Phenolic Reactant Contains At Least One Nitrogen, Phosphorus, Or Sulfur Atom Patents (Class 528/99)
  • Patent number: 4250293
    Abstract: This invention relates to epoxy powder coatings which have excellent shelf life at ambient temperature (70.degree. F.) with excellent cure rates at curing temperatures, the epoxy resin containing a latent amine salt of bis-phenol A, the amine represented by the formula: ##STR1## wherein n is 2 or 3, and R is a C.sub.1 -C.sub.4 alkyl group.
    Type: Grant
    Filed: March 19, 1979
    Date of Patent: February 10, 1981
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Burton D. Beitchman, Donald E. Jefferson, John P. Seymour
  • Patent number: 4237149
    Abstract: For manufacturing molded and impregnated parts from epoxy resin compositions, a reactive epoxy resin is employed which hardens more slowly at higher temperatures (120.degree. to 180.degree. C.) than at lower temperatures (80.degree. to 110.degree. C.). The reactive epoxy resin composition is applied at the higher temperature and subsequently hardened at the lower temperature.According to the method of the invention, molded parts (e.g., solution pump heads), cast-in electrical components (e.g., four-ring stray field electrodes) and impregnated parts are manufactured.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: December 2, 1980
    Assignee: Siemens Aktiengesellschaft
    Inventors: Hans Denk, Reiner Habrich
  • Patent number: 4230552
    Abstract: A polymeric product suitble for use as a pigment grinding vehicle is disclosed. The polymeric product is the reaction product of an organic polyepoxide and an organic amine containing an alkylarylpolyether moiety.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: October 28, 1980
    Assignee: PPG Industries, Inc.
    Inventors: Karl F. Schimmel, Lance C. Sturni, Martin J. Robles
  • Patent number: 4229563
    Abstract: Epoxy resins are cured with an amine adduct of orthohydroxybenzoic acid of the formula: ##STR1## where x is from 2 to about 8.
    Type: Grant
    Filed: August 3, 1979
    Date of Patent: October 21, 1980
    Assignee: Ameron, Inc.
    Inventors: Raymond E. Foscante, Albert P. Gysegem, Pamela J. Martinich
  • Patent number: 4200726
    Abstract: A semipermeable membrane composed of a water-insoluble, membrane-forming polymer (hereinafter referred to as "polymer (II)") which is obtained by partially converting the hydroxyl groups of a polymer represented by the following formula (hereinafter referred to as "polymer (I)"): ##STR1## wherein R and R' are halogen, nitro, methyl or ethyl, X stands for a divalent group selected from methylene, ethylene, isopropylidene, ether (--O--), carbonyl (--CO--), sulfide (--S--), sulfoxide (--SO--) and sulfone (--SO.sub.2 --), l and m are integers of from 0 to 4, p is 0 or 1, and n is an integer of from 100 to 1000,to sulfuric acid groups or alkali metal, ammonium or nitrogen-containing basic organic compound salts thereof.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: April 29, 1980
    Assignee: Daicel Ltd.
    Inventors: Kiyoshi Ishii, Ryoshu Suzuki, Zenjiro Honda, Hitoshi Tsugaya
  • Patent number: 4196066
    Abstract: A cured or uncured linear aromatic polyester composition melt-blended and composed of(A) 100 parts by weight of a saturated linear aromatic polyester in which at least 70 mole % of the acid component consists of an aromatic dicarboxylic acid, and(B) 0.1 to 50 parts by weight of a reactive compound which is solid at room temperature or is a liquid having a boiling point of at least 200.degree. C. under atmospheric pressure, and which contains in its molecule at least one aliphatic unsaturated group substantially non-reactive with the polyester (A) and the aliphatic unsaturated group of the reactive compound (B) under conditions of melt-blending with the polyester (A) and at least one epoxy group reactive with the polyester (A) under the melt-blending conditions. The cured linear aromatic polyester composition can be prepared by extruding the uncured linear aromatic polyester composition under melting conditions, and subjecting the resulting extrudate to a curing treatment.
    Type: Grant
    Filed: June 30, 1978
    Date of Patent: April 1, 1980
    Assignee: Teijin Limited
    Inventors: Hiroo Inata, Makoto Ogasawara, Tsuto Morinaga, Akihiro Norike
  • Patent number: 4195152
    Abstract: There is disclosed a class of N-alkylpolyamines and their use as curing agents for epoxy resins, and in particular to such polyamines having the formula R--[NH(CH.sub.2).sub.x ].sub.y --NHR' where R is an aliphatic hydrocarbon radical having from 5 through 8 carbon atoms, R' is H, R or R", x is an integer of 2 or 3 and y is an integer of 2-4. A monoepoxide adduct of the monoalkyl substituted polyamine is also disclosed wherein R" may then become an aliphatic substituent (2-14 carbon atoms) which may contain (a) an oxygen atom, (b) a hydroxyl group or (c) an aromatic substituent such as a phenyl ring.
    Type: Grant
    Filed: July 20, 1978
    Date of Patent: March 25, 1980
    Assignee: Henkel Corporation
    Inventor: Don E. Floyd
  • Patent number: 4195154
    Abstract: The title compounds are of the formula: ##STR1## wherein R is a chemical bond, oxygen, sulfur, alkylene or alkylidene; W is hydrogen or a (--CR.sub.1 R.sub.2 --CR.sub.3 R.sub.4 --NHR.sub.5) group with the proviso that at least two W groups are (--CH.sub.1 R.sub.2 --CR.sub.3 R.sub.4 --NHR.sub.5) groups; wherein R.sub.1 -R.sub.4 are each independently hydrogen, lower alkyl or hydroxy-substituted lower alkyl; R.sub.5 is hydrogen or a ##STR2## group, wherein R.sub.6 is hydrogen, hydrocarbyl or inertly substituted hydrocarbyl; X, Y and Z are each independently inert substituents; m and p are each independently integers of from zero to four, inclusive; n is an integer of from zero to three, inclusive; q is a number of from zero to about ten; and M is alkylene or alkylidene. They are conveniently prepared by reacting a 2-oxazoline of the formula: ##STR3## with a polyhydric polyphenol of the formula: ##STR4## in the presence of certain metal salt catalysts (e.g. zinc acetate).
    Type: Grant
    Filed: August 15, 1977
    Date of Patent: March 25, 1980
    Assignee: The Dow Chemical Company
    Inventors: Mark E. Kaiser, Harry A. Smith
  • Patent number: 4185132
    Abstract: The disclosed coating method has the ability to satisfy some or all of the very troublesome requirements of highway marking or striping and is therefore useful to mark or stripe paved surfaces. The method involves:(a) supplying to the point of application an amine co-curative which includes an aliphatic amine (e.g. trimethyl hexamethylene diamine) and a cycloaliphatic amine (e.g. cyclohexane-bis[methylamine]);(b) supplying to the point of application a suitable curable liquid vicinal epoxide composition;(c) applying the co-curative and the liquid epoxide to the paved surface (preferably after intimately mixing the co-curative and the liquid epoxide); and(d) permitting the resulting mixture to cure in situ on the paved surface.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: January 22, 1980
    Assignee: H. B. Fuller Company
    Inventor: Richard S. Gurney
  • Patent number: 4183869
    Abstract: Novel thermosetting oligomers are formed by reacting epoxy prepolymers with aminoarylacetylenes. When heated to 170.degree. C. or above, these oligomers undergo acetylenic polymerization to form resins which exhibit superior thermal and hydrolytic stability when compared to conventionally cured epoxy resins.
    Type: Grant
    Filed: August 4, 1978
    Date of Patent: January 15, 1980
    Assignee: Hughes Aircraft Company
    Inventor: Norman Bilow
  • Patent number: 4163098
    Abstract: The coating compound according to the invention contains an epoxide resin, a diprimary amine curing agent and as modifier a hydrazone of the formula ##STR1## wherein the radical R.sup.1 -R.sup.4 represent hydrogen or alkyl, provides after curing coatings having a smooth, lustrous and glass-like surface which has a good resistence to chemicals.
    Type: Grant
    Filed: August 30, 1978
    Date of Patent: July 31, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Helmut Zondler, Wolfgang Schneider
  • Patent number: 4152285
    Abstract: The present invention relates to curing agents for epoxy resins. More particularly, the present invention relates to water soluble or water-dispersible curing agents which are mixed with water dispersed or water emulsified epoxy resins to form coating compositions which are essentially free of volatile organic solvents or cosolvents and which have extended pot life at room temperature, but which cure under ambient conditions in less than 24 hours.
    Type: Grant
    Filed: December 12, 1975
    Date of Patent: May 1, 1979
    Inventor: Ivar P. Thomassen
  • Patent number: 4142034
    Abstract: Epoxy resin compositions comprising a) a 1,2-epoxide compound containing two or more 1,2-epoxide groups per molecule, b) a cyanic acid ester having two or more cyanic ester groups per molecule, and c) an organic amine are provided.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: February 27, 1979
    Assignee: Cincinnati Milacron Inc.
    Inventor: Gene E. Schroll
  • Patent number: 4136086
    Abstract: Curable mixtures of (a) epoxide compounds, (b) adducts containing mercapto groups, which adducts are produced by an advancement reaction of dimercapto compounds with diglycidyl compounds in an amount less than the equivalent amount, and (c) carboxylic anhydrides. The curable mixtures are suitable as casting resin mixtures, particularly for producing moulded articles of large volume.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: January 23, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Dieter Baumann, Heinz Rembold
  • Patent number: 4132706
    Abstract: The trisubstituted (2,5-dihydroxyphenyl)phosphonium hydroxide inner salts and their hydrolyzed derivatives are novel latent catalysts for promoting reaction between vicinal epoxides and phenols and/or carboxylic acids (or anhydrides). Precatalyzed epoxy resins are easily prepared using such catalysts.
    Type: Grant
    Filed: April 5, 1976
    Date of Patent: January 2, 1979
    Assignee: The Dow Chemical Company
    Inventors: George A. Doorakian, Lawrence G. Duquette
  • Patent number: 4129556
    Abstract: Curable mixtures containing (a) a polyepoxide compound having on average more than one epoxide group per molecule and (b) a diamine which contains hydroxyl groups and has the general formula Ia or Ib ##STR1## IN WHICH R is an alkyl radical having 2 to 16 C atoms, an aralkylene radical having 7 to 12 C atoms, an arylene radical having 6 to 16 C atoms, a cycloaliphatic radical having 6 to 12 C atoms or a radical containing at least one N, O or S atom in chains or cyclic groups, and R.sub.1 is a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 C atoms and in which, in formula Ia, the two OH groups are in the orthoposition or para-position relative to the methylene group, there being, in the mixtures, 0.5 to 1.5 equivalents of active hydrogen atoms, which are bonded to nitrogen and oxygen in the diamine containing hydroxyl groups, per 1 equivalent of epoxide groups.
    Type: Grant
    Filed: December 2, 1977
    Date of Patent: December 12, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Helmut Zondler, Roland Moser
  • Patent number: 4119592
    Abstract: Rubbery bladders are produced by rotational casting a liquid polymer composition containing (1) an epoxy resin, (2) a liquid carboxyl-terminated polymer, (3) an amine, (4) a dihydric compound, and (5) a plasticizer. In order to obtain the desired flex and tear properties, the equivalent ratio of the other reactants to epoxy must be from about 0.70 to about 1.15. The valve area of the bladder is reinforced with a spun bonded fabric.
    Type: Grant
    Filed: February 25, 1977
    Date of Patent: October 10, 1978
    Assignee: The B. F. Goodrich Company
    Inventor: Walter Thomas Murphy
  • Patent number: 4119609
    Abstract: Adducts of epoxy compounds with amino-substituted aromatic carboxylic acids are described. These carboxyl-containing adducts may be cured with conventional epoxy curing agents or solubilized to prepare aqueous coating systems.
    Type: Grant
    Filed: March 28, 1977
    Date of Patent: October 10, 1978
    Assignee: Shell Oil Company
    Inventors: Roy A. Allen, LeRoy W. Scott
  • Patent number: 4115296
    Abstract: To accelerate the curing of epoxide resins by particular curing agents, i.e., polyamines, polyaminoamides, polycarboxylic acids, or polycarboxylic acid anhydrides, there is employed an aliphatic or araliphatic monocarboxylic acid group at least two halogen atoms chosen from fluorine and chlorine atoms, or a salt thereof, such as magnesium trifluoroacetate and magnesium trichloroacetate.
    Type: Grant
    Filed: December 16, 1976
    Date of Patent: September 19, 1978
    Assignee: Ciba-Geigy Corporation
    Inventor: Christopher Michael Andrews
  • Patent number: 4113541
    Abstract: An improved method of bonding is disclosed using an epoxy resin composition which incorporates a select group of chlorine-containing polyols.
    Type: Grant
    Filed: June 17, 1977
    Date of Patent: September 12, 1978
    Assignee: Olin Corporation
    Inventors: Richard J. Turley, Alexandre Ozolins
  • Patent number: 4111771
    Abstract: New crosslinkable tetra-imidyl derivatives are described which are obtained by reaction of 3,5-bis-imidylphthalic acid derivatives, e.g. 3,5-bis-maleimidyl-phthalic acid anhydride, with monomeric, oligomeric or polymeric diamines. The new crosslinkable tetra-imidyl derivatives are suitable for the production of various shaped articles, such as coating compositions and mouldings, and are distinguished by their good crosslinking properties.
    Type: Grant
    Filed: December 6, 1976
    Date of Patent: September 5, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland Darms, Vratislav Kvita, Gerd Greber
  • Patent number: 4098769
    Abstract: Linear copolyesters formed from (A) isophthalic acid and, optionally, terephthalic acid and (B) bis(4-beta-hydroxyethoxyphenyl) sulfone and ethylene glycol are described. The linear polyesters contemplated have glass transition temperatures higher than that of poly(ethylene terephthalate) and oxygen and CO.sub.2 permabilities less than that of poly(ethylene terephthalate).
    Type: Grant
    Filed: July 5, 1977
    Date of Patent: July 4, 1978
    Assignee: Owens-Illinois, Inc.
    Inventor: Santos W. Go