Ether-esters Or Mixed Esters Patents (Class 536/108)
  • Patent number: 4119487
    Abstract: Novel starch ether derivatives are prepared by reacting starch with 3-chloro-2-sulfopropionic acid. The resulting 2-sulfo-2-carboxyethyl starch ether derivatives find use in many applications, but are particularly useful as pigment retention aids in papermaking processes.
    Type: Grant
    Filed: September 6, 1977
    Date of Patent: October 10, 1978
    Assignee: National Starch & Chemical Corporation
    Inventor: Martin M. Tessler
  • Patent number: 4098997
    Abstract: A granular starch base is reacted with a selected propiolate ester in aqueous medium to produce a granular, acetal cross-linked starch, the cross-linkages of which are substantially removable in acidic medium. The cross-linked starch product thus prepared is useful in producing highly-substituted granular starch derivatives from which the cross-linkages may be readily and substantially removed as desired.
    Type: Grant
    Filed: January 21, 1977
    Date of Patent: July 4, 1978
    Assignee: National Starch and Chemical Corporation
    Inventor: Martin M. Tessler
  • Patent number: 4067824
    Abstract: A gelled perfume formulation comprising conventional perfume oil or a commercial perfume composition and a polymeric carbohydrate derivative which acts as the gelling agent. The gelled formulation is applied on the skin as a smooth thin film. The composition possesses aesthetically pleasing clarity and enduring fragrance. This perfume can be conveniently transported and easily dispensed.
    Type: Grant
    Filed: September 27, 1976
    Date of Patent: January 10, 1978
    Assignee: Anheuser-Busch, Incorporated
    Inventors: James Teng, Marcella C. Stubits, Abraham Minton, James H. Baker
  • Patent number: 4061611
    Abstract: This invention is directed to aqueous compositions and the process for preparing same and more specifically to aqueous coating compositions comprising polymeric resin binders and pigments dispersed in an aqueous system with starch ester dispersants. The dispersant consists of mixed esters of starch derived from (a) low molecular weight hydrolyzed starch having a plurality of anhydroglucose units or a derivative of said starch and (b) at least about 0.5 mole of acylating agent for each anhydroglucose unit of the hydrolyzed starch or its derivative. The acylating agent is a combination of anhydrides or acyl compounds consisting of (i) from about 0.1 to 2.9 moles of at least one anhydride of a polycarboxylic acid and (ii) from 0.1 to 2.9 moles of at least one compound selected from the class consisting of anhydrides of monocarboxylic acids and the acyl halides of monocarboxylic acids.
    Type: Grant
    Filed: September 22, 1976
    Date of Patent: December 6, 1977
    Assignee: The Sherwin-Williams Company
    Inventors: Raymond Charles Glowaky, Stephen Edward Rudolph, Gordon Paul Bierwagen
  • Patent number: 4061610
    Abstract: This invention is directed to aqueous compositions and to the process for preparing same which comprises a dispersion of polymeric resin binders and pigments in an aqueous system with a dispersant. The dispersant consists of half-esters of starch derived from (a) low molecular weight hydrolyzed starch having a plurality of anhydroglucose units or a derivative of said starch and (b) at least about 0.25 mole of at least one cyclic anhydride of a polycarboxylic acid for each anhydroglucose unit of the hydrolyzed starch and/or its derivatives.These half-ester starch dispersants are characterized as having pendant carboxyl groups and average molecular weights ranging up to about 100,000 with a high degree of substitution, i.e. wherein on an average of about 0.25 to 3.0 of the hydroxyl groups of each anhydroglucose unit are esterified. The unreacted carboxyl groups pendant from the backbone of the starch esters may be further reacted, i.e.
    Type: Grant
    Filed: May 19, 1976
    Date of Patent: December 6, 1977
    Assignee: The Sherwin-Williams Company
    Inventors: Raymond Charles Glowaky, Stephen Edward Rudolph, Gordon Paul Bierwagen
  • Patent number: 4051316
    Abstract: An insoluble alkali metal-magnesium starch-xanthate composition is prepared which is capable of removing most heavy metal ions from aqueous solutions. Concentrations of heavy metal ions contained in several industrial effluents were reduced to below the most stringent aqueous discharge limits.
    Type: Grant
    Filed: June 14, 1976
    Date of Patent: September 27, 1977
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Robert E. Wing, William M. Doane
  • Patent number: 4048435
    Abstract: Highly substituted granular starches are prepared by reacting the starch in an aqueous system with a reagent capable of producing an acetal cross-linkage; reacting the resultant acetal cross-linked starch with a mono-functional esterifying or etherifying reagent under aqueous alkaline conditions and removing the acetal cross-linkages by treating under acid conditions. The highly substituted starches are particularly useful in operations, such as papermaking, wherein the cross-linkages can be removed and the starch readily dispersed during a relatively low pH starch cooking process.
    Type: Grant
    Filed: July 12, 1976
    Date of Patent: September 13, 1977
    Assignee: National Starch and Chemical Corporation
    Inventors: Morton W. Rutenberg, Wadym Jarowenko, Martin M. Tessler
  • Patent number: 4035572
    Abstract: This application involves a process of making chewing gum base which is basically hydroxypropyl starch acetate. This process involves preparation of the hydroxypropyl starch acetate gum and separation and purification of the gum from an emulsion state.
    Type: Grant
    Filed: May 9, 1975
    Date of Patent: July 12, 1977
    Assignee: Anheuser-Busch, Incorporated
    Inventors: Marcella C. Stubits, James Teng
  • Patent number: 4035569
    Abstract: Preparation of partially substituted nitrate and sulfate esters of polysaccharides or polyvinylalcohol, their esters containing a mixture of nitrite with sulfate or nitrate groups, aqueous media thickened with such esters, the simultaneous preparation of such esters and alkyl nitrites or such esters and inorganic nitrites or nitrates and resulting products, useful as thickeners, films, fibers and in many other applications.
    Type: Grant
    Filed: March 23, 1976
    Date of Patent: July 12, 1977
    Inventor: Richard G. Schweiger
  • Patent number: 4029544
    Abstract: The use in the manufacture of paper of additives comprising derivatives of starches having particular levels of water fluidity and which contain controlled proportions of cationogenic or cationic substituent groups as well as sulfo-succinate groups. The resulting paper containing the latter additives is characterized by improved retention of pigments and increased strength.
    Type: Grant
    Filed: July 12, 1976
    Date of Patent: June 14, 1977
    Assignee: National Starch and Chemical Corporation
    Inventors: Wadym Jarowenko, Henry R. Hernandez
  • Patent number: 4011392
    Abstract: This invention is directed to mixed esters of starch and to the method of preparing and the use of said starch esters which are derived from (a) low molecular weight hydrolyzed starch having a plurality of anhydroglucose units and (b) at least about 0.5 mole of acylating agent per anhydroglucose unit consisting of mono- and polycarboxylic acid anhydrides and acyl halides. These anionic esters of starch with average molecular weights ranging up to 100,000 are characterized as having a high degree of substitution, i.e. ranging up to 3.0 wherein at least about 0.1 of the total degree of substitution consist of ester groups having pendant carboxyl radicals derived from anhydrides of polycarboxylic acids.
    Type: Grant
    Filed: September 2, 1975
    Date of Patent: March 8, 1977
    Assignee: The Sherwin-Williams Company
    Inventors: Stephen Edward Rudolph, Raymond Charles Glowaky