From N=c=x Reactant Having At Least Two -c-nh-c(=x)- Groups Patents (Class 528/59)
  • Patent number: 8207286
    Abstract: The present invention provides methods for preparing polyurethanes from reaction components including: (a) reacting about 1 equivalent of at least one polyisocyanate; and about 0.1 to about 0.5 equivalents of at least one polyol having 2 to 18 carbon atoms to form an isocyanate functional urethane prepolymer; and (b) reacting the isocyanate functional urethane prepolymer, about 0.05 to about 1.0 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and up to about 0.9 equivalents of at least one polyol different from the branched polyol and having 2 to 18 carbon atoms, wherein the reaction components are essentially free of polyester polyol and polyether polyol, as well as methods for preparing polyurethanes using a one pot process.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: June 26, 2012
    Assignee: PPG Industries Ohio, Inc
    Inventors: Thomas G. Rukavina, Robert M. Hunia, Caroline S. Harris, Yan Wang, Veronica L. Frain
  • Publication number: 20120156506
    Abstract: There is provided an adhesive composition comprising (a) a polyisocyanate component comprising (i) monomeric 4,4? methylene diphenyl diisocyanate and (ii) an isocyanate functional prepolymer that is the reaction product of a prepolymer reactant mixture comprising (A) monomeric 4,4? methylene diphenyl diisocyanate, and (B) one or more diol having OH equivalent weight of 225 or less, and (C) one or more triol having OH equivalent weight of 1400 or more, and (b) a polyol component comprising one or more polyol.
    Type: Application
    Filed: November 18, 2011
    Publication date: June 21, 2012
    Inventors: Pankaj Vinubhai Shah, Kevin Miyake
  • Patent number: 8202618
    Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups.
    Type: Grant
    Filed: January 4, 2010
    Date of Patent: June 19, 2012
    Assignee: Bayer MaterialScience AG
    Inventors: Jan Weikard, Christoph Gurtler, Wolfgang Fischer, Jorg Schmitt, Holger Mundstock
  • Patent number: 8188208
    Abstract: This invention relates to solid elastomers which exhibit reduced dimensional shrinkage, and to a process for the production of these elastomers. These elastomers comprise the reaction product of a polyisocyanate component or prepolymer, with an isocyanate-reactive component comprising a high molecular weight component having an EO cap having less than 17% by wt., a chain extender and optionally, a crosslinker, in the presence of at least one catalysts. These solid elastomers are produced via the reaction injection molding process in a closed mold, preferably at an isocyanate index of about 70 to about 130.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: May 29, 2012
    Assignee: Bayer MaterialScience LLC
    Inventors: Stephen J. Harasin, William D. Keller, Jr.
  • Patent number: 8182647
    Abstract: A moisture-curable and biodegradable adhesive that includes the reaction product of: (a) an isocyanate component having an average functionality of at least 2; (b) an active hydrogen component having an average functionality greater than 2.1; and (c) an ionic salt component having an average hydroxyl or amino functionality, or combination thereof, of at least 1.
    Type: Grant
    Filed: May 20, 2008
    Date of Patent: May 22, 2012
    Assignee: Cohera Medical, Inc.
    Inventors: Jason Smith, Eric Beckman
  • Patent number: 8178167
    Abstract: The invention relates to humidity hardening compounds containing at least one polyurethane polymer, P, exhibiting an isocyanate group, at least one polyimine ALD of Formula (I) of at least 22% by weight, in relation to the sum of the components of the compound which contain the isocyanate group, as well as, if necessary, a polyisocyanate oligomer OP. The humidity hardening compound is particularly suitable for providing coatings and linings. The use of the imines makes possible VOC-free or VOC-poor compounds, which is a substantial advantage for indoor applications.
    Type: Grant
    Filed: June 29, 2007
    Date of Patent: May 15, 2012
    Assignee: Sika Technology AG
    Inventors: Burkhard Walther, Urs Burckhardt, Susanne Strauss, Carsten Zilg, Norman Blank
  • Patent number: 8178205
    Abstract: A multilayer polyurethane or polyurea erosion resistant coating with a matte topcoat over a primer layer and filled basecoat layer used to protect the leading edge against high speed liquid or solid particle erosion for helicopter rotor blades, propellers and other articles using polyurethane or polyurea compositions.
    Type: Grant
    Filed: June 14, 2010
    Date of Patent: May 15, 2012
    Assignee: Hontek Corporation
    Inventor: Shek C. Hong
  • Patent number: 8173760
    Abstract: Methods for producing dendrons of different generations with hydrophobic functional end-groups, and for producing polyurethanes with the side-chain dendrons are disclosed step-by-step. The dendron with hydrophobic functional end-groups in the polyurethane systems, and the honeycomb-like structure thin films are obtained by a breath-figure process. The structures of dendrons and dendritic side-chain polyurethanes are respectively expressed in the following and the end-groups (R) of the dendron are long alkyl chains or perfluoroalkyl derivatives.
    Type: Grant
    Filed: February 28, 2010
    Date of Patent: May 8, 2012
    Assignee: Chung-Shan Institute of Science and Technology, Armaments Bureau, Ministry of National Defense
    Inventors: Wen-Chiung Su, Wei-Ho Ting, Chun-Ming Yeh, Chia-Cheng Chang, Sheng-Hong Dai, Ru-Jong Jeng
  • Patent number: 8168260
    Abstract: The invention provides a cross-linkable elestomeric thermoplastic polyurethane that is urea free, isocyanutrate free, oxazolinyl free, functional radically-polymerizable pendant group free and having terminal functional radically-polymerizable groups at both ends, and thermoset polyurethanes obtained therefrom. The invention also provides applications of the compositions, and processes for manufacturing these compositions.
    Type: Grant
    Filed: June 5, 2007
    Date of Patent: May 1, 2012
    Assignee: Huntsman International LLC
    Inventors: Dominicus Limerkens, Chris Ian Lindsay, Conny Nijs, Steve Andre Woutters
  • Patent number: 8158741
    Abstract: A polyurethane resin forming composition comprising: a main agent (A) containing an isocyanate group-terminated prepolymer obtained by reacting an isocyanate group-containing compound (a1) with a polyfunctional polyether polyol (b1) having a specific molecular weight distribution obtained by the use of a compound having a functional group number of 8 as an initiator; and a curing agent (B) containing a castor oil-modified polyol (b2) obtained from castor oil and/or a castor oil fatty acid and a trimethylolalkane. This polyurethane resin forming composition is applicable to the production of large-sized hollow-fiber membrane modules and can form cured resins excellent in adhesion property and heat resistance, low in the temperature dependence of hardness and extremely small in the amount of substance eluted into water when immersed in the water.
    Type: Grant
    Filed: November 22, 2006
    Date of Patent: April 17, 2012
    Assignee: Nippon Polyurethane Industry Co., Ltd.
    Inventors: Kouji Yamato, Shyogo Itoh, Keiko Yoshida
  • Patent number: 8153751
    Abstract: Disclosed is a multifunctional urethane monomer prepared by reacting (a) an epoxy compound having two or more epoxy groups, (b) a diol compound having an acidic group and (c) a compound having an ethylenically unsaturated group and an isocyanate group with one another. The photosensitive resin composition comprising the multifunctional urethane monomer has low viscosity, superior sensitivity, excellent chemical resistance and heat-resistance and high development margin.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: April 10, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Yoon Hee Heo, Min Young Lim, Ho Chan Ji, Sung-Hyun Kim, Han Soo Kim, Sun Hwa Kim
  • Patent number: 8148488
    Abstract: Disclosed is a polyisocyanate composition which is excellent in both curability and drying characteristic. The polyisocyanate composition contains at least one compound selected from aliphatic diisocyanates, at least one compound selected from alicyclic diisocyanates and at least one compound selected from polyols, while satisfying all of the following conditions; i) the diisocyanate monomer concentration is not more than 3 mass %, ii) the polyol component concentration is 1-50 mass %; and iii) the glass transition temperature is from ?50° C. to 0° C.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: April 3, 2012
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yoshiyuki Asahina, Masakazu Yamauchi, Hironori Katagawa
  • Publication number: 20120077932
    Abstract: The invention relates to compositions based on 2,5-diisocyanato-1,4:3,6-dianhydro-2,5-dideoxy-D-manitol (I), 2,5-diisocyanato-1,4:3,6-dianhydro-2,5-dideoxy-D-glucitol (II), and/or 2,5-diisocyanato-1,4:3,6-dianhydro-2,5-dideoxy-L-iditol (III), alone or in any mixtures.
    Type: Application
    Filed: April 23, 2010
    Publication date: March 29, 2012
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Jan Pfeffer, Martina Ortelt, Emmanouil Spyrou, Thomas Haas, Uwe Korek, Harald Schmidt, Uwe Dingerdissen
  • Patent number: 8143325
    Abstract: Absorbable polyurethanes, polyamides and polyester urethanes prepared from at least one compound selected from: or the diamines and diisocyanates thereof, wherein each X represents a member independently selected from —CH2COO— (glycolic acid moiety), —CH(CH3)COO— (lactic acid moiety), —CH2CH2OCH2COO— (dioxanone), —CH2CH2CH2CH2CH2COO— (caprolactone moiety), —(CH2)yCOO— where y is one of the numbers 2, 3, 4 or 6-24 inclusive, and —(CH2CH2O)z?CH2COO— where z? is an integer between 2 and 24, inclusive; each Y represents a member independently selected from —COCH2O— (glycolic ester moiety), —COCH(CH3)O— (lactic ester moiety), —COCH2OCH2CH2O— (dioxanone ester), —COCH2CH2CH2CH2CH2O— (caprolactone ester), —CO(CH2)mO— where m is an integer between 2, 3, 4 or 6-24 inclusive, —COCH2O(CH2CH2O)n— where n is an integer between 2 and 24, inclusive; R? is hydrogen, benzyl or an alkyl group, the alkyl group being either straight-chained or branched; p is an integer between 1 and 4, inclusive; and Rn represents one or more
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: March 27, 2012
    Assignee: Bezwada Biomedical, LLC
    Inventor: Rao S. Bezwada
  • Patent number: 8143364
    Abstract: Process for preparing a composition by reacting a polyisocyanate, a monoalkoxy polyoxyalkylene monoamine and water. The composition and its use in making cellular products are claimed as well.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: March 27, 2012
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Hans Godelieve Guido Verbeke
  • Patent number: 8138297
    Abstract: A moisture-curable silylated resin possessing improved storage stability and short cure time is obtained by reacting a prepolymer with a silylating reactant comprising silane (i) possessing three methoxy groups, silane (ii) possessing three alkoxy groups independently containing from 2 to 4 carbon atoms, and, optionally, silane (iii) possessing two methoxy groups and one alkoxy group of from 2 to 4 carbon atoms and/or silane (iv) possessing one methoxy group and two alkoxy groups independently containing from 2 to 4 carbon atoms.
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: March 20, 2012
    Assignee: Momentive Performance Materials Inc.
    Inventors: Misty Weiyu Huang, Christine Lacroix
  • Patent number: 8137595
    Abstract: The present invention relates to a UV curable photochromic composition comprising a photochromic dye and an acrylate-based prepolymer having a polyol structure in which an acrylate-based functional group is introduced by using an iso-cyanate-based compound having two or more isocyanate functional groups as a linker, and to products formed by using the same.
    Type: Grant
    Filed: October 9, 2008
    Date of Patent: March 20, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Jee-Seon Kim, Hye-Min Kim, Ja-Young Han
  • Patent number: 8124235
    Abstract: A method of forming a matte topcoat for rotor blades, propellers and other articles used to protect a leading edge substrate against high speed liquid or solid particle erosion including premixing a concentrate of flatting agent dispersed in a solvent, reducing the moisture content using molecular sieves, blending the concentrate of flatting agent into a polyurethane or polyurea composition and forming a protective coating comprising a matte layer on the leading edge substrate.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: February 28, 2012
    Assignee: Hontek Corporation
    Inventor: Shek C. Hong
  • Patent number: 8114920
    Abstract: The UV-curable aqueous coating composition is characterized by using a UV-curable aqueous emulsion obtained by urethane reaction with a mixture including a poly-carbonate polyol or polyester polyol; an isocyanate compound; a urethane-reactive carboxylic acid; a UV-curable acrylic oligomer having 2 to 9 functional acrylate groups; a UV-curable acrylic monomer; and a urethane-reactive acrylate without an organic solvent. The aqueous composition provides good environmental acceptability and satisfactory film properties comparable to those of the prior oily UV-curable coating composition and, therefore, it is useful for coating various plastics.
    Type: Grant
    Filed: January 15, 2007
    Date of Patent: February 14, 2012
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Dong Soo Kim, Tae Yun Jeong, Su Dong Hong, Jung Hyun Oh
  • Patent number: 8106140
    Abstract: The present invention relates to a process for preparing low-viscosity reaction products of polyisocyanates containing activated, ethylenically unsaturated groups which react, with polymerization, on exposure to actinic radiation.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: January 31, 2012
    Assignee: Bayer MaterialScience AG
    Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
  • Patent number: 8101702
    Abstract: A silicone-containing composition comprises the reaction product of a first component and an excess of an isocyanate component relative to the first component to form an isocyanated intermediary. The first component is selected from one of a polysiloxane and a silicone resin. The first component includes a carbon-bonded functional group selected from one of a hydroxyl group and an amine group. The isocyanate component is reactive with the carbon-bonded functional group of the first component. The isocyanated intermediary includes a plurality of isocyanate functional groups. The silicone-containing composition comprises the further reaction product of a second component, which is selected from the other of the polysiloxane and the silicone resin. The second component includes a plurality of carbon-bonded functional groups reactive with the isocyanate functional groups of the isocyanated intermediary for preparing the silicone-containing composition.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: January 24, 2012
    Assignee: Dow Corning Corporation
    Inventor: Mustafa Mohamed
  • Patent number: 8097190
    Abstract: An optical resin composition with superior impact resistance and a method for producing an optical lens from the composition are disclosed. In one embodiment, the optical resin composition for a plastic optical lens has superior impact resistance as well as light-weight, superior moldability, excellent dyeing ability, a high Abbe number and good transparency. The optical lens produced from the composition exhibits superior impact resistance even after multi-coating. The optical resin composition with superior impact resistance has a solid refractive index (nD) of about 1.53 to about 1.57, an Abbe number of about 35 to about 48, a liquid specific gravity of about 0.97 to about 1.25 and a solid specific gravity of about 1.10 to about 1.35, by which the composition comprises a mixture of isophorone diisocyanate and hexamethylene diisocyanate, pentaerythritol tetrakis(3-mercaptopropionate), a UV absorber, a release agent and a polymerization initiator.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: January 17, 2012
    Assignee: KOC Solution Co., Ltd.
    Inventors: Dong Gyu Jang, Jong Hyo Kim
  • Patent number: 8097675
    Abstract: Isocyanate mixtures comprising: (a) NCO prepolymers having an NCO content of 1.5 to 18 wt. %; and (b) 1 to 40 wt. % of monomeric 2,2?-diisocyanatodiphenylmethane, based on the isocyanate mixture; wherein the isocyanate mixture has a total NCO content of from 2 to 22 wt. %; polyisocyanate polyaddition products prepared therefrom; and methods of making the same.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: January 17, 2012
    Assignees: Bayer MaterialScience AG, Polytex Sportbelage Produktions GmbH
    Inventors: Zdenka Finder, Jens Krause, Friedhelm Faehling, Manfred Schmidt, Dirk Wegener
  • Patent number: 8080626
    Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: December 20, 2011
    Assignee: Albemarle Corporation
    Inventors: Paul L. Wiggins, John Y. Lee, Judit Orgad
  • Patent number: 8080609
    Abstract: The invention is a composition comprising a) one or more prepolymers having on average three or more aliphatic isocyanate groups and further containing alkoxysilane groups; b) one or more aromatic polyisocyanates; c) one or more compounds having at least one heterocyclic ring which hydrolyzes when exposed to moisture to form at least one isocyanate reactive group; d) one or more solvents; and e) one or more amine and/or organometallic polyurethane catalysts; wherein the ratio of aromatic isocyanate groups to aliphatic isocyanate groups in the composition is from about 0.5:1.0 to about 1.5:1.0, preferably about 0.9:1.0 to about 1.5:1.0, and the equivalent ratio of isocyanate groups to isocyanate reactive groups derivable from the one or more compounds having at least one hydrolyzable heterocylic ring is from about 0.8:1.0 to about 5.3:1.0, and most preferably about 1.5:1.0 to about 1.7:1.0.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: December 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventor: Stefan Schmatloch
  • Patent number: 8071663
    Abstract: The present invention is directed to a medically acceptable formulation comprising a diisocyanate terminated macromer or mixture thereof, and bio-absorbable desiccant comprising a hygroscopic and/or hydrophilic or combination thereof. The present invention is also directed to methods of use for such formulations for medical procedures.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: December 6, 2011
    Assignee: Ethicon, Inc.
    Inventors: Benjamin D. Fitz, Elizabeth Vailhe, Joseph Zavatsky, Christopher M. Westergom
  • Publication number: 20110294929
    Abstract: The present invention relates to materials comprising (A) at least one rubber, (B) at least one polyimide selected from branched condensation products of (a) at least one polyisocyanate having on average more than two isocyanate groups per molecule, and (b) at least one polycarboxylic acid having at least 3 COOH groups per molecule or anhydride thereof.
    Type: Application
    Filed: May 24, 2011
    Publication date: December 1, 2011
    Applicant: BASF SE
    Inventors: Anna Cristadoro, Bernd Bruchmann, Anna Thome, Juergen Widler
  • Patent number: 8058343
    Abstract: Novel aqueous polyurethane dispersions and adhesive films formed therefrom are provided. The aqueous polyurethane dispersions are provided in solvent-free systems of a prepolymer comprising at least one polyether or polyester polyol, a mixture of MDI isomers, and a diol. The adhesive films from such dispersions can be heat-activated for bonding, lamination, and adhesion of textile fabrics, including stretch fabrics.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: November 15, 2011
    Assignee: Invista North America S.àr.l.
    Inventors: Hong Liu, Carmen A Covelli, Douglas K Farmer
  • Patent number: 8048979
    Abstract: The present invention involves the design of a radiation curable organic pre polymer resin material based on urethane acrylic linkage synthesized from the natural renewable resource cardanol or a derivative thereof, for coating application. These new molecules have a faster and better curing rate compared to the starting renewable resource—cardanol. This is brought about by the hydrogen bonding of the urethane linkage which leads to a pre organization of the molecules in such a way as to bring the cross linkable double bonds closer to each other. The present invention also involves a UV curable formulation of the above mentioned resins along with 2-10 parts by weight of a photopolymerization initiator. The resin, either in a formulation or alone turns into a cross linked film upon photopolymerization in presence of photoinitiator under a UV curable radiation source like a mercury vapor pressure lamp.
    Type: Grant
    Filed: December 30, 2005
    Date of Patent: November 1, 2011
    Assignee: Council of Scientific and Industrial Research
    Inventors: Asha Syamakumari, Chennakkattu Krishna Sadasivan Pillai
  • Patent number: 8048953
    Abstract: A polymer having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2CF2)p(CH2CH2)q(R1)r—XH??Formula (I) wherein p and q are each independently an integer of 1 to 3; r is 0 or 1; X is —O—, —NH— or —S—; R1 is a divalent radical selected from the group consisting of —S(CH2)n—, n is an integer of 2 to 4; s is an integer of 1 to 50; R2, R3, and R4 are each independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and Rf is a linear or branched chain perfluoroalkyl group having 1 to 6 carbon atoms; and (ii) reacting with (c) water, a linking agent, or a mixture thereof and methods for treating substrates to obtain surface effects is disclosed.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: November 1, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Sheng Peng, Stephen James Getty, Timothy Edward Hopkins, Ying Wang
  • Patent number: 8039573
    Abstract: Compositions for golf balls that include polyurethane linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurethane have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.
    Type: Grant
    Filed: May 16, 2008
    Date of Patent: October 18, 2011
    Assignee: Acushnet Company
    Inventors: Randy Petrichko, Shawn Ricci
  • Patent number: 8022138
    Abstract: Aqueous polyurethane dispersion are disclosed where the dispersions contain from 5 to 70 weight percent polyurethane solids wherein the solids are obtained from at least one isocyanate terminated prepolymer prepared by reacting (a) a polyol or polyol blend having a mean average equivalent weight of 200 to 2,000; and (b) at least one polyisocyanate where the prepolymer is dispersed in water; optionally in the presence of (c) one or more stabilizers; or (d) one or more amine chain extenders or both; wherein the prepolymers have an isocyanate (NCO) content of from 2 to 40 weight percent and the polyol or polyol blend (a) contains at least 15 weight percent of a polyester based on a polycarboxylic acid or lactone component and a glycol component, wherein the glycol component contains isomers of 1,3- and 1,4-cyclohexanedimethanol (1,3-/1,4-CHDM) where the ratio of the 1,3-/1,4-isomers is from 35:65 to 65:35.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: September 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: John N. Argyropoulos, Debkumar Bhattacharjee
  • Patent number: 8017720
    Abstract: The present invention provides polythiol oligomer formed by the reaction of at least two or more different dienes and at least one or more dithiol wherein stoichiometric ratio of the sum of the number of equivalents of all polythiols to the sum of the number of equivalents of all dienes used to form the polythiol oligomer is greater than 1.0:1.0; and wherein the two or more different dienes comprise (a) at least one non-cyclic diene and at least one cyclic diene; or (b) at least one aromatic ring-containing diene and at least one non-aromatic cyclic diene; or (c) at least one non-aromatic monocyclic diene and at least one non-aromatic polycyclic diene; Sulfur-containing polyurethane of the present invention can be prepared by combining polyisocyanate, polyisothiocyanate, or mixture thereof; the polythiol oligomer described above; and active hydrogen-containing material.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: September 13, 2011
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Nina V. Bojkova, Robert D. Herold, William H. McDonald, Marvin J. Graham, Robert A. Smith
  • Patent number: 8003744
    Abstract: The present invention provides a curable composition including: an organic polymer (A) which has on average 1.1 to 50 groups per one molecule thereof each represented by the general formula (1) and has one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds: —NR1—C(?O)—??(1) wherein R1 is a hydrogen atom, or a substituted or unsubstituted monovalent organic group; and a metal carboxylate and/or a carboxylic acid (B), the curable composition giving a cured article excellent in curability and also excellent in heat resistance although a non-organotin catalyst is used.
    Type: Grant
    Filed: August 12, 2004
    Date of Patent: August 23, 2011
    Assignee: Kaneka Corporation
    Inventors: Toshihiko Okamoto, Katsuyu Wakabayashi
  • Patent number: 7977401
    Abstract: An ultraviolet curable resin composition, which comprises a cationic photopolymerization initiator (B) and a urethane prepolymer (A) having a structure represented by the general formula (1); (wherein R1 and R2 each independently represent an alkylene group, R3, R4 and R5 each independently represent an alkyl group or hydrogen atom, R6 and R7 each independently represent an alkylene group having 2 to 4 carbon atoms, a represents 0 or 1, and b and c each independently represent an integer of 0 to 10).
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: July 12, 2011
    Assignee: DIC Corporation
    Inventors: Kouichi Yokota, Koujirou Tanaka, Kai-Uwe Gaudl, Artur Lachowicz
  • Patent number: 7973122
    Abstract: Polyamideimide coating compositions, including polyamideimide coating compositions suitable for magnet wire applications are described. Processes for preparing coating compositions, for coating articles such as magnet wire, and for curing coating compositions are also described.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: July 5, 2011
    Assignee: General Cable Technologies Corporation
    Inventor: James J. Xu
  • Publication number: 20110152449
    Abstract: A method for preparing a functionalized polymer, the method comprising the steps of polymerizing monomer to form a reactive polymer, and reacting the reactive polymer with a protected polyoxime compound.
    Type: Application
    Filed: December 21, 2009
    Publication date: June 23, 2011
    Applicant: Bridgestone Corporation
    Inventor: Steven Luo
  • Patent number: 7964695
    Abstract: This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: June 21, 2011
    Assignee: Albemarle Corporation
    Inventors: John Y. Lee, Paul L. Wiggins, Judit Orgad, Mahmood Sabahi, Vernon O. Brandt
  • Patent number: 7964668
    Abstract: Compositions for golf balls that include polyurea linkages and that are crosslinked in the soft segments of the polymer backbone. In particular, the compositions of the invention, which are based on a polyurea have improved crosslink density from the crosslinking between the soft, unsaturated segments of the polymer backbone. The curative blend includes at least one isocyanate-reactive component and a free radical initiator.
    Type: Grant
    Filed: May 16, 2008
    Date of Patent: June 21, 2011
    Assignee: Acushnet Company
    Inventors: Randy Petrichko, Shawn Ricci
  • Patent number: 7951868
    Abstract: Disclosed is a carboxyl group-containing polyurethane containing a structure derived from a polycarbonate diol (B), the polycarbonate diol (B) having: (i) a number-average molecular weight of 500 to 50,000; (ii) an alkylene group of 8 to 18 carbon atoms in its structure; and (iii) hydroxyl groups at both ends. The carboxyl group-containing polyurethane is suitable as materials of cured products that are excellent in adhesion with substrates, low warpage, flexibility, plating resistance, soldering heat resistance and long-term reliability.
    Type: Grant
    Filed: July 4, 2006
    Date of Patent: May 31, 2011
    Assignee: Showa Denko K.K.
    Inventors: Hiroshi Uchida, Ritsuko Azuma
  • Patent number: 7935776
    Abstract: The present invention relates to a radiation curable and developable polyurethane which is characterized by having a carboxy group in its main chain and a acryloyl group in its side chain and comprising the following repeat units (I), (II), and (II) in a random arrangement: wherein R1, R2, R3, R4, and T are defined in the specification. The polyurethane has a weight molecular weight measured by GPC in a range of from 3,000 to 400,000; an acid value in a range of from 5 to 120 mgKOH/g. The present invention also relates to a radiation curable and developable composition containing the polyurethane.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: May 3, 2011
    Assignee: AGI Corporation
    Inventors: Wei Hsiang Huang, Ying Jen Chen, Jui Ming Chang, Chun Hung Kuo, Hong Ye Lin, Li Chung Chang
  • Patent number: 7923489
    Abstract: The invention describes amphiphilic polymer compounds which are prepared by a) reacting a di-, tri- or tetraglycidyl compound (A) with an optionally unsaturated reactive component (B) consisting of C8-C28-fatty acid, a C8-C28-alcohol or a secondary C8-C28-amine, and allowing b1) the reaction product from stage a) to react further first with b1?) an aliphatic or aromatic polyisocyanate compound (C) b1?) and optionally then with a polyalkylene oxide compound (D), and b1?) reacting the reaction product from stage b1?) or optionally b1?) with a component (E) which is reactive towards isocyanates and has at least one OH, NH2, NH or SH group, or b2) allowing the reaction product from stage a) to react to completion with the reaction product of component (C) with component (E) and optionally (D) and (C), or b3) allowing the reaction product from stage a) to react to completion with the reaction product from component (C) and component (D) and optionally (C) and optionally the reaction product of component (C) and
    Type: Grant
    Filed: July 20, 2006
    Date of Patent: April 12, 2011
    Assignee: Construction Research & Technology GmbH
    Inventors: Stefan Ingrisch, Gerhard Albrecht, Stefen Thaler, Mathias Bauer
  • Patent number: 7923574
    Abstract: The invention relates to novel prepolymers which are accessible from the formamides of oligomeric di- or polyamines (formamide-terminated oligomers) and di- or polyisocyanates.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: April 12, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Marc Leimenstoll, Burkhard Köhler, Christos Karafilidis, Matthias Wintermantel
  • Patent number: 7906606
    Abstract: Solvent-containing formulations including NCO-containing prepolymers based on TDI isocyanurate polyisocyanates and diphenylmethane diisocyanates where some prepolymers are prepared using a polyetherdiol containing ethylene oxide blocks and having an ethylene oxide content of from 2 to 18% by weight, based on all the alkylene oxide units. The formulation have an NCO content of 1% to 7% by weight, a solids content of 20% to 70% by weight, a monomeric TDI content of less than 0.2% by weight and a monomeric methylenediphenyl diisocyanate content of less than 2% by weight. The solvent-containing formulations can be prepared in organic solvents by reacting at least one of A) a TDI component comprising TDI isocyanurate polyisocyanates and B) an MDI component comprising diphenylmethane diisocyanates with C) a polyetherdiol. The solvent-containing formulations can be used in moisture-curing coating compositions, adhesive bonds and/or seals with substrates.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: March 15, 2011
    Assignee: Bayer MaterialScience AG
    Inventors: Meike Niesten, Christoph Irle, Federico Comajuan, Maria Almató Guiteras, Amadeo Vicente
  • Patent number: 7906607
    Abstract: It is an object of the present invention to provide an isocyanate group-terminated urethane prepolymer which has a low viscosity at melting and a process for producing the same, and an adhesive which comprises the urethane prepolymer. The invention relates to a process for producing an isocyanate group-terminated urethane prepolymer which comprises reacting polyols with a polyisocyanate compound, wherein the polyols comprise 10 to 50% by mass of a polyester polyol and 90 to 50% by mass of a polycarbonate polyol and wherein a sebacic acid-derived polyester polyol which is a polycondensate of sebacic acid with a diol compound accounts for 50 to 100% by mass of the polyester polyol and wherein the polyisocyanate compound and the polyols are reacted in such amounts that the ratio (by mol) of the isocyanate group/hydroxyl group is 1.2 to 3.2.
    Type: Grant
    Filed: October 22, 2007
    Date of Patent: March 15, 2011
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomeyoshi Ohori, Hiroshi Wada
  • Publication number: 20110060101
    Abstract: New associative polyurethanes which are manufactured with cardanol which is potentially oxyethylated. Use of these polyurethanes as thickening agents for aqueous formulations.
    Type: Application
    Filed: August 19, 2010
    Publication date: March 10, 2011
    Applicant: COATEX S.A.S.
    Inventors: Jean-Marc SUAU, Denis Ruhlmann
  • Publication number: 20110052903
    Abstract: A water dilutable UV-curable polyurethane containing alkylene oxide groups, the polyurethane being obtained from components comprising at least: (i) 1 to 25 wt. % of at least one polyisocyanate; (ii) 0 to 80 wt. % of at least one hydroxyl functional compound containing alkylene oxide groups; (iii) 10 to 90 wt. % of at least one hydroxyl functional compound containing at least one polymerisable unsaturated (meth)acryloyl functional group per molecule; and (iv) 0 to 50 wt. % of at least one isocyanate-reactive compound not comprised by (ii) or (iii); wherein the sum of (i) to (iv) is 100%.
    Type: Application
    Filed: January 29, 2009
    Publication date: March 3, 2011
    Inventors: Josephus Christian Van Oorschot, Ronald Tennebroek, Roel Johannes Marinus Swaans, Marc Roelands
  • Patent number: 7893184
    Abstract: Dendritic or hyperbranched polyurethanes are prepared by 1) reacting diols or polyols having at least one tertiary nitrogen atom and at least two hydroxyl groups of differing reactivity toward isocyanate groups with diisocyanates or polyisocyanates to form an addition product, with the diols or polyols and diisocyanates or polyisocyanates being selected so that the addition product has, on average, one isocyanate group and more than one hydroxyl group or one hydroxyl group and more than one isocyanate group, 2) converting the addition product from step 1) into a polyaddition product by intermolecular reaction of the hydroxyl groups with the isocyanate groups, and with a reaction with a compound containing at least two hydroxyl groups, mercapto groups, amino groups or isocyanate groups also being able to be carried out first, 3) if desired reacting the polyaddition product from step 2) with a compound containing at least two hydroxyl groups, mercapto groups, amino groups or isocyanate groups.
    Type: Grant
    Filed: May 14, 2004
    Date of Patent: February 22, 2011
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Jean-Francois Stumbe
  • Publication number: 20110040065
    Abstract: Polyester resins (C) of the invention have a practically sufficient high molecular weight and a high crystallinity and have an amide group in the molecular chain. Processes for producing the polyester resins are also disclosed. In detail, the polyester resins (C) have a practically sufficient high molecular weight and a high crystallinity and have a biodegradable amide group in the molecular chain. Processes for producing the polyester resins are also disclosed. The polyester resins (C) are obtained by reacting an aliphatic polyester resin (A) and a polyisocyanate compound (B) in the presence of an amidation catalyst and contain a specific structural unit.
    Type: Application
    Filed: March 3, 2009
    Publication date: February 17, 2011
    Inventors: Shinichi Usugi, Ryohei Ogawa, Hideshi Hori
  • Publication number: 20110028641
    Abstract: The present invention relates to composition comprising at least one compound obtained from the reaction of at least one compound (i) having a refractive index nD20 of at least 1.50 comprising at least one isocyanate-reactable functional group-XH, wherein each of X is, independently, O or NR, at least one polyisocyanate (ii), and, optionally, at least one compound (iii) comprising at least one isocyanate-reactable functional group —YH and at least one curable functional group Q, wherein each of Y is, independently, O, NR or S, and its use for making high refractive index coatings and films.
    Type: Application
    Filed: November 7, 2008
    Publication date: February 3, 2011
    Applicant: CYTEC SURFACE SPECIALTIES, S.A.
    Inventors: Zhikai Jeffrey Wang, Christopher Wayne Miller, Marcus Lee Hutchins, James C. Matayabas, JR.