From N=c=x Reactant Having At Least Two -c-nh-c(=x)- Groups Patents (Class 528/59)
  • Publication number: 20080167423
    Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilising side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.
    Type: Application
    Filed: May 11, 2004
    Publication date: July 10, 2008
    Inventors: Stuart Nicholas Richards, Andrew James Shooter
  • Patent number: 7396875
    Abstract: The present invention is directed to a waterborne, UV-curable polyurethane emulsion and the use thereof in producing soft touch coatings. The emulsion is prepared by a) reacting specified hydroxy-functional components with di- and/or polyisocyanates, b) forming a dispersion of the resultant product with water and reacting the dispersion with amine functional materials.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: July 8, 2008
    Assignee: Bayer MaterialScience LLC
    Inventors: Aaron A. Lockhart, Michael J. Dvorchak, Lyubov K. Gindin
  • Publication number: 20080160304
    Abstract: Polyamideimide coating compositions, including polyamideimide coating compositions suitable for magnet wire applications are described. Processes for preparing coating compositions, for coating articles such as magnet wire, and for curing coating compositions are also described.
    Type: Application
    Filed: March 10, 2008
    Publication date: July 3, 2008
    Inventor: James J. Xu
  • Publication number: 20080139776
    Abstract: Process for continuous production of thermoplastically processable polyurethane elastomers with improved homogeneity, by metering a polyisocyanate (A), a proportion of from 1 to 80 equivalent %, based on the isocyanate group content of the polyisocyanate (A), of a compound (B) having an average of at least 1.8 and at most 3.0 hydrogen atoms having Zerewitinoff activity, with an average molar mass of from 450 g/mol to 5000 g/mol, a proportion of from 12 to 99 equivalent %, based on the isocyanate group content of the polyisocyanate (A), of a chain extender (C) having an average of at least 1.8 and at most 3.
    Type: Application
    Filed: January 31, 2006
    Publication date: June 12, 2008
    Applicant: Basf Aktiengesellschaft
    Inventors: Gunter Scholz, Marian Mours, Sven Lawrenz, Horst Papenfuss, Christoph Bahr, Rudiger Krech
  • Publication number: 20080139755
    Abstract: A polyurea compound obtainable by reacting one or more polyisocyanates with one or more non-chiral mono-amines (I) and one or more chiral mono-amines (II) and co-precipitating the reaction products to form the polyurea compound, wherein 2-98 mole % of the mono-amines in the polyurea compound are chiral mono-amines. The invention also relates to the use of said polyurea compound as a rheology modification agent, in particular as sag control agent (SCA) in coating compositions. The invention further relates to sag control agent compositions, coating compositions and coatings comprising the polyurea compound as sag control agent.
    Type: Application
    Filed: January 10, 2006
    Publication date: June 12, 2008
    Inventor: Richard Hendrikus Gerrit Brinkhuis
  • Patent number: 7361292
    Abstract: The invention is a composition comprising a) one or more isocyanate functional polyether based prepolymers containing one or more organic based polymers dispersed therein; b) one or more isocyanate functional polyester based prepolymers which is solid at 23° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more conductive carbon blacks in an amount such that the composition has a dielectric constant of about 15 or less; and e) one or more catalysts for the reaction of isocyanate moieties with hydroxyl groups, wherein the composition demonstrates upon cure a modulus of 2.0 MPa or greater at 25° C. measured according to ASTM D4065; a dielectric constant of about 15 or less; a sag of an uncured sample of less than 2 mm, a press flow viscosity of about 20 to about 50 and a storage modulus of about 5.3×105 Pa or greater.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: April 22, 2008
    Assignee: Dow Global Technologies Inc.
    Inventor: Lirong Zhou
  • Publication number: 20080081871
    Abstract: An aqueous reactive coating composition contains a mixture of: (a)(1) one or more hydrophobic polyisocyanate oligomers, (a)(2) one or more surface active agents, and (a)(3) one or more fluorinated solvents, and provides high gloss films and exhibit improved pot-life.
    Type: Application
    Filed: September 28, 2007
    Publication date: April 3, 2008
    Inventors: Amit Sehgal, Satyen Trivedi, Lichang Zhou
  • Publication number: 20080064844
    Abstract: Disclosed are improved isocyanate-terminated polycaprolactone polyurethane prepolymers comprising the reaction product of toluene diisocyanate and polyol compositions. Polyurethane elastomers with good physical and dynamic properties can be obtained by reacting the isocyanate-terminated polycaprolactone prepolymers of the invention with an amine chain extender.
    Type: Application
    Filed: September 13, 2006
    Publication date: March 13, 2008
    Inventors: Phaniraj T. Nagaraj, Ronald O. Rosenberg
  • Patent number: 7342068
    Abstract: Aqueous polyurethane dispersions comprising polyurethane polymer and methods for making and using same are disclosed herein. In one aspect of the present invention, aqueous polyurethane dispersions, comprising a polyurethane polymer having a weight average molecular weight ranging from 20,000 to 80,000, are prepared by controlling the weight average molecular weight of the polymer by reacting the isocyanate terminated prepolymer with at least one chain terminating agent; and/or maintaining a N/COOH molar ratio of amine in the neutralizing agent to acid functional group in the isocyanate reactive compound to from about 0.5:1 to about 1:1.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: March 11, 2008
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Eric Howard Klingenberg, Shafiq Nisarali Fazel
  • Patent number: 7339020
    Abstract: High-functionality polyisocyanates are prepared by a process which comprises (i) preparation of an addition product (A) which contains one group which is reactive toward isocyanate and at least two isocyanate groups by reacting (a) a diisocyanate or polyisocyanate I with (b1) compounds having at least three groups which are reactive toward isocyanate or (b2) compounds containing two groups which are reactive toward isocyanate or mixtures of (b1) and (b2), where at least one of the components (a) or (b) has functional groups having differing reactivities toward the functional groups of the other component and the reaction ratio is selected so that the addition product (A) contains an average of one group which is reactive toward isocyanate, (ii) if desired, intermolecular addition reaction of the addition product (A) to form a polyaddition product (P) containing an average of one group which is reactive toward isocyanate and an average of more than two isocyanate groups, and (iii) reaction of the addition
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: March 4, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Hans Renz, Rainer Königer, Ulrike Ehe, Ulrich Treuling, Rudolf Müller-Mall
  • Patent number: 7329717
    Abstract: A process for preparing polyisocyanate-modified polycarboxylic acids by conversion of anhydride-group-free polycarboxylic acids with isocyanate-functional compounds. The process includes reacting A) an anhydride-group-free polycarboxylic-acid component with B) an isocyanate-functional component having an (average) isocyanate functionality of at least 1.8, at an equivalent ratio of carboxylic acid groups to isocyanate groups of from 1.2:1 to 120:1. The polyisocyanate-modified polycarboxylic acids are solid below 40° C. and liquid above 130° C., and have an average carboxylic acid functionality of at least 1.8, a content of free carboxylic acid groups of from 4.0 wt. % to 80.0 wt. % and a content of amide groups of from 0.4 wt. % to 32.5 wt. %.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: February 12, 2008
    Assignee: Bayer MaterialScience AG
    Inventors: Hans-Josef Laas, Christoph Gürtler, Reinhard Halpaap, Michael Grahl, Peter Thometzek, James Rawlins
  • Patent number: 7323435
    Abstract: Fluorinated oligourethanes, having number average molecular weight lower than or equal to 9,000, having a branched structure, formed of the following monomers and macromers: a) aliphatic, cycloaliphatic or aromatic polyisocyanates, b) heterofunctional hydrogenated monomers having general formula: X0—(CR1AR2A)b—Y0 ??(Ib) one or more of the following compounds: c) bifunctional hydroxyl (per)fluoropolyethers (PFPE diols) having number average molecular weight in the range 400-3,000, e) monofunctional hydroxyl (per)fluoropolyethers or monofunctional hydroxyl (per)fluoroalkanes (e?), having number average molecular weight in the range 300-1,000, and optionally the following compounds: d) heterofunctional monomers, dI) hydrogen-active compounds, capable to form bonds with the NCO functions stable at the hydrolysis but weak at heat.
    Type: Grant
    Filed: June 12, 2000
    Date of Patent: January 29, 2008
    Assignee: Ausimont S.p.A.
    Inventors: Stefano Turri, Marinella Levi, Tania Trombetta
  • Patent number: 7323532
    Abstract: The present invention concerns a process for producing low-viscosity polyisocyanates or secondary products thereof, which carry activated, radiation-curable double bonds and can optionally also cure thermally, and low-viscosity polyisocyanate mixtures or secondary products thereof and their use in coating compounds.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: January 29, 2008
    Assignee: Bayer MaterialScience AG
    Inventors: Thomas Fäcke, Jan Weikard, Wolfgang Fischer
  • Patent number: 7307136
    Abstract: A polyisocyanate-based elastomer having a ratio of the storage modulus (E?) at 20° C. and the storage modulus (E?) at 120° C. of between 0.75 and 1.5, a tan ? at 100° C. of less than 0.1 and a maximum value of the tan ? of more than 0.8, the tan ? being the ratio of the loss modulus (E?) and the storage modulus (E?).
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: December 11, 2007
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Alan James Hamilton, Jan Willem Leenslag
  • Patent number: 7279505
    Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.
    Type: Grant
    Filed: October 5, 2005
    Date of Patent: October 9, 2007
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
  • Patent number: 7253252
    Abstract: The present invention relates to new water-soluble polyaspartic esters and also to their use in aqueous coating compositions.
    Type: Grant
    Filed: July 11, 2005
    Date of Patent: August 7, 2007
    Assignee: Bayer MaterialScience AG
    Inventors: Burkhard Köhler, Meike Niesten, Joachim Simon, Christian Wamprecht
  • Patent number: 7253244
    Abstract: A one-pack polyurethane adhesive containing a polyisocyanate prepolymer and at least one aminoether polyol, having a molar ratio of ether groups to amino nitrogen in the aminopolyether polyol of 7 to 30.
    Type: Grant
    Filed: March 11, 2004
    Date of Patent: August 7, 2007
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Gruenewaelder, Werner Haller, Bernhard Schoettmer, Thomas Empt, Hermann Kluth
  • Patent number: 7252927
    Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula wherein x is an integer of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, wherein said photosensitivity-imparting substituents are allyl ether groups, epoxy groups, or mixtures thereof. Also disclosed are a process for preparing a thermal ink jet printhead containing the aforementioned polymers and processes for preparing the aforementioned polymers.
    Type: Grant
    Filed: January 14, 2005
    Date of Patent: August 7, 2007
    Assignee: Xerox Corporation
    Inventors: Ram S. Narang, Timothy J. Fuller
  • Patent number: 7247695
    Abstract: Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: July 24, 2007
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Gwang Hoon Kwag, Sam Min Kim, Young Chan Jang, Pil Sung Kim, Seung Hwon Lee, Seung Hwa Lee, A Ju Kim
  • Patent number: 7223801
    Abstract: A composition and method for protecting pipeline joints is disclosed. A mold covers the exposed pipeline joint. A reaction composition including a polyol, an isocyanate, and an ester, preferably 2,2,4-trimethyl-1,2-pentanediol diisobutyrate, is added to the mold and allowed to react to form a polymer.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: May 29, 2007
    Assignee: Baysystems North America LLC
    Inventor: Scott A Brown
  • Patent number: 7217761
    Abstract: The invention relates to the use of a compound with an alkylene oxide chain as a thickener of aqueous compositions, containing a filler and/or pigmented, white or colored, with the aim of supplying pigmentary compositions for paint which provide excellent pigmentary compatibility and a high viscosity at small and medium shear stress gradient. The invention also relates to the said non-ionic thickener as well as the aqueous composition, containing a filler and/or pigmented, white or colored, containing same.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: May 15, 2007
    Assignee: Coatex S.A.S.
    Inventors: Denis Ruhlmann, Jean-Marc Suau
  • Patent number: 7211621
    Abstract: Polyurethaneurea resins containing at least one group of the formula (I) —NH(CO)XOR1O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—??(I) and/or at least one group of the formula (II) {—NH(CO)XO}a{CH2?CR2(CO)O}bR4{O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—}c??(II) wherein X=[O(CH2)4]q(OC2H4)x(OC3H6)y[(CH2)5(CO)]z; q=0 to 10; x=0 to 20; y=0 to 20; z=0 to 10; n=2 or 3; a=1 or 2; b=0 to 4; c=1 to 5; R1=—C2H4—, —C3H6—, —C4H8—, —CH(CH2O(CO)R5)CH2— or —CH2CH(O(CO)R5)CH2—; R2=H or CH3; R3=C1 to C4 alkyl; R4=a+b+c-valent, saturated hydrocarbon residue of a (cyclo)alkane polyol with a+b+c hydroxyl groups; R5=an acid residue of a monocarboxylic acid, with the proviso that a+b+c=3 to 6 and wherein the sequence of the subformulae indicated q, x, y and z may be varied at will and q, x, y and z in each case merely state the number of instances of the particular subformulae contained in the formulae (I) and (II).
    Type: Grant
    Filed: February 11, 2004
    Date of Patent: May 1, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Carmen Flosbach, Stefanie Matten
  • Patent number: 7208560
    Abstract: A process for the preparation of urethane resins, which comprises the steps of: preparing a product (A) having a hydrolysable group directly bonded to 1–10 silicon atoms and having less than two secondary amino groups in one molecule; preparing a product (B) having a terminal isocyanate group in an amount 4% or less by weight of the product (B); and reacting the product (A) with the product (B) in proportions of at least 0.5 equivalent of the product (A) per free NCO group of the product (B). The process readily gives urethane resins, which exhibit excellent storage stability and are enhanced in the degrees of freedom of the physical properties of the products of curing.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: April 24, 2007
    Assignee: Konishi Co., Ltd.
    Inventors: Shinichi Sato, Akihiro Sato
  • Patent number: 7205374
    Abstract: A method of preparing an adhesive, the method comprising combining an isocyanate, a polyhydroxyl phenol-containing compound, a polyol, and a trimerization catalyst.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: April 17, 2007
    Assignee: BFS Diversified Products, LLC
    Inventors: John W. Fieldhouse, Joseph J. Kalwara, Edward G. Kane, John B. Letts
  • Patent number: 7199207
    Abstract: A polyurethane prepolymer obtainable by reacting at least one aromatic polyisocyanate having symmetrical substitution of NCO groups and at least one aromatic polyisocyanate having asymmetric substitution of NCO groups, the fraction of aromatic polyisocyanate having symmetrical substitution of NCO groups being higher than the fraction of polyisocyanate having asymmetric substitution of NCO groups, and at least one polyol having an OH functionality of more than 2.5 and at least one polyol having an OH functionality of less than 2.5.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: April 3, 2007
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernhard Gruenewaelder, Werner Haller, Birgit Ness, Thomas Empt
  • Patent number: 7193011
    Abstract: The present invention relates to a method of preparing water-dispersible poly (urethane-urea) having aliphatic-aromatic isocyanate, more particularly to a method of preparing water-dispersible poly (urethane-urea) having aliphatic-aromatic isocyanate, with improved mechanical/thermal properties, such as heat resistance, chemical resistance and adhesion, good cost competitiveness and environmental friendliness, by reacting polyester polyol, dimethylol propionic acid and an aromatic isocyanate compound to obtain a hydroxyl (OH)-terminated prepolymer, adding an aliphatic isocyanate compound to said OH-terminated prepolymer to obtain an isocyanate (NCO)-terminated prepolymer wherein aromatic-aliphatic isocyanate is hybridized, neutralizing, water-dispersing and chain extending said NCO-terminated prepolymer.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: March 20, 2007
    Assignee: Yonsei University
    Inventors: Jung Hyun Kim, In Woo Cheong, Kyoung Min Ahn
  • Patent number: 7157519
    Abstract: A water-dispersible polyurethane resin comprising building blocks derived from polyisocyanates A, polyols B having a number-average molar mass Mn of at least 400 g/mol, where appropriate, low molar mass polyols C with Mn below 400 g/mol, compounds D which possess at least two groups which are reactive toward isocyanate groups and at least one group which is capable of forming anions, low molar mass polyols E which in relation to isocyanate groups carry no further reactive groups, compounds F, which are monofunctional toward isocyanates or contain active hydrogen of different reactivity and are different from the compounds E and also, where appropriate, compounds G, which are different from B, C, D, E and F and contain at least two groups which are reactive with NCO groups, wherein the number-average molar mass Mn of the polyurethane resin is at least 10 kg/mol, its weight-average molar mass Mw is at least 20 kg/mol, and its acid number is from 20 to 50 mg/g; a process for its preparation; and its use as a bin
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: January 2, 2007
    Assignee: Solutia Austria GmbH
    Inventors: Markus A. Schafheutle, Anton Arzt, Julius Burkl, Martina Glettler, Gerlinde Petritsch, Joerg Wango
  • Patent number: 7151154
    Abstract: Graft polymer curatives comprise a side chain having an average molecular weight of at least about 500, a main chain having an average molecular weight of less than about 200, and diol functionality on the main chain. The graft polymer curative is formed via free radical polymerization of at least one ethylenically-unsaturated monomer with a chain transfer agent or initiator.
    Type: Grant
    Filed: January 13, 2004
    Date of Patent: December 19, 2006
    Assignee: Lexmark International, Inc.
    Inventors: Kelly A. Killeen, Jing X. Sun
  • Patent number: 7148308
    Abstract: The present invention provides an one-part moisture-curable urethane composition which exhibits excellent adhesion particularly to a coated steel plate difficult to bond with no-primer and is useful in the bonding of automobile window glass. The urethane composition of the present invention comprises an isocyanate-terminated urethane prepolymer as the main component, and additional components comprising (A) a compound having solubility parameter value of 6.0 to 9.0 and/or (B) a compound having in the molecule at least one structure represented by the following formula: (wherein n is 0 to 3).
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: December 12, 2006
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Atsushi Inoue, Yoshinori Mayama, Yoshihiro Nakata
  • Patent number: 7148310
    Abstract: The present invention is directed to a multiple component coating composition comprising (a) a film forming binder component having isocyanate reactive groups; (b) a stable polyisocyanate solution comprising organic liquid and up to 30% by weight, based on the weight of the polyisocyanate solution, of a polyisocyanate having reactive isocyanate groups selected from an aromatic polyisocyanate having tertiary isocyanate groups or a (meth)acrylic polymer containing reactive isocyanate groups; and (c) optionally, a tinting composition comprising pigment, a dispersing agent and an organic liquid carrier; whereby components (a), (b) and (c) are blended together before application to a substrate and after application to a substrate the composition is cured to form a finish. The present invention is also directed to a method of producing a finish on a substrate and to the resulting coated substrate.
    Type: Grant
    Filed: August 13, 2004
    Date of Patent: December 12, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert John Barsotti, Christopher Scopazzi, Douglas Matt Lamb
  • Patent number: 7148287
    Abstract: Compositions incorporating water-curable urethane constituent(s) are formulated with favorable viscosity and viscosity stability characteristics, while at the same time, preserving desired hardness characteristics. The present invention is particularly useful in applications in which water-curable compositions include NCO-functional resins having relatively high NCO content and/or incorporate MDI-based constituents. Preferred modes of practicing the invention include implementing one or more formulation strategies to help retain hardness while preserving good viscosity characteristics. These preferred strategies involve (i) balancing scavenger, polyisocyanate and polyfunctional polyol content of the compositions or resins thereof, as the case may be, (ii) formulating an NCO-functional resin with chain extender constituent(s) to enhance viscosity stability, (iii) formulating with one or more plasticizers that enhance viscosity performance, and (iv) combinations of two or more of these strategies.
    Type: Grant
    Filed: May 13, 2004
    Date of Patent: December 12, 2006
    Inventor: Laxmi C. Gupta
  • Patent number: 7144955
    Abstract: Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: December 5, 2006
    Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AG
    Inventors: Scott A. Grace, Michael J. Dvorchak, Richard R. Roesler, Dinesh Pethiyagoda, Michael K. Jeffries, Jan Weikard
  • Patent number: 7138466
    Abstract: High green strength reactive hot melt adhesives are prepared using relatively low levels of reactive acrylic, and may be prepared with one or more difunctionals having cyclic or polycyclic structures.
    Type: Grant
    Filed: April 6, 2004
    Date of Patent: November 21, 2006
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Ju-Ming Hung, Yue S. Zhang, Yimin Zhang, Zhixin Li
  • Patent number: 7135128
    Abstract: At least one isocyanate-reactive monomer is reacted with an excess of molten monomeric diisocynate to produce at least one reaction product and a maximum of 0.5 wt % of free isocyanate groups. The reaction product is then mixed with at least 20 wt. %, based on the total weight of reaction product, of at least one isocyanate-terminated prepolymer which is essentially free of diisocyanate monomers and has a viscosity at 20° C. of at least 1.500 mPa·s, the isocyanate-terminated prepolymer having a content of free NCO groups of up to 25 wt % and containing a maximum of 0.1 wt. % of diisocyanate monomer(s) based on the weight of the isocyanate-terminated prepolymer. A polyurethane composition containing less than 0.1 wt. % of monomeric diisocyanate, based on the total weight of the resulting polyurethane composition, is produced.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: November 14, 2006
    Assignee: Jowat AG
    Inventors: Theodor Hippold, Dieter Guse, Christian Terfloth
  • Patent number: 7129312
    Abstract: Polyurethane compositions are produced in a two-stage method. In a first step, a diol component with a molecular weight of less than 2000 is reacted with a monomeric diisocyanate with a molecular weight of less than 500 and the unreacted monomeric diisocyanate is removed from this reaction product. In a second step, the resulting high-molecular diisocyanate is reacted with a polyol to produce a reactive prepolymer with isocyanate and groups. The addition of polyisocyanates which are capable of migration and which have a substantially lower vapor pressure than diphenylmethanediisocyanate, improves the addition behavior of the invention polyurethane compositions. Reactive polyurethane compositions of this type are suitable for using as binding agents for reactive one or two component adhesives/sealants, which may optionally contain solvents. These compositions are also suitable for producing reactive hot melt adhesives when suitable polyols are selected.
    Type: Grant
    Filed: November 25, 2000
    Date of Patent: October 31, 2006
    Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGAA)
    Inventors: Michael Krebs, Christoph Lohr, Andreas Brenger
  • Patent number: 7101950
    Abstract: The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: September 5, 2006
    Assignee: Dow Global Technologies Inc.
    Inventors: Lirong Zhou, Daniel P. Heberer
  • Patent number: 7078442
    Abstract: A composition and method for consolidating aggregate material is disclosed. The method includes introducing a reaction composition into the aggregate material and allowing it to reach on form a polymer which binds the aggregate together. The composition includes polyol, isocyanate, and ester.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: July 18, 2006
    Assignee: Baysystems North America LLC
    Inventor: Scott A Brown
  • Patent number: 7074850
    Abstract: The invention relates to polyurethane block copolymers of general formula (I) to (IV), in which the variables are defined as follows: A represents a polyurethane block, which contains at least one hydrophilic group, B is a hydrophobic polyurethane block, X1, X2 are hydrophilic end groups and n is a whole number from 1 to 20. The invention also relates to the production of cross-linkable dispersion additives from the inventive polyurethane block copolymers and to the use of said cross-linkable dispersion additives for colorant preparations, in particular inks for ink-jet printing.
    Type: Grant
    Filed: September 14, 2002
    Date of Patent: July 11, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrike Hees, Sophia Ebert, Ruediger Sens, Friedrich-Wilhelm Raulfs, Hans-Guenter Bohrmann, Lothar Schulz, Heinz Heissler, Johann Mueller, Karl Siemensmeyer, Guenter Renz
  • Patent number: 7045650
    Abstract: A polyol composition having a number average molecular weight of from about 1,000 to about 3,000 Daltons is made up of (1) at least 60% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 2,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 40% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than 1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethane elastomers, including one-shot processes, may be used to produce elastomers in accordance with the present invention.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: May 16, 2006
    Assignee: Bayer Materialscience LLC
    Inventors: Bruce D. Lawrey, Kurt C. Frisch, Nigel Barksby
  • Patent number: 7038003
    Abstract: A process for preparing polyisocyanate prepolymers containing allophanate structural units that includes reacting a) one or more polyisocyanates with b) one or more polyetherpolyols containing less than or equal to 0.02 milliequivalent of unsaturated end groups per gram of polyol and having a polydispersity of from 1.0 to 1.5 and/or an OH functionality of greater than or equal to 1.9 ?to provide an NCO-functional polyurethane prepolymer containing urethane groups that are partly or fully allophanatized by further reaction with c) polyisocyanates, which may be different from those from a), and d) catalysts and optionally adding e) acidic additives before, during and/or after the allophanatization. The polyisocyanate prepolymers can be used to produce coatings, adhesive bonds and/or seals. The coatings include one or more of the polyisocyanate prepolymers, and at least one diol or polyol and/or at least one linear and/or cyclic, aliphatic, araliphatic and/or aromatic diamine or polyamine.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: May 2, 2006
    Assignee: Bayer MaterialScience AG
    Inventors: Michael Mager, Joachim Simon, Malte Homann
  • Patent number: 7034097
    Abstract: Polyurethane elastomers are formed from first and second graft curatives, each graft curative having a molecular weight of at least about 800, wherein the first and second graft curatives are substantially immiscible with one another, and wherein the polyurethane elastomer exhibits a hardness of less than about 40 Shore A according to ASTM D2240-86 and a compression set of less than about 8% according to ASTM D395-89, method B, at a temperature of about 70° C. for about 22 hours. Rolls are manufactured using such polyurethane elastomers, particularly rolls that are suitable for use in image forming devices, such as electrophotographic print applications.
    Type: Grant
    Filed: January 13, 2004
    Date of Patent: April 25, 2006
    Assignee: Lexmark International, Inc.
    Inventors: Bradley L. Beach, Bhaskar Gopalanarayanan, Kelly A. Killeen, Johnny D. Massie, II, Ronald L. Roe
  • Patent number: 7022804
    Abstract: The invention relates to a moisture-crosslinkable hot-melt adhesive which is composed of a polyurethane prepolymer obtained by polyaddition of at least one polyol to at least one isocyanate chosen from the group of diisocyanates trimerized as isocyanurates and reaction products of diisocyanates with water, the prepolymer having a content of free NCO group of between 1 and 25% by weight. The adhesive according to the invention may be used for the adhesive bonding of fixing components of the Velcro® type to articles intended for hygiene.
    Type: Grant
    Filed: June 4, 2003
    Date of Patent: April 4, 2006
    Assignee: Bostik SA
    Inventors: Michel Miskovic, François Bauduin, Patrick Bouttefort, Jean-François Chartrel
  • Patent number: 7015299
    Abstract: Melt spun thermoplastic polyurethane polymers useful as textile fibers and having good tenacity and recovery and substantially no gelation are disclosed. The polymers are prepared by a three-step polymerization process including: preparation of “hard” segment oligomer, preparation of “soft” segment oligomer and final reaction of “hard” segment with “soft” segment in a twin-screw reaction extruder to obtain a final polyurethane product having relatively uniform distances between the “hard” segments. The “soft” segment oligomer comprises blocks of polymeric glycol (poly) urethanes end capped with isocyanate groups. The “hard” segment oligomer comprises blocks of low molecular weight C2–C6 glycol (poly) urethanes.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: March 21, 2006
    Inventor: W. Kenneth Wilkinson
  • Patent number: 7005477
    Abstract: A one component moisture-curing polyurethane adhesive composition having a long pot life that does not cause its user to experience breathing difficulty is described. In one embodiment the adhesive is prepared from a mixture of a high molecular weight component selected from the group consisting of polyols, diamines, and mixtures thereof; an isocyanate; and a low molecular weight component selected from the group consisting of diols, diamines, and mixtures thereof.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: February 28, 2006
    Assignee: MCP Industries, Inc.
    Inventors: Thomas M. Garrett, Xian Xian Du
  • Patent number: 7005482
    Abstract: A self-supporting reactive hot-melt adhesive element of a reactive one-component hot-melt adhesive which is solid at room-temperature. The adhesive element comprises at least one isocyanate being solid or liquid at room-temperature; and at least one isocyanate-reactive polymer and/or resin being solid at room-temperature. Also disclosed is a process of producing said adhesive element as well as its application and use, in particular in a hot-melt adhesive bonding process.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: February 28, 2006
    Assignee: Jowat Lobers und Frank GmbH & Co. KG
    Inventors: Dieter Guse, Theodor Hippold, Christian Terfloth
  • Patent number: 7001975
    Abstract: A hydrophilic or hydrophobic polyurethane containing on average per molecule at least one olefinically unsaturated structural unit selected from the group consisting of pendant, internal, and terminal, acyclic and cyclic terpene units; graft copolymers of the polyurethane with olefinically unsaturated monomers, processes for preparing the polyurethane and the graft copolymers, and their use for preparing coating materials, adhesives, and sealing compounds.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: February 21, 2006
    Assignee: BASF Coatings AG
    Inventors: Wolfgang Bremser, Thomas Krüger, Wilma Löcken, Peter-Heinz Rink, Stephan Schwarte
  • Patent number: 6997997
    Abstract: A method is provided for preparing thermoplastic elastomers. A blocks of the thermoplastic elastomers are crystalline at temperatures below about 60° C. and are derived from oxetane derivatives and/or tetrahydrofuran derivatives. B blocks of the thermoplastic elastomer are amorphous above about ?20° C. and are derived from oxetanes, tetrahydrofuran, oxiranes, and derivatives thereof. According to this method, the A and B blocks are dissolved into solution containing a non-halogenated solvent, preferably tetrahydrofuran, then dried by azeotropic distillation. The dried blocks are end-capped with a diisocyanate, preferably a diisocyanate having one isocyanate moiety substantially more reactive with the terminal groups of the blocks than the other isocyanate moiety of the diisocyanate. The end-capped blocks are then linked together with a linking compound.
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: February 14, 2006
    Assignee: Alliant Techsystems Inc.
    Inventors: Andrew J. Sanderson, Wayne W. Edwards
  • Patent number: 6995192
    Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: February 7, 2006
    Assignee: Novartis AG
    Inventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
  • Patent number: 6992164
    Abstract: In a uniformly copolymerized one-part polyurethane resin composition with improved processing behaviors and chemical resistance, the one-part polyurethane resin composition comprises about 20 to 50% by weight of a hard segment and about 50 to 80% by weight of a soft segment. The hard segment reduces drying time and recoating time of a film coated by the composition, and the soft segment improves processing behaviors of the film including rolling and spraying properties. The one-part polyurethane resin composition may further comprise a catalyst. The catalyst may regulate film drying time and improve gloss of a coated film. Thus, the resin composition may be applied in various fields.
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: January 31, 2006
    Assignee: DPI Co., Ltd.
    Inventors: Ju-Kil Lee, Hee-Jong Kim
  • Patent number: 6977290
    Abstract: The present invention relates to a method for preparing oligomeric aliphatic diols, polycarbonatediols based thereon and NCO-terminated prepolymers obtainable therefrom. The inventive compounds may find use in the preparation of polyurethanes.
    Type: Grant
    Filed: January 22, 2004
    Date of Patent: December 20, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Nefzger, Erika Bauer, Manfred Schmidt, Hans-Dieter Ruprecht, James-Michael Barnes