Polymerizing In The Presence Of A Specified Material Other Than A Reactant Patents (Class 528/408)
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Patent number: 6432488Abstract: A powder coating composition and method of applying it to a substrate, such as medium density fibreboard, consisting of a glycidyl methacrylate resin, a dicarboxylic acid cross-linking agent, a catalyst selected from phosphines, phosphonium, ammonium 2-phenyl-2-imidazoline, substituted imidazoline and isopropyl imidazole Bis-A epoxy resin adduct and a matte texturing agent. The inventive formulation is able to create a matte texture finish on the surface of the substrate. Since the cured final coating is resistant to yellowing and moisture, it is of great utility in the kitchen cabinet making industry.Type: GrantFiled: July 28, 2000Date of Patent: August 13, 2002Assignee: Rohm and Haas CompanyInventors: Andrew T. Daly, Richard P. Haley, Edward G. Nicholl
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Publication number: 20020103330Abstract: A naphthalene derivative, binaphthalene derivative and biphenyl derivative, all having an oxetane group, capable of being cationically polymerized and a cationically curable compound containing a naphthalene derivative having an oxetanyl group and an aromatic compound having an epoxy group or an oxetanyl group.Type: ApplicationFiled: December 13, 2001Publication date: August 1, 2002Applicant: Toagosei Co., Ltd.Inventors: Akira Kuriyama, Naokazu Ito, Tetsuya Suzuta, Takashi Tsuda
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Patent number: 6420460Abstract: The present invention relates to a thermally and cationically curable composition containing triarylcyclopropenylium salts and a solvent that is a Lewis base which contains acidic hydrogen and their use as thermal initiators in polymerization processes. The present invention includes the polymerization of epoxy resins, vinyl ethers and other cationically curable monomers.Type: GrantFiled: February 12, 2001Date of Patent: July 16, 2002Assignee: UCB S.A.Inventors: Wenqin Zhang, John H. Malpert, Douglas C. Neckers, Dustin B. Martin
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Patent number: 6410676Abstract: The object is to provide a method for producing a polyoxyalkylene polyol and a method for producing a derivative thereof wherein the remaining catalyst compound is efficiently removed from a crude polyoxyalkylene polyol by a simple manner, and a method for producing a polyoxyalkylene polyol wherein a crude polyoxyalkylene polyol is produced by addition polymerization of an epoxide compound to an active hydrogen compound using as a catalyst a compound having a P═N bond, then, the crude polyoxyalkylene polyol is allowed to contact with a solid acid having a specific surface area of 450 to 1200 m2/g and an average pore diameter of 40 to 100 Å to control the catalyst-remaining amount in the polyoxyalkylene polyol to 150 ppm or less, and a method for producing a derivative of the-above-described polyol are provided.Type: GrantFiled: May 30, 2000Date of Patent: June 25, 2002Assignee: Mitsui chemicals, Inc.Inventors: Satoshi Yamasaki, Yasunori Hara, Tamotsu Kunihiro, Fumio Yamazaki, Mikio Matsufuji, Ariko Nishikawa, Shinsuke Matsumoto, Tsukuru Izukawa, Masahiro Isobe, Kazuhiko Ohkubo, Kaoru Ueno
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Patent number: 6403842Abstract: Disclosed are a process for producing a poly(alkylene ether) glycol which comprises polymerizing a cyclic ether in the presence of at least a catalyst and a carboxylic acid anhydride, wherein the carboxylic acid anhydride has a ketene dimer content of 50 ppm or lower, and a process for producing a poly(alkylene ether) glycol which comprises polymerizing a cyclic ether in the presence of at least a catalyst and acetic anhydride, wherein the acetic anhydride is purified acetic anhydride obtained by treating acetic anhydride by contacting with at least one of a metal oxide and a mixed oxide, and optionally, distilling the acetic anhydride simultaneously with or after the contact treatment.Type: GrantFiled: January 13, 2000Date of Patent: June 11, 2002Assignee: Mitsubishi Chemical CorporationInventors: Mitsuharu Kobayashi, Nobuyuki Murai
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Patent number: 6403220Abstract: Novel phosphorus element-containing crosslinking agents for epoxy resin compositions based on an isomeric mixture of tris(2-hydroxyphenyl)-phosphine oxide compounds. Epoxy resins cured or crosslinked with the crosslinking agents of this invention yield non-halogenated, ignition resistant epoxy resin formulations. The ignition resistant epoxy resin formulations are advantageously used for making laminates for printed wiring boards and composite materials.Type: GrantFiled: December 11, 2000Date of Patent: June 11, 2002Assignee: The Dow Chemical CompanyInventors: David J. Brennan, John P. Everett, Bassam S. Nader
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Patent number: 6395340Abstract: This invention provides a thermosetting organic solvent paint comprising (A) a compound having at least two alicyclic epoxy groups in one molecule and having a number average molecular weight of less than 2000, (B) a secondary amino group-containing compound and (C) a thermolatent cationically polymerizable catalyst and further, under circumstances, (D) colloidal silica, and capable of forming a rigid coating film which is hard, tough and excellent in stain resistance, and from which pollutants, if adhered, are easily removed. This invention further provides a method to form a multi-layered top coating film which comprises applying, to a material to be coated, one or more species of colored paint and one or more species of clear paint in order, said method being characterized in that the above-mentioned paint is used as a clear paint which is to be applied on the uppermost layer.Type: GrantFiled: April 20, 2000Date of Patent: May 28, 2002Assignee: Kansai Paint Co., Ltd.Inventors: Seiji Wada, Satoshi Ikushima, Haruhiko Aida, Hideo Sugai
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Polymerization of poly(glycidyl nitrate) from high purity glycidyl nitrate synthesized from glycerol
Patent number: 6362311Abstract: Glycerol is nitrated with at least one nitrating source in a solvent to form a nitrated glycerol solution containing dinitroglycerin. The nitrated glycerol solution is treated with at least one cyclizing agent to convert the dinitroglycerin into glycidyl nitrate, which is polymerized into poly(glycidyl nitrate) (PGN). Distillation or other vaporization techniques are not required to remove nitroglycerin from the glycidyl nitrate prior to polymerization of the glycidyl nitrate. Rather, the nitroglycerin can be carried along with the dinitroglycerin during polymerization. As a consequence, the glycidyl nitrate is not exposed to elevated temperatures sufficient to cause accidental explosion or deflagration of the nitrate ester. Still more preferably, the glycidyl nitrate is not heated above room temperature at any time prior to polymerization. Moreover, given the high energy performance of nitroglycerin, the nitroglycerin can optionally be retained with the PGN, i.e.Type: GrantFiled: October 17, 2000Date of Patent: March 26, 2002Assignee: Alliant Techsystems Inc.Inventors: Thomas K. Highsmith, Andrew J. Sanderson, Louis F. Cannizzo, Robert M. Hajik -
Publication number: 20020033275Abstract: A paste for filling a throughhole, comprises: an epoxy resin; a curing agent; and a metal filler, wherein the metal filler is a powder comprising a base metal, and the curing agent is an imidazole compound represented by the following formula (1): 1Type: ApplicationFiled: July 13, 2001Publication date: March 21, 2002Applicant: NGK SPARK PLUG CO., LTD.Inventors: Hiroshi Sumi, Toshihumi Kojima
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Patent number: 6346592Abstract: A procedure for preparing compact and spherical self-activated polymer particles of vinyl monomers having a narrow or monodisperse size distribution in accordance with a special precipitation polymerization process in a polar organic medium, possibly in an organic polar medium mixed with water. The medium is a good solvent for the monomer and a poor solvent for the polymer. All ingredients are initially dissolved in the medium and when polymerization has been initiated, formed polymer precipitates from solution and by the aid of the dispersion stabiliser the polymer particles are kept apart as free spherical beads. The polymerization takes place with a temperature profile which produces a scattered chain length distribution, increases the conversion speed and reduces the particle size distribution. The method for producing the particles also achieves an increased degree of freedom for the production of particles with a certain particle size in a given conversion time.Type: GrantFiled: August 26, 1999Date of Patent: February 12, 2002Assignee: Norsk Hydro ASAInventors: Bård Sæthre, Steinar Pedersen
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Publication number: 20010029309Abstract: The present invention provides acetic anhydride, a method of purifying crude acetic anhydride, and a method of producing polyoxytetramethylene glycol using acetic anhydride.Type: ApplicationFiled: February 16, 2001Publication date: October 11, 2001Inventors: Seiji Nishioka, Ryosuke Maeda, Toshifumi Fukui, Mitsuru Yamashira
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Patent number: 6291540Abstract: The invention concerns a novel method for preparing non-toxic resins crosslinkable under radiation in the presence of an initiator system. Said resins are prepared from compositions of an organic and/or silicon type comprising monomers, oligomers and/or polymers with organofunctional groups, and are cross-linked in the presence of an initiator system consisting of an onium salt with low toxicity whereof the cationic structure is [(CH(CH3)2—C6H4—)—I—(—R1)]+(I).Type: GrantFiled: March 10, 2000Date of Patent: September 18, 2001Assignee: Rhodia ChimieInventors: Christian Priou, Jacques Richard
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Patent number: 6288208Abstract: The present invention relates to a highly branched polyamide oligomer of the general formula (I) as hereinabove defined, to the process for preparing and branched oligomers and to different uses thereof. As well known to the man skilled in the art, the implementations and efficacy of the different polyamide oligomers may vary, depending on their structure and valency (reactive groups composition). Polyamide oligomers may be used, for example, as epoxy hardeners in the preparation of thermosetting compositions, as thermoplastic hot melt adhesives, as adhesion promoters and many other suitable applications. The highly branched oligomers disclosed have been shown to be highly efficient, for example, as epoxy hardeners, inter alia, in the formation of glue, lacquer, enamel or sealant mixtures.Type: GrantFiled: April 20, 1999Date of Patent: September 11, 2001Assignee: Epox, Ltd.Inventor: Leonid Moshinsky
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Patent number: 6274700Abstract: In a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters thereof by polymerization of tetrahydrofuran in the presence of at least one telogen and/or comonomer over acid-activated montmorillonite catalysts, the montmorillonite catalyst after acid activation has a ratio of montmorillonite structure to the sum of muscovite and kaolin structures, determined from the intensities of the reflections at 2&thgr;=5.5° for montmorillonite, 2&thgr;=9.0° for muscovite and 2&thgr;=12.5° for kaolin measured in the X-ray powder pattern, of at least 5:1.Type: GrantFiled: June 8, 2000Date of Patent: August 14, 2001Assignee: BASF AktiengesellschaftInventors: Karsten Eller, Heinz Rütter, Michael Hesse, Rainer Becker
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Patent number: 6265459Abstract: Accelerators that can be useful for an energy polymerizable composition comprising a cationically curable material; energy polymerizable compositions comprising at least one cationically curable material and an initiation system therefor, the initiation system comprising at least one organometallic complex salt and at least one accelerator; and a method for curing the compositions. The cured compositions can provide useful articles. The invention also provides compositions of matter comprising an organometallic complex salt and at least one compound selected from the Class 1 and Class 2 compounds disclosed herein.Type: GrantFiled: December 31, 1998Date of Patent: July 24, 2001Assignee: 3M Innovative Properties CompanyInventors: Wayne Scott Mahoney, Peggy Sperl Willett
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Patent number: 6265519Abstract: The present invention relates to thiolamide curing agents and methods for their preparation and use. The thiolamide curing agents are the reaction product of a thiol containing compound and an amine containing compound.Type: GrantFiled: December 8, 1998Date of Patent: July 24, 2001Assignee: Molex IncorporatedInventor: Paul Krebaum
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Publication number: 20010003613Abstract: Flushable film compositions and methods of making flushable film compositions are disclosed. The film compositions comprise poly(ethylene oxide). The modification of the poly(ethylene oxide) can be accomplished by grafting polar vinyl monomers, such as poly(ethylene glycol) methacrylate and 2-hydroxyethyl methacrylate, onto poly(ethylene oxide). The modified poly(ethylene oxide) has improved melt processability and is used to melt process thin poly(ethylene oxide) films of less than 5 mils in thickness. Films can be produced that have balanced mechanical properties and that are water-dispersible and flushable.Type: ApplicationFiled: January 12, 2001Publication date: June 14, 2001Inventors: James Hongxue Wang, David Michael Schertz, Dave Allen Soerens
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Patent number: 6245827Abstract: This invention is of a resin composition including an additive of one or more organic peroxide thermal imitators to cationic photoinitiators, that are sensitized with alpha-hydroxy-ketones, which composition provides a self-propagating thermal curing reaction first activated by a short duration of surface ultraviolet radiation. The thermal reaction is non-directional, thus eliminating the line of sight limitation of current radiation curing processes. Complete curing can be achieved of the composition in a very short time; often after only a few minutes or less. The activation period can be provided by only a few seconds of ultraviolet light using a wide variety of commercial ultraviolet light sources.Type: GrantFiled: October 12, 1999Date of Patent: June 12, 2001Assignee: Elementis Specialties, Inc.Inventor: Scott Gregory
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Patent number: 6211261Abstract: A thermosetting pressure-sensitive adhesive which can obtain the high rate of polymerization without a decrease in the molecular weight by photopolymerization, thereby show the tackiness at ordinary temperatures to permit easy temporary adhesion to an adherend, can be cured by heating for a short period of time to exhibit strong adhesive strength and high heat resistance, and is excellent in storage stability before heating, comprising a photopolymerized product of a composition comprising a) 100 parts by weight of a monomer mixture comprising 70% to 99% by weight of an alkyl (meth)acrylate whose alkyl group has 2 to 14 carbon atoms on average, and 1% to 30% by weight of a monoethylenic unsaturated acid copolymerizable therewith based on the monomer mixture, b) 0.Type: GrantFiled: September 21, 1999Date of Patent: April 3, 2001Assignee: Nitto Denko CorporationInventors: Kazuhito Hosokawa, Masahiro Oura
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Patent number: 6207794Abstract: The present invention is a polyoxyalkylene polyol, its manufacture method, and derivatives, wherein: it is obtained using a phosphazenium compound as a catalyst; the hydroxyl value is 2˜200 mgKOH/g; total degree of unsaturation is 0.0001˜0.07 meq./g; the head-to-tail bond selectivity of the polyoxyalkylene polyol is 95 mole %; and when the maximum height of the peak of GPC elution curve is set to be 100%, W20 is defined as the peak width at the 20% peak height, and W80 is defined as the peak width at 80% peak height, the ratio of W20/W80 is 1.5 or greater, and less than 3.Type: GrantFiled: December 17, 1998Date of Patent: March 27, 2001Assignee: Mitsui Chemical, Inc.Inventors: Satoshi Yamasaki, Yasunori Hara, Satoshi Tamura, Fumio Yamazaki, Hitoshi Watanabe, Mikio Matsufuji, Shinsuke Matsumoto, Ariko Nishikawa, Tsukuru Izukawa, Masaaki Aoki, Tadahito Nobori, Usaji Takaki
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Patent number: 6207793Abstract: An improved process for Polytetramethylene-Ether-Glycol-Diesters of the formula R—CO—O(CH2—CH2—CH2—CH2—O)n-COR1, in which R and R1 are identical or different and are alkyl radicals or derivatives thereof, by polymerization of tetrahydrofuran in the presence of a heterogeneous polymerization catalyst and in the presence of a carboxylic anhydride. The use of aluminum silicate catalyst composed of acid-activated and calcinated natural halloysite instead of the known catalytic silicates as bentonite, zeolite or kaolinite. The new catalyst with a very long lifetime produces polymers having more uniform properties and narrow molecular weight distribution even with a relative impure monomer.Type: GrantFiled: July 15, 1999Date of Patent: March 27, 2001Assignee: Korea PTG Co., Ltd.Inventor: Sung-Il Kim
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Patent number: 6100375Abstract: Energetic polymers and methods for their synthesis are provided. The polymers are preferably produced from cyclic ether monomers having 4 or 5 member rings. The cyclic ether monomers preferably include energetic functional groups such that a polymer formed from the monomer is itself energetic. Polymerization is catalyzed by a combination of alkylating salt and alcohol. The preferred salts are triethoxonium salts with anions such as hexafluorophosphate, hexachloroantimonate, and tetrafluoroborate. It is found that by employing the combination of selected triethoxonium salts and selected alcohols that it is possible to produce an energetic polymer with predetermined functionality and molecular weight. The salt is found to scavenge water in the reaction mixture, thus increasing control over the functionality of the final product. The salt-alcohol combination also rapidly initiates polymerization and allows higher molecular weights to be achieved.Type: GrantFiled: April 26, 1994Date of Patent: August 8, 2000Assignee: Cordant Technologies, Inc.Inventors: Robert B. Wardle, W. Wayne Edwards
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Patent number: 6096836Abstract: Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.Type: GrantFiled: March 2, 1998Date of Patent: August 1, 2000Assignee: Kabushiki Kaisha ToshibaInventors: Shuzi Hayase, Yoshihiko Nakano, Shinji Murai, Yukihiro Mikogami
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Patent number: 6040419Abstract: An improved process for the polymerization of cyclic ethers to polyethers using strong Bronsted acid catalysts is disclosed. The catalysts are fluorinated sulfonic acid containing polymers. The resulting polyethers are useful as monomers and in adhesives.Type: GrantFiled: July 20, 1998Date of Patent: March 21, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Neville Everton Drysdale, Lin Wang, Zhen-Yu Yang
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Patent number: 6025406Abstract: Photocurable, addition polymerizable compositions contain an epoxy resin and a photoinitiator system containing (a) an epoxy resin and (b) a photoinitiator system comprising: (i) an iodonium salt; (ii) a visible light sensitizer; and (iii) an electron donor compound, wherein the photoinitiator system has a photoinduced potential of at least about 0 mV relative to a standard solution of 2.9.times.10.sup.-5 moles/g diphenyl iodonium hexafluoroantimonate and 1.5.times.10.sup.-5 moles/g camphorquinone in 2-butanone. The compositions cure on exposure to light in the visible spectrum and are useful in a variety of applications, including dental adhesives and composites.Type: GrantFiled: April 11, 1997Date of Patent: February 15, 2000Assignee: 3M Innovative Properties CompanyInventors: Joel D. Oxman, Dwight W. Jacobs
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Patent number: 6022945Abstract: A catalyst for the polymerization of an alkylene oxide compound is disclosed. This catalyst is composed of a phosphazene compound or a phosphazenium salt which is derived from the phosphazene compound and an active hydrogen compound. A poly(alkylene oxide) can be efficiently produced by polymerizing the alkylene oxide compound in the presence of the catalyst and, when the catalyst is composed of the phosphazene compound, the active hydrogen compound. The poly(alkylene oxide) contains no metal component and compared with those produced using conventional amine-base catalysts, has also been improved significantly in odor.Type: GrantFiled: May 28, 1999Date of Patent: February 8, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Masahiro Kouno, Tadahito Nobori, Kazumi Mizutani, Usaji Takaki
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Patent number: 5962547Abstract: Radiation- or thermally-initiated cationically-curable styrene oxides of the structure ##STR1## are suitable for use in cationically curable adhesive and coating compositions.Type: GrantFiled: May 14, 1998Date of Patent: October 5, 1999Inventors: Nikola A. Nikolic, Rose Ann Schultz
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Patent number: 5962546Abstract: Compositions containing conductivity enhancers, which are capable of being coated onto a substrate by means of electrostatic assistance. The compositions comprise one or more cationically polymerizable monomer(s), one or more cationic initiator(s), and one or more non-volatile conductivity enhancer(s) having anionic and cationic portions which are soluble in the monomer(s) and which do not interfere with cationic polymerization wherein the anionic portion is a non-coordinating carbon-containing anion. The compositions may further comprise one or more dissociation enhancing agent(s), oligomer(s) or polymer(s), preferably co-reactive, free-radically curable monomer(s), free-radical generating initiator(s), leveling agents, and other additives or adjuvants to impart specific properties to the polymerized composition.Type: GrantFiled: May 1, 1997Date of Patent: October 5, 1999Assignee: 3M Innovative Properties CompanyInventors: Albert I. Everaerts, William M. Lamanna, Albert E. Seaver, George V. D. Tiers
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Patent number: 5952457Abstract: A catalyst for the polymerization of an alkylene oxide compound is disclosed. This catalyst is composed of a phosphazene compound or a phosphazenium salt which is derived from the phosphazene compound and an active hydrogen compound. A poly(alkylene oxide) can be efficiently produced by polymerizing the alkylene oxide compound in the presence of the catalyst and, when the catalyst is composed of the phosphazene compound, the active hydrogen compound. The poly(alkylene oxide) contains no metal component and compared with those produced using conventional amine-base catalysts, has also been improved significantly in odor.Type: GrantFiled: September 4, 1996Date of Patent: September 14, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Masahiro Kouno, Tadahito Nobori, Kazumi Mizutani, Usaji Takaki
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Patent number: 5952458Abstract: Synthesis of a vinyl terminated polymer by reacting a cationically polymerizable monomer in the form of a cyclic ether with an acid chloride in a suitable solvent and in the presence of a Lewis acid. The vinyl-terminated polymers can be polymerized with other appropriate monomers resulting in thermoplastic elastomers having suitable properties for use as binders for explosives and propellants.Type: GrantFiled: September 24, 1998Date of Patent: September 14, 1999Assignee: The Government of the United States as represented by the Secretary of the NavyInventor: Mostafa A. H. Talukder
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Patent number: 5952446Abstract: An elastomeric epoxy composition and curing agents for elastomeric epoxy compositions, the elastomeric epoxy composition being the reaction product of a substituted amide and an epoxy.Type: GrantFiled: February 9, 1998Date of Patent: September 14, 1999Assignee: Molex IncorporatedInventor: Paul Krebaum
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Patent number: 5907054Abstract: The present invention provides a process for the production of an ester of polyoxyalkylene glycol on an industrially favorable basis which comprises the ring opening polymerization of a cyclic ether in the presence of a carboxylic anhydride and a solid acid polymerization catalyst to obtain a polymer esterified at some or all of the ends thereof, wherein the water content in the reaction system is maintained at not more than 30 ppm by weight during the polymerization reaction.Type: GrantFiled: June 2, 1997Date of Patent: May 25, 1999Assignee: Mitsubishi Chemical CorporationInventors: Tohru Setoyama, Yoshio Kabata, Mitsuharu Kobayashi
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Patent number: 5891970Abstract: The invention relates to a water-soluble self-acid-doped polyaniline derivatives and in particular, to a water-soluble self-acid-doped polyaniline derivatives obtained by reacting polyaniline derivatives with 2-sulfobenzoic anhydride derivatives, which is composed of structural unit having following formula (I): ##STR1## wherein, M may be H, Na, K or NH.sub.4 ;R.sub.1, R.sub.2, R.sub.3, R.sub.4 may be --H, --R.sub.o, --F, --Cl, --Br, --OR.sub.o, --COR.sub.o, --OCOR.sub.o, --NHCOR.sub.o, --NO.sub.2, --COOR.sub.o, --CN, --COOH;Q may be --H, --Ro, --F, --Cl, --Br, --OR.sub.o, --COR.sub.o, --OCOR.sub.o, --NHCOR.sub.o, --NO.sub.2, --COOR.sub.o, --CN, --COOH;R.sub.o is a C.sub.1 -C.sub.4 alkyl;n is an integer of 0 to 4; andx+y+2z.ltoreq.1.0, and x.gtoreq.0.1;and a process for preparing the same.The water-soluble self-acid-doped polyaniline derivatives exhibits some characteristics as follows:(1) a high water solubility;(2) a self-acid-doped property;(3) a high conductivity which may be up to 10.sup.-3 -10.sup.Type: GrantFiled: July 2, 1998Date of Patent: April 6, 1999Assignee: National Science Council of Republic of ChinaInventors: Shou-An Chen, Hsien-Kuang Lin
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Patent number: 5892067Abstract: Synthesis of a vinyl terminated polymer by reacting a cationically polymeable monomer in the form of a cyclic ether with an acid chloride in a suitable solvent and in the presence of a Lewis acid. The vinyl-terminated polymers can be polymerized with other appropriate monomers resulting in thermoplastic elastomers having suitable properties for use as binders for explosives and propellants.Type: GrantFiled: June 9, 1997Date of Patent: April 6, 1999Assignee: The United States of America as represented by the Secretary of the NavyInventor: Mostafa A. H. Talukder
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Patent number: 5886138Abstract: A process for the continuous and discontinuous production of tetrahydrofuran polymers by homopolymerizing tetrahydrofuran or copolymerizing tetrahydrofuran with 1,2-alkylene oxides in the presence of compounds with reactive hydrogen or carboxylic acid anhydrides on an acid-treated, calcined and granulated aluminium silicate catalyst which may consist of amorphous aluminium silicate, a zeolite or kaolin. By keeping the concentration of carboxylic acid anhydride or alkylene oxide constant below 1 wt. % in the polymerization recipe throughout the polymerization it is possible to largely prevent the formation of cyclic ethers and to obtain a polymer with a very narrow molecular weight distribution. In granular form, the catalysts exhibit a hitherto unknown activity and form polymers with a very narrow molecular weight distribution and low color and acid numbers.Type: GrantFiled: July 30, 1997Date of Patent: March 23, 1999Inventor: Herbert Muller
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Patent number: 5880222Abstract: Latexes are thickened by compounds of the formula:R.sup.1 -(O-A).sub.a -B.sup.1 -R.sup.2 -(B.sup.2 -R.sup.3).sub.d -(B.sup.3 -(A'-O).sub.b-f -(A'-B.sup.4).sub.f -R.sup.4 -(B.sup.5 -R.sup.5).sub.e).sub.n -B.sup.6 -(A"O).sub.c -R.sup.6wherein:R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group;R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent;R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl;B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5, and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylate group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.Type: GrantFiled: September 19, 1997Date of Patent: March 9, 1999Assignee: Henkel CorporationInventors: Michael S. Wiggins, Reuben H. Grinstein
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Patent number: 5854384Abstract: A process for preparing poly-.alpha.-amino acid particles comprising polymerizing an .alpha.-amino acid-N-carboxy anhydride using a polymerization initiator in an organic solvent in which both the solubility of the .alpha.-amino acid-N-carboxy anhydride and the solubility of the produced poly-.alpha.-amino acid are 0.1 g/100 ml or less at 25.degree. C. Polyamino acid particles having a high molecular weight and a small bulk specific gravity can be manufactured very easily without requiring specific procedures. The polyamino acid particles can be used as a coating material for papers, resins, rubbers, and fibers; particles for cosmetics; particles for diagnostic drugs; fillers for chromatography; and an encapsulating material for drugs, fertilizers, and perfumes.Type: GrantFiled: September 25, 1996Date of Patent: December 29, 1998Assignee: SR CorporationInventors: Kyoko Kuroda, Masayuki Hattori, Yoshitaka Yamakawa, Kenya Makino, Toshio Hayashi
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Patent number: 5854341Abstract: An anti-fogging coating composition contains (a) an inorganic alkoxide and/or a hydroxyl group-containing polymer formed therefrom by hydrolysis and polycondensation, the inorganic alkoxide being represented by the formula (I):M(OR).sub.n (X).sub.a-n (I),wherein M is an inorganic element selected from the group consisting of Si, Al, Ti, Zr, Ca, Fe, V, Sn, Li, Be, B and P; R is an alkyl group; X is an alkyl group with or without functional groups or a halogen atom; a is a number representing the valence of M; and n is an integer from 1 to a; (b) a polyalkylene oxide, a weight ratio of the polyalkylene oxide to the inorganic alkoxide and/or the hydroxyl group-containing polymer being 100/1-100/150; (c) 0.5 parts by weight or less of an acid catalyst per 100 parts by weight of (a); (d) 0.Type: GrantFiled: December 8, 1995Date of Patent: December 29, 1998Assignees: Nakato Laboratory, Inc., Canon Kabushiki KaishaInventors: Tohru Yamamoto, Shigeo Yoshida, Hatsumi Ikari
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Patent number: 5837771Abstract: For improved flame retardant finishing and better processability of an epoxy anhydride reaction resin system, the present invention provides a reaction resin system supplemented with phosphinic and/or phosphonic acid anhydride as the hardener component. The phosphorus-containing anhydrides do not deteriorate the hardening characteristics. Molded members manufactured therefrom exhibit adequate flame retardant behavior even with slight proportions of phosphinic or phosphonic acid anhydride given a property profile that is otherwise unmodified.Type: GrantFiled: January 11, 1996Date of Patent: November 17, 1998Assignee: Lemens AktiengesellschaftInventors: Ernst Wipfelder, Winfried Plundrich
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Patent number: 5817746Abstract: In polymerizing hexafluoropropene oxide (HFPO) into a fluorinated polyether, a liquefied gas of fluorocarbon having 1 to 4 carbon atoms is added to a reactor. HFPO is polymerized in the reactor while maintaining a gas phase in the reactor under a pressure lower than the vapor pressure of the liquefied gas and allowing the liquefied gas to evaporate from the polymerization system. Heat of polymerization can be efficiently removed from the HFPO polymerization system of high viscosity, and the polymerization temperature is kept low.Type: GrantFiled: September 30, 1997Date of Patent: October 6, 1998Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Noriyuki Koike, Takashi Matsuda, Shinichi Sato, Hirofumi Kishita, Masatoshi Arai
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Patent number: 5811497Abstract: Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.Type: GrantFiled: September 11, 1995Date of Patent: September 22, 1998Assignee: Kabushiki Kaisha ToshibaInventors: Shuzi Hayase, Yoshihiko Nakano, Shinji Murai, Yukihiro Mikogami
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Patent number: 5798412Abstract: A process in which carbon is used to catalyze production of alkylene glycols from alkylene oxides and water. Using this process, carbon may be employed to selectively catalyze the hydrolysis of alkylene oxides, such as ethylene oxide, to monoalkylene gylcols, such as monoethylene glycol. Typically, activated carbon is employed. Suitable forms of activated carbon or other carbon material include powders, granulates, extruded shapes, or mixtures thereof. The process may be carried out as a continuous or batch reaction process.Type: GrantFiled: July 16, 1997Date of Patent: August 25, 1998Assignee: Huntsman Petrochemical CorporationInventors: John R. Sanderson, Edward T. Marquis
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Patent number: 5798396Abstract: The present invention is directed to sulfonium salt-containing compounds represented by a following general formula; ##STR1## wherein R.sub.1 is alkyl containing from 1 to 18 carbon atoms, hydroxy, alkoxy containing from 1 to 18 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms or halogen, n is any of 0, 1, 2 or 3, however, each of R.sub.1 may be different from the others when n is 2 or more, R.sub.2 is alkyl containing from 1 to 6 carbon atoms, R.sub.3 and R.sub.4 are each independently hydrogen or alkyl containing from 1 to 6 carbon atoms, R.sub.5 and R.sub.6 are each independently hydrogen, alkyl containing from 1 to 6 carbon atoms, hydroxy, alkoxy containing from 1 to 6 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms or aromatic carbonyloxy, and R.sub.7 is alkyl containing from 4 to 20 carbon atoms or a group represented by a following formula; ##STR2## wherein R.sub.Type: GrantFiled: September 4, 1996Date of Patent: August 25, 1998Assignee: Nippon Soda Co., Ltd.Inventors: Eiji Takahashi, Hiroo Muramoto
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Patent number: 5786308Abstract: A new group of polymer flow controllers for powder resin lacquer is provided. The polymer flow controllers contain groups ##STR1## wherein n and m are numbers from 0 to 1000 with the sum of n+m=2-1000 and R.sub.1 and R.sub.2 are independently hydrogen, an optionally hydroxy substituted hydrocarbon group containing 1 to 36 carbon atoms aryl and aralkyl optionally substituted in the aromatic nucleus, or R.sub.3 --(--O--C.sub.2 H.sub.4 --)--.sub.p O--CH.sub.2 -- wherein R.sub.3 is an alkyl or alkenyl group containing 1 to 18 carbon atoms and p is a number of 1 to 10.Type: GrantFiled: August 27, 1996Date of Patent: July 28, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ulrich Eicken, Brigitte Hase, Herbert Fischer, Paul Birnbrich, Heinz-Guenter Schulte, Wolfgang Gress, Harald Frommelius
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Patent number: 5780555Abstract: An amine curing agent composition for an epoxy resin is provided having low volatility and good processability containing a) a polyamine curing agent and b) an aliphatic alcohol-alkylene oxide adduct. An epoxy resin-polyamine curing agent system containing an aliphatic alcohol-alkylene oxide adduct is also provided.Type: GrantFiled: September 16, 1996Date of Patent: July 14, 1998Assignee: Shell Oil CompanyInventors: Larry Steven Corley, Kalyan Ghosh, Joseph Michael Hunter, Derek Scott Kincaid, Leo Meilus, Daniel James Weinmann
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Patent number: 5763636Abstract: Polymers containing spiro atoms which can be used as electroluminescence materials, suitable for use in ligerting or display devices, and which improve the property profile of these devices. Specifically, a conjugated polymer comprising structural units of the formula (I), ##STR1## where the symbols and indices have the following meanings: D, E, F.sup.1, G are identical or different, and are --CR.sup.1 R.sup.1 --, --O--, --S--, --NR.sup.3 -- or a chemical bond;Ar.sup.1, Ar.sup.2 are carbocycles or heterocycles;U.sup.1, V.sup.1 are identical or different, and are --CR.sup.5.dbd.CR.sup.6 --, --CR.sup.7 R.sup.8 --, --CR.sup.9 R.sup.10 --CR.sup.11 R.sup.12 --, --NR.sup.13 --, --SiR.sup.14 R.sup.15 --, --O--, --S--, --SO--, --SO.sub.2 --, --CO-- or a chemical bond;Ar.sup.5, Ar.sup.6, X, Y.sup.1 are identical or different, and are cyclic or acyclic, conjugated hydrocarbons and X and/or y.sup.1 can also be H or R.sup.Type: GrantFiled: March 4, 1997Date of Patent: June 9, 1998Assignee: Hoechst AktiengesellschaftInventors: Willi Kreuder, Hubert Spreitzer
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Patent number: 5750218Abstract: A process for the production of biodegradable aliphatic polyester particles by (co)polymerizing 2-oxetanone or a mixture containing at least 80% by weight of 2-oxetanone and up to 20% by weight of a cyclic ester or cyclic ether other than 2-oxetanone in the presence of a polymerization initiator supported on a carrier in which an ion polymerization initiator is supported on poly(2-oxetanone) in a liquid medium having a solubility parameter of about 15 to about 18 MPa.sup.1/2 and being capable of dissolving 2-oxetanone, and in a polymerizing apparatus having an internal surface formed of a material which is free of polarity or whose polarity is very small, to form a particulate aliphatic polyester; and a biodegradable aliphatic polyester melt-extrusion film, which comprises the biodegradable aliphatic polyester having a weight average molecular weight of 20,000 to 2,000,000, and having a water vapor transmission rate of 300 to 700 g/m.sup.2 .multidot.24 hours.multidot.25 .mu.Type: GrantFiled: April 25, 1995Date of Patent: May 12, 1998Assignee: Tokuyama CorporationInventors: Haruo Nishida, Mitsuhiro Yamashita, Yoshiki Ochi, Tetsuo Kuwaki
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Patent number: 5746935Abstract: An amine curing agent composition for an epoxy resin is provided having low volatility and good processability containing a) a polyamine curing agent and b) an aliphatic alcohol-alkylene oxide adduct. An epoxy resin-polyamine curing agent system containing an aliphatic alcohol-alkylene oxide adduct is also provided.Type: GrantFiled: September 23, 1996Date of Patent: May 5, 1998Assignee: Shell Oil CompanyInventors: Larry Steven Corley, Kalyan Ghosh, Joseph Michael Hunter, Derek Scott Kincaid, Leo Meilus, Daniel James Weinmann
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Patent number: 5741866Abstract: Disclosed is a method for producing an acetal copolymer, which comprises copolymerizing trioxane with a cyclic ether in the presence of a cation-active catalyst, wherein the cyclic ether is obtained by adding to a fresh cyclic ether containing a peroxide derived therefrom in an amount of 15 ppm by weight or less in terms of hydrogen peroxide at least one sterically hindered phenol in an amount of from 10 to 500 ppm by weight, based on the weight of said fresh cyclic ether. By the method of the present invention, it has become possible not only to stably and efficiently produce an acetal copolymer having high thermal stability, but also to stably conduct a post-treatment of the obtained acetal copolymer for deactivating the remaining catalyst and changing the unstable terminals to stable terminals, so that an ultimate acetal copolymer having high thermal stability can be stably obtained.Type: GrantFiled: May 6, 1996Date of Patent: April 21, 1998Assignee: Asahi Kasei Kogo Kabushiki KaishaInventors: Shyuzi Yahiro, Minoru Yamamoto
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Patent number: 5728796Abstract: A process reaction between: (1) a compound that contains one or more epoxide moieties per molecule, and (2) a compound that contains one or more primary aliphatic hydroxyl groups per molecule; is catalyzed by: (3) a catalyst compound containing one or more trifluoromethanesulfonate moieties and one or more silyl moieties and run at a temperature of no more than 130.degree. C., such that the catalyst preferably catalyzes reaction at the primary aliphatic hydroxyl group, so that the resulting resin does not gel.Type: GrantFiled: May 31, 1996Date of Patent: March 17, 1998Assignee: The Dow Chemical CompanyInventors: Zeng K. Liao, James L. Bertram