Bonded To Triazine Ring Carbon Patents (Class 544/216)
  • Patent number: 4639436
    Abstract: The invention includes certain 3,4,5-trihydroxypiperidine compounds, methods for their preparation, compositions containing said 3,4,5-trihydroxypiperidine compounds and methods for the use of said compounds and compositions.The subject matter of the invention is useful against diabetes, hyperlipaemia and adiposity as well as in animal nutrition.
    Type: Grant
    Filed: August 23, 1978
    Date of Patent: January 27, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bodo Junge, Hans P. Krause, Lutz Muller, Walter Puls
  • Patent number: 4619998
    Abstract: Light-sensitive compounds are described which have the formula ##STR1## wherein R.sup.1 and R.sup.2 denote H or alkyl, R.sup.3 and R.sup.4 denote H or 4,6-bis-trichloromethyl-s-triazin-2-yl, R.sup.5 and R.sup.6 denote H or halogen, alkyl, alkenyl or alkoxy, and Ar denotes a mononuclear to trinuclear aromatic group.These compounds are suitable as photoinitiators for free-radical polymerization or as photolytic acid donors for acid-cleavable compounds, and for cross-linking and color formation reactions. They are distinguished by a high sensitivity in various spectral ranges.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: October 28, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Gerhard Buhr
  • Patent number: 4616002
    Abstract: Compounds of the formula I ##STR1## in which n represents 1, 2 or 3, Ar represents a carbocyclic or heterocyclic aryl radical, Ac represents the acyl radical of an acid, Z represents a radical --OR.sub.7 or --NR.sub.8 R.sub.9, R.sub.1 represents hydrogen, unsubstituted or substituted lower alkyl, a carbocyclic or heterocyclic aryl radical or free, etherified or esterified hydroxy, R.sub.2 and R.sub.3, independently of one another, each represents hydrogen, unsubstituted or substituted lower alkyl, formyl or functionally modified formyl, carboxy or functionally modified carboxy, a carbocyclic or heterocyclic aryl radical or unsubstituted or mono- or di-substituted amino, R.sub.4 represents hydrogen or lower alkyl, R.sub.5 and R.sub.6, independently of one another, each represents hydrogen, unsubstituted or substituted lower alkyl or a carbocyclic or heterocyclic aryl radical, R.sub.7, R.sub.8 and R.sub.
    Type: Grant
    Filed: January 6, 1986
    Date of Patent: October 7, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Bruno Kamber, Thomas Leutert, Hans Kuhnis, Kurt Eichenberger
  • Patent number: 4610824
    Abstract: Antibacterial activity is exhibited by novel compounds having the formula ##STR1## and pharmaceutically acceptable salts thereof.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: September 9, 1986
    Assignee: E. R. Squibb & Sons, Inc.
    Inventor: Uwe D. Truner
  • Patent number: 4578386
    Abstract: Provided are compounds of the structure: ##STR1## wherein R.sub.1, R.sub.3, R.sub.5 and R.sub.6 are independently H, alkyl, aralkyl, aryl, substituted aryl, heteroaryl, substituted heteroaryl, alkenyl, alkynyl, hydroxy, hydroxyalkyl, alkoxy, mercapto, mercaptoalkyl, alkylthio, amino, alkylamino, aminoalkyl, formyl, carboxy and salts thereof, carbalkoxy, alkanoyl, cyano, nitro, halo, trifluoromethyl, alkylsulfonyl, aminosulfonyl, carbamoyl or cycloalkyl; andR.sub.7 is H, alkyl, aryl, aralkyl, oxo, or alkanoyl;wherein at least one of R.sub.1 R.sub.5 or R.sub.6 is an aryl, heteroaryl, or heteroaryl substituted with H, alkyl, halo, amino, trifluoromethyl or cyano.
    Type: Grant
    Filed: February 10, 1984
    Date of Patent: March 25, 1986
    Assignee: USV Pharmaceutical Corp.
    Inventor: Thomas D. Lee
  • Patent number: 4565815
    Abstract: A compound having anti-ulcer activity and having the formula ##STR1## wherein D is H, SH, NH.sub.2, OH, R.sup.4 S where R.sup.4 is a lower alkyl group; E is OH or NH.sub.2 ; J is H or aryl; X is CH or N; Y is CH, N, or CT, wherein T is a halogen; Z is CH or N; A is ##STR2## and replaces a hydrogen of D, X, or E; R.sup.1 is H or CH.sub.3 ; L is CH.sub.2 S; Q is O or CH.sub.2 S; n is 0 or 1; 2 m 4; each R.sup.2 and R.sup.3, independently, is H, lower alkyl, cycloalkyl, or arylalkyl; or R.sup.2 and R.sup.3, together with the nitrogen atom to which they are attached, form a 4, 5, or 6 membered heterocyclic ring containing 0, 1, or 2 oxygen atoms and 1, 2, or 3 nitrogen atoms and being unsubstituted or lower alkyl substituted; or a pharmaceutically acceptable salt thereof.
    Type: Grant
    Filed: May 25, 1984
    Date of Patent: January 21, 1986
    Assignee: Biomeasure, Inc.
    Inventors: Sun H. Kim, Jacques-Pierre Moreau
  • Patent number: 4562185
    Abstract: The present invention relates to combating pests with five-membered nitrogen-containing heterocyclic compounds of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, X and Y have the meaning given in the description. Many of the compounds are new.
    Type: Grant
    Filed: March 15, 1984
    Date of Patent: December 31, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Jager, Rudolf Fauss, Kurt Findeisen, Benedikt Becker, Bernhard Homeyer
  • Patent number: 4559401
    Abstract: An improved method for the preparation of chromophore-substituted vinyl-halomethyl-s-triazines especially 2-(p-methoxystyryl)-4,6-bis-(trichloromethyl)-s-triazine. In the known preparation of these compounds, a two step procedure is utilized wherein an intermediate reaction product has to be isolated. This step of separating the intermediate is eliminated in the present process by dissolving the crude reaction product obtained in the first step in toluene, removing excess hydrogen chloride gas and catalysts by purging the reaction product solution with an inert gas, and then reacting p-anisaldehyde with the toluene solution of the reaction product mixture using piperidinium acetate catalyst to obtain 2-(p-methoxystyryl)-4,6-bis-(trichloromethyl)-s-triazine.As a further improvement of the art the Knoevenagel-type condensation is run until no further water is evolved. At this point the product formed is isolated by filtration and a like amount of catalyst as a second charge is added.
    Type: Grant
    Filed: June 4, 1984
    Date of Patent: December 17, 1985
    Assignee: Polychrome Corporation
    Inventors: William Rowe, Thomas Dooley, Ajay Shah
  • Patent number: 4523947
    Abstract: There are described triazine derivatives of the formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 independently of one another are each C.sub.1 -C.sub.5 -alkyl which is unsubstituted or monosubstituted by C.sub.3 -C.sub.6 -cycloalkyl, or mono- or polysubstituted by halogen, or is C.sub.3 -C.sub.6 - cycloalkyl which is unsubstituted or mono- or polysubstituted by halogen, or one of the substituents R.sub.1, R.sub.2 and R.sub.3 is also halogen or --NR.sub.4 R.sub.5, in which R.sub.4 is hydrogen or C.sub.1 -C.sub.5 -alkyl and R.sub.5 is hydrogen, C.sub.1 -C.sub.5 -alkyl, monochloroacetyl or dichloroacetyl. The triazine derivatives are used for the protection of maize and sorghum plants against the harmful effects of herbicidal chloroacetanilides and chloroacetamides.
    Type: Grant
    Filed: May 29, 1984
    Date of Patent: June 18, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Henry Szczepanski, Dagmar Berrer
  • Patent number: 4517010
    Abstract: There is provided a new class of derivatives of 2-nitro-5-(substituted-phenoxy) benzoyl compounds that have pre- and post-emergence herbicidal activity. The derivatives include certain substituted phenyl esters, phenyl thioesters; heterocyclic esters; substituted alkyl and alkylthio esters; carbonates and thiocarbonates; benzoyl phosphonates; substituted alkanones and substituted amides.
    Type: Grant
    Filed: April 15, 1983
    Date of Patent: May 14, 1985
    Assignee: Rhone-Poulenc Inc.
    Inventor: Robert J. Theissen
  • Patent number: 4497951
    Abstract: Acetylene terminated s-triazine oligomers are disclosed which polymerize into stable high temperature resins. The oligomers of this invention are readily prepared from off-the-shelf starting materials, they are soluble in conventional low boiling solvents and exhibit low melting points which facilitate ease of processing.
    Type: Grant
    Filed: April 21, 1983
    Date of Patent: February 5, 1985
    Assignee: Hughes Aircraft Company
    Inventor: Thomas W. Giants
  • Patent number: 4496392
    Abstract: Heterocyclic alkylaminocarbonylsulfonamides, such as N'-[(4,6-dimethylpyrimidin-2-yl)methylaminocarbonyl]-N,N-dimethyl-1,2-benz enedisulfonamide, are useful as herbicides.
    Type: Grant
    Filed: March 14, 1983
    Date of Patent: January 29, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: George Levitt
  • Patent number: 4493728
    Abstract: Hexahydrotriazinones substituted by a 5-substituted-1,2-oxazol-3-yl moiety, useful for controlling the growth of unwanted plants.
    Type: Grant
    Filed: June 27, 1983
    Date of Patent: January 15, 1985
    Assignee: Shell Oil Company
    Inventor: Kurt H. Pilgram
  • Patent number: 4486219
    Abstract: A compound of the formula ##STR1## wherein each R is H or alkyl and W is an optionally substituted unsaturated, cycloalkyl, secondary alkyl, aromatic or heterocyclic group, are useful as plant growth regulators and herbicides. The corresponding 6-oxabicyclo[3.2.1]octan-4-ols and 6-oxabicyclo[3.2.1]octan-4-ones are novel intermediates.
    Type: Grant
    Filed: April 21, 1983
    Date of Patent: December 4, 1984
    Assignee: Shell Oil Company
    Inventor: James E. Powell
  • Patent number: 4450093
    Abstract: There are disclosed dyes, compositions, imaging elements, and methods of forming images, wherein cyclopropenones are reacted with di- or tri-halogenated compounds in the presence of pyridine to form said dyes. In areas exposed to activating radiation, the cyclopropenone decomposes and prevents the dye reaction from occurring.
    Type: Grant
    Filed: November 22, 1982
    Date of Patent: May 22, 1984
    Assignee: Eastman Kodak Company
    Inventors: George L. Fletcher, Donald H. Wadsworth
  • Patent number: 4412856
    Abstract: The novel compounds of the formula I are useful selective herbicides for postemergence application in crops of cereals, maize and rice.In formula I, ##STR1## A is an unsubstituted or substituted amino group, Q is a C.sub.2 -C.sub.6 alkylene bridge, Y is an oxygen or sulfur atom or an unsubstituted or substituted nitrogen atom, and Z is an unsubstituted or substituted phenyl, naphthyl or heterocyclic radical, which phenyl radical, containing the bridge member Y, can additionally carry one to four further substituents.
    Type: Grant
    Filed: May 22, 1981
    Date of Patent: November 1, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans-Georg Brunner, Rolf Schurter, Henry Szczepanski
  • Patent number: 4393077
    Abstract: Compounds having the formula: ##STR1## wherein X.sub.1, X.sub.2, R, R.sub.1, R.sub.2 and R.sub.3 are as set forth hereinafter, their preparation and uses as ganglionic blocking agents are disclosed.
    Type: Grant
    Filed: July 2, 1981
    Date of Patent: July 12, 1983
    Assignee: William H. Rorer, Inc.
    Inventors: George H. Douglas, Henry F. Campbell
  • Patent number: 4391687
    Abstract: Photopolymerizable mixture of (a) acrylic monomer such as 95 parts of an alkyl acrylate and 5 parts of acrylic acid and (b) 0.01 to 2 parts by weight of a chromophore-substituted-halomethyl-s-triazine such as ##STR1## The novel mixtures are primarily useful as pressure-sensitive adhesive mixtures.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: July 5, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: George F. Vesley
  • Patent number: 4373021
    Abstract: There are disclosed dyes, compositions, imaging elements, and methods of forming images, wherein cyclopropenones are reacted with di- or tri-halogenated compounds in the presence of pyridine to form said dyes. In areas exposed to activating radiation, the cyclopropenone decomposes and prevents the dye reaction from occurring.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: February 8, 1983
    Assignee: Eastman Kodak Company
    Inventors: George L. Fletcher, Donald H. Wadsworth
  • Patent number: 4332722
    Abstract: An intermediate represented by the following formula, for synthesizing --3-hydroxy-3-cephem compounds. ##STR1## wherein A and B each is a hydrogen or amino substituent; R is a hydrogen or thiol substituent; Hal is a halogen; X is a hydroxy or carboxy protecting group; the broken line between A and R shows that when R and B are hydrogens, and A is a carboxylic acyl, the substituents can be combined to form an azetidinothiazoline bicyclic ring; and the enamine derivatives thereof.
    Type: Grant
    Filed: February 27, 1980
    Date of Patent: June 1, 1982
    Assignee: Shionogi & Co., Ltd.
    Inventors: Teruji Tsuji, Yoshio Hamashima, Mitsuru Yoshioka, Masayuki Narisada, Hiroshi Tanida, Taichiro Komeno, Wataru Nagata
  • Patent number: 4330590
    Abstract: Photopolymerizable mixture of (a) acrylic monomer such as 95 parts of an alkyl acrylate and 5 parts of acrylic acid and (b) 0.01 to 2 parts by weight of a chromophore-substituted-halomethyl-s-triazine such as ##STR1## The novel mixtures are primarily useful as pressure-sensitive adhesive mixtures.
    Type: Grant
    Filed: February 14, 1980
    Date of Patent: May 18, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: George F. Vesley
  • Patent number: 4329384
    Abstract: Pressure-sensitive adhesive tape, the adhesive layer of which is produced from a mixture of (1) a pressure-sensitive adhesive alkyl acrylate polymer and (b) a polynuclear-chromophore-substituted halomethyl-s-triazine such as ##STR1## which has been exposed to ultraviolet radiation to cause the polymer to become crosslinked.
    Type: Grant
    Filed: February 14, 1980
    Date of Patent: May 11, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: George F. Vesley, John D. Moon
  • Patent number: 4291147
    Abstract: Polyadducts, free from epoxide groups, are obtained from ammonia and epoxide compounds by reacting 1 mole of ammonia with from 1.2 to 2.0 equivalents of epoxide, so that if diepoxide compounds are used products of the general formula (I) ##STR1## are obtained, while if triepoxides and/or tetraepoxide compounds are used, by themselves, or together with diepoxide compounds, products of the general formula II ##STR2## are produced; in these formulae, the E.sup.1 's are identical or different hydroxyl-containing divalent radicals and the E.sup.2 's are identical or different hydroxyl-containing trivalent or tetravalent radicals, resulting from the opening of the oxirane rings of epoxide compounds containing two, three or four epoxide groups in the molecule, n.sup.1, n.sup.3 and n.sup.5 are from 0 to 3, n.sup.2 and n.sup.4 are from 1 to 3 and X is 0 or 1, and one or more of the divalent radicals E.sup.1 in the general formula (II) may or may not be replaced by polyvalent radicals E.sup.2.
    Type: Grant
    Filed: April 7, 1980
    Date of Patent: September 22, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz E. Kempter, Eberhard Schupp, Hans-Uwe Schenck, Erich Gulbins
  • Patent number: 4289892
    Abstract: Active hydrogen-containing fluorochemical is used as a foam stabilizer for polyurethane foams. For example, rigid or flexible polyurethane foams with high or low density and uniform cellular structure are prepared using fluoroaliphatic radical-substituted poly(oxyalkylene) polyols as foam stabilizers.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: September 15, 1981
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Fredrich A. Soch
  • Patent number: 4260622
    Abstract: The invention includes certain 3,4,5-trihydroxypiperidine compounds, methods for their preparation, compositions containing said 3,4,5-trihydroxypiperidine compounds and methods for the use of said compounds and compositions.The subject matter of the invention is useful against diabetes, hyperlipaemia and adiposity as well as in animal nutrition.
    Type: Grant
    Filed: September 20, 1979
    Date of Patent: April 7, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bodo Junge, Hans P. Krause, Lutz Muller, Walter Puls
  • Patent number: 4247692
    Abstract: Novel triazine derivatives which are with cyanoacetic acid, derivatives of cyanoacetic acid or malodinitrile substituted s-triazines and which provide stabilizers against ultraviolet radiation for organic polymers such as polyvinyl chloride or copolymers of polyvinyl chloride or polypropylene are obtained by reacting the corresponding chloro-s-triazinyl derivatives with sodium hydride or a metal lower alcoholate in an organic solvent, and isolating the resulting product by acidification.
    Type: Grant
    Filed: June 19, 1978
    Date of Patent: January 27, 1981
    Assignee: Akzona Incorporated
    Inventors: Hermannus J. M. Sinnige, Hendrik J. Hageman, Willem J. Mijs, Stephanus A. G. de Graaf, Vincent Oakes
  • Patent number: 4220765
    Abstract: A process for the preparation of a 4,6-dihalogeno-triazine of the formula ##STR1## wherein R represents an aryl or aryloxy radical or 5 or 6-membered nitrogen-containing aromatic heterocyclic radical which can be optionally mono or polysubstituted by a C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogeno, nitro, cyano, C.sub.1 -C.sub.4 -carbalkoxy, aryl or aryloxy andHal.sup.1 denotes a halogen atom is described wherein a trihalogenomethyl compound of the formulaR--C (Hal.sup.2).sub.3whereinR has the meaning indicated above andHal.sup.2 represents a halogen atom is reacted with Hal.sup.1 --CN in which Hal.sup.1 has the meaning indicated above at a temperature of 50.degree. to 200.degree. C. in the presence of a Lewis acid. Optionally the process can be conducted in the presence of an inert solvent.
    Type: Grant
    Filed: November 30, 1978
    Date of Patent: September 2, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventor: Kurt Findeisen
  • Patent number: 4217377
    Abstract: This invention is directed to low molecular weight, solid addition products having a softening point above 100.degree. F. and the method of preparing same and more particularly to the use of said addition products as crosslinking agents in various polymeric powder coatings, e.g. polyesters. The solid, low molecular weight products are derived from the addition reaction of at least one monohydroxy, single-ring aromatic carbon compound and hexakis (alkoxymethyl) amino-triazine.
    Type: Grant
    Filed: April 13, 1979
    Date of Patent: August 12, 1980
    Assignee: The Sherwin-Williams Company
    Inventors: Greg D. Shay, James H. Griffith
  • Patent number: 4189323
    Abstract: This invention relates to a radiation sensitive composition which comprises, as the radiation sensitive compound, an s-triazine corresponding to Formula I ##STR1## wherein X is bromine or chlorine, and m and n are whole numbers from 0 to 3 which, taken together, do not exceed 5, and in which R is a substituted or unsubstituted bi- or polynuclear aromatic or heterocyclic aromatic group which may be partially hydrogenated and which is linked via an unsaturated nuclear carbon atom.
    Type: Grant
    Filed: April 24, 1978
    Date of Patent: February 19, 1980
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Gerhard Buhr
  • Patent number: 4189421
    Abstract: This invention is directed to low molecular weight, solid addition products having a softening point above 100.degree. F. and the method of preparing same and more particularly to the use of said addition products as crosslinking agents in various polymeric powder coatings, e.g. polyesters. The solid, low molecular weight products are derived from the addition reaction of at least one monohydroxy, single-ring aromatic carbon compound and hexakis (alkoxymethyl) amino-triazine.
    Type: Grant
    Filed: May 20, 1977
    Date of Patent: February 19, 1980
    Assignee: The Sherwin-Williams Company
    Inventors: Greg D. Shay, James H. Griffith
  • Patent number: 4165434
    Abstract: Novel dyestuffs comprising at least one laser dyestuff radical and at least one fluorescent dyestuff radical, where the fluorescent range of the fluorescent dyestuff radical overlaps the absorption range of the laser dyestuff radical and is linked with the laser dyestuff radical directly or via a bridge member having a length of at most 20 A in such a manner that the .pi. electron systems of the individual radicals are decoupled, are outstandingly effective and long lived when used in dyestuff lasers. The dyestuffs can be of the formula:X--(CR.sub.1 R.sub.2).sub.n --X--[(CR.sub.1 R.sub.2).sub.n --X].sub.mwhereinN is 0 or an integer from 1 up to a number corresponding to a chain length of 20 A,m is 0, 1, 2 or 3,X is a laser dyestuff radical L or a fluorescent dyestuff radical F andR.sub.1 and R.sub.
    Type: Grant
    Filed: June 1, 1977
    Date of Patent: August 21, 1979
    Assignee: Max-Planck-Gesellschaft zur Forderung der Wissenschaften e.V.
    Inventors: Fritz P. Schafer, Wolfgang Luttke
  • Patent number: 4122233
    Abstract: Monomers of the formulas ##STR1## WHEREIN R and R.sup.1 are generally lower hydrocarbyl groups, R.sup.2 is an aromatic ultraviolet light-absorbing moiety bonded by aromatic carbon, a is 0 or 1 and b is 1 or 2 are useful in the formulation of light- and abrasion-resistant coatings for polymers.
    Type: Grant
    Filed: June 24, 1977
    Date of Patent: October 24, 1978
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Stephen Proskow
  • Patent number: 4058537
    Abstract: This invention describes new perfluoroalkyl substituted esters, diesters and polyesters which contain at least one cyclic 5-membered anhydride group or two carboxy groups, as well as half amides and half esters thereof; their synthesis and their use as surface-active reactants in polycondensate resin systems.The anhydrides are synthesized by reaction of perfluoroalkyl substituted alcohols or diols with dianhydrides or an anhydrides-acid chloride and have the general structure ##STR1## wherein: Q is the tetra-radical rest of a tri- or tetracarboxylic acid, which contains at least one 1,2-dicarboxy grouping,X is hydrogen or COOH,R.sub.f is a perfluoroalkyl or perfluoroalkoxy-perfluoroalkyl group of 4 to 18 carbon atoms,a is 1 or 2,A is hydrogen or ##STR2## wherein: M IS AN INTEGER FROM 0 TO 5, ANDR.sup.3 is the residue of a R.sub.f substituted alcohol or diol.
    Type: Grant
    Filed: January 5, 1976
    Date of Patent: November 15, 1977
    Assignee: Ciba-Geigy Corporation
    Inventor: Karl Friedrich Mueller