Polymerizing In The Presence Of A Specified Material Other Than A Reactant Patents (Class 528/408)
  • Patent number: 6432488
    Abstract: A powder coating composition and method of applying it to a substrate, such as medium density fibreboard, consisting of a glycidyl methacrylate resin, a dicarboxylic acid cross-linking agent, a catalyst selected from phosphines, phosphonium, ammonium 2-phenyl-2-imidazoline, substituted imidazoline and isopropyl imidazole Bis-A epoxy resin adduct and a matte texturing agent. The inventive formulation is able to create a matte texture finish on the surface of the substrate. Since the cured final coating is resistant to yellowing and moisture, it is of great utility in the kitchen cabinet making industry.
    Type: Grant
    Filed: July 28, 2000
    Date of Patent: August 13, 2002
    Assignee: Rohm and Haas Company
    Inventors: Andrew T. Daly, Richard P. Haley, Edward G. Nicholl
  • Publication number: 20020103330
    Abstract: A naphthalene derivative, binaphthalene derivative and biphenyl derivative, all having an oxetane group, capable of being cationically polymerized and a cationically curable compound containing a naphthalene derivative having an oxetanyl group and an aromatic compound having an epoxy group or an oxetanyl group.
    Type: Application
    Filed: December 13, 2001
    Publication date: August 1, 2002
    Applicant: Toagosei Co., Ltd.
    Inventors: Akira Kuriyama, Naokazu Ito, Tetsuya Suzuta, Takashi Tsuda
  • Patent number: 6420460
    Abstract: The present invention relates to a thermally and cationically curable composition containing triarylcyclopropenylium salts and a solvent that is a Lewis base which contains acidic hydrogen and their use as thermal initiators in polymerization processes. The present invention includes the polymerization of epoxy resins, vinyl ethers and other cationically curable monomers.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: July 16, 2002
    Assignee: UCB S.A.
    Inventors: Wenqin Zhang, John H. Malpert, Douglas C. Neckers, Dustin B. Martin
  • Patent number: 6410676
    Abstract: The object is to provide a method for producing a polyoxyalkylene polyol and a method for producing a derivative thereof wherein the remaining catalyst compound is efficiently removed from a crude polyoxyalkylene polyol by a simple manner, and a method for producing a polyoxyalkylene polyol wherein a crude polyoxyalkylene polyol is produced by addition polymerization of an epoxide compound to an active hydrogen compound using as a catalyst a compound having a P═N bond, then, the crude polyoxyalkylene polyol is allowed to contact with a solid acid having a specific surface area of 450 to 1200 m2/g and an average pore diameter of 40 to 100 Å to control the catalyst-remaining amount in the polyoxyalkylene polyol to 150 ppm or less, and a method for producing a derivative of the-above-described polyol are provided.
    Type: Grant
    Filed: May 30, 2000
    Date of Patent: June 25, 2002
    Assignee: Mitsui chemicals, Inc.
    Inventors: Satoshi Yamasaki, Yasunori Hara, Tamotsu Kunihiro, Fumio Yamazaki, Mikio Matsufuji, Ariko Nishikawa, Shinsuke Matsumoto, Tsukuru Izukawa, Masahiro Isobe, Kazuhiko Ohkubo, Kaoru Ueno
  • Patent number: 6403220
    Abstract: Novel phosphorus element-containing crosslinking agents for epoxy resin compositions based on an isomeric mixture of tris(2-hydroxyphenyl)-phosphine oxide compounds. Epoxy resins cured or crosslinked with the crosslinking agents of this invention yield non-halogenated, ignition resistant epoxy resin formulations. The ignition resistant epoxy resin formulations are advantageously used for making laminates for printed wiring boards and composite materials.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: June 11, 2002
    Assignee: The Dow Chemical Company
    Inventors: David J. Brennan, John P. Everett, Bassam S. Nader
  • Patent number: 6403842
    Abstract: Disclosed are a process for producing a poly(alkylene ether) glycol which comprises polymerizing a cyclic ether in the presence of at least a catalyst and a carboxylic acid anhydride, wherein the carboxylic acid anhydride has a ketene dimer content of 50 ppm or lower, and a process for producing a poly(alkylene ether) glycol which comprises polymerizing a cyclic ether in the presence of at least a catalyst and acetic anhydride, wherein the acetic anhydride is purified acetic anhydride obtained by treating acetic anhydride by contacting with at least one of a metal oxide and a mixed oxide, and optionally, distilling the acetic anhydride simultaneously with or after the contact treatment.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: June 11, 2002
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Mitsuharu Kobayashi, Nobuyuki Murai
  • Patent number: 6395340
    Abstract: This invention provides a thermosetting organic solvent paint comprising (A) a compound having at least two alicyclic epoxy groups in one molecule and having a number average molecular weight of less than 2000, (B) a secondary amino group-containing compound and (C) a thermolatent cationically polymerizable catalyst and further, under circumstances, (D) colloidal silica, and capable of forming a rigid coating film which is hard, tough and excellent in stain resistance, and from which pollutants, if adhered, are easily removed. This invention further provides a method to form a multi-layered top coating film which comprises applying, to a material to be coated, one or more species of colored paint and one or more species of clear paint in order, said method being characterized in that the above-mentioned paint is used as a clear paint which is to be applied on the uppermost layer.
    Type: Grant
    Filed: April 20, 2000
    Date of Patent: May 28, 2002
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Seiji Wada, Satoshi Ikushima, Haruhiko Aida, Hideo Sugai
  • Patent number: 6362311
    Abstract: Glycerol is nitrated with at least one nitrating source in a solvent to form a nitrated glycerol solution containing dinitroglycerin. The nitrated glycerol solution is treated with at least one cyclizing agent to convert the dinitroglycerin into glycidyl nitrate, which is polymerized into poly(glycidyl nitrate) (PGN). Distillation or other vaporization techniques are not required to remove nitroglycerin from the glycidyl nitrate prior to polymerization of the glycidyl nitrate. Rather, the nitroglycerin can be carried along with the dinitroglycerin during polymerization. As a consequence, the glycidyl nitrate is not exposed to elevated temperatures sufficient to cause accidental explosion or deflagration of the nitrate ester. Still more preferably, the glycidyl nitrate is not heated above room temperature at any time prior to polymerization. Moreover, given the high energy performance of nitroglycerin, the nitroglycerin can optionally be retained with the PGN, i.e.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: March 26, 2002
    Assignee: Alliant Techsystems Inc.
    Inventors: Thomas K. Highsmith, Andrew J. Sanderson, Louis F. Cannizzo, Robert M. Hajik
  • Publication number: 20020033275
    Abstract: A paste for filling a throughhole, comprises: an epoxy resin; a curing agent; and a metal filler, wherein the metal filler is a powder comprising a base metal, and the curing agent is an imidazole compound represented by the following formula (1): 1
    Type: Application
    Filed: July 13, 2001
    Publication date: March 21, 2002
    Applicant: NGK SPARK PLUG CO., LTD.
    Inventors: Hiroshi Sumi, Toshihumi Kojima
  • Patent number: 6346592
    Abstract: A procedure for preparing compact and spherical self-activated polymer particles of vinyl monomers having a narrow or monodisperse size distribution in accordance with a special precipitation polymerization process in a polar organic medium, possibly in an organic polar medium mixed with water. The medium is a good solvent for the monomer and a poor solvent for the polymer. All ingredients are initially dissolved in the medium and when polymerization has been initiated, formed polymer precipitates from solution and by the aid of the dispersion stabiliser the polymer particles are kept apart as free spherical beads. The polymerization takes place with a temperature profile which produces a scattered chain length distribution, increases the conversion speed and reduces the particle size distribution. The method for producing the particles also achieves an increased degree of freedom for the production of particles with a certain particle size in a given conversion time.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: February 12, 2002
    Assignee: Norsk Hydro ASA
    Inventors: Bård Sæthre, Steinar Pedersen
  • Publication number: 20010029309
    Abstract: The present invention provides acetic anhydride, a method of purifying crude acetic anhydride, and a method of producing polyoxytetramethylene glycol using acetic anhydride.
    Type: Application
    Filed: February 16, 2001
    Publication date: October 11, 2001
    Inventors: Seiji Nishioka, Ryosuke Maeda, Toshifumi Fukui, Mitsuru Yamashira
  • Patent number: 6291540
    Abstract: The invention concerns a novel method for preparing non-toxic resins crosslinkable under radiation in the presence of an initiator system. Said resins are prepared from compositions of an organic and/or silicon type comprising monomers, oligomers and/or polymers with organofunctional groups, and are cross-linked in the presence of an initiator system consisting of an onium salt with low toxicity whereof the cationic structure is [(CH(CH3)2—C6H4—)—I—(—R1)]+(I).
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: September 18, 2001
    Assignee: Rhodia Chimie
    Inventors: Christian Priou, Jacques Richard
  • Patent number: 6288208
    Abstract: The present invention relates to a highly branched polyamide oligomer of the general formula (I) as hereinabove defined, to the process for preparing and branched oligomers and to different uses thereof. As well known to the man skilled in the art, the implementations and efficacy of the different polyamide oligomers may vary, depending on their structure and valency (reactive groups composition). Polyamide oligomers may be used, for example, as epoxy hardeners in the preparation of thermosetting compositions, as thermoplastic hot melt adhesives, as adhesion promoters and many other suitable applications. The highly branched oligomers disclosed have been shown to be highly efficient, for example, as epoxy hardeners, inter alia, in the formation of glue, lacquer, enamel or sealant mixtures.
    Type: Grant
    Filed: April 20, 1999
    Date of Patent: September 11, 2001
    Assignee: Epox, Ltd.
    Inventor: Leonid Moshinsky
  • Patent number: 6274700
    Abstract: In a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters thereof by polymerization of tetrahydrofuran in the presence of at least one telogen and/or comonomer over acid-activated montmorillonite catalysts, the montmorillonite catalyst after acid activation has a ratio of montmorillonite structure to the sum of muscovite and kaolin structures, determined from the intensities of the reflections at 2&thgr;=5.5° for montmorillonite, 2&thgr;=9.0° for muscovite and 2&thgr;=12.5° for kaolin measured in the X-ray powder pattern, of at least 5:1.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: August 14, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Karsten Eller, Heinz Rütter, Michael Hesse, Rainer Becker
  • Patent number: 6265459
    Abstract: Accelerators that can be useful for an energy polymerizable composition comprising a cationically curable material; energy polymerizable compositions comprising at least one cationically curable material and an initiation system therefor, the initiation system comprising at least one organometallic complex salt and at least one accelerator; and a method for curing the compositions. The cured compositions can provide useful articles. The invention also provides compositions of matter comprising an organometallic complex salt and at least one compound selected from the Class 1 and Class 2 compounds disclosed herein.
    Type: Grant
    Filed: December 31, 1998
    Date of Patent: July 24, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Wayne Scott Mahoney, Peggy Sperl Willett
  • Patent number: 6265519
    Abstract: The present invention relates to thiolamide curing agents and methods for their preparation and use. The thiolamide curing agents are the reaction product of a thiol containing compound and an amine containing compound.
    Type: Grant
    Filed: December 8, 1998
    Date of Patent: July 24, 2001
    Assignee: Molex Incorporated
    Inventor: Paul Krebaum
  • Publication number: 20010003613
    Abstract: Flushable film compositions and methods of making flushable film compositions are disclosed. The film compositions comprise poly(ethylene oxide). The modification of the poly(ethylene oxide) can be accomplished by grafting polar vinyl monomers, such as poly(ethylene glycol) methacrylate and 2-hydroxyethyl methacrylate, onto poly(ethylene oxide). The modified poly(ethylene oxide) has improved melt processability and is used to melt process thin poly(ethylene oxide) films of less than 5 mils in thickness. Films can be produced that have balanced mechanical properties and that are water-dispersible and flushable.
    Type: Application
    Filed: January 12, 2001
    Publication date: June 14, 2001
    Inventors: James Hongxue Wang, David Michael Schertz, Dave Allen Soerens
  • Patent number: 6245827
    Abstract: This invention is of a resin composition including an additive of one or more organic peroxide thermal imitators to cationic photoinitiators, that are sensitized with alpha-hydroxy-ketones, which composition provides a self-propagating thermal curing reaction first activated by a short duration of surface ultraviolet radiation. The thermal reaction is non-directional, thus eliminating the line of sight limitation of current radiation curing processes. Complete curing can be achieved of the composition in a very short time; often after only a few minutes or less. The activation period can be provided by only a few seconds of ultraviolet light using a wide variety of commercial ultraviolet light sources.
    Type: Grant
    Filed: October 12, 1999
    Date of Patent: June 12, 2001
    Assignee: Elementis Specialties, Inc.
    Inventor: Scott Gregory
  • Patent number: 6211261
    Abstract: A thermosetting pressure-sensitive adhesive which can obtain the high rate of polymerization without a decrease in the molecular weight by photopolymerization, thereby show the tackiness at ordinary temperatures to permit easy temporary adhesion to an adherend, can be cured by heating for a short period of time to exhibit strong adhesive strength and high heat resistance, and is excellent in storage stability before heating, comprising a photopolymerized product of a composition comprising a) 100 parts by weight of a monomer mixture comprising 70% to 99% by weight of an alkyl (meth)acrylate whose alkyl group has 2 to 14 carbon atoms on average, and 1% to 30% by weight of a monoethylenic unsaturated acid copolymerizable therewith based on the monomer mixture, b) 0.
    Type: Grant
    Filed: September 21, 1999
    Date of Patent: April 3, 2001
    Assignee: Nitto Denko Corporation
    Inventors: Kazuhito Hosokawa, Masahiro Oura
  • Patent number: 6207793
    Abstract: An improved process for Polytetramethylene-Ether-Glycol-Diesters of the formula R—CO—O(CH2—CH2—CH2—CH2—O)n-COR1, in which R and R1 are identical or different and are alkyl radicals or derivatives thereof, by polymerization of tetrahydrofuran in the presence of a heterogeneous polymerization catalyst and in the presence of a carboxylic anhydride. The use of aluminum silicate catalyst composed of acid-activated and calcinated natural halloysite instead of the known catalytic silicates as bentonite, zeolite or kaolinite. The new catalyst with a very long lifetime produces polymers having more uniform properties and narrow molecular weight distribution even with a relative impure monomer.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: March 27, 2001
    Assignee: Korea PTG Co., Ltd.
    Inventor: Sung-Il Kim
  • Patent number: 6207794
    Abstract: The present invention is a polyoxyalkylene polyol, its manufacture method, and derivatives, wherein: it is obtained using a phosphazenium compound as a catalyst; the hydroxyl value is 2˜200 mgKOH/g; total degree of unsaturation is 0.0001˜0.07 meq./g; the head-to-tail bond selectivity of the polyoxyalkylene polyol is 95 mole %; and when the maximum height of the peak of GPC elution curve is set to be 100%, W20 is defined as the peak width at the 20% peak height, and W80 is defined as the peak width at 80% peak height, the ratio of W20/W80 is 1.5 or greater, and less than 3.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: March 27, 2001
    Assignee: Mitsui Chemical, Inc.
    Inventors: Satoshi Yamasaki, Yasunori Hara, Satoshi Tamura, Fumio Yamazaki, Hitoshi Watanabe, Mikio Matsufuji, Shinsuke Matsumoto, Ariko Nishikawa, Tsukuru Izukawa, Masaaki Aoki, Tadahito Nobori, Usaji Takaki
  • Patent number: 6100375
    Abstract: Energetic polymers and methods for their synthesis are provided. The polymers are preferably produced from cyclic ether monomers having 4 or 5 member rings. The cyclic ether monomers preferably include energetic functional groups such that a polymer formed from the monomer is itself energetic. Polymerization is catalyzed by a combination of alkylating salt and alcohol. The preferred salts are triethoxonium salts with anions such as hexafluorophosphate, hexachloroantimonate, and tetrafluoroborate. It is found that by employing the combination of selected triethoxonium salts and selected alcohols that it is possible to produce an energetic polymer with predetermined functionality and molecular weight. The salt is found to scavenge water in the reaction mixture, thus increasing control over the functionality of the final product. The salt-alcohol combination also rapidly initiates polymerization and allows higher molecular weights to be achieved.
    Type: Grant
    Filed: April 26, 1994
    Date of Patent: August 8, 2000
    Assignee: Cordant Technologies, Inc.
    Inventors: Robert B. Wardle, W. Wayne Edwards
  • Patent number: 6096836
    Abstract: Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: August 1, 2000
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Shuzi Hayase, Yoshihiko Nakano, Shinji Murai, Yukihiro Mikogami
  • Patent number: 6040419
    Abstract: An improved process for the polymerization of cyclic ethers to polyethers using strong Bronsted acid catalysts is disclosed. The catalysts are fluorinated sulfonic acid containing polymers. The resulting polyethers are useful as monomers and in adhesives.
    Type: Grant
    Filed: July 20, 1998
    Date of Patent: March 21, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Neville Everton Drysdale, Lin Wang, Zhen-Yu Yang
  • Patent number: 6025406
    Abstract: Photocurable, addition polymerizable compositions contain an epoxy resin and a photoinitiator system containing (a) an epoxy resin and (b) a photoinitiator system comprising: (i) an iodonium salt; (ii) a visible light sensitizer; and (iii) an electron donor compound, wherein the photoinitiator system has a photoinduced potential of at least about 0 mV relative to a standard solution of 2.9.times.10.sup.-5 moles/g diphenyl iodonium hexafluoroantimonate and 1.5.times.10.sup.-5 moles/g camphorquinone in 2-butanone. The compositions cure on exposure to light in the visible spectrum and are useful in a variety of applications, including dental adhesives and composites.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: February 15, 2000
    Assignee: 3M Innovative Properties Company
    Inventors: Joel D. Oxman, Dwight W. Jacobs
  • Patent number: 6022945
    Abstract: A catalyst for the polymerization of an alkylene oxide compound is disclosed. This catalyst is composed of a phosphazene compound or a phosphazenium salt which is derived from the phosphazene compound and an active hydrogen compound. A poly(alkylene oxide) can be efficiently produced by polymerizing the alkylene oxide compound in the presence of the catalyst and, when the catalyst is composed of the phosphazene compound, the active hydrogen compound. The poly(alkylene oxide) contains no metal component and compared with those produced using conventional amine-base catalysts, has also been improved significantly in odor.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: February 8, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiro Kouno, Tadahito Nobori, Kazumi Mizutani, Usaji Takaki
  • Patent number: 5962546
    Abstract: Compositions containing conductivity enhancers, which are capable of being coated onto a substrate by means of electrostatic assistance. The compositions comprise one or more cationically polymerizable monomer(s), one or more cationic initiator(s), and one or more non-volatile conductivity enhancer(s) having anionic and cationic portions which are soluble in the monomer(s) and which do not interfere with cationic polymerization wherein the anionic portion is a non-coordinating carbon-containing anion. The compositions may further comprise one or more dissociation enhancing agent(s), oligomer(s) or polymer(s), preferably co-reactive, free-radically curable monomer(s), free-radical generating initiator(s), leveling agents, and other additives or adjuvants to impart specific properties to the polymerized composition.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: October 5, 1999
    Assignee: 3M Innovative Properties Company
    Inventors: Albert I. Everaerts, William M. Lamanna, Albert E. Seaver, George V. D. Tiers
  • Patent number: 5962547
    Abstract: Radiation- or thermally-initiated cationically-curable styrene oxides of the structure ##STR1## are suitable for use in cationically curable adhesive and coating compositions.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: October 5, 1999
    Inventors: Nikola A. Nikolic, Rose Ann Schultz
  • Patent number: 5952446
    Abstract: An elastomeric epoxy composition and curing agents for elastomeric epoxy compositions, the elastomeric epoxy composition being the reaction product of a substituted amide and an epoxy.
    Type: Grant
    Filed: February 9, 1998
    Date of Patent: September 14, 1999
    Assignee: Molex Incorporated
    Inventor: Paul Krebaum
  • Patent number: 5952458
    Abstract: Synthesis of a vinyl terminated polymer by reacting a cationically polymerizable monomer in the form of a cyclic ether with an acid chloride in a suitable solvent and in the presence of a Lewis acid. The vinyl-terminated polymers can be polymerized with other appropriate monomers resulting in thermoplastic elastomers having suitable properties for use as binders for explosives and propellants.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: September 14, 1999
    Assignee: The Government of the United States as represented by the Secretary of the Navy
    Inventor: Mostafa A. H. Talukder
  • Patent number: 5952457
    Abstract: A catalyst for the polymerization of an alkylene oxide compound is disclosed. This catalyst is composed of a phosphazene compound or a phosphazenium salt which is derived from the phosphazene compound and an active hydrogen compound. A poly(alkylene oxide) can be efficiently produced by polymerizing the alkylene oxide compound in the presence of the catalyst and, when the catalyst is composed of the phosphazene compound, the active hydrogen compound. The poly(alkylene oxide) contains no metal component and compared with those produced using conventional amine-base catalysts, has also been improved significantly in odor.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: September 14, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiro Kouno, Tadahito Nobori, Kazumi Mizutani, Usaji Takaki
  • Patent number: 5907054
    Abstract: The present invention provides a process for the production of an ester of polyoxyalkylene glycol on an industrially favorable basis which comprises the ring opening polymerization of a cyclic ether in the presence of a carboxylic anhydride and a solid acid polymerization catalyst to obtain a polymer esterified at some or all of the ends thereof, wherein the water content in the reaction system is maintained at not more than 30 ppm by weight during the polymerization reaction.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: May 25, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tohru Setoyama, Yoshio Kabata, Mitsuharu Kobayashi
  • Patent number: 5892067
    Abstract: Synthesis of a vinyl terminated polymer by reacting a cationically polymeable monomer in the form of a cyclic ether with an acid chloride in a suitable solvent and in the presence of a Lewis acid. The vinyl-terminated polymers can be polymerized with other appropriate monomers resulting in thermoplastic elastomers having suitable properties for use as binders for explosives and propellants.
    Type: Grant
    Filed: June 9, 1997
    Date of Patent: April 6, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Mostafa A. H. Talukder
  • Patent number: 5891970
    Abstract: The invention relates to a water-soluble self-acid-doped polyaniline derivatives and in particular, to a water-soluble self-acid-doped polyaniline derivatives obtained by reacting polyaniline derivatives with 2-sulfobenzoic anhydride derivatives, which is composed of structural unit having following formula (I): ##STR1## wherein, M may be H, Na, K or NH.sub.4 ;R.sub.1, R.sub.2, R.sub.3, R.sub.4 may be --H, --R.sub.o, --F, --Cl, --Br, --OR.sub.o, --COR.sub.o, --OCOR.sub.o, --NHCOR.sub.o, --NO.sub.2, --COOR.sub.o, --CN, --COOH;Q may be --H, --Ro, --F, --Cl, --Br, --OR.sub.o, --COR.sub.o, --OCOR.sub.o, --NHCOR.sub.o, --NO.sub.2, --COOR.sub.o, --CN, --COOH;R.sub.o is a C.sub.1 -C.sub.4 alkyl;n is an integer of 0 to 4; andx+y+2z.ltoreq.1.0, and x.gtoreq.0.1;and a process for preparing the same.The water-soluble self-acid-doped polyaniline derivatives exhibits some characteristics as follows:(1) a high water solubility;(2) a self-acid-doped property;(3) a high conductivity which may be up to 10.sup.-3 -10.sup.
    Type: Grant
    Filed: July 2, 1998
    Date of Patent: April 6, 1999
    Assignee: National Science Council of Republic of China
    Inventors: Shou-An Chen, Hsien-Kuang Lin
  • Patent number: 5886138
    Abstract: A process for the continuous and discontinuous production of tetrahydrofuran polymers by homopolymerizing tetrahydrofuran or copolymerizing tetrahydrofuran with 1,2-alkylene oxides in the presence of compounds with reactive hydrogen or carboxylic acid anhydrides on an acid-treated, calcined and granulated aluminium silicate catalyst which may consist of amorphous aluminium silicate, a zeolite or kaolin. By keeping the concentration of carboxylic acid anhydride or alkylene oxide constant below 1 wt. % in the polymerization recipe throughout the polymerization it is possible to largely prevent the formation of cyclic ethers and to obtain a polymer with a very narrow molecular weight distribution. In granular form, the catalysts exhibit a hitherto unknown activity and form polymers with a very narrow molecular weight distribution and low color and acid numbers.
    Type: Grant
    Filed: July 30, 1997
    Date of Patent: March 23, 1999
    Inventor: Herbert Muller
  • Patent number: 5880222
    Abstract: Latexes are thickened by compounds of the formula:R.sup.1 -(O-A).sub.a -B.sup.1 -R.sup.2 -(B.sup.2 -R.sup.3).sub.d -(B.sup.3 -(A'-O).sub.b-f -(A'-B.sup.4).sub.f -R.sup.4 -(B.sup.5 -R.sup.5).sub.e).sub.n -B.sup.6 -(A"O).sub.c -R.sup.6wherein:R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group;R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent;R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl;B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5, and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylate group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: March 9, 1999
    Assignee: Henkel Corporation
    Inventors: Michael S. Wiggins, Reuben H. Grinstein
  • Patent number: 5854384
    Abstract: A process for preparing poly-.alpha.-amino acid particles comprising polymerizing an .alpha.-amino acid-N-carboxy anhydride using a polymerization initiator in an organic solvent in which both the solubility of the .alpha.-amino acid-N-carboxy anhydride and the solubility of the produced poly-.alpha.-amino acid are 0.1 g/100 ml or less at 25.degree. C. Polyamino acid particles having a high molecular weight and a small bulk specific gravity can be manufactured very easily without requiring specific procedures. The polyamino acid particles can be used as a coating material for papers, resins, rubbers, and fibers; particles for cosmetics; particles for diagnostic drugs; fillers for chromatography; and an encapsulating material for drugs, fertilizers, and perfumes.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: December 29, 1998
    Assignee: SR Corporation
    Inventors: Kyoko Kuroda, Masayuki Hattori, Yoshitaka Yamakawa, Kenya Makino, Toshio Hayashi
  • Patent number: 5854341
    Abstract: An anti-fogging coating composition contains (a) an inorganic alkoxide and/or a hydroxyl group-containing polymer formed therefrom by hydrolysis and polycondensation, the inorganic alkoxide being represented by the formula (I):M(OR).sub.n (X).sub.a-n (I),wherein M is an inorganic element selected from the group consisting of Si, Al, Ti, Zr, Ca, Fe, V, Sn, Li, Be, B and P; R is an alkyl group; X is an alkyl group with or without functional groups or a halogen atom; a is a number representing the valence of M; and n is an integer from 1 to a; (b) a polyalkylene oxide, a weight ratio of the polyalkylene oxide to the inorganic alkoxide and/or the hydroxyl group-containing polymer being 100/1-100/150; (c) 0.5 parts by weight or less of an acid catalyst per 100 parts by weight of (a); (d) 0.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: December 29, 1998
    Assignees: Nakato Laboratory, Inc., Canon Kabushiki Kaisha
    Inventors: Tohru Yamamoto, Shigeo Yoshida, Hatsumi Ikari
  • Patent number: 5837771
    Abstract: For improved flame retardant finishing and better processability of an epoxy anhydride reaction resin system, the present invention provides a reaction resin system supplemented with phosphinic and/or phosphonic acid anhydride as the hardener component. The phosphorus-containing anhydrides do not deteriorate the hardening characteristics. Molded members manufactured therefrom exhibit adequate flame retardant behavior even with slight proportions of phosphinic or phosphonic acid anhydride given a property profile that is otherwise unmodified.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: November 17, 1998
    Assignee: Lemens Aktiengesellschaft
    Inventors: Ernst Wipfelder, Winfried Plundrich
  • Patent number: 5817746
    Abstract: In polymerizing hexafluoropropene oxide (HFPO) into a fluorinated polyether, a liquefied gas of fluorocarbon having 1 to 4 carbon atoms is added to a reactor. HFPO is polymerized in the reactor while maintaining a gas phase in the reactor under a pressure lower than the vapor pressure of the liquefied gas and allowing the liquefied gas to evaporate from the polymerization system. Heat of polymerization can be efficiently removed from the HFPO polymerization system of high viscosity, and the polymerization temperature is kept low.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: October 6, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Noriyuki Koike, Takashi Matsuda, Shinichi Sato, Hirofumi Kishita, Masatoshi Arai
  • Patent number: 5811497
    Abstract: Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.
    Type: Grant
    Filed: September 11, 1995
    Date of Patent: September 22, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Shuzi Hayase, Yoshihiko Nakano, Shinji Murai, Yukihiro Mikogami
  • Patent number: 5798412
    Abstract: A process in which carbon is used to catalyze production of alkylene glycols from alkylene oxides and water. Using this process, carbon may be employed to selectively catalyze the hydrolysis of alkylene oxides, such as ethylene oxide, to monoalkylene gylcols, such as monoethylene glycol. Typically, activated carbon is employed. Suitable forms of activated carbon or other carbon material include powders, granulates, extruded shapes, or mixtures thereof. The process may be carried out as a continuous or batch reaction process.
    Type: Grant
    Filed: July 16, 1997
    Date of Patent: August 25, 1998
    Assignee: Huntsman Petrochemical Corporation
    Inventors: John R. Sanderson, Edward T. Marquis
  • Patent number: 5798396
    Abstract: The present invention is directed to sulfonium salt-containing compounds represented by a following general formula; ##STR1## wherein R.sub.1 is alkyl containing from 1 to 18 carbon atoms, hydroxy, alkoxy containing from 1 to 18 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms or halogen, n is any of 0, 1, 2 or 3, however, each of R.sub.1 may be different from the others when n is 2 or more, R.sub.2 is alkyl containing from 1 to 6 carbon atoms, R.sub.3 and R.sub.4 are each independently hydrogen or alkyl containing from 1 to 6 carbon atoms, R.sub.5 and R.sub.6 are each independently hydrogen, alkyl containing from 1 to 6 carbon atoms, hydroxy, alkoxy containing from 1 to 6 carbon atoms, alkylcarbonyloxy containing from 1 to 18 carbon atoms or aromatic carbonyloxy, and R.sub.7 is alkyl containing from 4 to 20 carbon atoms or a group represented by a following formula; ##STR2## wherein R.sub.
    Type: Grant
    Filed: September 4, 1996
    Date of Patent: August 25, 1998
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Eiji Takahashi, Hiroo Muramoto
  • Patent number: 5786308
    Abstract: A new group of polymer flow controllers for powder resin lacquer is provided. The polymer flow controllers contain groups ##STR1## wherein n and m are numbers from 0 to 1000 with the sum of n+m=2-1000 and R.sub.1 and R.sub.2 are independently hydrogen, an optionally hydroxy substituted hydrocarbon group containing 1 to 36 carbon atoms aryl and aralkyl optionally substituted in the aromatic nucleus, or R.sub.3 --(--O--C.sub.2 H.sub.4 --)--.sub.p O--CH.sub.2 -- wherein R.sub.3 is an alkyl or alkenyl group containing 1 to 18 carbon atoms and p is a number of 1 to 10.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: July 28, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ulrich Eicken, Brigitte Hase, Herbert Fischer, Paul Birnbrich, Heinz-Guenter Schulte, Wolfgang Gress, Harald Frommelius
  • Patent number: 5780555
    Abstract: An amine curing agent composition for an epoxy resin is provided having low volatility and good processability containing a) a polyamine curing agent and b) an aliphatic alcohol-alkylene oxide adduct. An epoxy resin-polyamine curing agent system containing an aliphatic alcohol-alkylene oxide adduct is also provided.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: July 14, 1998
    Assignee: Shell Oil Company
    Inventors: Larry Steven Corley, Kalyan Ghosh, Joseph Michael Hunter, Derek Scott Kincaid, Leo Meilus, Daniel James Weinmann
  • Patent number: 5763636
    Abstract: Polymers containing spiro atoms which can be used as electroluminescence materials, suitable for use in ligerting or display devices, and which improve the property profile of these devices. Specifically, a conjugated polymer comprising structural units of the formula (I), ##STR1## where the symbols and indices have the following meanings: D, E, F.sup.1, G are identical or different, and are --CR.sup.1 R.sup.1 --, --O--, --S--, --NR.sup.3 -- or a chemical bond;Ar.sup.1, Ar.sup.2 are carbocycles or heterocycles;U.sup.1, V.sup.1 are identical or different, and are --CR.sup.5.dbd.CR.sup.6 --, --CR.sup.7 R.sup.8 --, --CR.sup.9 R.sup.10 --CR.sup.11 R.sup.12 --, --NR.sup.13 --, --SiR.sup.14 R.sup.15 --, --O--, --S--, --SO--, --SO.sub.2 --, --CO-- or a chemical bond;Ar.sup.5, Ar.sup.6, X, Y.sup.1 are identical or different, and are cyclic or acyclic, conjugated hydrocarbons and X and/or y.sup.1 can also be H or R.sup.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: June 9, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Willi Kreuder, Hubert Spreitzer
  • Patent number: 5750218
    Abstract: A process for the production of biodegradable aliphatic polyester particles by (co)polymerizing 2-oxetanone or a mixture containing at least 80% by weight of 2-oxetanone and up to 20% by weight of a cyclic ester or cyclic ether other than 2-oxetanone in the presence of a polymerization initiator supported on a carrier in which an ion polymerization initiator is supported on poly(2-oxetanone) in a liquid medium having a solubility parameter of about 15 to about 18 MPa.sup.1/2 and being capable of dissolving 2-oxetanone, and in a polymerizing apparatus having an internal surface formed of a material which is free of polarity or whose polarity is very small, to form a particulate aliphatic polyester; and a biodegradable aliphatic polyester melt-extrusion film, which comprises the biodegradable aliphatic polyester having a weight average molecular weight of 20,000 to 2,000,000, and having a water vapor transmission rate of 300 to 700 g/m.sup.2 .multidot.24 hours.multidot.25 .mu.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: May 12, 1998
    Assignee: Tokuyama Corporation
    Inventors: Haruo Nishida, Mitsuhiro Yamashita, Yoshiki Ochi, Tetsuo Kuwaki
  • Patent number: 5746935
    Abstract: An amine curing agent composition for an epoxy resin is provided having low volatility and good processability containing a) a polyamine curing agent and b) an aliphatic alcohol-alkylene oxide adduct. An epoxy resin-polyamine curing agent system containing an aliphatic alcohol-alkylene oxide adduct is also provided.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: May 5, 1998
    Assignee: Shell Oil Company
    Inventors: Larry Steven Corley, Kalyan Ghosh, Joseph Michael Hunter, Derek Scott Kincaid, Leo Meilus, Daniel James Weinmann
  • Patent number: 5741866
    Abstract: Disclosed is a method for producing an acetal copolymer, which comprises copolymerizing trioxane with a cyclic ether in the presence of a cation-active catalyst, wherein the cyclic ether is obtained by adding to a fresh cyclic ether containing a peroxide derived therefrom in an amount of 15 ppm by weight or less in terms of hydrogen peroxide at least one sterically hindered phenol in an amount of from 10 to 500 ppm by weight, based on the weight of said fresh cyclic ether. By the method of the present invention, it has become possible not only to stably and efficiently produce an acetal copolymer having high thermal stability, but also to stably conduct a post-treatment of the obtained acetal copolymer for deactivating the remaining catalyst and changing the unstable terminals to stable terminals, so that an ultimate acetal copolymer having high thermal stability can be stably obtained.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: April 21, 1998
    Assignee: Asahi Kasei Kogo Kabushiki Kaisha
    Inventors: Shyuzi Yahiro, Minoru Yamamoto
  • Patent number: 5728796
    Abstract: A process reaction between: (1) a compound that contains one or more epoxide moieties per molecule, and (2) a compound that contains one or more primary aliphatic hydroxyl groups per molecule; is catalyzed by: (3) a catalyst compound containing one or more trifluoromethanesulfonate moieties and one or more silyl moieties and run at a temperature of no more than 130.degree. C., such that the catalyst preferably catalyzes reaction at the primary aliphatic hydroxyl group, so that the resulting resin does not gel.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: March 17, 1998
    Assignee: The Dow Chemical Company
    Inventors: Zeng K. Liao, James L. Bertram