The Chalcogen Is Part Of A -c(=x)x- Group, Wherein The X's Are The Same Or Diverse Chalcogens Patents (Class 556/147)
  • Patent number: 4908462
    Abstract: A cobalt recovery method wherein cobalt ions are selectively shifted into an extraction agent mainly composed of either 2-ethyl hexylphosphonate mono-2-ethyl hexylester or di-2 ethyl hexylphosphate in order to extract and separate the cobalt from a solution containing cobalt salts. The method further has a step of stripping the cobalt into an aqueous solution of oxalic acid by bringing the extraction agent containing the cobalt into contact with the aqueous solution of oxalic acid after separation from nickel ion, sodium salt, calcium salt, etc. Cobalt oxalate which does not contain any other salt is then recovered.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: March 13, 1990
    Assignee: Starloy Industrial Co., Ltd.
    Inventor: Nobuo Ohtsuka
  • Patent number: 4866093
    Abstract: The dihydro-M-4 and dihydro-IsoM-4 hydroxy carboxylic acids of the formula (II): ##STR1## wherein one of R.sup.1 represents a hydrogen atom and the other represents a hydroxy group and wherein the structure shown as ##STR2## represents a structure of formula ##STR3## and the salts and esters of said acids. The invention also provides pharmaceutical compositions containing said acids, salts and/or esters which are useful for inhibiting cholesterol biosynthesis in the liver.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: September 12, 1989
    Assignee: Sankyo Company Limited
    Inventors: Akira Terahara, Minoru Tanaka
  • Patent number: 4803291
    Abstract: The disclosed particulate composition of simple or mixed oxalate of ferromagnetic metals is characterized in that it is provided in the form of needle-shaped particles having a length comprised between 0.05 and 0.5 micrometer, with a proportion higher than 60% of particles having a length equal to the average length .+-.0.1 .mu.m. and an acicular ratio higher than 3, said average length being comprised between 0.15 and 0.35 .mu.m; its preparation and its application are also disclosed.
    Type: Grant
    Filed: July 2, 1987
    Date of Patent: February 7, 1989
    Assignees: Centre National de la Recherche Scientifique, Universite Paul Sabatier
    Inventors: Abel Rousset, Christiane B. Salvaing, Paul Mollard, Alain Manoux, Philippe Tailhades
  • Patent number: 4760170
    Abstract: A solution process is disclosed for preparing a solubilized metal salt ester by reacting an ester compound, such as 2,2'-thiodiethyl-bis (octadecenyl) succinate ester, with a metal carboxylate, such as calcium acetate, in the process of a mixture of (a) a first co-solvent and/or third co-solvent, such as toluene and/or dodecylbenzene respectively, and (b) a second co-solvent such as methanol, to form the metal salt ester product and an effluent mixture of an acid, such as acetic acid, optional co-solvent first, and second co-solvent, followed by the optional addition of a third co-solvent, and vacuum distilling the resulting mixture to remove the effluent mixture to produce a solution of the product and third co-solvent.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: July 26, 1988
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Jack Ryer, John G. Hedin, Robert A. Kleist, Stanley J. Brois
  • Patent number: 4748259
    Abstract: Mixtures of a metal salt of formula ##STR1## and a metal salt of formula ##STR2## in which formulae (1) and (2) Me is a metal ion of valency n,n is 2, 3 or 4, andeach of the rings A and B independently of the other is unsubstituted or substituted by halogen, lower alkyl, lower alkoxy or an .alpha.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: May 31, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Hermann Nachbur
  • Patent number: 4745203
    Abstract: Mixtures of a metal salt of formula ##STR1## and a metal salt of formula ##STR2## in which formulae (1) and (2) Me is a metal ion of valency n,n is 2, 3 or 4, andeach of the rings A and B independently of the other is unsubstituted or substituted by halogen, lower alkyl, lower alkoxy or an .alpha.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: May 17, 1988
    Assignee: Ciba-Geigy Corporation
    Inventor: Hermann Nachbur
  • Patent number: 4716239
    Abstract: New nickel composition having substantial solubility in hydrocarbons and prepared by reacting at least one inorganic divalent compound, at least one halogenoacetic acid and at least one ester of the formula R.sub.1 COO R.sub.2 wherein R.sub.1 is hydrogen or hydrocarbyl and R.sub.2 is hydrocarbyl.The resultant composition can be used in admixture with a hydrocarbylaluminum halide as catalyst for olefin dimerization.
    Type: Grant
    Filed: November 28, 1984
    Date of Patent: December 29, 1987
    Assignee: Institut Francais du Petrole
    Inventors: Gerard Provin, Alain Forestiere, Dominique Commereuc
  • Patent number: 4695587
    Abstract: Tetrahydro-M-4 and tetrahydro-IsoM-4 hydroxy carboxylic acids of the formula (II): ##STR1## wherein one of R.sup.1 and R.sup.2 represents a hydrogen atom and the other represents a hydroxy group, and the salts and esters of said acids which are useful for inhibiting chloresterol biosynthesis in the liver. The invention also provides pharmaceutical compositions containing said acid(s).
    Type: Grant
    Filed: April 26, 1984
    Date of Patent: September 22, 1987
    Assignee: Sankyo Company Limited
    Inventors: Akira Terahara, Minoru Tanaka
  • Patent number: 4687658
    Abstract: Homologs of Diester-DTPA-Paramagnetic compounds (such as dimethyl acetyl diethylene triamine triacetic acid) provide excellent contrast agents for magnetic resonance imaging (MRI). The magnetic dipole generated by the unpaired electron within the paramagnetic (PM) atom, causes a local reduction in the bulk magnetic field of the MRI system. The resulting shorting of the T1 (spin lattice) relaxation time in the local hydrogen protons within the area of interest, causes an intense "free induction signal" and a corresponding modulation in the collected scanning data. The tissue or organ of interest appears on the MRI display highlighted in white. Background tissue is displayed as darker or lower intensity greys. The ester homologs replace two carboxylic acids to form functional ester groups on the DTPA chelator. The homologs cause the Diester-DTPA-PM contrast agents to go into solution readily, and promotes organ selectivity.
    Type: Grant
    Filed: October 4, 1984
    Date of Patent: August 18, 1987
    Assignee: Salutar, Inc.
    Inventor: Steven C. Quay
  • Patent number: 4687869
    Abstract: The invention relates to metal salicylates of the formula ##STR1## wherein Me is a metal ion of valency n,n is 2, 3 or 4, andeach of the rings A and B independently of the other is unsubstituted or substituted by halogen, lower alkyl, lower alkoxy or an .alpha.-methylbenzyl radical.The metal salicylates are particularly suitable developers for the color former in pressure-sensitive or heat-sensitive recording materials.
    Type: Grant
    Filed: October 11, 1985
    Date of Patent: August 18, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Hermann Nachbur
  • Patent number: 4678496
    Abstract: As new compound is provided a cyclohexane derivative of the formula ##STR1## wherein R represents a hydrogen atom or an alkyl group, an alkylthioalkyl group or an unsubstituted or substituted phenyl group; and R.sup.1 represents an alkyl group, an unsubstituted or substituted benzyl group, a phenethyl group, a phenoxymethyl group, a 2-thienylmethyl group, an alkoxymethyl group or an alkylthiomethyl group, or a salt of said cyclohexane compound.This cyclohexane compound exhibits useful plant-growth regulating effects on crop-plants and also non-crop plants such as lawn and may be prepared by cyclization of an acetonylsuccinic acid dialkyl ester, followed by reaction with an organic acid chloride and by intermolecular rearrangement.
    Type: Grant
    Filed: August 1, 1985
    Date of Patent: July 7, 1987
    Assignee: Kumiai Chemical Industry Co., Ltd.
    Inventors: Kenji Motojima, Takeshige Miyazawa, Yasufumi Toyokawa, Masafumi Matsuzawa, Hiroshi Hokari, Shoji Kusano
  • Patent number: 4678854
    Abstract: Complex salts of cobalt useful for nutritional supplementation to provide cobalt in a form which effectively increases the bioavailability of cobalt, assuring adequate dietary requirement for growth and production of vitamin B.sub.12 by microorganisms present in the gut.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: July 7, 1987
    Assignee: Zinpro Corporation
    Inventor: Mahmoud M. Abdel-Monem
  • Patent number: 4633001
    Abstract: A process for preparing transition metal salt compositions of organic carboxylic acids having improved properties wherein the transition metal is one capable of having a multiplicity of oxidation states is described. The process comprises the steps of (a) providing at least one transition metal compound wherein the transition metal is at one of its higher positive oxidation states, (b) treating said transition metal compound with at least one reducing agent forming an intermediate containing the transition metal in a lower positive oxidation state, (c) reacting said intermediate with at least one organic carboxylic acid to form the transition metal salt of said carboxylic acid, and (d) mixing said transition metal salt formed in step (c) with (i) at least one antioxidant, or (ii) at least one additional metal salt wherein the additional metal is more electronegative than the transition metal, or (iii) mixtures of (i) and (ii).
    Type: Grant
    Filed: December 18, 1984
    Date of Patent: December 30, 1986
    Assignee: Mooney Chemicals, Inc.
    Inventor: Paul L. Cells
  • Patent number: 4594230
    Abstract: A process is disclosed for recovering cobalt in a relatively pure form from an impure cobalt bearing material. The process involves digesting the material in hydrochloric acid to form a solution essentially all of the cobalt and some impurities and insoluble material containing the remainder of the impurities, separating the solution from the insolubles, adding an oxalate producing compound in an amount sufficient to subsequently convert essentially all of the cobalt to cobalt oxalate to the solution, adjusting the pH of the oxalate treated solution to from about 1.5 to about 2.0 with a base to precipitate the cobalt, and finally separating the precipitate from the resulting mother liquor.
    Type: Grant
    Filed: February 4, 1985
    Date of Patent: June 10, 1986
    Assignee: GTE Products Corporation
    Inventors: Richard A. Scheithauer, Michael J. Miller, Clarence D. Vanderpool
  • Patent number: 4590255
    Abstract: A process for making metal salt (ionomers) of carboxylic acid-containing mono- and polyether polyol addition products by (1) reacting maleic acid, fumaric acid, itaconic acid, or mixtures thereof with at least one polyhydroxy-containing mono- or polyether compound (e.g. a polyether diol or triol) in the presence of a peroxy-type free radical initiator to form a carboxylic acid group-containing addition product and (2) neutralizing said addition product with a sufficient amount of metal ions selected from the group consisting of metals from Groups 1a, 2a, 8, 1b and 2b of the Periodic Table to convert at least about 10% of the carboxylic acid groups to ionomeric salt groups. These ionomers may be then changed into useful polyurethane elastomers by reaction with organic polyisocyanates.
    Type: Grant
    Filed: January 30, 1984
    Date of Patent: May 20, 1986
    Assignee: Olin Corporation
    Inventors: James M. O'Connor, Richard L. Frentzel
  • Patent number: RE32909
    Abstract: Metal oxycarboxylates are made by reacting a metal, a carboxylic acid, and hydrogen peroxide in aqueous reaction mixture. The metal oxycarboxylate is precipitated and removed from the reaction mixture in high yield and with high purity. The compound is effective in supplying the metal to plants, animals and humans.
    Type: Grant
    Filed: June 18, 1984
    Date of Patent: April 18, 1989
    Assignee: BioSystems Research Inc.
    Inventors: Joseph E. Lionelle, Jeffrey A. Staffa