c2+c3+d is greater than or equal to 1, are provided.
    Type: Grant
    Filed: February 20, 2013
    Date of Patent: February 3, 2015
    Assignee: Evonik Degussa GmbH
    Inventors: Frauke Henning, Sadik Amajjahe, Ute Linke, Michael Ferenz, Wilfried Knott, Volker Arning, Bastian Matthias Brugger, Kathrin Lehmann
  • Patent number: 8940852
    Abstract: The present invention is a method for manufacturing a reactive polysiloxane solution, the method comprising: a condensation process for hydrolyzing and copolycondensing a starting compound containing an organosilicon compound having a reactive functional group selected from a (meth)acryloyl group and an oxetanyl group, and also having a siloxane bond-forming group to synthetize a reactive polysiloxane represented by general formula (1); a dissolution process for dissolving the obtained reactive polysiloxane in an organic solvent for water washing; and a washing process for bringing the obtained organic solution and water in contact with each other to remove the water layer from the mixed liquid. The organic solvent for water washing that is used is a compound (e.g., propylene glycol mono butyl ether, 1-pentanol) including a hydroxyl group, having a boiling point at 1 atm of 110° C.-200° C., and a solubility of 10 g or less in 100 g of water at 20° C.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: January 27, 2015
    Assignee: Toagosei Co., Ltd.
    Inventors: Naomasa Furuta, Akinori Kitamura
  • Patent number: 8937136
    Abstract: A curable composition and use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.
    Type: Grant
    Filed: July 5, 2013
    Date of Patent: January 20, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
  • Patent number: 8937131
    Abstract: Provided are a curable composition and its use. The curable composition can exhibit excellent processability and workability. The curable composition exhibits excellent light extraction efficiency, hardness, thermal and shock resistance, moisture resistance, gas permeability and adhesiveness, after curing. In addition, the curable composition can provide a cured product that exhibits long-lasting durability and reliability even under harsh conditions, and that does not cause whitening and surface stickiness.
    Type: Grant
    Filed: July 29, 2013
    Date of Patent: January 20, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Min Jin Ko, Jae Ho Jung, Bum Gyu Choi, Min A Yu
  • Patent number: 8933187
    Abstract: Disclosed herein are self-crosslinking compositions containing a hydrosilation catalyst and the reaction product of a mixture comprising (i) a resinous copolymer having both silicon-bonded hydrogen and silanol groups, and (ii) one or more vinyl-functional polyorganosiloxanes. These compositions have stable post-cure adhesive properties and are suitable for use in electronic applications.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: January 13, 2015
    Assignee: Momentive Performance Material Inc.
    Inventor: Roy Melvin Griswold
  • Patent number: 8933186
    Abstract: Disclosed are novel polyorganosiloxane, a polycarbonate resin composition comprising the same and a modified polycarbonate resin. Disclosed is also a novel polyorganosiloxane derivative which may be utilized in various applications and is used in particular as an impact modifier, a modifier or a comonomer of polycarbonate resin.
    Type: Grant
    Filed: February 1, 2013
    Date of Patent: January 13, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Hyong Min Bahn, Moo Ho Hong, Young Young Hwang, Min Jeong Kim, Jung Jun Park
  • Patent number: 8933177
    Abstract: To provide a release modifier which provides a heavy release force to a cured release layer of silicone coating composition. The release modifier comprises an organopolysiloxane resin-organopolysiloxane condensation reaction product that is obtained by the condensation reaction of (a1) 100 weight parts of MQ-type organopolysiloxane resin in which the molar ratio of the M unit to the Q unit is 0.6 to 1.0 and the content of the hydroxyl group or alkoxy group is 0.3 to 2.0 weight % with (a2) 20 to 150 weight parts of chain-form diorganopolysiloxane that has an average degree of polymerization of 100 to 1000 and at least one hydroxyl group or alkoxy group; this organopolysiloxane resin-organopolysiloxane condensation reaction product preferably has a prescribed hydroxyl group content.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: January 13, 2015
    Assignee: Dow Corning Toray Company, Ltd.
    Inventors: Seiji Hori, Takateru Yamada, Chung Mien Kuo
  • Patent number: 8925626
    Abstract: A substrate is surface treated using a composition for forming a film that comprises (A) an organoalkoxysilane, (B) an organopolysiloxane having a silicon-bonded hydrogen atom, and (C) a condensation reaction catalyst. This composition for forming a film can form a highly hydrophobic water repellent film provided with sufficient water shedding performance. It is possible to provide a highly hydrophobic substrate such as a heat dissipating body.
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: January 6, 2015
    Assignee: Dow Corning Toray Co., Ltd.
    Inventors: Keiichi Akinaga, Tadashi Okawa, Kazuhiro Nishijima, Eiji Kitaura
  • Patent number: 8927674
    Abstract: Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation and crosslinking catalysts.
    Type: Grant
    Filed: August 14, 2013
    Date of Patent: January 6, 2015
    Assignees: Princeton University, Momentive Performance Materials Inc.
    Inventors: Cristia Carmen Hojilla Atienza, Paul J. Chirik, Susan Nye, Kenrick M. Lewis, Keith J. Weller, Julie L. Boyer, Johannes G. P. Delis, Aroop Roy, Eric Pohl
  • Patent number: 8921496
    Abstract: A curable composition and use thereof are provided. The exemplary curable composition can show excellent processability and workability. Also, the curable composition can have a high refractive index before or after curing. The composition has low moisture permeability before or after curing and shows excellent crack resistance, thermal shock resistance, adhesive property and hardness. In addition, the composition does not cause color change such as whitening, under a high-temperature or high-humidity condition, and does not exhibit stickiness on a surface thereof. The curable composition may be used as an adhesive material or as an encapsulation material for semiconductor devices such as an LED, a CCD, a photo coupler, or a photovoltaic cell.
    Type: Grant
    Filed: July 5, 2013
    Date of Patent: December 30, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Bum Gyu Choi, Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
  • Patent number: 8920931
    Abstract: A phosphosiloxane resin comprises a plurality of covalently bonded monomer units selected from phosphosiloxane units SiR23—O—P(?O)(R1)—(OR3)q(O1/2—)p and organosiloxane units R2m(OR3)nSiO(4-m-n)/2. R1 and each R2 are independently selected from the group consisting of hydrogen, C1 to C10 hydrocarbyl, and C1 to C10 hydrocarbylene; each R3 is independently selected from the group consisting of hydrogen and C1 to C10 hydrocarbyl; p is 0 or 1; q=1?p; m is 0, 1, 2, 3, or 4; n is 0, 1, or 2; and m+n is 0, 1, 2, 3, or 4. Curable silicone compositions comprise a phosphosiloxane resin having greater than one silicon-bonded alkenyl group, an organosilicon compound having at least two silicon-bonded hydrogen atoms, and a hydrosilylation catalyst. Fiber-reinforced free-standing films may comprise fibers dispersed in a cured product of the silicone composition. Laminated substrates comprise at least one fiber-reinforced free-standing film.
    Type: Grant
    Filed: August 23, 2011
    Date of Patent: December 30, 2014
    Assignee: Dow Corning Corporation
    Inventor: Bizhong Zhu
  • Patent number: 8916669
    Abstract: Embodiments of the invention provide for a method of producing a silylated polyoxyalkylene polymer having at least one crosslinkable silyl group and at least one hydroxyl group in each molecule. The method comprises providing a polyoxyalkylene polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, wherein the polyoxyalkylene polymer includes an impurity double metal cyanide complex mixed therein, and wherein the polyoxyalkylene polymer has not been treated with a metal-coordinating compound; and adding to the polyoxyalkylene polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction, wherein the hydrosilyation reaction is performed in an absence of a metal-coordinating compound.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: December 23, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Ling Zhang, Daniel A. Aguilar, Debkumar Bhattacharjee, William A. Koonce, Basudeb Saha
  • Patent number: 8916670
    Abstract: The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that has high ionic conductivity and is mechanically robust. An exemplary material can be characterized by a copolymer that includes at least one structural block, such as a vinyl polymer, and at least one ionically conductive block with a siloxane backbone. In various embodiments, the electrolyte can be a diblock copolymer or a triblock copolymer. Many uses are contemplated for the solid polymer electrolyte materials. For example, the novel electrolyte material can be used in Li-based batteries to enable higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.
    Type: Grant
    Filed: February 25, 2014
    Date of Patent: December 23, 2014
    Assignee: Seeo, Inc.
    Inventors: Bing R. Hsieh, Hany Basam Eitouni, Mohit Singh
  • Publication number: 20140360367
    Abstract: This invention relates to organopolysiloxane compounds. In some embodiments, the organopolysiloxane compound includes a siloxane unit having at least one trialkylsilyl pendant group attached thereto through an organic group spacer. The present invention also relates to methods of making the organopolysiloxane, a hydrosilylation-curable silicone composition including the organopolysiloxane, a cured product of the silicone composition, a membrane including the cured product, a method of making the membrane, and a method of separating components in a feed mixture using the membrane.
    Type: Application
    Filed: December 27, 2012
    Publication date: December 11, 2014
    Inventors: Dongchan Ahn, James S. Hrabal, Alexandra N. Lichtor
  • Patent number: 8907036
    Abstract: Self-adhesive crosslinkable silicone compositions may be transparent and prepared without conventional adhesion promoters, and contain (1) an organopolysiloxane having a minimum of two aliphatically unsaturated carbon-carbon bond-containing groups, (2) a pendant Si—H functional organopolysiloxane having at least 3 Si—H groups and a minimum of 0.7 weight percent of Si-bonded hydrogen, and (3) a linear organopolysiloxane bearing terminal Si—H groups, wherein the mol ratio of silicon-bonded hydrogen in (2) to that in [(2) and (3)] is from 0.05 to 1.
    Type: Grant
    Filed: February 17, 2012
    Date of Patent: December 9, 2014
    Assignee: Wacker Chemie AG
    Inventor: Christian Ochs
  • Patent number: 8907038
    Abstract: A material suitable for sealing an LED element or for a gas barrier layer for a resin component, and an LED device, an FPD device and a semiconductor device using it. A process for producing a polymer composition, which includes mixing and reacting as component (A), an unsaturated group-containing siloxane compound of the following formula (1): wherein the siloxane structure is a chain or cyclic structure, as component (B), a siloxane compound having a structure of the following formula (2) wherein hydrogen is directly bonded to silicon, wherein the siloxane structure is a chain or cyclic structure, as component (C), at least one member selected from the group consisting of organic metal compounds of Group 1, 2, 12, 13 and 14 metals of the periodic table, and as component (D), a metal catalyst of Group 8, 9 or 10 metal of the periodic table.
    Type: Grant
    Filed: June 8, 2011
    Date of Patent: December 9, 2014
    Assignee: Tosoh Corporation
    Inventors: Daiji Hara, Masato Shimizu
  • Patent number: 8907023
    Abstract: The present invention relates to a polysiloxane compound having a structure represented by formula 1: wherein each of F1, F2, F3 and F4 is individually selected from one of a first group, a second group, a third group and a fourth group, the first group is selected from a C2˜C10 hydrocarbon group having amino group(s), a C2˜C10 hydrocarbon group having epoxy group(s), a C2˜C10 hydrocarbon group having carbonyl group(s) or a C2˜C10 hydrocarbon group having alkoxy group(s), the second group is a C2˜C10 hydrocarbon group having amino group(s), the third group is selected from a C2˜C10 hydrocarbon group having epoxy group(s), a C2˜C10 hydrocarbon group having carbonyl group(s), a C2˜C10 hydrocarbon group having SiCl group(s) or a C2˜C10 hydrocarbon group having alkoxy group(s), the fourth group is selected from a C2˜C10 hydrocarbon group having aryl group(s) or a C2˜C10 hydrocarbon group having alkoxy group(s).
    Type: Grant
    Filed: August 7, 2013
    Date of Patent: December 9, 2014
    Assignee: Chi Mei Corporation
    Inventors: Kuan-Lin Hsieh, Kuei-Lun Cheng, Chih-Cheng Lee
  • Patent number: 8900668
    Abstract: The disclosure relates to curable polyureasil compounds, methods related to curing of such compounds via hydrolysis and/or condensation to form coatings on a substrate, and coated articles formed from the curable polyureasil compounds. The polyureasil compounds are generally hydrocarbon-based, including multiple urea groups and multiple hydrolysable silyl groups per molecule. The hydrolysable silyl groups can be hydrolyzed and subsequently condensed to provide a networked polymeric structure with siloxane/urea linkages between polyureasil compound precursors to form a cured polyureasil composition useful as a coating for a substrate, in particular an anti-corrosion coating for a metallic substrate.
    Type: Grant
    Filed: April 5, 2012
    Date of Patent: December 2, 2014
    Assignee: Eastern Michigan University
    Inventor: Vijaykumar M. Mannari
  • Patent number: 8889811
    Abstract: Provided is a curable composition and its use. The curable composition may exhibit excellent processibility and workability. The curable composition has excellent light extraction efficiency, crack resistance, hardness, thermal and shock resistance and an adhesive property after curing. The curable composition may provide a cured product exhibiting stable durability and reliability under severe conditions for a long time, and having no whitening and surface stickiness.
    Type: Grant
    Filed: December 23, 2013
    Date of Patent: November 18, 2014
    Assignee: LG Chem, Ltd.
    Inventors: Min Jin Ko, Myung Sun Moon, Jae Ho Jung, Bum Gyu Choi, Dae Ho Kang, Min Kyoun Kim, Byung Kyu Cho
  • Patent number: 8889809
    Abstract: One object of the present invention is to provide a silicone resin composition having remarkably low gas permeability which is useful for a purpose requiring lower gas permeability. Further, another object of the present invention is to provide an optical semiconductor device provided with a cured product obtained by curing the silicone resin composition which has discoloration resistance, durable reflection efficiency and high reliability. The present invention provides a silicone resin composition comprising (A) an organopolysiloxane having at least two alkenyl groups per molecule, and is represented by the average compositional formula (1), (B) an organohydrogenpolysiloxane having at least two hydrogen atoms bonded to a silicon atom, and is represented by the average compositional formula (2), (C) a catalytic amount of a curing catalyst, and (D) 0.001 to 3 parts by mass of an antioxidant, relative to a total 100 parts by mass of components (A) and (B).
    Type: Grant
    Filed: June 21, 2011
    Date of Patent: November 18, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshihira Hamamoto, Tsutomu Kashiwagi
  • Publication number: 20140332987
    Abstract: Provided is a curable resin composition capable of forming a cured product which has excellent heat resistance, transparency, and flexibility and particularly excels in reflow resistance and barrier properties to a corrosive gas. The curable resin composition includes a ladder-type polyorganosilsesquioxane and an isocyanurate compound such as a triglycidyl isocyanurate compound, a monoallyl diglycidyl isocyanurate compound, a diallyl monoglycidyl isocyanurate compound, or a triallyl isocyanurate compound.
    Type: Application
    Filed: December 19, 2012
    Publication date: November 13, 2014
    Inventors: Shigeaki Kamuro, Yasunobu Nakagawa
  • Patent number: 8883950
    Abstract: A silicone resin composition contains a silicon-containing component including a silicon atom to which a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group is bonded and a silicon atom to which an alkenyl group is bonded. The number of moles of alkenyl group per 1 g of the silicon-containing component is 200 to 2000 ?mol/g.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: November 11, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Ryuichi Kimura, Munehisa Mitani
  • Patent number: 8877885
    Abstract: Embodiments of the invention provide for methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The method comprises providing a polymer having at least one unsaturated group and at least one alcoholic hydroxyl group in each molecule, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polyoxyalkylene polymers, reacting the hydrosilylated polyoxyalkylene polymers with at least one isocyanate in the presence of a first tin-free catalyst to form an isocyanate reacted hydrosilylated polymer, and optionally reacting the isocyanate reacted hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form a polyol reacted crosslinkable silane-terminated polymer.
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: November 4, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Kamesh R. Vyakaranam, Ling Zhang, William A. Koonce, Juan Carlos Medina, Ganesh Kailasam, Rajat Duggal, Nathan Wilmot
  • Patent number: 8877860
    Abstract: A two-part curable liquid silicone rubber composition comprises a first liquid composition and a second liquid composition. The first and second liquid compositions are stored separately and yield, upon mixing, a silicone rubber forming composition. The silicone rubber composition comprises: (A) an alkenyl group-containing organopolysiloxane comprising (A-1) an organopolysiloxane having only a silicon-bonded alkenyl group at each molecular terminal and (A-2) an organopolysiloxane having from 1 to 4 silicon-bonded alkenyl groups in side molecular chains and containing not greater than 2.0 wt. % of alkenyl groups; (B) a calcium carbonate powder; (C) a hydrosilylation reaction catalyst; and (D) an organohydrogenpolysiloxane having silicon-bonded hydrogen atoms.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: November 4, 2014
    Assignee: Dow Corning Toray Co., Ltd.
    Inventors: Tomoko Tasaki, Yuichi Tsuji
  • Patent number: 8877886
    Abstract: To provide a method of producing a polyoxyalkylene-modified polysiloxane composition that is free of acid-mediated carbon-oxygen bond and silicon-oxygen bond cleavage, that is substantially deodorized and also does not generate odor with elapsed time, and that is therefore well suited for use in cosmetic applications, e.g., for hair cosmetics, skin cosmetics, and so forth. A production method of this invention is characterized by removing the odor-causing substance from a polyoxyalkylene-modified polysiloxane composition that has been synthesized by a hydrosilylation reaction, by subjecting the polyoxyalkylene-modified polysiloxane composition to a hydrolysis treatment in the presence of an acidic inorganic salt that is a solid at 25° C. and gives a specific pH at 25° C. in aqueous solution; for example, potassium hydrogensulfate.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: November 4, 2014
    Assignee: Dow Corning Toray Co., Ltd.
    Inventors: Tatsuo Souda, Seiki Tamura
  • Patent number: 8871867
    Abstract: The invention discloses a terminal-modified conjugated diene-vinyl aromatic copolymer and a method for manufacturing the same. The method comprises the following steps. An organic alkali metal initiator is added into a first mixture containing a conjugated diene monomer and a vinyl aromatic hydrocarbon monomer to perform reaction to obtain a conjugated diene-vinyl aromatic copolymer with active terminal. The conjugated diene-vinyl aromatic copolymer with active terminal reacts with polysiloxane to obtain a terminal-modified conjugated diene-vinyl aromatic copolymer. The aforementioned polysiloxane is expressed as chemical formula (I): R1, R2, R3 and R5 independently are alkyl group with 1˜20 carbon atoms. R4 is selected from one of alkyl group, alkoxy group or hydroxyl group with 1˜5 carbon atoms, m is an integer of 2˜50, and n is an integer of 0˜50.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: October 28, 2014
    Assignee: Chi Mei Corporation
    Inventors: Kuei-Lun Cheng, Chen-Pao Huang
  • Patent number: 8871890
    Abstract: Disclosed is a curable resin composition which includes a ladder-type silsesquioxane (A) having an aliphatic carbon-carbon double bond in the molecule; a ladder-type silsesquioxane (B) having a Si—H bond in the molecule; and a hydrosilylation catalyst. The curable resin composition is useful as sealants typically for optical semiconductor elements. Also disclosed is a cured article which is obtained by curing the curable resin composition. The curable resin composition can give such a cured article having properties including resistance to elevated temperatures, flexibility, transparency, resistance to thermal yellowing, and resistance to photoyellowing.
    Type: Grant
    Filed: October 31, 2011
    Date of Patent: October 28, 2014
    Assignee: Daicel Corporation
    Inventors: Keizo Inoue, Shigeaki Kamuro
  • Patent number: 8865858
    Abstract: The present invention relates to a process for producing a composite material composed of a) at least one oxidic phase and b) an organic polymer phase. The copolymerization of at least one compound of the formula I [(ArO)mMOnRrHp]q??(I) in which M is B, Al, Ga, In, Si, Ge, Sn, P, As or Sb, Ar is phenyl or naphthyl, R is alkyl, alkenyl, cycloalkyl or aryl, where aryl is unsubstituted or may have one or more substituents, with formaldehyde or formaldehyde equivalents, in a reaction medium which is essentially anhydrous, to obtain a composite material having an arrangement of phase domains similar to those nanocomposite materials obtainable by twin polymerization, and to the use of the composite material for production of gas storage materials, rubber mixtures, low-K dielectrics and electrode materials for lithium ion batteries.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: October 21, 2014
    Assignee: BASF SE
    Inventors: Arno Lange, Gerhard Cox, Hannes Wolf, Szilard Csihony
  • Patent number: 8865320
    Abstract: A light-emitting device including: a substrate; a light-emitting diode; and an optical resonance layer to resonate light emitted from the light-emitting diode. The optical resonance layer includes a first layer, including a polysilsesquioxane-based copolymer. A linking group connecting two different silicon (Si) atoms of the polysilsesquioxane-based copolymer can be —O—, or a substituted or unsubstituted C1-C30 alkylene group.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: October 21, 2014
    Assignees: Samsung Display Co., Ltd., Seoul National University Industry Foundation
    Inventors: Sun-Young Lee, Jong-Hyuk Lee, Young-Woo Song, Joon-Gu Lee, So-Young Lee, Do-Young Yoon
  • Patent number: 8859635
    Abstract: Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: October 14, 2014
    Assignee: Bluestar Silicones France SAS
    Inventors: John White, Michel Feder, Alain Pouchelon, Yassine Maadadi, Lucile Gambut-Garel
  • Patent number: 8847414
    Abstract: A resin for an encapsulation material includes a first polysiloxane including hydrogen bound to silicon (Si—H) at its terminal end, and a second polysiloxane including an alkenyl group bound to silicon (Si—Vi) at its terminal end, wherein a ratio (Si—H/Si—Vi) of hydrogen bound to silicon (Si—H) in the first polysiloxane to the alkenyl group bound to silicon (Si—Vi) in the second polysiloxane is about 1 to about 1.
    Type: Grant
    Filed: December 29, 2011
    Date of Patent: September 30, 2014
    Assignee: Cheil Industries, Inc.
    Inventors: Sung-Hwan Cha, Sang-Ran Koh, Yong Kook Kim, Woo-Han Kim, Ha Neul Kim, Chi Won An
  • Patent number: 8846507
    Abstract: Compositions and methods for controlled polymerization and/or oligomerization of hydrosilanes compounds including those of the general formulae SinH2n and SinH2n+2 as well as alkyl- and arylsilanes, to produce soluble silicon polymers as a precursor to silicon films having low carbon content.
    Type: Grant
    Filed: May 17, 2013
    Date of Patent: September 30, 2014
    Assignee: Thin Film Electronics ASA
    Inventors: Dmitry Karshtedt, Joerg Rockenberger, Fabio Zurcher, Brent Ridley, Erik Scher
  • Patent number: 8841400
    Abstract: The invention relates to organomodified additives, emulsifiers, dispersants and/or active nourishing ingredients present in the silicon part of branched siloxane block copolymers, to the use thereof, in particular for producing cosmetic, dermatological or pharmaceutical formulations as well as care and cleansing products, and to the preparations as such. Specifically the invention relates to branched polysiloxanes having trifunctional T units as well as polyether groups, alkyl radicals of more than 7 carbon atoms or multi-hydroxy functional radicals.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: September 23, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Frauke Henning, Juergen Meyer, Christian Hartung, Michael Ferenz, Wilfried Knott, Sascha Herrwerth
  • Patent number: 8835555
    Abstract: The present invention has an objective to easily obtain an emulsion exhibiting superior storage stability, and in particular, an emulsion of a polyorganosiloxane. The present invention provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of an oil and a surfactant, obtained by synthesizing the surfactant in the oil. In particular, the method is suitably used for the preparation of an emulsion of an organopolysiloxane (A) which is usually difficult to be stably emulsified. A silicone-based surfactant (B), and in particular, a silicone-based surfactant having a small degree of polymerization of a siloxane chain such as a trisiloxane is synthesized in an oil. Thereby, an emulsion exhibiting superior storage stability can be produced.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: September 16, 2014
    Assignee: Dow Corning Toray Co. Ltd.
    Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima
  • Publication number: 20140255373
    Abstract: The present invention relates to an alpha-alkoxysilane-terminated prepolymer preparable by reaction of at least one polyether polyol, of a polyisocyanate and of an alpha-alkoxysilane having at least one isocyanate-reactive group, said polyether polyol having a weight average of 500 to 7000 g/mol and having ethylene oxide and propylene oxide units, the proportion of ethylene oxide units being up to 50% by weight based on the polyether polyol. The invention further provides a process for preparing an inventive alpha-alkoxysilane-terminated prepolymer, a composition, a multicomponent system and a spray can comprising an inventive alpha-alkoxysilane-terminated prepolymer, and also a moulding obtainable by polymerization from an inventive alpha-alkoxysilane-terminated prepolymer.
    Type: Application
    Filed: September 25, 2012
    Publication date: September 11, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventor: Jan Schönberger
  • Patent number: 8829141
    Abstract: This invention relates to a silicone oil emulsion that contains cross-linked silicone particles in drops of silicone oil which have an average particle diameter of 0.1 to 500 ?m and are dispersed in water, wherein the silicone oil contains epoxy groups, acryl groups, methacryl groups, silicon-bonded alkoxy groups, or silicon-bonded hydroxyl groups but is free of silicon-bonded hydrogen atoms and alkenyl groups, said cross-linked silicone particles is formed by a hydrosilation reaction. Furthermore, this invention also relates to a silicone oil composition obtained by removing water from said emulsion.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: September 9, 2014
    Assignee: Dow Corning Toray Co., Ltd.
    Inventors: Yoshitsugu Morita, Kazuo Kobayashi
  • Patent number: 8828551
    Abstract: The general field of the invention is that of airbags. The invention relates to a process for improving the tear strength and the combing strength of coated fabrics intended for uses in the field of inflatable bags, using a silicone composition comprising an additive consisting of a polyorganosiloxane resin (V) and a calcium carbonate. After coating the composition onto the fabric supports and curing, the coated supports not only have optimum adhesion and crease resistance properties, but also have good properties in terms of combing strength and tear strength.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: September 9, 2014
    Assignee: Bluestar Silicones France SAS
    Inventors: Laurent Dumont, Alain Pouchelon
  • Patent number: 8822626
    Abstract: Embodiments of the invention provide for compositions including a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer comprises a reaction product of at least a isocyanate capped hydrosilylated polymer and a polyol having a nominal functionality of at least 2 which is at least one of a polycarbonate polyol, a natural oil based polyol, a polyoxyalkyleneamine, a difunctional aromatic amine, a polybutyloxide polyether polyol, and a polytetramethylene glycol.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: September 2, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Kameswara R. Vyakaranam, Ling Zhang, William A. Koonce, Sara Arshad, Venkat S. Minnikanti, Dwight D. Latham, Phillip S. Athey
  • Patent number: 8809478
    Abstract: A curable composition includes: 100 parts by mass of a silicon-containing polymer having a Mw of 3,000 to 100,000 obtainable by hydrolysis-condensation of an organosilane mixture including R1SiX3, R2SiX3, R3R4SiX2 and R5SiX3, the total of R2SiX3 and R3R4SiX2 being 5 to 60 mol %, optionally a prepolymer, optionally a cyclic siloxane compound, 0.0001 to 10 parts by mass of an organic peroxide and optionally a metal catalyst, and 10 to 1,500 parts by mass of a filler, wherein R1 is a C2-6 alkenyl group, R2 is a C1-6 alkyl group, R3 and R4 are each a C1-6 alkyl group, R5 is a phenyl group optionally substituted with a C1-6 alkyl group, and X is a C1-6 alkoxy group, one or more of R2 to R4 is a methyl group, f represents a number of 2 to 10, g represents a number of 0 to 8, and n represents 1 or 2.
    Type: Grant
    Filed: June 6, 2011
    Date of Patent: August 19, 2014
    Assignee: Adeka Corporation
    Inventors: Masako Saito, Ichiro Hiratsuka, Masahiro Wada, Ryota Chiba, Takuya Kanazawa, Osamu Yoshioka, Takehito Tsukamoto, Junko Toda
  • Patent number: 8809482
    Abstract: This invention pertains to silsesquioxane resins useful in antireflective coatings wherein the silsesquioxane resin comprises the units (Ph(CH2)rSiO(3-x)/2(OR?)x)m (HSiO(3-x)/2(OR?)x)n (MeSiO(3-x)/2(OR?)x)o (RSiO(3-x)/2(OR?)x)p (R1SiO(3-x)/2(OR?)x)q where Ph is a phenyl group, Me is a methyl group; R? is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R is selected from a carboxylic acid group, a carboxylic acid forming group, and mixtures thereof; and R1 is selected from substituted phenyl groups, ester groups, polyether groups; mercapto groups, sulfur-containing organic functional groups, hydroxyl producing group, aryl sulphonic ester groups, and reactive or curable organic functional groups; and r has a value of 0, 1, 2, 3, or 4; x has a value of 0, 1 or 2; wherein in the resin m has a value of 0 to 0.90; n has a value of 0.05 to 0.99; o has a value of 0 to 0.95; p has a value of 0.01 to 0.5; q has a value of 0 to 0.5; and m+n+o+p+q?1.
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: August 19, 2014
    Assignee: Dow Corning Corporation
    Inventors: Peng-Fei Fu, Eric Moyer, Craig Yeakle
  • Patent number: 8810046
    Abstract: A silicone resin composition contains a cage octasilsesquioxane having a group represented by the following formula (1), an alkenyl group-containing polysiloxane containing an alkenyl group having a number of moles larger than that of a hydrosilyl group in the cage octasilsesquioxane, a hydrosilylation catalyst, and an organohydrogenpolysiloxane. (where, in formula, R1 represents a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group. R2 represents hydrogen or a monovalent hydrocarbon group selected from a saturated hydrocarbon group and an aromatic hydrocarbon group. The molar ratio of the monovalent hydrocarbon group:hydrogen in R2 in the cage octasilsesquioxane as a whole is, as an average value, in the range of 6.5:1.5 to 5.5:2.5).
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: August 19, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Haruka Ona, Hiroyuki Katayama