From N=c=x Reactant Having At Least Two -c-nh-c(=x)- Groups Patents (Class 528/59)
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Publication number: 20080167423Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilising side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.Type: ApplicationFiled: May 11, 2004Publication date: July 10, 2008Inventors: Stuart Nicholas Richards, Andrew James Shooter
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Patent number: 7396875Abstract: The present invention is directed to a waterborne, UV-curable polyurethane emulsion and the use thereof in producing soft touch coatings. The emulsion is prepared by a) reacting specified hydroxy-functional components with di- and/or polyisocyanates, b) forming a dispersion of the resultant product with water and reacting the dispersion with amine functional materials.Type: GrantFiled: January 20, 2004Date of Patent: July 8, 2008Assignee: Bayer MaterialScience LLCInventors: Aaron A. Lockhart, Michael J. Dvorchak, Lyubov K. Gindin
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Publication number: 20080160304Abstract: Polyamideimide coating compositions, including polyamideimide coating compositions suitable for magnet wire applications are described. Processes for preparing coating compositions, for coating articles such as magnet wire, and for curing coating compositions are also described.Type: ApplicationFiled: March 10, 2008Publication date: July 3, 2008Inventor: James J. Xu
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Publication number: 20080139776Abstract: Process for continuous production of thermoplastically processable polyurethane elastomers with improved homogeneity, by metering a polyisocyanate (A), a proportion of from 1 to 80 equivalent %, based on the isocyanate group content of the polyisocyanate (A), of a compound (B) having an average of at least 1.8 and at most 3.0 hydrogen atoms having Zerewitinoff activity, with an average molar mass of from 450 g/mol to 5000 g/mol, a proportion of from 12 to 99 equivalent %, based on the isocyanate group content of the polyisocyanate (A), of a chain extender (C) having an average of at least 1.8 and at most 3.Type: ApplicationFiled: January 31, 2006Publication date: June 12, 2008Applicant: Basf AktiengesellschaftInventors: Gunter Scholz, Marian Mours, Sven Lawrenz, Horst Papenfuss, Christoph Bahr, Rudiger Krech
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Publication number: 20080139755Abstract: A polyurea compound obtainable by reacting one or more polyisocyanates with one or more non-chiral mono-amines (I) and one or more chiral mono-amines (II) and co-precipitating the reaction products to form the polyurea compound, wherein 2-98 mole % of the mono-amines in the polyurea compound are chiral mono-amines. The invention also relates to the use of said polyurea compound as a rheology modification agent, in particular as sag control agent (SCA) in coating compositions. The invention further relates to sag control agent compositions, coating compositions and coatings comprising the polyurea compound as sag control agent.Type: ApplicationFiled: January 10, 2006Publication date: June 12, 2008Inventor: Richard Hendrikus Gerrit Brinkhuis
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Patent number: 7361292Abstract: The invention is a composition comprising a) one or more isocyanate functional polyether based prepolymers containing one or more organic based polymers dispersed therein; b) one or more isocyanate functional polyester based prepolymers which is solid at 23° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more conductive carbon blacks in an amount such that the composition has a dielectric constant of about 15 or less; and e) one or more catalysts for the reaction of isocyanate moieties with hydroxyl groups, wherein the composition demonstrates upon cure a modulus of 2.0 MPa or greater at 25° C. measured according to ASTM D4065; a dielectric constant of about 15 or less; a sag of an uncured sample of less than 2 mm, a press flow viscosity of about 20 to about 50 and a storage modulus of about 5.3×105 Pa or greater.Type: GrantFiled: November 8, 2004Date of Patent: April 22, 2008Assignee: Dow Global Technologies Inc.Inventor: Lirong Zhou
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Publication number: 20080081871Abstract: An aqueous reactive coating composition contains a mixture of: (a)(1) one or more hydrophobic polyisocyanate oligomers, (a)(2) one or more surface active agents, and (a)(3) one or more fluorinated solvents, and provides high gloss films and exhibit improved pot-life.Type: ApplicationFiled: September 28, 2007Publication date: April 3, 2008Inventors: Amit Sehgal, Satyen Trivedi, Lichang Zhou
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Publication number: 20080064844Abstract: Disclosed are improved isocyanate-terminated polycaprolactone polyurethane prepolymers comprising the reaction product of toluene diisocyanate and polyol compositions. Polyurethane elastomers with good physical and dynamic properties can be obtained by reacting the isocyanate-terminated polycaprolactone prepolymers of the invention with an amine chain extender.Type: ApplicationFiled: September 13, 2006Publication date: March 13, 2008Inventors: Phaniraj T. Nagaraj, Ronald O. Rosenberg
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Patent number: 7342068Abstract: Aqueous polyurethane dispersions comprising polyurethane polymer and methods for making and using same are disclosed herein. In one aspect of the present invention, aqueous polyurethane dispersions, comprising a polyurethane polymer having a weight average molecular weight ranging from 20,000 to 80,000, are prepared by controlling the weight average molecular weight of the polymer by reacting the isocyanate terminated prepolymer with at least one chain terminating agent; and/or maintaining a N/COOH molar ratio of amine in the neutralizing agent to acid functional group in the isocyanate reactive compound to from about 0.5:1 to about 1:1.Type: GrantFiled: November 18, 2003Date of Patent: March 11, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Eric Howard Klingenberg, Shafiq Nisarali Fazel
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Patent number: 7339020Abstract: High-functionality polyisocyanates are prepared by a process which comprises (i) preparation of an addition product (A) which contains one group which is reactive toward isocyanate and at least two isocyanate groups by reacting (a) a diisocyanate or polyisocyanate I with (b1) compounds having at least three groups which are reactive toward isocyanate or (b2) compounds containing two groups which are reactive toward isocyanate or mixtures of (b1) and (b2), where at least one of the components (a) or (b) has functional groups having differing reactivities toward the functional groups of the other component and the reaction ratio is selected so that the addition product (A) contains an average of one group which is reactive toward isocyanate, (ii) if desired, intermolecular addition reaction of the addition product (A) to form a polyaddition product (P) containing an average of one group which is reactive toward isocyanate and an average of more than two isocyanate groups, and (iii) reaction of the additionType: GrantFiled: March 19, 2001Date of Patent: March 4, 2008Assignee: BASF AktiengesellschaftInventors: Bernd Bruchmann, Hans Renz, Rainer Königer, Ulrike Ehe, Ulrich Treuling, Rudolf Müller-Mall
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Patent number: 7329717Abstract: A process for preparing polyisocyanate-modified polycarboxylic acids by conversion of anhydride-group-free polycarboxylic acids with isocyanate-functional compounds. The process includes reacting A) an anhydride-group-free polycarboxylic-acid component with B) an isocyanate-functional component having an (average) isocyanate functionality of at least 1.8, at an equivalent ratio of carboxylic acid groups to isocyanate groups of from 1.2:1 to 120:1. The polyisocyanate-modified polycarboxylic acids are solid below 40° C. and liquid above 130° C., and have an average carboxylic acid functionality of at least 1.8, a content of free carboxylic acid groups of from 4.0 wt. % to 80.0 wt. % and a content of amide groups of from 0.4 wt. % to 32.5 wt. %.Type: GrantFiled: June 21, 2004Date of Patent: February 12, 2008Assignee: Bayer MaterialScience AGInventors: Hans-Josef Laas, Christoph Gürtler, Reinhard Halpaap, Michael Grahl, Peter Thometzek, James Rawlins
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Patent number: 7323435Abstract: Fluorinated oligourethanes, having number average molecular weight lower than or equal to 9,000, having a branched structure, formed of the following monomers and macromers: a) aliphatic, cycloaliphatic or aromatic polyisocyanates, b) heterofunctional hydrogenated monomers having general formula: X0—(CR1AR2A)b—Y0 ??(Ib) one or more of the following compounds: c) bifunctional hydroxyl (per)fluoropolyethers (PFPE diols) having number average molecular weight in the range 400-3,000, e) monofunctional hydroxyl (per)fluoropolyethers or monofunctional hydroxyl (per)fluoroalkanes (e?), having number average molecular weight in the range 300-1,000, and optionally the following compounds: d) heterofunctional monomers, dI) hydrogen-active compounds, capable to form bonds with the NCO functions stable at the hydrolysis but weak at heat.Type: GrantFiled: June 12, 2000Date of Patent: January 29, 2008Assignee: Ausimont S.p.A.Inventors: Stefano Turri, Marinella Levi, Tania Trombetta
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Patent number: 7323532Abstract: The present invention concerns a process for producing low-viscosity polyisocyanates or secondary products thereof, which carry activated, radiation-curable double bonds and can optionally also cure thermally, and low-viscosity polyisocyanate mixtures or secondary products thereof and their use in coating compounds.Type: GrantFiled: September 29, 2003Date of Patent: January 29, 2008Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Jan Weikard, Wolfgang Fischer
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Patent number: 7307136Abstract: A polyisocyanate-based elastomer having a ratio of the storage modulus (E?) at 20° C. and the storage modulus (E?) at 120° C. of between 0.75 and 1.5, a tan ? at 100° C. of less than 0.1 and a maximum value of the tan ? of more than 0.8, the tan ? being the ratio of the loss modulus (E?) and the storage modulus (E?).Type: GrantFiled: February 4, 2002Date of Patent: December 11, 2007Assignee: Huntsman International LLCInventors: Gerhard Jozef Bleys, Alan James Hamilton, Jan Willem Leenslag
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Patent number: 7279505Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.Type: GrantFiled: October 5, 2005Date of Patent: October 9, 2007Assignee: Novartis AGInventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
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Patent number: 7253252Abstract: The present invention relates to new water-soluble polyaspartic esters and also to their use in aqueous coating compositions.Type: GrantFiled: July 11, 2005Date of Patent: August 7, 2007Assignee: Bayer MaterialScience AGInventors: Burkhard Köhler, Meike Niesten, Joachim Simon, Christian Wamprecht
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Patent number: 7253244Abstract: A one-pack polyurethane adhesive containing a polyisocyanate prepolymer and at least one aminoether polyol, having a molar ratio of ether groups to amino nitrogen in the aminopolyether polyol of 7 to 30.Type: GrantFiled: March 11, 2004Date of Patent: August 7, 2007Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernhard Gruenewaelder, Werner Haller, Bernhard Schoettmer, Thomas Empt, Hermann Kluth
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Patent number: 7252927Abstract: Disclosed is a composition which comprises a polymer containing at least some monomer repeat units with photosensitivity-imparting substituents which enable crosslinking or chain extension of the polymer upon exposure to actinic radiation, said polymer being of the formula wherein x is an integer of 0 or 1, A is one of several specified groups, such as B is one of several specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units, wherein said photosensitivity-imparting substituents are allyl ether groups, epoxy groups, or mixtures thereof. Also disclosed are a process for preparing a thermal ink jet printhead containing the aforementioned polymers and processes for preparing the aforementioned polymers.Type: GrantFiled: January 14, 2005Date of Patent: August 7, 2007Assignee: Xerox CorporationInventors: Ram S. Narang, Timothy J. Fuller
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Patent number: 7247695Abstract: Disclosed is a novel high 1,4-cis polybutadiene-polyurethane copolymer and a preparation method thereof. The present invention provides a high 1,4-cis polybutadiene-polyurethane copolymer represented by the following formula 1 and having an average molecular weight of at least 100,000, and a method for preparing the high 1,4-cis polybutadiene-polyurethane copolymer that includes polymerizing 1,3-butadiene or butadiene derivatives with a catalyst comprising a rare earth compound, a halogen-containing compound and an organoaluminum compound in the presence of a non-polar solvent, to prepare a polybutadiene having a high 1,4-cis content of at least 95%; and then introducing a polyurethane group to the polybutadiene.Type: GrantFiled: April 19, 2004Date of Patent: July 24, 2007Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Gwang Hoon Kwag, Sam Min Kim, Young Chan Jang, Pil Sung Kim, Seung Hwon Lee, Seung Hwa Lee, A Ju Kim
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Patent number: 7223801Abstract: A composition and method for protecting pipeline joints is disclosed. A mold covers the exposed pipeline joint. A reaction composition including a polyol, an isocyanate, and an ester, preferably 2,2,4-trimethyl-1,2-pentanediol diisobutyrate, is added to the mold and allowed to react to form a polymer.Type: GrantFiled: March 5, 2004Date of Patent: May 29, 2007Assignee: Baysystems North America LLCInventor: Scott A Brown
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Patent number: 7217761Abstract: The invention relates to the use of a compound with an alkylene oxide chain as a thickener of aqueous compositions, containing a filler and/or pigmented, white or colored, with the aim of supplying pigmentary compositions for paint which provide excellent pigmentary compatibility and a high viscosity at small and medium shear stress gradient. The invention also relates to the said non-ionic thickener as well as the aqueous composition, containing a filler and/or pigmented, white or colored, containing same.Type: GrantFiled: June 6, 2002Date of Patent: May 15, 2007Assignee: Coatex S.A.S.Inventors: Denis Ruhlmann, Jean-Marc Suau
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Patent number: 7211621Abstract: Polyurethaneurea resins containing at least one group of the formula (I) —NH(CO)XOR1O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—??(I) and/or at least one group of the formula (II) {—NH(CO)XO}a{CH2?CR2(CO)O}bR4{O(CO)CHR2CH2N[CnH2nSi(OR3)3](CO)NH—}c??(II) wherein X=[O(CH2)4]q(OC2H4)x(OC3H6)y[(CH2)5(CO)]z; q=0 to 10; x=0 to 20; y=0 to 20; z=0 to 10; n=2 or 3; a=1 or 2; b=0 to 4; c=1 to 5; R1=—C2H4—, —C3H6—, —C4H8—, —CH(CH2O(CO)R5)CH2— or —CH2CH(O(CO)R5)CH2—; R2=H or CH3; R3=C1 to C4 alkyl; R4=a+b+c-valent, saturated hydrocarbon residue of a (cyclo)alkane polyol with a+b+c hydroxyl groups; R5=an acid residue of a monocarboxylic acid, with the proviso that a+b+c=3 to 6 and wherein the sequence of the subformulae indicated q, x, y and z may be varied at will and q, x, y and z in each case merely state the number of instances of the particular subformulae contained in the formulae (I) and (II).Type: GrantFiled: February 11, 2004Date of Patent: May 1, 2007Assignee: E. I. du Pont de Nemours and CompanyInventors: Carmen Flosbach, Stefanie Matten
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Patent number: 7208560Abstract: A process for the preparation of urethane resins, which comprises the steps of: preparing a product (A) having a hydrolysable group directly bonded to 1–10 silicon atoms and having less than two secondary amino groups in one molecule; preparing a product (B) having a terminal isocyanate group in an amount 4% or less by weight of the product (B); and reacting the product (A) with the product (B) in proportions of at least 0.5 equivalent of the product (A) per free NCO group of the product (B). The process readily gives urethane resins, which exhibit excellent storage stability and are enhanced in the degrees of freedom of the physical properties of the products of curing.Type: GrantFiled: June 17, 1998Date of Patent: April 24, 2007Assignee: Konishi Co., Ltd.Inventors: Shinichi Sato, Akihiro Sato
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Patent number: 7205374Abstract: A method of preparing an adhesive, the method comprising combining an isocyanate, a polyhydroxyl phenol-containing compound, a polyol, and a trimerization catalyst.Type: GrantFiled: October 10, 2003Date of Patent: April 17, 2007Assignee: BFS Diversified Products, LLCInventors: John W. Fieldhouse, Joseph J. Kalwara, Edward G. Kane, John B. Letts
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Patent number: 7199207Abstract: A polyurethane prepolymer obtainable by reacting at least one aromatic polyisocyanate having symmetrical substitution of NCO groups and at least one aromatic polyisocyanate having asymmetric substitution of NCO groups, the fraction of aromatic polyisocyanate having symmetrical substitution of NCO groups being higher than the fraction of polyisocyanate having asymmetric substitution of NCO groups, and at least one polyol having an OH functionality of more than 2.5 and at least one polyol having an OH functionality of less than 2.5.Type: GrantFiled: November 12, 2004Date of Patent: April 3, 2007Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernhard Gruenewaelder, Werner Haller, Birgit Ness, Thomas Empt
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Patent number: 7193011Abstract: The present invention relates to a method of preparing water-dispersible poly (urethane-urea) having aliphatic-aromatic isocyanate, more particularly to a method of preparing water-dispersible poly (urethane-urea) having aliphatic-aromatic isocyanate, with improved mechanical/thermal properties, such as heat resistance, chemical resistance and adhesion, good cost competitiveness and environmental friendliness, by reacting polyester polyol, dimethylol propionic acid and an aromatic isocyanate compound to obtain a hydroxyl (OH)-terminated prepolymer, adding an aliphatic isocyanate compound to said OH-terminated prepolymer to obtain an isocyanate (NCO)-terminated prepolymer wherein aromatic-aliphatic isocyanate is hybridized, neutralizing, water-dispersing and chain extending said NCO-terminated prepolymer.Type: GrantFiled: June 24, 2004Date of Patent: March 20, 2007Assignee: Yonsei UniversityInventors: Jung Hyun Kim, In Woo Cheong, Kyoung Min Ahn
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Patent number: 7157519Abstract: A water-dispersible polyurethane resin comprising building blocks derived from polyisocyanates A, polyols B having a number-average molar mass Mn of at least 400 g/mol, where appropriate, low molar mass polyols C with Mn below 400 g/mol, compounds D which possess at least two groups which are reactive toward isocyanate groups and at least one group which is capable of forming anions, low molar mass polyols E which in relation to isocyanate groups carry no further reactive groups, compounds F, which are monofunctional toward isocyanates or contain active hydrogen of different reactivity and are different from the compounds E and also, where appropriate, compounds G, which are different from B, C, D, E and F and contain at least two groups which are reactive with NCO groups, wherein the number-average molar mass Mn of the polyurethane resin is at least 10 kg/mol, its weight-average molar mass Mw is at least 20 kg/mol, and its acid number is from 20 to 50 mg/g; a process for its preparation; and its use as a binType: GrantFiled: September 27, 2002Date of Patent: January 2, 2007Assignee: Solutia Austria GmbHInventors: Markus A. Schafheutle, Anton Arzt, Julius Burkl, Martina Glettler, Gerlinde Petritsch, Joerg Wango
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Patent number: 7151154Abstract: Graft polymer curatives comprise a side chain having an average molecular weight of at least about 500, a main chain having an average molecular weight of less than about 200, and diol functionality on the main chain. The graft polymer curative is formed via free radical polymerization of at least one ethylenically-unsaturated monomer with a chain transfer agent or initiator.Type: GrantFiled: January 13, 2004Date of Patent: December 19, 2006Assignee: Lexmark International, Inc.Inventors: Kelly A. Killeen, Jing X. Sun
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Patent number: 7148308Abstract: The present invention provides an one-part moisture-curable urethane composition which exhibits excellent adhesion particularly to a coated steel plate difficult to bond with no-primer and is useful in the bonding of automobile window glass. The urethane composition of the present invention comprises an isocyanate-terminated urethane prepolymer as the main component, and additional components comprising (A) a compound having solubility parameter value of 6.0 to 9.0 and/or (B) a compound having in the molecule at least one structure represented by the following formula: (wherein n is 0 to 3).Type: GrantFiled: October 1, 2002Date of Patent: December 12, 2006Assignee: Sunstar Giken Kabushiki KaishaInventors: Atsushi Inoue, Yoshinori Mayama, Yoshihiro Nakata
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Patent number: 7148310Abstract: The present invention is directed to a multiple component coating composition comprising (a) a film forming binder component having isocyanate reactive groups; (b) a stable polyisocyanate solution comprising organic liquid and up to 30% by weight, based on the weight of the polyisocyanate solution, of a polyisocyanate having reactive isocyanate groups selected from an aromatic polyisocyanate having tertiary isocyanate groups or a (meth)acrylic polymer containing reactive isocyanate groups; and (c) optionally, a tinting composition comprising pigment, a dispersing agent and an organic liquid carrier; whereby components (a), (b) and (c) are blended together before application to a substrate and after application to a substrate the composition is cured to form a finish. The present invention is also directed to a method of producing a finish on a substrate and to the resulting coated substrate.Type: GrantFiled: August 13, 2004Date of Patent: December 12, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert John Barsotti, Christopher Scopazzi, Douglas Matt Lamb
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Patent number: 7148287Abstract: Compositions incorporating water-curable urethane constituent(s) are formulated with favorable viscosity and viscosity stability characteristics, while at the same time, preserving desired hardness characteristics. The present invention is particularly useful in applications in which water-curable compositions include NCO-functional resins having relatively high NCO content and/or incorporate MDI-based constituents. Preferred modes of practicing the invention include implementing one or more formulation strategies to help retain hardness while preserving good viscosity characteristics. These preferred strategies involve (i) balancing scavenger, polyisocyanate and polyfunctional polyol content of the compositions or resins thereof, as the case may be, (ii) formulating an NCO-functional resin with chain extender constituent(s) to enhance viscosity stability, (iii) formulating with one or more plasticizers that enhance viscosity performance, and (iv) combinations of two or more of these strategies.Type: GrantFiled: May 13, 2004Date of Patent: December 12, 2006Inventor: Laxmi C. Gupta
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Patent number: 7144955Abstract: Solvent-based, dual cure coatings incorporating thermally curable blocked polyisocyanates, which also contain unsaturated linkages, and a method for preparing these coatings. The unsaturated linkages, such as acrylate groups, can be crosslinked by free-radical mechanisms such as UV curing.Type: GrantFiled: October 27, 2003Date of Patent: December 5, 2006Assignees: Bayer MaterialScience LLC, Bayer MaterialScience AGInventors: Scott A. Grace, Michael J. Dvorchak, Richard R. Roesler, Dinesh Pethiyagoda, Michael K. Jeffries, Jan Weikard
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Patent number: 7138466Abstract: High green strength reactive hot melt adhesives are prepared using relatively low levels of reactive acrylic, and may be prepared with one or more difunctionals having cyclic or polycyclic structures.Type: GrantFiled: April 6, 2004Date of Patent: November 21, 2006Assignee: National Starch and Chemical Investment Holding CorporationInventors: Ju-Ming Hung, Yue S. Zhang, Yimin Zhang, Zhixin Li
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Patent number: 7135128Abstract: At least one isocyanate-reactive monomer is reacted with an excess of molten monomeric diisocynate to produce at least one reaction product and a maximum of 0.5 wt % of free isocyanate groups. The reaction product is then mixed with at least 20 wt. %, based on the total weight of reaction product, of at least one isocyanate-terminated prepolymer which is essentially free of diisocyanate monomers and has a viscosity at 20° C. of at least 1.500 mPa·s, the isocyanate-terminated prepolymer having a content of free NCO groups of up to 25 wt % and containing a maximum of 0.1 wt. % of diisocyanate monomer(s) based on the weight of the isocyanate-terminated prepolymer. A polyurethane composition containing less than 0.1 wt. % of monomeric diisocyanate, based on the total weight of the resulting polyurethane composition, is produced.Type: GrantFiled: February 21, 2003Date of Patent: November 14, 2006Assignee: Jowat AGInventors: Theodor Hippold, Dieter Guse, Christian Terfloth
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Patent number: 7129312Abstract: Polyurethane compositions are produced in a two-stage method. In a first step, a diol component with a molecular weight of less than 2000 is reacted with a monomeric diisocyanate with a molecular weight of less than 500 and the unreacted monomeric diisocyanate is removed from this reaction product. In a second step, the resulting high-molecular diisocyanate is reacted with a polyol to produce a reactive prepolymer with isocyanate and groups. The addition of polyisocyanates which are capable of migration and which have a substantially lower vapor pressure than diphenylmethanediisocyanate, improves the addition behavior of the invention polyurethane compositions. Reactive polyurethane compositions of this type are suitable for using as binding agents for reactive one or two component adhesives/sealants, which may optionally contain solvents. These compositions are also suitable for producing reactive hot melt adhesives when suitable polyols are selected.Type: GrantFiled: November 25, 2000Date of Patent: October 31, 2006Assignee: Henkel Kommanditgesellschaft Auf Aktien (Henkel KGAA)Inventors: Michael Krebs, Christoph Lohr, Andreas Brenger
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Patent number: 7101950Abstract: The invention is an composition comprising a) one or more isocyanate functional polyether based prepolymers; b) one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of from about 45 to about 59° C.; c) one or more polyisocyanates having a nominal functionality of about 3 or greater; d) one or more nonconductive carbon blacks; e) one or more catalysts for the reaction of isocyanates moieties with hydroxyl groups. In a preferred embodiment the composition of the invention further comprises one or more isocyanate functional polyester prepolymers wherein the one or more polyesters used to prepare the prepolymers having melting points of about 60 to about 90° C.Type: GrantFiled: August 19, 2004Date of Patent: September 5, 2006Assignee: Dow Global Technologies Inc.Inventors: Lirong Zhou, Daniel P. Heberer
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Patent number: 7078442Abstract: A composition and method for consolidating aggregate material is disclosed. The method includes introducing a reaction composition into the aggregate material and allowing it to reach on form a polymer which binds the aggregate together. The composition includes polyol, isocyanate, and ester.Type: GrantFiled: March 5, 2004Date of Patent: July 18, 2006Assignee: Baysystems North America LLCInventor: Scott A Brown
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Patent number: 7074850Abstract: The invention relates to polyurethane block copolymers of general formula (I) to (IV), in which the variables are defined as follows: A represents a polyurethane block, which contains at least one hydrophilic group, B is a hydrophobic polyurethane block, X1, X2 are hydrophilic end groups and n is a whole number from 1 to 20. The invention also relates to the production of cross-linkable dispersion additives from the inventive polyurethane block copolymers and to the use of said cross-linkable dispersion additives for colorant preparations, in particular inks for ink-jet printing.Type: GrantFiled: September 14, 2002Date of Patent: July 11, 2006Assignee: BASF AktiengesellschaftInventors: Ulrike Hees, Sophia Ebert, Ruediger Sens, Friedrich-Wilhelm Raulfs, Hans-Guenter Bohrmann, Lothar Schulz, Heinz Heissler, Johann Mueller, Karl Siemensmeyer, Guenter Renz
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Polyurethane elastomers having improved physical properties and a process for the production thereof
Patent number: 7045650Abstract: A polyol composition having a number average molecular weight of from about 1,000 to about 3,000 Daltons is made up of (1) at least 60% by weight of a low monol polyoxypropylene polyol having a number average molecular weight of from about 2,000 to 12,000 Da and a degree of unsaturation less than or equal to 0.02 meq/g and (2) no more than 40% by weight of a polyol having a number average molecular weight of from about 400 to about 1,000 Da and a polydispersity index greater than 1.1. This polyol composition is reacted with a diisocyanate, a polyisocyanate, an isocyanate-terminated prepolymer or an isocyanate-terminated quasi-prepolymer to produce polyurethane elastomers having good physical and mechanical properties. Any of the known processes for producing polyurethane elastomers, including one-shot processes, may be used to produce elastomers in accordance with the present invention.Type: GrantFiled: September 2, 2004Date of Patent: May 16, 2006Assignee: Bayer Materialscience LLCInventors: Bruce D. Lawrey, Kurt C. Frisch, Nigel Barksby -
Patent number: 7038003Abstract: A process for preparing polyisocyanate prepolymers containing allophanate structural units that includes reacting a) one or more polyisocyanates with b) one or more polyetherpolyols containing less than or equal to 0.02 milliequivalent of unsaturated end groups per gram of polyol and having a polydispersity of from 1.0 to 1.5 and/or an OH functionality of greater than or equal to 1.9 ?to provide an NCO-functional polyurethane prepolymer containing urethane groups that are partly or fully allophanatized by further reaction with c) polyisocyanates, which may be different from those from a), and d) catalysts and optionally adding e) acidic additives before, during and/or after the allophanatization. The polyisocyanate prepolymers can be used to produce coatings, adhesive bonds and/or seals. The coatings include one or more of the polyisocyanate prepolymers, and at least one diol or polyol and/or at least one linear and/or cyclic, aliphatic, araliphatic and/or aromatic diamine or polyamine.Type: GrantFiled: March 23, 2005Date of Patent: May 2, 2006Assignee: Bayer MaterialScience AGInventors: Michael Mager, Joachim Simon, Malte Homann
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Patent number: 7034097Abstract: Polyurethane elastomers are formed from first and second graft curatives, each graft curative having a molecular weight of at least about 800, wherein the first and second graft curatives are substantially immiscible with one another, and wherein the polyurethane elastomer exhibits a hardness of less than about 40 Shore A according to ASTM D2240-86 and a compression set of less than about 8% according to ASTM D395-89, method B, at a temperature of about 70° C. for about 22 hours. Rolls are manufactured using such polyurethane elastomers, particularly rolls that are suitable for use in image forming devices, such as electrophotographic print applications.Type: GrantFiled: January 13, 2004Date of Patent: April 25, 2006Assignee: Lexmark International, Inc.Inventors: Bradley L. Beach, Bhaskar Gopalanarayanan, Kelly A. Killeen, Johnny D. Massie, II, Ronald L. Roe
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Patent number: 7022804Abstract: The invention relates to a moisture-crosslinkable hot-melt adhesive which is composed of a polyurethane prepolymer obtained by polyaddition of at least one polyol to at least one isocyanate chosen from the group of diisocyanates trimerized as isocyanurates and reaction products of diisocyanates with water, the prepolymer having a content of free NCO group of between 1 and 25% by weight. The adhesive according to the invention may be used for the adhesive bonding of fixing components of the Velcro® type to articles intended for hygiene.Type: GrantFiled: June 4, 2003Date of Patent: April 4, 2006Assignee: Bostik SAInventors: Michel Miskovic, François Bauduin, Patrick Bouttefort, Jean-François Chartrel
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Patent number: 7015299Abstract: Melt spun thermoplastic polyurethane polymers useful as textile fibers and having good tenacity and recovery and substantially no gelation are disclosed. The polymers are prepared by a three-step polymerization process including: preparation of “hard” segment oligomer, preparation of “soft” segment oligomer and final reaction of “hard” segment with “soft” segment in a twin-screw reaction extruder to obtain a final polyurethane product having relatively uniform distances between the “hard” segments. The “soft” segment oligomer comprises blocks of polymeric glycol (poly) urethanes end capped with isocyanate groups. The “hard” segment oligomer comprises blocks of low molecular weight C2–C6 glycol (poly) urethanes.Type: GrantFiled: April 30, 2001Date of Patent: March 21, 2006Inventor: W. Kenneth Wilkinson
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Patent number: 7005477Abstract: A one component moisture-curing polyurethane adhesive composition having a long pot life that does not cause its user to experience breathing difficulty is described. In one embodiment the adhesive is prepared from a mixture of a high molecular weight component selected from the group consisting of polyols, diamines, and mixtures thereof; an isocyanate; and a low molecular weight component selected from the group consisting of diols, diamines, and mixtures thereof.Type: GrantFiled: May 16, 2002Date of Patent: February 28, 2006Assignee: MCP Industries, Inc.Inventors: Thomas M. Garrett, Xian Xian Du
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Patent number: 7005482Abstract: A self-supporting reactive hot-melt adhesive element of a reactive one-component hot-melt adhesive which is solid at room-temperature. The adhesive element comprises at least one isocyanate being solid or liquid at room-temperature; and at least one isocyanate-reactive polymer and/or resin being solid at room-temperature. Also disclosed is a process of producing said adhesive element as well as its application and use, in particular in a hot-melt adhesive bonding process.Type: GrantFiled: February 8, 2002Date of Patent: February 28, 2006Assignee: Jowat Lobers und Frank GmbH & Co. KGInventors: Dieter Guse, Theodor Hippold, Christian Terfloth
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Patent number: 7001975Abstract: A hydrophilic or hydrophobic polyurethane containing on average per molecule at least one olefinically unsaturated structural unit selected from the group consisting of pendant, internal, and terminal, acyclic and cyclic terpene units; graft copolymers of the polyurethane with olefinically unsaturated monomers, processes for preparing the polyurethane and the graft copolymers, and their use for preparing coating materials, adhesives, and sealing compounds.Type: GrantFiled: September 12, 2002Date of Patent: February 21, 2006Assignee: BASF Coatings AGInventors: Wolfgang Bremser, Thomas Krüger, Wilma Löcken, Peter-Heinz Rink, Stephan Schwarte
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Patent number: 6997997Abstract: A method is provided for preparing thermoplastic elastomers. A blocks of the thermoplastic elastomers are crystalline at temperatures below about 60° C. and are derived from oxetane derivatives and/or tetrahydrofuran derivatives. B blocks of the thermoplastic elastomer are amorphous above about ?20° C. and are derived from oxetanes, tetrahydrofuran, oxiranes, and derivatives thereof. According to this method, the A and B blocks are dissolved into solution containing a non-halogenated solvent, preferably tetrahydrofuran, then dried by azeotropic distillation. The dried blocks are end-capped with a diisocyanate, preferably a diisocyanate having one isocyanate moiety substantially more reactive with the terminal groups of the blocks than the other isocyanate moiety of the diisocyanate. The end-capped blocks are then linked together with a linking compound.Type: GrantFiled: November 9, 1999Date of Patent: February 14, 2006Assignee: Alliant Techsystems Inc.Inventors: Andrew J. Sanderson, Wayne W. Edwards
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Patent number: 6995192Abstract: The present invention provides a radiation-curable prepolymer. The radiation-curable prepolymer of the invention is prepared by reacting an isocyanate-capped polyurethane with an ethylenically unsaturated amine or an ethylenically unsaturated monohydroxy compound or a mixture thereof, wherein the isocyanate-capped polyurethane is a copolymerization production of: (a) at least one polyalkylene glycol; (b) at least one branching agent having at least three hydroxy groups; and (c) at least one di- or polyisocyanate. The radiation-curable prepolymer of the invention can find use in economically producing contact lenses which have durable, highly elastic soft contact lenses with desired physical properties. In addition, the present invention provides method for making a radiation-curable prepolymer of the invention and for making a medical device, preferably an ophthalmic device, more preferably a contact lens.Type: GrantFiled: August 13, 2003Date of Patent: February 7, 2006Assignee: Novartis AGInventors: John Christopher Phelan, Michael Hugh Quinn, Joshua Andrew Wallach
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Patent number: 6992164Abstract: In a uniformly copolymerized one-part polyurethane resin composition with improved processing behaviors and chemical resistance, the one-part polyurethane resin composition comprises about 20 to 50% by weight of a hard segment and about 50 to 80% by weight of a soft segment. The hard segment reduces drying time and recoating time of a film coated by the composition, and the soft segment improves processing behaviors of the film including rolling and spraying properties. The one-part polyurethane resin composition may further comprise a catalyst. The catalyst may regulate film drying time and improve gloss of a coated film. Thus, the resin composition may be applied in various fields.Type: GrantFiled: June 27, 2003Date of Patent: January 31, 2006Assignee: DPI Co., Ltd.Inventors: Ju-Kil Lee, Hee-Jong Kim
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Patent number: 6977290Abstract: The present invention relates to a method for preparing oligomeric aliphatic diols, polycarbonatediols based thereon and NCO-terminated prepolymers obtainable therefrom. The inventive compounds may find use in the preparation of polyurethanes.Type: GrantFiled: January 22, 2004Date of Patent: December 20, 2005Assignee: Bayer AktiengesellschaftInventors: Hartmut Nefzger, Erika Bauer, Manfred Schmidt, Hans-Dieter Ruprecht, James-Michael Barnes