From Phosphorus-containing Reactant Patents (Class 528/398)
  • Publication number: 20020091230
    Abstract: Biodegradable terephthalate polymers are described comprising the recurring monomeric units shown in formula I: 1
    Type: Application
    Filed: August 2, 2001
    Publication date: July 11, 2002
    Inventors: Hai-Quan Mao, Kam W. Leong, Wenbin Dang, Hungnan Lo, Zhong Zhao, David P. Nowotnik, James P. English
  • Patent number: 6403237
    Abstract: Provided is a high heat-resistant polymeric fluorescent substance having a divalent condensed polycyclic aromatic group of specific size having a bonding part at specific position shows fluorescence at a long wave length from orange to red, which is useful for fabricating an organic EL device having excellent properties by a coating method.
    Type: Grant
    Filed: June 8, 1999
    Date of Patent: June 11, 2002
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Takanobu Noguchi, Masamitsu Ishitobi, Makoto Kitano
  • Publication number: 20020062004
    Abstract: The present invention relates to a molecular weight-enlarged, homogeneously soluble ligand, which includes:
    Type: Application
    Filed: January 24, 2001
    Publication date: May 23, 2002
    Inventors: Hans-Peter Krimmer, Jens Woeltinger, Olaf Burkhardt, Ingo Klement, Hans Henniges, Karlheinz Drauz, Andreas Bommarius, Jean-Louis Philippe, Andreas Karau
  • Publication number: 20020058779
    Abstract: High refractive index, melt processable polyphosphonates and methods for preparing the same are provided. These polymers are particularly useful for optical and ophthalmic parts, such as lenses. A method of preparing optical and ophthalmic lenses by injection molding the polymers of the present invention into the form of the optical or ophthalmic lenses is also provided.
    Type: Application
    Filed: June 22, 2001
    Publication date: May 16, 2002
    Applicant: Johnson & Johnson Vision Products, Inc., and Virginia Tech Intellectual Properties, Inc.
    Inventors: Hosadurga K. Shobha, Venkat Sekharipuram, James E. McGrath, Atul Bhatnagar
  • Patent number: 6380349
    Abstract: The present invention relates to golf equipment, such as golf shoes, golf clubs, golf gloves, or portions thereof, formed from compositions comprising a sulfonated, carboxylated, or phosphonated acid moieties, or a mixture thereof. The preferred ionomer composition comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers, and mixtures thereof. The compositions include a blend of about 1 weight % to about 99 weight % of at least one sulfonated, carboxylated, or phosphonated ionomer and about 99 weight % to about 1 weight % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer, or mixtures thereof.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: April 30, 2002
    Assignee: Acushnet Company
    Inventor: Murali Rajagopalan
  • Patent number: 6376644
    Abstract: Biodegradable polymers are described comprising the recurring monomeric units shown in formula I or II: wherein X is —O— or —NR′—, where R′ is H or alkyl; L is a branched or straight chain aliphatic group having from 1-20 carbon atoms; M1 and M2 are each independently (1) a branched or straight chain aliphatic group having from 1-20 carbon atoms; or (2) a branched or straight chain, oxy-, carboxy- or amino-aliphatic group having from 1-20 carbon atoms; Y is —O—, —S— or —NR′—, where R′ is H or alkyl; R is H, alkyl, alkoxy, aryl, aryloxy, heterocyclic or heterocycloxy; the molar ratio of x:y is about 1; the molar ratio n:(x or y) is between about 200:1 and 1:200; and the molar ratio q:r is between about 1:99 and 99:1; wherein said biodegradable polymer is biocompatible before and upon biodegradat.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: April 23, 2002
    Assignees: Guilford Pharmaceuticals, Inc., Johns Hopkins University School of Medicine
    Inventors: Hai-Quan Mao, Kam W. Leong, Zhong Zhao, James P. English
  • Publication number: 20020045263
    Abstract: The present invention provides biodegradable polymers, polymer compositions, particles composed thereof and methods of using same for the controlled release of a biologically active substance to a specified tissue or cells. Preferred polymers include biodegradable, amphiphilic polyphosphates which are capable of complexing one or more biologically active substances. Preferred methods include the controlled release of biologically active substances and gene therapy using polymers and nanoparticles composed thereof.
    Type: Application
    Filed: May 31, 2001
    Publication date: April 18, 2002
    Inventors: Kam Leong, Wen Jie, Hai-Quan Mao
  • Patent number: 6372873
    Abstract: Linear backbone phosphorus-boron polymers of the general formula (I): wherein R1, R2, R3, and R4, are the same or different and selected from H, optionally substituted alkyl, alkenyl and phenyl; and n is at least 2, and particularly high molecular weight polymers of absolute weight average molecular weight of at least 10,000. The polymers are of use as fire retardants.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 16, 2002
    Inventors: Ian Manners, Hendrik Dorn
  • Patent number: 6362309
    Abstract: New compositions, metal-ligand complexes and arrays are disclosed that catalyze the polymerization of monomers into polymers.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: March 26, 2002
    Assignee: Symyx Technologies, Inc.
    Inventors: Cheryl Lund, Keith Anthony Hall, Thomas Boussie, Vince Murphy, Gregory Hillhouse
  • Publication number: 20020028911
    Abstract: The present invention provides improved processes for purifying polymer preparations by removing contaminants, such as metal contaminants. The present invention also provides improved processes for producing phosphopolymers, which can yield improved polymers in terms of molecular weight, homogeneity, consistency and purity. Polymers and polymer preparations also are provided. The present invention is time, labor and energy efficient, and thus marks an improvement over past approaches.
    Type: Application
    Filed: June 21, 2001
    Publication date: March 7, 2002
    Inventors: Deborah Barnette, James English, Keith Branham, Donna Hall, Reuben Land, Doug Mink, Zhong Zhao
  • Publication number: 20010049431
    Abstract: A polymeric composition, a process for producing the composition, and a process for using the composition in, for example, hydrocyanation or isomerization are disclosed. The composition comprises repeat units derived from (1) a carbonyl compound, a monomer, and phosphorochloridite; (2) phosphorus trichloride, a polyhydric alcohol, and an aromatic diol; or (3) combinations of (1) and (2) in which the monomer can be a polyhydric alcohol, an amine, combinations thereof. The composition can further comprise a Group VIII metal and optionally a Lewis acid.
    Type: Application
    Filed: May 25, 2001
    Publication date: December 6, 2001
    Inventors: Wilson Tam, Sigridur Soley Kristjansdottir, Robin Nikolas Greene
  • Patent number: 6322797
    Abstract: Biodegradable terephthalate polymers are described comprising the recurring monomeric units shown in formula I: wherein R is a divalent organic moiety; R′ is an aliphatic, aromatic or heterocyclic residue; x is ≧1; and n is 0-5,000, wherein the biodegradable polymer is biocompatible before and upon biodegradation. Processes for preparing the polymers, compositions containing the polymers and biologically active substances, articles useful for implantation or injection into the body fabricated from the compositions, and methods for controllably releasing biologically active substances using the polymers, are also described.
    Type: Grant
    Filed: April 2, 1998
    Date of Patent: November 27, 2001
    Assignees: Guilford Pharmaceuticals, Inc., Johns Hopkins University
    Inventors: Hai-Quan Mao, Kam W. Leong, Wenbin Dang, Hungnan Lo, Zhong Zhao, David P. Nowotnik, James P. English
  • Patent number: 6316591
    Abstract: Ordered poly(arylene-vinylene)terpolymers, process for their preparation and their use as electroluminescence materials Poly(arylene-vinylene) terpolymers comprising repeating units of the formula (I), where the symbols have the following meanings: Ar1, Ar2, Ar3 are identical or different and are monocyclic or polycyclic, substituted or unsubstituted aryl or heteroaryl groups which may be linked via one or more bridges or be fused, R1, R2, R3, R4, R5, R6, R7, R8 are identical or different and are each H or a hydrocarbon radical having from 1 to 22 carbon atoms which may be substituted, preferably by F, and may also contain heteroatoms, preferably O, are suitable as electroluminescence materials.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: November 13, 2001
    Assignee: Aventis Research & Technologies GmbH & Co. KG
    Inventors: Willi Kreuder, Hans-Heinrich Hörhold, Henning Rost, Annett Hartmann
  • Publication number: 20010031378
    Abstract: Poly(paraphenylenevinylene) derivatives and their use as electroluminescence materials
    Type: Application
    Filed: February 28, 2001
    Publication date: October 18, 2001
    Inventors: Willi Kreuder, Donald Lupo, Josef Salbeck, Hermann Schenk, Thomas Stehlin, Hans-Heinrich Horhold, Andrea Lux, Annett Teuschel
  • Publication number: 20010025095
    Abstract: Use in the treatment of ceramic materials for obtaining an easy stain removal, of mono- and bifunctional (per)fluoropolyether derivatives having the following structures:
    Type: Application
    Filed: February 28, 2001
    Publication date: September 27, 2001
    Applicant: Ausimont S.p.A.
    Inventors: Mattia De Dominicis, Gabriella Carignano
  • Patent number: 6288210
    Abstract: High refractive index, melt processable polyphosphonates and methods for preparing the same are provided. These polymers are particularly useful for optical and ophthalmic parts, such as lenses. A method of preparing optical and ophthalmic lenses by injection molding the polymers of the present invention into the form of the optical or ophthalmic lenses is also provided.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: September 11, 2001
    Assignees: Virginia Tech. Intellectual Properties, Inc., Johnson & Johnson Vision Products, Inc.
    Inventors: Hosadurga K. Shobha, Venkat Sekharipuram, James E. McGrath, Atul Bhatnagar
  • Patent number: 6284865
    Abstract: A polymeric composition, a process for producing the composition, and a process for using the composition in, for example, hydrocyanation or isomerization are disclosed. The composition comprises repeat units derived from (1) a carbonyl compound, a monomer, and phosphorochloridite; (2) phosphorus trichloride, a polyhydric alcohol, and an aromatic diol; or (3) combinations of (1) and (2) in which the monomer can be a polyhydric alcohol, an amine, combinations thereof. The composition can further comprise a Group VIII metal and optionally a Lewis acid.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: September 4, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Wilson Tam, Sigridur Soley Kristjansdottir, Robin Nikolas Greene
  • Patent number: 6284869
    Abstract: The invention pertains to an adduct comprising epoxy groups obtainable by condensation of an epoxy compound and at least a monocyclic phosphite according to Formula 1: wherein R1 and R2 may be the same or different and represent H or C1-4 alkyl and m is 1, optionally, in admixture with a bicyclic phosphite according to Formula 1 wherein R1 and R2 are absent, m is 2, and wherein R3-R6 may be the same or different and represent H or C1-4 alkyl.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: September 4, 2001
    Assignee: Akzo Nobel N.V.
    Inventors: Antonius Johannes Wilhelmus Buser, Jan André Jozef Schutyser
  • Patent number: 6277502
    Abstract: The invention relates to novel crosslinkable, photoactive silane derivatives of the formula I mixtures of silane derivatives of the formula I and mixtures of silane derivatives of the formula I with uncrosslinkable silane derivatives as usually used for silanizing inorganic, oxide-containing surfaces. The invention furthermore relates to the use of silane derivatives of the formula I and of mixtures which contain at least one silane derivative of the formula I as orientation layers for liquid crystals and for the production of unstructured or structured optical elements and multilayer systems.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: August 21, 2001
    Assignee: Rolic AG
    Inventors: Richard Buchecker, Guy Marck, Hubert Seiberle
  • Patent number: 6273543
    Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with water-solubility- or water-dispersability-imparting substituents and at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula wherein x is an integer of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units. In one embodiment, a single functional group imparts both photosensitivity and water solubility or dispersability to the polymer. In another embodiment, a first functional group imparts photosensitivity to the polymer and a second functional group imparts water solubility or dispersability to the polymer.
    Type: Grant
    Filed: February 9, 1999
    Date of Patent: August 14, 2001
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 6255448
    Abstract: The invention relates to a process for the polymerization or copolymerization of at least one monomer which is polymerizable by the radical route in the presence of a stable free radical from the nitroxide family. The stable free radical is &bgr;-substituted and provides excellent control of polydispersity while ensuring a better rate of polymerization or copolymerization, if they are compared with the stable free radicals used in the prior art.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: July 3, 2001
    Assignee: Atofina
    Inventors: Sandra Grimaldi, François Lemoigne, Jean-Pierre Finet, Paul Tordo, Pascal Nicol, Muriel Plechot, Yves Gnanou
  • Publication number: 20010005745
    Abstract: Salt of a 1,3,5-triazine compound with polyphosphoric acid with a virtually linear structure, with the number average degree of condensation n being higher than 20, the content of the 1,3,5-triazine compound being higher than 1.1 mole per mole of phosphorus atom and the pH of a 10% slurry in water being higher than 4.5. Further, a process for the preparation of the polyphosphate salt of a 1,3,5-triazine compound with a number average degree of condensation n that is higher than 20, by converting a 1,3,5-triazine compound with orthophosphoric acid at room temperature into the phosphate of the 1,3,5-triazine compound, after which this salt is converted at elevated temperature into a polyphosphate of the 1,3,5-triazine compound, and further flame retardant polymer compositions comprising the polyphosphate salt of a 1,3,5-triazine compound with a number average degree of condensation n higher than 20.
    Type: Application
    Filed: January 8, 2001
    Publication date: June 28, 2001
    Inventors: Johanna G. Kersjes, Renier H.M. Kierkels
  • Patent number: 6225367
    Abstract: The present invention relates to polymers comprising one or more perfluoroalkylpolyether units and one or more different charged units, to a process for producing such polymers in non-porous or particularly in porous form and to mouldings composed thereof. The novel polymers have an improved wettability and cell growth ability and are thus useful, for example, for the manufacture of biomedical devices, in particular opthalmic devices.
    Type: Grant
    Filed: September 16, 1999
    Date of Patent: May 1, 2001
    Assignee: Novartis AG
    Inventors: Hassan Chaouk, Timothy Charles Hughes, John Stuart Wilkie, Gordon Francis Meijs
  • Patent number: 6166173
    Abstract: Biodegradable polymers are described comprising the recurring monomeric units shown in formula I or II: wherein X is --O-- or --NR'--, where R' is H or alkyl; L is a branched or straight chain aliphatic group having from 1-20 carbon atoms; M.sub.1 and M.sub.2 are each independently (1) a branched or straight chain aliphatic group having from 1-20 carbon atoms; or (2) a branched or straight chain, oxy-, carboxy- or amino-aliphatic group having from 1-20 carbon atoms; Y is --O--, --S-- or --NR'--, where R' is H or alkyl; R is H, alkyl, alkoxy, aryl, aryloxy, heterocyclic or heterocycloxy; the molar ratio of x:y is about 1; the molar ratio n:(x or y) is between about 200:1 and 1:200; and the molar ratio q:r is between about 1:99 and 99:1; wherein said biodegradable polymer is biocompatible before and upon biodegradat.
    Type: Grant
    Filed: April 2, 1998
    Date of Patent: December 26, 2000
    Assignees: Guilford Pharmaceuticals Inc., Johns Hopkins University
    Inventors: Hai-Quan Mao, Kam W. Leong, Zhong Zhao, James P. English
  • Patent number: 6111061
    Abstract: A polymer composition including phosphorus substituents which comprises:(a) a phosphono-substituted carboxylic acid or an ester of such acid; and(b) a mono- or polyfunctional entity polymerizable with (a).Substances suitable for use as (a) are aliphatic or aromatic phosphono substituted dicarboxylic acids or esters thereof.Substances suitable for use as (b) are polyhydric alcohols, aliphatic mononuclear or polynuclear aromatic polycarboxylic acids or esters or anhydrides thereof. Also suitable for use as (b) are aliphatic or aromatic polyamines and aliphatic or aromatic polyisocyanates or polyepoxides.
    Type: Grant
    Filed: May 8, 1997
    Date of Patent: August 29, 2000
    Assignee: Albright & Wilson UK Limited
    Inventors: Mohsen Zakikhani, Karen Sarah Mitchie
  • Patent number: 6093759
    Abstract: Flame-retardant thermoplastic molding compositions compriseA) from 5 to 99% by weight of a thermoplastic polymer,B) from 0.1 to 50% by weight of a phosphazene of the general formula I(PN.sub.2-x H.sub.1-y).sub.z Iwhere the numerical values of x, y and z, independently of one another, are as follows:1>x>0.051>y>0.05z>1, andC) from 0 to 70% by weight of other additives and processing aids,where the total of the percentages by weight of components A) to C) is 100%.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: July 25, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Brigitte Gareiss, Hans-Michael Schneider, Martin Weber
  • Patent number: 6077930
    Abstract: A preparation process of a polymer comprising conducting ring-opening polymerization of a 4- to 10-membered ring-opening polymerizable cyclic monomer in the presence of a phosphazenium salt of an active hydrogen compound represented by the chemical formula (1): ##STR1## wherein n is an integer of 1 to 8 and indicates the number of phosphazenium cations, Z.sup.n- is an anion of a n-valent active hydrogen compound derived by releasing n protons from an active hydrogen compound having a maximum of 8 active hydrogen atoms, a, b, c and d are individually a positive integer or 0 and are not all 0 at the same time, R's are the same or different hydrocarbons having 1 to 10 carbon atoms, and two R's located on each common nitrogen atom may be coupled together to form a ring structure; or in the presence of the phosphazenium salt of the active hydrogen compound and the active hydrogen compound is disclosed.
    Type: Grant
    Filed: May 15, 1998
    Date of Patent: June 20, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tadahito Nobori, Shinji Kiyono, Takaomi Hayashi, Usaji Takaki
  • Patent number: 6066712
    Abstract: The present invention relates to a styryl polymer, represented by the following formula (I) or (II), a production method thereof and use thereof to a photosensitive member and a electroluminescence element: ##STR1## in which Ar.sub.11 is an arylene group which may have a substituent; Ar.sub.12 is an aryl group, a polycondensed ring group or a heterocyclic ring group; n.sub.1 is a natural number; ##STR2## in which Ar.sub.21, Ar.sub.22, and Ar.sub.24 are respectively an arylene group which may have a substituent; Ar.sub.25 is an arylene group or a bivalent polycondensed ring group, which may have a substituent; Ar.sub.23 and Ar.sub.26 are respectively an alkyl group, an aralkyl group or an aryl group, which may have a substituent; m.sub.2 is 0, 1, 2 or 3; n.sub.2 is a natural number.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: May 23, 2000
    Assignee: Minolta Co., Ltd.
    Inventors: Hideaki Ueda, Takeshi Kitahora, Tsuyoshi Nozaki
  • Patent number: 6060583
    Abstract: This invention relates to a polymerizable phosphazene derivative with a general structural formula[.brket open-st.NP(A).sub.a (B).sub.b).brket close-st.]xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: May 9, 2000
    Assignee: DaimlerChrysler A.G.
    Inventors: Thomas Raith, Wolfgang Nuding
  • Patent number: 6020081
    Abstract: This invention relates to a polymerizable phosphazene derivative with a general structural formula.brket open-st.NP(A).sub.a (B).sub.b).brket close-st..sub.xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: February 1, 2000
    Assignee: Daimler-Benz Aktiengesellschaft
    Inventors: Thomas Raith, Wolfgang Nuding
  • Patent number: 6008318
    Abstract: A process for making a phosphoester polymer comprising the recurring monomeric units of formula I: ##STR1## wherein: X is --O-- or --NR"--, where R" is H or alkyl;L is a divalent organic moiety;R' is H, alkyl, alkoxy, aryl, aryloxy, heterocyclic, or heterocycloxy; andn is between about 25 to 2,000,is described. The process comprises the steps of:(a) polymerizing in the presence of a solvent p moles of a di-XH compound having formula II:H--X--L--X--H IIwherein X and L are as defined above, with q moles, where p.apprxeq.q, of a phosphorodihalo compound to form a polymer of formula I, wherein n is about 12 to 1000, having a first molecular weight Mw.sub.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: December 28, 1999
    Assignees: Guilford Pharmaceuticals Inc., Johns Hopkins University
    Inventors: Zhong Zhao, Hai-quan Mao, Kam W. Leong
  • Patent number: 5994497
    Abstract: The invention relates to hardenable compositions which contain as the essential constituent, in the non-hardened condition, at least one phosphazene derivative of the general formula [NP--(X--Y--Z).sub.2 ].sub.n, and at least one cross-linking agent with at least two functional groups which are selected among the Z radicals and which can react with the functional Z radicals of the phosphazene derivative is provided, whereinX radicals are from the group --O--, --S--, --NH-- or --NR--, preferably oxygen,Y are aliphatic, cycloaliphatic, aromatic and/or heteroaromatic hydrocarbon groups,Z are functional radicals from the group --OH, --NH.sub.2, --NCO, --COOH, --CHO, --CH.dbd.CH.sub.
    Type: Grant
    Filed: November 4, 1997
    Date of Patent: November 30, 1999
    Assignee: DaimlerChrysler AG
    Inventors: Thomas Raith, Wolfgang Nuding
  • Patent number: 5969032
    Abstract: The invention relates to an emulsion polymerization process for preparing a latex binder for use in paint. The process involves reacting a water-soluble or water-dispersible polymerizable surfactant having a terminal allyl amine moiety with at least one ethylenically unsaturated monomer and ionic monomer at a pH from about 2 to about 7. Significantly lower levels of the polymerizable surfactants are required to control the latex particle size and to stabilize the latex particles at high solids content as compared to the amount of conventional anionic surfactants used to stabilize a latex.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: October 19, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Lien Phan, Rajeev Farwaha
  • Patent number: 5912321
    Abstract: This invention relates to a polymerizable phosphazene derivative with a general structural formula.brket open-st.NP(A).sub.a (B).sub.b).brket close-st..sub.xwherein the groups A and B are bonded to phosphorus atoms through --O--, --S--, --NH--, or --NR-- (with R=C.sub.1 -C.sub.6) alkyl), and wherein A stands more precisely for a vinyl ether group or a styrene ether group, and B stands more precisely for a hydrocarbon group. The invention also relates to procedures for synthesizing such phosphazene derivatives. The phosphazenes derivatives of the invention can be cured by a process that is initiated cationically, which leads to a large number of advantages. The phosphazene derivatives of the invention can, in particular, be used as curable binders for paints, coatings, fillers, mastics, adhesives, moldings, or films. Paints or coatings comprising the phosphazene derivatives of the invention show especially high mechanical resistance and scratch resistance.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: June 15, 1999
    Assignee: Mercedes-Benz
    Inventors: Thomas Raith, Wolfgang Nuding
  • Patent number: 5900469
    Abstract: The present invention relates to a storage-stable, phosphorus-modified epoxy resin having an epoxide value of 0.05 to 0.6 mol/100 g and comprising 5 to 25% by weight of an ester-anhydride formed from a phosphonic acid diester, phosphinic acid ester or mixture of these esters and phosphorus pentoxide, and to a process for its preparation by reaction of 95 to 75 parts by weight of an epoxy resin (A) having an epoxide value of 0.1 to 0.8 mol/100 g and 5 to 25 parts by weight of the ester-anhydride in the presence or absence of a solvent at -20 to 150.degree. C.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: May 4, 1999
    Assignee: Aventis Research & Technologies GmbH
    Inventors: Hans-Jerg Kleiner, Sebastian Horold, Guido Scholz
  • Patent number: 5880243
    Abstract: New and useful products are based on sheeted cellulose impregnated with a polyfunctional isocyanate and a fire retardant material. The fire retardants are chosen from organophosphorous esters compatible with the isocyanate in the proportions used. Preferred impregnating compositions use about one part of isocyanate and two parts of a halogenated diphosphate ester. Other compatible phosphorous based materials may be included for viscosity control.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: March 9, 1999
    Assignee: Weyerhaeuser Company
    Inventors: David W. Park, Bruce A. Thompson
  • Patent number: 5854341
    Abstract: An anti-fogging coating composition contains (a) an inorganic alkoxide and/or a hydroxyl group-containing polymer formed therefrom by hydrolysis and polycondensation, the inorganic alkoxide being represented by the formula (I):M(OR).sub.n (X).sub.a-n (I),wherein M is an inorganic element selected from the group consisting of Si, Al, Ti, Zr, Ca, Fe, V, Sn, Li, Be, B and P; R is an alkyl group; X is an alkyl group with or without functional groups or a halogen atom; a is a number representing the valence of M; and n is an integer from 1 to a; (b) a polyalkylene oxide, a weight ratio of the polyalkylene oxide to the inorganic alkoxide and/or the hydroxyl group-containing polymer being 100/1-100/150; (c) 0.5 parts by weight or less of an acid catalyst per 100 parts by weight of (a); (d) 0.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: December 29, 1998
    Assignees: Nakato Laboratory, Inc., Canon Kabushiki Kaisha
    Inventors: Tohru Yamamoto, Shigeo Yoshida, Hatsumi Ikari
  • Patent number: 5854371
    Abstract: The invention relates to a flame-resistant epoxy resin mixture comprising epoxy resins, phosphorus-containing compounds and a curing agent, wherein the epoxy resin mixture comprises phosphorus-containing structural units of the formula I ##STR1## in which R1 is an alkyl or aryl group having from 1 to 10 carbon atoms, R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms and R is an alkylene, cycloalkylene or arylene group having from 2 to 20 carbon atoms.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: December 29, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Sebastian Horold
  • Patent number: 5847184
    Abstract: The present invention relates to a process for preparing of phosphorus-containing dicarboxylic acids of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are identical or different and are each a straight-chain or branched alkyl radical having from 1 to 8 carbon atoms, a cycloaliphatic radical having 5 or 6 carbon atoms in the ring, an unsubstituted or substituted aryl radical having from 6 to 10 carbon atoms, or R.sup.1 and R.sup.2 form, with inclusion of the phosphorus atom, a ring having from 5 to 8 members, and m and n are each, independently of one another 0 or 1, by reacting a compound of the formula (II) ##STR2## where R.sup.1, R.sup.2 and m are as defined above, with fumaric acid, maleic acid or itaconic acid in the presence of a saturated aliphatic monocarboxylic acid having a total of from 1 to 5 carbon atoms as solvent at from 100.degree. to 200.degree. C. under atmospheric pressure or superatmospheric pressure.
    Type: Grant
    Filed: September 22, 1995
    Date of Patent: December 8, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hans-Jerg Kleiner
  • Patent number: 5842471
    Abstract: A method for purification of a polyphosphazene polyacid or acid salt thereof in which a polyphosphazene polyacid or acid salt thereof is dissolved in a concentrated aqueous solution of a salt of monovalent ions. The resulting aqueous solution of the polyphosphazene polyacid or acid salt thereof and the at least one salt of monovalent ions then is diluted to reduce the concentration of the at least one salt of monovalent ions, whereby the polyphosphazene polyacid or acid salt thereof is precipitated. The precipitated polyphosphazene polyacid or acid salt thereof then is recovered.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: December 1, 1998
    Assignee: Virus Research Institute, Inc.
    Inventors: Alexander K. Andrianov, Mark P. LeGolvan, Yuri Svirkin, Sameer S. Sule
  • Patent number: 5830973
    Abstract: The invention relates to a phosphorus-modified epoxy resin having an epoxide value of from 0 to 1.0 mol/100 g, comprising structural units derived from(A) polyepoxide compounds having at least two epoxide groups per molecule and(B) diphosphinic acids,to a process for their preparation and to their use.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: November 3, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Sebastian Horold, Hans-Peter Schmitz
  • Patent number: 5824765
    Abstract: Process for the preparation of polycondensates of amino acids or of the polypeptide hydrolysates thereof, by bulk thermal polycondensation of amino acids in pulverulent medium, in the presence of phosphoric acid, phosphorus pentoxide or polyphosphoric acid (catalyst) which is uniformly distributed in the said pulverulent medium, optionally followed by hydrolysis. The said pulverulent medium may be obtained by empasting the amino acid and the catalyst with water, removal of the water and grinding.Use of polyimide polycondensates or the polypeptide hydrolysates thereof in detergent compositions.
    Type: Grant
    Filed: August 12, 1997
    Date of Patent: October 20, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventor: Jean-Luc Lepage
  • Patent number: 5817736
    Abstract: Epoxy resin mixtures to produce prepregs and composites contain the following components:a phosphorus-modified epoxy resin with an epoxy value of 0.02 to 1 mol/100 g, made up of structural units derived from(a) polyepoxy compounds with at least two epoxy groups per molecule and(b) phosphinic acid anhydrides, phosphonic acid anhydrides or phosphonic acid half-esters;dicyandiamide and/or an aminobenzoic acid derivative as the hardener;an amino hardening accelerator.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: October 6, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Wolfgang von Gentzkow, Jurgen Huber
  • Patent number: 5817745
    Abstract: A process for the manufacture of polyketones wherein carbon monoxide and at least one olefin are polymerized in the presence of a catalyst. The catalyst is prepared by reacting together a promotor; a source of a Group VIII metal; and a compound of the formula A.sub.2 PR.sup.1 PA.sub.2 wherein each A is independently a hydrocarbyl group or a Group B bonded to the phosphorous of the PA.sub.2 moiety directly through a nitrogen, sulphur or oxygen and R.sup.1 is a divalent organic group, with the proviso that at least one of the two A groups bonded to each phosphorous is a Group B.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: October 6, 1998
    Assignee: BP Chemicals Limited
    Inventors: Neil Andrew Cooley, Evert Jan Ditzel
  • Patent number: 5811188
    Abstract: The present invention relates to phosphorus-modified epoxy resins of the formulae (I) and/or (II) ##STR1## The invention furthermore relates to a process for the preparation of these phosphorus-modified epoxy resins and to their use for the production of shaped articles, coatings or laminates.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: September 22, 1998
    Assignees: Siemens Aktiengesellschaft, Aventis Research & Technologies GmbH & Co. KG
    Inventors: Jurgen Huber, Heinrich Kapitza, Hans-Jerg Kleiner, Wolfgang Rogler
  • Patent number: 5811486
    Abstract: For better flame-retardant finishing and better workability of an epoxy-anhydride reaction resin system, it is proposed to supplement the reaction resin system with phosphonic semi-ester as additional reactive constituents. These are produced by conversion of phosphonic acid anhydride with single-valent or multi-valent alcohols. As a result of the selection of the alcohol constituent, property features of the molding material modified therewith that are already advantageous can be designationally set without thereby negatively influencing the hardening characteristic. Even with slight parts of phosphonic acid semi-ester, shaped members manufactured therefrom exhibit an adequate flame-retardant behavior given an otherwise unmodified property profile.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: September 22, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Ernst Wipfelder, Windfried Plundrich
  • Patent number: 5759692
    Abstract: The invention relates to expandable, halogen-free, flame-retardant coating compositions comprising epoxy resins, polyphosphoric esters and a curing agent, which composition comprises from 75 to 95 parts by weight of epoxy resin and from 5 to 25 parts by weight of polyphosphoric ester and wherein the overall weight ratio of epoxy resin and polyphosphoric ester to curing agent is (1.1 to 10) to 1. The invention likewise relates to a process for preparing such expandable, halogen-free coating flame-retardant, compositions comprising epoxy resins and polyphosphoric esters and a curing agent, and to their use, in particular as an intumescent coating.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: June 2, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Guido Scholz, Sebastian Harold, Wolf-Dieter Pirig
  • Patent number: 5759690
    Abstract: Epoxy resin mixtures for the production of prepregs and composites contain the following components:a phosphorus-modified epoxy resin with an epoxy value of 0.02 to 1 mol/100 g, made up of structural units derived from(a) polyepoxy compounds with at least two epoxy groups per molecule, and(b) phosphinic acid anhydrides, phosphonic acid anhydrides, or phosphonic acid half-esters;an amine-substituted aromatic sulfonic acid amide or hydrazide as a hardener;an amino hardening accelerator.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: June 2, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Wolfgang von Gentzkow, Jurgen Huber, Heinrich Kapitza, Wolfgang Rogler
  • Patent number: 5759691
    Abstract: The invention relates to an expandable, halogen-free, flame-retardant coating composition comprising epoxy resins, polyphosphoric/polyphosphonic esters and a curing agent, which composition comprises from 75 to 95 parts by weight of epoxy resin and from 5 to 25 parts by weight of polyphosphoric/polyphosphonic ester and wherein the overall weight ratio of epoxy resin and polyphosphoric/polyphosphonic ester to curing agent is (1.1 to 10) to 1. The invention likewise relates to a process for preparing such coating compositions and to their use.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: June 2, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Guido Scholz, Sebastian Horold, Wolf-Dieter Pirig
  • Patent number: 5756638
    Abstract: The present invention relates to phosphorus-modified epoxy resins having an epoxy number from 0 to 1 mol/100 g, comprising structural units which are derived from(A) polyepoxy compounds having at least two epoxy groups per molecule, and(B) phosphinic and/or phosphonic anhydrides.The invention further provides a process for preparing these phosphorus-modified epoxy resins and provides for the use of the resins in producing moldings, coatings or laminates.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: May 26, 1998
    Assignee: Hoechst AG
    Inventors: Wolfgang von Gentzkow, Jurgen Huber, Heinrich Kapitza, Wolfgang Rogler, Hans-Jerg Kleiner, Uwe Schonamsgruber