Metal Containing Patents (Class 536/101)
  • Patent number: 10252943
    Abstract: Provided are a cement mortar additive for extrusion molding, a cement mortar for extrusion molding, and an extrusion-molded product. The disclosed cement mortar additive for extrusion molding includes hydrogelated cellulose ether.
    Type: Grant
    Filed: May 8, 2015
    Date of Patent: April 9, 2019
    Assignee: LOTTE FINE CHEMICAL CO., LTD.
    Inventors: Bon Hyeok Gu, Tae Hong Kim, Won Hee Lee, Min Seok Kang, Myung Jae Lee, Myeong Ho Jeon, Gyu Chul Lee
  • Patent number: 10059846
    Abstract: The present invention relates to a process for preparing an aqueous suspension comprising a mineral pigment material and a depolymerized carboxymethylcellulose having a degree of carboxylation in the range from 0.2 to 2.2, a molecular weight in the range from 5000 to 40000 g/mol, and a polydispersity index in the range from 2 to 10.
    Type: Grant
    Filed: October 24, 2014
    Date of Patent: August 28, 2018
    Assignee: Omya International AG
    Inventors: Samuel Rentsch, Matthias Buri, Fabio Ippolito, Patrick A. C. Gane
  • Patent number: 9603867
    Abstract: A pharmaceutical composition for improving wound healing is provided. The pharmaceutical composition includes (a) hyaluronic acid or its derivation, (b) an effective amount of an active ingredient; and optionally (c) pharmaceutically acceptable carriers and/or excipients. In one embodiment, the active ingredient includes vitamin. In another embodiment, the active ingredient includes acexamic acid. In still another embodiment, the pharmaceutical composition can further comprise sorbic acid.
    Type: Grant
    Filed: March 3, 2015
    Date of Patent: March 28, 2017
    Assignee: YUNG SHIN PHARM. IND. CO., LTD.
    Inventors: Chiung-Ju Tsai, Yen-Ling Yi, Man-Hsin Wang, Shih-Lung Chang, Chia-Chun Lee
  • Patent number: 9534061
    Abstract: The invention is an efficient method for preparing alkali cellulose having the low water content and a uniform alkali distribution therein. More specifically, the invention is a method for continuously preparing alkali cellulose comprising steps of bringing pulp into continuous contact with an alkali metal hydroxide solution to generate a contact mixture and then draining the contact mixture by a centrifugal separator. The invention also includes a method for preparing cellulose ether comprising a step of etherifying the alkali cellulose.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: January 3, 2017
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuo Narita, Masaki Tabata, Atsushi Yoshida, Hiroshi Umezawa
  • Patent number: 9475887
    Abstract: A novel compound is disclosed, said compound comprising hyaluronic acid, optionally cross-linked, or an oligomer, optionally cross-linked, dimer or monomer thereof, which is salified or at least partially salified with carnosine, wherein the carnosine is in the form of an L- or D-enantiomer or a racemate; a process for producing this compound, its cosmetic and therapeutic use as well as pharmaceutical and cosmetic compositions containing the same are also disclosed.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: October 25, 2016
    Inventor: Gianfranco De Paoli Ambrosi
  • Publication number: 20150141531
    Abstract: The instant disclosure relates to a process for manufacturing a fibrillated cellulose powder suitable for being dispersed in an aqueous medium, comprising a step of adding a monovalent salt to a fibrillated cellulose suspension, followed by a lyophilisation step.
    Type: Application
    Filed: June 24, 2013
    Publication date: May 21, 2015
    Inventors: Julien Bras, Naceur Belgacem, Karim Missoum
  • Patent number: 8901290
    Abstract: A new method to control the dispersibility of dried nanocrystalline cellulose (NCC) by controlling solution pH and ionic strength is provided; when stable, non-reswellable acid-form NCC (H-NCC) films are placed in concentrated sodium hydroxide solutions, they swell but do not disperse; while sodium-form NCC (Na-NCC) or other NCC films having neutral monovalent counterions readily disperse in pure water, Na-NCC films placed in hydrochloric acid and sodium chloride as well as sodium hydroxide solutions of sufficient ionic strength swell, but do not disperse; similar properties are observed for freeze-dried NCC products. The dispersibility of these NCC films is a function of the ionic strength and the identity of the electrolyte solutions to which they are exposed. NCC films are envisaged that have barrier properties in an electrolyte solution but that disintegrate or disperse when rinsed with pure water at the end of their useful lifespan.
    Type: Grant
    Filed: December 10, 2009
    Date of Patent: December 2, 2014
    Assignee: Fpinnovations
    Inventors: Stephanie Beck, Jean Bouchard, Richard Berry, Joseph Donat Louis Godbout
  • Patent number: 8864943
    Abstract: Provided is a method for preparing nonionic water-soluble cellulose ether having low insoluble content and providing a transparent solution. More specifically, provided is a method for preparing nonionic water-soluble cellulose ether comprising at least the steps of: drying a pulp sheet or pulp chips into which the pulp sheet has been converted, bringing the dried pulp sheet or pulp chips into contact with an alkali metal hydroxide solution to obtain alkali cellulose, draining the alkali cellulose, and reacting the drained alkali cellulose with an etherifying agent.
    Type: Grant
    Filed: August 28, 2012
    Date of Patent: October 21, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Mitsuo Narita
  • Patent number: 8859758
    Abstract: The present invention relates to a process for producing a water-absorbent polysaccharide including the process steps of bringing into contact an uncrosslinked polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel and crosslinking the polysaccharide gel. The invention further relates to a water-absorbent polysaccharide obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the water-absorbent polysaccharides or of the composites as well as the use of polyphosphates.
    Type: Grant
    Filed: September 12, 2013
    Date of Patent: October 14, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Markus Frank, Frank Loeker, Dirk Magolei, Scott J. Smith
  • Publication number: 20140213764
    Abstract: Nanocellulose foams containing at least one active ingredient and methods of preparing such nanocellulose foams containing one or more active ingredients are provided herein. In some embodiments, a method for preparing nanocellulose foam containing active ingredients may include forming a liquid mixture of nanocellulose, wherein the nanocellulose is at least one of dispersed, suspended or gelled in the liquid mixture; drying the liquid mixture of nanocellulose to form a nanocellulose foam; and mixing at least one active ingredient into at least one of the liquid mixture of nanocellulose or the nanocellulose foam. In some embodiments, a nanocellulose structure may include a nanocellulose foam comprising at least one of a carboxylate group, a hydroxyl group, or a sulfate group bonded to an active ingredient. In some embodiments, the nanocellulose structures are enhanced or crosslinked with metal cations.
    Type: Application
    Filed: March 31, 2014
    Publication date: July 31, 2014
    Applicant: U.S. Army Research Laboratory ATTN: RDRL-LOC-I
    Inventors: HONG DONG, James F. Snyder
  • Patent number: 8785623
    Abstract: The present invention relates to ferromagnetic materials based on nano-sized bacterial cellulose templates. More specifically, the present invention provides an agglomerate free magnetic nanoparticle cellulose material and a method of forming such magnetic nanoparticle cellulose material. Further, the magnetic nonoparticles are physically attached on the cellulose material and evenly distribute.
    Type: Grant
    Filed: March 31, 2008
    Date of Patent: July 22, 2014
    Assignee: Cellutech AB
    Inventors: Richard T. Olsson, My Ahmed Said Samir Azizi, Lars Berglund, Ulf W. Gedde
  • Publication number: 20140018532
    Abstract: The present invention relates to a process for producing a water-absorbent polysaccharide including the process steps of bringing into contact an uncrosslinked polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel and crosslinking the polysaccharide gel. The invention further relates to a water-absorbent polysaccharide obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the water-absorbent polysaccharides or of the composites as well as the use of polyphosphates.
    Type: Application
    Filed: September 12, 2013
    Publication date: January 16, 2014
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Markus Frank, Frank Loeker, Dirk Paepen, Scott J. Smith
  • Publication number: 20130330417
    Abstract: Nanocellulose foams containing at least one active ingredient and methods of preparing such nanocellulose foams containing one or more active ingredients are provided herein. In some embodiments, a method for preparing nanocellulose foam containing active ingredients may include forming a liquid mixture of nanocellulose, wherein the nanocellulose is at least one of dispersed, suspended or gelled in the liquid mixture; drying the liquid mixture of nanocellulose to form a nanocellulose foam; and mixing at least one active ingredient into at least one of the liquid mixture of nanocellulose or the nanocellulose foam. In some embodiments, a nanocellulose structure may include a nanocellulose foam comprising at least one of a carboxylate group, a hydroxyl group, or a sulfate group bonded to an active ingredient. In some embodiments, the nanocellulose structures are enhanced or crosslinked with metal cations.
    Type: Application
    Filed: June 7, 2013
    Publication date: December 12, 2013
    Inventors: Hong Dong, James F. Snyder
  • Patent number: 8551371
    Abstract: A method of treating a material to improve flame retardancy, the method comprising applying to the material urea, phosphorous acid or a salt thereof, and a base comprising a monovalent metallic cation.
    Type: Grant
    Filed: September 3, 2008
    Date of Patent: October 8, 2013
    Assignee: Perachem Limited
    Inventors: Jamie Anthony Hawkes, Paul Webb, David Malcolm Lewis, Andrew Bayliff
  • Patent number: 8496782
    Abstract: Provided is a method for preparing cellulose ether which is transparent as dissolved in water and has low water-insoluble content. More specifically, provided are a method for preparing alkali cellulose comprising a contact step of bringing a pulp sheet having a pore volume of 1.0 ml/g or greater, or chips into which the pulp sheet has been converted, into contact with an alkali metal hydroxide solution to obtain an alkali cellulose reaction mixture, and a drain step of draining the alkali cellulose reaction mixture; and a method for preparing water-soluble cellulose ether comprising a step of reacting the alkali cellulose with an etherifying agent.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: July 30, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Mitsuo Narita
  • Patent number: 8378091
    Abstract: A cellulose derivative which has a suitable elastic modulus and viscosity when it is dissolved in water and is useful as an adhesion barrier. The cellulose derivative has a molecular weight of 5×103 to 5×106 and is composed of a repeating unit represented by the following formula (1): wherein R1, R2 and R3 are each independently selected from the group consisting of the following formulas (a), (b), (c) and (d) in predetermined amount: (X in the formula (c) is an alkali metal, and R4 and R5 in the formula (d) are each independently an alkyl group or alkenyl group having 10 to 28 carbon atoms).
    Type: Grant
    Filed: August 3, 2006
    Date of Patent: February 19, 2013
    Assignee: Teijin Limited
    Inventors: Hiroaki Kaneko, Eiichi Kitazono, Masaya Ito, Yoshihiko Sumi
  • Publication number: 20130040911
    Abstract: Provided are a novel carboxymethyl cellulose (CMC) structure and a method for producing the same. The CMC structure of the present invention is useful as a medical material and particularly as an adhesion-preventing material, and has good biocompatibility and bioabsorbability and controllable periods of functioning and dissolving, or has both effects for preventing adhesions and wound healing. The CMC structure of the present invention is substantially composed of carboxymethyl celluloses, comprising an acid carboxymethyl cellulose and an alkaline metal carboxymethyl cellulose in a mixed state. The method of production of the present invention comprises subjecting the alkaline metal (or acid) carboxymethyl cellulose structure to an acid (or alkali) treatment, wherein the acid (or alkali) treatment is terminated before the alkaline metal (or acid) carboxymethyl cellulose is fully converted to the acid (or alkaline metal) carboxymethyl cellulose.
    Type: Application
    Filed: December 9, 2010
    Publication date: February 14, 2013
    Applicant: HOGY MEDICAL CO., LTD.
    Inventors: Gilbu Soe, Motonori Aoshima, Toshiki Inoue, Kiyotaka Hasegawa
  • Patent number: 8324374
    Abstract: Disclosed is a novel process which has low facility load, requires a reduced amount of energy, is highly safe, and enables to produce a monosaccharide such as glucose and xylose by decomposing a cellulose-based substance under conditions where a substance used for decomposing the cellulose-based substance (e.g., a solvent, a catalyst) can be separated, collected and re-used readily. Also disclosed is a novel process for producing ethanol from the monosaccharide through ethanol fermentation. Specifically disclosed is a process for producing a monosaccharide, which comprises disaggregating/finely pulverizing a cellulose-based substance, mixing the resulting material with a phosphate solution to disperse the resulting material in the phosphate solution, and decomposing cellulose in the solution at a temperature of 100° C. or lower while irradiating with ultraviolet ray optionally in the presence of titanium dioxide.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: December 4, 2012
    Assignee: Taiyu Kensetsu Kabushiki Kaisha
    Inventor: Takashi Kawasaki
  • Patent number: 8258501
    Abstract: A method of using a metal complex as an n-dopant for doping an organic semiconducting matrix material in order to alter the latter's electrical characteristics is provided. In order to provide n-doped organic semiconductors with matrix materials having a low reduction potential, while achieving high conductivities, the n-dopant is a neutral electron-rich metal complex with a neutral or charged transition metal atom as a central atom and having at least 16 valence electrons. The complex can be polynuclear and can possess at least one metal-metal bond. At least one ligand can form a ? complex with the central atom, which can be a bridge ligand, or it can contain at least one carbanion-carbon atom or a divalent atom. Methods for providing the novel n-dopants are provided.
    Type: Grant
    Filed: March 3, 2005
    Date of Patent: September 4, 2012
    Assignee: Novaled AG
    Inventors: Ansgar Werner, Olaf Kühl, Simon Gessler, Horst Hartmann, Andre Grüssing, Michael Limmert, Andrea Lux, Kentaro Harada
  • Publication number: 20120214984
    Abstract: When a combination of pulps having different alkali metal hydroxide solution absorption rates is as a raw material, contact conditions such as a contact temperature and a contact time have to be changed frequently, depending on the absorption rate of pulps currently processed, thereby causing a problem of reduced productivity. For solving the problem, provided is a method for producing alkali cellulose, comprising at least the steps of: bringing two or more types of pulps having different alkali metal hydroxide solution absorption rates into contact with an alkali metal hydroxide solution to obtain a contact product; and draining the contact product, wherein the highest absorption rate is not more than 4.0 times as fast as the lowest absorption rate.
    Type: Application
    Filed: February 16, 2012
    Publication date: August 23, 2012
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Mitsuo Narita
  • Publication number: 20120214982
    Abstract: There is provided a method for producing alkali cellulose comprising efficiently removing cellulose particles which are introduced by a pulp and have accumulated in a circulating alkali metal hydroxide solution. More specifically, there is provided a method for producing alkali cellulose, comprising at least the steps of bringing a pulp into contact with an alkali metal hydroxide solution to obtain a contact product, draining the contact product by a drainer, reusing an alkali metal hydroxide solution recovered in the step of draining for contact with a pulp, and adjusting an amount of cellulose particles in the recovered alkali metal hydroxide solution to 0.5% by weight or less prior to reusing for contact with the pulp.
    Type: Application
    Filed: February 16, 2012
    Publication date: August 23, 2012
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Mitsuo Narita
  • Publication number: 20120041187
    Abstract: The present invention relates to a process for the production of alkali cellulose for the production of alkali cellulose and, optionally, cellulose ethers from cellulose in the presence of alkali and, if applicable, with alkylating and/or hydroxyalkylating agent(s) comprising the reaction of a cellulose with an alkali metal hydroxide, wherein the alkali metal hydroxide is mixed with cellulose in a mixing apparatus, the mixing apparatus (1) having an upper region (20, 102a, 202a) with a first cross-section and a lower region (21, 102b, 202b) with a second cross-section, the second cross-section being the same as or smaller than the first cross-section and comprising at least one non-horizontally oriented mixing device (23, 27, 121, 221, 224).
    Type: Application
    Filed: January 8, 2010
    Publication date: February 16, 2012
    Inventors: Matthias Sprehe, Bettina Hoelzer
  • Patent number: 8017766
    Abstract: Provided is a method for preparing alkali cellulose having alkali distributed uniformly therein. A uniform alkali distribution in the alkali cellulose makes it possible to prepare cellulose ether which has been substituted uniformly in an etherification reaction step. The resulting cellulose ether does not contain a floating water-insoluble portion which will otherwise appear owing to insufficient substitution. More specifically, provided are a method for preparing alkali cellulose, comprising simultaneously feeding pulp powder and an aqueous alkali solution to a high speed disperser to continuously bring them into contact with each other and a method for preparing cellulose ether, comprising reacting the resulting alkali cellulose with an etherifying agent.
    Type: Grant
    Filed: June 7, 2006
    Date of Patent: September 13, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mitsuo Narita, Atsushi Hatayama, Hiroshi Umezawa
  • Publication number: 20110183141
    Abstract: Dried nanocrystalline cellulose (NCC), in particular films of NCC, of controlled water dispersibility and a method to control the dispersibility of dried NCC by controlling electrolyte solution ionic strength and ion valency is described. Neutral M-NCC suspensions containing monovalent counterions (e.g., M=Na+, K+, NH4+, Et4N+) produced by neutralization of acid-form NCC (H-NCC) with the appropriate hydroxide, are readily dispersible in water when fully dried; this is in contrast to H-NCC. The dispersion of dried M-NCC in aqueous media is effectively prevented by a combination of (1) increased electrolyte concentration and ionic strength, and (2) higher valency of the cation component of the dissolved salt. Additionally, pre-treatment of dried M-NCC films with an electrolyte solution having a polyvalent cation, for example a divalent or trivalent cation is sufficient to prevent the subsequent dispersion of the M-NCC film in pure water.
    Type: Application
    Filed: January 18, 2011
    Publication date: July 28, 2011
    Applicant: FPINNOVATIONS
    Inventors: Stephanie Beck, Jean Bouchard, Richard Berry
  • Publication number: 20110147292
    Abstract: There is provided a cellulose hydrate membrane having a porous double structure which consists of micropores having a diameter in the range from >100 nm to 20 ?m and ultrapores which have a diameter of <100 nm and which are not accessible to Blue Dextran having an average molecular weight Mw of 2 000 000, wherein the fraction of the volume of the ultrapores is more than 15% of the entire pore volume accessible to water. In addition, a method for producing the membrane, its use as an adsorption membrane, and an apparatus for membrane chromatography are specified.
    Type: Application
    Filed: February 10, 2009
    Publication date: June 23, 2011
    Applicant: SARTORIUS STEDIM BIOTECH GMBH
    Inventors: Wolfgang Demmer, René Faber, Hans-Heinrich Hörl, Csilla Kiss, Dietmar Nußbaumer
  • Publication number: 20110015596
    Abstract: An absorbent article, such as a diaper, panty diaper, sanitary napkin or incontinence device includes a liquid-permeable topsheet, a backsheet and an absorbent core enclosed between the liquid-permeable topsheet and the backsheet. The absorbent core includes acidic fluff pulp having a pH of 5.5 or less and an organic zinc salt, in particular zinc ricinoleate. The combination of organic zinc salt and acidic fluff pulp exerts a synergetic effect in the suppression of ammonia.
    Type: Application
    Filed: November 17, 2006
    Publication date: January 20, 2011
    Applicant: SCA Hygiene Products AB
    Inventors: Jan Wästlund-Karlsson, Jan Petrusson, Madeleine Pehrson, Åsa Lindström, Linus Fredlinger
  • Publication number: 20100317844
    Abstract: The invention provides a metal salt of a crosslinked cellulose derivative represented by the following formula (I), wherein the degree of substitution of the hydroxyl group of glucose unit of the crosslinked cellulose derivative by a functional group a is 1 or more. R—O-A??(I) {In the formula (I), R represents a crosslinked cellulose residue and A represents a functional group a having cation-exchange ability.
    Type: Application
    Filed: December 26, 2007
    Publication date: December 16, 2010
    Inventors: Naoyuki Yoshida, Kazushi Ishida, Shuji Sasaki, Ippei Yamaoka
  • Publication number: 20100224840
    Abstract: A method of treating a material to improve flame retardancy, the method comprising applying to the material urea, phosphorous acid or a salt thereof, and a base comprising a monovalent metallic cation.
    Type: Application
    Filed: September 3, 2008
    Publication date: September 9, 2010
    Inventors: Jamie Anthony Hawkes, Paul Webb, David Malcolm Lewis, Andrew Bayliff
  • Patent number: 7285157
    Abstract: An air-filter for a circulating and/or recirculating air system using a filter medium containing a microbiologically effective amount of a polymeric biguanide or salt thereof. Also claimed is a method for reducing odors and/or air-borne micro-organisms in a circulating or recirculating air system using the air-filter, and a method for protecting an air-filter medium against microbial degradation by incorporating in, or on, the medium a microbiologically effective amount of a polymeric biguanide or salt thereof.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: October 23, 2007
    Assignee: Arch UK Biocides Limited
    Inventors: Helen Dukes, John David Payne
  • Patent number: 6908995
    Abstract: Ethanol is produced from biomass by the process of a heated aqueous solution containing 20 to 40 percent alkali metal hydroxide to break the lignin-cellulose bond. Then the biomass is heated further to remove carbon dioxide from the cellulose and lignin to produce a mixture of carbohydrates, modified sodium lignin, micro-cellulose, lignin-cellulose resinous products and sodium carbonate. Water is added to the mixture and most of the mixture is water soluble. An acidic salt forming compound is added to the aqueous solution until a pH of 3-7 is obtained. The lignin is precipitated. The lignin-cellulose resinous products float to the top and is skimmed off. The solution containing the carbohydrates and salt is decanted off the lignin and is concentrated by evaporating off water. The carbohydrates crystalizes from the solution and the water and salt is filtered off. Water is added to the carbohydrates then it is fermented to form ethanol. The ethanol is recovered from the water by evaporation.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: June 21, 2005
    Inventor: David H. Blount
  • Patent number: 6699363
    Abstract: A process that can be used for producing a starch product is provided. The process comprises heating a composition, which comprises or consists essentially of a starch, a polyacrylamide, and a multivalent cation. The weight ratio of starch to polyacrylamide is greater than about 2 to 1. The process can also comprise heating a composition, which comprises or consists essentially of a starch and a polyacrylamide to produce a heated composition followed by contacting the heated composition with a multivalent cation. The heating can be carried out at a pH above 7.0 if the polyacrylamide is a cationic polyacrylamide or nonionic polyacrylamide and, if the starch is a cationic starch and the polyacrylamide is an amphoteric polyacrylamide or anionic polyacrylamide, the heating neutralizes less than 75% of the cationic starch.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: March 2, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Robert Harvey Moffett
  • Patent number: 6669863
    Abstract: An anionic cellulose ether obtainable by a process comprising reacting an alkali metal cellulose with one or more reagents A selected from the group consisting of haloacetic acids, alkali metal haloacetates, alkali metal vinyl sulfonates, vinyl sulfonic acid, and precursors thereof, and one or more reagents B having the formula R1—(OCH2CH(R2))n-P, wherein R2 represents hydrogen or a methyl group; n is 0-2; P represents a glycidyl ether group, a 1,2-epoxy group or a precursor thereof, if P represents a glycidyl ether group, R1 represents a linear C3-C5 alkyl group, optionally containing an oxygen atom, a phenyl group, or a benzyl group, and if P represents a 1,2-epoxy group, R1 represents a linear C3-C5 alkyl group, optionally containing an oxygen atom. Preferably, reagent A is chloroacetic acid and reagent B is n-butyl glycidyl ether. The invention also relates to the use of said anionic cellulose ether as an associative thickener, rheology modifier or stabilizer.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: December 30, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Berend Jan Dijk, Jan Gerardus Batelaan
  • Patent number: 6608184
    Abstract: Fatty oil and acids, glycerol, glycols, lactic acid, urea, fertilizer, carbohydrates, ethanol are recovered or produced from sewer sludge by the process of concentrating and filtering out the solid sewer sludge, hydrolysis of the cellulose in the sewer sludge by an alkali or acid catalyst to carbohydrates, fermentation of the carbohydrates to produce ethanol, then recover the ethanol by distillation or membrane technology. The glycerol, glycols and lactic acids are recovered by membrane technology. The polysacchride carbohydrates are hydrolyzed to monosacchrides then fermented to alcohol. The unsoluble sewer sludge and the salts such as ammonium sulfate, nitrogen containing compounds and urea from the aqueous solution left after the ethanol is distilled off are mixed, dried and utilized as fertilizer.
    Type: Grant
    Filed: May 10, 2001
    Date of Patent: August 19, 2003
    Inventor: David H. Blount
  • Publication number: 20030150571
    Abstract: Provided are methods of deacidifying a cellulose-based material by providing a deacidification composition comprising a hydrofluorocarbon and a deacidification agent dispersed within the hydrofluorocarbon, and contacting the cellulose-based material with the composition to increase the pH associated with the cellulose-based material. Also provided are deacidification compositions for use in the present methods.
    Type: Application
    Filed: November 18, 2002
    Publication date: August 14, 2003
    Inventors: Raymond H. Thomas, David L. Diggs
  • Patent number: 6593468
    Abstract: This invention relates to a process for producing a substantially fiber-free carboxymethyl cellulose which predominantly exhibits elastic properties, to the use thereof as a superabsorbent material, and to the use thereof as an adjuvant substance for achieving suitable rheological and water retention properties for the cosmetics, pharmaceutical and food sectors, and for industrial applications, e.g. as an additive for coating materials, for the sealing of cables and for use in tunnelling and in civil and underground engineering.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: July 15, 2003
    Assignee: Wolff-Walsrode AG
    Inventors: Werner Lange, Bernd Schriewer, Friedrich-Karl Lampert, Wilhelm Oppermann, Jörn-Bernd Pannek, René Kiesewetter
  • Publication number: 20020099203
    Abstract: The present invention provides a process for the production of an alkali cellulose which exhibits a very uniform distribution of alkali in the alkali cellulose and has a high bulk density. Moreover, the high bulk density of the alkali cellulose makes it possible to charge a smaller reaction vessel with a greater amount of the alkali cellulose in an etherification reaction step and thereby produce a cellulose ether having very excellent solubility. Specifically, powdered pulp obtained by grinding pulp to a powder is continuously fed to a double-shaft kneader and mixed with an aqueous alkaline solution which is simultaneously and continuously fed thereto through the same inlet port or at another site. After they are mixed and densified within the kneader, the resulting product is continuously discharged from an outlet port. The feed rate of the powdered pulp is controlled by a metering feeder so as to feed it at a desired flow rate.
    Type: Application
    Filed: February 15, 2001
    Publication date: July 25, 2002
    Inventor: Kazuto Kobayashi
  • Patent number: 6403777
    Abstract: Transition metal complexes, referred to hereinafter as “metalloligands”, that catalyze the degradation of DNA and the cleavage of RNA at select sites are provided. In one embodiment, the metalloligand has the following structure: wherein R1 is an amino group, i.e. an NH, or an alkylamino group comprising 1 or 2 carbon atoms; wherein R2 is selected from the group consisting of an amino group, a hydroxyl group, i.e., O(H), an alkylamino group comprising 1 or 2 carbon atoms; and an alkylhydroxyl group comprising 1 or 2 carbon atoms; wherein J is a ligand which comprises at least one carbon-containing five-membered or six-membered ring structure; and wherein M is a transition metal ion which is bound via coordinate bonds to R1 and R2.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: June 11, 2002
    Assignee: The Ohio State University Research Foundation
    Inventor: James A. Cowan
  • Patent number: 6333399
    Abstract: A process for the preparation of chitosan-glucan complexes from biological sources by treating said biological sources with solutions, characterized in that a) chitin-containing microorganisms as said biological sources are treated at least once with a first alkaline solution; b) thereafter, the product obtained from step a) is treated with diluted mineral acid; c) followed by a further treatment with a second alkaline solution the alkalinity of which is higher than that of the alkaline solution of step a) to incomplete deacetylation of the fraction obtained step b); d) separating the solid components, discarding the supernatant, neutralizing and washing the residue with water.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: December 25, 2001
    Inventors: Alexander Teslenko, Woewodina Irina Nikolaewna
  • Patent number: 5985916
    Abstract: A polymer-platinum compound for use in tumor treatment is described. The compound is composed of a biodegradable diamido-diamine polymer linked to a platinum species. The platinum species is released from the polymer to yield a platinum species having anti-tumor activity.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: November 16, 1999
    Assignee: Access Pharmaceuticals, Inc.
    Inventors: Ruth Duncan, Paolo Ferruti, Evagoras G. Evagorou
  • Patent number: 5955601
    Abstract: Rare earth chelate-conjugated oligonucleotides useful in nucleic acid hybridization assays and for generating chelate-labelled probes of any desired sequence are disclosed. The particular class of chelates utilized exhibit an unusually high efficiency of rare earth element capture, correlated with emission of a high level of signal in time-resolved fluorescence spectroscopy compared to other structurally related chelate compounds.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: September 21, 1999
    Assignee: E G & G Wallac
    Inventors: David Gordon Sherman, Charlene Elinor Bush, Laura Ann Beninsig, Kurt Mathew VandenBrink
  • Patent number: 5844058
    Abstract: A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: December 1, 1998
    Assignee: Brookhaven Science Associates
    Inventor: Toshifumi Sugama
  • Patent number: 5804166
    Abstract: Disclosed are hair spray compositions containing non-ionic cellulosic ethers in a solvent base containing water and volatile organic solvent wherein the level of volatile organic solvent in the composition is about 80% or less, and wherein the non-ionic cellulose ether is characterized by a solution viscosity of less than about 50 cps at 25.degree. C. for an aqueous solution containing 3 wt. % solids and 55 wt. % ethanol. The preferred non-ionic cellulosic ether is methylhydroxypropyl cellulose.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: September 8, 1998
    Assignee: Hercules Incorporated
    Inventors: Anita N. Chan, Anthony B. Clayton, Jashawant J. Modi
  • Patent number: 5801239
    Abstract: This invention relates to a process for the preparation of alkali salt of carboxyalkyl cellulose with good solubility in salt water which is useful for pertroleum drilling muds, which comprises (a) powdering high alpha cellulose obtained from fast growing plants or bamboo pulp, (b) preparing the alkali metal salt of cellulose by mixing the high alpha cellulose pulp obtained from fast growing plant or bamboo with an alkalinating agent in the presence of an inert organic solvent, (c) etherifying the prepared alkali cellulose to alkali metal salt of cellulose with an etherifying agent at a temperature in the range of 70.degree.-80.degree. C., (d) recovering the alkali metal salt of carboxyalkyl cellulose and (e) drying the resulting alkali metal salt of carboxalkyl cellulose.
    Type: Grant
    Filed: January 17, 1997
    Date of Patent: September 1, 1998
    Assignee: Council of Scientific & Industrial Research
    Inventors: Chowdhury Nath Saikia, Tridip Goswami, Anil Chandra Ghosh
  • Patent number: 5686602
    Abstract: A cellulose polymer network crosslinked with metal ions selected from the group consisting of: Al.sup.+3, Zr.sup.+4, and Ti.sup.+4, the crosslinked cellulose polymer network having incorporated therein a colloidal sol containing metal oxide-hydroxide particles wherein the metal is Al, Zr, or Ti. The inventive material is optically clear and can be used to cast microporous films, either supported or unsupported, which are useful as coatings on ink jet recording materials.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: November 11, 1997
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Omar Farooq, David W. Tweeten, Mohammad Iqbal, Subodh K. Kulkarni
  • Patent number: 5410037
    Abstract: There is described a process for silylizing carbohydrates in liquid nitrogen compounds,the carbohydrates being reacted under pressure in an autoclave at a tempperature of about 0.degree. to 200.degree. C. with a silylizing agent of the formula (I) ##STR1## in a liquid nitrogen compound of the formula (II) ##STR2## the respective radicals in the two formulas (I) and (II) being, independently of each other:hydrogen, a low alkyl group with 1 to 4 carbon atoms, a cycloalkyl group with 3 to 6 carbon atoms, an aryl group in the form of a phenyl or naphthyl radical, an aralkyl group with 7 to 18 carbon atoms, an alkylaryl group with 7 to 18 carbon atoms, or an O-, S- or N-containing heterocyclic group with 2 to 5 carbon atoms.An especially suitable silylizing agent is hexamethyl disilazane. As liquid nitrogen compound preferably ammonia is taken, which under the process conditions is liquid. The process according to the invention is of advantage ecologically and economically.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: April 25, 1995
    Assignee: Rhone-Poulenc Rhodia Aktiengesellschaft
    Inventors: Thomas Wagner, Werner Mormann
  • Patent number: 5250672
    Abstract: A polysaccharide chemically joined to a nitroxyl spin label (NSL) compound has use for the preparation of an NMR diagnostic composition. An agent for modifying H.sub.2 O relaxation times in NMR diagnosis may comprise a polysaccharide to which is chemically linked both an NSL compound and an organic complexing agent to which is complexed a paramagnetic metal ion, such as Gd(III) or Cu(II). Polysaccharides include dextran, starch and cellulose. The preferred NSL compound is 4-amino-2,2,6,6-tetramethylpiperidine-1-oxyl.
    Type: Grant
    Filed: June 30, 1987
    Date of Patent: October 5, 1993
    Assignee: Guerbet S.A.
    Inventors: Peter J. Sadler, Charles T. Harding
  • Patent number: 5208324
    Abstract: There are provided paramagnetic compounds comprising a paramagnetic metal species chelated by a chelating moiety bound by an amide group to a linker group itself bound by an ester group to a macromolecule, wherein said linker group provides a carbon chain of at least 2 atoms between said amide group and said ester group. The novel compounds are particularly suitable as contrast agents, e.g. in magnetic resonance imaging.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: May 4, 1993
    Assignee: Nycomed Imaging AS
    Inventors: Jo Klaveness, Pal Rongved, Per Strande
  • Patent number: 5204457
    Abstract: A complex of a carboxyalkyl ether of a polysaccharide with a magnetic metal oxide. This complex is extremely excellent in stability in preservation in the form of aqueous sol and has only a low toxicity, and thus is useful, for example, for medical use as a nuclear magnetic imaging molding agent or the like.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: April 20, 1993
    Assignees: Meito Sangyo Kabushiki Kaisha, Shigeo Maruno
    Inventors: Shigeo Maruno, Masakatsu Hasegawa
  • Patent number: 5202122
    Abstract: Process for enhancing the natural bile acid binding capacity of edible pulp material by either heating an aqueous slurry of the pulp material to at least 40.degree. C. and/or sequentially reacting pulp with a first reactant, such as sodium hydroxide, for activating the pendant hydroxyl groups on the polysaccharide components of the pulp material, a second reactant, such as chloroacetic acid, for carboxylating the activated pendant groups on the polysaccharides, and a third reactant, such as calcium hydroxide, for providing calcium ions which can ionically bond to the carboxylated pendant groups.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: April 13, 1993
    Assignee: Humanetics Corporation
    Inventors: Frederic A. Graves, Ani Huang
  • Patent number: 5182380
    Abstract: Water-soluble, reversibly gelable cellulose ethers containing sulphoethyl groups (DS-sulphoethyl) and dihydroxpropyl groups (MS-dihydroxypropyl).
    Type: Grant
    Filed: July 30, 1991
    Date of Patent: January 26, 1993
    Assignee: Wolff Walsrode Aktiengesellschaft
    Inventors: Jorn Breckwoldt, Klaus Szablikowski