Abstract: Disclosed are a papermaking method comprising the steps of sheet-formation of an aqueous papermaking stock which contains a cellulose fiber or the said fiber and an inorganic filler, dewatering and drying, charaacterized by the addition of a starch ether derivative of a general formula (I): ##STR1## where St--O represents a starch molecule residue, R.sub.1, R.sub.2 and R.sub.3 independently represent an alkyl group having from 1 to 18 carbon atoms or a benzyl group, provided that two or more of these R.sub.1, R.sub.2 and R.sub.3 must not be a benzyl group or an alkyl group having from 5 to 18 carbon atoms at the same time, and any two of these R.sub.1, R.sub.2 and R.sub.3 may be bonded to form a cyclic structure, the said derivative containing the ether bond preferably in a degree of substitution of from 0.01 from 0.1, to the said papermaking stock in an amount of from 0.05 to 5.

Abstract: Improved amphoteric starch derivatives containing tertiary amino or quaternary ammonium groups and anionic phosphate groups are disclosed. The derivatives which are defined by a minimum bound phosphorus content, a minimum viscosity and other criteria have use as wet-end additives and provide improved drainage properties in the manufacture of paper.

Abstract: Polysaccharide aldehydes having the formula ##STR1## or Sacch--O--CH.sub.2 --Ar--CHO (II) such as starch, cellulose, and gum aldehydes, are useful as paper additives for imparting strength and as the granular or gelatinized portion of a corrugating adhesive. Those having formula I are prepared by a nonoxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. In the formula Ar is an aryl group, optionally containing an ether linkage, or an alkaryl group and A and A' are lower alkyls or together form at least a 5-membered cyclic acetal. The polysaccharide aldehydes are crosslinked by the addition of selected polyfunctional crosslinkers such as an aliphatic primary polyamine or polyketone.

Abstract: A dry process for preparation of cationic starch ethers by reaction of starch with alkylidene epoxides in the presence of water in an alkaline medium at a temperature of 5.degree. to 40.degree. C. in the presence of a finely divided silica.

Abstract: A process for producing novel water-soluble compounds of the formula (HO).sub.m --A--(OCH.sub.2 NR.sup.1 COR).sub.p comprises forming a dispersion of an aqueous solution of a substrate A(OH).sub.n which is an alcohol or, preferably, a carbohydrate and a derivatising reagent HOCH.sub.2 NR.sup.1 COR.sup.2 in a water immiscible liquid and azeotroping the dispersion to remove water and thereby to drive the condensation reaction. The process can achieve high degrees of substitution and is of particular use in the production of water-soluble unsaturated polymersable products, preferably methylol acrylamide derivatives, in a process in which the aqueous dispersed phase contains a water-soluble polymerisation inhibitor. The unsaturated products may be used as cross-linking monomers in many aqueous polymerisation reactions, for instance an aqueous composition containing them with a water-soluble photo-initiator system including a dye are used as curing inks.

Abstract: Polysaccharide aldehydes having the general structure ##STR1## such as starch, cellulose and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. R is (CH.sub.2).sub.n or a divalent aromatic group and n os 0 or greater; R.sup.1, R.sup.6, and R.sup.7 are hydrogen or an organic group; R.sup.2, R.sup.5, and R.sup.8 are (CH.sub.2).sub.m with m being 1-6; R.sup.3 and R.sup.4 are hydrogen or a lower alkyl; Y is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.

Abstract: Polysaccharide aldehydes having the general structure ##STR1## such as starch, cellulose and gum aldehydes, are useful for imparting wet, dry, or temporary wet strength to paper. They are prepared by a non-oxidative method which involves reacting the polysaccharide base, in the presence of alkali, with a derivatizing acetal reagent having the general structure ##STR2## and then hydrolyzing the acetal by adjusting the pH to less than 7, preferably 2-4. R is (CH.sub.2).sub.n or a divalent aromatic group and n is 0 or greater; R.sup.1, R.sup.6, and R.sup.7 are hydrogen or an organic group; R.sup.2, R.sup.5, and R.sup.8 are (CH.sub.2).sub.m with m being 1-6; R.sup.3 and R.sup.4 are hydrogen or a lower alkyl; Y is an anion; Z is an organic group capable of reacting with the polysaccharide base to form an ether derivative and selected from the group consisting of an epoxide, ethylenically unsaturated group, halohydrin, and halogen; R.sup.

Abstract: The present invention relates to a process for producing novel cationic starch comprising the step of reacting starch having cyanoethyl groups or starch having cyanoethyl groups and quaternary aminoalkyl groups with hydroxylamine or the salts thereof to amidoximate the reaction product.The resulting cationic starch of the invention exhibits significant advantages as compared with those of conventional cationic starch as a dry strengthening agent.

Abstract: Production of starch derivatives by reacting a starch derivatizing agent with chemically-mechanically gelatinized starch.

Abstract: A process for preparing a cationic starch dispersion wherein an alkaline, gelatinized starch is reacted with a cationic reagent either concurrently with, or subsequently to, the cooking process resulting in a product in which the cationic reagent is chemically bound to the starch molecule. The process is conducive to on-site preparation of a cationic starch derivative which can be utilized without additional treatment as a papermaking adjunct, textile size, waste-water treatment or tailings flocculent, etc.

Abstract: An improved size composition of a modified starch and polyvinyl alcohol especially useful as a textile size is disclosed. The modified starch is a hydroxyalkyl and tertiary amino alkyl starch with a D.S. of aminoalkyl groups between 0.02 to 0.30 and a M.S. of hydroxypropyl groups between 0.02 and 0.50. The ratio of polyvinyl alcohol: modified starch in the size composition varies between 1:9 and 9:1. The method of applying the size composition to yarn and the method of making the size composition are also disclosed. High amylose starch, as compared to common or waxy, is the preferred starch.

Abstract: An improved method is disclosed for producing amino polyols useful in preparing polyurethane foams. The improvement concerns charging ammonia, a primary amine or a secondary amine to the reaction vessel at the end of the oxide digestion step. The amine or ammonia scavenges the residual oxide and the resulting alkanol amine becomes one of the components of the polyol mixture. Alkanol amines are beneficial components of urethane polyols.In prior art industrial practice, residual oxide is vented to a scrubber system and then stripped to a low concentration.

Abstract: A method for the modification of starch by silanes wherein the starch and silane are contacted in an organic solvent in the presence of a metallic acid ester of a metal of groups IVB or VB of the Periodic Table of the elements. The resulting suspension is stirred. The subsequently separated starch exhibits better working characteristics than the corresponding unmodified starch.

Abstract: A process for making a cationic starch which comprises reacting by heating starch with a quaternary amine chlorohydrin in the presence of an alkali metal oxide or hydroxide, adding thereto after a period of time an alkaline earth oxide or hydroxide and maintaining the mixture for a time and at a temperature sufficient to complete the reaction, neutralizing filtering, washing and recovering the cationic starch product.

Abstract: A photocurable, ethylenically-unsaturated, water-soluble oligomer comprising the reaction product of 100 parts by weight of a dextrin compound, and 35 to 70 parts by weight of at least one ethylenically-unsaturated monomer capable of reacting with at least one hydroxyl group of the dextrin compound, the oligomer having an average in the range of 0.1 to 0.7 ethylenically-unsaturated moiety per anhydroglucose unit and an equivalent weight of 440 to 990, and at least 75 weight percent of the oligomer is water soluble at 20.degree. C. in a concentration of at least 2.5 percent by weight. The oligomer when photocured in combination with an ethylenically-unsaturated monomer is useful as a photoresist in positive-acting, water-developable, lithographic printing plates.

Abstract: Highly dielectric organic compounds can be obtained by cyanoethylating a dihydroxyalkylate of a water-soluble polysaccharide or a derivative thereof with acrylonitrile.

Abstract: Warp sizing compositions and starches useful therefor are prepared from high amylose starches which are converted to a water fluidity viscosity within the range of 65 to 80 and then reacted with an etherification reagent to achieve a nitrogen content of 0.5 to 0.9% (dry basis).

Abstract: A process whereby a gelatinized starch having a cationic reagent chemically bound to the starch backbone and a reduced viscosity is prepared by (1) gelatinizing starch and substantially simultaneous with gelatinization reacting said treated starch with an alkyl or alkenyl amine and a water soluble oxidant or (2) simultaneously reacting an alkyl or alkenyl amine and a water soluble oxidant with a gelatinized starch. The process is conducive to the on-site preparation of a thinned cationic starch derivative which can be utilized without additional treatment as a papermaking additive, textile size, waste water treatment, tailing flocculent, etc.

Abstract: A novel process for the preparation of starch-amine-based polyols which involves reacting starch with a polyhydric alcohol in the presence of an acid catalyst to form a crude polyglucoside reaction product, the proportion of alcohol to starch being at least 0.3 mole of alcohol per glucose unit weight of starch. An amine compound is admixed with the reaction product, and the mixture is then oxyalkylated with a lower alkylene oxide. Polyurethane foams may be prepared by reacting the resulting polyether polyols with an organic polyisocyanate in the presence of a foaming agent and a reaction catalyst. The physical properties of the resulting foams are excellent.

Abstract: A novel process for the preparation of starch-amine-based polyols which involves reacting starch with a polyhydric alcohol in the presence of an acid catalyst to form a crude polyglucoside reaction product, the proportion of alcohol to starch being at least 0.3 mole of alcohol per glucose unit weight of starch. An amine compound is admixed with the reaction product, and the mixture is then oxyalkylated with a lower alkylene oxide. Polyurethane foams may be prepared by reacting the resulting polyether polyols with an organic polyisocyanate in the presence of a foaming agent and a reaction catalyst. The physical properties of the resulting foams are excellent.

Abstract: The known process for the production of cationic starch ethers by the reaction of starch with cationic etherifying agents in the presence of water in an alkaline medium is improved by reacting the starch at a temperature of about 50.degree. to 120.degree. C. with an alkylidene epoxide which has a tertiary amino group or quaternary ammonium group in a medium which contains about 10 to 35 weight percent water and about 0.2 to 2.0 weight percent calcium hydroxide or calcium oxide. There are produced in short reaction times yields not previously attainable.

Abstract: The invention relates to the carbonylation of cross linked substituted and unsubstituted polysaccharides, their copolymers with macroporous synthetic polymers, macroporous synthetic polymers and rigid supports with pendant hydroxyalkyl groups. The carbonylated product can be used to prepare an affinity chromatography matrix which remains an uncharged species at varying pH's. The carbonylated product is also useful for the preparation of other compounds: Typical polysaccharides are agarose, starch, dextran, cellulose and regenerated cellulose, typical macroporous synthetic polymers are acrylamides, acrylates and methacrylates, typical rigid supports are silica beads coated with hydroxy alkyl groups and typical cabonylating agents are N,N'-carbonyl diimidazole; N,N'carbonyl di-1,2,3-benzotriazole; and N,N'-carbonyl di-1,2,4-triazole.

Abstract: The present invention relates to novel isocyano derivatives of linear or cross-linked, natural or synthetic macromolecules, the derivatives being of the general formula P--O--Q--NC, wherein P is the macromolecular backbone, the oxygen atom is part of the hydroxy group, Q is a group --(CH.sub.2).sub.n --wherein n is an integer of at least 3 carbon atoms, and up to about 20 carbon atoms, or Q is an aralkyl group, to a process for preparing such derivatives and to a process of linking to same biologically active proteins and to the products thus obtained.

Abstract: A method for oven drying chemically modified cellulosic materials, especially fibers, having improved fluid absorbency involves incorporating into the cellulose structure while swollen an amphiphilic compound miscible with water which will not evaporate when the fiber is oven dried and will remain in the fiber to prevent collapse of the fiber as the water is removed. The improved method of drying the fibrous cellulosic material produces a product having saline absorbency about equal to that produced when the fibers are dried with a water-miscible solvent and avoids the use of volatile solvents and the disadvantages inherent therewith. The fibers provided by the invention are especially suitable for use in pads which are to be used for absorbing water and body fluids.

Abstract: Cationic starch is prepared by an essentially pollution-free method wherein starch is reacted with a mixture of an epoxide etherifying reagent and alkali catalyst using substantially dry reaction conditions. The resultant cationic starches find particular use in papermaking applications.

Abstract: The present invention relates to a chloral derivative having the general formula ##STR1## in which Y' is a polysaccharide consisting of a chain of anhydroglucose, modified anhydroglucose or uronic acid units as substituent group and in which R is selected from --H, --COCH.sub.2 OH, --[(CH.sub.2).sub.n 0].sub..chi. --H in which n is 2 to 5 and .chi. is 1 to 7; --CH.sub.2 OSO.sub.2 X' or --CH.sub.2 COOX' in which X' is NH.sub.4 or a single equivalent of a non-toxic metallic cation, --(CH.sub.2).sub.n H where n is 1 to 7, --(CH.sub.2).sub.n (OH).sub..chi. Y where Y is --H or --CH.sub.3 n is 1 to 7, .chi. is 1 to 12 and the --OH groups are attached to any or all of the carbon atoms by substitution and wherein when Y.sup.1 is a chain of unmodified anhydroglucose units, these units have the following configurations:.alpha.-D-glucopyranosyl units having a predominantly 1-4 linkage.beta.-D-glucopyranosyl units having a predominantly 1-4 linkage and/or.beta.

Abstract: Starch ether derivatives are prepared by reacting a starch base with N-(2-haloethyl)iminobis(methylene)diphosphonic acid or with a N-(alkyl)-N-(2-haloethyl)aminomethylphosphonic acid. The derivatives contain aminophosphonic acid groups (or their salts) as zwitterion substituents which consist of either one or two anionic methylene phosphonic acid groups bound to a cationic nitrogen. Their cationic or anionic characteristics may be increased by introducing suitable cationic or anionic groups either by simultaneous reaction with the aminophosphonic acid reagent or by consecutive reaction either prior to or subsequent to the aminophosphonic acid reaction. They are especially useful as pigment retention aids in paper making processes.

Abstract: Crosslinked starch is reacted with an epihalohydrin in the presence of a strong acid catalyst to produce the 3-halo-2-hydroxypropyl ether. Substitution of the halogen with nitrogen-containing compounds enables the preparation of novel water-insoluble cationic, anionic, and chelating starch ethers, as well as starch ethers having degrees of substitution heretofore unattainable in the prior art.

Abstract: Carbonylation of a polysaccharide and the product of that carbonylation. The carbonylated product can be used to prepare an affinity chromatography matrix which is an uncharged species of varying pH's. The carbonylated product is also useful for the preparation of other compounds. Typical polysaccharides are agarose, starch, dextran, cellulose and regenerated cellulose and typical carbonylating agents are N,N'-carbonyl diimidazole; N,N' carbonyl di-1,2,3-benzotriazole; and N,N'-carbonyl di-1,2,4-triazole.

Abstract: A process and apparatus are described for producing modified starch products. In the method of the invention, a slurry of starch is continuously moved at elevated temperature and pressure through a tubular heating zone and the hot fluid mass emerging from the heating zone is forced through a flow restricting zone within which the fluid mass is highly compressed. This highly compressed fluid material emerges from the confining zone into a tubular reaction zone with a sudden release of energy in the form of a fine spray or mist. The compressive forces followed by the sudden energy release act on the starch molecules to temporarily greatly increase the reactivity of the starch within the reaction zone, whereby modified starch products are quickly formed.

Abstract: A novel starch ether derivative of which the crosslinking properties may be altered by adjusting the pH of the cook is prepared by reacting under controlled conditions a starch base in aqueous medium with an N-(alkoxymethyl)acrylamide wherein the alkoxy group contains 1-4 carbon atoms, and is preferably an isobutoxy group. The starch derivatives herein may be used as insolubilizing or strengthening agents in adhesives, coatings, and in other applications wherein controlled crosslinking is desirable.

Abstract: Covers an aminated starch derivative prepared by the reductive amination of an oxidized starch by reaction with ammonia or ammonium hydroxide. Also, covers a process of preparing said derivative.

Abstract: A polysaccharide or polyvinyl alcohol containing a mixture of nitrite ester groups with sulfate or nitrate ester groups with the mixture of ester groups being substantially uniformly distributed among the polymer units of the polysaccharide or polyvinyl alcohol.A nitrite ester of a polysaccharide alcohol having a degree of substitution of less than about 2.0. A nitrite ester of polyvinyl alcohol having a degree of substitution of 1.0 or less.

Abstract: A novel process is disclosed for preparing cationic starches and flours by reacting starch-containing materials in a dry state with a halohydrin at a pH of 9 or below without the necessity for subsequent alkali neutralization or washing. The resultant products have cationic properties remarkably superior to prior art cationic starches over a broad range of acid and alkaline pH's. In the manufacture of paper, they serve as excellent pigment retention and dry-strength improvement agents.

Abstract: Covers an aminated starch derivative prepared by the reductive amination of an oxidized starch by reaction with a dialkyl amine. Also, covers a process of preparing said derivative.

Abstract: Novel starch ether derivatives are prepared by reacting starch with 3-chloro-2-sulfopropionic acid. The resulting 2-sulfo-2-carboxyethyl starch ether derivatives find use in many applications, but are particularly useful as pigment retention aids in papermaking processes.

Abstract: This invention relates to an improvement in the process for the manufacture of modified starch ethers in which, prior to, during, or after etherification, a reaction with a modifying agent is conducted in a wet alkaline medium, the improvement comprising that, if etherification were the only reaction conducted, an at least preponderantly water-soluble starch ether would be formed, and the modification results in an absorbent modified starch ether more than 40 per cent by weight of which is insoluble in water.

Abstract: Water-absorbent, starch copolymerizates are prepared by copolymerizing an ethylenically unsaturated starch with other ethylenically unsaturated monomers which contain water-attractant groups or precursors of water-attractant groups. The water-absorbent starch copolymerizates may be easily prepared into the desired configuration for a particular end-use or combined with other substrates or carriers. The unpolymerized starch and monomers or precursors thereof may be applied or incorporated into a suitable carrier or substrate (e.g., cellulosic materials such as textiles, papers, etc.) and copolymerized in situ to provide a composite article of unitary construction with the water-absorbent starch copolymerizate permanently bonded or affixed thereto.

Abstract: Preformed, homogeneous, non-linear starch copolymerizate articles may be prepared by copolymerizing a preformed, homogeneous mixture of water, ethylenically unsaturated starch and ethylenically unsaturated monomers to provide a labyrinth of copolymerized starch chains interconnected with each other by the copolymerized monomeric units. The invention is particularly suitable for preparing high-binder, aqueous coating compositions which may be applied to a variety of substrates and subsequently copolymerized with polymerization initiating systems. Improved water- and detergent-resistance may be obtained by incorporating film-forming additives, cross-linking reagents or polyunsaturated compounds into the copolymerizable starch composition.

Abstract: Diethylaminoethyl (DEAE)-Cotton, prepared so that the tertiary amine nitrogens have unshared electrons and are thus in the Lewis-base form, is reacted with an alcoholic solution of an alpha-omega dihaloalkane to quaternize amino groups. The fabric produced by this process is crosslinked between tertiary amine nitrogen groups in cellulose and every alkylene group introduced is connected to two quaternary ammonium ions. The products of this process have strong base anion exchange properties and fabrics of high nitrogen content are imparted both wet and dry crease resistance.

Abstract: The invention relates to starch acrylamides containing polymerizable pendant acrylamide groups. The hydrophilic or hydrophobic properties of the starch can be altered or modified by the acrylamide groups or the type of starch chain. The starch acrylamides can be homopolymerized or copolymerized with other ethylenically unsaturated monomers as well as other cross-linking reagents to provide water-resistant, clear, flexible coatings or shaped articles. The hydrophilic starch acrylamide hydrolyzates herein readily disperse into water at a high solids level to provide low-viscosity pastes which may be used as a vehicle to prepare flexible, water-insoluble starch-based coatings. The starch acrylamides may be prepared by etherifying a starch with N-methylol acrylamides in the presence of an acid catalyst and a polymerization inhibitor.

Abstract: A reagent for the modification of starch is prepared from the reaction of a 2,3-dihalopropionamide with a secondary amine. When starch is treated with this modifying reagent, a novel cationic starch characterized by the presence of a carboxamide group bound directly to a cationic amine substituent is produced.

Abstract: Preparation of partially substituted nitrate and sulfate esters of polysaccharides or polyvinylalcohol, their esters containing a mixture of nitrite with sulfate or nitrate groups, aqueous media thickened with such esters, the simultaneous preparation of such esters and alkyl nitrites or such esters and inorganic nitrites or nitrates and resulting products, useful as thickeners, films, fibers and in many other applications.

Abstract: Paper and other cellulose materials are sized with a cationic starch which comprises the reaction product between an anionic starch and a condensate of epichlorohydrin with an equimolar quantity of dimethylamine, in which up to 30% molar ammonia may be substituted for a like molar amount of dimethylamine.

Abstract: A reagent useful for the chemical modification of starch is prepared by the reaction of a 2,3-dihalopropionic acid or alkyl ester thereof with a secondry amine. The reaction of the reagent with starch, carried out in an aqueous solution under controlled conditions, produces novel amino acid ether derivatives which are characterized by the presence of both a cationic and an anionic substituent group on the same reactive site. The resulting starch ethers are characterized by their stability, their ability to form cooked pastes which are more resistant to gelling upon cooling and their lowered gelatinization temperatues.

Abstract: This invention relates to novel polymers containing a plurality of hydroxyl groups having aminimide groups attached thereto through an ether linkage and to methods for attaching said aminimide groups onto said polymers containing a plurality of hydroxyl groups.

Abstract: A polysaccharide or polyvinyl alcohol containing a mixture of nitrite ester groups with sulfate or nitrate ester groups with the mixture of ester groups being substantially uniformly distributed among the polymer units of the polysaccharide or polyvinyl alcohol.A nitrite ester of a polysaccharide alcohol having a degree of substitution of less than about 2.0. A nitrite ester of polyvinyl alcohol having a degree of substitution of 1.0 or less.