Mixed Ethers Patents (Class 536/44)
  • Patent number: 4526961
    Abstract: Disclosed is a process for preparing water-soluble sodium carboxymethyl cellulose (NaCMC), including mixed ethers of NaCMC, by etherifying cellulose with alkyl monochloroacetates in an aqueous-alkaline dispersion containing at least one organic solvent. In the process, cellulose is first alkalized in an aqueous-alkaline dispersion, which optionally already contains the organic solvent. Subsequently, the alkali cellulose is reacted essentially with an alkyl monochloroacetate as the etherifying agent, in the presence of the organic solvent.
    Type: Grant
    Filed: September 30, 1983
    Date of Patent: July 2, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Eberhard Perplies, Utz H. Felcht
  • Patent number: 4474950
    Abstract: Modified cellulose reaction products, which are dispersible in aqueous media over a broad pH range without lump formation, are prepared by reacting water-soluble cellulose ether with a specified silane modifying agent in the amount of from 0.0001 to 0.12 mole of modifying agent per mole of cellulose in the cellulose ether.
    Type: Grant
    Filed: August 26, 1983
    Date of Patent: October 2, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Utz-Hellmuth Felcht, Helmut Berenbold
  • Patent number: 4460766
    Abstract: In modern processes for preparing cellulose ethers containing one or more types of substituents, such as MC, CMC, HEC, HPC, MHEC or EHEC, cellulose is reacted with an etherifying agent in the presence of water, base and at least one inert organic solvent (as a dispersing auxiliary). Dimethoxyethane (ethylene glycol dimethyl ether) is employed as a new organic solvent for these syntheses, particularly in quantities of 1 to 30 parts by weight per part by weight of cellulose.
    Type: Grant
    Filed: November 19, 1982
    Date of Patent: July 17, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Utz-Hellmuth Felcht, Eberhard Perplies
  • Patent number: 4438262
    Abstract: Highly dielectric organic compounds can be obtained by cyanoethylating a dihydroxyalkylate of a water-soluble polysaccharide or a derivative thereof with acrylonitrile.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: March 20, 1984
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Ichiki Murase, Fumio Fujita, Toshihiro Ohnishi, Toshifumi Tamura
  • Patent number: 4428876
    Abstract: A process for isolating saponins and flavonoids from leguminous plant which comprises extracting a part or the whole of the said plant with an aqueous alkaline solution, separating the extract from insoluble matters comprising fibrous materials, applying the extract on non-polar or slightly polar adsorbent resin to adsorb the saponins and flavonoids on the said resin, and treating the resin with a polar solvent to elute the saponins and the flavonoids adsorbed on the said resin.
    Type: Grant
    Filed: June 17, 1983
    Date of Patent: January 31, 1984
    Assignee: Tokiwa Kanpo Pharmaceutical Co., Ltd.
    Inventor: Junichi Iwamura
  • Patent number: 4413121
    Abstract: Disclosed is a cellulose ether having at least one phosphorus-containing substituent or a mixed ether of said cellulose ether having in addition at least one phosphorus-free substituent comprising alkyl, hydroxyalkyl, carboxyalkyl, sulfonoalkyl, aminoalkyl, or diaminoalkyl, wherein the phosphorus-containing substituent(s) comprise(s) groups of the formula ##STR1## wherein R.sup.1 and R.sup.2 are OX; or R.sup.1 is OX and R.sup.2 is OY; or R.sup.1 is OX and R.sup.2 is (CH.sub.2).sub.n --CH.sub.3 ; or R.sup.1 and R.sup.2 are (CH.sub.2).sub.n --CH.sub.3 ; or R.sup.1 is (CH.sub.2).sub.n --CH.sub.3 and R.sup.2 is (CH.sub.2).sub.p --CH.sub.3, whereinX,Y are identical or different and comprise a hydrogen atom or a monovalent cation;m is an integer from 1 to 4; andn,p are identical or different and are 0 or 1; with the proviso that when m is 1 or 2, R.sup.1 and R.sup.2 may not be OX and R.sup.1 and R.sup.2 may not be OX and OY, respectively. Also disclosed is a process for producing these cellulose ether products.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: November 1, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Lothar Brandt, Arno Holst, Hans-Jerg Kleiner
  • Patent number: 4330440
    Abstract: The invention relates to the carbonylation of cross linked substituted and unsubstituted polysaccharides, their copolymers with macroporous synthetic polymers, macroporous synthetic polymers and rigid supports with pendant hydroxyalkyl groups. The carbonylated product can be used to prepare an affinity chromatography matrix which remains an uncharged species at varying pH's. The carbonylated product is also useful for the preparation of other compounds: Typical polysaccharides are agarose, starch, dextran, cellulose and regenerated cellulose, typical macroporous synthetic polymers are acrylamides, acrylates and methacrylates, typical rigid supports are silica beads coated with hydroxy alkyl groups and typical cabonylating agents are N,N'-carbonyl diimidazole; N,N'carbonyl di-1,2,3-benzotriazole; and N,N'-carbonyl di-1,2,4-triazole.
    Type: Grant
    Filed: March 10, 1980
    Date of Patent: May 18, 1982
    Assignee: Development Finance Corporation of New Zealand
    Inventors: John S. Ayers, Geoffrey S. Bethell, William S. Hancock, Milton T. W. Hearn
  • Patent number: 4272526
    Abstract: The present invention relates to a chloral derivative having the general formula ##STR1## in which Y' is a polysaccharide consisting of a chain of anhydroglucose, modified anhydroglucose or uronic acid units as substituent group and in which R is selected from --H, --COCH.sub.2 OH, --[(CH.sub.2).sub.n 0].sub..chi. --H in which n is 2 to 5 and .chi. is 1 to 7; --CH.sub.2 OSO.sub.2 X' or --CH.sub.2 COOX' in which X' is NH.sub.4 or a single equivalent of a non-toxic metallic cation, --(CH.sub.2).sub.n H where n is 1 to 7, --(CH.sub.2).sub.n (OH).sub..chi. Y where Y is --H or --CH.sub.3 n is 1 to 7, .chi. is 1 to 12 and the --OH groups are attached to any or all of the carbon atoms by substitution and wherein when Y.sup.1 is a chain of unmodified anhydroglucose units, these units have the following configurations:.alpha.-D-glucopyranosyl units having a predominantly 1-4 linkage.beta.-D-glucopyranosyl units having a predominantly 1-4 linkage and/or.beta.
    Type: Grant
    Filed: May 8, 1979
    Date of Patent: June 9, 1981
    Assignee: Macarthys Pharmaceuticals Limited
    Inventors: David E. Simpkins, John B. O. Taylor
  • Patent number: 4243757
    Abstract: Small particles of cellulose-containing plants, fine granular oxidated silicon compounds and an alkali metal hydroxide are mixed, then heated to 150.degree. C. to 220.degree. C. while agitating until the plant particles soften or melt, thereby producing an alkali metal cellulose silicate condensation product.
    Type: Grant
    Filed: January 15, 1980
    Date of Patent: January 6, 1981
    Inventor: David H. Blount
  • Patent number: 4224439
    Abstract: Carbonylation of a polysaccharide and the product of that carbonylation. The carbonylated product can be used to prepare an affinity chromatography matrix which is an uncharged species of varying pH's. The carbonylated product is also useful for the preparation of other compounds. Typical polysaccharides are agarose, starch, dextran, cellulose and regenerated cellulose and typical carbonylating agents are N,N'-carbonyl diimidazole; N,N' carbonyl di-1,2,3-benzotriazole; and N,N'-carbonyl di-1,2,4-triazole.
    Type: Grant
    Filed: February 2, 1978
    Date of Patent: September 23, 1980
    Assignee: Development Finance Corporation of New Zealand
    Inventors: John S. Ayers, Geoffrey S. Bethell, William S. Hancock, Milton T. W. Hearn
  • Patent number: 4172736
    Abstract: Thickening of "cellulose reactive dyes" with carboxyethyl guar.
    Type: Grant
    Filed: February 17, 1978
    Date of Patent: October 30, 1979
    Assignee: Henkel Corporation
    Inventors: William H. Minkema, Gerald J. Shelso
  • Patent number: 4009329
    Abstract: Cellulose ethers which are resistant to enzyme catalyzed hydrolysis can be prepared by using a mixture of sodium and lithium hydroxides as the catalysts in conjunction with etherification reagents, such as, epoxides or alkyl halides.
    Type: Grant
    Filed: November 14, 1975
    Date of Patent: February 22, 1977
    Assignee: Union Carbide Corporation
    Inventors: William Charles Arney, Clarence Alfred Williams, Joseph Edward Glass, Jr.