From Fluorine-containing Reactant Patents (Class 528/401)
  • Patent number: 6117964
    Abstract: The degree of bonding of a perfluoro polyether lubricant topcoat to various protective overcoats of magnetic recording media is improved by forming a silyl ether of the perfluoro polyether lubricant. The degree of bonding of the lubricant topcoat to a particular protective overcoat is optimized and controlled by selecting a silyl ether end group having a high affinity for the protective overcoat.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: September 12, 2000
    Assignee: Seagate Technology, Inc.
    Inventor: Samuel J. Falcone
  • Patent number: 6114497
    Abstract: Polybenzoxazole precursors are used to prepare resins with good electrical characteristics and thermal characteristics as well as low water absorption.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: September 5, 2000
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Masahiro Tada, Mitsumoto Murayama, Takuya Hatao, Takashi Yamaji
  • Patent number: 6111050
    Abstract: A fluorine-containing curable composition comprises (A) a linear perfluoro compound having at least two secondary amino groups per molecule and a divalent perfluoroalkylene or divalent perfluoropolyether structure in the main chain, and (B) a crosslinkable fluorinated compound having at least three functional groups which are crosslinkable with the secondary amino groups of (A). This composition readily cures, with standing at room temperature or heating only, to a cured product having excellent solvent and chemical resistance.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: August 29, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kouichi Yamaguchi, Noriyuki Koike, Masatoshi Arai, Hirofumi Kishita
  • Patent number: 6090453
    Abstract: Disclosed is a process which comprises the steps of (a) providing a polymer containing at least some monomer repeat units with halomethyl group substituents which enable crosslinking or chain extension of the polymer upon exposure to a radiation source which is electron beam radiation, x-ray radiation, or deep ultraviolet radiation, said polymer being of the formula ##STR1## wherein x is an integer of 0 or 1, A is one of several groups, as specified in the claims, and B is one of several groups, as specified in the claims or mixtures thereof, and n is an integer representing the number of repeating monomer units, and (b) causing the polymer to become crosslinked or chain extended through the photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead by the aforementioned curing process.
    Type: Grant
    Filed: September 30, 1998
    Date of Patent: July 18, 2000
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 6057417
    Abstract: A polymer system having repeating units of the formula: ##STR1## wherein A is --H or --OH, x has a value of 0.5 to 1.0 and y has a value of 1.0-x, exhibits a high glass transition temperature (T.sub.g) and a low dielectric constant. The polymer system is useful in the area of microelectronic packaging.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: May 2, 2000
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Fred E. Arnold, Thuy D. Dang, Robert J. Spry, Max D. Alexander, Patrick T. Mather
  • Patent number: 6054492
    Abstract: Block copolymers containing a fluorinated hydrocarbon unit, a hydrocarbon unit, and a poly(oxyethylene) unit are useful in fluid formulations of pharmaceutical agents. A typical embodiment is:C.sub.11 H.sub.23 --CONHC.sub.2 H.sub.4 NHCO--C.sub.8 F.sub.16 --CONHC.sub.2 H.sub.4 NHCOO--(C.sub.2 H.sub.4 O).sub.34 --H.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: April 25, 2000
    Assignee: Supratek Pharma Inc.
    Inventors: Alexander V. Kabanov, Serguei V. Vinogradov
  • Patent number: 6028165
    Abstract: Epoxides containing a perfluorovinyl group, and polymers made therefrom by polymerization of the epoxy function are disclosed. Such epoxides form polymers and copolymers useful for coatings, adhesion control agents, surface modifiers and crosslinking agents.
    Type: Grant
    Filed: March 29, 1999
    Date of Patent: February 22, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ming-Hong Hung, Shlomo Rozen
  • Patent number: 6025092
    Abstract: This invention concerns substantially fluorinated, but not perfluorinated, ionomers consisting of a polyethylene backbone having pendant groups of fluoroalkoxy sulfonic acids and metal salts thereof. Such ionomers are useful for electrochemical applications.
    Type: Grant
    Filed: February 13, 1998
    Date of Patent: February 15, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Christopher Marc Doyle, William Brown Farnham, Andrew Edward Feiring, Peter Arnold Morken, Mark Gerrit Roelofs
  • Patent number: 6020458
    Abstract: Fluorinated chemical precursors, methods of manufacture, polymer thin films with low dielectric constants, and integrated circuits comprising primarily of sp.sup.2 C-F and some hyperconjugated sp.sup.3 C-F bonds are disclosed in this invention. Precursors are disclosed for creating fluorinated silanes and siloxanes, and fluorinated hydrocarbon polymers. Thermal transport polymerization (TP), chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), high density PECVD (HPCVD), photon assisted CVD (PACVD), and plasma-photon assisted (PPE) CVD and PPETP of these chemicals provides thin films with low dielectric constants and high thermal stabilities for use in the manufacture of integrated circuits.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: February 1, 2000
    Assignee: Quester Technology, Inc.
    Inventors: Chung J. Lee, Hui Wang, Giovanni Antonio Foggiato
  • Patent number: 6011135
    Abstract: The triazine thiol derivative having a perfluoro group of the present invention is represented by the following chemical formula: ##STR1## in which "n" is an integer of 1-12, "R" is represented by the following general formula;C.sub.m H.sub.2m+1wherein m is an integer of 0-24, and M.sub.1 and M.sub.2 respectively represent H or an alkali metal. Such triazine thiol derivative having a perfluoro group is excellent in reactivity, solubility and surface activity.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: January 4, 2000
    Assignee: Iwate University
    Inventor: Kunio Mori
  • Patent number: 6010641
    Abstract: Methods for loading and alignment of liquid crystal polymers in electro-optic and electro-active devices comprise in-situ polymerisation between substrates of monomer material in the presence of a cationic initiator. This allows for the synthesis of liquid crystal polymers containing polyether backbones.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: January 4, 2000
    Assignee: The Secretary of State for Defence in her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Ian C Sage, Keith M Blackwood, Mark A Verrall, David Coates, David R Beattie
  • Patent number: 5986045
    Abstract: A method is disclosed for making hydroxy-substituted ethynylated biphenyl compounds and for reacting such compounds with a family of noncross-linking thermosetting poly(arylene ethers) to produce novel poly(arylene ether) compositions which, when cured at glass transition temperatures greater than about 350.degree. C. to form thin films, possess properties such as low dielectric constant, low moisture absorption, and high thermal stability. These films are suitable for use as intermetal dielectrics for multilevel interconnection.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: November 16, 1999
    Assignee: AlliedSignal Inc.
    Inventors: Kreisler Lau, Neil Hendricks, William Wan, Aaron Smith
  • Patent number: 5969074
    Abstract: A reaction of perfluoroolefins with bis(silyl) ethers to produce novel partially fluorinated and perfluorinated copolymers and macrocyclic compounds is disclosed.
    Type: Grant
    Filed: May 21, 1993
    Date of Patent: October 19, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: William Brown Farnham, Mario Joseph Nappa
  • Patent number: 5962631
    Abstract: The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C.sub.5-20 ring structure formed with the 9-carbon on the fluorene ring or a C.sub.4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7'-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7'-positions.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: October 5, 1999
    Assignee: The Dow Chemical Company
    Inventors: Edmund P. Woo, William R. Shiang, Michael Inbasekaran, Gordon R. Roof
  • Patent number: 5948478
    Abstract: A method of protecting objects from graffiti using fluorinated polymers based on fluoropolyethers in a dry formulation wherein the fluorinated polymer includes a fluorinated part R.sub.F and optionally an hydrogenated part R.sub.H not containing groups capable of linking to basic acceptors by means of hydrogen bonds, the bonds linking the fluorinated part, derived from (per)fluoropolyethers, to the hydrogenated part being of simple C--O ether type, the T' terminal groups being such as to render the structure bi- or polyfunctional thus making possible the curing reaction, and subsequent curing of the fluorinated polymer.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: September 7, 1999
    Assignee: Ausimont S.P.A.
    Inventors: Daria Lenti, Roberta Marchetti, Stefano Turri
  • Patent number: 5942572
    Abstract: Non-ionic compound having the general formula:R.sub.f --L--(OCHR.sub.1 --CHR.sub.2).sub.n --O--L'--R.sub.f' (I)wherein:n is an integer comprised between 4 and 60, preferably between 8 and 30;L and L', equal to or different from each other, can be selected from:--(CFY--CO--O).sub.p R'-- and --(CFY--CO--NH).sub.p R'--wherein: p is 0 or 1; Y can be F or CF.sub.3 ; R' is an alkylic radical C.sub.1 -C.sub.5,R.sub.1, R.sub.2 can be both H or the former one H and the latter CH.sub.3.R.sub.f and R.sub.f', equal to or different from each other, can be perfluoropolyethereal radicals having a number average molecular weight comprised between 250 and 1500, preferably between 400 and 1000; and its use as thickener of aqueous latexes based on fluoropolymers.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: August 24, 1999
    Assignee: Ausimont S.p.A.
    Inventors: Alba Chittofrati, Paolo Lazzari, Daria Lenti
  • Patent number: 5942598
    Abstract: Perfluoroalkyleneethertriazine oligomer obtained by reacting a dinitrile compound NC-Rf.sup.0 --CN, where Rf.sup.0 is --(CFXOCF.sub.2).sub.a (CF.sub.2).sub.b (CF.sub.2 OCFX).sub.c --, where X is a fluorine atom or a CF.sub.3 group, a is an integer of 1 to 5, b is an integer of 1 to 2 and c is an integer of 1 to 5, or Rf.sup.0 is --CF.sub.2 O(CF.sub.2 O).sub.d CF.sub.2 --, where d is an integer of 1 to 8 with ammonia, further reacting the resulting diamizine compound with a dinitrile compound NC-Rf.sup.1 --CN, where Rf.sup.1 has the same meaning as that for Rf.sup.0 or Rf.sup.1 is a perfluoroalkylene group having 4 to 8 carbon atoms thereby obtaining a perfluoroalkyleneetherpolyimidoylamizine oligomer, then reacting the resulting oligomer with a perfluoronitrile compound Rf.sup.2 CN, where Rf.sup.2 is CF.sub.3 (OCF.sub.2).sub.e --, where e is an integer of 3 to 10, and then subjecting the resulting terminal-treated oligomer to a ring-closing reaction with a perfluoroacylating agent Rf.sup.3 COY, where Rf.sup.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: August 24, 1999
    Assignees: Nippon Mektron, Limited, S.V. Lebedev
    Inventors: Riichi Iwa, Haruyoshi Tatsu, Sokolov Sergey Vasilyevich, Kollar Alexander Nikolaevich
  • Patent number: 5936111
    Abstract: Fluorinated amide compounds of formula (1) wherein Rf is a perfluoroalkyl or perfluoropolyether group having 1 to 800 carbon atoms, R is hydrogen, methyl or phenyl, and letter a is 1, 2 or 3 are novel and useful as a modifier intermediate capable of improving various properties of silicone and liquid fluororubber.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: August 10, 1999
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yasuo Tarumi, Kenichi Fukuda, Masatoshi Arai
  • Patent number: 5929199
    Abstract: The present invention is a cyanate resin monomer having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n is an even integer from 6 to 10, inclusive.Another aspect of the invention is an essentially pure cyanate resin mono having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: July 27, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Arthur W. Snow, Leonard J. Buckley
  • Patent number: 5925475
    Abstract: Phthalonitrile thermoset polymers and composites having flame resistance formed by combining a phthalonitrile monomer in the melt stage with a halogen-containing aromatic amine curing agent. The halogen-containing aromatic amine curing agent is selected from the group consisting of aromatic amine curing agents having the general formula:NH.sub.2 --(Ar.sup.2 O--).sub.y Ar.sup.1 --X--Ar.sup.1 (--OAr.sup.2).sub.y --NH.sub.2wherein Ar.sup.1 and Ar.sup.2 are substituted or unsubstituted aromatic groups, y is 0 or greater, and X is --C(CF.sub.3).sub.2 -- and aromatic amine curing agents having the general formula:NH.sub.2 --(Ar.sup.4 O--).sub.u Ar.sup.3 --Z--Ar.sup.3 (--OAr.sup.4).sub.u --NH.sub.2wherein Z is a connecting bond or a linking group other than oxygen or --C(CF.sub.3).sub.2 --, u is 0 or greater, and Ar.sup.3 and Ar.sup.4 are aromatic groups and wherein either Ar.sup.3 or Ar.sup.1 or both Ar.sup.3 and Ar.sup.4 are substituted with at least one halogen atom or halo-substituted alkyl group.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: July 20, 1999
    Assignee: United States of America as represented by the Secretary of the Navy
    Inventors: Satya B. Sastri, Teddy M. Keller
  • Patent number: 5859182
    Abstract: A fluorine-containing polyquinazolone polymer having a bisquinazolone unit represented by Formula 1 as the repeating unit is used for a gas separation membrane so that great chemical and heat resistance is provided. The membrane also has great permeability and effective separability, as well as excellent mechanical strength. ##STR1## where R.sub.1 indicates a tetravalent organic group, R.sub.2 respectively indicate an alkyl group or an aromatic group, R.sub.3 indicates a divalent organic group, and R.sub.1 and/or R.sub.3 indicates an organic group having at least one fluorine atom.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: January 12, 1999
    Assignee: Nitto Denko Corporation
    Inventors: Hisao Hachisuka, Kenichi Ikeda
  • Patent number: 5856434
    Abstract: Use in electrooptical switching and display devices of a polymer comprising conjugatively linked chromophore segments whose emission properties are determined by the emission properties of the individual chromophore segments.Electroluminescence devices comprising the polymers of the present invention have, inter alia, a high color purity. The polymers used according to the present invention enable, in particular, blue and white electroluminescence to also be achieved.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: January 5, 1999
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Roland Stern, Hermann Schenk, Josef Salbeck, Thomas Stehlin, Ullrich Scherf, Klaus Mullen, Gunther Leising
  • Patent number: 5834620
    Abstract: Described herein are polyesters and polyamides which contain repeat units derived from novel dicarboxylic acids comprising arylene groups having ortho ethers substituted thereon. Also disclosed are novel compounds from which these polymers can be made. The polymers are especially useful for molding resins and coatings.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: November 10, 1998
    Assignee: University of Liverpool
    Inventors: Geoffrey Charles Eastmond, Jerzy Paprotny
  • Patent number: 5814698
    Abstract: Polytetrafluoroethylene (PTFE) dispersions in an organic solvent, comprising:(A) from 2 to 40% by weight of PTFE in powder form;(B) from 50 to 95% by weight of an organic solvent;(C) from 0.5 to 10% by weight of a dispersing agent of formula:(R.sub.H --L).sub.y --(R.sub.F --L).sub.x R.sub.H (I)wherein:x is an integer from 1 to 3;y is 0 or 1, with the proviso that x=1 when y=1;R.sub.H is a x-functional radical having an alkylic or polyoxyalkylenic structure;R.sub.F is (per)fluoropolyoxyalkylenic radical;L is a divalent organic group.Such dispersions are utilized for the surface treatment of metals, glass fibers, and the like, and in particular as mold release agents.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: September 29, 1998
    Assignee: Ausimont S.p.A.
    Inventors: Laura Montagna, Ezio Strepparola
  • Patent number: 5807967
    Abstract: The present invention is a cyanate resin monomer having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n is an even integer from 6 to 10, inclusive.Another aspect of the invention is an essentially pure cyanate resin mono having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: September 15, 1998
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Arthur W. Snow, Leonard J. Buckley
  • Patent number: 5804649
    Abstract: The present invention discloses a water-soluble self-acid-doped polyaniline, and its sodium salt, which can be cast into free-standing films from their aqueous solutions. A process for preparing a water-soluble self-acid-doped polyaniline is also disclosed, which comprises reacting a polyaniline with a strong base to convert the amino nitrogen thereof to anionic nitrogen; reacting sultone with the anionic nitrogen to form a side chain alkanesulfonic acid group; doping with protonic acid to form precipitate; dissolving (undoping) the precipitate in an alkaline aqueous solution; removing excess alkali from the alkaline aqueous solution; and contacting the resulting aqueous solution with a H.sup.+ -type ion exchange resin. Moreover, an aqueous solution of the present water-soluble self-acid-doped PAn can be easily mixed with an additional water soluble polymer or polymer emulsion, which can then be cased into a polymer blend film having improved mechanical properties and coupling strength to a substrate.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: September 8, 1998
    Assignee: National Science Council
    Inventors: Show-An Chen, Gue-Wuu Hwang
  • Patent number: 5789534
    Abstract: The purification process comprises removing carboxylic acids and/or carboxylic acid salts contained as impurities in a fluorinated polyether having at at least one end thereof a terminal vinyl group linked thereto through an amide group-containing linkage by heating, in the presence of an amine compound such as triethylamine and dimethylaminotrimethylsilane, the fluorinated polyether containing said impurities or a reaction mixture obtained after the completion of reaction in a process of producing said fluorinated polyether. According to the purification process, the impurities can be easily removed from said fluorinated polyether. When the thus purified fluorinated polyether is used as a starting material for an addition type curable composition together with a SiH group-containing organosilicon compound, a liquid rubber material excellent in curability and storage stability can be obtained.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: August 4, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Noriyuki Koike, Shinichi Sato, Takashi Matsuda
  • Patent number: 5789532
    Abstract: Perfluoroalkyleneethertriazine oligomer obtained by reacting a dinitrile compound NC--RF.sup.0 --CN where Rf.sup. is --(CFXOCF.sub.2)a(CF.sub.2)b(CF.sub.2 OCFX)c--, where X is a fluorine atom or a CF.sub.3 group, a is an integer of 1 to 5, b is an integer of 1 to 2 and c is an integer of 1 to 5, or Rf.sup.0 is --CF.sub.2 O(CF.sub.2 O)dCF.sub.2 --, where d is an integer of 1 to 8, with ammonia, further reacting the resulting diamizine compound with a dinitrile compound NC--Rf.sup.1 --CN, Rf.sup.1 has the same meaning as that for Rf.sup.0 or Rf.sup.1 is a perfluoroalkylene group having 4 to 8 carbon atoms thereby obtaining a perfluoroalkyleneetherpolyimidoylamizine oligomer, then reacting the resulting oligomer with a perfluoronitrile compound Rf.sup.2 CN, Rf.sup.2 is CF.sub.3 (OCF.sub.2)e-- where e is an integer of 3 to 10 thereby treating the terminal groups thereof, and then subjecting the resulting terminal-treated oligomer to a ring-closing reaction with a perfluoroacylating agent RF.sup.3 COY, Rf.sup.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: August 4, 1998
    Assignees: Nippon Mektron, Limited, S.V. Lebedev
    Inventors: Riichi Iwa, Haruyoshi Tatsu, Sokolov Sergey Vasilyevich, Kollar Alexander Nikolaevich
  • Patent number: 5786071
    Abstract: New polyquinoline polymers are provided, as well as new methods for preparing the polyquinoline polymers using a novel combination of monomers. The polyquinoline polymers comprise repeat units comprising at least one quinoline nucleus and at least one ether linkage and having as end groups either fluoro groups or hydroxy groups or a combination of fluoro and hydroxy groups. The polymers are formed by providing a monomer comprising two fluoro groups, where each such fluoro group is activated by a quinoline nucleus, a diol monomer provided in the form of its bis-oxide salt, or in the presence of a base capable of deprotonating the diol and reacting the difluoro and diol monomers together in a dipolar solvent to form the polyquinoline polymer.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: July 28, 1998
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Matthew L. Marrocco, III, Ying Wang
  • Patent number: 5761809
    Abstract: Disclosed is a process which comprises reacting a haloalkylated aromatic polymer with a material selected from the group consisting of unsaturated ester salts, alkoxide salts, alkylcarboxylate salts, and mixtures thereof, thereby forming a curable polymer having functional groups corresponding to the selected salt. Another embodiment of the present invention is directed to a process for preparing an ink jet printhead with the curable polymer thus prepared.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: June 9, 1998
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Crandall
  • Patent number: 5753783
    Abstract: Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with an acetyl halide and dimethoxymethane in the presence of a halogen-containing Lewis acid catalyst and methanol, thereby forming a haloalkylated polymer. In a specific embodiment, the haloalkylated polymer is then reacted further to replace at least some of the haloalkyl groups with photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: May 19, 1998
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Crandall
  • Patent number: 5739254
    Abstract: Disclosed is a process which comprises reacting a polymer of the general formula ##STR1## wherein x is an integer of 0 or 1, A is one of several specified groups, such as ##STR2## B is one of several specified groups, such as ##STR3## or mixtures thereof, and n is an integer representing the number of repeating monomer units, with an acetyl halide and dimethoxymethane in the presence of a halogen-containing Lewis acid catalyst and methanol, thereby forming a haloalkylated polymer. In a specific embodiment, the haloalkylated polymer is then reacted further to replace at least some of the haloalkyl groups with photosensitivity-imparting groups. Also disclosed is a process for preparing a thermal ink jet printhead with the aforementioned polymer.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: April 14, 1998
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Ram S. Narang, Thomas W. Smith, David J. Luca, Raymond K. Grandall
  • Patent number: 5731095
    Abstract: A water-soluble or water-dispersible fluorine-containing dendritic polymer surfactant having at least one terminal fluorocarbon moiety and at least one terminal anionic moiety, and which is suitable for use in preparing protective coating compositions is disclosed. The water-soluble or water-dispersible fluorine-containing dendritic polymer surfactants are represented by the general formula: ##STR1## where D represents a dendritic polymer, R.sub.F represents a fluorocarbon containing moiety, A.sup.- represents an anionic containing moiety, C.sup.+ represents a cation, T represents a terminal group of the dendritic polymer which has not been functionalized with a fluorocarbon or anionic moiety, n and m are at least each at least one, and the sum of n+m+q is the total number of terminal groups on the dendritic polymer. Also disclosed is a coating composition capable of forming a highly crosslinked, non-stick, protective coating.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: March 24, 1998
    Assignee: Oxazogen, Inc.
    Inventors: Larry A. Milco, Donald A. Tomalia
  • Patent number: 5728749
    Abstract: This photopolymerizable composition includes an grafted reactive telomer containing trifluoroethyl methacrylate units, a reactive diluent and a photopolymerization initiator. It gives hydrophobic transparent coatings.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: March 17, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Didier Vanhoye, Elsa Ballot, Robert Legros, Olivier Loubet, Bernard Boutevin, Bruno Ameduri
  • Patent number: 5719259
    Abstract: Perfluoroalkylene oxide copolymer having acid fluoride moieties are prepared by reaction of hexafluoropropylene oxide and 1,2-epoxypentafluoropropane 3-fluorosulfate in the presence of a cesium alkoxide initiator. The copolymers may be cured at room temperature and are useful in sealant and coating formulations. Derivatives of the copolymers containing ester, amide, nitrile, and ether moieties are also disclosed.
    Type: Grant
    Filed: August 12, 1996
    Date of Patent: February 17, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Galina Mikhailovna Tyul'ga, Olga Borisovna Platonova, Irina Gennadievna Solodkaya, Dimetrii Stefanovich Rondarev, Yurii Kalmanovich Starobin, Sergey Vasilievich Sokolov, Albertus VanCleeff
  • Patent number: 5714266
    Abstract: Compositions for treating pulp slurry in the wet end comprising (A) a mixture of fluoroaliphatic radical-containing phosphate esters comprising at least 70% of a phosphate monoester, e.g., C.sub.8 F.sub.17 SO.sub.2 N(C.sub.2 H.sub.5)C.sub.2 H.sub.4 OP(O) (OH) (O.sup.- NH.sub.4.sup.+) and (B) an alkyl ketene dimer are disclosed. Methods for using such compositions and the resulting treated products are also disclosed.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: February 3, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Susan S. Harrison, Karlan B. Hunt
  • Patent number: 5708119
    Abstract: Bisperfluoroalkyl-substituted diols containing sulfide, sulfone or polysulfide linkages and a method for making them are described. These diols can react with isocyanates to form urethanes; diisocyanates to form polyturethanes; chloroformates to form carbonates; with carboxylic, sulfuric or phosphoric acids or derivatives to form carboxylate esters, sulfate esters, phosphate esters respectively. These diol compounds and their derivatives are useful for imparting oil and water repellency to substrates such as glass, wood, paper, leather, wool, cotton, polyester and other substrates.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: January 13, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ted Deisenroth, Marlon Haniff
  • Patent number: 5708130
    Abstract: The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C.sub.5-20 ring structure formed with the 9-carbon on the fluorene ring or a C.sub.4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7'-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7'-positions.
    Type: Grant
    Filed: July 28, 1995
    Date of Patent: January 13, 1998
    Assignee: The Dow Chemical Company
    Inventors: Edmund P. Woo, William R. Shiang, Michael Inbasekaran, Gordon R. Roof
  • Patent number: 5705604
    Abstract: This invention relates to novel tire sealer and inflator compositions. The compositions may be aqueous or non-aqueous and comprise a petroleum residual resin sealant, an amorphous polyolefin, an organic solvent, a vapor pressure depressant, and a non-flammable propellant/inflator having an ozone depletion potential of zero. For the aqueous system, the composition further comprises an emulsifier. The compositions are useful for sealing and inflating a punctured tire in combination with a propellant/inflator.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: January 6, 1998
    Assignee: Pennzoil Products Company
    Inventor: Jiafu Fang
  • Patent number: 5693747
    Abstract: Bisperfluoroalkyl-substituted diols containing sulfide, sulfone or polysulfide linkages and a method for making them are described. These diols can react with isocyanates to form urethanes; diisocyanates to form polyurethanes; chloroformates to form carbonates; with carboxylic, sulfuric or phosphoric acids or derivatives to form carboxylate esters, sulfate esters, phosphate esters respectively. These diol compounds and their derivatives are useful for imparting oil and water repellency to substrates such as glass, wood, paper, leather, wool, cotton, polyester and other substrates.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: December 2, 1997
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ted Deisenroth, Marlon Haniff
  • Patent number: 5672767
    Abstract: A process for the preparation of a perfluoropolyether having a general formula: ##STR1## as defined hereinbefore, which process includes the direct fluorination with elemental fluorine of a polyether having a general formula: ##STR2## as defined hereinbefore, wherein the fluorination is carried out in the presence of a solvent which is an ether having at least one substituent R.sub.F, wherein R.sub.F is a fluorinated hydrocarbon group. The said solvent ether is preferably a fluorinated volatile ether. The said solvent ether preferably has at least two groups R.sub.F which may be the same or different groups. Each group R.sub.F preferably has from two to four carbon atoms and at least two fluorine atoms. The said solvent ether may be an alicyclic ether having from 3 to 5 carbon atoms in its alicyclic ring.
    Type: Grant
    Filed: July 5, 1996
    Date of Patent: September 30, 1997
    Assignee: BNFL Fluorochemicals Ltd.
    Inventors: Richard Dickinson Chambers, Andrew Keith Joel
  • Patent number: 5670603
    Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electon donating group substituted to different phenyl rings of the fluorene moiety.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: September 23, 1997
    Assignee: AlliedSignal Inc.
    Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
  • Patent number: 5668241
    Abstract: Hydroxy-terminated poly(2-fluoro-2,2-dinitroethyl) polynitroorthocarbonate repolymers of the formula ##STR1## which are prepared by reacting bis(2-fluoro-2,2-dinitroethyl)dichloroformal with a diol of the formula ##STR2## wherein n>1, and wherein W, X, Y, and Z vary independently and are F or NO.sub.2, and wherein A is --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 --, --CF.sub.2 --, --CF.sub.2 CF.sub.2 --, --CF.sub.2 CF.sub.2 CF.sub.2 --, --CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 --, --CH.sub.2 OCH.sub.2 --, --CH.sub.2 OCH.sub.2 OCH.sub.2 --, --CH.sub.2 OCF.sub.2 OCH.sub.2 --, or --CH.sub.2 N(NO.sub.2)CH.sub.2 --. These prepolymers are reacted with curing agents (e.g., polyisocyanates) to form energetic polymeric binders.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: September 16, 1997
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: G. William Lawrence, William H. Gilligan
  • Patent number: 5663280
    Abstract: Disclosed is a carbonate polymer composition comprising (a) a carbonate polymer having a weight average molecular weight of from about 20,000 to about 40,000 and (b) from greater than about 0.1 to less than about 1.0 weight percent (based on carbonate polymer composition weight) low volatility aromatic phosphate ester compound, and optionally (c) from about 0.001 to about 0.1 weight percent (based on carbonate polymer compositions weight) of an alkali metal salt having a pH of at least about 7. Preferably the low volatility aromatic phosphate ester is selected from the group of aromatic phosphate ester oligomer compounds or haloaryl phosphate compounds. It has been found to be preferable to use a low volatility aromatic phosphate ester which experiences a weight loss of no more than 5 weight percent at 250.degree. C. when heated to a temperature of 500.degree. C. in a thermogravimetric analysis (TGA) at a heating rate of 20.degree. C. per minute, more preferably no more than 40 percent at 300.degree. C.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: September 2, 1997
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Nancy J. Schrock, Jimmie D. Spoon
  • Patent number: 5648448
    Abstract: New polyquinoline polymers are provided, as well as new methods for preparing the polyquinoline polymers using a novel combination of monomers. The polyquinoline polymers comprise repeat units comprising at least one quinoline nucleus and at least one ether linkage and having as end groups either fluoro groups or hydroxy groups or a combination of fluoro and hydroxy groups. The polymers are formed by providing a monomer comprising two fluoro groups, where each such fluoro group is activated by a quinoline nucleus, a diol monomer provided in the form of its bis-oxide salt, or in the presence of a base capable of deprotonating the diol and reacting the difluoro and diol monomers together in a dipolar solvent to form the polyquinoline polymer.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 15, 1997
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Matthew L. Marrocco, III, Ying Wang
  • Patent number: 5629404
    Abstract: A high impact polymer comprising repeating monomer units of the formula: ##STR1## wherein R.sub.2 and R.sub.2 are substituents selected from the group consisting of hydrogen, an alkyl group, an aryl ring and a group promoting hydrogen bonding with a hydrogen atom of a phenyl ring, at least one of R.sub.1 and R.sub.2 being from the group promoting hydrogen bonding.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 13, 1997
    Inventors: Douglas A. Smith, Charles W. Ulmer, II
  • Patent number: 5621145
    Abstract: When a novel bisamidoxime compound represented by the following general formula: ##STR1## where R is an alkylidene group having 1 to 6 carbon atoms, or a perfluoroalkylidene group having 1 to 10 carbon atoms, is used as a vulcanizing agent for fluorine-containing elastomers having cyano groups as cross-linkable groups, the resulting vulcanizates having a satisfactory compression set are obtained without any problem of processability such as roll kneadability, etc.
    Type: Grant
    Filed: January 5, 1996
    Date of Patent: April 15, 1997
    Assignee: Nippon Mektron, Limited
    Inventors: Satoru Saito, Haruyoshi Tatsu, Lev Solomonovich, deceased, Ziefman Y. Vilovich, Postovoi S. Anatol'evich, Sterlin S. Rafailovich
  • Patent number: 5589552
    Abstract: Coatings obtainable from crosslinkable polyesters resins based on perfluoropolyethers obtainable from hydroxy-terminated PFPE, with acid anhydride and/or a diacid, a polyol with functionality higher than 2 and optionally in mixtures of diols having a functionality of 2, the resins being also even 70% weight/weight soluble in xylene.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: December 31, 1996
    Assignee: Ausimont, S.p.A.
    Inventors: Giovanni Simeone, Fabrizio Mutta, Angelo Locaspi, Claudio Tonelli
  • Patent number: 5574126
    Abstract: Hydroxy-terminated poly(2-fluoro-2,2-dinitroethyl) polynitroorthocarbonate repolymers of the formula ##STR1## which are prepared by reacting bis(2-fluoro-2,2-dinitroethyl)dichloroformal with a diol of the formula ##STR2## wherein n>1, and wherein W, X, Y, and Z vary independently and are F or NO.sub.2, and wherein A is --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 --, --CF.sub.2 --, --CF.sub.2 CF.sub.2 --, --CF.sub.2 CF.sub.2 CF.sub.2 --, --CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 --, --CH.sub.2 OCH.sub.2 --, --CH.sub.2 OCH.sub.2 OCH.sub.2 --,--CH.sub.2 OCF.sub.2 OCH.sub.2 --, or --CH.sub.2 N(NO.sub.2)CH.sub.2 --. These prepolymers are reacted with curing agents (e.g., polyisocyanates) to form energetic polymeric binders.
    Type: Grant
    Filed: May 23, 1985
    Date of Patent: November 12, 1996
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: G. William Lawrence, William H. Gilligan
  • Patent number: 5521013
    Abstract: Partially fluorinated polymer comprising a backbone and side-chains, in which the backbone and side-chains are each 4 atoms long and are chemically incompatible, one chain being at least predominantly hydrocarbon and the other comprising a C.sub.4+ perfluorocarbon moiety.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: May 28, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Anselm C. Griffin, Ladislav M. Wilson