Plural Polycyclo Ring Systems Having The Oxazole Ring As One Of The Cyclos In Each Of The Ring Systems Patents (Class 548/219)
  • Patent number: 4831152
    Abstract: Novel benzoxazole compound having, at the 2 position, a group bonding through a carbon atom having no or one hydrogen atom and introduced with a chlorine or bromine atom at the 5 position. The compounds are key intermediates useful for preparing 2-amino-5-nitrophenol derivatives which are useful as intermediates for synthesis of industrial materials, reducing agents, antioxidants, cyan-image-forming couplers and the like.
    Type: Grant
    Filed: June 14, 1985
    Date of Patent: May 16, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Isamu Itoh, Mitsunori Ono, Hidetoshi Kobayashi, Kazuyoshi Yamakawa
  • Patent number: 4794071
    Abstract: An improved photographic support, especially useful for color prints, is comprised of a paper base material having thereon a polyolefin coating containing a white pigment and a mixture of optical brighteners, such mixture comprising certain fluorescent bis(benzoxazolyl)stilbenes. The support exhibits improved brightness at low brightener concentration and unexpected resistance to brightener exudation.
    Type: Grant
    Filed: March 23, 1987
    Date of Patent: December 27, 1988
    Assignee: Eastman Kodak Company
    Inventors: Donna L. Tomko, Kenneth Harbison
  • Patent number: 4746351
    Abstract: This invention relates to herbicidally active substituted benzoxazole (or benzothiazole) compounds and to the use of such compounds to control the growth of noxious plants, i.e., weeds.
    Type: Grant
    Filed: May 12, 1986
    Date of Patent: May 24, 1988
    Assignee: PPG Industries, Inc.
    Inventor: Donald R. Nielsen
  • Patent number: 4707548
    Abstract: Novel bisisoindoline pigments of the formula (I) ##STR1## where the radicals A are identical or different radicals of a methylene-active compound, X is a divalent radical and the rings L are each unsubstituted or substituted, possess good fastness properties and are therefore suitable for a very wide range of applications, for example for pigmenting plastics, printing inks and surface coatings.
    Type: Grant
    Filed: January 24, 1986
    Date of Patent: November 17, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Lotsch, Gustav Bock, Peter Neumann
  • Patent number: 4701512
    Abstract: The adducts of isocyanates wtih benzoxazolones or benzoxazinediones are novel compounds which may be employed as blocked isocyanates and are particularly useful as latent, epoxide curing agents. At typical epoxide curing temperatures, the isocyanate is oxirane or hydroxyl reactive and the benzoxazole or benzoxazinedione acts like a di- or trifunctional phenol, respectively.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: October 20, 1987
    Assignee: The Dow Chemical Company
    Inventor: Theodore L. Parker
  • Patent number: 4661600
    Abstract: A process for the production of a product selected from the group consisting of a 2-oxazoline or a 2-oxazine and a 2-imidazoline or a 2-imidazine comprising reacting a bicyclic amide acetal with a member selected from the group consisting of an alkanol amine and an alkylene polyamine, respectively, at a temperature in the range of from about 20.degree. C. to 200.degree. C. is described.
    Type: Grant
    Filed: May 20, 1985
    Date of Patent: April 28, 1987
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4661583
    Abstract: The process for preparing novel monomers and polymers by reaction of a bicyclic amide acetal with an imide compound at a temperature in the range of from about 0.degree. C. to 250.degree. C. is disclosed.
    Type: Grant
    Filed: June 24, 1985
    Date of Patent: April 28, 1987
    Assignee: Ashland Oil, Inc.
    Inventor: Anil B. Goel
  • Patent number: 4652655
    Abstract: An improved process for preparing bicyclic amide acetals from an organic nitrile and a dialkanol amine wherein the reaction temperature is maintained in the range of from room temperature to 140.degree. C., and the bicyclic amide acetal product is removed from the reaction mixture by extraction into a hydrocarbon or organic nitrile solvent prior to its purification is described.
    Type: Grant
    Filed: May 20, 1985
    Date of Patent: March 24, 1987
    Assignee: Ashland Oil, Inc.
    Inventors: Anil B. Goel, Harvey J. Richards
  • Patent number: 4585875
    Abstract: A process for preparing 4,4'-bis-benz-ox(-thi,-imid)-azol-2-yl-stilbenes of the formula ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 may be the same or different from each other and denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, chlorine, bromine, nitro or sulfo and X denotes oxygen, sulfur or NH, which comprises reacting a (4-chloromethyl)-iminobenzoic acid alkyl ester of the formula ##STR2## wherein R denotes C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxyethyl, or HCl salts thereof, with o-aminophenol, o-aminothiophenol or o-phenylene diamine and reacting the resulting 2-benz-ox(-thi,-imid)-azolyl-4-chloromethyl-benzenes with potassium hydroxide or sodium hydroxide in a polar aprotic solvent.
    Type: Grant
    Filed: February 16, 1984
    Date of Patent: April 29, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Lorenz Heiss
  • Patent number: 4552876
    Abstract: Compounds of the formula: ##STR1## wherein, R is H, alkyl, cycloalkyl, aryl, or heteroaryl;R.sub.1 is H, alkyl, cycloalkyl, aryl, heteroaryl, substituted heteroaryl, aralkyl, substituted aryl, halo, OR.sup.2, SR.sup.2, NR.sub.2, CF.sub.3, NO.sub.2, CN, COOR.sup.2, CHO, SO.sub.3 H or SO.sub.2 NH.sub.2,whereinR.sup.2 is H, methyl, ethyl or propyl;Y is ##STR2## Z is O, S, NH or CH.sub.2 ; X is --CH.sub.2 --, ##STR3## or --(CH.sub.2).sub.n CHOH(CH.sub.2).sub.n --; whereinR.sup.2 is H, methyl, ethyl or propyl;n is 1-10, and pharmaceutically acceptable salts thereof have antiallergy and antiinflammatory activity.
    Type: Grant
    Filed: July 9, 1984
    Date of Patent: November 12, 1985
    Assignee: USV Pharmaceutical Corp.
    Inventors: Howard Jones, Ernest Magnien, John H. Musser, Mujahid L. Shaikh
  • Patent number: 4539408
    Abstract: Quaternary sulfoalkyl or sulfoalkenyl salts of tertiary amine bases are prepared by reacting the tertiary amine bases at elevated temperatures with a hydroxy alkane sulfonic acid or a hydroxyalkene sulphonic acid.
    Type: Grant
    Filed: April 28, 1978
    Date of Patent: September 3, 1985
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Helmut Kampfer, Marie Hase, Max Glass
  • Patent number: 4508903
    Abstract: A process for the preparation of 4,4'-bis[benz(ox, othi or imid)azol-2-yl]stilbenes of the formula ##STR1## in which R, R.sup.1, R.sup.2 and R.sup.3 are identical or different and denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, chlorine, bromine, nitro or sulfo and X denotes oxygen, sulfur or NH, by reacting alkyl (4-halomethyl)iminobenzoates of the formula ##STR2## or their HCl or HBr salts, R denoting C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxyethyl and X denoting Cl or Br, with o-aminophenol, o-aminothiophenol or o-phenylenediamine and allowing the 2-benz(ox, othi or imid)azol-4-ylhalomethylbenzenes obtained thereby to react with an approximately equivalent amount of sodium tert.-butylate. The stilbene compounds obtained thereby are used as optical brighteners.
    Type: Grant
    Filed: April 25, 1983
    Date of Patent: April 2, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Lorenz Heiss
  • Patent number: 4454322
    Abstract: Process for the preparation of 2-benzoxazolone and derivatives by the reaction, in the liquid phase, at a temperature from 100.degree. to 500.degree. C. and a pressure from 20 to 500 bars, of an ortho-nitrophenol of the formula: ##STR1## in which R represents a hydrogen or halogen atom, an alkyl group containing from 1 to 10 carbon atoms or an alkoxy group OR' in which R' represents an alkyl group containing from 1 to 10 carbon atoms, and carbon monoxide under pressure, characterized in that the process is carried out in the presence ofa. a supported catalyst formed by the association of a noble metal of Group VIII and a second transition metal selected from Groups, V.sub.b, VI.sub.b or VIII of the Periodic Classification, in the metallic or oxide form, andb. a nitrogenous heteroaromatic base; the process may be carried out in the presence of a solvent.
    Type: Grant
    Filed: January 24, 1983
    Date of Patent: June 12, 1984
    Assignee: Atochem
    Inventors: Jacques Kervennal, Jean-Marie Cognion, Pierre Durual
  • Patent number: 4371607
    Abstract: This invention relates to a novel 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivative; to a radiation-sensitive composition which, as the radiation-sensitive compound, contains a 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivative; and to a process for the preparation of the novel 4-halogeno-5-(halogenomethyl-phenyl)-oxazole derivatives.
    Type: Grant
    Filed: June 9, 1981
    Date of Patent: February 1, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Reinhard Donges
  • Patent number: 4371606
    Abstract: This invention relates to a novel 2-(halogenomethyl-phenyl)-4-halogeno-oxazole derivative; to a radiation-sensitive composition which, as the radiation-sensitive compound, contains a 2-halogenomethyl-phenyl)-4-halogeno-oxazole derivative; and to a process for the preparation of the novel 2-(halogenomethyl-phenyl)-4-halogeno-oxazole derivatives.
    Type: Grant
    Filed: June 9, 1981
    Date of Patent: February 1, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Reinhard Donges
  • Patent number: 4363814
    Abstract: Racemic or optically active compounds of the formulaQ--C.sub.n H.sub.2n --NH--Rwherein Q is ##STR1## where R.sub.1 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, trifluoromethyl or amino,R.sub.2 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms or trifluoromethyl, orR.sub.1 and R.sub.2, together with each other, are methylenedioxy or ethylenedioxy;n is an integer from 2 to 6, inclusive; andR is hydrogen, benzyl or ##STR2## and non-toxic, pharmacologically acceptable acid addition salts thereof. The compounds as well as their salts are useful as vasodilators and CNS-stimulators.
    Type: Grant
    Filed: December 22, 1980
    Date of Patent: December 14, 1982
    Assignee: Boehringer Ingelheim GmbH
    Inventors: Anton Mentrup, Kurt Schromm, Ernst-Otto Renth, Richard Reichl, Werner Traunecker
  • Patent number: 4327209
    Abstract: Benzazolyl compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are specific substituents, X is oxygen or R.sub.3 N--, Q is a radical of the formula ##STR2## wherein R.sub.4 denotes specific substituents, and A is 2,5-furylene, 2,5-thenylene or a bridge member which contains at least one double bond between 2 carbon atoms or is the direct bond. These compounds are obtained by condensation of organic carboxylic acids with aminobenzenes in diphenyl ether or a mixture of diphenyl ether and diphenyl.
    Type: Grant
    Filed: November 28, 1980
    Date of Patent: April 27, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Werner Schreiber
  • Patent number: 4311786
    Abstract: Direct-positive photographic material which has at least one layer which contains a silver halide emulsion surface-fogged by chemical means or by exposure and, as a sensitizer, a trinuclear tetramethinecyanine dye in which all or some of the methine hydrogen atoms have been replaced by fluorine, chlorine, bromine or iodine atoms. The novel trinuclear tetramethinecyanine dyes impart an excellent blue-sensitivity to the photographic materials. Furthermore, high maximum densities and very low minimum densities are achieved.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: January 19, 1982
    Assignee: Ciba-Geigy AG
    Inventors: Rolf Steiger, Jean F. Reber
  • Patent number: 4271158
    Abstract: Racemic and optically active compounds of the formulaQ--C.sub.n H.sub.2n --NH--RwhereinQ is ##STR1## where R.sub.1 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, trifluoromethyl or amino,R.sub.2 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atomsor trifluoromethyl,R.sub.1 and R.sub.2, together with each other, are methylenedioxy or ethylenedioxy, andA is --O--, --CH.sub.2 --CH.sub.2 --, or --NR.sub.3 -- where R.sub.3 is hydrogen or alkyl of 1 to 4 carbon atoms,n is an integer from 2 to 6, inclusive, andR is hydrogen, benzyl or ##STR2## where R.sub.4 is hydrogen, methyl or ethyl,R.sub.5, R.sub.6 and R.sub.7, which may be identical to or different from each other, are each hydrogen, halogen, hydroxymethyl, trifluoromethyl, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, nitro, cyano, --CONHR.sub.3, --CONHOH, --COOR.sub.3, R.sub.8 O--, methylsulfonylmethyl or, when one or two of R.sub.5 through R.sub.
    Type: Grant
    Filed: December 13, 1979
    Date of Patent: June 2, 1981
    Assignee: Boehringer Ingelheim GmbH
    Inventors: Anton Mentrup, Kurt Schromm, Ernst-Otto Renth, Richard Reichl
  • Patent number: 4269846
    Abstract: New benzoheterocyclic oxadiazolones and triazolones are described. These compounds are useful as anti-allergic reagents.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: May 26, 1981
    Assignee: USV Pharmaceutical Corporation
    Inventors: Fu C. Huang, John H. Musser
  • Patent number: 4267343
    Abstract: A process for the manufacture of 2,5-bis-(benzoxazolyl)-thiophenes of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 represent hydrogen or certain non-chromophoric substituents and each of R.sub.4 and R.sub.5 independently represents a hydrogen atom or an alkyl group or together they represent a trimethylene or tetramethylene radical, by reacting a sulphide of the formula ##STR2## with a dicarbonyl compound of the formula ##STR3## or with a derivative thereof is described.
    Type: Grant
    Filed: November 14, 1979
    Date of Patent: May 12, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Leonardo Guglielmetti
  • Patent number: 4263153
    Abstract: A dispersant or dispersant mixture that is useful in fuel and lubricant compositions, and that is characterized by its derivation from a long chain dicarboxylic acid material and an amino alcohol, is stabilized against oxidation by sulfurization by reaction with sulfur or with a sulfur compound selected from the group consisting of carbon disulfide, sulfides of phosphorus including P.sub.2 S.sub.5 and P.sub.4 S.sub.3, and phosphosulfurized olefins. More particularly, the dispersant so treated will usually comprise a mono or bis-oxazoline prepared by reaction of a hydrocarbyl-substituted C.sub.4 -C.sub.10 dicarboxylic acid or anhydride or ester thereof, having at least 50 carbon atoms in the hydrocarbyl group, with a 2,2-disubstituted 2-amino-1-alkanol that has from two to three hydroxy groups and that contains from 4 to 8 total carbon atoms.
    Type: Grant
    Filed: October 11, 1979
    Date of Patent: April 21, 1981
    Assignee: Exxon Research & Engineering Co.
    Inventors: Rosemary O'Halloran, Esther D. Winans
  • Patent number: 4249010
    Abstract: The subject of the invention are dyestuffs of the formula ##STR1## wherein R is hydrogen or a hydrocarbon radicalQ is arylX is .dbd.C(W)-- or .dbd.N--,W is a nitrile ester or amide groups andA represents the remaining members of a heterocyclic radical.The dyestuff are preferably suitable for dyeing polyester fibres which are dyed in orange, red, violet or bluish shades with good fastness to light.
    Type: Grant
    Filed: October 15, 1979
    Date of Patent: February 3, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventor: Horst Harnisch
  • Patent number: 4174321
    Abstract: The invention relates to polychromophoric dibenzoxazole compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the polychromophoric dibenzoxazole composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.
    Type: Grant
    Filed: September 1, 1977
    Date of Patent: November 13, 1979
    Assignee: Eastman Kodak Company
    Inventors: Richard H. S. Wang, Joseph S. Zannucci