Heterocyclic Nitrogen-containing Ring Contains A Single Atom Of Nitrogen And Two Atoms Of Carbon As Ring Members Patents (Class 528/424)
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Publication number: 20010014722Abstract: The present invention provides a novel amino-group-containing polymer (salt) and a production process therefor wherein the amino-group-containing polymer (salt) is a product by a process including the step of introducing amino groups into a grafted polymer having a polyether skeleton, and can make good use of the reactivity or cationic property of at least primary amino groups and further, according to circumstances, secondary amino groups, and further can display various performances, such as curability useful for various uses and adsorbency onto films or fibers.Type: ApplicationFiled: February 8, 2001Publication date: August 16, 2001Applicant: Nippon Shokubai Co., Ltd.Inventors: Ichimoto Akasaki, Masahito Takagi, Takuya Saeki, Koichiro Saeki
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Publication number: 20010014730Abstract: Provided are processes by which an ethylenimine polymer and an aqueous solution thereof can advantageously be produced at low costs in an industrial scale. The ethylenimine polymer can be produced by polymerizing crude ethylenimine obtained by a simple distilling operation from an ethylenimine-containing reaction mixture produced by subjecting ethanolamine to intermolecular dehydration reaction, preferably crude ethylenimine having impurity contents which are controlled in the specific ranges. When the above crude ethylenimine is polymerized in an aqueous medium, capable of being obtained is an aqueous solution of an ethylenimine polymer having a higher molecular weight than that produced by non-solvent polymerization. The ethylenimine polymer can be purified by, for example, adding water thereto, mixing them and then vaporizing and removing water under heating. The aqueous solution of an ethylenimine polymer can be purified by heating and condensing it.Type: ApplicationFiled: January 30, 2001Publication date: August 16, 2001Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Seiichi Suzuki, Yoshiyuki Onda, Isao Satoh
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Patent number: 6235220Abstract: The invention concerns compositions for manufacturing composite materials containing a polyaniline. These compositions are formed by a solution in a solvent such as m-cresol of the following constituents: a) a conductive polyaniline protonated by means of a protonation agent able to promote the dissolution of the polyaniline in the solvent, for example phenylphosphonic acid, b) an insulating polymer chosen for example from amongst the cellulosic polymers and polyvinyl chlorides such as cellulose acetate, and c) an insulating plasticiser such as a mixture of dimethyl phthalate, diethyl phthalate and triphenyl phosphate. By pouring this solution and evaporating the solvent, it is possible to obtain a flexible film of conductive composite material having good electrical and mechanical properties.Type: GrantFiled: January 29, 1999Date of Patent: May 22, 2001Assignee: Commissariat a l'Energie AtomiqueInventors: Adam Pron, Yann-Florent Nicolau, Maxime Nechtschein, Françoise Genoud
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Patent number: 6218503Abstract: Prepolymers of Formula (I) are useful in hydrogel materials wherein M is a hydrophilic radical derived from at least one hydrophilic ethylenically unsaturated monomer and having a molecular weight of about 500 to 5000; each R is independently selected from an alkylene group having 1 to 10 carbon atoms wherein the carbon atoms may include ether, urethane or ureido linkages therebetween; each R′ is independently selected from hydrogen, monovalent hydrocarbon radicals or halogen substituted monovalent hydrocarbon radicals wherein the hydrocarbon radicals have 1 to 18 carbon atoms which may include ether linkages therebetween; a is an integer equal to or greater than 1; each U is independently a divalent urethane or ureido segment; x is greater than or equal to 1, y is greater than or equal to 1; and z is greater than or equal to 1; and each E is independently a polymerizable, ethylenically unsaturated radical.Type: GrantFiled: February 25, 2000Date of Patent: April 17, 2001Assignee: Bausch & Lomb IncorporatedInventors: Yu-Chin Lai, Edmond T. Quinn
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Patent number: 6197923Abstract: N-Oxides of nitrogenous heterocycle or nitrogenous fused heterocycle polymers of general formula (1) or (7) (wherein any two of a, b, c, d, e, f, g and h are carbon atoms participating in the bonding between repeating units; at least one of them is N→O; the rest are each CH, N or N→O; and the degree of polymerization “n” is at least 5). These polymers have excellent heat resistance, are soluble in aqueous or organic solvents and controllable in the degree of depolarization and electrochemical redox potential, exhibit clear color changes by chemical or electrochemical oxidation or reduction, and are conductive per se . They can be used as moldings such as fibers and films; electrochromic elements; active materials and electrodes of cells; semiconductors including n-type semiconductors; and so on.Type: GrantFiled: April 20, 1998Date of Patent: March 6, 2001Assignee: Nissan Chemical Industries, Ltd.Inventor: Takakazu Yamamoto
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Patent number: 6166105Abstract: A process for making an ink jet ink comprising:a) providing a dispersion containing a pigment, a hydrocarbon carrier and a polyamine/fatty acid condensation polymer dispersant;b) mixing the pigment dispersion with rigid milling media less than 100 .mu.m;c) introducing the mixture of step (b) into a mill;d) milling the mixture from step (c) until the pigment particle size is below about 100 nanometers;e) separating the milling media from the mixture milled in step (d); andf) diluting the mixture from step (e) to obtain an ink jet ink having a pigment concentration suitable for ink jet printers.Type: GrantFiled: October 13, 1998Date of Patent: December 26, 2000Assignee: Eastman Kodak CompanyInventors: Domenic Santilli, Charles E. Romano, Jr., David Erdtmann
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Patent number: 6162876Abstract: Curable compositions used in circuit boards, structural composite, encapsulating resins, and the like, comprise at least one of a cyanate ester and a cyanate ester prepolymer, a cyanate ester-free aryloxytriazine, and a curing catalyst.Type: GrantFiled: June 11, 1998Date of Patent: December 19, 2000Assignee: General Electric CompanyInventors: Gary William Yeager, Yiqun Pan
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Patent number: 6150460Abstract: Novel polyfunctional glyoxylated compounds and compositions containing the same are disclosed which are particularly suitable for use as crosslinking components in curable compositions and also find use in imparting wet adhesion properties to water-based paints and coatings. A process for preparing novel polyfunctional glyoxylated compounds is also disclosed.Type: GrantFiled: November 3, 1999Date of Patent: November 21, 2000Assignee: Cytec Technology Corp.Inventors: Balwant Singh, Laurence Wu-Kwang Chang
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Patent number: 6147225Abstract: Thiacrown ether and polymeric thiacrown ether compounds are disclosed. The thiacrown ether ring structures are substituted and have from 4 to about 10 sulfur atoms on each of the crown rings. The polymeric thiacrown ether ring structures are substituted with polymers and have from 4 to about 10 sulfur atoms on each of the crown rings. The thiacrown compounds of the present invention are expected to have utility in a wide range of applications including but not limited to utility as metal ion chelating, sequestering, and complexing agents. The thiacrown compounds are also expected to have utility as corrosion inhibitors for cooling tower, boiler, and waste water systems, hydrocarbon process systems and metal surface treatments systems.Type: GrantFiled: June 2, 1998Date of Patent: November 14, 2000Assignee: Betzdearborn Inc.Inventors: Janet A. Gaboury, Fu Chen
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Patent number: 6140276Abstract: A method of reducing the deposition of wax from a crude oil containing wax which comprises adding thereto at least one N-substituted polyalkylene imine which has at least one organic substituent that is a hydroxy-substituted alkyl group of 12-24 carbon atoms.Type: GrantFiled: June 4, 1998Date of Patent: October 31, 2000Assignee: BP Exploration Operating Company LimitedInventors: Simon Neil Duncum, Keith James, Christopher George Osborne
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Patent number: 6059999Abstract: The invention provides conductive compositions of matter, as well as methods for the preparation of the conductive compositions of matter, solutions comprising the conductive compositions of matter, and methods of preparing fibers or fabrics having improved anti-static properties employing the conductive compositions of matter.Type: GrantFiled: August 6, 1999Date of Patent: May 9, 2000Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Tito Viswanathan
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Patent number: 5977293Abstract: A process for the continuous preparation of homopolymers of ethyleneimine by polymerization of ethyleneimine in a solvent in the presence of catalysts at temperatures of at least 80.degree. C., in homogeneous liquid phase in a tubular reactor in which the ratio of length to internal diameter is at least 5:1. There are obtained polyethyleneimines having a content of secondary nitrogen atoms of more than 40 to 60% and molecular weight distribution M.sub.w /M.sub.n of from 1.5:1 to 3:1.Type: GrantFiled: June 8, 1998Date of Patent: November 2, 1999Assignee: BASF AktiengesellschaftInventors: Ulrich Steuerle, Wolfgang Reuther, Wolfgang Harder
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Patent number: 5948186Abstract: A tire includes polybenzazole (PBZ) fibers, preferably either polybenzoxazole (PBO) or polybenzothiazole (PBT) fibers which are liquid-crystalline. The PBZ fibers can be incorporated into either the carcass of the tire, the reinforcing belts, or both. Preferably the PBZ fibers have a) a tensile strength of at least 4.0 GPa; b) a tensile modulus of at least 140 GPa; and c) an average void diameter of 25 .ANG. or less.Type: GrantFiled: July 10, 1995Date of Patent: September 7, 1999Assignee: Toyobo Co., Ltd.Inventor: Kazuyuki Yabuki
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Patent number: 5830948Abstract: Polyoxazolines having the structural formula: ##STR1## wherein R is phenylene or alkylene containing 2 to 18 carbon atoms, R.sup.2 is C.sub.1-4 alkyl and R.sub.1 is selected from the group consisting of C.sub.1-12 alkyl, vinyl, isopropylidene, pentafluoroethyl, phenyl, hydroxyphenyl which is optionally interrupted by up to 20 ethylene oxide groups, C.sub.1-2 -alkoxyphenyl which is optionally interrupted by up to 20 ethylene oxide groups and .paren open-st.CH.sub.2 CH.sub.2 --O.paren close-st..sub.r CH.sub.3 in which r ranges from 1-20, X is NH.sub.2 or OH, n ranges from 2 to 50 and m ranges from 0 to 50, wherein R.sub.1 is hydroxyphenyl optionally interrupted by up to 20 ethylene oxide groups only when X is NH.sub.2, are polymerizable to form hyperbranched polymers which have a number average molecular weight ranging from 5,000 to 150,000, a weight average molecular weight ranging from 5,500 to 5,000,000 and a polydispersity ranging from 1.Type: GrantFiled: February 28, 1997Date of Patent: November 3, 1998Assignee: Cornell Research Foundation, Inc.Inventors: Jean J.M. Frechet, Koji Yui
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Patent number: 5756601Abstract: A process for preparing an N-substituted polyaniline comprising the steps of reacting an alkali hydride and a polyaniline having imine bonds, mixing the reaction mixture with an alkyl or alkoxyalkyl halide to generate a polymer, precipitating the generated polymer, and undoping the polymer. The N-substituted polyaniline can be dissolved in organic solvents having low boiling points and can be doped to provide films with a conductivity of 10.sup.-6 to 10.sup.-2 s/cm.Type: GrantFiled: January 28, 1997Date of Patent: May 26, 1998Assignee: National Science CouncilInventors: Show An Chen, Gue Wuu Hwang, Jyh Shyong Lin, Kuan Ying Wu
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Patent number: 5688873Abstract: Electroconductive polymers having a chemical structure represented by, for example, the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 independently represent H, a C.sub.1 to C.sub.20 alkyl or alkoxy group, an amino group, a trihalomethyl group or a phenyl group, X represents S, O, Se, Te or NR.sub.3 R.sub.3 represents H, a C.sub.1 to C.sub.6 alkyl group or an aryl group, M represents a cation such as H.sup.+, an alkali metal ion or a quaternary ammonium ion, and m is 0.2 to 2 and a process for producing the polymer.Type: GrantFiled: June 7, 1995Date of Patent: November 18, 1997Assignee: Showa Denko K.K.Inventors: Yoshihiro Saida, Yoshiaki Ikenoue, Reiko Ichikawa
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Patent number: 5648453Abstract: Electroconductive polymers having a chemical structure represented by, for example, the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 independently represent H, a C.sub.1 to C.sub.20 alkyl or alkoxy group, an amino group, a trihalomethyl group or a phenyl group, X represents S, O, Se, Te or NR.sub.3 R.sub.3 represents H, a C.sub.1 to C.sub.6 alkyl group or an aryl group, M represents a cation such as M.sup.+, an alkali metal ion or a quaternary ammonium ion, and m is 0.2 to 2 and a process for producing the polymer.Type: GrantFiled: June 7, 1995Date of Patent: July 15, 1997Assignee: Showa Denko K.K.Inventors: Yoshihiro Saida, Yoshiaki Ikenoue, Reiko Ichikawa
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Patent number: 5637675Abstract: Crystalline compounds with ferromagnetic properties are described which are inclusion compounds comprising metal salts in copolymers in which the repeating unit includes one unit from a first group of aminoaromatic derivatives of 1-naphthylamine and corresponding oxidized forms, connected to one unit from a second group of substituted aminoaromatic compounds selected from substituted amines containing at least two condensed benzene nuclei, substituted polycyclic compounds containing at least one aniline moiety in their structure, and aniline derivatives carrying a substituent connected to the nucleus by an ethynylene or para-phenylene unit, and corresponding oxidized compounds. Methods for the preparation of these compounds are also described.Type: GrantFiled: May 2, 1995Date of Patent: June 10, 1997Assignee: Alcatel Alsthom Compagnie Generale d'ElectriciteInventors: Alain Le Mehaute, Stanislas Galaj, Denis Cottevieille, Fran.cedilla.ois Tsobnang, Fran.cedilla.ois Lefort
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Patent number: 5635571Abstract: Polyoxazolines having the structural formula: ##STR1## wherein R is phenylene or alkylene containing 2 to 18 carbon atoms, R.sup.2 is C.sub.1-4 alkyl and R.sub.1 is selected from the group consisting of C.sub.1-12 alkyl, vinyl, isopropylidene, pentafluoroethyl, phenyl, hydroxyphenyl which is optionally interrupted by up to 20 ethylene oxide groups, C.sub.1-2 -alkoxyphenyl which is optionally interrupted by up to 20 ethylene oxide groups and .paren open-st.CH.sub.2 CH.sub.2 --O.paren close-st..sub.r CH.sub.3 in which r ranges from 1-20, X is NH.sub.2 or OH, n ranges from 2 to 50 and m ranges from 0 to 50, wherein R.sub.1 is hydroxyphenyl optionally interrupted by up to 20 ethylene oxide groups only when X is NH.sub.2, are polymerizable to form hyperbranched polymers which have a number average molecular weight ranging from 5,000 to 150,000, a weight average molecular weight ranging from 5,500 to 5,000,000 and a polydispersity ranging from 1.Type: GrantFiled: June 5, 1996Date of Patent: June 3, 1997Assignee: Cornell Research Foundation, Inc.Inventors: Jean M. J. Frechet, Koji Yui
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Patent number: 5616637Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub.36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.Type: GrantFiled: March 13, 1996Date of Patent: April 1, 1997Assignee: Ciba-Geigy CorporationInventor: Alfred Steinmann
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Patent number: 5521282Abstract: The invention relates to polyethers of the formula I ##STR1## in which m is 0 or 1; n is an integer in the range from 3 to 100; R.sup.1, in the case where m is 0 or 1, is C.sub.1 -C.sub.36 alkyl or C.sub.7 -C.sub.36 aralkyl, each of which is unsubstituted or substituted by C.sub.5 -C.sub.8 cycloalkyl, is interrupted in the aliphatic part by C.sub.5 -C.sub.8 cycloalkylene or by oxygen or sulfur or --NR.sup.11 -- or is substituted in the aromatic part by 1 to 3 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.3 -C.sub.36 alkenyl; C.sub.5 -C.sub.12 cycloalkyl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy radicals; C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub. alkoxy radicals; and R.sup.1, in the case where m is 0, can alternatively be hydrogen; C.sub.1 -C.sub.36 alkoxy or C.sub.7 -C.sub. 36 aralkoxy, each of which is unsubstituted or substituted by C.sub.5 -C.sub.Type: GrantFiled: July 7, 1994Date of Patent: May 28, 1996Assignee: Ciba-Geigy CorporationInventor: Alfred Steinmann
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Patent number: 5498409Abstract: An insoluble material for adsorbing a pyrogen comprising a polymer of an aziridine compound. According to the present invention, a large amount of the pyrogen can be easily removed from a solution containing pyrogen, and a large amount of the material for adsorbing the pyrogen can be prepared in easy steps. Therefore, the adsorbing material can greatly contribute to the preparation of medicines.Type: GrantFiled: February 10, 1993Date of Patent: March 12, 1996Assignees: Chuichi Hirayama, Kohjin Co., Ltd.Inventors: Chuichi Hirayama, Keijun Hiraoka, Sunao Morimoto
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Patent number: 5426134Abstract: A dental material which is curable in a first stage to an elastic phase in which the material can be worked mechanically or surpluses removed, and in a second stage to its final form, comprising:(a) at least one polyfunctional epimine (aziridine);(b) at least one ethylenically unsaturated monomer;(c) at least one catalyst for the hot, cold, or light polymerization of the ethylenically unsaturated monomer; and(d) at least one catalyst to accelerate the polymerization of epimine (a), but which does not however influence the polymerization of (b).Type: GrantFiled: June 25, 1993Date of Patent: June 20, 1995Assignee: Ivoclar AGInventors: Volker Rheinberger, Ulrich Salz, Peter Burtscher
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Patent number: 5422423Abstract: This invention relates to thermally stable electrically conductive conjugated polymer complexes comprising a substituted or unsubstituted positively charged conjugated polymer doped with a dopant anion substituted with one or more anionic functionalities as for example a sulfonate or phosphonate functionalities, and substituted with one or more hydrogen bonding groups such as hydroxyl or carboxyl.Type: GrantFiled: June 3, 1992Date of Patent: June 6, 1995Assignee: AlliedSignal Inc.Inventors: Lawrence W. Shacklette, Chien-Chung Han, Ronald L. Elsenbaumer
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Patent number: 5412054Abstract: A catalyst: mixture for ring-opening polymerization of heterocyclic monomers and polymers includes a catalyst composed of a cobalt carbonyl complex; and a cocatalyst composed of at least one Si-H-containing compound. A curable composition, which may be a two-part kit, is also disclosed and includes the catalyst; the cocatalyst; and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring. A method of producing a polymeric product by ring-opening polymerization of heterocyclic monomers and polymers is also disclosed which includes the steps of preparing a mixture including a catalyst composed of a cobalt carbonyl complex, a cocatalyst composed of at least one Si-H-containing compound, and at least one polymerizable compound which is a monomer or polymer containing a heterocyclic ring; and reacting the mixture, preferably at about room temperature, to promote ring-opening polymerization of the at least one polymerizable compound to produce the polymeric product.Type: GrantFiled: November 30, 1993Date of Patent: May 2, 1995Assignee: General Electric CompanyInventors: James V. Crivello, Ming-Xin Fan
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Patent number: 5370825Abstract: Disclosed is a novel composition of matter comprising a polyacid and a polymer containing repeating units which contain one or more basic atoms. The complex is water-soluble and electrically conductive. The complex is useful in providing organic discharge layers for use in electronic applications and fabrications.Type: GrantFiled: March 3, 1993Date of Patent: December 6, 1994Assignee: International Business Machines CorporationInventors: Marie Angelopoulos, Jeffrey D. Gelorme, Thomas H. Newman, Niranjan M. Patel, David E. Seeger
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Patent number: 5367051Abstract: Fullerene-functionalized amine-containing polymers and polymerizable monomers are disclosed characterized by high temperature stability, i.e., capable of withstanding a temperature of at least about 300.degree. C., and in some instances as high as 650.degree. C., when in polymerized form. The fullerene groups are bonded to the polymers through the amine groups on the polymer. In some instances enhanced mechanical properties also result and, in the case of cross-linked polymers, a composite can be formed from such materials which is structurally reinforced at the molecular level, with the fullerene groups acting as the molecular level structural reinforcement.Type: GrantFiled: July 22, 1993Date of Patent: November 22, 1994Assignee: SRI InternationalInventors: Subhash C. Narang, Susanna C. Ventura, Sivapackia Ganapathiappan, Tilak R. Bhardwaj, Asutosh Nigam
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Patent number: 5357039Abstract: Poly-N-acylalkyleneimines corresponding to the following formula ##STR1## are used as an oxidatively crosslinking constituent in paints. In formula (I), R--CO represents the acyl radical of a mono- or polyunsaturated, aliphatic C.sub.16-22 carboxylic acid or a mixture of such radicals, R'--CO represents the acyl radical of a C.sub.1-22 carboxylic acid or a mixture of such radicals and x and y represent the percentages by weight of the particular polymer units, x assuming values of 20 to 100% and preferably 20 to 95% and y assuming values of 80 to 0% and preferably 80 to 5%. The indices m and n independently of one another may assume the value 2 or 3.Type: GrantFiled: April 26, 1993Date of Patent: October 18, 1994Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Brigitte Hase, Ulrich Eicken, Herbert Fischer, Horst-Juergen Krause, Wolfgang Gress, Norbert Stork
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Patent number: 5346649Abstract: An electrically conducting plastic material is produced by blending a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof. A reaction product or blend of a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof can be brought to an easy-to-handle or directly melt-processable form through a heat-treatment process carried out at approx. +40.degree. to +250.degree. C. The obtained plastic material is advantageously further improved by blending the heat-treated reaction product or blend with a thermoplastic polymer and then melt-processing the mixed blend. The properties of the resulting compound material exhibit complete compatibility of the heat-treated reaction product or blend with the thermoplastic polymer.Type: GrantFiled: December 4, 1992Date of Patent: September 13, 1994Assignee: Neste OyInventors: Toivo Karna, Jukka Laakso, Kalle Levon, Esko Savolainen
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Patent number: 5340913Abstract: 2,4-Polybenzoxazoles are synthesized from a biosynthetically prepared AB monomer. The biosynthetically produced precursor, 2,3-dihydro-3-hydroxyanthranilic acid (DHAA), is chemically transformed to the AB monomer, 3-hydroxyanthranilic acid (HAA). This AB monomer is used to prepare said polybenzoxazoles.Type: GrantFiled: March 19, 1993Date of Patent: August 23, 1994Assignee: General Electric CompanyInventor: Thomas J. Meade
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Patent number: 5300287Abstract: Novel polymeric antimicrobials having spacer moieties between amine and/or ammonium moieties have good antifungal activity. These compounds are useful in pharmaceutical and cosmetic compositions as preservatives and in contact lens care compositions as preservatives and/or disinfectants.Type: GrantFiled: November 4, 1992Date of Patent: April 5, 1994Assignee: Alcon Laboratories, Inc.Inventor: Joonsup Park
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Patent number: 5280084Abstract: Polymer material is surface modified with the intention of increasing the hydrophilicity of the polymer surface, by producing carboxyl groups, carbonyl groups and hydroxyl groups on the polymer surface in a first stage, by oxidizing with, e.g., oxidizing acid solutions or in some other manner, and by reacting the groups on the polymer surface in a second step with heterocyclic compounds having three or four ring atoms or with isocyanate compounds or carbodiimide compounds.Type: GrantFiled: June 10, 1993Date of Patent: January 18, 1994Assignee: PP Polymer ABInventor: Swaraj Paul
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Patent number: 5233020Abstract: Poly-N-acylalkyleneimines corresponding to the following formula ##STR1## are used as an oxidatively crosslinking constituent in paints. In formula (I), R--CO represents the acyl radical of a mono- or polyunsaturated, aliphatic C.sub.16-22 carboxylic acid or a mixture of such radicals, R'--CO represents the acyl radical of a C.sub.1-22 carboxylic acid or a mixture of such radicals and x and y represent the percentages by weight of the particular polymer units, x assuming values of 20 to 100% and preferably 20 to 95% and y assuming values of 80 to 0% and preferably 80 to 5%. The indices m and n independently of one another may assume the value 2 or 3.Type: GrantFiled: July 12, 1991Date of Patent: August 3, 1993Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Brigitte Hase, Ulrich Eicken, Herbert Fischer, Horst-Jurgen Krause, Wolfgang Gress, Norbert Stork
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Patent number: 5232631Abstract: Solutions and plasticized compositions of electrically conductive substituted and unsubstituted polyanilines in nonpolar organic fluid phases with functionalized protonic acids are disclosed as are methods of forming such solutions or compositions and use of same to form conductive articles.Type: GrantFiled: June 12, 1991Date of Patent: August 3, 1993Assignee: Uniax CorporationInventors: Yong Cao, Paul Smith, Alan J. Heeger
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Patent number: 5175217Abstract: The invention relates to a method for the photochemical conversion of tachysterol compounds into previtamin D compounds and of trans-vitamin D compounds into cis-vitamin D compounds under the influence of radiation, by exposing the tachysterol compound and trans-vitamin D compound, respectively, dissolved in a suitable solvent system, in the presence of a polymeric photosensitizer consisting of a polymer chain ("backbone") comprising covalently bound sensitizers suitable for the photochemical conversion, to light with a wavelength of preferably between approx. 300 and approx.Type: GrantFiled: August 23, 1990Date of Patent: December 29, 1992Assignee: Duphar International Research B.V.Inventors: Eric Goethals, Sebastianus J. Halkes, Robert B. Koolstra
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Patent number: 5164477Abstract: A polyfunctional polymerization initiator suitable to cationic ring-opening polymerization of heterocyclic monomers, having at least one carbon atom bonded directly to a carbon-carbon double bond in a linear or cyclic organic group and, further, having at least two following groups containing the above said carbon atoms and represented by the general formula:--CH.sub.2 Xwhere X represents an electron attracting group such as I, Br, Cl, F, --OSO.sub.2 R, --SOR, --OCOR, --OPO(OR).sub.2 and --OP(OR)R and R is optionally selected from (substituted) alkyl groups or (substituted) aryl groups.Various types of telechelic polymer, block copolymer, comb-like polymer and star-like polymer having controlled molecular weight and narrow molecular weight distribution can be produced efficiently from the heterocyclic monomer as the starting material.Type: GrantFiled: August 2, 1991Date of Patent: November 17, 1992Assignee: Shiro KobayashiInventors: Shiro Kobayashi, Hiroshi Uyama
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Patent number: 5152918Abstract: An improved liquid crystal-aligning coating composed mainly of a specified high molecule, mainly a polyether polyimide or a polyimide, and capable of controlling the alignment and pretilt angle of liquid crystals; a liquid crystal display element using the coating; and a dinitro compound and a diol compound each as an intermediate of a diamino compound constituting the polyimide ether, are provided, which specified high molecule contains in its molecular long chain, a substituted cyclohexylidene group or a cyclohexylidene group expressed by the formula ##STR1## wherein R.sub.1 to R.sub.6 of the cyclohexyl group each represent H, 1-15C alkyl group, a cyclohexyl group or a cyclohexyl group having 1-15C alkyl group, and may be each the same or partly or totally different.Type: GrantFiled: February 2, 1990Date of Patent: October 6, 1992Assignee: Chisso CorporationInventors: Shizuo Murata, Minoru Nakayama, Kenji Furukawa, Ryuji Kobayashi
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Patent number: 5132377Abstract: Quaternary ammonium salts of a non-nucleophilic anion having an .alpha.-substituted benzyl group attached to the quatenary nitrogen atom or having a heterocycle including the quaternary nitrogen atom are useful as a cation polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.Type: GrantFiled: June 4, 1990Date of Patent: July 21, 1992Assignee: Nippon Paint Company, LimitedInventors: Shinji Nakano, Satoshi Urano
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Patent number: 5130348Abstract: There is disclosed a polyether impression material containing(a) a polyether,(b) a catalyst, and(c) a mixing additive,in which the components (a) and (b) are spatially separate from each other, and in which the mixing additive (c) is polyalkylene oxide derivative with a molecular weight above 300, which is chemically inert with the other components present and in particular, does not contain hydroxyl groups, acid groups, primary amino groups, ionic groups, halogen groups or groups capable of polymerization. The composition can be mixed easily, has outstanding storage stability and does not dissociate even under increased pressure.Type: GrantFiled: September 11, 1990Date of Patent: July 14, 1992Assignee: THERA Patent GmbH & Co., KGInventors: Wolf-Dietrich Zahler, Oswald Gasser, Klaus Ellrich
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Patent number: 5039787Abstract: Methods are disclosed for the production of (I) a cationic water-soluble resin by the reaction of a polyethylene glycol polyhalohydrin ether resulting from the reaction between polyethylene glycol and an epihalohydrin with an aziridine compound and (II) and (III) cationic water-soluble resins by the reaction of (I) the resin with an epihalohydrin and/or a polyfunctional epoxy compound in the presence or absence of a polyalkyleneimine. The resins (I), (II), and (III) are stable over a wide range of pH value and are useful as a water-treating agent.Type: GrantFiled: February 21, 1989Date of Patent: August 13, 1991Assignee: Nippon Shokubai Kagaku Kogyo, Co., Ltd.Inventors: Yasumasa Tanaka, Shigehiro Nishimura, Masatoshi Kurahashi, Yugi Sugiura, Yoshinori Sano
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Patent number: 4631337Abstract: Dense star polyamines having terminal group densities greater than extended conventional star polyamines exhibit greater and more uniform reactivity than their corresponding extended conventional star polyamines. For example, a second generation, amine-terminated polyamine dense star polyamine prepared from tri(2-aminoethyl)amine and aziridine has 4.7.times.10.sup.-3 amine moieties per unit volume (cubic Angstrom units) in contrast to the 1.7.times.10.sup.-3 amine moieties per unit volume contained by an extended conventional star polyamine. Such dense star polyamines are useful as calibration standards, high efficiency proton scavengers and in making size selective membranes.Type: GrantFiled: July 15, 1985Date of Patent: December 23, 1986Assignee: The Dow Chemical CompanyInventors: Donald A. Tomalia, James R. Dewald
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Patent number: 4599389Abstract: Photographic elements and diffusion transfer assemblages described which contain a novel mordant comprising a polymeric backbone having appended thereto nitrogen-coordinating ligands having the formula: ##STR1## wherein D.sup.1, D.sup.2, and D.sup.3 each independently represents the atoms necessary to complete an aromatic heterocyclic nucleus having at least one ring of 5 to 7 atoms.In a preferred embodiment, the mordant comprises recurring units having the formula: ##STR2## wherein: R.sup.1 and R.sup.2 each independently represents hydrogen or an alkyl or substituted alkyl group having from 1 to about 6 carbon atoms;Link represents a bivalent linking group; andLIG represents a nitrogen-coordinating ligand as described above.Type: GrantFiled: October 24, 1985Date of Patent: July 8, 1986Assignee: Eastman Kodak CompanyInventors: James A. Reczek, Ignazio S. Ponticello, Philip S. Bryan
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Patent number: 4532268Abstract: Imidazoles in dissolved form act as an agent for retarding the gelation of the polymerization of aziridine compounds initiated with sulfonium salts. The composition is particularly useful in dentistry applications, such as in the preparation of impressions and provisional denture parts.Type: GrantFiled: December 1, 1983Date of Patent: July 30, 1985Assignee: ESPE, Fabrik pharmazeutischer Praparate GmbHInventors: Peter Jochum, Heijo Hubner, Oswald Gasser
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Patent number: 4492788Abstract: Ultra-high molecular weight poly(N-propionylethylenimines) are disclosed that are useful as water purification agents. The polymers of this invention include partially deacylated poly(N-propionylethylenimines) derived from poly(N-propionylethylenimines) having a weight average molecular weight, M.sub.w, between about 1 million and about 20 million. The polymers have a degree of deacylation that ranges from about 10% to about 90%.Type: GrantFiled: January 3, 1983Date of Patent: January 8, 1985Assignee: Allied CorporationInventor: Robert S. Cooke
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Patent number: 4478938Abstract: Polyalkylenepolyamines are crosslinked in a non-anhydrous environment to yield water-swellable, essentially water-insoluble gels. The polyalkylenepolyamine is contacted with a polyisocyanate at a pH between about 5 and about 8 and subjected to a high rate of agitation. The process of this invention can be employed to immobilize proteins, enzymes, antibodies, etc.Type: GrantFiled: March 2, 1984Date of Patent: October 23, 1984Assignee: The Dow Chemical CompanyInventor: Harold H. Freedman
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Patent number: 4382130Abstract: Certain aryloxyphosphonium salts have been found to be effective as curing agents for various cationically polymerizable organic materials, such as epoxy resins, when incorporated into such materials. The materials are found to be moisture curable coating compositions.Type: GrantFiled: October 14, 1981Date of Patent: May 3, 1983Assignee: General Electric CompanyInventors: Robert H. Ellison, Martin A. Byrne
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Patent number: 4375357Abstract: A family of polymeric black colorants is disclosed. The subject colorants are composed of an organic polymer backbone comprised of a plurality of aromatic rings from which depend via azo groups a plurality of chromophore units having the structure ##STR1## wherein M is hydrogen or preferably a cation. These polymeric colorants are water-soluble, and noncrystalline and form dyes and inks that are fast to paper stock.Type: GrantFiled: June 9, 1981Date of Patent: March 1, 1983Assignee: DynapolInventors: Robert E. Wingard, Jr., Steve Y. W. Ng, Sally A. Swanson
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Patent number: 4228259Abstract: A dye for keratinic material comprises a water-soluble cationic polymer having a molecular weight ranging between about 800 and 10,000 and having secondary, tertiary or quaternary ammonium amine groups wherein said amine groups are either a part of, or aid in the direct or indirect linking to the polymer chain, an aryl or arylaliphatic chromophore or chromogen group carrying compound, with the proviso that when the main chain of the polymer has amine groups derived from the said chromophore or chromogen group carrying compound, the said main chain must also have at least 10 percent aliphatic amine groups relative to the total number of amine groups of the said chain.Type: GrantFiled: August 8, 1977Date of Patent: October 14, 1980Assignee: L'OrealInventors: Gregoire Kalopissis, Alexandre Zysmann, Henri Sebag, Guy Vanlerberghe, Jean-Louis Huron, Andree Bugaut
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Patent number: 4224421Abstract: Water-soluble, crosslinked nitrogen-containing condensation products, the viscosity of which, in aqueous solution, increases with increasing temperature, are obtained by reacting a block copolymer of the formula: ##STR1## x is from 50 to 250, y is from 20 to 100, the ratio of x to y is from 6.5:1 to 1:15, with compounds having at least four basic NH groups in a weight ratio of from 0.8:1 to 30:1. The products are added to aqueous systems, e.g. polymer solutions and polymer dispersions, to improve the viscosity characteristics.Type: GrantFiled: July 3, 1978Date of Patent: September 23, 1980Assignee: BASF AktiengesellschaftInventors: Werner Streit, Rolf Fikentscher, Karl Gans, Gerhard Welzel, Klaus Glaser, Emil Schaefer
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Patent number: 4224429Abstract: A process for the anionic polymerization or copolymerization of olefinic monomers, dienic monomers, vinyl monomers and heterocyclic monomers is described which comprises reacting at least one monomer which is an olefinic monomer, a vinyl monomer or an heterocyclic monomer with a catalyst capable of inducing anionic polymerization and an aprotic macroheterocyclic cryptant, said at least one monomer being the only medium for the reaction.The macroheterocyclic complexing agent has general formula ##STR1## in which: R.sub.1 is hydrogen, a hydrocarbon radical or alkoxycarbonyl, or the two R.sub.1 together can form a group of the general formula: ##STR2## in which A is a hydrocarbon radical,D is oxygen, sulfur, or a hydrocarbon radical, with the proviso that at leat two of the D groups are oxygen or sulfur and that if R.sub.1 is hydrogen, a hydrocarbon radical or alkoxycarbonyl, one of these two D groups is oxygen or sulfur and the other is oxygen, andn and p are integers from 1 to 3 and m is 2 or 3.Type: GrantFiled: August 11, 1977Date of Patent: September 23, 1980Assignee: Societe Nationale des Poudres et ExplosifsInventors: Jean-Marie Lehn, Francois Schue, Sylvie Boileau, Alain A. Cau, Bernd Kaempf, Jean R. Moinard, Serge F. Raynal